Water treatment plant operation volume 2 7th edition answer key

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Water  Treatment  Plant  Operation  Volume  2.  A  Field 

Study  Training  Program.  Revised. 

California  State  Univ.,  Sacramento.  School  o£ 

Engineering.;  National  Environmental  Training 

Association,  Valparaiso,  IN. 

California  State  Dept.  of  Health  Services, 

Sacramento.  Sanitary  Engineering  Branch.; 

Environmental  Protection  Agency,  Washington,  DC. 

Office  of  Drinking  Water. 

88 

T-901361-01-0 

690p.;  Some  charts  and  drawings  may  not  reproduce 
well.  Pages  containing  final  examination  and  answers 
are  printed  on  dark  grey  paper  and  maybe 
illegible . 

Mr.  Ken  Kerri,  California  State 

University-Sacramento,  6000  J  Street,  Sacramento,  CA 
95819-2654. 

Guides  -  Classroom  Use  -  Guides  (For  Teachers)  (052) 
—  Guides  -  Classroom  Use  -  Materials  (For  Learner) 
(051)  —  Tests/Evrluation  Instruments  (160) 

MF04/PC28  Plus  Postage. 

Chemical  Analysis;  *Course  Content;  ^Drinking  Water; 
^Environmental  Education;  Fluoridation;  *Home  Study; 
Laboratory  Procedures;  Postsecondary  Education; 
Safety;  Training  Methods;  *Water  Quality;  *Water 
Treatment 


ABSTRACT 

The  purpose  of  this  water  treatment  field  study 
training  program  is  to:  (1)  develop  new  qualified  water  treatment 
plant  operators;  (2)  expand  the  abilities  of  existing  operators, 
permitting  better  service  both  to  employers  and  public;  and  (3) 
prepare  operators  for  civil  service  and  certification  examinations 
(examinations  administered  by  state/professional  associations  which 
operators  take  to  indicate  a  level  of  professional  competence). 
Voliune  2  is  a  continuation  of  voliune  1,  in  which  the  emphasis  was  on 
the  knowledge  and  skills  needed  by  operators  of  conventional  surface 
water  treatment  plants.  This  12-chapter  volume  contains  information 
on:  iron  and  manganese  control;  fluoridation;  softening; 
trihalomethanes;  demineralization;  handling  and  disposal  of  processed 
wastes;  maintenance;  instrumentation;  safety;  advanced  laboratory 
procedures;  drinking  v^ater  regulations;  and  administration. 
Objectives,  glossary,  lessons,  questions  (with  suggested  answers), 
and  a  test  are  provided  for  each  chapter.  A  final  examination  (with 
answers),  how  to  solve  water  treatment  plant  arithmetic  problems, 
water  abbreviations,  complete  glossary,  and  subject  index  are 
provided  in  an  appendix.  Information  on  objectives,  scope,  and  uses 
of  this  manual  and  instructions  to  participants  in  home-study  courses 
are  found  in  volume  1.  (TW) 


ERIC 


Environmental  Protection  Agency  Review  Notice 


This  training  manual  has  been  reviewed  by  the  Office  of  Drinking  Water, 
U.S.  Environmental  P  -^♦'^^tion  Agency  and  the  California  Department  of 
Health  Services.  Both  agencies  have  approved  this  manual  for  publication. 
Approval  does  not  signify  that  the  contents  necessarily  reflect  the  views 
and  policies  of  the  Environmental  Protection  Agency  nor  the  California 
Department  of  Health  Services.  Mention  of  trade  names  or  commercial 
products  does  not  constitute  endorsement  or  recommendation  for  use  by 
the  Environmental  Protection  Agency;  California  Department  of  Health 
Services;  California  State  University,  Sacramento;  National  Environmental 
Training  Association;  authors  of  the  chapters  or  project  reviewers,  consul- 
tants, and  directors. 


WATER  TREATMENT  PLANT  OPERATION 

Volume  II 
A  Field  Study  Training  Program 


prepared  by 

California  State  University,  Sacramento 

School  of  Engineering 
Applied  Research  and  Design  Center 


in  cooperation  with  the 
National  Environmental  Training  Association 


Kenneth  D.  Kern,  Project  Director 


for  the 

California  Department  of  Health  Services 
Sanitary  Engineering  Branch 
Standard  Agreement  #80-64652 
and 

U.S.  Environmental  Protection  Agency 
Office  of  Drinking  Water 
Grant  No.  T-901 361 -01-0 


1988 


ERIC 


OPERATOR  TRAINING  MANUALS 


OPERATOR  TRAINING  MANUALS  IN  THIS  SERIES  are  available  from  Ken 
Karri,  California  State  University,  Sacramento,  6000  J  Street,  Sacramento,  CA 
95819-2654,  phone  (916)  278-6142. 

1.  WATER  TREATMENT  PLANT  OPERATION,  2  Volumes, 

2.  SMALL  WATER  SYSTEM  OPERATION  AND  MAINTENANCE, 

3.  WATER  DISTRIBUTION  SYSTEM  OPERATION  AND  MAINTENANCE. 

4.  OPERATION  OF  WASTEWATER  TREATMENT  PLANTS,  2  Volumes, 

5.  ADVANCED  WASTE  TREATMENT, 

6.  INDUSTRIAL  WASTE  TREATMENT, 

7.  TREATMENT  OF  METAL  WASTESTREAMS, 

8.  PRETREATMENT  FACILITY  INSPECTION,  AND 

9.  OPERATION  AND  MAINTENANCE  OF  WASTEWATER  COLLECTION 
SYSTEMS,  2  Volumes. 

NOTICE 

This  manual  is  revised  and  updated  before  each  printing  based  on  comments 
from  persons  using  the  manual. 

First  printing,  1983  7,000 
Second  printing,  1988  5,000 


Copyright©  1988  by 
Hornet  Foundation,  Inc 
California  State  University,  Sacramento 


PREFACE 


VOLUME  II 


Volume  II  IS  a  continuation  of  Volume  I.  In  Volume  I.  the  emphasis  was  on  the  knowledge  and  skills  needed  by 
operators  of  cor  /entional  surface  water  treatment  plants.  Volume  II  stresses  information  needed  by  those 
operators  but  also  includes  information  on  specialized  water  treatment  processes  for  i^-on  and  manganese 
control,  fluoridation,  softening,  trihalomethanes.  demineralization  and  the  handling  and  disposal  of  process 
wastes.  Topics  of  importance  to  the  operators  of  all  water  treatment  plants  include  maintenance,  instrumenta- 
tion, safety,  advanced  laboratory  procedures,  water  quality  regulations,  administration,  and  how  to  solve  water 
treatment  plant  arithmetic  problems. 

You  may  wish  to  concentrate  your  studies  on  those  chapters  that  apply  to  your  water  treatment  plant.  Upon 
successful  completion  of  this  entire  volume,  you  will  have  gained  a  broad  and  comprehensive  knowledge  of  the 
entire  water  treatment  field. 

For  information  on: 

1.  Objectives  of  this  manual, 

2.  Scope  of  this  manual, 

3.  Uses  of  this  manual, 

4.  Instructions  to  participants  in  the  home-study  course,  and 

5.  Summary  of  procedure. 

please  refer  to  Volume  I. 

The  Project  Director  is  indebted  to  the  many  operators  and  other  persons  who  contributed  to  this  manual. 
Every  effort  was  made  to  acknowledge  material  from  the  many  excellent  references  in  the  water  treatment  field. 
Reviewers  Leonard  Ainsworth,  Jack  Rossum,  and  Joe  Monscvitz  deserve  special  recognition  for  their  extremely 
thorough  review  and  helpful  suggestions.  John  Trax.  Chet  Pauls,  and  Ken  Hay.  Office  of  Drinking  Water,  U.S.  En- 
vironmental Protection  Agency,  and  John  Gaston.  Bill  MacPherson,  Bert  Ellsworth,  Clarence  Young,  Ted  Bakker, 
and  Beverlie  Vandre.  Sanitary  Engineering  Branch.  Californici  Department  of  Health  Services,  ail  performed 
outstanding  jobs  as  resource  persons,  consultants  and  advisors.  Larry  Hannah  served  as  Education  Consultant. 
Illustrations  were  drawn  by  Martin  Garrity.  Charlene  Arora  helped  type  the  field  test  and  final  manuscript  for  print- 
ing. Special  thanks  are  well  deserved  by  the  Program  Administrator.  Gay  Kornweibel,  v/ho  typed,  administered 
the  field  test,  managed  the  office,  administered  the  budget,  and  did  everything  else  that  had  to  be  done  to  com- 
plete this  project  successfully. 

KENNE-^H  D.  KERRI 
PROJECT  DIRECTOR 


ERIC 


TECHNICAL  CONSULTANTS 


John  Brady 
Gerald  Davidson 
Larry  Hannah 


Jim  Sequeira 
Susuma  Kawamura 
Mike  Young 


NATIONAL  ENVIRONMENTAL  TRAINING  ASSOCIATION  REVIEWERS 

George  Kinias,  Project  Coordinator 
E.  E.  "Skeet"  Arasmith   Andrew  Holtan  William  Redman 


Terry  Engelhardt 
Dempsey  Hall 
Jerry  HIggins 


Deborah  Horton 
Kirk  Laflin 
Rich  Metcalf 


Kenneth  Walimaa 
Anthony  Zigment 


PROJECT  REVIEWERS 


Leonard  Ainsworth 
Ted  Bakker 
Jo  Boyd 
Dean  Chausee 
Walter  Cockrell 
Fred  Fahlen 
David  Fitch 
Richard  Haberman 
Lee  Harry 
Jerry  Hayes 
Ed  Henley 
Charles  Jeffs 


Chet  Latif 
Frank  Lewis 
Perry  Libby 
D.  Mackay 
William  Maguire 
Nancy  McTlgue 
Joe  Monscvitz 
Angela  Moore 
Harold  Mowry 
Theron  Palmer 
Eugene  Parham 
Catherine  Perman 


David  Rexing 
Jack  Rossum 
William  Ruff 
Gerald  Samuel 
Carl  Schwing 
David  Sorenson 
Russell  Sutphen 
Robert  Wentzel 
James  Wright 
Mike  Yee 
Clarence  Young 


ERIC 


7 


COURSE  OUTLINE 


WATER  TREATMENT  PLANT  OPERATION,  VOLUME 


1 .  The  Water  Treatment  Plant  Operator 
by  Ken  Kern 

2.  Water  Sources  and  Treatment 
by  Bert  Ellsworth 

3.  Reservoir  Management  and  Intake  Structures 
by  Dick  Barnett 

4.  Coagulation  and  Flocculatlon 
by  Jim  Beard 

5.  Sedimentation 
by  Jim  Beard 

6.  Filtration 

by  Jim  Beard 

7.  Disinfection 

by  Tom  Ikesaki 

8.  Corrosion  Control 
by  Jack  Rossum 


Page 
1 

15 
39 
91 
143 
195 
247 
333 


9.  Taste  and  Odor  Control 
by  Russ  Bowen 

10.  Plant  Operation 
by  Jim  Beard 

11.  Laboratory  Procedures 
by  Jim  Sequeira 

Appendix  by  Ken  Kern 

Final  Examination 

How  to  Solve  Water  Treatment 
Plant  Arithmetic  Problems 

Water  Abbreviations 

Water  Words 

Subject  Index 


Page 
373 

413 

455 

527 
528 

541 
586 
587 
633 


COURSE  CyiLINE 

WATER  TREATMENT  PLANT  OPERATION.  VOLUME  II 


Page 

12.  Iron  and  Manganese  Control  1 
by  Jack  Rossum 

13.  Fluoridation  25 
by  Harry  Tracy 

14.  Softening  63 
by  Don  Gibson  and  Marty  Reynolds 

1 5.  Trihalomethanes  1 1 5 
by  Mike  McQuIre 

1 6.  Dem  ineralization  1 35 
by  Dave  Argo 

17.  Handling  and  Disposal  of  Process  Wastes  179 
by  George  Uyeno 

18.  Maintenance  207 
by  Parker  Robinson 

19.  Instrumentation  331 
by  Leonard  Ainsworth 


20.  Safety 

by  Joe  Monscvitz 

21.  Advanced  Laboratory  Procedures 
by  Jim  Sequeira 

22.  Drinking  Water  Regulations 
by  Tim  Gannon 

23.  Administration 
by  Tim  Gannon 

Appendix  by  Ken  Kern 

Final  Examination 

How  to  Solve  Water  Treatment 
Plant  Arithmetic  Problems 

Water  Abbreviations 

Water  Words 

Subject  Index 


Page 
387 

445 

487 

535 

561 
563 
573 

599 
601 
649 


ERIC 


S 


CHAPTER  12 

IRON  AND  MANGANESE  CONTROL 

by 

Jack  Rossum 
with  a  special  section  by 
Gerald  Davidson 


o 

ERIC 


2  Plant  Operation 


TABLE  OF  CONTENTS 

Chap'^^r  12.   Iron  and  Manganese  Control 

OBJECTIVES   3 

GLOSSARY   4 

12.0  Need  to  Control  Iron  and  Manganese   5 

12.1  Measurement  of  Iron  and  Manganese    5 

12.10  Occurrence  of  Iron  and  Manganese   5 

12.11  Collection  of  Iron  and  Manganese  Samples   7 

12.12  Analysis  for  Iron  and  Manganese   7 

12.2  Remedial  Action   g 

12.20  Alternate  Source   9 

1 2.21  Phosphate  Treatment   9 

12.22  Removal  by  Ion  Exchange  11 

12.23  Oxidation  by  Aeration  12 

12.24  Oxidation  with  Chlorine   13 

12.25  Oxida  ion  with  Permanganate   13 

12.26  Operation  of  Filters   14 

12.27  Proprietary  Processes  by  Bill  Hoyer  14 

12.28  Monitoring  of  Treated  Water  15 

12.29  Summary   15 

12.3  Operation  of  an  Iron  and  Manganese  Removal  Plant 

by  Gerald  Davidson   1g 

1 2.30  Description  of  Process   1  g 

12.31  Description  of  the  Plant   17 

12.32  Operation  of  the  Greensand  Process   19 

12.4  Maintenance  of  a  Chemical  Feeder   20 

12.5  Troubleshooting  Red  Water  Problems  21 

12.6  Arithmetic  Assignment   21 

12.7  Additional  Reading   2i 

Suggested  Answers   22 

Objective  Test   23 


ERJC 


10 


iron  and  Mang^r.ese  3 


OBJECTIVES 

Chapter  12.   IRON  AND  MANGANESE  CONTROL 


Foilowing  completion  of  Chapter  12,  you  shoula  be  able 
to: 

1.  Identify  and  describe  the  various  processes  used  to 
control  iron  and  manganese, 

2.  Collect  samples  for  analysis  of  iron  and  manganese, 

3.  Safely  operate  and  maintain  the  following  iron  and  man- 
ganese control  processes: 

a.  Phosphate  treatment, 

b.  ton  exchange, 

c.  Oxidation  by  aeration, 

d.  Oxidation  with  chlorine, 

e.  Oxidation  v/ith  permanganate, 

f.  Greensand, 

g.  Proprietary  processes,  and 

4.  Troubleshoot  red  water  problems. 


ERIC 


11 


4  Plant  Operation 


GLOSSARY 

Chapter  12.    IRON  AND  MANGANESE  CONTROL 


ACIDIFIED  (uh-SID-uh-FIE-d)  ACIDIFIED 

Smnte  so  it  w^n^rfJnS."?''''  °'  '."""h"^  *°  '  '"'"'"^  *°  2.0.  The  purpose  of  acidification  is  to  "fix"  a 

sample  so  it  won  t  change  until  it  js  analyzed. 

AQUIFER  (ACK-wi-fer)  ^0^^,^^^ 
suSSj  of  water^'°""'^        °'  ^^'^'-''""'^9  "^^'^^'als  (sand,  gravel)  usually  capable  of  yielding  a  large  amount  or 

BACKFLOW 

JfTn^fihi'°''ff  '"7^*^"  ^  difference  In  water  pressures,  which  causes  water  to  flow  back  into  the  distribution  pipes 
or  a  potable  water  supply  from  any  source  or  sources  other  than  an  intended  source.  Also  see  BACKSIPHONAGE. 

BACKSIPHONAGE  BACKSIPHONAGE 
A  form  of  backflow  caused  by  a  negative  or  below  atmospheric  pressure  within  a  water  system.  Also  see  BACKFLOW. 

BENCH  SCALE  TESTS  BENCH  SCALE  TESTS 

A  method  of  studying  different  ways  or  chemical  doses  for  treating  water  on  a  small  scale  in  a  laboratory. 

BREAKPOINT  CHLORINATION  BREAKPOINT  CHLORINATION 

TlfZZ°L':\^?rl^^nl^^TJ,  ""h-  has  been  satisfied.  At  this  point,  further  additions  of  chlorine  will  result  in 

a  free  residual  chlonne  that  is  directly  proportional  to  the  amount  of  chlorine  added  beyond  the  breakpoir>t. 

CHELATION  (key-LAY-shun)  CHELATION 
J/pn'^'f  1''^'",'"^'' °'  i°i"'"9  together)  of  metallic  cations  (such  as  copper)  with  certain  organic  compounds,  such 
SEQUESTR?TloS^  '  "'"'^  *°  P'^'^"*       precipitation  of  metals  (copper).  Also  see 

COLLOIDS  (CALL-loids)  COLLOIDS 

an'li^lrSfihJno'^^  ^^^"^'1^^,  '^""^'^  dispersed  in  a  liquid  for  a  long  time  due  to  their  small 

Thi^  ron  t         charge^ When  rnost  of  the  particles  in  water  have  a  negative  electrical  charge,  they  tend  to  repel  each  other 
This  repulsion  prevents  the  particles  from  clumping  together,  becoming  heavier,  and  settling  out. 

DIVALENT  (die-VAY-lent)  DIVALENT 
Having  a  valence  of  two,  such  as  the  ferrous  ion.  Fe^^.  Also  called  BIVALENT. 

^^^^^^'^^O  GREENSAND 

?/n?h'i'j"^f"'^  1°°"^  ""^  ^^"'^  ^'''^^P*  9^««" t^o'or-  The  sand  is  a  natural  ion  exchange  matenal  which  is 

capable  of  softening  water  and  removing  iron  and  manganese.  "'aiei.ai  w.i.un  it, 

INSOLUBLE  (in-SAWL-you-bull)  INSOLUBLE 
Something  that  cannot  be  dissolved. 

'^"^  ^^^"^'^^^  ION  EXCHANGE 

?nM!!c,n®n"!f"*  ''K,''^-^^  reversible  interchange  (switching)  of  ions  between  the  water  being  treated  and  the 

solid  resin.  Undesirable  ions  in  the  water  are  switched  with  acceptable  ions  on  the  resin. 

ION  EXCHANGE  RESINS  ,0^  EXCHANGE  RESINS 

ERIC  12 


Iron  and  Manganese  5 


RESINS 

See  ION  nXCHANGE  RESINS. 


RESINS 


SEQUESTRATION  (SEE-kwes-TRAY-shun)  SEQUESTRATION 

A  chemical  complexing  (forming  or  joining  together)  of  matallic  cations  (such  cs  iron)  with  certain  inorganic  compounds,  such 
as  phosphate  Sequestration  prevents  the  precipitation  of  the  metals  (iron).  Also  see  CHELATION. 


ZEOLITE 


ZEOLITE 


A  type  of  ion  exchangt  '-^aterial  used  to  soften  water.  Natuial  zeolites  are  siliceous  compounds  (made  of  silica)  which  remove 
calCM  *^  and  m'.gnesiui..  m  hard  water  and  replace  them  with  sodium.  Synthetic  or  organic  zeolites  a'-e  ion  exchange  materi- 
als \  ,  rc^iCva  ca'c:  jm  or  magnesium  and  replace  them  with  either  sodium  or  hydrogen.  Manganese  zeolites  are  used  to  re- 
move .dnganese. 


ERIC 


13 


6  Plant  Operation 


CHAPTER  12.    IRON  AND  MANGANESE  CONTROL 


12.0    NEED  TO  CONTROL  IRON  AND  MANGANESE 

Like  the  cit»es  of  Minneapolis  and  St.  Paul,  iron  and 
manganese  are  referred  to  as  a  pair.  They  are,  in  fact,  two 
distinct  elements  and  are  often  found  in  vyater  separately 
Neither  of  them  has  any  direct  adverse  health  effects. 
Indeed,  both  are  essential  to  the  growtli  of  many  plants  and 
animals,  including  humans. 

However,  the  iron  and  manganese  found  in  drinking  water 
have  no  nutrient  value  for  humans.  Even  if  they  were 
available  in  beneficial  amounts,  the  presence  of  iron  and 
manganese  m  drinking  water  would  still  be  objectionable. 

Clothes  laundered  in  water  containing  Iron  and  manga- 
nese above  certain  levels  come  out  stained.  When  bleach  is 
added  to  remove  the  stains,  they  are  only  Intensified  and 
become  fixed  so  that  no  amount  of  further  washing  with 
iron-free  water  will  remove  the  stains.  They  can  be  removed 
by  treatment  with  oxalic  acid,  but  this  is  rather  hard  on 
fabrics  or  by  the  use  of  commercial  rust  removers.  Exces- 
sive amounts  of  iron  and  manganese  are  also  objectionable 
because  they  impart  stains  on  plumbing  fixtures,  bath  tubs 
and  Sinks. 

Perhaps  the  most  troublesome  consequence  of  iron  and 
manganese  in  the  water  is  that  they  promote  the  growth  of  a 
group  of  microorganisms  known  as  iron  bacteria.  These 
organisms  obtain  energy  for  their  growth  from  the  chemical 
reaction  that  spontaneously  occurs  between  iron  and  man- 
ganese and  dissolved  oxygen.  These  bacteria  form  thick 
slimes  on  the  walls  of  the  distribution  system  mams.  Such 
slimes  are  rust  colored  from  iron  and  black  from  manga- 
nese. Variations  in  flow  cause  these  slimes  to  come  loose 
which  result  in  dirty  water  (a  big  source  of  consumer 
complaints).  Furthermore,  these  slimes  will  cause  foul  tastes 
and  odors  in  the  water. 

The  growth  of  iron  bacteria  is  controlled  by  chlonnation 
However,  when  water  contains,  ron  is  chlorinated,  the  iron 
is  converted  into  rust  particles,  and  manganese  is  converted 


into  a  jet  black  compound  called  manganese  dioxide  These 
materials  form  a  loosely  adherent  coating  on  the  pipe  walls, 
^leces  of  this  coating  will  break  loose  from  the  pipe  walls 
when  there  are  changes  or  reversals  of  flow  in  the  distribu- 
tion system. 

Iroii  and  manganese  in  water  can  be  easily  detected  by 
observing  the  color  of  the  inside  walls  of  filters  and  the  filter 
media  If  the  raw  water  is  prechlorinated,  there  will  be  black 
stains  on  the  walls  below  the  water  level  and  a  black  coating 
over  the  top  portion  of  the  sand  filter  bed.  This  black  co'^r 
will  usually  indicate  a  high  level  of  manganese  in  the  raw 
water  while  a  brownish-black  stain  indicates  the  presence  of 
both  iron  and  manganese. 

The  generally  acceptable  limit  for  iron  in  drinking  water  is 
0.3  mg/L  and  that  for  manganese  is  0  ^^5  mg/L.  However,  if 
the  water  contains  more  than  0.02  mg/^  of  manganese,  the 
operator  should  .  <itiate  an  effective  flushing  program  to 
avoid  complaints.  By  regularly  flushing  the  water  mams,  the 
buildup  of  black  manganese  dioxide  can  be  prevented. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  22. 

1 2  OA  What  problems  are  caused  by  iron  anc*  manganese  m 
drinking  water*? 

1 2  OB  How  can  the  growth  of  iron  bacteria  be  controlled*? 

1 2.0C  What  are  the  generally  acceptable  limits  for  iron  and 
manganese  in  urinkmg  water*? 

12.1    MEASUREMENT  OF  IRON  AND  MANGANESE 

12.10   Occurrence  of  Iron  and  Manganese 

Because  both  .ron  and  manganese  react  with  dissolved 
oxygen  to  form  INSOLUBLE  COMPOUNDS.^  they  arc  not 
found  in  high  concentrations  in  waters  containing  dissolved 
oxygen  except  as  COLLOIDAL  SUSPENSIONS^  of  the 
oxides.  Accordingly,  surface  waters  are  generally  free  from 
both  iron  and  manganese.  One  exception  to  this  rule  is  that 
manganese  up  to  one  mg/L  or  higher  may  be  found  in 
shallow  reservoirs  and  may  come  and  go  several  times  a 
year. 


^  Insoluble  Compounds  (in-SAWL-you-bull).  Compounds  that  cannot  be  dissolved 
?nr"^fnnL^f^^^^^  ^'"^'^  ^'^'^^^  ^^''^^  (particles  that  do  not  dissolve)  that  remain  dispersed  in  a  liquid 

fZn  f  inT.  t  '^/^^'!lf ^'^^  electrical  charge.  When  most  of  the  particles  in  water  have  a  negative  electrical  charge,  they 
tend  to  repel  each  other  This  repulsion  prevents  the  particles  from  clumping  together,  becoming  heavier,  and  settling  out. 

ERIC  :  ^ 


iron  and  Manganese  7 


Iron  or  manganese  is  most  frequently  found  in  water 
systems  supplied  by  wells  and  springs.  Horizontal  wells 
under  rivers  are  notoriously  prone  to  produce  water  contain- 
ing iron.  Bacteria  will  reduce  iron  oxides  in  soil  to  the 
soluble,  DIVALENT^  form  of  iron  (Fe'^)  which  will  produce 
groundwater  with  a  high  iron  content. 

Iron  bacteria  can  make  use  of  the  ferrous  ion  (Fe^').  These 
bacteria  will  oxidize  the  iron  and  use  the  energy  for  reducing 
carbon  dioxide  to  organic  forms  (sl.mes).  The  manganous 
ion  (Mn^^)  IS  used  in  a  similar  fashion  by  certain  bactena. 
Very  small  concentrations  of  iron  and  manganese  in  water 
can  cause  problems,  because  bacteria  obtain  the  nutrients 
(iron  and  manganese)  from  water  in  order  to  grow  even 
when  the  concentrations  are  very  low. 


flow  rate  is  suitable  for  filling  the  sample  bottle.  Allow  the 
sample  water  to  flew  for  at  least  one  minute  for  each  10  feet 
(3  m)  of  sample  lino  before  the  sample  is  collected. 

Samples  for  iron  and  manganese  should  be  tested  within 
48  hours  unless  they  have  been  acidified.  If  the  sample 
contains  any  clay  or  if  any  particles  of  rust  ire  picked  up 
from  a  steel  pipe  or  fitting,  an  acidified  sampL  will  dissolve 
the  iron  in  these  substances  and  the  results  will  be  too  high 
If  clay  or  rust  particles  are  observed  in  a  sample,  do  not 
acidify  and  request  lab  to  analyze  sample  immediately 
Furthermore,  many  laboratories  fail  to  be  sure  that  iron  and 
manganese  are  in  the  divalent  form  (Fe^^  or  Mn^^)  by  adding 
enough  nitric  acid  pnor  to  the  tests  to  lower  the  pH  to  less 
than  two,  so  laboratory  errors  may  be  even  greater  than 
sampling  errors. 


Iron  bacteria  are  found  nearly  everywhere.  They  are 
frequently  foun  j  in  irop  water  pipes  and  everywhere  else 
that  a  combination  of  dissolved  oxygen  and  dissolved  iron  is 
usually  or  frequently  present.  Or^ly  one  cell  of  iron  bacteria  is 
needed  to  start  an  infestation  ol  iron  bacteria  in  a  well  or  a 
distribution  system.  Unfortunately  it  is  almost  impossible  to 
dnil  a  well  and  maintain  stenle  conditions  to  prevent  the 
introduction  of  iron  bacteria. 

12.11    Collection  of  Iron  and  Manganese  Samples 

The  best  way  to  determine  if  there  Is  an  iron  and  manga- 
nese problem  in  a  water  supply  is  to  look  at  the  plumbing 
fixtures  in  a  couple  of  houses.  If  the  fixtures  are  stained, 
then  there  is  a  problem.  Determination  of  the  concentrations 
of  iron  and  manganese  in  water  is  useful  when  evaluating 
well  waters  for  use  and  treated  waters  for  effectiveness  of 
treatment  processes. 

The  results  of  tests  for  iron  and  manganese  are  wrong 
more  often  than  they  are  right.  This  is  because  samples  for 
these  substances  are  difficult  to  collect.  Both  iron  and 
manganese  form  loosely  adherent  (not  firmly  attached) 
scales  on  pipe  walls,  including  the  sample  lines.  When  the 
sample  tap  is  opened,  particles  of  scale  may  be  dislodged 
and  enter  the  sample  bottle.  If  many  of  these  particles  enter 
the  sample  bottle,  the  error  can  b  '^me  very  large.  Further- 
more, unless  the  sample  is  aciditied  (enough  nitric  acid 
added  to  drop  the  pH  to  less  than  2),  both  iron  and 
manganese  tend  to  form  an  adherent  scale  on  the  walls  of 
the  sample  bottle  in  the  few  days  that  sometimes  elapse 
before  the  analysis  is  started.  When  the  sample  is  poured 
from  the  bottle  for  testing,  most  of  the  iiron  and  manganese 
will  then  remain  inside  the  sample  bottle. 

To  avoid  this  situation,  samples  should  be  taken  from  a 
plastic  sample  line  located  as  close  to  the  well  or  other 
source  as  possible.  Open  the  sampling  tap  slowly  so  that  the 


12.12  Analysis  for  Iron  and  Manganese 

The  preferred  method  of  testing  for  iron  and  manganese  is 
atomic  absorption,  but  for  the  small  plant  the  equipment  is 
too  expensive.  With  careful  attention  to  laboratory  proce- 


dures, cole  rimetric  methods  (companng  colors  of  unknowns 
with  known  standards)  can  provide  sufficient  accuracy  in 
most  instances.  These  colorimetric  methods  use  either  a 
spectrophotometer,  a  filter  photometer,  or  the  less  satisfac- 
tory set  of  matched  Nesslei  tubes  with  standards.  Good 
results  have  been  obtained  by  the  use  of  properly  calibrated 
colonmeters  (Figure  12.1).  For  detailed  procedures  on  how 
to  use  a  spectrophotometer  to  measure  iron  and  manga- 
nese, see  Chapter  21,  "Advanced  Laboratory  Procedures." 


QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  22. 

12.1  A  How  do  iron  and  manganese  form  insoluble  com- 
pounds? 

12.1B  Why  must  iron  and  manganese  samples  be  acidified 
when  they  are  collected? 

12.1C  Where  sh'^uld  a  sample  for  iron  and  manganese 
testing  bi  ollected? 


3  Divalent  (die-VAY'leni).   Having  a  valence  of  two,  such  as  the  ferrous  ton,  Fe^\  Also  called  BIVALENT. 


ERIC  I 


8  Plant  Operation 


PANEL  ALARM 
(optional) 


RECOMMENDED 
(furnUhtd  by  cuatomtr) 


u 


SAMPLE 

'stream 


.1 


FLOWMETEn/ 
CONTROL  VALVE 
(r«coinmtnd«d) 


STRAINER 
(optlonit) 


SHUT-OPP 
VALVE 


ALTERNATE 
WATER 
SUPPLY 


CONTROLLER 
(option  tl) 


RECORDER 
(opilonil) 


TYPICAL  INSTALLATION 


Fig.  12, 1   Typical  continuous  on-line  pump-colorimeter  analyzer 
for  iron,  manganese  or  permanganate 

(Perm)SS»on  ol  Hach) 


16 


ERIC 


Iron  and  Manganese  9 


12.2  REMEDIAL  ACTION 

Several  methods  are  available  to  control  iron  and  manga- 
nese in  water.  This  section  discusses  how  to  operate  the 
most  common  treatment  processes. 

1 2.20  Alternate  Source 

The  construction  of  a  plant  to  remove  iron  and  manganese 
will  cost  as  much  as  or  more  than  a  new  well  so  it  pays  to  in- 
vestigate the  possibility  of  obtaining  an  alternate  supply  of 
water  that  is  free  from  iron  and  manganese.  This  investiga- 
tion should  include  samples  from  nearby  private  wells, 


1.  Treat  a  series  of  samples  with  a  standard  chlorine 
solution  to  determine  the  chlonne  dose  required  to  pro- 
duce the  desired  chlorine  residual. 

2.  Prepare  a  standard  polyphosphate  solution  by  dissolving 
1.0  gram  of  polyphosphate  in  a  liter  of  distilled  water. 

3.  Treat  another  senes  of  samples  with  varying  amounts  of 
polyphosphate  solution.  One  mL  of  the  standard  poly- 
phosphate solution  (0.1%  solution)  in  a  liter  sample  is 
equivalent  to  8.34  pounds  of  polyphosphate  per  million 
gallons  (see  Examples  2  and  3  on  pages  15  and  16).  Stir 
to  assure  Inat  the  polyphosphate  has  been  well  mixed; 
and  continue  stirnng  while  adding  the  previously  deter- 
mined chlonne  dose  so  as  to  minimize  the  creation  of 
high  concentrations  of  chlorine. 

4.  Observe  ♦^^e  samples  daily  against  a  white  background, 
noting  the  amount  of  discoloration.  The  proper  polyphos- 
phate dose  is  the  lowest  dose  that  delays  noticeable 
discoloration  for  a  perion  of  four  days. 


discussions  with  well  drillers  who  have  been  active  in  the 
locality  and  discussions  with  engineers  in  the  state  agency 
responsible  for  the  regulation  of  well  drilling. 

If  the  water  produced  by  the  well  contains  dissolved 
oxygen  along  with  iron  and  manganese,  this  is  an  indication 
that  water  is  being  drawn  from  more  th?n  one  AQUIFER.^ 
One  or  more,  of  the  aquifers  must  be  prooucing  water 
containing  dissolved  oxygen  but  is  free  of  iron  and  manga- 
nese since  oxygen  reacts  with  both  elements  to  form  insolu- 
ble compounds.  Furthermore,  it  is  highly  probable  that  the 
iron-  or  manganese-bearing  water  is  from  deeper  aquifers 
so  that  It  may  be  possible  to  cure  the  problem  simply  by 
sealing  off  these  deeper  aquifers. 

12.21   Phosphate  Treatment 

If  the  water  contains  manganese  up  to  0.3  mg/i.  and  less 
than  0.1  mg/L  of  iron,  an  inexpensive  and  reasonably 
effective  control  can  be  achieved  by  feeding  the  water  with 
one  of  the  polyphosphates  listed  below.  Chlonne  usually 
must  oe  fed  along  with  the  polyphosphate  to  prevent  the 
growth  cf  iron  bacteria.  The  effect  of  the  polyphosphate  is  to 
delay  the  precipitation  of  ox  dized  manganese  for  a  few  days 
so  that  the  scale  that  builds  on  the  pipe  walls  is  greatly 
reduced. 

The  chlonne  dose  for  phosphate  treatment  should  be 
sufficient  to  produce  a  free  chlonne  residual  of  approximate- 
ly 0.25  mg/L  after  a  five-minute  contact  time  (a  higher 
chlonne  dose  may  be  required  with  some  water  to  maintain  a 
free  chlorine  residual  of  at  least  0.2  mg/i.  throughout  the 
distribution  system). 

Any  of  the  three  polyphosphates  (pyrophosphate,  tnpoly- 
phosphate,  and  metaphosphate)  can  be  used,  but  sodium 
metaphosphate  is  effective  in  lower  concentrations  than  the 
others.  The  proper  phosphate  dose  is  determined  by  labora- 
tory BENCH  SCALE  TESTS^  in  the  following  manner 


Samples  for  the  above  bench  test  should  be  as  fresh  as 
possible  and  should  be  kept  away  from  direct  sunlight  lo 
avoid  heating. 


Polyphosphate  treatment  to  control  iron  and  manganese 
is  usually  most  effective  when  the  polyphosphate  is  added 
upstream  from  the  chlorine,  but  satisfactory  results  may  be 
obtained  by  feeding  them  together.  The  chlonne  should 
never  be  fed  ahead  of  the  polyphosphate  because  the 
chlorine  will  oxidize  the  iron  and  manganese  (cause  insolu- 
ble precipitates  to  form  too  soon). 

If  you  are  able  to  install  a  one-half  inch  (12  mm)  polyethyl- 
ene hose  in  the  well  so  that  it  discharges  a  few  inches  below 
the  suction  screen,  you  can  construct  a  very  satisfactory 
semi-automatic  feed  system.  Use  a  gas-feed  chlorinator 
whose  water  supply  is  obtained  from  the  well  discharge 
downstream  from  the  check  valve  (Figure  12.2).  In  this  way, 
the  chlorinator  operates  only  when  the  pump  is  running.  The 
chlonne  solution  is  fed  down  the  polyethylene  tube.  Poly- 
phosphate IS  fed  down  the  same  tube  by  means  of  a  plastic 
tee.  The  phosphate  is  fed  by  means  of  an  electrically 
operated  solution  feeder  so  connected  as  to  run  when  the 
well  pump  runs. 

The  chlorine  solution  flowing  through  the  polyethylene  is 
extremely  corrosive.  If  the  tube  does  not  discharge  into 
flowing  water,  the  corrosive  effect  of  the  solution  on  a  metal 
surface  can  be  disastrous.  Wells  have  been  destroyed  by 
corrosion  from  this  cause.  The  following  simple  test  should 
be  made  at  least  once  every  three  months. 


^  Aquifer  (ACK-wt-fer).  A  natural  underground  layer  of  porous,  water-beanng  materials  (sand,  gr&  nl)  usually  capable  of  yielding  a  large 
amount  or  supply  of  water. 

5  Bench  Scale  Tests.  A  method  of  studying  different  ways  or  chemicsil  doses  for  treating  on  a  small  scale  in  a  .aboratory 


17 


10  Plant  Operation 


POLYPHOSPHATE 
SOLUTION  FEEDER 


PLASTIC 
TEE 


CHLORINE 
SOLUTION 


GAS-FEED 
CHLORINATOR 


1=1 


PUMP 


t 


7777r7T7T77TT77T?7777T7T77 


POLYETHYLENE- 
HOSE 


WATER 
SUPPLY 


1 


CHECK  VALVE 


WATER  LEVEL 


-SUCTION  SCREEN 


PUMP 

DISCHARGE 


ERIC 


Fig.  12.2  Polyphosphate  and  chlorine  system 

18 


Iron  and  Manganese  11 


EXAMPLE  1 

1.  Calculate  the  time  required  for  water  to  flow  from  the 
Dump  suction  ;o  the  pump  discharge. 

a.  Record  the  following  information: 

(1)  Length  of  pump  column  from  suction  to  discharge 
in  feet,  324  ft. 

(2)  Diameter  of  pump  column  in  Inches,  8  in. 

(3)  Discharge  rate  from  pump  in  gallons  per  minute, 
423  GPM. 

b.  Calculate  the  volume  of  the  pump  column  In  inches. 

^^ci'Tn  '  =  {0.7tt5)(Diameter,^  ln)2(Length,  ft)(12  in/ft) 
=  (0.785){8  in)2(324  ft)(1?  in/ft) 
=  195,333  cubic  inches 

c.  Convert  the  pump  column  volume  from  cubic  inches  to 
gallons. 

Volume,  gal  =  Volume,  cu  in 

231  cu  in/gal 
^195,333  cu  in 

231  cu  in/gal 
=  846  gallons 

d.  Determine  the  time  required  for  the  water  to  flow  from 
the  pump  suction  to  the  pump  discharge. 

Time,  mm  =     VQ^^"^^,  gallons 

Pump  Discharge,  GPM 
^  846  gallons 
423  gal/min 
=  2.0  minutes 

2.  Turn  off  the  water  supply  to  the  chlorinator.  Since  some 
of  the  chlonne  in  the  feed  line  will  drain  into  the  well,  it 
may  take  several  minutes  for  the  chlonne  residual  to 
disappear.  Check  to  be  sure  there  is  no  chlorine  residual 
in  the  water. 

3.  Turn  the  chlorinator  back  on,  noting  the  exact  time.  Take 
samples  for  chlorine  residual  every  15  seconds.  If  the 
chlorine  residual  has  reached  Its  proper  value  within  30 
seconds  of  the  calculated  time,  you  can  be  sure  that  the 
polyethylene  tube  is  properly  positioned  below  the  suc- 
tion screen. 

Soiutlons  of  polyphosphate  containing  more  than  one-half 
pound  per  gallon  (60  gm/i.)  may  be  very  viscous  (thick  like 
molasses),  depending  upon  which  of  the  polyphosphates  is 
used.  Do  not  use  a  solution  much  over  48  hours  old  because 
the  polyphosphates  react  slowly  with  water  to  form  ortho- 
phosphates  which  are  much  less  effective  In  preventing 
manganese  deposits. 


There  are  some  reports  In  the  literature  of  the  successful 
use  of  tetrasodium  pyrophosphate  on  iron-bearing  waters, 
but  many  attempts  to  control  iron  have  failed.  The  available 
information  is  not  clear  as  to  whether  the  process  works 
only  under  special  conditions  or  whether  the  reports  of 
success  are  in  error. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  tnose  on  page  22. 

12.2A  If  a  well  produces  watercontaining  dissolved  oxygen 
as  well  as  iron  and  manganese,  how  would  you 
attempt  to  solve  the  iron  and  manganese  problem? 

1 2.2B  How  could  you  find  out  if  nearby  wells  produce  water 
containing  iron  and  manganese? 

1 2.2C  What  are  bench  scale  tests? 

12. 2D  Why  should  polyphosphate  solutions  over  48  hours 
old  not  be  used'? 

12.22   Removal  by  ION  EXCHANGE^ 


The  actual  location  of  the  ION  EXCHANGE  RESINS'^  with 
respect  to  other  water  treatment  processes  will  depend  on 
the  raw  water  quality  and  the  design  engineer.  If  the  water  to 
be  treated  contains  no  oxygen,  both  iron  and  manganese 
may  be  removed  by  ion  exchange  using  the  same  resins  that 
are  used  for  water  softening.  If  the  water  being  treated 
contains  any  dissolved  oxygen,  the  resin  becomes  fouled 
with  iron  rust  or  manganese  dioxide.  The  resin  can  be 
cleaned  but  this  is  expensive  and  the  capacity  is  reduced. 
Well  water  may  contain  no  oxygen  in  normal  operating 
conditions  except  immediately  after  the  well  is  first  turned 
on.  If  this  IS  the  case,  provisions  should  be  made  to  run  the 
well  to  waste  until  the  oxygen  is  no  longer  present. 

In  one  Eastern  city,  an  ion  exchange  plant  had  operated 
for  seven  years,  reducing  iron  from  52  mg/L  to  0.1  mg/L  and 
manganese  from  1.3  vng/L  to  zero.  When  a  pump  was 
repaired,  a  gasket  on  the  suction  side  of  the  pump  was 
improperly  installed,  allowing  air  to  enter  the  raw  water. 
Within  three  months  the  resin  was  fouled  by  iron  oxide. 

The  mam  advantage  of  ion  exchange  for  iron  and  manga- 
nese removal  is  that  the  plant  requires  little  attention.  The 
disadvantages  are  the  danger  of  fouling  the  ion  exchange 
resin  with  oxides  and  high  Initial  cost. 


^  Ion  Exchange  A  water  treatment  process  involving  the  reversible  interchange  (switching)  of  ions  between  the  water  being  treated  and 
the  solid  resin.  Undesirable  ions  in  the  water  are  switched  with  acceptable  ions  on  the  resins. 

7  Ion  Exchange  Resms  Insoluble  polymers,  used  in  water  treatment,  that  are  capable  of  exchanging  (switching  or  giving)  acceptable  cati- 
ons or  anions  to  the  water  being  treated  for  less  desirable  ions. 

d  19 

ERIC  \ 


12  Plant  Operation 


To  operate  an  ion  exchange  unit,  iry  to  operate  as  close 
as  possible  to  design  flows.  Monitor  the  treated  water  for 
iron  and  manganese  on  a  daily  basis.  When  iron  and 
manganese  start  to  appear  m  the  treated  water,  the  unit 
must  be  regenerated.  Regeneration  is  accomplished  with  a 
orine  solution  that  is  treated  with  0.01  pound  of  sodium 
bisulfite  per  gallon  (1.2  gm/L)  of  brine  to  remove  oxygen 
present.  After  regeneration  is  complete,  the  brine  must  be 
disposed  of  in  an  approved  manner. 

See  Chapter  14,  "Softening,"  for  procedures  on  how  to 
calculate  the  frequency  for  regenerating  the  unit  Details  are 
given  in  Chapter  17,  "Handling  and  Disposal  of  Process 
Wastes,"  on  how  to  properly  dispose  of  bnne  solutions. 

12.23  Oxidation  by  Aeration 

Iron  can  be  oxidized  by  aerating  the  water  to  form 
insoluble  ferric  hydroxide.  As  shown  in  Figure  12.3,  this 
reaction  is  accelerated  by  an  increase  in  pH.  The  rates 


indicated  in  Figure  12.3  were  determined  at  PS^'C  under 
laboratory  conditions.  If  the  water  contains  any  organic 
substances,  the  rates  will  be  significantly  lower,  reduced 
temperatures  will  also  lower  the  rates. 

Since  pH  is  increased  by  the  removal  of  carbon  dioxide,  it 
IS  important  that  the  aeration  (which  removes  carbon  diox- 
ide) be  as  efficient  as  possible.  Lime  is  sometimes  added  to 
the  woter  to  increase  the  pH  as  well  as  remove  carbon 
dioxide.  The  higher  the  pH,  the  shorter  the  time  required  for 
aeration,  as  shown  in  Fgure  12.3. 

Operation  of  the  aeration  process  to  remove  iron  and 
manganese  requires  careful  control  of  the  flow  through  the 
process.  If  the  flow  becomes  too  great,  not  enough  time  will 
be  available  for  the  reactions  to  occur.  Flows  are  controlled 
by  the  use  of  variable  speed  pumps  or  the  selection  of  the 
proper  number  or  combinations  of  pumps.  Carefully  monitor 
the  iron  and  manganese  content  of  the  treated  water.  If  iron 
IS  detected,  the  flews  may  have  to  be  reduced. 


6.00 


50 


100 


150  200 
TIME,  MINUTES 


250 


300 


350 


Fig.  12.3  pH  vs.  time  to  oxidize  99  percent  iron 


ERIC 


20 


iron  and  Manganese  13 


There  are  several  methods  of  providing  aeration.  Either 
the  water  being  treated  is  dispersed  (scattered)  into  the  air 
or  air  is  bubbled  through  the  water.  Aeration  may  be 
achieved  by  the  use  of  compressed  air  which  passes 
through  diffusers  in  the  water.  These  diffusers  produce 
many  small  bubbles  which  allow  the  transfer  of  oxygen  in  the 
air  to  dissolved  oxygen  in  the  water. 

Other  aeration  techniques  include  forced  draft,  nultiple 
trays,  cascades  and  sprays  These  methods  may  develop 
slime  growths  on  surfaces  or  coatings  on  media.  Slime 
growths  and  coatings  on  media  should  be  controlled  to 
prevent  the  development  of  tastes  and  odors  in  the  product 
water  and  the  sloughing  off  of  the  slimes.  Chlorination  may 
be  used  to  control  slime  growths  and  coatings.  Regularly 
inspect  aeration  equipment  for  the  development  of  anything 
unusual. 

A  reaction  basin  (sometimes  called  a  collection  or  deten- 
tion basin)  follows  the  aeration  process.  The  purpose  of  the 
reaction  basin  is  to  allow  time  for  the  oxidation  reactions  to 
take  place.  The  aeratior  process  should  produce  sufficient 
dissolved  oxygen  for  the  iron  to  be  oxidized  to  insoluble 
ferric  hydroxide.  A  minimum  recommended  detention  time  is 
20  minutes  with  desirable  detention  times  ranging  from  30  to 
60  minutes  (see  Example  4,  page  16).  As  shown  in  Figure 
12.3,  the  pH  of  the  water  strongly  influences  the  time  for  the 
reaction  to  take  place.  Sometimes  chlorine  is  added  before 
the  reaction  basin. 

The  reaction  basin  may  be  a  cylindncally  (circular)  shaped 
basin  similar  to  a  clarifier.  C'ten  the  basin  is  baffled  to 
prevent  short-circuiting  and  the  deposition  of  solids.  Since 
there  are  no  provisions  for  sludge  removal,  the  basin  must 
be  drained  and  cleaned  regularly.  If  the  basins  are  not 
cleaned,  slugs  of  deposits  or  sludge  or  also  mosquito  or  fly 
larvae  (young  or  any  insect)  could  reach  the  filters  in  the  next 
process  and  cause  thrm  to  plug. 

Operators  of  reaction  basins  must  always  be  on  the  alert 
for  potential  sources  of  contamination.  These  basins  should 
have  covers  and  protective  lids  to  keep  out  rain,  storm  water 
runoff,  rodents  and  insects.  All  vents  must  be  properly 
screened.  The  outlet  to  the  dram  must  not  be  connected 
directly  to  a  sewer  or  storm  water  drain.  There  must  be  an 
air  gap  or  some  other  protective  device  to  prevent  contami- 
nation from  BACKFLOW.^ 


After  the  fernc  hydrc  .rde  is  formed,  it  is  removed  by 
sedimentation  or  by  filtration  alone.  If  only  filtration  ts  used, 
water  from  the  reaction  basin  is  usually  pumped  to  pressure 
filters  for  filtration.  The  water  may  also  be  pumped  oi  flow  by 
gravity  to  rapid  sand  filters.  For  details  on  how  to  operate 
r.nd  maintain  filters,  see  Chapter  5,  "Filtration." 

The  oxidation  of  manganese  by  aeration  is  so  slow  that 
this  process  is  not  used  on  waters  with  high  manganese 
concentrations. 

The  main  advantage  of  this  method  is  that  no  chemicals 
are  required;  however,  lime  may  be  added  to  increase  the 
pH  The  major  disadvantage  is  that  small  changes  in  raw 
surface  water  quality  may  affect  the  pH  and  soluble  organics 
level  and  slow  the  oxidation  rates  to  a  point  where  the 
capacity  of  the  plant  Is  reduced. 

12.24  Oxidation  with  Chlorine 

Chlorine  will  oxidize  manganese  to  the  insoluble  manga- 
nese dioxide  and  will  oxidize  iron  to  insoluble  ferric  hydrox- 
ide which  can  then  be  removed  by  filtration.  The  hiyher  the 
chlorine  residual,  the  faster  this  reaction  occurs.  Some  very 
compact  plants  have  been  constructed  by  treating  the  water 
to  a  free  chlorine  residual  of  5  to  10  mg/L,  filtering,  and 
dechlorlnating  to  a  residua!  suitable  for  domestic  use.  Do  not 
use  high  doses  of  chlorine  if  the  water  contains  a  high  level 
of  organic  color  because  excessive  concentrations  of  total 
trihalomethanes  (TTHMs)  could  develop.  The  water  is  de- 
chlonnated  by  the  use  of  reducing  agents  such  as  sulfur 
dioxide  (SOg),  sodium  bisulfite  (NaHSOj),  and  sodium  sulfite 
(NagSOg).  Bisulfite  is  commonly  used  because  It  is  cheaper 
and  more  stable  than  sulfite.  When  dechlorlnating  with 
reducing  agents  be  very  careful  not  to  overdose  because 
inadequate  disinfection  could  result  (no  chlorine  residual 
remains^  and  if  the  dissolved  oxygen  level  in  the  water  is 
depleted,  fish  kills  could  occur  in  home  aquariums.  Fre- 
quently, a  reaction  basin  (as  described  in  Section  12.23, 
"Oxidation  by  Aeration")  is  installed  between  the  chlonnation 
processes  to  allow  time  for  the  reactions  to  occur. 

Chlorine  oxidizes  iron  to  insoluble  ferric  hydroxide  which 
IS  removed  by  filtration  along  with  the  manganese  dioxide. 

12.25  Oxidation  with  Permanganate 

Potassium  permanganate  oxidizes  iron  and  manganese  to 
insoluble  oxides,  and  can  be  used  to  remove  these  elements 
in  the  same  way  chlorine  is  used.  The  dose  of  potassium 
permanganate  must  be  exact.  Bench  scale  tests  are  re- 
quired to  determine  the  proper  dosage.  Too  small  a  dose  will 
not  oxidize  all  the  manganese  in  the  water  and  too  large  a 
dose  will  allow  permanganate  to  enter  the  system  and  may 
produce  a  pink  color  in  the  water.  Actual  observations  of  the 
water  being  treated  will  tell  you  if  any  adjustments  of  the 
chemical  feeder  are  necessary. 

Experience  from  many  water  treatment  plants  has  shown 
that  a  regular  filter  bed  (a  rapid  sand  filter  or  a  dual  media  fil- 
ter bed)  can  remove  manganese  as  long  as  iron  and  manga- 
nese are  both  under  one  milligram  per  liter.  These  plants  use 
either  chlonne  or  permanganate  to  oxidize  the  iron  and 
manganese  before  the  water  being  treated  flows  through  the 
filter  bed. 


Backflow  A  reverse  flow  conditior),  created  by  a  difference  in  water  pressures,  which  causes  water  to  flow  back  into  the  dis  nbution 
pipes  of  a  potable  water  supply  from  any  source  or  sources  other  than  an  intended  source. 


21 


14  Plant  Operation 


Potassium  permanganate  is  often  used  with  "manganese 
ZEOLITE^''  or  "manganese  GREENSAND.  "  Greensand  is  a 
granular  matenal.  After  the  greensand  has  been  treated  with 
potassium  permanganate  it  can  oxidize  both  iron  and  man- 
ganese to  their  insoluble  oxides.  The  greensand  also  acts  as 
a  filter.  This  mineral  is  regenerated  with  potassium  perman- 
ganate after  backwashing  to  remove  the  insoluble  oxides. 

A  modification  of  this  procedure  called  CR  (Continuous 
Regeneration)  consists  of  feec'  ng  a  potassium  permangan- 
ate solution  into  the  water.  If  ar.  excess  of  permanganate  is 
fed.  the  effluent  may  be  colored  pink.  For  more  information 
on  this  process,  see  Section  12.3.  "Operation  of  an  Iron  and 
Manganese  Removal  Plant." 

12.26  Operation  of  Filters 

When  iron  and  manganese  are  oxidized  to  insoluble  forms 
by  aeration,  chlorination  or  permanganate,  the  oxidation 
processes  are  usually  followed  by  filters  to  remove  the 
mciOluble  material.  In  addition  to  the  procedure*;  for  operat- 
ing and  maintaining  filters  that  were  outlined  in  'Chapter  6, 
Tiltrationr  the  procedures  discussed  in  this  section  apply  to 
filters  used  to  remove  iron  and  manganese. 

Iron  tests  should  be  made  monthly  on  the  water  entering  a 
filter  to  be  sure  the  iron  is  in  the  ferric  (Fe^^)  state.  Collect  a 
sample  of  the  water  and  pass  the  water  through  a  filter 
paper.  Run  an  iron  test  on  the  water  which  has  passed 
through  the  filter.  If  the  iron  is  still  in  the  soluble  ferrous 
(Fe^^)  state,  there  will  be  iron  in  the  water.  If  aeration  is  being 
used  to  o.cidize  the  iron  from  the  soluble  ferrous  to  the 
insoluble  ferric  state  and  iron  is  still  present  in  the  soluble 
state  in  the  water  entering  the  filter,  tr/  adding  chlonne  or 
potassium  permanganate.  If  chlorine  or  potassium  perman- 
ganate are  being  used  and  soluble  iron  Is  in  the  water 
entering  the  filter,  tr>'  Increasing  tne  chemical  dose.  If 
potassium  permanganate  is  being  used,  the  sand  may  be 
replaced  by  greensand  to  improve  the  efficiency  of  the 
process. 

If  oxidation  is  being  accomplished  by  either  aeration  o* 
chlorination,  a  free  chlorine  residual  must  be  maintained  in 
the  effluent  of  the  filter  to  prevent  the  insoluble  ferric  iron 
from  returning  to  ihe  soluble  ferrous  form  and  passing 
through  the  filter. 

Most  iron  removal  treatment  plants  are  designed  so  that 
the  filters  are  backwashed  according  to  head  loss.  If  iron 
breakthrough  is  a  problem,  filters  should  be  backwashed 
when  breakthrough  occurs  or  just  before  breakthrough  is 
expected.  Accurate  records  can  reveal  when  breakthrough 
occurs  and  also  when  breakthrough  can  be  expected. 

12.27  Proprietary  Processes  by  Bill  Hoyer 

There  are  several  patented  processes  that  are  available 
for  iron  and  manganese  control.  The  best  way  to  learn  about 
the  effectiveness  and  maintenance  requirements  of  these 
processes  is  to  contact  someone  who  has  one.  Once  you 
are  operating  one  of  these  processes,  the  manufacturer  is  a 
good  source  of  help  when  troubleshooting.  Remember  that 


various  sources  of  raw  water  are  different  ano  what  works 
for  one  operator  mav  not  work  at  your  water  treatment  plant. 

Electromedia  iron  and  manganese  removal  systems  are 
generally  used  on  groundwater  supplies  at  individual  well 
Sites  because  of  their  compactness  and  simplicity  of  treat- 
ment The  system  uses  reaction  vessels  where  chemical 
reactions  take  place  and  an  adsorbtive  media  that  requires 
no  regeneration  by  special  chemicals.  Chlorine  is  used  as 
the  oxidizing  chemical  because  of  its  cost  and  efficiency. 
(Any  suitable  oxidizing  chemical  can  be  used.)  Almost  30 
percent  less  chlorine,  pound  for  pound,  is  required  to 
perform  the  same  amount  of  oxidation  as  potassium  per- 
manganate. 

After  oxidation  with  chlorine  a  small  dose  of  sulfur  dioxide 
(0  25  to  0  50  mg/L)  is  introduced  prior  to  the  second  reaction 
vessel-  This  dosage  is  factory  set  according  to  the  general 
mineral  analysis  of  the  raw  water.  Dosage  should  not  ba 
altered.  The  sulfur  dioxide  is  used  to  accelerate  the  oxida- 
tion of  any  sulfur  compounds  in  the  water  to  form  com- 
pounds having  no  objectionable  taste  or  odor. 

The  water  is  then  sent  to  a  filter  operating  at  a  preset  rate 
of  up  to  15  gallons  per  minute  per  square  foot  (10  liters  per 
second  per  square  meter  or  10  millimeters  per  second).  In 
the  filter  vessel,  the  iron  and  manganese  are  adsorbed  on 
the  surface  of  the  media  until  backwashing.  The  media  can 
withstand  a  very  high  backwash  rate  (20  gallons  per  minute 
per  square  foot,  13.6  L/sec/sq  m  or  13.6  mm/sec)  and 
requires  only  a  four-minute  backwash  to  obtain  thorough 
cleaning. 

The  filter  effluent  can  t)e  sampled  by  a  continuously 
monitoring  analyzer  that  drn/es  a  30-day  strip  chart  recorder. 
The  recorder  may  have  a  color-coded  indicating  strip  to 
direct  the  operator  in  the  proper  chemical  dosage.  If  the 
recorder  trace  falls  out  of  the  green,  the  operator  increases 
the  chlorine  dosage.  The  dosage  is  adjusted  by  turning  one 
knob  and  can  be  read  immediately.  The  effect  of  the  change 
can  be  seen  on  the  chart  trace  in  five  minutes  and  will  reach 
a  steady  state  within  ten  minutes.  Thus  the  operator  can 
quickly  determine  the  proper  dosage.  With  the  chemical 
dosage  set  properly,  a  free  chlorine  residual  exists  in  the 
filter  effluent  providing  the  required  disinfection  in  the  distri- 
bution system.  Variations  in  water  quality  are  quickly  reflect- 
ed in  the  chart  tracing.  Since  no  permanganate  is  used,  there 
are  no  "black  water"  or  "pink  water"  complaints  from  acci- 
dental underdosage  or  overdosage  of  chemicals. 

The  process  uses  BREAKPOINT  CHLORINATION,^^  and 
the  very  effective  adsorbtive  qualities  of  the  media.  Each 
system  is  provided  with  an  automatic  control  panel  that 
permits  adjustment  of  any  of  the  filter  cycles  simply  by 
rotating  a  timer  knob.  Status  of  the  system  is  displayed  on 
the  front  panel  with  pilot  lights  for  easy  viewing.  The 
automatic  control  panel  operates  the  manually  set  chemical 
feed  system  using  gaseous  chlorine  and  gaseous  sulfur 
dioxide.  Backwash  ts  accomplis.hed  automatically  by  using  a 
process  signal  and  filtration  timer  with  a  differential  pressure 
override. 


^  Zeolite  A  type  of  ion  exchange  material  used  to  soften  water  Natural  zeolites  are  siliceous  compounds  (made  of  silica)  which  remove 
calcium  and  magnesium  from  hard  water  and  replace  them  with  sodium.  Synthetic  or  organic  zeolites  are  ion  exchange  materials  which 
remove  calcium  or  magnesium  and  replace  them  with  either  sodium  or  hydrogen.  Manganese  zeolites  are  used  to  remove  iron  and  man- 
ganese from  water. 

Greensand  A  sand  which  looks  like  ordinary  filter  sand  except  that  it  is  green  in  color.  The  sand  is  a  natural  ion  exchange  material 
which  is  capable  of  softening  water  and  removing  non  and  manganese. 
11  Breakpoint  Chlorination.  Addition  of  chlorine  to  water  until  the  chlorine  demand  has  been  satisfied.  At  this  point,  further  additions  of 
chlorine  will  result  in  a  free  residual  chlorine  that  is  directly  proportional  to  the  amount  of  chlorine  added  beyond  the  breakpoint. 


ERIC 


22 


Iron  and  Manganese  15 


Maintenance  on  the  system  is  quite  limited.  Most  systems 
are  built  with  an  automatic  standby  for  the  chemicals  that  will 
switch  from  an  empty  container  to  a  full  container.  Table 
12.1  lists  the  recommended  maintenance. 


Each  application  for  iron  and  manganese  removal  is 
based  on  the  general  mineral  analysis  of  the  raw  water.  The 
required  chemical  treatment  is  provided  for  iron,  manganese 
and  sulfide  treatment.  Additional  equipment  may  be  pro- 
vided where  corrosivity  and/or  chelating  compounds  are 
found  to  be  present.  Aeration  may  precede  the  process 
where  methane  extraction  and/or  carbon  dioxide  removal  is 
required  Plant  operators  are  directed  to  the  operation  and 
maintenance  instructions  provided  wi*h  the  equipment  for 
additional  details. 


12.29  Summary 

Small  iron  and  manganese  water  treatment  plants  can  be 
very  difficult  to  operate.  If  your  plant  is  not  operating  as 
desired,  talk  to  other  operators  in  your  area  and  see  if  they 
have  any  suggestions.  If  you  have  problems,  you  will  have  to 
try  different  chemical  doses  and  procedures.  Keep  accurate 
records  so  you  can  evaluate  the  effectiveness  of  your 
efforts. 


A  lot  of  "iron  complaints"  in  drinking  water  are  caused  by 
old  steel  or  cast  iron  water  mams.  A  possible  solution  to  this 
problem  is  to  inject  polyphosphates  directly  into  the  distribu- 
tion mams.  See  Section  12.5,  "Troubleshooting  Red  Water 
Problems,"  for  additional  ideas  on  how  to  solve  problems. 


TABLE  12.1    RECOMMENDED  MAINTENANCE  FOR  THE 
ELECTROMEDIA  PROCESS 

Datly    Weekly  Monthly 

1 .  Inspection  of  chart  paper  for  X 
proper  chemical  dosage 

2.  Free  chlorine  residual  test  X 

3.  Total  chlorine  residual  test  X 

4.  Addition  of  buffer  solution  in  X 
the  analyzer 

5.  Colorimetenc  analysis  of  the  X 
influent  and  effluent  for 

iron  concentration 

6.  Laboratory  tests  for  analysis  of  X 
influent  and  effluent  for  iron 

and  manganese  concentration 

7.  Changing  of  chart  paper  X 

8.  Routine  maintenance  checks  X 
associated  with  valves,  pipes 

and  pumps 


FORMULAS 

A  standard  polyphosphate  solution  is  prepared  by  mixing 
and  dissolving  a  known  amount  of  polyphosphate  in  a 
container  and  adding  distilled  water  to  the  one  liter  mark.  To 
determine  the  settings  on  polyphosphate  chemical  feeders: 

1 .  Prepare  a  series  of  samples  and  test  with  polyphosphate, 

2.  Select  the  optimum  dosage  in  mg/L,  and 

3.  Calculate  the  chemical  feeder  setting  in  pounds  of  poly- 
phosphate per  day. 

Stock        ^  (Polyphosphate,  grams)(1 000  mg/gram) 
mg/ml"'  (Solution.  Iiter)(1000  m/./l) 

Dose.  ^ (Stock  Solution.  mg/ml)(Volume  Added,  ml) 

"^9/^-  Sample  Volume,  L 

Dose,  ^(Dose,  mg/l)(3.785  l/gal)(  1.000,000) 

Ibs/MG       ^^QQQ  mg/gm)(454  gm/lb)(1  Million) 

Chemical 


Feeder, 
lbs/day 


=  (Flow.  MGD)(Dose,  mg/l)(8.34  lbs/gal) 


12.28   Monitoring  of  Treated  Water 

When  controlling  iron  and  manganese  by  aeration  or  with 
chemicals,  the  product  water  must  be  monitored  closely.  If 
lab  facilities  are  available,  the  treated  water  can  be  analyzed 
for  iron  and  manganese  to  be  sure  treatment  is  adequate.  A 
quick  way  to  monitor  treated  water  is  to  collect  a  sample  and 
add  a  dose  of  chionne.  If  a  brown  or  rust-colored  floe 
develops,  then  the  treatment  is  inadequate.  You  will  either 
have  to  increase  the  chemical  doses  or  reduce  the  flows.  If  a 
pink  color  appears  in  the  product  water  when  using  perman- 
ganate, then  the  dose  Is  too  high  and  must  be  reduced  until 
the  pink  color  is  no  longer  visible. 


EXAMPLE  2 

A  standard  polyphosphate  solution  is  prepared  by  mixing 
and  r*issolving  1,0  grams  of  polyphosphate  in  a  container 
and  ddding  distilled  water  to  the  one-hter  mark.  Determine 
the  concentration  of  the  stock  solution  in  milligrams  per 
milliliter,  if  5  milliliters  of  the  stock  solution  are  added  to  a 
one-liter  sample,  what  is  the  polyphosphate  dose  in  milli- 
grams per  liter  and  pounds  per  million  gallons'? 

Known  Unknown 

Polyphosphate,  gm  =  1 .0  gm  1 .  StocK  Solution,  mg/mL 
Solution.  L  =~'^.0  L     2.  Dose.  mg/L 

Stock  Solution,  mi.  =  5  mi.    3.  Dose.  Ibs/MG 
Sample.  L  =  1  i. 

1 .  Calculate  the  concentration  of  the  stock  solution  in  milli- 
grams per  milliliter. 

Stock  Solution.  _  (Polyphosphate.  gm)(1000  mg/gm) 
"^9/"^^  (Solution,  l)(1000  ml/l) 

^  (1.0  gm)(1000  mg/gm) 

(1  l)(1000ml/l) 
=  1.0  mg/mL 


ERIC 


23 


16  Plant  Operation 


2  Determine  the  polyphosphate  dose  in  the  sample  m 
milligrams  per  liter. 

Dose.  mg/L  =  (Stock  Solution.  mg/mL)(VoL  Added.  mL) 
Sample  Volume.  L 
^(10  mg/mL)(5  L) 
1  L 

=  5.0  mg/L 

3  Determine  the  polyphosphate  dose  in  the  sample  m 
pounds  of  phosphate  per  million  gallons. 

Dose.  Ibs/MG  =(Dose.  mg/L)(3.785  L/gal)(1. 000.000) 
(1000  mg/gmK454  gm/lb)(1  Million) 
^  (5.0  mg/L)(3.785  L/gal)(1. 000.000) 
(1000  mg/gmH454  gm/lb)(1  Million) 
=  42  Ibs/MG 

EXAMPLE  3 

Determine  the  chemical  feeder  setting  in  pounds  of  poly- 
phosphate per  day  if  0.4  MOD  is  treated  with  a  dose  of  5 
mg/L. 

Known  Unknown 
Flow.  MGD  =  0.4  MOD  Chemical  Feeder,  lbs/day 

Dose,  mg/L==  5  ng/L 

Determine  the  chemical  feeder  setting  in  pounds  per  day. 

^  ^^^^'^    ^^^""^^  MGD)(Dose,  mg/L)(8.34  lbs/gal) 

=  (0  4  MGD)(5  mg/L)(8.34  lbs/gal) 


=  17  lbs/day 


FORMULAS 


To  calculate  the  average  detention  time  for  a  reaction 
basin: 

1.  Determine  the  dimensions  of  the  basin,  and 

2.  Measure  and  record  the  flow  of  water  being  treated. 
Basin  Vol..  cu  ft  =  (0.785)(Diameter.  ft)2(Depth.  ft) 
Basin  Vol..  gal  =  (Basin  Vol..  cu  ft)(7.48  gal/cu  ft) 
Detention  Time.  ^  (Basin  Vol..  gal)(24  hr/day)(60  min/hr) 


2  Convert  the  basin  volume  from  cubic  feet  to  gallons 
Basin  Vol .  gal  =  (Basin  >/ol..  cu  ft)(7.48  gal/cu  ft) 
-  (565  cu  ft)(7.48  gal/cu  ft) 
=  4226  gal 

3.  Determine  the  average  detention  time  in  minutes  for  the 
reaction  basin 

Detention  time.  ^(Basm  Vol..  ga()(24  hr/day)(60  min/hr) 

Flow,  gal/day 
^  (4226  gal)(24  hr/day)(60  mm/hr) 

200.000  gal/day 
=  30  minutes 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  23. 

12. 2E  What  happens  if  water  being  treated  for  Iron  and 
manganese  by  ion  exchange  contains  any  dissolved 
oxygen? 

12.2F  How  does  the  pH  of  the  water  influence  the  rate  of 
oxidation  of  iron  to  insoluble  ferric  hydroxide'^ 

1 2  2G  What  is  the  purpose  of  a  reaction  basin  following  the 
aeration  process? 

12.2H  After  chlonne  has  been  added  to  oxidize  iron  and 
manganese,  how  is  the  water  dechlorinated? 

12.21  How  are  greensands  regenerated  after  being  used  to 
oxidize  iron  and  manganese'? 


mm 


(Flow,  gal/day) 


EXAMPLE  4 

A  reaction  basin  12  feet  in  diameter  and  5  feet  deep  treats 
a  flow  of  200.000  gallons  per  day.  What  is  the  average 
detention  time  in  minutes? 


Unknown 
Detention  Time,  mm 


Known 

Diameter,  ft  =  12  ft 
Depth,  ft     -  5  ft 
Flow,  GPD  =  200,000  GPD 

1.  Calculate  the  basin  volume  in  cubic  feet 

Basin  Vol.,  cu  ft  =  (0.785)(Diameter,  ft)2(Depth.  ft) 

=  (0.785)(12  ft)2(5  ft) 

=  565  cu  ft 


ERIC 


12.3   OPERATION  OF  AN  IRON  AND  MANGANESE 
REMOVAL  PLANT  by  Gerald  Davidson 

12.30  Description  of  Process 

The  operation  of  an  iron  and  manganese  removal  plant 
using  continuously  regenerated  manganese  greensand  in- 
volves a  number  o^  .\oerational  procedures  which  must  be 
checked  on  a  daily  basis. 

The  very  low  recommended  limits  for  iron  (0.3  mg/L)  and 
manganese  (0.05  mg/L)  In  water  makes  these  contaminants 
difficult  to  treat  and  sometimes  the  processes  are  expen- 
sive. Because  of  this,  operators  should  know  how  the 
processes  work  and  what  to  check  for  when  something 
goes  wrong  and  the  limits  are  exceeded. 


24 


iron  and  Manganese  17 


The  filter  is  the  most  important  piece  of  treatment  equip- 
ment. Figure  12.4  illustrates  a  typical  filter  consisting  of 
layers  of  gravel,  filter  sand,  greensand  and  anthracite  coal. 
One  inch  (25  mm)  of  filter  sand  is  placed  on  top  of  the 
support  gravel.  This  layer  helps  support  the  fine  greensand. 
Differences  between  greensand  filters  and  conventional 
filters  are:  (1)  the  greensand  is  very  fine;  and  (2)  the  filtration 
rate  is  slower  and  should  not  exceet^  3  GPM/sq  ft  (2  liters 
per  sec/sq  m  or  2  mm/sec);  the  backwash  rate  is  lower  and 
should  be  less  if  anthracite  coal  is  used;  and,  the  time  of  the 
backwash  should  be  increased  when  using  greensand  to 
insure  that  the  media  is  clean. 

12.31   Description  of  the  Plani  (Figure  12.5) 

The  following  is  a  descrption  of  an  iron  and  manganese 
removal  plant  using  continuously  regenerated  manganese 
greensand.  The  treatment  plant  provides  chemical  floccula- 
tion.  sedimentation,  pressure  filtration  (anthracite  coal, 
greensand,  and  filter  sand),  and  chlorination  of  raw  well 
water  that  contains  three  mg/L  iron  and  0.75  to  one  mg/L 
manganese. 

The  treatment  plant  in  Figure  12.5  has  two  flocculator/ 
clanfiers  (solids  contact  units)  32  feet  (10  m)  in  diameter  with 
2.0  hours  detention  time  at  maximum  flow.  The  clanfiers  can 
be  operated  in  senes  or  in  parallel.  At  the  present  time  they 
are  being  operated  in  senes.  The  raw  water  is  being  pumped 
from  a  50-foot  (15  m)  deep  well  to  the  *.rst  clarifier.  The  raw 
water  is  injected  with  chlonne  at  8.65  mg/L,  flash  mixed,  and 
flocculated  for  a  penod  of  ten  minutes.  The  water  is  then 
injected  with  60  cfm  of  air  through  sixteen  ^ine  bubble 
diffusers.  The  aeration  detention  time  is  1.9  hours  at  maxi- 
mum flows.  The  raw  water  changes  from  zero  mg/L  dis- 


solved oxygen  to  saturation  at  the  water  temperature.  The 
colder  the  water  is.  the  more  oxygen  it  will  hold.  During 
aeration  the  iron  concentration  drops  from  3  mg/L  to  0.15 
ng/L  which  is  95  percent  removal  in  pnmary  clarification 

The  chlorination  and  air  injection  also  remove  100  mg/L 
carbon  dioxide  (COg)  and  0.03  mg/L  hydrogen  sulfide  (H^S) 
which  helps  in  taste  and  odor  control.  This  process  also 
raises  the  pH  of  the  raw  water  from  6.2  to  7.0.  The  air  will 
oxidize  most  of  the  manganese  to  an  insoluble  precipitate. 
.After  pnmary  clanfication,  the  water  goes  to  the  secondary 
clarifier,  in  the  secondary  treatment,  and  the  water  is  inject- 
ed with  potassium  permanganate  (1.22  mg/L)  and  sodium 
hydroxide  (30  mg/L).^^  j^q  sodium  hydroxide  is  added  to 
raise  the  pH  for  control  of  corrosion.  Detention  times  are  the 
same  as  with  pnmary  clanfiration.  After  secondary  clanfica- 
tion, the  water  is  passed  through  pressure  filters  with 
greensand  and  the  iron  and  manganese  levels  are  reduced 
to  0.01  mg/L  iron  and  0.01  mg/L  manganese,  which  i?  a  99 
percent  removal. 

The  potassium  permanganate  feed  system  consists  of  a 
50-gallon  (1G0  L)  polyethlene  solution  \  two  V4-HP  mixers, 
liquid  level  switches,  and  a  metenng  pump.  Provision  has 
been  made  to  add  dilution  water  to  the  chemical  feeder 
pump  discharge.  The  dilutiofi  water  will  prevent  the  crystali- 
zation  of  potassium  permanganate  which  could  cause  fail- 
ure of  the  pump  discharge  piping.  The  mixers  do  not  have  to 
run  continuously  because  of  the  solubility  of  potassium 
permanganate  in  water.  When  a  batch  of  potassium  oerman- 
ganate  solution  is  prepared,  the  potassium  permanganate 
chemical  is  mixed  with  hot  water  to  help  disperse  the 
chemical  in  the  solution. 


WATER  TO  BE 
TREATED 


(FROM  SECONDARY 
FLOCCULATOR 
CLARIFIER) 


TREATED 
WATER 


Fig.  12.4   Multimedia  manganese  greensand  filter  (horizontal) 


ERLC 


^2  NOTE.  Addition  of  30  mg/L  of  sodium  hydroxide  (NaOH)  will  increase  the  sodium  content  of  the  water  by  17  mg/L.  If  you  are  trying  to 
keep  the  sodium  level  below  20  mg/L,  then  the  sodium  in  the  raw  water  must  be  below  3  mg/L 

O  r- 


ADD  CHLORINE 
(FLASH  MIXING  AND 
FLOCCULATION  FOR 
10  MINUTES) 


RAW  WATER 


(FROM  WELL) 


IRON  PRECIPITA  .es 


ADDKMn04 
AND  NaOH 
(FLASH  MIXING  AND 
FLOCCULATION  FOR 

10  MINUTES) 


GREEN  SAND 
PRESSURE 
FILTER 


ADD  CHLORINE 
FOR  DISINFECTION 


TREATED  WATER 
TO  CONSUMERS 


REMOVES  MOST  OF 
REMAINING  IRON 
AND  MANGANESE 


TWO  FLOCCULA'  OR/CLARIFIERS 
BEING  OPERATED  IN  SERIES 


Fig.  12.5  Schmatic  of  iron  and  manganese  removal  plant  using  greensand 


Iron  and  Manganese  19 


12.32  Operation  of  the  Greensand  Process 

Good  iron  and  manganese  removal  with  greensand  can 
remove  95  percent  of  both  iron  and  manganese.  However,  if 
the  iron  is  above  20  mg/L.  the  efficiency  of  the  greensand 
drops  very  quickly.  A  residual  of  potassium  permanganate 
must  be  present  in  the  effluent  wat-ir  from  the  greensand  for 
the  greensand  media  to  be  effec  / 

When  using  the  continuously  regenerated  manganese 
greensand  for  iron  and  manganese  removal,  the  greensand 
must  be  regenerated  or  recharged  with  potassium  perman- 
ganate (KMnO^)  If  the  potassium  pern  nganate  charge  is 
lost  in  the  filter  bed  (none  in  the  filter  effluent),  the  operator 
must  regenerate  the  greensand.  There  are  two  ways  to 
regenerate  the  bed: 

1.  Shut  down  and  pour  a  saturated  solution  of  potassium 
permanganate  (about  5  percent)  into  the  filters:  let  the 
saturated  sohition  sit  for  approximately  24  hours.  Aftor 
the  saturated  solution  sits  for  24  hours,  backwash  the 
filters  at  a  normal  rate  to  flush  out  the  excess  potassium 
permanganate;  or 

2.  Recharge  the  greensand  by  increasing  the  potassium 
permanganate  dosage  until  pink  water  flows  out  of  the 
greensand  media.  Then  decrease  the  potassium  perman- 
ganate until  you  have  a  slight  pink  color  before  filtration. 
There  should  be  no  ^\nk  water  after  filtration  when  the 
water  is  being  pumped  into  the  distribution  system.  If 
there  is  still  pink  water  after  filtration,  keep  decreasing 
the  potassium  permanganate  dose  until  no  pink  water  is 
present  In  the  water  after  filtration.  The  pink  color  is  the 
best  indication  that  the  greensand  is  regenerated  or 
recharged  with  potassium  permanganate.  One  problem 
with  this  method  is  that  you  might  reduce  the  permangan- 
ate level  too  far  and  pass  water  with  iron  and  manganese. 
This  could  cause  red-colored  water  In  the  distribution 
system  and  stain  clothes  and/or  bathroom  fixtures.  Be- 
cause of  the  importance  of  the  potassium  permanganate 
in  the  greensand  process,  it  is  highly  recommended  that 
some  type  of  fail-safe  system  be  installed  to  prevent 
filtering  water  :r.  the  event  the  potassium  permanganate 
solution  vat  reaches  a  low  level.  When  a  low  level  is 
reached,  the  plant  should  be  automatrcally  shut  down. 
Typical  fail-safe  systems  include  low-level  alarms  in  the 
vat  or  an  automatic  switch  over  system  to  another  vat 
when  the  level  drops  too  low  in  the  vat  in  use. 

Some  operators  find  that  method  No.  1  is  more  effective. 
Since  all  treatment  plants  are  unique  in  some  respect,  one 
method  or  the  other  or  some  modification  may  work  best  for 
your  plant.  Therefore,  procedures  and  methods  should  be 
developed  through  actual  experience.  These  methods 
should  be  adopted  only  if  they  provide  the  desired  results 
without  eliminating  any  concepts  of  design  or  of  good 
operating  practice. 

Problems  will  develop  in  the  iron  and  manganese  removal 
process  using  greensand  if  you  have  too  short  a  detention 
time  for  the  chemicals  to  react.  That  is,  it  takes  a  little  time 
for  the  chemicals  to  stait  working.  If  the  plant  you  are 
operating  does  not  have  sufficient  detention  time  for  the 
chemical  reactions  to  take  place,  you  should  perform  exten- 
sive jar  tests  to  see  if  a  flash  mix  will  improve  performance. 
In  some  plants  the  injection  of  the  potassium  permanganate 
solution  in  the  volute  of  the  pump  will  produce  complete 
mixing  of  potassium  permanganate. 

To  prepare  a  potassium  permanganate  solution,  mix  the 
potassium  permanganate  chemical  with  hot  water  in  a 
solution  tank  to  make  the  chemical  disperse  completely. 


Inject  the  potassium  permanganate  solution  mto  the  water 
being  treated 

The  operator  of  an  iron  and  manganese  removal  plant 
using  greensand  must  run  jar  tests  to  determine  the  dosage 
of  all  chemicals  used  (chlorine,  permanganate,  and  sodium 
hydrox.de).  In  Chapter  3  of  this  water  treatment  manual, 
there  is  a  complete  description  of  how  to  run  jar  tests.  Iron  in 
the  ferrous  form  (Fe^*)  takes  about  0.60  mg/L  potassium 
permanganate  for  each  mg/L  iron  (Figure  1 2.6)  and  0.64  mg/ 
L  chlorine  for  each  mg/L  of  iron.  The  pH  of  the  water  has  a 
pronounced  effect  on  iron  removal.  The  oxidation  potential 
of  chlorine  and  potassium  permanganate  decreases  as  the 
pH  increases,  although  the  rate  of  reaction  increases  signifi- 
cantly with  the  increase  in  pH. 


0       2       4        6       8       10      12      14       16      18  20 


IRON  nig'L 


1 

-4- 

OOSF  2  mg  L  K'MnO^ 
PER  1  mgL 


0        2       4        6        8       10      12     14       16      18  20 


MANGANFSE.  mg'L 


Fig.  12  6  Potassium  permanganate  demand  for  oxidation 
of  iron  and  manganese 

CO 


20  Plant  Operation 


If  the  filtration  system  you  are  using  does  not  have  surface 
washers,  it  is  highly  recommended  that  they  be  installed. 
The  benefits  of  surface  washers  in  plants  that  treat  for  iron 
and  manganese  removal  are  well  recognized.  The  surface 
washers  help  prevent  mudballs  (in  any  type  of  plant)  and  the 
buildup  or  iron  and  manganese  oxide  on  the  filter  The 
buildup  IS  even  greater  when  anthraote  coal  is  use 

Remember  that  dally  tescs  shoula  also  be  perfonned. 
These  daily  tests  should  include  iron,  manganese,  pH  and 
chlorine  residual,  li.e  Iron  and  manganese  test  tells  the 
operator  if  the  treatment  plant  is  working  and  meeting  state 
and  federal  water  quality  requirements.  The  ph  test  is  also 
very  important  because  of  the  relationship  between  pH  and 
the  corrosivity  of  water.  Corrosive  waters  can  cause  deteno- 
ration  of  water  mams  and  red  water  complaints. 


FORMULA 

To  calculate  the  potassium  permanganate  dosage,  you 
need  to  know  the  concentration  of  iron  and  manganese  in 
the  water  being  treated  at  the  location  in  the  process  where 
the  permanganate  is  added. 

KMn04  Dose,  mg/L  =  0.6(lron,  mg/l)  +  2.0(Manganese,  mg/l) 
EXAMPLES 

Calculate  the  potassium  permanganate  dose  in  milligrams 
per  liter  for  a  well  water  with  3  mg/L  iron  before  aeration  and 
0.2  mg/L  after  "»ration.  The  manganese  concentration  is  1 .0 
mg/L  both  beiv.^  and  after  aeration. 

Known  Unknown 

Iron,  mg/L  =0.2  mg/L  KMnO^  Dose.  mg/L 

Manganese,  mg/L  =1.0  mg/L 

Calculate  the  potassiunr,  permanganate  dose  in  milligrams 
per  liter. 

KMn04  Dose,  mg/L  =  0  6(lron,  mg/L)  +  2.0(Manganese,  mg/L) 
=  0,6(0  2  mg/L)  +  2.0(1  0  mg/L) 
=  2.12  mg/l 

NOTE:  The  calculated  2.12  mg/L  potassium  permanganate 
dose  is  the  minimum  dose.  This  dose  assumes 
there  are  no  oxidizable  compounds  in  the  raw 
water.  However,  typical  oxidizable  compounds 
usually  found  include  organic  color,  bacteria  and 
even  hydrogen  sulfide  (HgS).  Therefore,  the  actual 
dose  may  be  higher.  A  bench  scale  test  should  be 
performed  to  determine  the  required  dose 

QUESTIONS 

Wnte  your  ansv,^ers  in  a  nnebook  and  then  compare  your 
answers  with  those  on  page  23. 

12.3A  What  are  the  accepteci  limits  for  Iron  and  manga- 
nese? 

12.3B  What  happens  in  the  two  flocculator/clanfiers  de- 
scnbed  in  this  chapter'? 


12.3C  Why  IS  dilution  water  added  at  the  discharge  of  the 
chemical  feeder  pump'? 

12  3D  Why  should  a  greensand  plant  be  shut  down  when 
the  permanganate  solution  level  in  the  *'at  gets  low? 


12.4   MAINTENANCE  OF  A  CHEMICAL  FEEDER 

In  small  water  treatment  plants  that  remove  iron  and 
manganese,  a  hypochlorite  solution  may  be  used  to  provide 
chlorine  instead  of  using  chlorine  gas.  Commercial  sodium 
hypochlorite  solutions  (such  as  chlorox)  contain  an  excess 
of  caustic  (sodium  hydroxide,  NaOH).  When  the  solution  is 
diluted  with  water  containing  carbonate  alkalinlty,^^  the  re- 
sulting solution  becomes  supersaturated  wilh  calcium  car- 
bonate. This  calcium  carbonate  tends  to  form  a  coating  on 
the  poppet  valves  in  the  solution  feeder.  The  coated  valves 
do  not  seal  properly  and  the  '  'er  fails  to  pump  the 
hypochlorite  solution  properly. 


This  calcium  carbonate  scale  can  be  removed  by  using  the 
following  procedure: 

1.  Fill  a  one  quart  (946  mL)  Mason  jar  half  full  of  tap  water. 

2.  Add  one  fluid  ounce  (44  mL)  of  30  to  37  percent  hydro- 
chlonc  acid  (HCI)  to  the  Mason  jar. 

3.  Finish  filling  the  jar  to  the  top  with  tap  water. 

4.  Place  the  suction  hose  of  the  hypochlorlnator  in  the  jar 
and  pump  the  entire  contents  of  tho  jar  through  the 
system. 

5.  Return  the  suction  hose  to  the  solution  tank  and  resume 
normal  operation. 


^3  See  Chapter  14.  "Soften-ng."  for  a  discussion  of  carbonate  alkalinity 

Er|c  29 


Iron  and  Manganese  21 


The  hydrochloric  acid  (HC\,,  also  called  muriatic  acid,  can 
be  obtained  from  stores  selling  swimming  pool  supplies 

One  way  to  avoid  tho  formation  of  calcium  carbonate 
coatings  is  to  obtain  the  dilution  water  for  the  hypochlonte 
from  an  ordinary  home  water  softener. 

For  additional  information  on  the  operation  and  mainte- 
nance of  various  types  of  chemical  feeders,  see  Chapter  13. 
fluoridation." 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  23 

12.4A  What  problems  may  develop  in  a  chemical  feeder 
pumping  sodium  hypochlonte? 

2.4B  How  can  the  problems  caused  by  calcium  carbonate 
scale  on  a  hypochlorinator's  poppet  valves  be 

SOlVcO? 

12.5  TROUBLESHOOTING  RED  WATER  PROBLEMS 

The  first  step  when  troubleshooting  red  or  dirty  water 
complaints  is  to  be  sure  Ine  iron  and  manganese  treatnicnt 
processes  are  working  properly.  If  the  iron  and  manganese 
are  being  removed  by  the  treatment  processes,  investigate 
the  distribution  system  for  sources  to  the  problem. 

Red  water  or  dirty  water  problems  may  be  caused  by 
corrosive  waters  or  iron  bacteria  in  the  distribution  system 
When  an  unstable  or  corrosive  water  (see  Chapter  8.  "Corro- 
sion Control")  is  pumped  into  the  distribution  system,  the 
water  attacks  cast  iron  pipes  and/or  metal  service  lines, 
picks  up  iron,  and  causes  red  ;vater  complaints  All  water 
treatment  plants  should  run  a  "Marble  Test"  see  page  353  in 
Chapter  6)  If  the  test  indicates  that  the  water  is  corrosive, 
the  addition  of  caustic  (sodium  hydroxide,  NaOH)  to  the 
water  to  increase  the  pH  will  help  When  the  water  becomes 
stable  (according  to  the  Marble  Test),  some  of  the  red  water 
complaints  could  be  eliminated. 

The  growth  of  iron  bacteria  inside  water  mams  causes  one 
of  the  most  troublesome  and  most  difficult  to  eliminate  red 
water  problems  These  bacteria  are  not  harmful.  They  live 
and  accumulate  the  iron  in  the  water  flowing  through  the 
distribution  system.  As  the  bacterial  growths  increase, 
slimes  will  build  up  m  the  mams  and  eventually  slough  off 
into  the  water.  When  these  slimes  come  out  a  consumer  s 
water  tap,  you  can  expect  complaints  of  red  water  and 
slimes. 

Slime  growths  can  be  controlled  by  maintaining  a  free 
chlorine  residual  throughout  the  distribution  system.  Some- 
times the  residual  is  very  difficult  to  maintain.  If  bacterial 
growths  have  been  in  the  distribution  system  for  a  long  time 
and  are  flourishing,  it  is  very  difficult  to  maintain  a  free 
chlorine  residual  at  the  extremes  or  in  dead  ends  of  the 
system.  Also  if  the  water  has  a  natural  high  chlorine  demand, 
your  chlormation  equipment  may  not  be  capable  of  feeding 
encugh  chlorine  to  maintain  a  free  chlorine  residual.  Re- 
member that  frequently  when  consumers  complain  about 
chlorine  or  swimming  pool  tasting  water,  the  solution  is  to 
add  mo.e  chlorine  in  order  to  get  past  thp  breakpoin*. 

Oneway  tr  id  a  distribution  system  of  iron  bacteria  is  to 
develop  a  flushing  program.^^  Flushing  should  start  at  the 
location  where  the  water  enters  the  distribution  system, 
such  as  an  elevated  tank.  Flush  the  water  mams  by  working 


towards  the  extremes  or  most  distant  points  of  the  distribu- 
tion system  Usually  only  one  portion  of  the  distribution 
system  is  flushed,  followed  by  another  portion  until  the 
entire  system  has  been  flushed. 

A  common  practice  is  to  open  a  hydrant  at  the  extr«^me 
end  of  the  system  at  the  start  of  the  flushing  job  to  be  sure 
the  water  being  flushed  will  carry  the  sediment  and  insoluble 
precipitates  in  the  desired  direction  and  out  oi  the  system 
Flushing  is  often  done  late  at  night  when  water  demands  are 
low  so  facilitieswon't  be  overworked  and  consumers  will  not 
be  inconvenienced. 

Valves  will  have  to  be  opened  and  closed  m  the  proper 
sequences  to  be  sure  the  desired  mams  are  being  flushed 
and  that  no  one  will  be  without  water  Hydrants  that  are 
opened  to  allow  flushing  must  be  of  sufficient  size  to 
produce  flushing  velocities  (2  5  up  to  5  0  ft/sec  preferred  or 
0  75  to  1  5  m/sec)  in  the  mains.  Also  the  mams  providing  the 
flushing  flows  must  have  sufficient  capacity  to  deliver  the 
desired  flows. 

When  flushing  a  system,  be  sure  the  pressure  in  the 
distribution  system  does  not  drop  below  20  psi  (1  4  kg/sq  cm 
or  138  kPa).  If  a  four-inch  (100  mm)  water  mam  is  flushed 
using  a  six-inch  (1 50  mm)  hydrant,  the  water  pressure  m  the 
mam  downstream  from  the  hydrant  could  become  danger- 
ously low.  When  this  happens,  the  distribution  system  could 
be  subject  to  contamination  by  BACKSIPHONAGE:^  NEV- 
ER ALLOW  A  BACKSIPHON  CONDITION  TO  DEVELOP  IN 
A  DISTHIBUTION  SYSTEM. 

In  summary,  to  minimize  red  water  or  dirty  water  probleir.s 
and  complaints,  you  must  provide  aaequate  treatment  to 
control  iron  and  manganese.  This  is  necessary  to  assure 
that  the  water  pumped  into  the  distribution  system  contains 
little  or  no  iron  and  manganese.  The  water  must  be  stable 
(noncorrosive)  so  that  iron  will  not  be  picked  up  in  the 
distribution  system.  Corrosion  control  treatment  processes 
can  produce  a  stable  water.  If  bacterial  growths  are  a 
problem,  a  free  chlonne  residual  must  be  maintained  in  all 
water  throughout  the  distribution  system  If  red  or  dirty  water 
problems  exist  in  a  distribution  system,  a  thorough  flushing 
program  can  be  very  helpful 

12.6  ARITHMETIC  ASSIGNMENT 

Turn  to  the  Appendix  at  the  back  of  this  manual  and  read 
Section  A.30.  "Iron  and  Manganese  Control  '  Check  all  of  the 
arithmetic  m  this  section  using  an  electronic  calculator  You 
should  be  able  to  get  the  same  answers 

12.7  ADDITIONAL  READING 

1.  NEW  YORK  MANUAL.  Chapter  13,  "Iron  and  Manga- 
nese." 

2  TEXAS  MANUAL.  Chapter  11.  "Special  Water  Treatment 
(Iron  and  Manganese  Removal) " 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  23. 

12  5A  Lisi  the  possible  causes  of  red  or  dirty  water  com- 
plaints 

12  5B  How  can  slime  growths  be  controlled  m  water  distri- 
bution systems? 


ERIC 


14  See  WATER  DISTRIBUTION  SYSTEM  OPERATION  AND  MAINTEN.^,NCE,  par^>  215,  Pipe  Flushing. 

15  Backsip'ionage.  A  form  of  backflow  caused  by  a  negative  or  below  atmo  .^henc  pressure  within  a  watei  system. 


22  Plant  Operation 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  12.   IRON  AND  MANGANESE  CONTROL 


Please  answer  these  discussion  and  review  questions 
before  continuing.  The  purpose  of  these  questions  is  to 
indicate  to  you  how  well  you  understand  the  material  in  the 
lesson.  Write  the  answers  to  these  questions  before  con- 
tinuing with  the  Objective  Test  on  page  23 

1  Why  should  iron  and  manganese  be  controlled  in  drink- 
ing water'^ 

2.  Why  are  accurate  results  of  tests  for  iron  and  manga- 
nese difficult  to  obtain? 

3.  Why  IS  chlorine  usually  fed  with  polyphosphates  when 
controlling  iron  and  manganese'? 

4.  How  do  polyphosphates  control  manganese? 

5.  How  IS  the  proper  polyphosphate  dose  determined'? 

6.  What  happens  when  an  ion  exchange  resin  becomes 
fouled  with  iron  rust  or  manganese  dioxide'? 


7.  When  should  iron  and  manganese  ion  exchange  units 
be  regenerated'? 

8.  How  would  you  determine  whether  or  not  to  adjust  the 
flows  to  an  oxidation  by  aeration  process  to  remove 
iron'? 

9.  Why  should  reaction  basins  be  drained  and  cleaned'? 

10.  What  are  the  advantages  and  disadvantages  of  the 
oxidation  by  aeration  process  to  remove  iron? 

11.  What  happens  if  the  dose  of  potassium  permanganate 
to  remove  iron  and  manganese  is  not  exact? 

12.  What  must  you  do  if  the  potassium  permanganate 
ch;-rge  is  lost  in  the  filter  bed'? 

13.  Wiy  should  the  filtration  system  for  the  greensand 
process  have  surface  washers'? 

14.  How  would  you  attempt  to  prevent  red  or  dirty  water 
complaints? 


SUGGESTED  ANSWERS 

Chapter  12.   IRON  AND  MANGANESE  CONTROL 


Answers  to  questions  on  page  6. 

12.0A  When  clothes  are  washed  in  water  containing  iron 
and  manganese,  they  will  come  out  stained.  Iron 
bacteria  will  cause  thick  slimes  to  form  on  the  walls 
of  water  mams.  These  slimes  are  rust  colored  from 
iron  and  black  from  manganese.  Variations  in  flow 
cause  these  olimes  to  slough  which  results  in  dirty 
water.  Furthermore,  these  slimes  will  impart  foul 
tastes  and  odors  to  th  water. 

12. OB  The  growth  of  iron  bacteria  is  easily  controlled  by 
chlorination.  However,  when  water  containing  iron  is 
chlorinateo,  the  iron  is  converted  into  rust  particles 
and  manganese  is  converted  into  a  jet  black  com- 
pound, manganese  dioxide. 

12.0C  The  generally  accepted  limit  for  iron  is  0.3  mg/L  and 
that  for  manganese  is  0.05  vng/L 

Answers  to  questions  on  page  7. 

1«?.1A  Iron  and  manganese  react  with  dissolved  oxygen  or 
chlorine  to  form  insoluble  compounds. 

1 2.1  B  Iron  and  manganese  samples  are  acidified  when  they 
are  collected  to  prevent  the  formation  of  iron  and 
manganese  scales  on  the  walls  of  the  sample  bot- 
tles. 

ERLC 


12. 1C  Samples  for  iron  and  manganese  testing  should  be 
collected  as  close  to  the  well  or  source  of  water  as 
possible. 


Answers  to  questions  on  page  11. 

12.2A  If  a  well  produces  water  containing  dissolved  oxygen 
as  well  as  iron  and  manganese,  the  iron  and  manga- 
nese are  probably  coming  from  the  lower  aquifers. 
Try  to  seal  off  the  lower  aquifers. 

1 2  2B  To  determine  if  nearby  wells  contain  iron  and  manga- 
nese, samples  could  b^  collected  and  analyzed  from 
nearby  private  wells.  Also,  discussions  with  well 
drillers  who  have  been  active  in  the  locality  and  with 
engineers  with  the  state  agency  responsible  for  the 
regulation  of  well  drilling  will  be  helpful. 

12.2C  Bench  scale  tests  are  a  method  of  studying  different 
ways  or  chemical  doses  for  treating  water  on  a  small 
scale  in  a  laboratory. 

12  2D  If  polyphosphate  solutions  are  much  over  48  hours 
old,  they  will  react  slowly  with  water  to  form  ortho- 
phosphates  which  are  much  less  effective  in  p^-event- 
ing  manganese  deposits. 


Iron  and  Manganese  23 


Answers  to  questions  on  page  16. 

12  2E  If  water  being  treated  for  iron  and  manganese  by  ton 
exchange  contains  any  dissolved  oxygen,  the  resin 
becomes  fouled  with  iron  rust  or  insoluble  manga- 
nese dioxide. 

12.2F  The  higher  the  pH.  the  faster  the  rate  of  oxidation  of 
iron  to  insoluble  ferric  hydroxide. 

12.2G  The  purpose  of  the  reaction  basin  is  to  allow  time 
for  he  oxidation  reactions  to  take  place.  The  aera- 
tion process  should  produce  sufficient  dissolved 
oxygon  for  the  iron  to  be  oxidi7ed  to  insoluble  ferric 
hydroxide. 

12  2H  Water  can  be  dechlorinated  by  the  use  of  reducing 
agents  such  as  sulfur  dioxide  (SO2),  sodium  bisulfite 
(NaHSOg),  and  sodium  sulfite  (NagSOj)  Bisulfite  is 
commonly  used  because  it  is  cheaper  and  more 
stable  than  sulfite. 

12  21  To  oxidize  greensands  used  to  oxidize  iron  and 
man'ianese,  backwash  the  greensands.  After  back- 
washing,  regenerate  with  potassium  permanganate 

Answers  to  questions  on  page  20. 

12  3A  The  accepted  limits  for  iron  and  manganese  are  0.3 
mg/L  for  iron  and  0.05  mg/L  for  manganese. 

12.3B  In  the  first  flocculator/clarifier,  chlorine  is  added  with 
flash  mixing  and  flocculatlon  for  10  minutes.  During 
the  next  1.9  hours,  aeration  occurs  through  fine 
bubble  diffusers.  This  process  removes  95  percent 
of  the  iron.  The  treated  water  then  flows  to  the 
second  flocculator/clarifier  and  the  water  is  injected 
with  potassium  permanganate  and  sodium  hydrox- 
ide. This  IS  followed  by  flash  mixing,  10  minutes  of 
flocculation  and  1.9  hours  of  settling.  After  this 
process,  the  water  is  passed  through  filters  which 
produce  treated  waters  with  0.01  mg/i.  of  iron  and 
also  0.01  mg/L  oi  manganese. 


12.3C  Dilution  water  is  added  at  the  discharge  of  the 
chemical  feeder  pump  to  prevent  the  crystalizatlon  of 
potassium  permanganate  which  could  cause  failure 
of  the  pump  discharge  piping 

12.3D  A  greensand  plant  should  be  shut  down  when  the 
permanganate  solution  level  in  the  vat  gets  low 
because  of  the  importance  of  the  permanganate  in 
the  process.  Without  permanganate  the  greensand 
could  lose  its  charge  and  iron  and  manganese  will 
enter  the  distribution  system. 

Answers  to  questions  on  page  21. 

12.4A  When  a  chemical  feeder  pumps  hypochlorite,  cal- 
cium carbonate  coatings  may  develop  on  the  poppet 
valves  if  the  dilution  water  contains  carbonate  alka- 
linity. Coated  valves  do  not  seal  properly  and  the 
feeder  fails  to  pump  the  hypochlorite  solution  prop- 
erly. 

12.48  The  problems  caused  by  calcium  carbonate  scale  on 
a  hypochlonnator  s  popoet  valves  can  be  solved  in 
two  ways: 

1.  A  hydrochloric  acid  solution  can  be  pumped 
through  the  system,  or 

2.  The  dilution  water  for  the  feeder  can  be  obtained 
from  an  ordinary  home  water  softener. 

Answers  to  questions  on  page  21. 

12.5A  Red  or  dirty  water  complaints  may  be  caused  by: 

1.  Iron  and/or  manganese  in  the  water, 

2.  Corrosive  waters,  and 

3.  Iron  bacteria  in  the  distribution  system. 

12  58  Slime  growths  in  distribution  systems  can  be  con- 
trolled by  maintaining  a  free  chlorine  residual 
throughout  the  distribution  system  and  by  a  distribu- 
tion syslem  flushing  program. 


OBJECTIVE  TEST 


Chapter  12.   IRON  AND  MANGANESE  CONTROL 


Please  write  your  name  and  mark  the  correct  answer  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1.  There 
may  be  more  than  one  correct  answer  to  the  mulitple  choice 
questions. 

True-False 

1.  Iron  and  manganese  must  be  removed  from  water  due 
to  adverse  health  effects. 

1.  True 

2.  False 

2.  Iron  and  manganese  are  rarely  found  in  groundwater. 

1.  True 

2.  False 

3.  Acidified  samples  for  iron  may  produce  high  results  if 
clay  particles  are  present. 

1.  True 

2.  False 

4.  If  the  water  orcduced  by  a  well  contains  dissolved 
oxygen  along  with  iron  and  manganese,  this  is  an 


indication  that  water  is  being  drawn  from  only  one 
aquifer. 

1.  True 

2.  False 

5.  Chlorine  should  never  be  fed  ahead  of  polyphosphate. 

1.  True 

2.  False 

6.  If  the  water  to  be  treated  contains  dissolved  oxygen, 
both  iron  and  manganese  may  be  removed  by  ion 
exchange  using  the  same  resins  that  are  used  for  water 
softening. 

1.  True 

2.  False 

7.  Oxidation  of  manganese  by  aeration  is  commonly  used 
on  waters  with  high  manganese  concentrations. 

1  True 
2.  False 


ERLC 


32 


24  Plant  Operation 


8.  Chlorine  will  oxidize  manganese  to  insoluble  manga- 
nese dioxide. 

1.  True 

2.  False 

9.  Chlonne  will  oxidize  iron  to  insoluble  ferric  hydroxide 

1.  True 

2.  False 

10.  Potassium  permanganate  oxidizes  iron  and  manganese 
to  insoluble  oxides  in  the  same  way  as  chlonne. 

1.  True 

2.  False 

1 1  Greensand  is  capable  of  oxidizing  both  iron  and  manga- 
nese and  is  also  capable  of  filtration. 

1.  True 

2.  False 

12.  The  flocculator/clarifiers  are  the  most  important  pro- 
cess in  the  greensand  treatment  plant. 

1.  True 

2.  False 

13.  The  solution  mixers  in  the  solution  vat  must  run  continu- 
ously to  keep  the  potassium  permanganate  in  solution 

1.  True 

2.  False 

14.  A  residual  of  potassium  permanganate  must  be  present 
in  the  filter  effluent  for  the  greensand  media  to  be 
effective. 

1.  True 

2.  False 

15.  Commercial  sodium  hypochlorite  solutions  (such  as 
Jhlorox)  contain  an  excess  of  lime 

1.  True 

2.  False 


Multiple  Choice 

16.  Problems  caused  by  iron  ind  manganese  in  water 
include 

1.  Corrosion. 

2.  Dirty  water. 

3.  Illness. 

4.  Stainec'  laundry. 

5.  Tastes  and  odors. 

17.  Iron  and  manganese  react  with  to  form  insoluble 

compounds. 

1.  Alum 

2.  Chlorine 

3.  Dissolved  oxygen 

4.  Ion  exchange  resins 

5.  Lime 

18.  Methods  or  equipment  used  to  test  for  iron  include 

1.  Amperometric. 

2.  Atomic  af/soi  ption. 

3.  Nessler  tubes. 

4.  Phosphate. 

5.  Spectrophotometer. 

19.  The  proper  polyphosphate  dose  is  the  lowest  dose  tha* 
delays  noticeable  discoloration  for  a  period  of  at  least 

1.  4  hours. 

2.  12  hours. 

ERLC 


3.  24  hours 

4.  2  days. 

5.  4  days. 

20.  Do  not  use  polyphosphate  solution  much  over  

hours  old. 

1  3 

2.  6 

3.  12 

4.  24 
5  48 

21  The  rate  of  oxidation  of  iron  to  form  insoluble  ferric 
hydroxide  is  decreased  by  inci  eases  in 

1 .  Carbon  dioxide. 

2.  Lime  dose. 

3.  Organic  substances 

4.  pH. 

5.  Temperature. 

22.  Chemical  doses  being  added  to  control  iron  and  manga- 
nese are  inadequate  if 

1 .  Addition  of  chlorine  to  the  treated  water  produces  a 
brownish  floe. 

2.  Analysis  of  treated  water  contains  iron. 
3  Consumers  complain  of  black  particles. 

4.  Consumers  complain  of  pink  water. 

5.  Consumers  complain  of  rusty  water. 

23.  The  differences  between  greensand  filters  and  conven- 
tional filters  include  the 

1 .  Backwash  rate  is  higher  for  greensand  filters. 

2.  Backwash  time  should  be  decreased  for  greensand 
filters. 

3.  Filtration  rate  is  faster  for  greensand  filters. 

4.  Greensand  is  coarser  than  conventional  sand. 

5.  Greensand  removes  iron  and  manganese. 

24.  Determine  the  setting  on  a  potassium  permanganate 
chemical  feeder  In  pounds  per  day  if  the  chemical  dose 
determined  from  a  jar  test  is  2.5  mg/L  and  the  flow  is 

0.  45  MGD. 

1.  8.4  lbs/day 

2  9.4  lbs/day 

3.  10.4  lbs/day 

4.  12.9  lbs/day 

5.  22.5  lbs/day 

25.  Determine  the  setting  on  a  potassium  permanganate 
chemical  feeder  in  pounds  per  million  gallons  if  the 
chemical  dose  determined  from  a  jar  test  is  2.5  mg/L 

1.  21  Ibs/M  Gal 

2.  32  Ibs/M  Gal 

3.  43  Ibs/M  Gal 

4.  46  Ibs/M  Gal 

5.  50  Ibs/M  Gal 

26.  A  reaction  basin  18  feet  in  diameter  and  6  feet  deep 
treats  a  flow  of  500,000  gallons  per  day.  What  is  the 
average  detention  time  in  minuies? 

1 .  25  minutes 

2.  28  minutes 

3.  30  minutes 

4.  33  minutes 

5.  35  minutes 


33 


CHAPTER  13 

FLUORIDATION 

by 

Harry  Tracy 


ERIC 


26  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  13.  Fluoridation 

OBJECTIVES  

GLOSSARY  

13.0  Importance  of  Fluoridation  

13.1  Fluoridation  Programs  

13.2  Compounds  Used  to  Furnish  Fluoride  Ion  

13.3  Fluoridation  Systems  

13.30  Chemical  Feeders  

13.31  Saturators  

13.32  Downflow  Saturators  

13.33  Upflow  Saturators  

13.34  Large  Hydrofluosillcic  Acid  Systems  

13.4  Final  Checkup  of  Equipment  

13.40  Avoid  Overfeeding  

13.41  Review  of  Designs  and  Specifications  

13.5  Chemical  Feeder  Startup  ^3 

13.6  Chemical  Feeder  Operation  ^ 

13.60  Fine  Tuning   ^ 

13.61  Preparation  of  Fluonde  Solution  ^ 

13.62  Fluoridation  Log  Sheets  ^5 

1 3.620  Hydrofluosillcic  Acid  ^ 

13.621  Sodium  Sllicofluoride  4 

13.7  Prevention  of  Ove^'feeding   4 

13.8  Underfeeding   ^ 

13.9  Shutting  Down  Chemical  Systems  5 

13.10  Maintenance    5 

13.1 1  Safety  In  Handling  Fluoride  Compounds  5 

13.110  Avoid  Overexposure  5 

13.111  Symptoms  of  Fluoride  Poisoning   5 

13.112  Basic  First  Aid  5 

13.1 13  Protecting  Yourself  and  Your  Family  5 

13.114  Training  5 

13.12  Calculating  Fluoride  Dosages  5 

13.13  Arithmetic  Assignment  5 

13.14  Additional  Reading  c 

13.15  Acknowledgments  5 

Suggested  Answers  5 

Objective  Test  g 

ErJc  :,35 


Fluoridation  27 


OBJECTIVES 


Chapter  13.  FLUORIDATION 


Following  completion  of  Chapter  13,  you  should  be  able  to: 

1  Explain  the  reason  for  fluoridating  drinking  water, 

2  Describe  how  fluoridation  programs  are  implemented, 

3.  List  the  compounds  used  to  furnish  fluoride  ion, 

4.  Review  designs  and  specifications  of  fluoridation  equip- 
ment, 

5.  Inspect  fluoridation  equipment, 

6.  Start  up  a  cnemical  feeder, 

7.  Operate  and  maintain  a  chemical  feeder, 

8.  Calculate  and  prepare  fluoride  solutions, 

9.  Develop  and  keep  accurate  fluoride  log  sheets, 

10.  Prevent  overfeeding  of  fluoride, 

11.  Shut  down  chemical  feed  systems,  and 
12  Safely  handle  fluoride  compounds. 


ERIC 


28  Water  Treatment 


GLOSSARY 

Chapter  1 3.  FLUORIDATION 


BATCH  PROCESS 


BATCH  PROCESS 


A  treatment  process  in  which  a  tank  or  reactor  is  filled,  the  water  is  treated  or  a  chemical  solution  is  prepared,  and  the  tank  is 
emptied.  The  tank  may  then  be  filled  and  the  process  repeated. 

DAY  TANK  DAY  TANK 

A  tank  used  to  store  a  chemical  solution  of  known  concentration  for  feed  to  a  chemical  feeder.  A  day  tank  usually  stores  suffi- 
cient chemical  solution  to  properly  treat  the  water  being  treated  for  at  least  one  day.  Also  called  an  AGE  TANK. 

ENDEMIC  (en-DEM-ick)  ENDEMIC 
Something  peculiar  to  a  particular  people  or  locality,  such  as  a  disease  which  is  always  present  in  the  population. 

FLUORIDATION  (FLOOR-uh-DAY-shun)  FLUORIDATION 

The  add.tion  of  a  chemical  to  increase  the  concentration  of  fluoride  ions  in  drinking  water  to  a  predetermined  optimum  limit  to 
reduce  the  incidence  (number)  of  dental  caries  (tooth  decay)  in  children. 

GRAVIMETRIC  FEEDER  GRAVIMETRIC  FEEDER 

A  dry  chemical  feeder  which  delivers  a  measured  weight  of  chemical  during  a  specific  time  period. 

POSITIVE  DISPLACEMENT  PUMP  POSITIVE  DISPLACEMENT  PUMP 

A  type  of  piston,  diaphragm,  gear  or  screw  pump  that  delivers  a  constant  volume  with  each  stroke.  Positive  displacement 
pumps  are  used  az  chemical  solution  feeders. 

SATURATOR  (SAT-you-RAY-tore)  SATURATOR 

A  device  which  produces  a  fluoride  solution  for  the  .'luoridation  process.  The  device  is  usually  a  cylindrical  container  with  granu- 
lar sodium  fluoride  on  the  bottom.  Water  flows  either  upward  or  downward  through  the  sodium  fluoride  to  provide  the  fluoride 
solution. 


VOLUMETRIC  FEEDER 

A  dry  chemical  feeder  which  delivers  a  measured  volume  of  chemical  during  a  specific  time  period. 


VOLUMETRIC  FEEDER 


ERIC 


37 


Fluoridation  29 


CHAPTER  13.  FLUORIDATION 


13.0   IMPORTANCE  OF  FLUORIDATION 

During  the  period  1902  to  1931  Dr.  Frederick  S.  McKay,  a 
dentist  practicing  in  Colorado  Springs,  noted  what  seemed 
an  ENDEMIC^  brown  stain  on  the  teeth  of  his  patients. 
McKay  devoted  much  of  his  time  researching  the  case  of 
mottled  (brown,  chalky  deposits)  tooth  enamel  but  it  was  not 
until  1931  that  the  cause  was  found  to  be  excessive  fluoride 
in  the  water  supplies  (2  to  13  mg/L).  During  this  period 
McKay  had  also  noted  that  the  mottled  teeth  seemed  to  have 
fewer  dental  carles  (decay  or  cavities). 

The  next  logical  step  was  to  add  fluoride  to  waters  that 
were  deficient  in  fluoride  and  to  discover  if  children  dnnking 
water  treated  with  fluoride  had  fewer  cavities.  In  1945 
controlled  fluoridation  was  started  in  the  cities  of  Grand 
Rapids,  Michigan  and  Newburgh,  New  York  with  control 
cities  of  Muskegon  and  Kingston. 

Finally  in  1955  the  results  were  in  and  they  showed  a  60 
percent  reduction  of  canes  in  those  children  who  drank 
fluoridated  water  compared  to  those  children  in  the  control 
cities. 

The  progress  of  fluoridation  did  not  go  smoothly.  Anti- 
fluoridationists  became  increasingly  vocal  and  were  able  to 
stop  fluoridation  In  many  cities  through  action  in  the  political 
arena. 

Although  dentists  practicing  in  areas  with  naturally  high 
fluoride  waters  noted  that  their  patients  had  remarkably  few 
cavities,  there  were  still  those  disfiguring  brown  stains. 
Mottling  of  the  teeth  occurs  when  the  fluoride  level  exceeds 
about  1.5  mg/L.  Fluoride  concentrations  in  excess  of  1000 
mg/L  have  been  found  in  waters  from  volcanic  regions. 
Waters  with  fluoride  concentrations  more  than  1 .4  to  2.4  mg/ 


L  should  be  treated  to  reduce  the  level  to  approximately  the 
one  milligram  per  liter  level.  The  exact  point  that  exceeds  the 
dnnking  water  standards  depends  upon  the  annual  average 
of  the  maximum  daily  air  temperatures  (Tabel  13.1). 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  59. 

13. OA  What  happens  if  a  person  drinks  water  with  an 
excessive  concentration  of  fluoride? 

13. OB  What  happens  if  children  drink  a  recommended  dose 
of  fluoride? 


13.1  FLUORIDATION  PROGRAMS 

Generally  speaking,  fluoridation  programs  start  with  citi- 
zens' inquiries  about  fluoridation  of  their  water  supplies  and 
encouragement  of  the  local  dental  society.  These  requests 
for  the  addition  of  fluonde  to  prevent  dental  caries  are 
passed  along  to  appropriate  governing  agencies.  The  gov- 
erning body  will  usually  rely  upon  a  vote  of  the  people,  or  it 
may  be  forced  into  a  vote  by  threat  of  a  referendum.  If  the 
decision  Is  made  to  fluoridate,  the  water  department  or 
water  company  will  alnost  always  make  the  final  decisions 
as  to  types  of  chemical  and  feeding  equipment  to  be  used. 

13.2  COMPOUNDS  USED  TO  FURNISH  FLUORIDE  ION 

The  most  commonly  used  compounds  to  fluoridate  water 
systems  are  sodium  fluoride,  sodium  silicofluoride  and  hy- 
drofluosilicic  acid  (HI-dro-FLEW-oh-suh-lys-ik).  There  are 


TABLE  13.1    INTERIM  PRIMARY  DRINKING  WATER  REGULATIONS  FOR  FLUORIDE  AND  RECOMMENDED  LEVELS 


Annual  Average  Maximum  Daily 
Temperatures^ 


Recommended  Control  Limits 
of  Fluoride  Levels,  mg/L 


Lower 


Optimum 


Maximum  Contaminant  Level, 


a. 

53.7  ft  Below 

12.0  &  Below 

0.9 

1.2 

1.7 

2.4 

b. 

53.8  to  58.3 

12.1  to  14.6 

0.8 

1.1 

1.5 

2.2 

c. 

58.4  to  63.8 

14.7  to  17.6 

0.8 

1.0 

1.3 

2.0 

d. 

63.9  to  70.6 

17.7  to  21.4 

0.7 

0.9 

1.2 

1.8 

e. 

70.7  to  79.2 

21.5  to  26.2 

0.7 

0.8 

1.0 

1.6 

f. 

79.3  to  90.5 

26.3  to  32.5 

0.6 

0.7 

0.8 

1.4 

»  Contact  your  local  Weather  Service  Office  to  determine  the  "Annual  Average  Maximum  Daily  Air  Temparature"  for  your  service  area. 


^  Endemic  (en-DEM-ick) 
population. 


ERJC 


Something  peculiar  to  a  particular  people  or  locality,  such  as  a  disease  which  is  alv^'ays  prese  it  in  the 

38 


30  Water  Treatment 


also  a  few  systems  using  such  compounds  as  hydrofluoric 
acid  and  ammonium  silicofluonde  All  of  these  chemicals  are 
refined  from  minerals  found  in  nature  and  they  yield  flurnde 
ions  identical  to  those  found  in  natural  waters  Hydrofluosili- 
cic  acid  (also  called  fiuonsiiicic  acid)  is  the  compound  most 
commonly  used  in  several  states  (California,  Florida  and 
Illinois). 


The  compounds  most  commonly  used  are  covered  by 
American  Water  Works  Association  Standards.  In  order  for 
you  to  be  confident  of  the  fluoride  compound  you  are  using, 
insist  that  your  supplier  furnish  only  compounds  meeting  the 
appropriate  AWWA  specifications. 

The  plant  should  have  as  part  of  its  records  several  copies 
of  the  appropriate  AWWA  standard  for  reference.  Standards 
can  be  purchased  from  the  Data  Processing  Department, 
American  Water  Works  Association,  6666  W.  Quincy  Ave- 
nue, Denver,  Colorado  80235 


HydrofiuosiliCic  acid  is  usually  the  easiest  fluondation 
chemical  to  feed.  However,  hydrofluosilicic  acid  produces 
poisonous  fumes  that  must  be  vented  and  is  very  irritating  to 
your  skin  Sodium  fluonde  is  easier  to  feed  than  the  other 
powdered  fluoridation  chemicals  because  it  is  more  soluble 
in  water. 

Operators  can  receive  instructions  from  the  manufacturer 
on  how  to  make  up  the  chemical  solutions  and  how  much 
solution  to  meter  per  million  gallons.  See  Section  13.61, 
"Preparation  of  Fluoride  Solution,"  for  calculations  and  pro- 
cedure details. 

Prior  to  fluoridation,  the  water  should  be  checked  for  its 
natural  fluoride  level.  If  there  is  natural  fluoride  in  the  water. 
It  is  only  necessary  to  add  enough  more  to  bring  the  total  to 
the  desired  level  recommended  by  the  local  health  authon- 
ties. 


TABLE  13,2   FLUORIDE  COMPOUNDS 


Sodium 

Sodium 

Hydrofluo- 

Silico- 

Fluoride 

silicic  Acid 

fluonde 

Na2SIFe 

NaF 

HzSiFfi 

1  Form 

Powder 

Powder  or 

Liquid 

Crystal 

2  Molecular  Weight 

188  1 

42  0 

144  1 

3  Commercial  Punty.  % 

98-99 

95-98 

22-30  by 

weight 

4  Fluonde  ion.  % 

60  7  (I007o) 

45  3  (100%) 

79  2(100%) 

{Purity.  %) 

59  8  {98  5) 

43  4  (96) 

23  8  (30) 

5  Density 

55-72 

65-90 

10  5(30%) 

Ib/cu  ft 

Ib/cu  ft 

ib/gal 

6  Solubility  in  Water,  7o 

0  76 

4  05 

lOOa 

{gram/1 00  mi  water 

at  77°F  or  25°C) 

7  pH  of  Saturated 

3.5 

76 

1  2 

Solution 

{1%  Solution) 

Price 

Standard        Chemical       Members  Nonmembers  Order  No. 

B701 -84  Sodium  Fluoride         $5.50  $7.00  42701 

B702-84  Sodium  Silicofluonde  $5.50  $7  00  42702 

B703-84  Hydrofluosilicic  Acid    $5.50  $7.00  42703 

Only  ♦tie  fluoride  ion  in  these  compounds  Is  of  any 
importance  in  the  fluoridation  of  water;  therefore,  pound-for- 
pound,  each  compound  wiH  provide  a  different  final  fluoride 
level.  If  you  switch  from  one  type  of  fluoride  compound  to 
another,  you  will  have  to  make  separate  calculations  for 
each  type.  Table  13.2  summarizes  the  important  properties 
of  fluoride  compounds. 


a  Infinite  because  we  are  dealing  with  a  liquid. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  59. 

1 3  1 A  Who  makes  the  final  decisions  as  to  types  of  fluonde 
chemicals  and  feeding  equipment  to  be  used'^ 

13.2A  List  the  three  compounds  most  commonly  used  to 
fluoridate  water. 


When  selecting  a  fluoridation  chemical,  several  important 
factors  must  be  considered.  The  solubility  of  the  chemical  in 
water  is  very  important  if  we  are  using  the  powder  or  crystal 
form  of  a  chemical  because  we  want  the  chemical  to  readily 
dissolve  in  water  and  remain  in  solution.  Operator  safety  and 
ease  of  handling  must  be  given  serious  consideration. 
Storage  and  feeding  requirements  as  well  as  costs  must 
also  be  studied  when  selecting  any  chemical. 


ERIC 


39 


13.3   FLUORIDATION  SYSTEMS 

Dnnking  waters  may  come  to  contain  fluoride  ions  by 
three  different  types  of  situations.  First,  the  raw  water 
source  may  have  adequate  or  excessive  fluoride  ions  natu- 
rally present.  Second,  sometimes  two  water  Gources  are 
blended  together  to  produce  an  acceptable  level  of  fluoride 
ions.  This  can  occur  when  one  source  has  a  higher  than 
acceptable  level  of  fluoride  ions  and  the  other  is  below  the 
desired  level.  This  chapter  is  mainly  concerned  with  the  third 
situation  m  which  fluoride  ions  must  be  added  to  the  water  to 
achieve  an  acceptable  level  of  fluoride  ions. 


Fluoridation  31 


13.30  Chemical  Feeders 

Fluoride  ions  are  added  to  water  by  either  chemical 
solution  feeders  or  dry  feeders.  Solution  feeders  are  POSI- 
TIVE DISPLACEMENT^  diaphragm  pumps  (Figure  13  1). 
peristaltic  pumps  (Figure  13.2),  or  electronic  pumps  (Figure 
13  3),  that  deliver  a  fixed  amount  of  liquid  fluoridation 
chemical  with  each  stroke  or  pulse.  The  dry  feeders  are 
either  VOLUMETRIC^  or  GRAVIMETRIC^  type?  of  chemical 
feeders.  Volumetnc  feeders  (Figures  13.4  and  13.5)  are 
usually  simpler,  less  expensive,  less  accurate  and  feed 
smaller  amounts  of  chemicals  than  gravimetric  feeders. 
Gravimetric  feeders  (Figure  13.6)  are  usually  more  accurate 
than  volumetric  feeders,  however,  they  are  more  expensive 
and  require  more  space  for  installation.  The  amount  fed  is 


measured  on  the  basis  of  the  weight  of  chemical  to  be  fed  to 
the  system  Fluoride  chemical  feeders  must  be  very  accu- 
rate. 

Whatever  the  type  of  feeding  system  or  chemical  used,  the 
design  should  be  planned  by  the  engineer  experienced  m 
developing  feeding  systems  (Figure  13  7).  The  design  must 
incorporate  means  to  prevent  both  overfeeding  and  back 
siphonage  along  with  a  means  to  monitor  the  amount  of 
chemical  used  It  is  also  desirable  to  incorporate  some 
means  of  feeding  fluonde  which  is  adjusted  (paced)  accord- 
ing to  the  plant  flow  rate.  Also  a  means  to  continuously 
measure  the  finished  water's  fluoride  ion  content  with  an 
adjustable  "high"  fluonde  alarm  is  desirable.  Fluoride  doses 
must  never  be  metered  against  a  negative  or  suction  head. 


MANUAL  STROKE  ADJUSTER 
ADJUSTING  WEDGE 
RETURN  SPRING 
PUSH  ROD 

BALL  BEARING 

ECCENTRIC 


BALL  BEARING 


INPUT  SHAFT 
4  WORM 


OIL  PUMP 


Fig.  13. 1   Positive  displacement  diaphragm  pumps 

(Permission  of  Wallace  &  Tiernan  Division,  Pennwatt  Corporation) 


2  PoJtive  Displacement  Pump    A  type  of  piston,  diaphragm,  gear  or  screw  pump  that  delivers  a  constant  volume  with  each  stroh  3.  Posi- 
tive dibplacement  pumps  are  used  as  chemica'  'Solution  feeders, 

3  Volumetnc  Feeder  A  dry  chemical  feeder  which  delivers  a  measured  volume  of  chemical  during  a  specific  time  period. 
^  Gravimetric  Feec^er.   A  dry  chemical  feeder  which  delivers  a  measured  weigh*  of  chemical  during  a  specific  time  period 


32  Water  Treatment 


THREE-QUARTER  VIEW 


END  VIEW 


ROLLER 


PUMPING 
TUBE 


DETAIL  OF 
PLASTiCTUBE 
HOUSING 


.  SIDE  VIEW 


IK 


# 


GEAR  MOTOR 


MECHANICAL 
FEED  RATE 
CONTROL 


PLASTIC 

TUBE 
HOUSING 


Fig.  13,2  Peristaltic  ^eeder 

{Reproduced  from  WATER  FLUORIDATION.  A  Tratntng  Course  Manual  for  Engineers 
and  Technicians,  by  permission  of  the  Dental  Disease  Prevention  Activity, 
U  S  Public  Health  Service) 


ERIC 


41 


Fluoridation 


Fig  13,3  Electronic  feeder 

(Reproduced  from  WATER  FLUORIDATION.  A  Training  Course  Manual  for  Engineers 
and  Technicians,  by  permission  of  the  Denial  Disease  Prevention  Activity 
U  S  Public  Health  Service) 


34  Water  Treatment 


Fig.  13.4   Volumetric  feeder,  roll-type 

(Reproduced  from  WATER  FLUORIDATION.  A  Training  Course  Manual  for  Engineers 
and  Technicians,  by  permission  of  the  Denial  Disease  Prevention  Activity. 
U  $  Public  Health  Service) 


43 


Fluoridation 


Fig.  13.5   Volumetric  feeder,  screw-type 

(Reproduced  from  WATER  FLUORIDATION,  A  Trarnmg  Course  Manual  for  Engineers 
and  Technicians,  by  permission  of  the  Dental  Drsease  Prevention  Activity. 
U  S  Public  Health  Service) 


41 


36  Water  Treatment 


Fig.  13,6  Gravimetric  feeder,  belt-type 

(Reproduced  from  WATER  FLU0RI0A7.0N  A  Training  Course  Manual  for  Engineers 
and  Technicians,  by  permission  of  the  Oentaf  Disease  Prevention  Aclmty 
U  S  Public  Health  Service) 


ERIC 


45 


Fluoridation  37 


LOSS  OF  WEIGHT     aNTI  SYPHON  VALVE 
RECORDER  p  METE^^ING  PUMP  (0> 


I 


PLATFORM  SCALE 


Direct  Acid  Feed  System 


WATER  SUPPLY 
RIGID  PIPE 

ANTI  SYPHON 
VALVE 


TRANSFER  PUMP  ,// 


-  -  --|T7 
30%  ACID 


H  P  OVERFLOW  CONN 


lib 


ACID  TANK 


Diluted  Acid  Feed  System 


ALARM 


WATER  SUPPLY 


MIXER 


Q    METERING  PUMP 


ANTI  SYPHON 
VALVE 


MIXlNr:  TANK 


DAY  TANK 


Manual  Batch  System  w/ith  Dry  Chemicals 


Fig.  13.7  Typical  fluoridation  systems 

(Permission  of  Wallace  &  Tiernan  Division,  Pennwdit  Corporation) 


ERIC 


4G 


38  Water  Treatment 


13.31  Saturators 

Only  crystal-grade  (20  to  60  mesh)  sodium  fluoride  should 
be  fed  with  a  SATURATORS  (Figure  13.8).  Sodium  fluoride 
has  a  nearly  constant  solubility  at  normal  temperature 
ranges  and  thus  produces  a  fluoride  solution  of  uniform 
strength.  Sodium  silicofluonde  is  not  recommended  to  feed 
through  the  saturator  because  of  its  very  low  solubility  m 
water  (see  Table  13.2).  Maintain  a  depth  of  six  to  ten  inches 
(150  to  250  mm)  in  the  sodium  fluoride  bed  of  the  saturator. 
The  use  of  powdered  sodium  fluoride  is  not  recommended 
because  this  chemical  will  clog  the  saturator. 

Many  dry  chemical  feed  systems  include  a  mixer,  dissolv- 
ing tank  and  DAY  TANK^  (.'  ,gure  13.9).  The  mixer  mixes  a 
known  amount  of  chemicals  with  a  measured  amount  of 
water  in  a  dissolving  tank  or  solution  chamber.  This  is  a 
"batch  mixed"  process  because  the  chemicals  are  mixed 
With  a  specified  amount  of  water,  rather  than  being  mixed  in 
flowing  water.  The  dissolved  tank  allows  the  chemicals  to 
become  dissolved  in  water  which  is  continuously  applied  to 
the  water  being  treated  or  is  stored  in  a  day  tank  or  storage 
tank.  The  day  tank  usually  stores  at  least  enough  chemical 
solution  to  properly  treat  the  plant  flow  for  at  least  one  day 
The  chemica!  solution  is  fed  from  the  day  tank  to  the  water 
being  treated  by  a  chemical  feeder  (feed  pump)  whose  feed 
rate  continuously  adjusts  to  the  flow  being  treated  (flow- 
paced). 

When  working  with  fluoridation  systems  using  a  sodium 
fluoride  solution,  the  hardness  of  the  water  is  very  important. 
Hard  water  can  produce  problems  in  systems  using  satura- 
tors and  dissolving  tanks  through  the  formation  of  low 
solubility  calcium  and  magnesium  fluoride  compounds.  If  the 
dilution  water  has  a  hardness  of  less  than  1 0  mg/L  hardness 
as  CaCOj,  there  will  be  no  problem.  If  the  hardness  range  is 
above  1 0  mg/L  and  below  75  mg/L,  it  is  a  case  of  how  much 
cleaning  and  maintenance  a  particular  system  wants  to  put 
up  with.  Above  a  hardness  of  75  mg/L,  a  softened  water 
must  be  used  for  the  water  to  prepare  a  fluoride  solution  in 
order  to  prevent  severe  scaling  m  the  equipment. 

As  an  alternative  to  the  water  softener,,  poly^jhosphates 
(at  7  to  1 5  mg/L)  may  be  used  instead  of  a  zeolite  sofxener  to 
prevent  plugging  by  scale  in  the  feed  system.  The  polyphos- 
phates are  added  to  the  day  tank  to  prevent  bcale  deposits. 
If  neither  a  zeolite  softener  nor  polyphosphates  are  used, 
plugging  may  occur  at  any  point  m  the  feed  system,  including 
valves,  saturator  bed,  and  injection  point.  Remove  these 
hardness  deposits  by  flushing  the  system  with  vinegar  or  a 
five  percent  solution  of  hydrochlonc  acid  (muriatic  acid).  The 
saturator  beds  also  may  require  the  removal  of  water 
hardness  deposits. 


The  saturator  is  a  special  application  o:  a  solution  feeder, 
small  pump  delivers  a  saturated  solution  of  sodium 
fluoride  into  the  water  system  The  principle  of  a  saturator  is 
that  a  saturated  solution  will  result  if  water  is  allowed  to 
trfCkle  through  a  bed  containing  sodium  fluoride.  Although 
saturated  solutions  of  sodium  fluoride  can  be  manually 
prepared,  generally  the  easiest  and  best  way  is  an  automatic 
feed  device  Saturators  should  be  stirred  every  day  to 
prevent  fluonde  solids  from  building  up  on  the  bottom.  There 
are  two  kinds  of  saturators,  the  upflow  saturator  and  the 
ucwnflow  saturator. 

13.32  Downflow  Saturators  (Figure  13.10) 

In  the  downflow  saturator,  the  solid  sodium  fluonde  is  held 
in  a  plastic  drum  or  barrel  and  is  isolated  from  the  prepared 
solution  by  a  plastic  cone  or  a  pipe  manifold.  A  filtration 
barrier  is  provided  by  layers  of  sand  and  gravel  to  prevent 
particles  of  undissolved  sodium  fluoride  from  infiltrating  the 
solution  area  under  the  cone  or  within  the  pipe  manifold.  The 
feeder  pump  draws  the  solution  from  within  the  cone  or 
manifold  at  the  bottom  of  the  plastic  drum.  Downflow 
saturators  require  clean  gravel  and  sand.  In  some  systems 
the  gravel  and  sand  must  be  cleaned  every  day  or  two. 

13.33  Upflow  Saturators  (Figure  13.1 1) 

In  an  upflow  saturator.  undissolved  sodium  fluonde  forms 
Its  own  bed  below  which  water  is  forced  upwa»'d  under 
pressure.  No  burner  is  used  since  the  water  comes  up 
through  the  bed  of  sodium  fluoride  and  the  specific  gravity  of 
the  solid  matenal  keeps  it  from  rising  into  the  area  of  the 
clear  solution  above.  A  spider  type  water  distributor  located 
at  the  bottom  of  the  tank  contains  hundreds  of  very  small 
slits.  Water,  forced  under  pressure  through  these  slits,  flows 
upward  through  the  sodium  fluonde  bed  at  a  controlled  rate 
to  assure  the  desired  four  percent  solution.  The  feeder 
pump  intake  line  floats  on  top  of  the  solution  in  order  to 
avoid  withdrawal  of  undissolved  sodium  fluoride.  The  water 
pressure  requirements  are  20  psi  (138  kPa)  minimum  to  125 
psi  (862  kPa)  maximum  and  the  flow  is  regulated  at  4  GPM 
(0  25  L/sec).  Since  introduction  of  water  to  the  bottom  of  the 
saturator  constitutes  a  definite  cross-connection.  A  ME- 
CHANICAL SIPHON-BREAKER  MUST  BE  INCORPORAT- 
LD  INTO  THE  WATER  LINE:  or  better  still,  the  saturator  can 
be  factory  modified  to  include  an  air-gap  and  a  water  feed- 
pump. 

Figures  13.8  and  13  11  show  two  configurations  of  up- 
flow'lype  saturators  which  feed  and  prepare  constant 
strer.gth  fluoride  solution  from  granular  sodium  fluonde.  The 
upfUw  type  is  the  preferred  type  over  the  downflow  satura- 
tes as  It  Is  much  ecsier  to  clean  and  maintain.  Under  normal 
conditions,  it  should  ne^d  cleaning  only  once  a  year;  so.  we 
have  discussed  its  cot.^ujction  and  use  in  some  detail. 

To  prepare  an  upflow  saturator  for  use,  the  following 
step'*  should  be  taken. 

1.  With  the  distributor  tubes  In  place,  and  the  floating 
suction  device  removed,  add  200  to  300  pounds  (91  to 
136  kg)  of  sodium  fluoride  directly  to  the  tank.  Any  type  of 
sodium  fluonde  can  be  used,  from  coarse  crystal  to  fine 
  crystal,  but  fine  crystal  will  dissolve  better  than  coarse 

5  Saturator  (SAT-you-RA  Y-tore)  A  device  which  produces  a  fluoride  solution  for  the  fluoride  process.  The  device  /o  usually  a  cylindrical 
container  with  granular  sodium  fluoride  on  the  bottom  Water  flows  either  upward  or  downward  through  the  sodium  fluoride  to  produce 
fne  fiuorioe  solution. 

6  Day  Tank  A  tank  used  to  store  a  chemical  solution  of  known  concentration  for  feed  to  a  chemical  feeder.  A  day  tank  usually  stores  suf- 
ficient chemical  solution  to  properly  treat  the  water  being  treated  for  at  least  one  day.  Also  called  an  'AGE  TANK." 


ERIC 


47 


Fluoridation  39 


ANTI-SIPHON  VALVE    METERING  PUMP 


SOLENOID  VALVE 


4 


nr 


•45- 


I  ;  FLUORIDE 
SOLUTION 


SODIUM 
FLUORIDE 


—  o- 


OVERFLOW 
CONNECTION 


FOR  SAMPLING 
AND 
CALIBRATION 


V 


WATER  SOFTENER       WATER  METER 


SATURATOR 


DRAIN 


Fig.  13.8  Fluoride  saturator 

(Permission  ol  Wallace  4  Tiernan  Division.  Pennwalt  Corporation) 


ERIC 


40  Water  Treatment 


MIXING 
FUNNEL  I 


OPTIONAL 


ADD  A  MEASURED  AMOUNT  Or  CHEMICAL 
4  MECHANICAL  MIXER 


MEASURED 
AMOUNT  OF 
WATER 


DISSOLVING  TANK 
(BATCH  MIXED) 


KNOWN 

CONCENTRAT?ON 
OF  SOLUTION 


DAY  TANK  OR 
STORAGE  TANK 


CHEMICAL 
FEEDER 
(FLOW- 
PACED) 


TO  WATER 

BEING 

TREATED 


Fig.  13  9  Dry  chemical  dissolves  day  tank  and  feeder 


ERIC 


49 


Ftg.  13.10  Downflow  saturator 

(Reproduced  from  WATER  FLUORIDATION.  A  Training  Course  Manual  for  Engineers 
and  Technicians,  by  permission  of  the  Dental  Disease  Prevention  Activity. 
U  S  Public  Health  Service) 


Fig.  13.11   Upflow  saturator 

(Reproduced  from  WATER  FLUORIDATION,  A  Training  Course  Manual  for  Engineers 
and  Technicians,  by  permission  of  the  Dental  Disease  Prevention  Activity. 
U  S  Public  Health  Service) 


50 


42   Water  Treatment 


matenal  if  crystal  >s  not  available  for  some  reason, 
powder  can  be  used,  but  is  not  as  desirable  as  a  crystal 
form  of  sodium  fluoride. 

2.  Connect  the  solenoid  water  valve  to  an  electric  outlet  and 
turn  on  the  water  supply.  The  water  level  should  be 
slightly  below  the  overflow;  if  it  is  not,  the  liquid  level 
switch  should  be  adjusted. 

3.  Replace  the  intake  float  and  connect  it  to  the  feeder 
intake  line.  The  saturator  is  now  ready  to  use. 

4  By  looking  through  the  translucent  wall  of  the  saturator 
tank,  you  should  be  able  to  see  the  level  of  undissolved 
sodium  fluoride.  Whenever  the  level  is  low  enough,  add 
another  100  pounds  (45  kg)  of  fluoride. 

5.  The  water  distributor  slits  are  supposed  to  be  essentially 
self-cleaning,  and  the  accumulation  of  insolubles  and 
precipitates  does  not  constitute  as  serious  a  problem  as  it 
does  in  a  down-flow  saturator.  However,  a  periodic 
cleaning  is  still  required  Frequency  of  cleaning  is  dictated 
by  the  severity  of  use  and  the  rate  of  accumulation  of 
debns. 

6.  Because  of  the  thicker  bed  of  sodium  fluoride  attainable 
in  an  upflow  saturator,  higher  withdrawal  rates  are  possi- 
ble. With  300  pounds  (136  kg)  of  sodium  fluoride  in  the 
saturator  tank,  more  than  15  gallons  per  hour  (58  L/hr)  of 
saturated  solution  can  be  fed.  This  rate  is  sufficient  lo 
treat  about  5,000  gallons  per  minute  (135  L/sec)  of  water 
to  a  fluoride  level  of  1 .0  mg/L. 

7.  The  fixed  water  inlet  rate  of  4  GPM  (0.25  L/sec)  should 
register  satisfactorily  on  a  Ve-mch  (16  mm)  meter. 

From  a  financial  point  of  view,  many  water  systems  will 
want  to  design  their  fluoridation  plants  for  unattended  oper- 
ation; so  there  will  be  designed  into  the  system  means  for 
automatic  shut  down  and  alarm.  For  the  sake  of  the  operator 
that  has  to  respond  at  all  hours,  alarm  lights  should  be  wired 
to  indicate  reasons  for  plant  shutdown. 

A  few  example  alarms  include  low  water  flow  in  the  mam 
pipeline;  high  fluoride  flow;  high  or  low  fluoride  levels,  low 
injection  water  pressure,  power  outage,  and  running  time 
meter  to  indicate  "down"  time.  These  warning  systems  are 
partially  helpful  in  large  systems. 

13.34  Large  Hydrofluosillcic  Acid  Systems  (Figure  13.12) 

A  more  complicated  system  for  fluoridation  is  a  closed- 
loop  control  feeding  system  using  hydrofluosilicic  acid.  This 
system  finds  use  in  large  installations  where  the  hydrofluosi- 
licic acid  can  be  delivered  by  tanker  truck  of  around  4.000 
gallons  (1 5,140  L);  although  of  course,  smaller  amounts  can 
be  purchased.  The  installation  depicted  in  Figure  13.12  can 
treat  up  to  285  million  gallons  per  day  (1 ,079  ML/day).  The 
advantages  in  this  system  are  V^e  elimination  of  dusting  and 
also  labor  requirements  are  a',  a  minimum. 

The  storage  tanks  are  fiberglass  filament  wound  with 
interior  lining  of  Dera  Kane  41 1-45  Resixl  with  a  final  barrier 
of  Nexus  Veil  which  has  replaced  Dynel.  Steel  tanks  lined 
with  at  least  3/32  inch  (2.34  mm)  polyvinyl  chloride  sheet  or 
neoprene  sheet  secured  to  the  metal  surface  with  adhesive 
can  also  be  used.  Hydrofluosilicic  acid  storage  tanks  con- 
structed of  plastic  should  be  housed  in  enclosures  to  protect 
the  tanks  from  vandalism.  Leaks  could  be  dangaous  to 
passers  by  and  will  kill  surrounding  vegetation.  The  tanks 
must  be  vented  to  the  outsiue  as  the  fumes  from  the  acid  are 
highly  corrosive. 

Inspection  of  internal  conditions  of  the  hydrofluosilicic 

ERIC  t 


tanks  should  be  made  on  two  year  intervals  as  some  lining 
detenoration  can  be  expected  over  a  penod  of  time.  Should 
small  leaks  occur  in  the  PVC  piping,  repairs  should  be  made 
at  once  as  they  will  only  become  worse  and  any  acid 
dripping  on  concrete  surfaces  vyill  dissolve  the  surface  fairly 
quickly. 

The  use  of  a  closed-loop  control  system  in  an  unattended 
plant  utilizing  a  fluoride  analyzer  as  one  of  the  controls  is  '  ot 
recommended.  The  problem  is  that  if  the  analyzer  goes 
haywire  and  incorrectly  indicates  low  fluoride  levels,  the 
system  wiil  try  to  correct  itself  and  increase  the  addition  of 
fluoride  chemical.  The  net  result  will  be  to  actually  over- 
fluoride  the  water  supply. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  59. 

13.3A  List  the  three  different  types  of  situations  whereby 
drinking  waters  may  contain  fluoride  ions. 

13.3B  List  three  important  design  features  o*  fluoridation 
systems. 

13.3C  What  problems  can  be  created  by  hard  water  in 
systems  using  saturators  and  dissolving  tanks? 

13.3D  What  is  a  saturator? 


13.4  FINAL  CHECKUP  OF  EQUIPMENT 
13.40  Avoid  Overfeeding 

The  operator  must  be  certain  that  there  will  be  no  over- 
feed of  fluoride  ions.  A  gross  overfeed  can  cause  illness  and 
bad  public  relations.  Of  ail  the  chemicals  used  in  the  water 
treatment  plant,  fluoride  concentrations  are  probably  the 
most  sensitive  to  correct  maximum  dosages. 


13.41   Review  of  Designs  and  Specifications 

When  reviewing  fluoride  feeding  system  designs  and 
specifications,  the  operator  should  check  the  items  listed 
below. 

1 .  Review  the  results  of  pre-design  tests  to  determine  the 
fluoride  rate  for  both  the  present  and  future.  The  fluori- 
dator  should  be  sized  to  handle  the  full  range  of 
chemical  doses  or  provisions  should  be  made  for  future 
expansion. 

2.  Determine  if  sampling  points  are  provided  to  measure 
chemical  feeder  output. 


SQUARE  ROOT 
CONVERTER 


POWER  SUPPLY 


RECEIVER 


RATIO 
CONTROLLER 


SUCTION 


r. 


CHEM/METER  PUMP 


D/P  CELL  TRANSMITTER 


PRIMARY  DEVICE 


TRANSMISSION  MAIN 


ERIC 


52 


Fig.  13. 12  Large  automatic  hydrofluosilicic  system 


^  FLOW  TO  CURRENT 
CONVERTER 

^  METERING 

i  TRANSMITTER 


i 


DISCHARGE 


3 


53 


c 
o 

3 

a 

01 

5* 

3 


44  Water  Treatment 


3.  Examine  plans  for  valving  to  allow  flushing  the  system 
with  water  before  removing  from  service 

4.  Be  sure  corrosion-resistant  drams  are  provided  to  pre- 
vent chemical  leaks  from  reaching  the  floor,  for  exam- 
ple, dnps  from  pump  packing. 

5  Check  that  all  piping,  valves  and  fittings  are  made  of 
corrosion -resistant  materials  such  as  PVC  or  Stainless 
Steel  Type  316. 

6.  Determine  the  arount  of  maintenance  required.  The 
system  should  require  a  minimum  of  maintenance. 
Equipment  should  be  standard,  with  replacement  parts 
readily  available. 

7.  Consider  the  effect  of  changing  head  v^onditions  (both 
feeder  suction  and  discharge  head  conditions)  on  the 
chemical  feeder  output.  Changing  head  conditions  will 
not  affect  tfie  output  if  the  proper  chemical  feeder  has 
been  specified  and  installed. 

8.  Determine  whether  locations  for  monitoring  readouts 
and  dosage  controls  are  convenient  to  the  operation 
center  and  easy  to  read  and  record. 

9.  Any  switches  that  throw  the  equipment  from  automatic 
into  a  hand  or  manual  mode  should  be  equipped  with  a 
red  warning  light  to  indicate  that  the  equipment  is  on 
"hanc?"  or  "manual."  This  can  easily  be  accomplished  by 
a  double-throw,  double-poie,  toggle  switch.  Lights  with 
different  colors  can  be  used  to  indicate  normal  or 
automatic  operation  as  well  as  on  or  off  in  order  to  avoid 
confusion. 

1 0.  The  location  where  flu.,-'de  is  added  to  the  water  should 
be  where  there  will  be  the  least  possible  removal  o* 
fluoride  by  other  chemicals  added  to  the  water  (after 
filtration  and  before  the  clear  well) 

1 1  Be  sure  the  chemical  hoppers  are  located  where  there 
IS  plenty  of  room  so  they  can  be  conveniently  and  safely 
filled  With  the  fluoride  chenical. 

12.  Dust  exhaust  systems  should  be  installed  wnere  sub- 
stantia! amounts  of  dry  chemicals  are  handled. 

13.  In  any  fluoridation  system,  except  the  sodium  fluoride 
saturator,  scales  are  necessary  for  weighing  the  quanti- 
ty of  chemical  (including  solution)  fed  per  day. 

14.  Aktrms  are  important  to  signal  and  prevent  both  the  loss 
of  feed  and  overfeeding. 

15.  Any  potable  water  line  connected  to  a  chemical  feeder 
unit  must  be  provided  with  a  vacuum  breaker  or  an  a.r 
gap  to  prevent  a  cross-connection. 


n  .5   CHEMICAL  FEEDER  STARTUP 

After  the  chemical  feed  system  has  been  purchased  and 
installed,  carefully  chock  the  system  out  before  startup 
Even  if  the  contractor  who  installed  the  system  is  responsi- 
ble for  insuring  that  the  equipment  operates  as  designed, 
the  operation  by  plant  personnel,  the  functioning  of  the 
equipment  and  the  results  from  the  process  are  the  respon- 
sibility of  the  chief  operator.  Therefore,  before  startup, 
check  the  items  listed  below. 

1.  Inspect  the  electrical  syster.  for  proper  voltage;  for 
properly  sized  overload  protection;  for  proper  operation 
of  control  lights  on  the  control  panel;  for  pioper  safety 
lock-out  switches  and  operation;  and  for  proper  equip- 
ment rotation. 

ERIC  54  • 


2  Confirm  that  the  manfacturer's  lubncation  and  startup 
procedures  are  being  followed  Equipment  may  be 
damaged  in  minutes  if  it  is  run  without  lubncation. 

3.  Examine  all  fittings,  inspection  olates  and  drains  to 
assure  that  they  will  not  leak  when  placed  into  service. 

4.  Determine  the  proper  positions  for  all  valves.  A  positive 
displacement  pump  will  damage  itself  or  rupture  lines  in 
seconds  if  allowed  to  run  against  a  closed  valve  or 
system. 

5.  Be  sure  that  the  type  of  fluonde  to  be  fed  is  available 
and  in  the  hopper  or  feeder.  A  progressive  cavity  pump 
will  be  damaged  in  minutes  if  it  is  allowed  to  run  dry. 

6.  Inspect  all  equipment  for  binding  or  rubbing. 

7.  Confirm  that  safety  guards  are  r  place. 

8  Examine  the  operation  of  all  auxiliary  equipment  includ- 
ing the  dust  collectors,  fans,  cooling  water,  mixing 
water,  and  safety  equipment. 

9.  Check  the  operation  of  alarms  and  safety  shut-offs.  If  it 
IS  possible,  operate  these  devices  by  manually  tripping 
each  one.  Examples  of  these  devices  are  alarms  and 
shut-offs  for  high  water,  low  water,  high  temperature, 
high  pressure  and  high  chemical  levels. 

10,  Be  sure  that  safety  equipment  such  as  eyewash,  drench 
showers,  dust  masks  face  shields,  gloves  and  vont 
fans,  are  in  place  and  functional. 

11.  Record  all  important  nameplate  data  and  place  it  in  the 
plant  files  for  future  reference. 

QUESTIONS 

Write  your  answers  ir  a  notebook  and  then  compare  your 
answers  with  those  on  page  59. 

13.4A  Why  must  overfeeding  of  fluoridation  chemicals  be 
prevented? 

13  4B  What  should  be  the  capacity  or  size  of  the  fluorida- 
tor? 

13  5 A  What  items  should  be  considered  when  inspecting 
the  fluoridaJon  electncal  system'? 

13  5B  List  the  safety  equipment  that  should  Ls  available 
near  a  fluoridation  system 

13.6   CHEMICAL  FEEDER  OPERATION 

13.60  Fine  Tuning 

Once  the  chemical  feed  equipment  is  in  operation  and  the 
major  "bugs"  are  worked  out,  the  feeder  will  need  to  be  "fine 
tuned  "  To  a  j  in  fine  tuning  and  build  confidence  in  the  entire 
chemical  feed  system,  the  operator  must  maintain  accurate 
records  (see  Section  13.62,  "Fluoridation  Log  Sheets"). 


Fluoridation  45 


A  comment  or  remarks  section  should  be  used  to  note 
abnormal  conditions,  such  as  a  feeder  plugged  for  a  short 
time,  related  equipment  that  malfunctions  and  other  prob- 
lems Daily  logs  should  be  summanzed  into  a  form  that 
operators  can  use  as  a  future  reference. 


13.61   Preparation  of  Fluoride  Solution 

To  learn  how  to  make  up  a  fluoride  solution,  let's  assume 
a  hypothetical  case  using  the  following  data: 

1.  Flow  to  be  treated  is  10  million  gallons  per  day, 

2.  Hydrofluosihcic  Acid  20%  is  the  chemical  to  be  used, 

3.  The  unfluoridated  water  contains  0,05  mg/L  (ppm)  flu- 
oride ion  (F"),  and 

4.  The  desired  fluoride  concentration  in  the  treated  watei  is 
1.C  mg/L 

What  should  the  feed  rate  be? 

See  Treatment  Chart  I,  Hydrofluosilicic  Acid,  located  on 
the  next  page. 

Locate  the  10  MGD  flow  on  the  left  hand  scale  of  the  graph 
and  follow  that  line  to  the  right  until  it  intersects  the  20 
PERCE/vr diagonal  line.  Project  this  point  down  vertically  to 
the  intersection  of  bottom  line  indicating  gallons  per  day  (or 
gallons  per  hour)  required  to  produce  a  one  mg/L  (ppm) 
dose  of  fluoride  (F).  The  answer  is  50  GALLONS  PER  DAY 
or  a  little  less  than  2. 1  GFH (gallons  per  hour).  Multiply  the  50 
by  (1 .00-0.05)  to  give  the  needed  treatment  of  47.5  gallons 
per  day  or  2  GPH.  The  1 .00  is  the  desired  dose  of  1 .00  mg/L 
and  X\\e  0.05  is  the  actual  fijoride  concentration  of  0.05  mg/L 
in  the  untreated  water. 

In  some  cases  it  might  be  desirable  to  use  a  weaker  acid 
solution  to  avoid  feed  rates  below  the  minimum  capacity  of 
the  metering  pump.  Dilution  then  is  in  order.  Tho  concentra- 
tion may  be  reciucea  by  volumetnc  proportions,  for  example 
one  gallon  of  20  percent  acid  plus  one  gallon  of  water  results 
in  two  gallons  of  10  percent  acid.  If  possible  try  to  avoid 
having  to  dilute  acid  because  of  potential  errors  and  prob- 
lems, especially  with  hard  water.  Peristaltic  and  electronic 
feeder  pumps  (Figures  13.2  and  13.3)  may  be  used  when  the 
feed  rates  are  low. 

See  Section  13.12,  "Calculating  Fluoride  Dosages,"  for 
eleven  example  problems. 

13.82  Fluoridation  Log  Sheets 

You  will  probably  want  to  design  your  own  log  sheets  so 
they  will  be  consistent  with  the  installation  features  at  your 
plant.  Sample  log  sheets  are  shown  on  Figures  13.13,  13.14 
and  13.15  (see  pages  49,  50  and  51). 

13.620  Hydrofluosilicic  Acid 

Figure  13.13  shows  a  typical  log  sheet  from  a  hydrofluosi- 
licic acid  station.  An  explanation  of  the  various  columns  is 
given  beiow. 

1.  "Date"  refers  to  calendar  date  when  readings  were 
logged  or  the  date  a  shipment  of  fluoride  was  received. 

2.  "Time"  refers  to  time  eve^lt  happened. 

3.  "Tank"  that  is  supplying  the  feeder  is  circled.  "Gals." 
refers  to  the  gage  reading  of  the  amount  of  acid  in  the 
tank. 

ERLC 


4.  "%  &  Sp.Gr "  Each  delivery  is  accompanied  by  a  ven- 
dor's laboratory  analysis.  The  specific  gravity  is  not 
measured  until  the  tank  is  ready  to  be  placed  in  service. 
When  mixing  acids  of  varying  strengths,  the  end  per- 
centage must  be  calculated  and  entered  in  the  proper 
column.  See  Example  10  in  Section  13.12,  "Calculating 
Fluoride  Dosages." 

5.  For  each  tank  follow  the  directions  givt    n  Step  4. 

6.  "Tank  Loss  Gals"  refers  to  the  amount  of  feed  during  the 
reporting  period.  In  the  sample  2930-2600  =  330  gal- 
lons. The  feeding  equipment  should  be  equipped  with 
an  acid  totalizer  readout. 

7.  The  "ratio"  column  indicates  the  feed  setting  computed 
using  the  acid  strength,  specific  gravity  and  required 
dosage.  The  following  steps  illustrate  how  to  calculate 
the  feed  setting  for  a  specific  piece  of  equipment. 

(a)  (Sp.Gr.)(lbs/gal  water)(%  H2SIFe)(%  P-  (in  H2SiFg)) 
=  lbs  F7gal. 

(b)  Substituting  figures  in  the  above  formula. 

(c)  (1.226)(8.34)(0.229)(0.791)  =  1.85  lbs  F7gal. 

(d)  Dosage:  8.34  1.85  -  4.51  gallons  acid/M.G. 
water. 

(e)  In  order  to  compensate  for  the  .05  mg/L  F~  m  the 
raw  water  supply,  the  above  figure  of  4.51  should 
be  reduced  by  5%  which  is  the  relationship  of  the 
desired  level  of  say  1  mg/L  F'  to  the  raw  water  level 
of  .05  mg/L  F". 

(f)  4.51  -  (.05  X  4.51)  =  4.51  -  .23  -  4.28. 

(g)  Ratio  setting  therefore  is  4.28  ^  4.80  or  0.89. 

(h)  The  flow  capacity  of  the  pipeline  water  meter  at 
100%  is  300  MGD. 

(0  The  flow  capacity  of  the  acid  feed  pump  is  1440 
gallons  of  HgSiFg/day. 

The  ratio  of  the  above  two  100%  capacities  is  1440 
^  300  or  4.8gal/MG. 

Note  the  difference  of  the  setting  of  0.88  and  the 
calculated  figure  of  0.89.  This  adjustment  is  made  in 
order  that  the  fluoride  dosage  will  agree  with  the 
laboratory  results.  In  all  instances,  the  laboratory 
results  should  govern  the  feed  settings. 

The  small  difference  in  calculated  setting  and  actual 
setting  can  also  result  from  accumulated  errors  m 
the  control  equipment,  i.e.,  flow  transmitter,, 
\/        extractor,  and  ratio  controller. 

8.  "HgSiFg  Gals."  IS  the  actual  amount  of  acid  fed  into  the 
system  and  is  denved  as  follows: 

885005.50  -  884676.08  -  329.42  gallons 
Ths  figure  should  be  fairly  close  to  the  reading  obtained 
at  Step  6.  If  it  is  not,  look  for  e.  rors  in  readings,  leaks  or 
equipment  malfunctioning. 

10.  "Water  Meter  Totalizer"  is  the  cumulative  total  of  the 
amount  of  water  being  treated  measured  by  a  venturi  or 
some  other  type  of  pnmary  water  meter. 

11.  "Wdler  M/Gals."  is  the  actual  amount  of  water  passing 
through  the  water  meter  for  the  time  period  involved  and 
again  is  derived  by  simple  subtraction: 

268.00  -  191.01  =  76.99  Million  Gallons. 

53  .... 


46  Water  Treatment 


TREATMENT  CHART  I 
Hydrofluosilicic  Acid 


TREATMENT  CHART  li 
Hydrofluosilicic  Acid 

Treatment  Charts  Courtesy  of 
Wallace  &  Tiernan  Division,  Pennwalt  Corporation 


ERIC 


56 


Fluoridation  47 


TREATMENT  CHART  IV 

Treatment  Charts  Courtesy  of 
Wallace  &  Tiernan  Division,  Pennwait  Corporation 


ERIC 


48  Water  Treatment 


12  "Acid  Gal/MG"  is  the  rate  of  treatment  for  hydrofluosili- 
cic  acid  and  is  obtained  by  dividing  the  figures  from  Step 
9  by  the  figure  from  Step  1 1 . 
329.42  ^  76.99  =  4.28 

13.  T  RESID.  PPM"  jc  actual  fluoride  content  in  the  treated 
water  as  read  by  continuous  flow  fluoride  ion  analyzer. 

1 4.  "Down  Time"  The  equipment  should  be  equipped  with  a 
rr*  ling  time  meter  reading  in  seconds  that  begins  to 
operate  any  time  the  plant  shuts  down.  This  will  give 
reasons  for  low  feed  as  indicated  by  the  readings  in 
Step  12.  The  operator  should  know  why  this  deviation 
occurred. 

15.  "OBS.BY**  This  will  be  the  operator's  initials. 
13.621   Sodium  Silicofluoride 

1  Figure  13.14  is  a  typical  log  sheet  for  a  gravimetric 
feeder  feeding  powder  sodium  silicofluoride. 

2.  "Date"  and  "Time"  are  entered  in  the  first  two  columns. 

3.  Totalizer  Reading  (lbs.)"  This  reading  indicates  a  cumu- 
lative reading  of  the  amount  of  silicofluoride  that  has 
been  fed  by  the  machine. 

4.  "Weight  Loss  per  24  hrs.  (lbs)"  is  the  amount  of  silico- 
fluoride actually  fed  during  the  time  frame  and  is  deter- 
mined from  the  readings  observed  in  Step  3  as  follows. 

44165.5  -  43276.9  =  888.6. 

5.  "Mach.  Feed  Setting"  is  the  feed  rates  being  used.  This 
rate  may  vary  from  machine  to  machine  depending  upon 
gear  ratios  and  other  devices  used  to  control  the  rate  of 
chemical  feed.  If  the  laboratory  te sts  indicate  low  or  high 
fluoride  ion  level,  the  adjustment  is  made  with  this 
setting  on  a  percentage  basis.  If  the  laboratory  fluoride 
ion  level  is  10  percent  low,  then  this  setting  should  be 
raised  10  percent. 

6.  'Chem  Added  to  Bin  (lbs.)"  is  the  amount  of  chemical 
taken  from  storage  and  dumped  into  the  feeder  hopper 

7.  "Chemical  Left  in  Storage  (lbs.)"  is  the  amount  of  fluoride 
in  the  bulk  storage.  This  is  useful  in  programming 
supply  orders  and  in  checking  the  accuracy  of  the 
feeder  over  a  period  of  time  To  check  accuracy,  com- 
pare this  amount  with  the  amount  indicated  in  Step  4 
over  a  six  month  or  one-year  period. 

8.  Tump  Operating"  Is  useful  if  several  pumps  are  avail- 
able to  inject  the  dissolved  sodium  silicofluoride  into  the 
water  main. 

9.  "WaterMeter  Reading  (10,000  gals)"  IS  the  reading  from 
the  main  line  water  meter. 

10.  "Water  Treated  (m.g.)"  ,  the  amount  of  water  actually 
treated  and  is  derived  from  Step  9  data  as  follows: 
39829.73  -  39762.41  =  67.32. 

1 1  "Dosage  (lbs.  per  m.g.)"  represents  the  actuai  dosage  of 
fluoride  in  the  water.  This  figure  should  Ls  constant, 
barring  down  time;  changes  in  machine  feed  setting. 
Step  5  or  equipment  malfunctioning.  The  value  is  de- 
rived from  the  weight  loss  (Step  4)  divided  by  the  \  .er 
treated  (Step  10)  as  follows: 
888.6    67.32  =  13.2. 

12.  "Plant  Down  Time  (Hrs the  period  of  tlrr.e  fluoride 
was  not  bein^  fed  and  the  plant  was  shut  down  because 
of  power  failure  or  automatic  shutdown.  The  installation 


should  be  equipped  ^\\h  a  resettable  running  time  meter 
reading  hours  and  tenths. 

13.  Figure  13.15  is  a  typical  small  plant  log  l  .oet  used  in 
plants  utilizing  sodium  silicof'ucide.  This  log  sheet  is 
provided  through  the  courtesy  of  the  City  of  Palo  Alto. 
California. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  59. 

*i3.6A  What  should  be  the  feed  rate  m  gallons  per  day  for 
tre^iting  6  f^GD  with  hydrofluosilicic  acid  20  percent  if 
the  desired  fluonde  ion  concentration  is  1.2  mg/L? 
Assume  the  raw  water  does  not  contain  any  fluoride 
ion. 

1 3  68  What  could  be  the  causes  of  differences  between  the 
recorded  volume  of  acid  used  from  a  storage  tank 
and  the  volume  of  acid  fed  into  the  system  as 
measured  by  a  flow  meter? 

13.7    PREVENTION  OF  OVERFEEDING 

1.  Operatois  must  be  assured  that  no  overfeeding  occurs, 
because  no  additional  benefits  result  from  overfeeding 
and  there  is  a  waste  of  chemicals  and  money.  Excessive 
overfeeding  could  be  harmful  to  consumers. 


2  If  the  Size  of  the  installation  warrants,  a  continuous 
fluoride  ion  analyser  should  be  installed  in  the  treated 
water  line  located  downstream  a  sufficient  distance  so 
that  adequate  mixing  is  assured. 

3.  In  a  large  plant  involving  shift  operation,  grab  samples 
can  be  analyzed  for  the  fluoride  level  during  each  shift, 
otherwise,  once-a-day  checks  will  suffice. 

4.  If  th  plant  uses  one  of  the  solid  iiuoride  compounds  and 
the  opeiator  questions  whether  there  is  total  solubility, 
the  fluoride  feeder  can  be  shut  down  and  the  lack  of 
fluoride  traced  out  in  the  distribution  system.  There 
should  be  a  sudden  drop  to  zero  fluoride  or  to  the 
background  level  if  total  solubility  is  not  being  achieved 
(the  undissolved  solid  fluoride  compound  will  settle  out). 

5.  All  liquid  systems  should  be  checked  for  positive  protec- 
tion against  back  siphonage  from  fluoride  storage  tanks. 

6.  Shut  down  the  plant  if  there  is  any  significant  overfeeding. 
Start  flushing  the  affected  mams  and  notify  the  local  and 
state  health  departments.  The  water  department  and  the 
health  departments  will  then  decide  if  public  notification 
should  be  undertaken. 

13.8  UNDERFEEDING 

In  contrast  to  the  chlorination  operation  where  continuous 
operation  must  be  assured,  fluoridation  does  not  have  to  be 
continuous.  Shutdowns  for  cleaning,  adjustments,  or  due  to 


58 


BYPASS  TUNNEL  FLUORIDE  STATION 

WEEK  ENDING  h f^.^^ii m tT  // ^  J9S/ 


DATE 

TIME 

ACID    STOR  AGE 

TANK 
LOSS 
GALS 

RATIO 

H2SIF6 
TOTALIZER 

HjSlFg 
GALS 

WATER  METER 
TOTALIZER 

WATER 
M/GALS. 

ACID 
GAL/MG 

F 

RESID 
PPM 

DOWN 
1 IME 

08S 
BY 

(^tankO 

TANK  2 

TANK  3 

TANK  4 

GALS. 

%  & 

SP.  GR 

GALS 

%  & 

SP  GR 

GALS 

%  & 
SP  GR 

GALS 

%  & 
SP  GR 

END  OF 
PREVIOUS  WEEK 

 *it  V  r  I  *^  

-^-2^ — 

lt*rt^  A 
ILOQ  h. 

1 

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 \  

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1 

1 

i 
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1 

1 

1 

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i 

.1 

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1 

\ 
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i 

i 

: 

1 

1 

1 

1 
i 

BPF              FLOW        F&P  1 
METER  METER 

■   L 

REMARKS 

Fig.  13. 13  Log  sheet  for  bypass  tunnel  fluonde  station  ^  ()  S 


Station_ 


FLUORIDE  STATION  REPORT 


Week  Ending.  .2)^.4^  g  / 


Date 


Time 


Totaliicr 
Reading 
(lbs) 


Weight 
Loss  per 
24hr$ 
(IbO 


Mach 
Feed 
Set* 
tmjj 


Chem. 
Added 
to  Bin 
(lbs) 


Chemjcal 
Left  in 

Storage 
(IbO 


Pump 
Oper- 
ating 


Water 
Meter 
Reading 
(10,000  gal.) 


Water 
Treated 
(m  g  ) 


Dosage 

(lbs 

pjr 
mj!  ) 


Plant 
Down  Time 
(Hrs) 


Feeder 
Time 
Lapse 
(-ec  ) 


Ohs' 


o 


i 

3 


END  OF  PREVIOUS  WEI 


lA. 


AM. 


U. 


*0  0       ^  ^  ''^  ^"'^  fluor/c^e  .stef/on  reports  '  f^ry 


ERIC 


City  of  Palo  Alto 


Water  Division 


Week  Ending  We J. 


WFEKLY  WATER  PRODUCTION  AND  TREATMEffT  LOG 

19        •  Station: 


Sacks 
on  hand 

F  L  J  0  R  1  D  E 

Feedor  Lbs. 

Feed 
Se 1 1  in>; 

Gale 

Timer 

Start 

AJd 

F  ma  1 

Used 

3ettin« 

Total 

Wed. 

Tues . 

Mon . 

Fri  . 

Thur s . 

Previous 

Pump  A 


No.  motor  starts 


□ NO. 
No»  running  hours 

Lead  Pump  | 

□No»  motor  starts 
No»  running  hours 


WATER     (  CCF  ) 

SAND 
(ml) 

Meter  Record 

ConfluHption 

REMARKS 

OTHER  METER  READINGS 

iiftter  Function 

Present  Reading 

Previous  Reading 

Difference 

cn 
»• 

C  H 

1.  0  R 

I  N  E 

q;  ^ 
•o  c 
C  n> 
•H 

Cy  1 1  rider  , 

Lbs. 

OTO 

FopJ 

1  cs  id . 

u  •/ 

Crot  ^ 

fare 

Usfd 

Rate 

n..:/l 

Prv- V  lou 

Thurs . 

Fi  1 

M,.n. 

I 

J, 

Tot  ji 

r)3 


MISCELLANEOUS  Mf-:ASUKEMKN1  S 

We  1 1  static  level .  ft. 

Well  pumping  level.  It. 

Head  against  well,  pump,  psi 

Amp  drav  reading 

L  IC 

R 

c 
o 

a 
o 

3 


52  Water  Treatment 


safety  controls  can  be  tolerated  for  short  time  periods.  This 
does  not  mean  that  Sioppy  operation  and  maintenance  is 
desirable.  Every  attempt  should  be  made  to  maintain  con- 
stant feeding.  For  example,  the  installation  of  standby  elec- 
trical generating  equipment  just  to  maintain  fluoridation 
equipment  m  operation  would  not  be  warranted.  If  the 
standby  generator  had  to  be  purchased  for  other  reasons, 
then  the  emergency  circuit  may  also  include  the  fluoride 
feeding  equipment  Underfeeding  should  not  be  allowed 
because  this  results  in  a  very  significant  reduction  of  the 
benefits  of  fluondation. 


Daily  inspection  of  the  fluoridation  equipment,  fiuoride 
tests  on  the  treated  water,  and  calculation  of  the  dosage 
from  water  treatment  and  chemical  use  data  can  greatly 
minimize  the  possibility  of  both  overfeeding  and  underfeed- 
ing. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  59. 

13.7A  Why  should  overfeeding  be  prevented? 

137B  What  should  be  done  if  significant  overfeeding  oc- 
curs'^ 

13.8A  Why  might  a  fluoridation  operation  be  shut  down? 
13.9  SHUTTING  DOWN  CHEMICAL  SYSTEMS 

If  the  fluoridation  equipment  Is  going  to  be  shut  down  for 
an  extended  length  of  time.  It  should  be  cleaned  out  to 
prevent  corrosion  and/or  the  solidifying  of  the  chemical. 
Lines  and  equipment  could  be  damaged  when  restarted  if 
chemicals  left  in  them  solidify.  Operators  could  be  seriously 
Injured  if  they  open  a  chemical  line  that  has  not  been 
properly  flushed  out. 

The  following  items  should  be  included  in  your  checklist 
for  shutting  down  the  chemical  system: 

1 .  Flush  out  the  chemical  supply  with  water, 

2.  Run  dry  chemicals  completely  out  of  the  equipment  and 
clean  equipment  by  using  a  vacuum  cleaner, 

3.  Flush  out  all  the  solution  lines  with  water  until  the  lines  are 
clean, 

4.  Shut  off  the  eiectncal  power, 

5.  Shut  off  the  water  supply  and  PROTECT  FROM  FREEZ- 
ING, 

6.  Drain  and  clean  the  mix  and  feed  tanks,  and 

7.  Padlock  (lock  out)  the  mam  electric  switch  box  to  the 
fluoride  equipment. 


13.10  MAINTENANCE 

Maintenance  should  follow  the  same  routine  as  with  any 
Similar  chemical  feeder,  including  regular  clean  up  and 
painting  of  the  equipment  and  appurtenant  metal  piping  and 
conduits  In  order  to  give  the  plant  a  fresher  look  and  hold 
down  on  painting,  consider  using  all  plastic  piping  even 
though  It  IS  used  only  for  the  water  supply.  Conduit  and 
fittings  should  also  be  plastic  for  the  same  reason.  Vacuum 
any  gears  and  other  similar  parts  to  remove  fluoride  dusL 


Since  fluoride  solutions  are  extremely  corrosive,  be  con- 
stantly on  the  lookout  for  dnps  or  leaks  and  any  other 
evidence  of  corrosion.  Repair  these  conditions  as  quickly  as 
possible.  Also  look  for  the  buildup  of  insoluble  deposits  in 
feedllnes  and  equipment.  Schedule  the  removal  of  Insoluble 
deposits  on  a  regular  oasis  to  prevent  buildups  from  creat- 
ing any  problems. 

AH  containers  of  fluoride  chemicals  must  be  disposed  of  in 
an  acceptable  manner.  Thoroughly  rinse  all  containers  with 
water  to  remove  all  traces  of  chemicals  before  allowing 
containers  to  leave  your  plant.  You  may  burn  the  containers 
if  a  nuisance  will  not  be  created.  Remember  that  fluoride 
fumes  can  kill  vegetation. 

You  don't  need  to  be  too  concerned  about  checking  the 
feed  rate  by  catching  a  given  amount  of  fluoride  over  a  time 
period.  The  log  will  show  long-period  discrepancies  and  the 
daily  laboratory  tests  will  indicate  any  drifting  from  the 
desired  fluonde  concentration  in  ♦^^e  treated  water. 

Either  you  or  the  laboratory  personnel  must  analyze  the 
fluoriaated  water  daily.  Check  the  results  for  any  deviations 
from  the  norm  and  take  corrective  action.  Hand-held  colori- 
meters are  available  for  measuring  fluoride  in  water.  See 
Chapter  21,  "Advanced  Laboratory  Procedures,"  for  details 
on  how  to  analyze  samples  for  the  fluoride  ion. 

An  important  part  of  your  maintenance  program  is  the 
prevention  of  any  sanitary  defects  that  could  adversely 
affect  the  safety  or  quality  of  your  treated  drinking  wator. 
Sanitary  defects  that  could  develop  in  fluondation  syste.nii 
include: 

1.  Lack  of  or  inadequate  start-stop  controls, 

2.  Inadequate  feed  rate  control  equipment, 

3.  No  analyzer  to  measure  fluonde  ion  levels  in  treated 
water, 

4.  Lack  of  or  inadequate  backflow  safeguards, 

5.  Fluondation  chemical  not  meeting  AWWA  specifications, 
and 

6.  inadequate  free  chlonne  residual  in  treated  water. 


Fluoridation  53 


13.11    SAFETY  IN  HANDLING  FLUORIDE  COMPOUNDS^ 

From  the  operators  viewpoint,  fluoride  chemicals  have 
one  thing  in  common  with  all  other  chemicals  found  in 
treatment  plants:  FLUORIDE  CHEMICALS  can  seriously 
mjure  or  kill  the  careless  or  untrained  operator.  Safety 
should  be  of  special  concern  to  YOU  because  it  is  your  own 
health  that  is  at  stake. 

13.110  Avoid  Overexposure 

One  of  the  major  causes  of  overexposure  is  the  inhalation 
of  fluoride  dust  This  usually  occurs  while  a  dry  feeder  or 
saturator  is  being  loaded.  Even  with  the  use  of  dust  collector 
systems,  dust  will  circulate  In  the  air.  Always  use  approved 
respirators  equipped  with  cartridges  for  organic  dusts  and 
vapors,  protective  coveralls  and  gloves  when  emptying 
sacks  or  cleaning  up  equipment  and  plant  surfaces. 

When  loading  a  saturator,  dust  will  be  minimized  if  crystal- 
line sodium  fluonde  is  fed  instead  of  powdered  sodium 
fluoride.  V^hen  loading  a  cry  feedei  you  should  wear  a 
mask,  apron,  and  rubber  gloves  to  minimize  exposure. 

When  the  protection  gear  is  removed,  the  remaining  small 
traceb  of  chemical  should  also  be  removed  from  your  body. 
Some  large  water  plants  have  dust-collection  systems  that 
use  a  partial  vacuum  to  draw  dust  from  your  body  and  vent  it 
to  the  outside  air  after  fjitenng. 

Care  should  be  taken  when  emptying  bags  of  chemicals 
into  a  feeder  hopper.  Tl  e  bags  should  be  opened  carefully 
at  the  top  and  the  contents  poured  gently  to  minimize  dust. 
Care  should  also  be  taken  during  storage  of  the  bags.  Bags 
should  be  stored  in  a  dry  place,  preferably  off  the  floor.  If 
bags  are  stacked  too  high  there  is  the  possibility  of  them 
falling  and  breaking  open. 

If  a  saturator  is  used,  you  should  be  cautious  about 
allowing  the  solution  to  come  in  contact  with  skin  and 
clothing.  If  this  does  happen,  the  affected  area  should  be 
washed  immediately  with  water.  This  also  applies  to  other 
fluoride  solutions  (such  as  the  dissolving  water  used  in  a  dry 
feeder). 

If  a  fluoride  acid  is  being  fed,  extra  precaution  must  be 
taken.  Fluoride  acid  is  probably  the  most  corrosive  chemical 
found  in  a  water  plant  The  dH  of  fluoride  acid  is  approxi- 
mately 1.2  and  will  eat  through  glass  faster  than  chlorine. 
Special  care  should  betaken  to  keep  fumes  to  a  minimum.  If 
the  acid  does  come  in  contact  with  your  skin,  you  may  not  be 
able  to  wash  it  off  fast  enough  to  prevent  a  burn.  If  this 
happens,  standard  first  aid  should  be  administered  as  soon 
as  possible. 

A  good  pair  of  safety  goggles  should  be  worn  at  all  times 
when  working  around  fluoridation  equipment  where  there  is 
any  possibility  of  splashing  fluoride  solutions.  Be  especially 
cautious  around  the  fluoride  acids  as  the  concentrated  acid 
can  dissolve  the  whites  of  one's  eyes  in  addition  to  the  usual 
burns  associated  with  acids.  Another  "musf  is  a  safety 
shower.  This  must  be  Iricated  within  easy  access  to  both  the 
unh  iding  operation  z  id  points  of  liquid  usage. 

Another  safety  precaution  that  should  be  followed  is  the 
labeling  of  all  feeders  and  solution  tanks.  Proper  labeling  will 
help  prevent  placement  of  chemicals  in  the  wrong  feeder.  If 
possible,  fluoride  chemical  should  be  tinted  blue  to  differen- 
tiate it  from  ether  water  tr  ^atment  chemicals. 


13.111  Symptoms  of  Fluoride  Poisoning 

In  the  event  that  someone  is  poisoned,  it  is  vitally  impor- 
tant to  recognize  the  early  symptoms. 

Some  of  the  obvious  signs  of  poisoning  are  vomiting, 
stomach  cramps,  and  diarrhea.  Usually,  the  person  will 
become  very  weak,  have  trouble  speaking,  be  very  thirsty, 
and  have  poor  color  vision.  In  cases  of  extreme  poisoning, 
there  are  strong,  jerky  muscle  contractions  m  the  arms  and 
legs  leading  to  convulsions.  If  poisoning  is  not  treated 
immediately,  the  person  may  die.  Fatal  doses  range  from  4 
to  5  gm,  or  about  a  tablespoon.  Tl.is  equals  about  2,000 
times  the  amount  of  fluoride  swallowed  by  a  person  from  a 
water  supply. 

If  a  person  is  poisoned  by  Inhaling  fluoride,  the  first 
symptoms  will  be  a  sharp,  biting  pam  in  the  nose  followed  by 
a  runny  nose  or  nose  bleed.  It  is  doubtful  that  a  person  could 
inhale  enough  fluonde  to  produce  the  same  effects  as 
encountered  from  drinking  a  large  amount  of  fluoride.  How- 
ever, the  sudden  presence  of  bad  stomach  cramps  and 
pains  In  the  nose  and  eyes  should  not  be  ignc  3d. 

The  victim  should  see  a  doctor  immediately,  and  the  water 
treatment  practices  should  be  checked  to  determine  the 
source  of  the  fluoride  poisoning.  It  Is  probably  a  good  idea  to 
check  out  treatment  practices  occasionally. 

The  importance  of  quick  treatment  for  fluoride  poisoning 
cannot  be  over  emphasized.  In  such  cases  a  doctor  should 
be  called  immediately,  and  If  the  poisoning  is  severe,  an 
ambulance  should  be  called. 

13.112  Basic  First  Aid 

Once  It  IS  established  that  it  is  fluoride  poisoning,  first  aid 
should  be  started  while  waiting  for  medical  help  The  follow- 
ing are  recommended  first-aid  procedures: 

1 .  Move  the  person  away  from  any  contact  with  fluoride  and 
keep  warm, 

2.  Give  the  person  three  teaspoons  full  of  table  salt  In  a 
glass  of  warm  water, 

3.  If  the  person  is  conscious.  Induce  vomiting  by  rubbing  the 
back  of  the  ♦hroat  with  a  spoon  or  your  finger;  if  available 
use  syrup  of  ipecac, 

4.  Give  the  person  a  glass  of  milk, 

5.  Repeat  the  salt  and  vomiting  several  times,  and 

6.  Take  the  person  to  the  hospital  as  soon  as  possible. 

First  aid  for  a  person  with  a  nose  bleed  from  inhaling  a 
high  concentration  of  fluoride  is: 

1.  Take  the  person  away  from  the  source  of  the  fluonde; 

2.  Tip  the  person's  head  back  while  placing  cotton,  cloth,  or 
paper  towels  inside  the  nostnis  (change  these  often); 

3.  Take  the  person  to  a  doctor  if  you  cannot  stop  the 
bleeding. 

If  common  sense  and  good  safety  practice  are  used,  the 
hazard  to  the  water  plant  operator  should  be  as  small  as  the 
hazard  to  the  water  consumer. 

Gm^datbK  dicmie3iUarc  ^ot^fuyy^. 


7  Portions  of  the  material  in  fhts  section  were  adopted  from  "Safety  Procedures  Necessary  During  Fluoridation  Process, "  by  Ed  Hansen 
Reproduced  from  OPFLOW,  Volume  9,  No,  7,,  (July  1983)  by  permission.  Copyrigfit  1983,  Tfie  American  Water  Works  Association. 


54  Water  Treatment 


13.113  Protecting  Yourself  and  Your  Family 

Avoid  swallowing  fluoridation  chemicals.  Don't  eat,  dnnk 
nr  smOKO  in  or  around  chemical  storage  or  feed  areas.  Do 
riot  inhale  chemical  dusts  or  vapors.  Wear  a  respirator.  Be 
sure  exhaust  fans  and  dust  collectors  are  operating  proper- 
ly. Prevent  hydrofluosilicic  acid  from  coming  in  contact  with 
your  skin  or  eyes  t)ecause  hydrofluosilicic  acid  is  very 
corrosive.  If  any  hydrofluosilicic  acid  touches  you.  flood  the 
contact  area  with  plenty  of  water.  If  you  are  acutely  poisoned 
by  a  fluoride  chemical,  you  may  be  thirsty,  vomit  and  have 
stomach  cramps,  diarrhea,  difficulty  in  speaking  and  dis- 
turbed color  vision.  If  any  of  these  symptoms  occur,  consult 
a  physician  immediately. 

When  leaving  the  fluoride  plant,  wash  your  hands  and 
change  coveralls  so  that  fluoride  dust  Is  not  carried  home. 

13.114  Training 

Special  safety  training  must  be  given  to  all  operators  who 
will  handle  fluoride  compounds.  Training  must  include  how 
to  safely  receive  compounds  from  supplier,  store  until 
needed,  prepare  solutions,  load  feeders,  and  dose  water 
being  treated. 

QUESTIONS 

Write  your  answe/s  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  59. 

10,9A  Why  should  fluoridation  equipment  be  cleaned  out 
if  the  equipment  is  going  to  be  shut  down  for  an 
extended  length  of  time? 

13.1  OA  How  can  fluoride  dust  be  removed  from  gears? 

^3.^  jB  How  would  you  determine  if  your  fluoridation  equip- 
ment was  providing  the  desired  dosage? 

13.11  A  What  are  the  symptoms  of  acute  fluoride  poison- 

ing? 

13.12  CALCULATING  FLUORIDE  DOSAGES 

FORMULAS 

1 .  Charts  can  be  used  to  determine  feed  rates.  The  feed  rate 
is  usually  based  on  a  dose  of  one  mg/L;  therefore  actual 
feed  rates  must  be  adjusted. 

Actual  Feed  Rate,  6PD  =  (Chart  Feed  Rate.  GPD)(Actuai  Dose.  mg/L) 

1  mg/L 

2.  Feed  rates  may  be  calculated  on  the  basis  of  pounds  per 
day  or  gallons  per  aay.  Consideration  must  be  given  to 
the  pounds  of  fluoride  ion  per  pound  of  commercial 
chemical 


or 


or 


Feed  Rate.  ^(Flow,  MGD)(Dose.  mg/L)(8.34  lbs/gal)(1QQ%) 
Solution.  %  F 
Feed  Rate,  lbs  F/day 


lbs/day 
Feed  Rate, 


lbs/day  ^i^^  Commercial  Chemical 
Feed  Rate.  _     Feed  Rate,  lbs/day 


gal/day 


Chemical  Solution,  lbs/gat 


3.  If  the  water  being  treated  contains  some  fluoride  ion,  but 
not  sufficient,  then  a  feed  dose  must  be  calculated. 

Feed  Dose,  mg/L  -  Desired  Dose.  mg/L  -  Actual  Concentration.  mg/L 

4.  Commercial  chemicals  usually  are  not  100  percent  pure. 
Also,  the  chemical  only  contains  a  portion  of  the  ion  of 
concern  (fluoride  ion  in  this  chapter). 


Portion  F  =  (Commercial  Purity,  %)(Fluoride  Ion,  %) 
(100%)(100%) 

The  portion  F  is  the  pounds  of  F  per  pound  of  commercial 
chemical.  For  exa'*7)le,  0.6  pounds  F  per  one  pound  of 
commercial  sodluni  silicofluoride. 

5.  To  calculate  the  fluoride  dosage  or  any  chemical  dosage, 
you  need  to  know  the  pounds  of  chemical  and  volume  of 
water  in  million  gallons. 


Dosage,  mg/L 


Chemical,  lbs 


(Water,  M  GalK8.34  lbs/gal) 
^   lbs  Chemical 

Million  lbs  Water 
If  we  substitute  milligrams  for  pounds,  we  get 
^   mg  Chemical 

Million  mg  Water 

One  million  milligrams  of  water  occupy  a  volume  of  one 
liter. 

^  mg  Chemical 


Liter  of  Water 


=  mg/L 

6.  To  determine  the  amount  of  feed  solution  in  either  gallons 
or  gallons  per  day  to  treat  a  water,  you  need  to  know  the 
amount  of  water  to  be  treated  in  gallons  or  gallons  per 
day,  the  feed  dose  in  milligrams  per  liter  and  the  feed 
solution  in  milligrams  per  liter. 

Feed  Solution,  ^  (Flow,  gal)(Feed  Dose,  mg/L) 


gal 


Feed  Solution,  mg/L 


NOTE:  If  the  Teed  Solution"  is  in  gallons  per  day 
instead  of  gallons,  then  the  Tlow"  must  be  in 
gallons  per  day  also  instead  of  gallons. 

7.  When  mixing  the  same  two  acids  or  chemicals,  but  of 
different  strengths,  the  volumes  or  flows  of  the  chemicals 
and  their  strengths  must  be  known. 


Mixture      ^  (Volume  l.  gaiKStrength  1.%)+{Vofume  2,  gafXStrength  2.%) 

Strength.   '  

%  Volume  1.  gal  +  Volume  2.  ga! 


NOTE:  The  "Volumes"  may  be  in  gallons  or  treated  as 
flows  in  GPD  or  MGD.  The  "Strengths"  may  be  in 
percentages  or  concentrations  such  as  mg/L. 

8.  When  using  chemicals  for  fluoridation,  we  need  to  know 
the  percentage  fluoride  lon  purity.  This  information  will 
allow  us  to  convert  the  pounds  of  chemical  dosage  to 
pounds  of  fluoride  ion  available. 

Fluoride  lon  ^  (Molecular  Weight  of  Fluoride)(100%) 
Purity,  %        Molecular  Weight  of  Chemical 
EXAMPLE  1 

A  flow  of  4  MGD  is  to  be  treated  with  a  20  percent  solution 
of  hydrofluosilicic  acid  (HgSiFg).  The  water  to  be  treated 
contains  no  fluoride  and  thp  desired  fluride  concentration  is 
1.8  mg/L.  What  should  be  the  feed  rate  of  hydrofluosilicic 
acid?  Use  the  treatment  charts. 

Known  Unknown 
Flow,  MGD        =  4  MGD     1.  Feed  Rate,  gal/day 
Acid  Solution.  %  =  20%        2.  Feed  Rate,  gal/hr 
Desired  F,  mg/L  =  1.0  mg/L 


Ftuoridation  55 


1 .  Use  treatment  Chart  I  on  pa^e  46  because  we  are  treating 
a  relatively  small  flow  (4  MGD). 

2.  Start  on  the  left  side  at  the  4  MGD  value  and  move 
horizontally  to  the  right  to  the  20  percent  diagonal  line. 

3.  At  this  point  drop  vertically  downward  to  the  bottom  lines 
and  read  the  feed  rates  for  onf*  mg/L  (ppm). 

a.  Feed  Rate,  gallons  per  day  =  19  gal/day 

b.  Feed  Rate,  gallons  per  hour  =  0.8  gal/hr 

4  Calculate  the  feed  rate  to  produce  the  desired  fluoride 
concentration  of  1 .8  mg/L. 

?  Feec*  ''ate.  GPD  =(Peed  Rate.  GPD)(Desired  F.  mg/L) 

1  mg/L 
^(19GPDK1.8  mg/L) 


b.  Feed  Rate, 
gal/hr 


1  mg/L 
=  34.2  gallons/day 

^  (Feed  Rate,  gal/hr)(Desired  F,  mg/L) 
1  mg/L 

^  (0.8  gal/JirH1  8  mg/L) 

TrngTZ 
=  1.44  gal/hr 


EXAMPLE  2 

A  flow  of  4  MGD  is  to  be  .reated  with  a  20  percent  solution 
of  hydrofluosilicic  acid  (HgSiFg).  The  water  to  be  treated 
contaii.o  no  fluonde  and  the  desired  fluoride  concentration  is 
1.8  mg/L.  Assume  the  hydrofluosilicic  acid  weighs  9.8 
pounds  per  gallon.  What  should  be  the  feed  rate  of  hydro- 
fluosilicic acid?  Calculate  the  feed  rate. 

Known  Unknown 
Flow.  MGD       =  4  MGD         1.  Feed  Rate,  gal/day 
Acid  Solution,  %  =  20%  2.  Feed  Rate,  gal/hr 

Acid.  ..ri/gal      =  9.8  lbs/gal 
Desired  F,  mg/L  =  1 .8  mg/L 

1.  Calculate  the  hydrofluc-  ictc  acid  feed  rate  in  pounds  per 
day. 

Feed  Rate.  ^  (Flow.  MGDKDesired  F.  mg/L){8.34  ibs/gai)(100%) 
'^'/^^y   '  Add  Solution.  % 

^  (4  MGDK1  8  nrg/LKS  34  ibs/aai){1 00%) 
20">o 

=  300  lbs  acid/day 

2.  Determine  the  feed  rate  of  the  acid  in  gallons  per  day. 
Feed  Rate.  ^Feed  Rate,  'bs/day 

9a'/day  9.8  Ibs/gai 

^  c^OO  lbs  ac'i/day 


0.8  lbs  v.cid/gal  acid 
=  31  gal  acid/day 

NOTE:  We  obtained  a  f^ed  rate  of  34  gallons  of  acid  per 
day  from  Treatment  Chart  I.  The  differences 
result  from  the  problems  of  drawing  and  reading 
the  chart  accurately. 
3.  Calculate  the  feed  rate  in  gallons  of  acid  per  hour. 

Feed  Rate,  gal/hr  =.Feed  Rr.e,  g;^l/day 
24  hr/day 

^31  gal  acid/day 


24  hr/day 
=  1.3  c,. :  acid/hr 


EXAMPLE  3 

A  flow  of  20^"  .PM  IS  to  be  ireated  with  a  2.4  percent  (0.2 
lbs/gallon)  solution  of  scdium  fluonde  (NaF).  The  water  to  be 
treated  contains  0.7  mg/L  of  fluonde  ion  and  the  desired 
fluoride  ion  concentration  is  1.6  mg/L.  What  should  be  the 
feed  rate  of  sodium  fluoride'^  Use  the  treatment  charts. 


Known 

Flow.  MGD        =  200  MGD 
NaF  Solution.  %  =  2  4% 
Desired  F.  mg/L  =  1  6  mg/L 
Actual  F,  mg/L  =  0.7  mg/L 


Unknown 

1.  Feed  Rate,  gal/day 

2.  Feed  Rate,  gal/hr 


ERIC 


1.  Use  treatment  Chart  III  on  page  47  because  we  are 
treating  200  GPM. 

2.  Start  at  the  left  side  at  the  200  GPM  value  and  move 
horizontally  to  the  right  to  the  2.4  percent  diagonal  line. 

3.  At  this  point  drop  vertically  downward  to  the  bottom  lines 
and  read  the  feed  rates  for  one  mg/L  (ppm). 

a.  Feed  Rate,  gallons  per  day  =  26.5  gal/day 

b.  Feed  Rate,  gallons  per  hour  =  1.1  gal/hr 

4.  Calculate  the  feed  rate  to  produce  the  desired  fluoride 
concentration  of  1.6  mg/L. 

Feed  Dose,  mg/L  =  Desired  Dose.  mg/L  -  Actual  Cone .  mg/L 
=  1.6  mg/L  -  0  7  mg/L 
=  0.9  mg/L 

Feed  Rate.  GPD  =(Feed  Rate.  GPD;(Feed  Dose.  mg/L) 

1  mg/L 
^  (26.5  gal/day)(Q  9  mg/L) 

1  mg/L 
=  23.8  GPD 

Feed  Rate.         ^(Feed  Rate.  gal/hr)(Feed  Dose.  mg/L) 

gal/hr  

^  '  1  mg/L 

^(1.1  gal/hr)(0.9  mg/L) 

1  mg/L 

=  0.99  gal/hr  or  1  gal/hr 


EXAMPLE  4 

A  flow  of  200  GPM  is  to  be  treated  with  a  2.4  percent  (0.2 
pounds  per  gallon)  solution  of  sodium  fluoride  (NaF).  The 
water  to  be  treated  contains  0.7  mg/L  of  fluoride  ion  and  the 
desired  fluoride  ion  concentration  is  1.6  mg/L.  What  should 
be  the  feed  rate  of  sodium  fluonde?  Calculate  the  feed  rate. 
Assume  the  sodium  fluoride  has  a  fluoride  purity  of  43.4 
percent. 

Known  Unknown 

Flow.  MGD  =  200  MGD    1.  Feed  Rate,  gal/day 

NaF  Solution,  %       =  2.4%         2.  Feed  Rate,  gal/hr 
NaF  Solution,  ibs/gal  =  0.2  lbs/gal 
Desired  F.  mg/L       =  1.6  mg/i 
Actual  F,  mg/L        =  0.7  mg/L 
Purity.  %  =  43.4% 

68 


56   Water  Treatment 


1  Convert  flow  from  gallons  per  minute  to  million  gallons 
per  day. 

Flow.  MGD  =  ('"'ow.  gaj/min)(.0  min/hr)(24  hr/day)(1  Million) 

1,000.000 

^  (200  gal/min)(60  min/hr)(24  hr/day)(1  Million) 
1,000.000 

=  0.288  MGD 

2  Determine  the  fluoride  feed  dose  in  milligrams  per  liter. 
Feed  Dose,  mg/l  =  Cesired  Dose.  mg/L  -  Actual  Cone  ,  mg/l 

=  1 .6  mg/l  -  0  7  mg/l 
=  0.9  mg/l 

3.  Calculate  the  feed  rate  in  pounds  of  fluoride  ion  per  day 

lbs  F/day  "         MGD)(Feed  Dose,  mg/l)(8.34  lbs/gal) 

=  (0  2B8  MGD)(0  9  mg/l)(8  34  lbs/gal) 
=  2.16  lbs  F/day 

4.  Convert  the  feed  rate  from  pounds  of  fluoride  per  day  to 
gallons  of  sodium  fluoride  solution  per  day. 

Feed  Rate,  ^  (Feed  Rate,  lbs  F/day)(100%) 

gal/day     ^jg^p  solution,  lbs  F/gallon)(Purity,  %) 
^(2.16  ibsF/dav)(100%) 
(0.2  lbs  F/gal)(43.4%) 
=  24.9  gal/day 

NOTE:  We  obtained  a  feed  rate  of  23.8  gil/day  using 
the  treatment  chart.  The  differences  could  have 
resulted  from  accurately  preparing  and  reading 
the  Chart  as  well  as  the  assumed  purity  of 
fluoride  ion  in  the  ,odium  fluoride. 

5.  Convert  the  feed  rate  fror  ya.  ^     per  d^y  to  gallons  per 
hour. 

Feed  Rate.  ^(Feed  Rate,  gcl/day) 
9^'/^^  24  hr/day 

^  (24.9  gal/day) 

24  gal/hr 
=  1.0  gal/hr 


EXAMP'.E  5 

A  flow  of  1  MGD  is  treated  with  sodium  silicofluoride 
(NagSiFg)  to  provide  a  fluoride  ion  dose  of  1.4  mg/L.  What  i? 
the  feed  rate  in  pounds  per  day?  Commercial  sodium 
silicofluoride  has  a  purity  of  98.5  percent  and  the  fluoride  ion 
purity  as  sodium  silicofluoride  is  60.7  percent. 

Known  Unknown 

Flow,  MGD  =  1  MGD      1.  Feed  Rate,  lbs/day 

Dose,  mg/L  =  1.4  mg/L 

NagSiFg  Purity,  %  =  98.57o 
Fluoride  Ion  Purity,  %  =  60.7% 


1.  Calculate  the  portion  of  fluoride  ion  in  the  commercial 
sodium  Silicofluoride. 

Portion  F    (Na^SiFe  Punty,  %)(Fluonde  Ion  Punty,  %) 
(100%)(100%) 
^  (98.5%)(60.7%) 
(100%)(100%) 
=  0.598 

This  says  that  there  are  0.598  pounds  of  fluoride  ion  in  a 
pound  of  commercial  sodium  silicofluoride. 

2.  Calculate  the  pounds  of  fluoride  required  per  day. 

'"'ibsJSay"         MGDKDose,  mg//.)(8.34  lbs/gal) 
=  (1  MGD)(1.4  mg/L)(8.34  lbs/gal) 
=  11.7  lbs  F/day 

3.  Determine  the  chemical  feed  rate  for  the  commercial 
sodium  silicofluoride  in  pounds  per  day. 

Feed  Rate,  ^  Fluoride,  lbs/day  

lbs/day      Fluoride,  lbs/lb  Commercial  NagSiFg 

=  1 1 .7  lbs  F/day  

0.598  lbs  F/lb  Commercial  NagSiF^ 
=  19.5  lbs/day  Commercial  Na^SiF- 


EXAMPLE  6 

A  flow  of  1.4  MGD  is  treated  with  sodium  silicofluoride. 
The  raw  water  contains  0.4  mg/L  of  fluoride  ion  and  the 
desired  fluoride  ion  concentration  is  1 .6  mg/L.  What  should 
be  the  chemical  feed  rate  in  pounds  per  day?  Assume  each 
pound  of  commercial  sodium  silicofluoride  (NagSiFg)  con- 
tains 0.6  pounds  of  fluoride  ion. 

Known  Unknown 

Flow,  MGD  =1.4  MGD      Feed  Rate,  lbs/day 

Raw  Water  F,  mg/L  =  0.4  mg/L 
Desired  F,  mg/L  =  1.6  mg/L 
Chemical,  lbs  F/lb   =  0.6  lbs  F/lb 

1.  Determine  the  fluoride  feed  dose  in  milligrams  per  liter. 
Feed  Dose,  mg/L  =  Desired  Dose,  mg/L  -  Actual  Cone,  mg/L 

=  1  6  mg/L  -  0.4  mg/L 
=  1.2  mg/L 

2.  Calculate  fhe  fluoride  feed  rate  in  pounds  per  day. 
Feed  Rdtp 

lbs  F/day  "         MGD)(Feed  Dose.  mg/L)(8.34  lbs/gal) 
=  (1.4  MGD)(1.2  mg/L)(8.34  lbs/gal) 
=  14.0  lbs  F/day 

3.  Determine  the  chemical  feed  rate  in  pounds  of  commer- 
cial sodium  silicofluoride  per  day. 

Feed  Rate,  Feed  Rate,  lbs  F/day 

lbs/day  ^^y^  Commercial  Na^SiFg 


14.0  lbs  F/day 


EMC 


0.6  lbs  F/lb  Commercial  NajSiFg 
=  23.4  lbs/day  Commercial  NagSIFg 


69 


Fluoridation  57 


EXAMPLE  7 

The  totalizer  for  a  water  treatment  plant  indicated  that  a 
total  of  100,000  gallons  of  water  had  been  feated  with  three 
pounds  of  98  percent  pure  sodium  fluoride  (NaF).  The 
fluoride  ion  punty  for  sodium  fluoride  is  45.3  percent.  What 
was  I  'a  added  fluoride  ion  dosage  in  milligrams  per  hter'^ 

Known  Unknown 
Water  Treated,  MG  =  0  1  M  Gal      Fluoride  Dosage,  mg/L 


NaF,  lbs 
NaF  Purity,  % 
F  Ion  Punty,  % 


=  3  lbs 
=  98% 
=  45.3% 


1  Calculate  the  portion  of  fluoride  ion  in  the  commercial 
sodium  fluoride. 

Portion  F  =(N3F  Purity,  %)(Fluoride  !on  Purity,  %) 
(100%)(100%) 
^  (98%)(45.3%) 
(100%)(100%) 
=  0.444 

or     =  0.444  lbs  F/lb  commercial  NaF 

2.  Calculate  the  pounds  of  fluoride  used. 

^'"bs      -  (Commercial  NaF,  lbs)(0  444  lbs  F/lb  Comm.  NaF) 
^  (3  lbs  Comm.  NaF)(0.444  lbs  F/lb  Comm.  NaF) 
=  1.33  lbs  F 

3.  Calculate  the  fluoride  dosage  in  milligrams  per  liter 
Fluoride    ^  Fluoride,  lbs  F 

Dosage,    (vvater  Treated,  M  Gal)(8.34  lbs/gal) 
1.33  lbs  F 
(0.1  M  Gal)(8.34  lbs/gal) 
1.33  lbs  F 


(0.834  Million  lbs  Water) 
_     1.6  lbs  F 


1  M  lbs  Water 
1.6  mg/L 


EXAMPLE  8 


Determine  the  percentage  of  fluoride  ion  in  the  feed 
solution  from  a  saturator.  The  saturator  contains  95  percent 
pure  sodium  fluoride,  the  maximum  water  solubility  for 
sodium  fluoride  is  four  percent,  and  sodium  fluoride  is  45  3 
percent  fluoride  ion. 

Known  Unknown 
Commercial  NaF  Purity,  %  =  95**':  Solution,  %  F 

NaF  Solubility,  %  =  4% 

F  Ion  Purity,  %  =45.3% 

Calculate  the  percentage  of  fluoride  ion  in  the  feed  solution. 

Solution  %  F  =  (NaF  Solubility,  %)  (F  Ion  Punty,  %) 


(100%) 


(4%)  (45.3%) 


(100%) 

=  1.8% 

NOTE:  In  a  saturator,  the  commercial  NaF  purity  of  95 
percent  does  not  enter  into  the  calculations 
because  the  four  percent  solubility  Is  ail  NaF. 


EXAMPLE  9 

The  feed  solution  from  a  saturator  containing  1.8  percent 
fluoride  ion  is  used  to  treat  a  total  flow  of  400,000  gallons  of 
water.  The  raw  water  has  a  fluonde  ion  content  of  0  5  mg/L 
and  the  desired  fluoride  in  the  finished  water  is  1.8  mg/L. 
How  many  gallons  of  feed  solution  are  needed'^ 

Known  Unknown 
Flow  Vol.,  gal        =  400,000  gal    Feed  Solution,  gallons 
Raw  Water  F,  mg/L=  0.5  mg/L 
Desired  F,  mg/L     =  1.8  mg/L 
Feed  Solution,  %  F  =  1.8%  F 

1  Convert  the  feed  solution  from  a  percentage  fluoride  lon 
to  milligrams  fluonde  ion  per  liter  of  water. 

1.0%  F  =  10,000  mg  F/L 

Feed  Solution,  mg/L  ^(Feed  Solution.  %)(1 0,000  mg/L) 

1% 

^  (1  8%)(1 0,000  mg/L) 
1% 

-  18,000  mg/L 

2  Determine  the  fluoride  feed  dose  in  milligrams  per  liter. 
Feed  Dose.  mg/L  =  Desired  Dose,  mg/L  -  Raw  Water  F,  mg/L 

=  1  8  mg/L  -  0.5  mg/L 
=  1  3  mg/L 

3.  Calc  :iate  the  gallons  of  feed  solution  needed. 

Feed  Solution,  gal  =f!^  Vol,  Gal)(Feed  Dose.  mg/L) 

Keed  Solution,  mg/L 

^(400,000  gal)(1.3  mg/L) 

18,000  mg/L 
=  28.9  gallons 

EXAMPLE  10 

A  hydrofluosihcic  acid  (HgSiF^)  tank  contains  300  gallons 
of  acid  with  a  strength  of  18  percent.  A  comm>3rcial  vendor 
delivers  2000  gallons  of  acid  with  a  strength  of  20  percent  to 
the  tank  What  is  the  resulting  strength  of  the  mixture  as  a 
percentage'? 


Unknown 
Mixture  Strength,  % 


Known 

Tank  Contents,  gal  -  300  gal 
Tank  Strength,  %    =  18% 
Vendor,  gal  =  2000  gal 

Vendor  Strength,  %  =  20% 

Calculate  the  strength  of  the  mixture  as  a  percentage. 
Mixture         ^  (Tank,  gal)(Tank,  %)  +  (Vendor,  gal)(Vendor.  %) 
^^''^"9th,%  Tank,  gal  -f  Vendor,  gal 

^  (300  garni 8%\  +  (2000  gal)(2Q%) 

300  gal  ^  2000  gal 
^  6400  4-  40.000 
2300 


^  45,400 
2.300 
=  19.7% 


•70 


58  Water  Treatment 


EXAMPLE  11 

Sodium  silicofluoride  (Na2SiFg)  is  used  as  the  chemicai  to 
fluoridate  a  water  supoly.  What  is  the  fluoride  ion  purtty  as  a 
percentage? 


Known 

Atomic  Weights 


Na 

Si 

F 


22  99 
=  28.09 
=  19.00 


Unknown 
Fluoride  ion  Purity,  % 


1  Determine  the  molecular  weight  of  the  fluoridation  chemi- 


cal, sodium  Silicofluoride.  NajSiF^. 

Symbol   No.  Atoms  x  Atomic  Wt.* 

Nag  2        X      22  99 

Si  1        <  28.09 

Fe  6        X  19.00 

Molecular  Wt  of  Chemical 


Molecular  Wt. 

45.98 
28  09 
114U0 


188  07 


•  Atomic  weight  values  can  be  obtained  from  a  chemistry 
book. 


2  Calculate  the  fluoride  ion  punty  as  a  percentage. 
Fluoride  Ion  ^(Molecular  Weight  of  Fluoride)(lOO%) 
Purity,  %         Molecular  Weight  of  Chemical 
^(114  00)(100%) 

188.07 
=  60.62% 

This  means  that  there  are  0.6062  pounds  of  fluoride  ion  tn 
every  pound  of  sodium  silicofluonde. 

13.13  ARITHMETIC  ASSIGNMENT 

T  jrn  to  the  Anthmetic  Appendix  at  the  back  of  this  manual. 
In  Section  A.3.  "Typical  Water  Treatment  Plant  Problems." 
read  and  work  the  problems  in  Section  A.31.  "Fluoridation." 

13.14  ADDITIONAL  READING 

1.  NEW  YORK  MANUAL,  Chapter  16.  "Fluoridation." 

2  TEXAS  MANUAL  Chapter  1 1 .  "Special  Water  Treatment 
(Fluoridation)." 

3  WATER  FLUORIDATION  PRINCIPLES  AND  PRACTICES 
(M4).  Available  from  Data  Processing  Department,  Ameri- 
can Water  Works  Association,  6666  W.  Quincy  Avenue, 
Denver,  Colorado  80235.  Price  for  members,  $13.50; 
Non-members,  $17.00.  Order  No.  30004. 

4  WATER  FLUORIDATION  A  Training  Course  Manual  for 
Engineers  a.id  Technicians.  Available  from  Dental  Dis- 
ease Prevention  Activity.  Center  lOr  Prevention  Services. 
Centers  for  Disease  Control.  U.  S.  Public  Health  Service. 
Atlanta.  Georgia  30300. 

13.15  ACKNOWLEDGMENTS 

The  author  wishes  to  acknowledge  the  assistance  gra- 
ciously given  by  Robert  A.  Hewitt,  Assi:,tant  Water  Quality 
Engineer,  San  Francisco  Water  Department,  San  Francisco. 
California,  and  Tom  Reeves.  Centers  for  Disease  Control. 
Center  for  Prevention  Services,  Dental  D'sease  Prevention 
Activity,  Atlanta,  Georgia. 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chaptens.  FLUORIDATION 


Please  work  these  discussion  and  review  questions  be- 
fore continuing  with  the  Objective  Test  on  page  60  The 
purpose  of  these  questions  is  to  indicate  to  you  how  well  yoj 
understand  the  matenal  in  the  chapter,  Wnte  the  answers  to 
these  questions  in  your  notebook. 

1.  Why  are  dnnking  waters  fluoridated'? 

2  What  factors  would  you  consider  when  selecting  a 
fluoridation  chemicaP 

3  Why  should  the  finished  water's  fluoride  lon  content  be 
automatically  monitored  on  a  continuous  basis'? 

4  How  can  water  be  softened  prior  to  use  with  fluoridation 
equipment? 


5  What  items  should  be  considered  when  reviewing  plans 
and  specifications  for  the  location  of  fluoride  chemical 
hoppers'? 

6  How  can  overfeeding  be  prevented'? 

7.  What  should  be  done  if  significant  overfeeding  occurs"? 

8  What  should  be  done  when  fluoridation  equipment  is 
going  to  be  shut  down  for  an  extended  length  of  time? 

9  How  would  you  dispose  of  fluonde  chemical  contain- 
ers'? 

10  How  would  you  protect  yourself  from  the  dusts  of  dry 
f'uoride  compounds'? 


Fluoridation  59 


SUGGESTED  ANSWERS 

Chapter  13.  FLUORIDATION 


Answers  to  questions  on  page  29. 

13.0A  If  a  person  dnnks  water  with  an  excessive  amc  jnt  of 
fluoride,  the  teeth  become  mottled  (brown,  chalky 
deposits). 

13.0B  Children  who  drink  a  recommended  dose  of  fluoride 
have  fewer  dental  caries  (decay  or  cavities). 

Answers  to  questions  on  page  30. 

13  1 A  The  water  department  or  water  company  makes  the 
final  decisions  as  to  types  of  fluoride  chemicals  and 
feeding  equipment  to  be  used. 

13.2A  The  three  compounds  most  common'y  used  to  fluori- 
date water  are  hydrofluosillcic  acid,  sodium  fluoride 
and  sodium  silicofluoride. 

Answers  to  questions  on  page  42. 

13.3A  Dnnking  waters  may  contain  fluoride  ions  by  three 
different  types  of  situations: 

1.  Raw  water  source  may  have  adequate  or  exces- 
sive fluoride  ions  naturally  present, 

2.  Two  water  sources  may  be  blended  together  (one 
higher  and  one  lower  than  acceptable  level)  to 
produce  an  acceptable  level,  and 

3.  Fluoride  ions  must  be  added  to  the  water  to 
achieve  an  acceptable  level 

13.3B  Fluoridation  systems  must  incorporate  means  to 
prevent  both  overfeeding  and  backsiphonage  along 
with  means  to  monitor  the  amount  of  chemical  used. 

13.3C  Hard  water  can  produce  problems  in  systems  using 
saturators  and  dissolving  tanks  through  the  forma- 
tion of  low  solubility  (deposits  of)  calcium  and  mag- 
nesium fluoride  compounds. 

13.3D  A  saturator  is  a  device  which  produces  a  *;uoride 
solution  for  the  fluoridation  process.  The  device  is 
usually  a  cylindrical  container  with  granular  sodium 
fluoride  on  the  bottom.  Water  flows  either  upward  or 
downward  through  the  sodium  fluoride  to  produce 
the  fluoride  solution. 

Answers  to  questions  on  page  44. 

13.4A  Overfeeding  of  fluoridation  chemicals  must  be  pre- 
vented to  avoid  illness  and  bad  public  relations. 

13.4B  The  fluoridator  should  be  sized  to  handle  the  full 
range  of  both  present  and  future  doses  or  provisions 
should  Is  made  for  future  expansion. 

13.5A  When  Inspecting  the  fluoridation  electrical  system, 
inspect  th  e  system  for  (1 )  proper  voltage;  (2)  properly 
sized  overload  protection;  (3)  proper  operation  of 
control  lights  on  control  panel;  (4)  proper  safety  lock- 
out switches  and  operation;  and  (5)  proper  equip- 
ment rotation. 

13.58  Safety  equipment  that  should  be  available  near  a 
fluoridation  system  include  an  eyewash,  drench 


showers,  dust  masks,  face  shields,  gloves  and  vent 
fans. 

Answers  to  questions  on  page  48 

13.6A  Known  Unknown 

Flow.  MGD  =  6  MGD  Feed  Rate,  gal/day 

Cone  Fluoride,  mgfL  =  1.2  mg/L 
Hydrofluosillcic  acid  =  20% 

1.  Use  Treatment  Chart  I,  Hydrofluosilicic  Acid.  Start 
at  the  left  side  with  6  MGD  and  move  horizontally 
to  the  right  to  the  intersection  of  the  20%  diagonal 
line. 

2.  Drop  down  vertically  to  the  chemical  feed  rate  of 
30  GALLONS  PER  DAY,  for  1  mg/L  fluoride  appli- 
cation. 

3.  Adjust  the  flow  rate  for  a  dose  of  1.2  mg/L. 

Flow  Rate.    ^  (Ftow  Rate  from  Cnart.  gal/dayKDestred  Dose,  mg/i.) 

^(30  gal/dayKI  2  mg/L) 

1  mgIL 
^  36  ga./day 

13.6B  Differences  between  the  volume  of  acid  used  from  a 
storage  tank  and  the  volume  actually  fed  into  the 
system  could  be  caused  by  errors  in  readings,  leaks 
or  equipment  malfunctions. 

Answers  to  questions  on  page  52. 

137A  Overfeeding  shculd  be  prevented  because  no  addi- 
tional benefits  result  from  overfeeding  and  there  is  a 
waste  of  chemicals  and  money.  Lxcessive  overfeed- 
ing could  be  harmful  to  consumers. 

13.7B  If  significant  overfeeding  occurs,  the  plant  should  be 
shut  down.  The  affected  mains  should  be  flushed 
and  the  local  and  state  health  departments  notified. 

13.8A  A  fluoridation  operation  could  be  shut  down  for 
cleaning,  adjustments  or  due  to  safety  controls. 

Answers  to  questions  on  page  54. 

13.9A  If  fluoridation  equipment  is  going  to  be  shut  down 
for  an  extended  length  of  tine,  it  should  be  cleaned 
out  to  prevent  corrosion  and/or  the  solidifying  of 
the  chemical.  Lines  and  equipment  could  be  da- 
maged when  started  if  chemicals  left  in  them  solidi- 
fy. 

13.1  OA  Fluoride  dust  can  be  removed  from  gears  by  the 
use  of  a  vacuum  cleaner. 

13.1  OB  To  determine  if  the  fluoridation  equipment  is  provid- 
ing the  desired  dosage,  monitor  the  fluoride  ion 
concentration  in  the  treated  water. 

13.11  A  If  you  are  acutely  poisoned  by  a  fluoride  chemical, 
you  may  be  thirsty,  vomit  and  have  stomach 
cramps,  disrrhea,  difficulty  in  speaking  and  dis- 
turbed color  vision. 


ERLC 


72 


60  Water  Treatment 


OBJECTIVE  TEST 

Chapter  13.  FLUORIDATION 


Please  write  your  name  and  mark  the  correct  answers  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1 .  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
questions. 

True-False 

1 .  Governing  bodies  usually  rely  upon  a  vote  of  the  people 
to  decide  the  types  of  fluoride  chemicals  and  feeding 
equipment  to  be  used. 

1.  True 

2.  False 

2.  Water  should  be  analyzed  for  its  natural  fluonde  level 
before  fluondation. 

•  True 
2  False 

3.  Fluoridation  cnemicals  are  harmful  to  consumers  at  high 
levels. 

1.  True 

2.  False 

4.  Scale  formation  in  chemical  feed  systems  may  be 
prevented  by  ti.e  use  of  polyphosphates  instead  of  a 
zeolite  softener 

1.  True 

2.  False 

5.  A  day  tank  usually  stores  sufficient  chemical  solution  to 
treat  water  for  at  least  one  day. 

1.  True 

2.  False 

6.  Chemical  feed  systems  should  allow  the  chemical  feed 
to  vary  with  changing  head  cond:'  ons. 

1.  True 

2.  False 

7.  Equipment  may  be  damaged  in  minutes  if  it  is  run 
without  lubrication. 

1.  True 

2.  False 

8.  A  positive  displacement  pump  will  damage  itself  or 
rupture  lines  in  seconds  if  allowed  to  run  against  a 
clos'^d  valve  or  system. 

1.  True 

2.  False 

9.  Fluoridation  must  be  a  continuous  operation. 

1.  True 

2.  False 

10.  Operators  could  be  seriously  injured  if  they  open  a 
chemical  line  that  has  not  been  properly  flushed  out. 

1.  True 

2.  False  >^  ^ 


11.  Hydrofluosilicic  acid  solutions  can  irntate  your  skin. 

1.  True 

2.  False 

12  Never  eat,  drink  or  smoke  in  or  around  fluoridation 
chemical  storage  o*  feed  areas. 

1.  True 

2.  False 

13.  Sanitary  defects  may  develop  in  fluoridation  systems. 

1.  True 

2.  False 

14.  Hydrofluosilicic  acid  must  be  washed  off  your  skin 
immediately. 

1.  True 

2.  False 

15.  Special  safety  training  must  be  given  to  ail  operators 
who  must  handle  fluoride  compounds. 

1.  True 

2.  False 

Multiple  Choice 

16.  The  Maximum  Contaminant  Level  (MCL)  for  fluoride  in 

dnnking  water  ranges  from  mg/L,  defjending 

on  the  annual  average .     imum  daily  air  temperatures. 

1.  0.4  to  0.8 

2.  0.9  to  1.3 

3.  1.4  to  2.4 

4.  2.5  to  3.5 

5.  3.6  to  5.0 

17.  The  compounds  most  commonly  used  to  fluoridate 
water  include 

1.  Ammonium  silicofluonde. 

2.  Calcium  fluoride. 

3.  Hydrofluosilicic. 

4.  Silicofluonde. 

5.  Sodium  fluoride. 

18.  Which  o'  the  following  items  must  be  considered  when 
selecting  a  fluoridation  chemical? 

1.  Costs 

2.  Ease  of  handling 

3.  Operator  safety 

4.  Solubility  of  chemical  in  water 

5.  Storage  requirements 


19.  Water  with  a  hardness  above 


mg/L  must  be 


ERIC 


softened  to  prevent  severe  scaling  of  fluoridation  equip- 
ment. 

1.  10 

2.  25 

3.  40 

4.  55 

5.  75 


Fluoridation  61 


20.  Fluoridation  chemicals  that  may  be  fed  with  a  saturator 
include 

1.  Granular  calcium  fluoride. 

2.  Granular  sodium  fluoride. 

3.  Hydrofluosilicic  acid. 

4.  Powdered  calcium  fluoride. 

5.  Powdered  sodium  fluoride. 

21-  The  responsibility  of  the  chief  ope-ator  regarding  fluori- 
dation equipment  includes 

1.  Design. 

2.  Functioning  of  equipment. 

3.  Maintenance. 

4.  Operation  by  plant  personnel 

5.  Results  from  the  process. 

22.  Fluoridation  operations  may  be  temporarily  shut  down 
due  to 

1.  Adjustments. 

2.  Calculating  dosages. 

3.  Cleaning. 

4.  Maintaining  storage  area 

5.  Safety  controls. 

23  Which  of  the  following  items  should  be  Included  in  your 
checklist  for  shutting  down  a  fluoridation  chemical  sys- 
tem? 

1.  Clean  the  mix  and  feed  tanks. 

2.  Drain  the  mix  and  feed  tanks. 

3.  Fill  the  chemical  hoppers. 

4.  Flush  out  all  the  solution  lines. 

5.  Turn  on  the  electncal  power 

24.  A  flow  of  2  MGD  is  to  be  treated  with  an  18  percent 
solution  of  hydrofluosilicic  acid  HjSiFg).  The  water  to  be 
treated  contains  no  fluoride  and  the  desired  fluoride 
concentration  is  1 ,2  mg/L.  Assume  the  hydrofluosilicic 
acid  weighs  9  6  pounds  per  gallon.  Calculate  the  hydro- 
fluosilicic acid  feed  rate  in  gallons  per  day.  Sele.t  the 
closest  answer. 

1.  12  GPD 

2.  15  GPD 


3.  30  GPD 

4.  110  GPD 

5.  300  GPD 

25  A  flow  of  250  GPM  is  to  be  treated  with  a  2.4  percent 
(0.2  pounds  per  r^allon)  solution  of  sodium  fluoride 
(NaF).  The  water  to  be  treated  contains  0.3  mg/L  of 
fluoride  ion  and  the  desired  fluoride  ion  concentration  is 
1.4  mg/L.  Calculate  the  sodium  fluoride  feed  rate  in 
gallons  per  day.  Assume  the  sodium  fluoride  has  a 
fluoride  purity  of  43.4  percent.  Select  the  closest  an- 
swer. 

1.  1.1  gal/day 

2.  2.2  gal/day 

3.  3.3  gal/day 

4.  25  gal/day 

5.  38  gal/day 

26.  A  flow  of  0.8  MGD  is  treated  with  sodium  silicofluoride 
(NagSiFg)  to  provide  a  fluoride  ion  dose  of  1.2  mg/L. 
What  Is  the  feed  rate  in  pounds  per  day?  Commercial 
sodium  fluoride  has  a  punty  of  98.5  percent  and  the 
fluoride  ion  purity  of  sodium  silicofluoride  is  60.7  per- 
cent. Select  the  closest  answer. 

1.  6.0  lbs/day 

2.  8.0  lbs/day 

3.  11.7  lbs/day 

4.  13.4  lbs/day 

5.  19.5  lbs/day 

27.  The  feed  solution  from  a  saturator  containing  1.8  per- 
cent fluoride  ion  is  used  to  treat  a  flow  of  500,000 
gallons  per  day.  The  desired  dose  is  1 2  mg/L  of  fluoride 
ion  and  the  raw  water  does  not  have  any  fluoride. 
Calculate  the  feed  rate  in  gallons  per  day  of  the  satura- 
tor solution.  Select  the  closest  answer. 

1.  18.0  gal/day 

2.  19.5  gal/day 

3.  26.6  gal/day 

4.  28.9  gal/day 

5.  33.3  gal/day 


ERIC 


74 


CHAPTER  14 

SOFTENING 

by 

Don  Gibson 
and 

Marty  Reynolds 


64  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  14.  Softening 

Page 

OBJECTIVES    gg 

GLOSSARY   Qj 

LIME-SODA  ASH  SOFTENING  bv  Don  Gibson 

Lesson  1 

14.0  What  Makes  Water  Hard?   70 

14.1  Why  Soften  Water'?   71 

14.2  Chemistry  of  Softening   72 

14.20  Hardness   72 

14.21  pH   73 

14.22  Alkalinity   73 

14.3  How  Water  Is  Softened   75 

14.30  Basic  Methods  of  Softening    75 

14.31  Chemical  Reactions   75 

14.310  Lime    7g 

14.31 1  Removal  of  Carbon  Dioxide   75 

14.312  Removal  of  Carbonate  Hardness   76 

14.313  Removal  of  Noncarbonate  Hardness   76 

14.314  Stability   7g 

14.315  Caustic  Soda  Scftening   77 

14.316  Calculation  of  Chemical  Dosages   77 

14.32  Lime  Softening   73 

14.33  Split  Treatment   7g 

14.34  Lime-Soda  Ash  So'    ting    81 

14.35  Caustic  Soda  Softening   81 

14.36  Handling,  Application  and  Storage  of  Lime   82 

14.4  Interactions  with  Coag-  lants   82 

14.5  Stability   83 

14.6  Safety   84 

14.7  Sludge  Recirculation  and  Disposal   85 

14.8  Records   85 


EMC 


76 


Softening  65 


14.9  Jar  Tests   85 

14.90  Typical  Procedures   85 

14  91  Examples   86 

14.92  Calculation  of  Chemical  Feeder  Settings   86 

iON  EXCHANGE  SOFTENING  by  Mai  ^^ynolds 

Lesson  2 

14.10  Description  ot  Ion  Exchange  Softening  Process   91 

14.11  Operations   95 

14.110  Service   95 

14.111  Backwash   95 

14.112  Brine   97 

14.113  Rinse   97 

14.12  Control  Testing  of  Ion  Exchange  Softeners   97 

14.13  Limitations  Caused  by  Iron  and  Manganese   98 

14.14  Disposal  of  Spent  Brine   98 

14.15  Maintenance   99 

14.1C  Troubleshooting   100 

14.160  Test  Units   100 

14.161  Service  Stage   100 

14.162  Backwash  Stage   100 

14.163  Rinse  Stage   100 

14.164  Brine  Injection  Stage   100 

14.17  Startup  and  Shutdown  of  Unit   101 

14.18  Ion  Exchange  Arithmetic    101 

14.19  Blending    105 

14.20  Recordkeeping   106 

14.21  Arithmetic  Assignment   106 

14.22  Additional  Reading   106 

14.23  Acknowledgments    107 

Suggested  Ansvi/ers   107 

Objective  Test   Ill 


66  Water  Treatment 


OBJECTIVES 


Chapter  14.  SOFTENING 


Following  completion  of  Chapter  14,  you  should  be  able 


1.  Explain  what  makes  water  hard  and  the  advantages  of 
softening, 

2.  Describe  the  processes  used  to  soften  water, 

3.  Prepare  chemical  doses  to  soften  water  with  consider- 
ations given  to  coagulants  and  stability, 

4.  Safely  handle  softening  chemicals, 

5.  Dispose  of  process  sludges  and  brines, 

6.  Keep  neat  and  accurate  softening  records, 

7.  Perform  jar  tests  and  apply  results, 

8.  Operate  and  maintain  chemical  precipitation  and  ion 
exchange  softening  processes, 

9.  Start  up  anc  shut  down  water  softening  units,  and 

10.  Blend  softened  waters  with  unsoftened  waiters  (split 
treatment)  for  delivery  to  consumers. 


to: 


ERIC 


Softening  67 


GLOSSARY 

Chapter  14.  SOFTENING 


ALKALINITY  (AL-ka-LIN-it-tee)  ALKALINITY 

The  capacity  of  water  to  neutralize  acids.  This  capacity  is  caused  by  the  water's  content  of  carbonate,  bicarbonate,  hydroxide, 
and  occasionally  borate,  silicate,  and  phosphate.  Alkalinity  is  expressed  in  milligrams  per  liter  of  equivalent  calcium  carbonate 
Alkalinity  is  a  measure  of  how  much  acid  can  be  added  to  a  liquid  without  causing  a  great  change  in  pH. 

ANION  ,AN-EYE-on)  ANION 

A  negatively  charged  ion  in  an  electrolyte  solution,  attracted  to  the  anode  under  the  influence  of  a  difference  in  electrical  poten- 
tial. Chloride  (CI")  is  an  anion. 

CALCIUM  CARBONATE  EQUILIBRIUM  CALCIUM  CARBONATE  EQUILIBRIUM 

A  water  is  considered  stable  when  it  is  just  saturated  v/ith  calcium  carbonate.  In  this  condition  the  water  will  neither  dissolve  nor 
deposit  calcium  carbonate.  Thus,  in  this  water  the  calcium  carbonate  is  m  equilibrium  with  the  hydrogen  ion  concentration 

CALCIUM  CARBONATE  (CaCOj)  EQUIVALENT  CALCIUM  CARBONATE  (CaCOj)  tvJUIVALENT 

An  expression  of  the  concentration  of  specified  constituents  in  water  in  ter.,is  of  their  equivalent  value  ^o  calcium  carbonate. 
For  example,  the  hardness  in  water  which  is  caused  by  calcium,  magnesium  and  other  ions  is  usually  described  as  calcium  car- 
bonate equivalent. 

CATION  (CAT-EYE-on)  CATION 

A  positively  charged  ion  in  an  electrolyte  solution,  attracted  to  the  cathode  under  the  influence  of  a  difference  m  electrical  poten- 
tial. Sodium  ion  (Na^)  is  a  cation. 

DIVALENT  (die-VAY-lent)  DIVALENT 
Having  a  valence  of  two,  such  as  the  ferrous  ion,  Fe^\ 

EQUIVALENT  WEIGHT  EQUIVALENT  WEIGHT 

That  weight  which  will  react  with,  displace  or  is  equivalent  to  one  gram  atom  of  hydrogen. 

GREENSAND  GREENSAND 

A  sand  which  looks  like  ordinary  filter  sand  except  that  it  is  green  in  color  This  sand  is  a  natural  ion  exchange  mineral  which  is 
capable  of  softening  water  and  removing  iron  and  manganese. 

HARD  WATER  HARD  WATER 

Water  having  a  high  concentration  of  calcium  and  magnesium  ions.  A  water  may  be  considered  hard  if  it  has  a  hardness  greater 
than  the  typical  hardness  of  water  from  the  region.  Some  textbooks  define  hard  water  as  water  with  a  hardness  of  more  than 
100  mg/L  as  calcium  carbonate. 

HARDNESS,  WATER  HARDNESS.  WATER 

A  characteristic  of  water  caused  mainly  by  the  salts  of  calcium  and  magnesium,  such  as  bicarbonate,  carbonate,  sulfate,  chlo- 
ride and  nitrate.  Excessive  hardness  in  water  is  undesirable  because  it  causes  the  formation  of  soap  curds,  increased  use  of 
soap,  deposition  of  scale  in  boilers,  damage  in  some  industrial  processes,  and  sometimes  causes  objectionable  tastes  in  drink- 
ing water. 

HYDRATPD  LIME  HYDRATED  LIME 

Limestone  that  has  been  "burned"  and  treated  with  water  under  controlled  conditions  until  the  calcium  oxide  portion  has  been 
converted  to  calcium  hydroxide  {Ca(0H)2).  Hydrated  lime  is  quicklime  combined  with  water.  CaO  +  Hfi  Ca(0H)2.  Also  see 
QUICKLIME. 

INSOLUBLE  (in-SAWL-you-bull)  INSOLUBLE 
Somscning  that  cannot  be  dissolved. 


ERIC 


79 


68  Water  Treatment 


'ON  ,0N 
An  electrically  charged  atom,  radical  (such  as  SO^^  ),  or  molecule  formed  by  the  loss  or  gam  of  one  or  more  electrons 

ION  EXCHANGE  EXCHANGE 
A  water  treatment  process  involving  the  reversible  interchange  (switching)  of  ions  between  the  water  being  treated  and  the 
solid  resm.  IJndestrable  Ions  in  the  water  are  switched  with  acceptable  ions  m  the  resin. 

ION  EXCHANGE  RESIN  ,0N  EXCHANGE  RESIN 

Insoluble  polymers,  used  in  water  treatment,  that  are  capable  of  exchanging  (switching  or  giving)  acceptable  cations  or  anion^ 
to  the  water  being  treated  for  less  desirable  ions 

METHYL  ORANGE  ALKALINITY  METHYL  ORANGE  ALKALINITY 

A  measure  of  the  total  alkalinity  .n  a  water  sample  The  alkalinity  is  measured  by  the  amount  of  standard  sulfuric  acid  required 
to  lower  the  pH  of  the  water  to  a  pH  level  of  4.5.  as  ind.cated  by  the  change  in  color  of  methyl  orange  from  orange  to  pink 
Methyl  orange  alkalinity  is  expressed  as  milligrams  per  liter  equivalent  calcium  carbonate. 

NPDES  PERMIT  NPDES  PERMIT 

National  Pollutant  Discharge  Elimination  System  permit  Is  the  regulatory  ac,  jncy  document  designed  to  control  all  discharges  of 
pollutants  from  point  sources  In  U.S.  waterways.  NPDES  permits  regulate  discharges  into  navigable  waters  from  all  point 
sources  of  pollution,  including  industries,  municipal  treatment  plants,  large  agncultural  feed  lots  and  return  irrigation  flows. 

PHENOLPHTHALEIN  ALKALINITY  (FEE-nol-THAY-leen)  PHENOLPHTHALEIN  ALKALINITY 

The  alkalinity  in  a  water  sample  measured  by  the  amount  of  standard  acid  required  to  lower  the  pH  to  a  level  of  8  3.  as  indicated 
by  the  change  in  color  of  phenolphthalein  from  pink  to  clear.  Phenolphthalein  alkalinity  is  expressed  as  milliarams  per  liter 
equivalent  calcium  carbonate. 

PRECIPITATE  (pre«SIP-uh-TATE)  PRECIPITATE 

(1)  An  insoluble,  finely  divided  substance  which  is  a  product  of  a  chemical  reaction  w-'  in  a  liquid. 

(2)  The  separation  from  solution  of  an  insoluble  substance. 

QUICKLIME  QUICKLIME 
A  material  that  is  mostly  calcium  oxide  (CaO)  or  calcium  oxide  in  natural  association  with  a  lesser  amount  of  magnesium  oxide 
Quicklime  is  capable  of  combining  with  water  to  form  hydrated  lime.  Also  see  HYDRATED  LIME. 

RECARBONATION(re-CAR-bun-NAY-shun)  RECARBONATION 
A  process  in  which  carbon  dioxide  is  bubbled  into  the  water  being  treated  to  lower  the  pH.  The  pH  may  also  be  lowered  by  the 
addition  of  acid  Pecarbonation  is  the  final  stage  in  the  lime-soda  ash  softening  procerus.  This  process  converts  carbonate  ions 
to  bicarbonate  ions  and  stabilizes  the  solution  against  the  precipitation  of  carbonate  compounds. 


RESINS  RESINS 
See  ION  EXCHANGE  RESINS. 

SATURATION  SATURATION 

The  condition  of  a  liquid  (water)  when  it  has  taken  into  solution  the  maximum  po&sible  quantity  of  a  given  substance  at  a  given 
temperature  and  pressure. 

SLAKE  SLAKE 
To  mix  with  water  with  a  true  chemical  combination  (hydrolysis)  taking  place,  such  as  in  the  slaking  of  lime. 

Er|c  80 


Softening  89 


SLAKED  LIME  SLAKED  LIME 

See  HYDRATED  LIME. 

SUPERSATURATED  SUPERSATURATED 

An  unstable  condition  of  a  solution  (water)  m  whicf  i  the  solution  contains  a  substance  at  a  concentration  greater  than  the  satu- 
ration concentration  for  the  substance. 

TITRATE  (TIE-trate)  TITRATE 

To  TITRATE  a  sample,  a  chemical  solution  of  known  strength  is  added  on  a  drop-by-drop  basis  until  a  certain  color  change, 
precipitate,  or  pH  change  in  the  sample  is  observed  (end  point).  Titration  is  the  process  of  ad  jing  the  chemical  reagent  in  incre- 
ments until  completion  of  the  reaction  as  signaled  by  the  end  point. 


81, 


ERIC 


70  Water  Treatrent 


CHAPTER  14  SOFTENING 

jm6'Soda  Ash  Softening  by  Don  Gibson 

(Lesson  1  of  2  Lessons) 


14.0   WHAT  MAKES  WATER  HARD?^ 


Water  hardness  is  a  measure  of  the  soap  or  detergent 
consuming  power  of  water.  Technically  hardness  is  caused 
by  DIVALENT^  nnetallic  cations  which  are  capable  of  reach- 
ing (1)  with  soap  (detergent)  to  form  precipitates  and  (2)  wim 
certain  anions  present  in  water  to  form  scale. 


Cations  Causing 
Haro.  'ss 

Calciufii,  Ca^^ 
Magnesium.  Mg^^ 
Strontium,  Sr^^ 
li-on,  Fe2^ 
Manganese,  Mn^* 


Most  Common  Anions 


Bicarbonate,  HCO3 
Sulfate,  SO/- 
Chloride,  Cr 
Nitrate,  NO3- 
bilicate,  SiOg^- 


Ca'^^ium  and  magnesium  are  usually  the  only  cations  that  are 
presont  In  significant  concentrations.  Therefore,  ^-ardnebd  is 
generally  considered  to  be  an  expression  of  the  total  con- 
centration of  the  calcium  and  magnesium  ions  that  are 
present  in  the  water.  However,  if  any  of  the  other  cations 
listed  are  present  in  significant  amounts,  they  should  be 
included  in  the  hardness  determination. 

Table  14.1  descnbes  various  levels  of  hardness.  Different 
textbooks  will  use  s'.-nilar  classifications.  Hardness  levels  in 
source  waters,  local  conditions,  and  local  usage  will  influ- 
ence consumers'  attitudes  towards  the  hardness  of  their 
water. 


TABLE  14.1    DESCRIPTION  OF  VARIOUS  LEVELS  OF 
HARDNESS^ 

Description 


1 .  Extremely  soft  to  soft 

2.  Soft  to  moderately  hard 

3.  Moderately  hard  to  hard 

4.  Hard  to  very  hard 

5.  Very  hard  to  excessively 
hard 

6.  Too  hard  for  ord:*^ary  domestic 
use 


Hardness  in  Terms  of 
nig/L  as  Calcium 
Carbonate 

0-45 

46-90 

91-130 
131-170 
171-250 

OVER  250 


To  help  you  understand  this  chapter  on  water  softening, 
some  of  the  terms  used  are  defirted  below. 

HARD  WATER  is  a  water  havin^  a  high  concentration  of 
'^alcium  and  magnesit.n  ions.  A  water  ma;  be  considered 
hird  if  •.  has  a  hardness  greater  than  the  typical  hardness  of 
water  from  the  region.  Some  textbooks  defiiie  hard  water  ^^s 
a  water  v^ith  a  hardness  of  more  than  100  mg/L  as  ca'c'  71 
carbonate. 


•  Portions  of  the  material  covered  in  the  first  three  sections  of  this  chapter  were  provided  by  Don  Gibbon,  f^arty  Reynolds  Susumu  Ka^^^a- 
mura,  Teny  Engelhardt,  Jack  Rossum  and  Mike  Curry. 

2  Divalent  (dic-VA  Y-lent).  Having  a  valence  of  two,  such  as  ferrous  ion,  Fe^^. 

3  Lipe,  LA.  and  M.D.  C  \rry  ''ion  Exch^ngn  Water  Softening,"  a  discussion  for  water  treatment  plant  operators,  1974-75  seminar  seric 
sponsored  by  Illinois  Environmental  Protection  Agency. 


ERIC 


82 


Softening  71 


HARDNESS  is  i  characteristic  of  water  caused  mainly  by 
the  salts  of  ralcium  and  magnesium,  such  as  bicarbonate, 
carbonatf,  sulfav^,  chlonde  and  nitrate.  Excessive  hardness 
in  water  is  undesirable  because  it  causes  the  formation  of 
soap  curds,  increased  use  of  soap,  deposition  of  scale  in 
boilers,  damage  in  some  industrial  processes,  and  some- 
t:mes  may  cause  objectionable  tastes  in  drinking  water. 

CALCIUM  HARDNESS  is  :iused  by  calcium  ions  (Ca^^). 

MAGNESIUM  HARDNESS  is  caused  by  magnesium  ions 

mn 

TOTAL  HARDNESS  is  the  sum  of  the  hardness  caused  by 
both  calcium  and  magnesium  Ions. 

CARBONATE  HARDNESS  is  caused  by  the  alkalinity 
present  in  water  up  to  the  total  hardness.  This  value  is 
usually  less  than  the  total  hardness. 

NONCARBONATE  HARDNESS  Is  that  portion  of  the  total 
hare  '9SS  in  excess  of  the  alkalinity. 

yALMLMrv^lAL-ka-LIN-it-tee)  is  the  capacity  o*  water  to 
neutralize  ?jlds.  This  capacity  is  caused  by  the  water's 
content  of  carbonate,  bicarbonate,  hydroxide,  and  occasion- 
ally borate,  silicate,  and  phospiiate.  Alkalinity  is  expressed  in 
milligrams  per  liter  of  equivalent  calcium  carbonate.  Alkalin- 
ity is  a  measure  cf  how  much  acid  can  be  added  to  a  water 
without  causing  a  great  change  in  pH. 

CALCiUM  CARBONATE  (CeCO^)  EQUIVALENT  is  an 
t  <pression  of  the  concentration  of  specified  constituents  in 
Wcter  in  terms  of  their  equivalent  value  to  calcium  carbonate. 
For  example,  the  hardness  in  water  which  is  caused  by 
calcium,  magnesium  and  other  ions  is  usually  described  as 
calcium  carbonate  equivalent. 

14.1   WHY  SOFTEN  WATER? 

The  dissolved  minerals  (calcium  and  magnesium  Ions)  in 
water  cause  difficulties  in  doing  the  laundry  and  in  dishwash- 
ing in  the  household.  These  ions  also  cause  a  coating  to 
form  inside  the  hot  water  heater  similar  to  that  in  a  tea  kettle 
after  repeated  use. 


Hardness,  in  addition  to  inhibiting  the  cleaning  action  of 
soaps,  will  tend  to  shorten  the  life  of  fabrics  that  are  washed 
in  hard  water.  The  scum  or  curds  may  become  lodged  in  the 
fibers  of  the  fabric  and  cause  them  to  lose  their  softness  and 
elasticity. 

In  industry  hardness  can  cajse  Aven  nreater  problems. 
Many  processes  are  affected  by  the  hardness  content  of  the 


wa.er  used.  Industrial  plants  usin*-  boilers  for  processing 
steam  or  heat  must  remove  the  t  iess  from  their  make- 
up water,  even  beyond  what  a  water  treatment  plant  would 
do.  The  reason  for  this  is  that  the  minerals  will  plate  out  on 
the  boiler  tubes  and  form  a  scale.  This  scale  forms  an 
insulation  barriei  which  prevents  proper  heat  transfer,  thus 
causing  excessive  energy  requirements  to  fire  the  boilc  s. 
The  problems  associated  with  process  water  softening  are 
too  numerous  to  go  into;  however,  everything  from  food 
processing  to  intricate  manufactunng  processes  is  affected 
by  the  hardness  of  water 

In  addition  to  the  removal  of  hardness  frorn  water,  some 
other  benefits  of  softening  include: 

1.  Removal  of  iron  and  manganese, 

2.  Control  of  corrosion  when  proper  stabilization  of  water  is 
achieved, 

3.  Disinfection  due  to  high  pH  values  when  using  lime 
(especially  the  excess  lime  softening  process), 

4.  Sometimes  a  redi  cti»^ii  In  tastes  and  odors, 

5.  Reduction  of  sorne  total  solids  content  by  the  lime  treat- 
ment process,  and 

6.  Removal  of  radioactivity. 

Possible  limitations  of  softening  might  include: 

1 .  Free  chlorine  residual  is  predominantly  liypochonte  at  pH 
levels  above  7.5  and  is  a  less  powerful  disinfectant. 

2.  Costs  and  benefits  must  be  carefully  weighed  to  justify 
softening. 

3.  Ultimate  disposal  of  process  wastes. 

4.  At  the  pH  levels  associated  with  softening  chemical 
precipitation,  the  tr:  lomethane  fraction  in  the  treated 
water  may  increase  (depends  on  several  othor  factors). 

5.  Producing  an  "aggressive"  water  which  would  tend  to 
corrode  metal  ions  from  the  distribution  system  piping. 
Hard  waters  usually  do  not  corrode  pipe.  However, 
excessively  hard  water  can  cause  scaling  on  the  inside  of 
pipes  and  thereby  restrict  flow. 

In  many  cases,  the  decision  to  soften  the  water  is  left  up  to 
each  community  as  softening  is  done  mostiy  as  a  customer 
service.  Hard  water  does  not  have  an  adverse  effect  on 
health,  but  can  create  several  unwanted  side  affects,  some 
of  which  are: 

1 .  Over  a  periou  of  time,  the  detergent-consuming  power  of 
hard  water  can  be  very  costly, 

2.  Scale  problems  on  fixtures  will  be  more  noticeable,  and 

3.  The  life  cycle  of  several  types  of  clothing  will  be  reduced 
with  repeated  washing  in  hard  water.  Also,  a  residue  can 
be  left  in  clothing,  creating  a  dirty  appearance. 

Once  the  decision  is  made  to  soften,  a  method  must  be 
selected.  The  two  most  common  methods  used  to  soften 
water  are  chemical  precipitation  (lime-soda  ash)  and  ION 
EXCHANGE^.  Ion  exchange  soft^-^ning  can  best  be  applied  to 
waters  high  in  noncarbonate  hardness  and  where  the  total 
hardness  does  not  exceed  360  mg/L.  This  method  of 
softening  can  produce  a  water  of  zero  hardness,  as  op- 
posed to  lime  softening  where  zero  hardness  cannot  be 
reached. 


Ion  Exchange.  A  water  treatment  ^ess  involving  the  reversible  interchange  (switching)  of  ions  between  the  water  being  treated  and 
the  solid  resin.  Undesirable  ions  in  the  water  are  switched  with  acceptable  ions  in  the  resin. 

83 


72  Waiar  Treatment 


Ion  exchange  softening  will  also  remove  ncncarbonate 
hardness  without  the  addition  of  soda  ash  whicn  is  required 
with  lime  softening.  Ion  exchange  is  a  nonselective  method 
of  softening.  This  means  it  will  remove  total  hardness  (the 
sum  of  carbo.  ite  and  noncarbonate  hardness)  making  it  a 
very  desirable  means  of  water  softening. 

Limitations  of  the  ion  exchange  softening  process  include 
an  increase  in  the  sodium  content  of  the  softened  water  if 
the  ion  exchanger  is  regenerated  with  sodium  hydroxide 
The  sodium  level  should  not  exceed  20  mg/L  in  treated 
water  because  of  the  potentially  harmful  effect  on  persons 
susceptible  to  hypertension.  Also  the  ultimate  disposal  of 
spent  brine  and  rinse  waters  from  softeners  can  be  a  major 
problem  for  many  installations. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  1 07. 

14.0A  What  causes  hardness  in  wat*^ 

14 1 A  Why  IS  excessive  hardness  unoesirable  in  a  domestic 
water  supply'? 

14.1B  What  are  some  of  the  limitations  of  the  ion  exchange 
softening  process? 

14.2  CHEMISTRY  CF  SOFTENING 

To  understand  how  water  hardness  is  described  and  also 
how  hardness  is  removed  from  water  by  softening  proc- 
esses, operators  need  to  have  an  idea  of  the  chemical 
reactions  that  take  place  in  water.  In  this  section  hardness, 
pH,  and  alkalinity  reactions  in  water  will  be  discussed. 

14.^u  Hardness 

Hardness  is  due  to  the  presence  of  divalent  metallic 
cations  in  water,  but  the  Fifteenth  Edition  of  STANDARD 
METHODS^  identifies  only  calcium  and  magnesium  as  hard- 
ness constituents.  Hardness  is  commonly  measured  by 
TITRATION^  as  described  in  Volume  I  on  page  513.  Individ- 
ual divalent  cations  may  be  measured  in  the  laboratory  using 
an  atomic  adsorption  (AA)  spectrophotometer  for  veiy  accu- 
rate work. 

Hardness  is  usually  reported  as  CALCIUM  CARBONATE 
(CaCOj)  EQUIVALENTJ  This  procedure  allows  us  to  com- 
bine or  add  up  the  hardness  caused  by  both  calcium  and 
magnesium  and  report  the  results  as  total  hardness. 


Calcium  Hardness  Equivalent  Weight  of  CaC03 

mg/LasCaC03    "  ^^^^"^'^"^  "^"^^ ^^(^ii^>,^\eu\^Q,qhX  o\  0^\z'^^ 

=  (Ca,  mq/L)  ) 
20 

-  2  50(Ca,  mg/L) 

This  equation  indicates  that  if  the  ca'.dum  concentration  in 
milligrams  per  liter  is  multiplied  by  2.50.  the  result  is  the 
calCium  hardness  in  milligrams  per  liter  as  calcium  carbon- 
ate. The  EQUIVALENT  WEIGHT^  of  most  elements  or 
chemical  radicals  ^80/  is  a  radical)  can  be  obtained  by 
dividing  the  molecular  weight  by  the  valence. 

Equivalent  Weight  ^  Atomic  Weight 
of  Calci'  }  Valence 

2 

-  20 

To  express  the  magnesium  hardness  of  v»'ater  as  calcium 
carbonate  equivalent  use  the  following  formula. 

Magnesium  Hardness.  Equivalent  Weight  oi  CaC03 

ng/LasCaCOa       "  ^Magnesium  mniL)  (gqu.vale.it  Weight  o.     <)(.«b.o(ii  J 

50 

=   (Mg.  mg/UCJJ^) 

-  4  12  (Mg,  mg/L) 

The  total  hardness  of  water  is  the  sum  of  the  calcium  and 
magnesium  hardness  as  CaCOg. 

Total  Hardness.  ^  Calcium  Hardness.^  Magnesium  Hardness. 
mg/L  as  CaCOg    mg/L  as  CaCOg       mg/L  as  CaCOg 

EXAMPLE  1 

Determine,  thp  total  hardness  as  CaCOg  for  a  sample  of 
water  with  a  calcium  content  of  30  mg/L  and  a  magnesium 
content  of  20  mg/L. 

Known  Unknown 

Calcium.  mg/L     =  30  mg/L  Total  Hardness, 

Magnesium.  mg/L  =  20  mg/L  n^Q/^  as  CaCOg 

Calculate  the  total  hardness  as  milligrams  per  liter  of 
calcium  carbonate  equivalent. 


^  STANDARD  MET^-IODS  FOR  THE  EXAMINATION  OF  WATER  AND  WASTEWATER,  16th  Edition,  1985.  Order  No.  1 0035.  Available  from 
Data  Processing  Department,  American  Water  Works  Association,  6666  W.  Quincy  Avenue,  Denver,  Colorat^o  60235.  Price  to  members 
$72.00;  nonrr embers  $90.00. 

6  Titrate  (TIE-trate)  To  TITRATE  a  sample,  a  chemical  solution  of  knov^/n  strength  is  added  on  a  drop-by-drop  basis  until  a  certain  color 
change,  precipitate,  orpH  change  in  the  sample  is  observed  (end  point).  Titration  is  the  process  of  adding  the  chemical  reagent  in  incre- 
ments until  completion  of  the  reaction,  as  signaled  by  the  end  point 

7  Calvum  Carbonate  (CaCO^)  Equivalent  An  expression  of  the  concentration  of  specified  constituents  in  water  in  terms  of  their 
equivalent  value  to  calcium  carbonate  For  example,  the  hardness  in  water  whicn  is  caused  by  calnum,  magnesium  and  other  ions  is 
usually  described  as  calcium  carbonate  equivalent. 

8  Equivalent  Weight.  That  weight  which  will  react  with,  displace  or  is  equivalent  to  one  gram  atom  of  hydrogen.  The  equivalen  weight  of 
an  ^'lement  (such  as  Ca^^)  is  equal  to  the  atomic  weight  divided  by  the  valence. 

Molecular  Weight 

Equivalent  Weight  of  CaCOs  =  

Number  o^  Equivalents 

"  "2 


ERIC 


Softening  73 


Total  Hardness.  ^  Calcium  Hardness.^  Magnesium  Hardness, 
mg/L  as  CaCOg    nrig/L  as  CaCOg       mg/L  as  CaCOj 

=  2  50(Ca.  mg/L)  +  4  12  (Mg.  mg/l) 

=  2  50(30  mg/L)  +  4.12(20  mg/L) 

=--  75  mg/L  +  82  4  mg/L 

=  157.4  mg/L  as  CaCOa 

Total  hardness  is  also  described  as  the  sum  of  the 
carbonate  hardness  (temporary  hardness)  and  noncarbon- 
ate  hardness  (permanent  hardness). 

Total  Hardness.  _  Carbonate  Hardness.  Noncarbonate  Hardness. 
mg/L  as  CaCO^  ^  mg/L  as  CaCOa         mg/L  as  CaCOs 

The  amount  of  carbonate  and  noncarbonate  hardness 
depends  on  the  alkalinity  of  the  water.  This  relationship  can 
be  descnbed  as  follows: 

1.  When  the  alkalinity  (expressed  as  calcium  carbonate 
equivalent)  is  greater  than  the  total  hardness,  all  the 
hardness  is  in  the  carbonate  form. 

Carbonate  Hardness,  ^  Total  Hardness, 
mg/L  as  CaCOg  mg/L  as  CaCOg 

2.  When  the  total  hardn^^a  is  greater  than  the  alkalinity,  the 
alkalinity  is  carbonate  hardness  and  noncarbonate  hard- 
ness Is  the  difference  between  total  hardness  and  alkalin- 
ity. 

Carbonate  Hardness.     _  Alkalinity. 
mg/L  as  CaCOs  "  mg/L  as  CaCOa 

Noncarbonate  Hardness.^  Total  Hardness,  _  Alkalinity. 
mg/L  as  CaCOa  '  mg/L  as  CaCOa     mg/L  as  CaCO^ 


14.21  pH 

pH  is  an  expression  of  the  intensity  of  the  basic  or  acid 
condition  of  a  liquid.  Mathematically,  pH  is  the  logarithni 
(base  10)  of  the  reciprocal  of  the  hydrogen  ion  activity. 

1 

cH  =  Log  

(H^) 

The  pH  may  range  from  0  to  14.  where  zero  is  most  acid.  14 
most  basic,  and  7  neutral.  Natural  waters  usually  have  a  pH 
between  6.5  and  8.5.  Table  14.2  shows  the  relationship 
between  pH  and  hydrogen  and  hydroxide  ions. 


TABLE  1 4.2   RELATIONSHIP  BETWEEN  pH  AND 
HYDROGEN  AND  HYDROXIDF  IONS 


pH 

Hydrogen  Ion  (H**"), 

Hydroxide  Ion  (OH  ), 

Moles/Liter 

Moles/Liter 

0 

1.0 

0.000  000  000  000  01 

1 

0.1 

0.000  000  000  000  1 

2 

0.01 

0.000  000  000  001 

3 

0.001 

0.000  000  000  01 

4 

0.000  1 

0.000  000  000  1 

5 

0.000  01 

0.000  000  001 

6 

0.000  001 

0.000  000  01 

7 

0.000  000  1 

0.000  000  1 

8 

0.000  000  01 

0.000  001 

9 

0.000  000  001 

0.000  01 

0 

C  000  000  000  1 

0.000  1 

11 

0.000  000  000  01 

0.001 

12 

0.000  000  000  001 

0.01 

13 

0.000  000  000  000  1 

0.1 

14 

0.000  000  000  000  01 

1.0 

When  treating  waters  th  b  pH  is  very  important  The  pH  of 
water  may  be  increased  cr  decreased  by  the  acJition  of 
certain  chemicals  used  to  treat  water  (Table  14.3).  In  many 
instances,  the  effect  on  pH  of  adding  one  chemical  is 
neutralized  by  the  addition  of  another  chemical  When  soft- 
ening v;ater  by  chemical  precipitation  processes  (lime-soda 
softening  for  example),  the  pH  must  be  raiced  to  1 1  for  the 
desired  chemical  reactions  to  occur  The  leve's  of  carbon 
diox'de.  bicarbonaxs  lor  and  carbonate  ion  in  waters  are 
very  sensitive  to  pH 


I  ABLE  1 4.3   INFLUENCE  OF  WATER  TREATMENT 
CHEMICALS  ON  pH 


Lowers  pH 

Aluminum  Sulfate  (Alum), 

Al2(SOJ3«18H20 
Carbon  Dioxide,  COg 
Chlorine,  CIg 
Ferric  Chloride,  FeClg 
Hydrofluosilicic  Acid,  HgSiFg 
SulfuncAcid.  HgSO^ 


lacreases  pH 

Calcium  Hypochlorite. 

Ca(0CI)2 
Caustic  Soda,  NaOH 
Hydrated  Llme,Ca(0H)2 
Soda  Ash,  NagCOg 
Sodium  Aluminate,  NaAlOg 
Sodium  Hydrochlorite, 

NaOCI 


ERIC 


The  stability  of  treated  water  is  determined  by  measuring 
the  pH  and  calculating  the  Langelier  Index  (see  Chapter  8, 
"Corrosion  Control,"  pages  357  to  360).  This  index  reflects 
the  equilibnum  pH  of  a  water  with  respect  to  calcium  and 
alkalinity. 

Langelier  Index  (L.L)  =  pH  -  pH^ 

pH  =  actual  pH  of  water,  and 

pHg  =  pH  at  which  water  having  the  same 
alkalinity  and  calcium  content  is 
just  saturated  with  calcium  carbon- 
ate 

A  negative  LangeliL  Index  indicates  that  the  water  is  corro- 
sive and  a  positive  index  indicates  that  the  water  is  scale 
forming.  After  water  has  been  softened,  the  treated  water 
distributed  to  consumers  must  be  stable  (neither  corrosive 
nor  scale  forming). 

14.22  Alkalinity 

Alkalinity  is  the  capacity  of  water  to  neutralize  acids.  This 
capacity  is  caused  by  the  water's  content  of  carbonate, 
bicarbonate,  hydroxide,  and  occasionally  borate,  silicate, 
and  phosphate.  Alkalinity  is  expressed  In  milligrams  per  liter 
of  equivalent  calcium  carbonate.  Alkalinity  is  measure  of 
how  much  acid  can  be  added  to  a  liquid  without  causing  a 
great  change  in  pH. 

85 


74  Water  Treatment 


Alkalinity  is  measured  in  the  laboratory  by  iUe  addit.  .r  of 
color  indicator  solutions  and  the  alkalinity  is  then  determined 
by  the  amount  of  acid  required  to  reach  a  titration  end  point 
(specific  color  change)  (see  Chapter  1 1 ,  "Laboratory  Proce- 
dures," pages  491  to  493).  The  P  (phenolphthalein)  end  point 
is  at  pH  8.3.  When  the  pH  is  below  8.3,  there  is  no  P  alkalinity 
present.  When  the  pH  is  above  8.3,  P  alkalinity  is  present.  No 
carbon  dioxide  is  present  when  the  pH  is  above  8.3,  so  there 
IS  no  carbon  dioxide  in  the  water  when  P  alkalinity  is  present 
Also,  hydroxide  and  carbonate  alkalinity  are  not  present 
when  pH  is  below  8.3. 

The  relationship  between  the  vanous  alkalinity  constitu- 
ents (bicarbonate  (HCO3-),  carbonate  (COg^-)  and  hydroxide 
(OH"))  can  be  based  on  the  P  (phenolphthalein  and  T  (total  or 
methyl  orange^  alkalinity  as  shown  in  Table  14.4  and  Fiqure 
14.1.  ^ 


TABLE  14.4   ALKALINITY  CONSTITUENTS 
Alkalinity,  mg/L  as  CaC03 
Titration  Result         Bicarbonate  Carbonate  Hydroxide 


P=  0 

T 

0 

0 

P  is  less  than  V2T 

T-2P 

2P 

0 

P  =  V2T 

0 

2P 

0 

P  Is  greater  than  V2T 

0 

2T-2P 

2P-T 

P=  T 

0 

0 

T 

where  P  =  phenolphthalein  alkalinity 
T  =  total  alkalinity 


When  the  pH  is  less  than  8.3,  all  alkalinity  is  in  the 
carbonate  form  and  is  comrrjonly  referred  to  as  natural 
alkalinity.  When  the  pH  is  above  8.3,  the  alkalinity  may 
consist  of  bicarbonate,  carbonate  and  hydroxide.  As  the  pH 
'ncreases,  the  alkalinity  progressively  shifts  to  carbonate 
and  hydroxide  forms. 


Total  -ilkalinity  is  the  sum  of  the  bicarbonate,  carbonate 
and  hydroxide.  Each  of  these  values  can  be  determined  by 
measuring  the  P  and  T  alkalinity  in  the  laboratory  and 
referring  to  Taole  14.4.  Alkalinity  is  expressed  in  milligrams 
per  liter  as  calcium  carbonate  equivalence.  Alkalinity  is 
influenced  by  chemicals  used  to  treat  water  as  shown  in 
Table  14.5. 


TABLE  14.5   INFLUENCE  OF  WATER  TREATMENT 
CHEMICALS  ON  ALKALINITY 


•.owers  Alkalinity 

Aluminum  Sulfate  (AlumV 

Al3(SOJ3.18H20 
Carbon  Dioxide,  COg 
Chlorine  Gas,  CI2 
Ferric  Chloride,  FeCL 
Ferric  Sulfate,  Fe2(S0 


Sulfuric  Acid,  HgSO^ 


4/3 


Increases  Alkalinity 

Calcium  Hypochlorite, 

Ca(0CI)2 
Caustic  Soda,  NaOH 
Hydrated  Lime,  Ca(0H)2 
Soda  Ash,  Na2C03 
Sodium  Aluminate,  NaAlO, 


EXAMPLE  2 

Results  from  alkalinity  titrations  on  a  raw  water  sample 
were  as  follows: 

Known 

Sample  size,  mL  =100  mL 

mL  titrant  used  to  pH  8.3,  A  =  0  mL 
Total  mL  of  titrant  used,  B  =  8.2  mL 
Acid  normality,  N  =  0.02  N  H2SO4 

Unknown 

1.  Total  Alkalinity,  mg/L  as  CaCOg 

2.  Bicarbonate  Alkalinity,  mg/L  as  CaCOg 

3.  Carbonate  Alkalinity,  mg/L  as  CaCOg 

4.  Hydroxide  Alkalinity,  mg/L  as  CaCOg 

See  Chapter  11,  "Lab  Procedures,"  pages  491-493  for 
details  and  formulas. 


Softening  75 


1  Calculate  the  phenolphthalein  alkalinity  in  mg//.  as 


CaC03. 


Phenolphthalein      ^    N  ^  50  000 

Alkalinity.  

mg/L  as  CaC03  sample 


(0  mL)  >  (0  02  N)  a  (50.000) 


100  mL 


=  0  mg/L 


2  Calculate  the  total  alkalinity  ir\  mg/L  as  CaCOg. 

Total  Alkalinity.    _  B  x  N  x  50.000 
mg/L  as  CaCOj      ni/_  of  sample 

(8.2  mL)  X  (0.02  N)  x  (50,000) 


100  mL 


=  82  mg/L 


3.  Refer  to  Table  14  3  for  alkalinity  constituents.  The  first 
rov/  indicates  that  since  P  =  0.  the  total  alkalinity  is  equal 
to  the  bicarbonate  alkalinity. 

Bicarbonate  Alkalinity,  ^  Total  Alkalinity. 
mg/L  as  CaCOj  mg/L  as  CaCOg 

=  82  mg/L 

The  first  row  also  indicates  that  since  P  =  0.  the  carbon- 
ate and  hydroxide  alkalinlties  are  also  zero. 

Carbonate  Alkalinity,    n  r««// 
mg/LasCaC03      '  ^ 

Hydroxide  Alkalinity.  ^  q  , 
mg/LasCaCOj  ^^^jI- 

QUESTiONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  107. 

14  2A  What  laboratory  procedures  are  used  to  measure 
hardness? 

14  2B  Determine  the  total  hardness  of  CaC03  for  a  sample 
of  water  with  a  calcium  content  of  25  mg/L  and  a 
•nagnesium  content  of  14  mg/L. 

14  20  Which  water  treatment  chemicals  lower  the  pH  when 
added  to  water? 

1 4.2D  Results  from  alkalinity  titrations  on  a  sample  of  water 
were  as  follows:  sample  size.  100  mL;  mL  titrant 
used  to  pH  8.3.  1.2  mL;  total  mL  of  titrant  used.  5.6 
mL.  and  the  acid  normality  was  0.02  N  KSO^. 
Ca  .ulate  the  total,  bicarbonate,  carbonate  and  hy- 
droxide alkalinity  as  CaCOg. 


14.3   HOW  WATER  IS  SOFTENED 

14.30  Basic  Methods  of  Softening 

The  two  basic  methods  of  softening  a  municipal  water 
supply  are  chemical  precipitation  and  ion  exchange.  Ion 
exchange  will  be  discussed  in  the  second  portion  of  this 
chapter  in  Sections  14.10  through  14  21.  We'll  begin  here 
with  the  chemical  precipitation  methoos.  mainly  lirr.e-soda 
ash  softening  and  vanations  of  this  process. 


Hardness  is  not  completely  removed  by  the  chemical 
precipitation  methods  used  in  water  treatment  plants.  That 
IS.  hardness  is  not  reduced  to  zero.  Water  having  a  hardness 
of  150  mg/L  as  CaCOj  or  more  is  usually  treated  to  reduce 
the  hardness  to  80  to  90  .ng/L  v^hen  softening  is  chosen  as  a 
v;f,t::r  treatment  option 

The  minimum  hardness  that  can  be  achieved  by  the  lime- 
soda  ash  process  is  around  30  to  40  mg/L  as  CaCOj.  The 
effluent  from  an  ion  exchange  softener  could  contain  almost 
zero  hardness.  Regardless  of  the  method  used  to  soften 
water,  consumers  usually  receive  a  blended  water  with  a 
hardness  of  around  80  to  90  mg/L  as  CaCOj  when  softening 
IS  used  in  water  treatment  plants. 

Lime-soda  softening  may  produce  benefits  In  addition  to 
the  softening  of  water.  These  advantages  include: 

1  Removal  of  iron  and  manganese. 

2.  Reduction  of  solids, 

3.  Removal  and  inactivation  of  bacteria  and  virus  due  to  high 

4  Control  of  corrosion  and  scale  formation  with  proper 
stabilization  of  treated  water,  and 

5  Removal  of  excess  fluoride. 

Limitations  of  the  lime-soda  softening  process  Include: 
1  Unable  to  remove  all  hardness, 

2.  A  high  degree  of  operator  control  must  be  exercised  for 
maximum  efficiency  in  cost,  hardness  removal  and  water 
stability. 

3.  Color  removal  may  be  complicated  by  the  softening 
process  due  to  high  pH  levels,  and 

4.  Large  quantities  of  sludge  are  created  which  must  be 
handled  and  disposed  of  in  an  acceptable  manner. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  108. 

14.3A  What  IS  the  minimum  hardness  that  can  be  achieved 
by  the  lime-soda  ash  process? 

14.3B  List  some  of  the  benefits  that  could  result  from  the 
hme-soda  softening  process  in  addition  to  softening 
the  water. 


14.31   Chemical  Reactions 

In  the  chemical  precipitation  process,  the  hardness  caus- 
ing ions  are  converted  from  soluble  to  insoluble  forms. 
Calciurn  and  magnesium  become  less  soluble  as  the  pH 
increases.  Therefore,  calcium  and  magnesium  can  be  re- 
moved from  water  as  insoluble  precipitates  at  high  pH 
levels. 

Addition  of  lime  to  water  increases  the  hydroxide  concen- 
trations, thus  increasing  the  pH.  Addition  of  lime  to  water 
also  converts  alkalinity  from  the  bicarbonate  form  to  thj 
c.'irbonate  form  which  causes  the  calcium  to  be  precipitated 
as  '.'alcium  carbonate  (CaC03).  As  additional  lime  is  added  to 
the  water,  th^  ohenolphthaleir,  (P)  »'^lkalinity  increases  to  a 
level  where  hydroxide  becomes  present  (excess  causticity) 
allowing  magnesium  to  precipitate  as  magnesium  hydroxide. 


ERIC 


87 


76  Water  Treatment 


Following  the  chemical  softening  process,  the  pH  is  high 
and  the  water  is  SUPERSATURATED^  with  excess  caustic 
alkalinity  in  either  the  hydroxide  or  carbonate  form.  Carbon 
dioxide  can  be  used  to  decrease  the  causticity  and  scale 
forming  tendencies  of  the  water  prior  to  filtration. 

The  chemical  reactions  which  take  olace  In  water  during 
the  ciiemlcal  precipitation  process  a  e  described  In  the 
remainder  of  this  section.  The  procedures  for  softening 
water  derand  on  whether  the  (  ardness  to  be  removed  is 
carbona.  or  noncarbonate  hardness.  Carbonate  hardness 
(also  called  "temporary  hardness")  can  be  removed  by  the 
use  of  lime  only.  Removal  of  noncarbonat'  ardness  (also 
called  "permanent  hardness")  requires  both  lime  and  soda. 

14.310  Lime 

The  lime  used  in  the  chemical  precipitation  softening 
process  may  be  from  either  HYDRATED  LIME^^  (Ca(CH)2). 
calcium  hydroxide,  or  "slaked"  lime)  or  calcium  oxide  (CaO, 
QUICKUME^^  or  "unslaked"  lime).  The  hydrated  lime  may  be 
used  directly.  The  calcium  oxide  or  quicklime  must  first  be 
SLAKED.^^  This  Involves  adding  the  calcium  oxide  (CaO) 
pellets  to  water  and  heating  to  cause  "slaking"  (the  formation 
of  calcium  hydroxide  (Ca(0H)2))  hefore  use.  Small  facilities 
commonly  use  hydrated  lime  (Ca(0H)2).  Large  facilities  may 
*ind  it  .more  economical  to  use  quicklime  (CaO)  and  slake  it 
on  site. 

14.31 1  Removal  of  Carbon  Dioxide 

The  application  of  lime  for  the  removal  of  carbonate 
hardness  also  removes  carbon  dioxide.  Carbon  dioxide 
does  not  contribute  to  hardness  and  therefore  does  not 

eed  to  be  removed.  However,  carbon  dioxide  will  consume 
a  portion  of  the  lime  to  be  used  and  therefore  must  be 
considered.  Equation  (1)  describes  the  reaction  of  carbon 
dioxide  with  lime. 

(1)  Carbon  Dioxide  ^  Ume     -^Calcium  Carbonatei  +  water 

CO2  +  Ca(OH)2-  CaC03i  4  H2O 

14.312  Removal  of  Carbonate  Hardness 

The  equations  bel'  describe  the  removal  of  carbonale 
hardness. 

(2)  Calcium  Bicarbonate    Ume     —  Calcium  Carbonatel  water 

Ca(HC03H  ^  Ca(0H)2  -  2  raC03|  +  2  H2O 

(3)  Magnesium  Calcium  Magnesium 
Bicarbonate^            ^  Carbonaiei  ^  Carbonate  ^  W^*®' 

Mg(HC03)2  *  Ca(0H)2  -     CaC03i  4  MgC03      +  2  H2O 

(4)  Magnesium  Calcium  Magnesium 
Carbonate                ^  Carbonate|  ^  Hydroxide| 

MgC03      +  Ca(0H)2-.     CaC03l  +  Mg(0H)2l 


When  lime  is  added  to  water,  any  carbon  dioxide  present  is 
converted  to  calcium  carbonate  if  enough  iime  is  added 
(Equation  1).  With  the  addition  of  more  lime  the  calcium 
bicarbonate  will  be  precipitated  as  calcium  carbonate.  To 
remove  both  the  calcium  and  magnesium  bicarbonate,  an 
excess  of  lime  must  be  used. 

14.313  Removal  of  Noncarbonate  Hardness 

Magnesium  noncarbonate  hardness  requires  the  addition 
of  both  lime  and  soda  ash  (sodium  carbonate,  Na2C03). 

(5]    agnesium  Sulfate    Ume     _  Magr.asium  Hydroxide]    (  Actum  Sulfate 
MgS04  +  Ca(0H)2-  Mg(0H)2  +  CaS04 

(6)  Caic  um  Sulfate  4  Soda  Ash  ^  Calcium  Carbonate]    Sodium  Sulfate 
CaS04  +  Na2C03  -  CaC03i  +  Na2S04 

Equation  (6)  is  also  one  of  the  equations  ,or  the  removal  of 
calcium  noncarbonate  hardness.  Similar  equaJons  can  be 
written  for  the  removal  of  noncarbonate  hardness  caused  by 
calcium  and  magnesium  chloride. 

14.314  Stability 

The  main  chemical  reaction  products  from  the  lime-soda 
softening  process  are  CaC03l  and  Mg(0H)2l.  The  water  thus 
treated  has  been  chemically  changed  and  is  no  longer  stable 
because  of  pH  and  alkalinity  changes.  Lime  soda  softened 
water  Is  usually  supersaturated  with  calcium  carbonate 
{CaC03).  The  degree  of  instability  and  excess  calcium  car- 
bonate depends  on  the  degree  to  which  the  water  is  sof- 
tened. Calcium  carbonate  hardness  is  removed  at  a  lower 
pH  than  magnesium  carbonate  hardness.  If  maximum  car- 
bonate hardnesc  removal  is  practiced  (thus  requiring  a  high 
pH  to  remove  the  magnesium  carbonate  hardness),  the 
water  will  be  supersaturated  with  calcium  carbonate  and 
magnesium  hydroxide.  Under  these  conditions  deposition  of 
precipitates  will  occur  in  filters  and  pipelines. 

Excess  lime  addition  to  remove  magnesium  carbonate 
hardness  results  In  supersaturated  conditions  and  a  residual 
of  lime  which  will  produce  a  pH  of  about  10.9.  The  excess 
lime  is  called  caustic  alkalinity  since  it  has  the  effect  of 
raising  the  pH.  If  the  pH  Is  then  lowered,  better  precipitation 
of  calcium  carbonate  and  magnesium  hydroxide  will  occur. 
Alkalinity  will  be  lowerc^  also.  This  is  usually  accomplished 
by  pumping  carbon  dioxide  (CO2)  gas  into  the  water.  This 
addition  of  carbon  dioxide  to  the  treated  watei  is  called 
RECARBONATfON.^^ 

Recarbonation  may  be  carried  out  in  two  steps.  The  first 
addition  of  carbon  dio)  ide  would  follow  excess  lime  addition 
to  lower  the  pH  to  about  1 0.4  and  encourage  the  precipita- 
tion of  calcium  carbonate  and  magnesium  hydroxlae.  A 
second  addition  of  carbon  dioxide  would  be  after  treatment 
to  remove  noncarbonate  hardness.  This  would  again  lower 
the  pH  to  about  9.8  and  would  encourage  precipitation.  By 


^  Supersaturated.  An  uristable  condition  of  a  solution  (water)  in  which  the  solution  contains  a  substance  at  a  concentrat  on  greater  than 
the  saturation  concentration  for  the  substance. 

Hydrated  Lime.  Limestone  that  has  been  "burned"  and  treated  with  water  under  controlled  conditions  until  the  calcium  oxid3  portion 
has  been  converted  to  calcium  hydroxide  (Ca(0H)2).  Hydrated  lime  is  quicldime  combined  with  water.  CaO  +  HoO  —  CaiOHU.  Also 
called  slaked  limo. 

^  ^  Quicklima.  A  material  that  m?sf/y  calcium  oxide  (CaO)  or  calciun:  oxide  in  natural  assomation  with  a  lesser  amount  of  magnesium 
oxide.  Quicklime  is  capable  of  combining  with  water  to  form  hydrated  lime. 

^2  Slake.  To  mix  with  water  with  a  true  chemical  combination  (hydrolysis)  taking  place,  such  as  in  the  shaking  of  lime. 

13  Recarbonation  (re-CAR-bun-NAY-shun).  A  process  in  which  carbon  dioxide  is  bubbled  into  the  water  being  treated  to  lower  the  pH. 
The  pH  may  also  be  lowered  by  the  addition  of  acid.  Recarbonation  is  the  final  stage  in  the  lime-soda  ash  softening  process.  This  proc- 
ess converts  carbonate  ions  to  bicarbonate  ions  and  stabi'izos  the  solution  against  the  precipitation  of  carbonate  compounds. 

ERIC  88 


Softening  77 


carrying  out  recarbonation  prior  to  filtration,  the  build  up  of 
excess  lime  and  also  calcium  carbonate  and  magnesium 
hydroxide  precipitates  in  the  filters  will  be  prevented  or 
minimized.  The  recarbonation  reaction  *or  excess  lime  re- 
moval is  shown  below. 

(7)  Calcium  Hydroxtde    Carbon  Dioxide  «  Calcium  Carbonatei  Water 

Ca(0H)2  ^  CO2  ^  CaC03l  H2O 

Care  musi  be  exercised  when  using  recarbonation  Feed- 
ing excess  carbon  dioxide  may  result  in  no  lowering  of  the 
hardness  by  causing  calcium  carbonate  precipitates  to  go 
back  into  solution  and  cause  carbonate  hardness. 

(8)  Calcium  Carbonate  r  Carbon  OiOxide  -f  Water  ^  Calcium  Bicarbonate 

CaC03  .  CO2  +  H2O  —  Ca(HC03)2 


14.315  Caustic  Soda  Softening 

An  alternate  method  in  the  lime-soda  softening  process  is 
the  use  of  sodium  hydroxide  (NaOH,  often  called  caustic 
soda)  place  of  soda  ash.  The  chemical  reactions  of 
scdiurr.  .ydroxide  with  carbonate  and  non-carbonate  hard- 
ness are  listed  beiow. 

(9)  Carbon  DiOxide  ^  Sodium  Hydroxide-^  Sodium  Carbonate  Water 
CO2  +  2NaOH  —  Na2C03  +  H2O 


(10)  Calr4um 
Btcartx)nate 


Sodium 
Hydroxide"" 

Ca(HC03)2  +  2  NaCH  — 


Calcium 
Carbonatei 


Sodium        ...  . 
Carbonate*  water 


CaC03i  +  Na2C03    +  2  H2O 


(11) 


Magnesium 
Bicart>onate 


Sodium 
Hydroxide 

Mg(HC03)2  +  4  NaCH    -  M9(OH)2l 


Magnesium 
Hydroxide! 


Sodium 


.  +  Water 


Carbonate 
+  2  Na2C03  +  2  H2O 


ERLC 


(12)  Magnesium    Sodium       Magnesium  Sodium 
Sulfate        Hydroxide""  Hydroxide!  Sulfate 

MgS04  ^  2  NaOH    ^  Mg{0H)2     ^  Na2S04 

These  chemical  reactions  show  that  in  removing  carbon 
dioxide  and  carbonate  hardness,  sodium  carbonate 
(Na2C03,  soda  ash)  is  formed  which  will  react  to  remove  the 
noncarbonate  hardness.  Not  only  will  sodium  hydroxide 
substitute  for  soda  ash,  but  it  may  replace  all  or  part  of  the 
lime  (Ca(0H)2)  requirement  for  removal  of  the  carbonate 
hardness.  The  use  of  caustic  soda  (usually  as  a  5C  percent 
solution)  may  have  several  ?dvantages: 

1 .  Stability  in  storage, 

2.  Less  sludge  is  formed,  and 

3.  Ease  of  handling  and  storage. 

Safe  handling  procedures  for  caustic  soda  must  be  used 
at  ail  t'mes.  A  50  percent  caustic  solution  is  very  dangerous. 
Caustic  soda  Is  a  strong  base  and  will  attack  fabrics  and 
leather  and  cause  severe  burns  to  the  skin.  Rubber  gloves, 
respirator,  safety  goggles  and  a  rubber  apron  must  be  worn 
when  handling  caustic  soda.  A  safety  shower  and  an  emer- 
gency eye  wash  must  be  readily  available  at  all  times. 

The  decision  to  use  caustic  soda  rather  than  soda  ash 
depends  on  the  quality  of  the  source  water  ano  me  deliver^jd 
costs  of  the  various  chemicals. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  wi^h  those  on  page  108. 

14.3C  What  causes  the  pH  to  increase  during  the  lime-soda 
softening  proces*;? 


14  3D  Why  is  the  pH  increased  during  the  lime-soda  soften- 
ing process'? 

USE  How  are  the  scale  forming  tendencies  reduced  in 
water  after  the  chemical  softening  process'^ 

14  3F  Under  what  condiuons  might  caustic  soda  softening 
be  used'? 


14.316  Calculation  of  Chemical  Dosages 

There  are  several  dif.'arent  approaches  to  calculating 
chemical  doses  for  the  lime-soda  softening  process.  This 
section  Illustrates  one  step-by-step  procedure.  To  use  this 
procedure  you  need  to  obtain  a  chemical  analysis  of  the 
water  you  are  softening.  From  this  analysis  obtain  the 
known  values  for  your  water  similar  to  the  "Knowns"  listed  m 
EXAMPLE  2.  Then  calculate  the  dosages  of  chemicals  for 
your  water  by  following  the  steps  in  the  example. 

To  help  you  understand  where  some  of  the  numbers  como 
from  m  the  formulas,  we  have  listed  the  molecular  weights  of 
the  major  chemical  components  involved  in  the  chemical 
precipitation  softening  process. 


Quicklime,  CaO 

=  56 

Hydrated  Lime,  Ca(0H)2 

=  74 

Magnesium,  f^g^* 

=  24.3 

Carbon  Dioxide,  CO2 

=  44 

Magnesium  Hydroxide,  Mg(0H)2 

=  58.3 

Soda  Ash,  Na2C03 

=  106 

Alkalinity,  as  CaCOj 

=  100 

Hardness,  as  CaC03 

=  100 

FORMULAS 

1  The  lime  dosage  for  softening  can  be  estimated  by  using 
the  following  formula: 

Quicklime  (CaO)   ^     (A  +  B  +  C  +  0)1.15 


Feed,  mg/L 

Where  A  = 

B  = 


Purity  of  Lime,  as  a  decimal 

:  CO2  in  source  water 
(mg/L  as  C02)(56/44) 

Bicarbonate  alkalinity  removed  in  softening 
{mg/L  as  CaCOaXSe/lOO) 

C  =  Hydroxide  alkalinity  in  softener  eff luer : 
(my/L  as  CaC03(56/1 00) 

D  =  Magnesium  removed  in  softening 
,  ^g|L  as  Mg2+K56/24.3) 

1.15  =  Excess  lime  dosage 

(using  a  15  percent  excess) 

NOTE    If  hydrated  lime  (Ca(0H)2)  is  used  instead  of  quick- 
lime substitute  74  for  56  in  A,  B,  C  and  D. 


2  The  soda  ash  dosage  to  remove  noncarbonate  hardness 
can  t3  estimated  by  using  the  formula  below. 

^^^eeTmglL^^^^^'   (Noncarbonate  Ha-iness.  tngfL  asCaCO3K106/100) 

3  The  dosage  of  carbon  dioxide  required  for  recarbonation 
can  be  estimated  using  the  formula  below. 


Total  COo 


Feed,  mg/L 

89 


^  (CavOH)2  excess,  mg/L)(44/74) 

f  (Mg(0H)2  residual,  mg/L)(44/58.3) 


78  Water  Treatment 


EXAMPLES 

Calculate  the  hydra*ed  lime  (CatOH)^)  with  90  percent 
purity,  soda  ash,  and  carbon  dioxide  dose  requirements  in 
milligrams  per  liter  for  the  v/ater  shown  below. 

Known 


Softened  Water 
After  Recarfoonation 
Source  Water  and  Filtration 

6  mg/L  =  0  mg/L 

170  mg/L  as  CaC03=  30  mg/L  as  CaCOa 
280  mg/L  as  CaCOa^  70  mg/L  as  CaCOa 
=  3  mg/L 
=  8.8 


Constituents 

CP2.  mg/L 
Total  Alkalmtty,  mg/L 
Total  Hardness,  mg/L 
Mg2*,  mg/L  =  21  mg/L 

pH  =  7.5 

Lime  Purity,  %         =  90% 

Unknown 

1.  Hydrated  Lime,  mg/L 

2.  Soda  Ash,  mg/L 

3.  Carbon  Dioxide,  mg/L 

1.  Calculate  the  hydrated  lime  (CapHjj)  required  in  milli- 
grams per  liter. 


A  = 

B  = 

C  = 
D 


(CO2,  mg/L)(74/44) 
(6  mg/LM74/44) 
10  mg/L 

(Alke:inity,  mg/LX74/100) 
=  (170mg/LX74''  )0) 
■■  126  mg/L 

=  0 

=  (Mg2*,  mg/L)(74/24.3) 
=  (21  mg/L)(74/24.3) 
=  64  mg/L 


Hydrated  Lime 
(Ca{0H)2)  Feed,  ^ 
mg/L 


(A  +  B  +  C  +  D)1.15 


Purity  of  Lime,  as  a  decimal 
10  mg/L  -f  126  mg/L  +  0  +  64  mg/L)1.15 
"090 


^(200  mg/LM1.15) 

O90 
=  256  mg/L 

2.  Calculate  t.ie  soda  ash  required  in  milligrams  per  liter. 

Noncarl)onate  Hardness,  ^  Total  Hardness,    _Cart>onate  Hardn'*':, 
mg/L  as  CaCOa         "   mg/i.  as  CaCOa  ~   mg/L  as  CaCOa 

=  280  mg/L  -  170  mg/L 

«  110  mg/L  as  CaCOa 

Soda  Ash  (NapCQa)  _  /  Noncarbonate  Hardness, .  ,^naitM\ 
Feed.  mg/L  *       "  ^      mg/L  as  CaCOa      ^  ^06/100) 

=  (I10mg/L)(106/100) 
=  117  mg/L 

3.  Calculate  the  dosage  of  ca*'bon  dioxide  required  for 
recarbonation. 

Excess  Ume,  mg/L  -  (A  +  B  +  C  +  OX0.15) 

«  (10  mg/L  +  126  mg/L  +0  +  6^  mg/LK0 15) 

-  (200mg/LX0.15) 

-  30  mg/L 


Total  CO2      ^(Ca(0H)2  excess,  mg/L)(44/74) 
Feed,  mg/L   ^  (f^g2-  residual,  rng/L)(44/24.3) 

=  (30  mg/L)(44/74)  +  (3  mg/L)(44/24.3) 
=  18  mg/L  +  6  mg/L 
=  24  mg/L 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  108. 

1 4.3G  Calculate  the  hydrated  lime  (CiJOHlj)  with  90  percent 
purity,  soda  ash,  and  carbon  oioxide  dose  require- 
ments in  milligrams  per  liter  for  the  water  shown 
below. 

Softened  Water 
After  Recarbonation 
Constituents  Source  Water  and  Filtration 

CO2,  mg/L  =  5  mg/L  =  0  mg/L 

Total  Alkalinity,  mg/L  =  150  mg/L  as  CaCO  =^  20  mg/L  as  CaCO 

Total  Hardness,  mg/L=  240  mg/L  as  CaCO  =  50  mg/L  as  CaCO 

Mg2\  mg/L  =  16  mg/L  =  2  mg/L 

pH  =  7.4  =  8.8 

Ume  Pu'ity,  %  =  90% 


14.32  Lime  Softening  (Figure  14.2) 

Water  having  hardness  caused  by  calcium  and  magne- 
sium bicarbonate  (carbonate  hardness)  can  usually  be  sof- 
tened to  an  acceptable  level  using  only  lime.  The  lime  reacts 
with  the  bicarbonate  to  form  calcium  carbonate  which  will 
precipitate  and  settle  out  (convert  from  soluble  to  insoluble 
form)  at  a  pH  above  1 0  and  magnesium  carbonate  which  will 
remain  in  solution.  The  magnesium  carbonate  reacts  with 
additional  lime  at  a  pH  above  11  to  form  magnesium 
hydroxide  which  will  precipitate. 

In  practice,  if  enough  hardness  can  be  removed  by  react- 
ing lime  with  the  calcium  bicarbonate,  softening  can  be 
accomplished  at  less  expense.  This  procedure  is  sometimes 
called  partial  lime  softening  (no  magner^iu.  removal).  On  the 
other  hand,  if  some  of  the  magnesium  is  to  be  removed, 
additional  lime  will  be  required. 

Figure  14.2  is  a  flow  diagram  of  a  typical  straight  lime 
softening  treatment  plant.  Settling  should  be  provided  after 
the  addition  of  carbon  dioxide  (recarbonation)  to  ease  the 
load  on  the  filters.  Recarbonation  is  used  to  lower  the  pH  of 
the  water.  When  properly  recarbonated  the  water  is  still 
supersaturated  with  calcium  cartK)nate  {CaC03),  If  the  pH  is 
much  above  9,  the  water  will  usually  cause  scale  to  form.  By 
recarbonation  the  pH  can  be  lowered  to  a  range  between  8.8 
and  8.4  and  the  Langelier  Index  will  still  be  positive;  there- 
fore there  will  be  little  or  no  corrosion.  A  polyphosphate  is 
sometimes  added  to  the  water  to  prevent  excessively  heavy 
calcium  carbonate  scale  deposits  from  forming.  A  polyphos- 
phate may  not  be  necessary  if  recarbonation  is  prope ^ly 
controlled.  Addition  of  acid  will  A/07  accomplish  the  sarne 
things  as  recarbonation  and  the  addition  of  a  polyphos- 
phate. 


14.33  Split  Treatment 

The  amount  of  calcium  and  magnesium  in  source  waters 
may  vary.  When  the  water  contains  a  high  level  of  magne- 
sium, a  method  known  as  split  treatment  may  be  uoed 
(Figure  14.3).  Split  treatment  can  be  used  in  lime  treatment 


ERLC 


90 


Softening  79 


only  or  lime-soda  ash  treatment.  In  split  treatment  a  portion 
of  the  water  (say  90  percent)  is  treated  with  an  excess 
amount  of  lime  to  remove  the  magnesium  at  a  pH  of  over  1 1 . 
Then  source  water  (the  other  20  percent)  is  added  in  the  next 
basin  to  neutralize  (lower  the  pH)  the  excess-llme-tteated 
portion.  The  percentages  will  vary  depending  upon  the  water 
hardness,  treatment  layout,  and  desired  results. 

Split  treatment  softening  can  eliminate  the  need  for  recar- 
bonation  as  well  as  offer  a  significant  savings  in  lime  feed. 
Since  the  fraction  of  the  water  that  is  treated  has  a  high  lime 
dose,  magnesium  is  almost  completely  removed  from  this 
portion.  When  this  water  is  mixed  with  the  unsoftened  water, 
the  carbon  dioxide  and  bicarbonate  in  the  unsoftened  trac- 
tion of  the  water  tend  to  recarbonate  in  the  final  blend  or  mix 
of  the  treated  water  (effluent). 

If  the  water  shown  In  Figure  14.4  was  treated  by  conven- 
tional treatment  (not  split  treatment),  it  would  require  a  lime 
dose  of  400  mg/L  as  CaCOg  which  is  25  percent  higher  and  a 


carbon  dioxide  dose  of  145  mg/L  as  CaCOg  to  produce  a 
water  having  a  hardness  of  61  mg/L  as  CaCOa  and  a  pH  of 
8.63. 

While  split  treatment  may  be  used  in  the  lime-soda  proc- 
ess. It  IS  often  aovantageous  to  use  a  lime-ion  exchange 
process  (see  Section  14.10).  The  salt  used  to  remove 
noncarbonate  hardness  in  the  ion  exchange  process  is 
much  less  expensive  than  the  soda  ash  required  in  the  lime- 
soda  ash  process. 

The  curves  shown  in  Figure  14.4  assume  that  carbonate 
equilibrium  has  been  achieved.  In  practice,  it  is  not  possible 
to  a'ltain  equilibrium,  but  if  the  reactions  take  place  in  solids- 
contact  units  the  results  are  very  close  to  carbonate  equilib- 
rium. 

The  proper  fraction  of  water  to  bypass  is  rather  critically 
dependent  on  the  lime  dose  and  chemical  composition  of  the 
unsoftened  ;vater.  The  proper  fraction  may  be  calculated, 
but  the  calculations  are  very  complex.  An  experienced  water 
chemist  can  perform  the  calculations. 


COAGULANT 
LIME 


SOURCE 


ILIM 


MIX 


SETTLE 


CO2 


FILTERS 


SETTLE 


I 

(OPTIONAL) 


Fig.  14.2  Straight  lime  treatment 


LiME 

4 


SOURCE 


MIX 


SETTLE 


MIX 


BYPASS 
COAGULANT 


CO2 

SETTLE  jJ\  *^I-EAR  \ 

I  piz^W  W.U ) 

P04  P04 


P04 

(OPTIONAL) 


Fig.  14.3  Split  lime  treatment 


ERIC 


91 


80  Water  Treatment 


UNSOFTENED  WATER 

TEMPERATURE   =  25°C  Ca   =  150  mg/L  as  CaCOa 

TDS  =  400mg/L  Mg  =  100  mg/Las  CaCOa 

PH  =  7.2  Alk  =  250  mg/L  as  CaCOs 

DOSAGE 


LIME  =  320  mg/L  as  CaCOs 


UNSOFTENED  WATER  BYPASSED,  % 


ERIC 


F/g.  14.4  Spin  treatment  softening 

92 


Softening  81 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  109. 

14  3H  What  compounds  are  formed  when  calcium  and 
magnesium  are  piecipitated  out  of  water  in  the  lime 
softening  process? 

14.31  What  hardness  is  removed  by  partial  lime  softening 
(no  magnesium  removal)? 

14  3J  What  is  split  lime  treatment? 

14.3K  What  IS  recarbonation'? 

14.34  Lime-Soda  Ash  Softening 

Let's  look  now  at  hardness  requiring  lime-soda  ash  treat- 
ment for  removal  (Figure  14.5). 

When  water  cannot  be  softened  to  the  desired  level  with 
lime  only,  it  no  r'.dbt  contains  noncarbonate  hardness. 
Noncarbonate  hardness  requires  the  addition  of  a  com- 
pound which  increases  carbonate  concentration,  usually 
soda  ash  (sodium  carbonate). 

A  water  could  contain  only  calcium  hardness,  yet  require 
both  lime  and  soda  ash  treatment.  This  would  occur  if  the 
hardness  were  only  calcium  bicarbonate,  sulfate  and/or 
chloride.  In  other  words,  all  of  the  hardness  is  calcium 
carbonate  and  calcium  noncarbonate  hardness.  This  would 
not  require  split  treatmen*  (Figure  14.6). 

14.35  Caustic  Soda  Softening 

An  alternative  to  the  lime-soda  ash  process  is  the  use  of 
caustic  soda  (sodium  hydroxide,  NaOH)  instead  of  soda  ash. 


The  reactions  of  caustic  soda  with  the  carbonate  and 
noncarbonate  hardness  are  given  in  Section  14.315.  Recall 
that  caustic  soda  reacts  with  the  carbonate  hardness  to  form 
soda  ash  (sodium  carbonate)  which  will  react  with  calcium 
sulfate  to  form  calcium  carbonate  (CaCOgl)  as  Phown  pre- 
viously. 


The  advantages  of  using  liquid  caustic  soda  include  ease 
of  handling  and  feeding,  lack  of  deterioration  in  storage,  and 
less  calcium  carbonate  sludge  to  handle  and  dispose  of. 
Caustic  soda  is  capable  of  removing  both  carbonate  and 
noncarbonate  hardness.  Therefore,  caustic  soda  may  be 
used  instead  or  soda  ash,  but  also  in  place  of  part  or  all  of 
the  lime  requirement.  The  use  of  caustic  soda  depends  on  a 
comparison  of  the  costs  of  caustic  joda,  lime  and  soda  ash 
and  the  characteristics  of  the  source  water. 


LIME 


SOURCE 


SODA  ASH 


MIX 

COAGULANT 


PO4 

(OPTIONAL) 


Fig.  14.5  Lime-soda  ash  treatment 


SOURCE 


  J  ''^4 

I  (OPTIONAL) 
COAGULANT 


Fig.  14.6  Lime- soda  ash  split  treatment 


82  Water  Treatment 


Two  points  to  observe  are  that  sodium  does  not  contribute 
to  hardness,  thus  all  the  reactions  having  sodium  com- 
pounds as  an  end  product  are  non-hardness-producing 
compounds  However,  sodium  levels  in  dnnking  water 
should  be  less  than  20  mg/L  The  second  point  is  that  the 
precipitated  compounds,  CaCOjl  and  Mg(0H)2l  are  the 
desired  end  products  whether  lime  or  lime-soda  ash  or 
caustic  soda  treatment  is  used. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  109. 

14.3L  Under  what  conditions  would  lime-soda  ash  soften- 
ing be  used'? 

14.3M  What  chemical  is  used  to  remove  noncarbonate 
hardness  in  the  chemical  precipitation  softening  pro- 
cess? 

14.36  Handling,  Application  and  Storage  of  Lime 

Where  the  daily  requirements  for  lime  are  small,  lime  is 
usually  delivered  to  the  water  treatment  plant  in  bags.  At 
larger  treatment  plants  either  quick  (CaO)  or  hydrated 
(Ca(0H)2)  lime  is  delivered  in  bulk  quantities.  Truck  loads  of 
lime  are  commonly  transferred  to  weather-tight  bins  or  silos 
by  mechanical  or  pneumatic  conveying  systems. 

Storage  areas  for  bagged  lime  must  be  covered  to  prevent 
ram  from  wetting  the  bags.  Bagged  quicklime  (CaO  or 
calcium  oxide)  should  never  be  stored  close  to  combustible 
materials  because  considerable  heat  will  be  generated  if  the 
lime  accidentally  gets  wet.  Quicklime  may  be  stored  as  long 
as  six  months,  but  in  general  should  not  be  stored  over  three 
months.  Hydrated  lime  should  not  be  stored  for  more  than 
three  months  before  using. 

Lime  may  be  applied  by  dry  feeding  techniques  using 
volumetric  or  gravimetric  feeders.  Lime  is  too  insoluble  to 
make  "solution  feeding"  by  pump  feeders  practical  because 
of  the  accumulation  of  carbonate  precipitation.  See  Chapter 
13,  "Fluoridation,"  for  additional  details  and  pictures  of  the 
various  types  of  chemical  feeders. 

Operator  safety  must  be  considered  before  atternpting  to 
work  with  lime.  A  properly  designed  lime  feeding  system  can 
minimize  or  eliminate  lime  dust  problems.  If  lime  dust  is  a 
problem,  operators  must  wear  protective  clothing  to  avoid 
burns  from  contact  with  lime.  Protective  clothing  includes 
long-sleeved  shirt  with  sleeves  and  collar  buttoned,  trousers 
with  legs  down  over  tops  of  shoes  or  boots,  head  protection, 
and  gloves.  Clothing  should  not  fit  too  tightly  around  your 
neck,  wrists  or  ankles,  A  protective  cream  should  be  applied 
to  exposed  parts  of  the  body,  especially  your  neck,  face  and 
wrists.  You  should  wear  a  light-weight  filter  mask  and  tight- 
fitting  safety  glasses  with  side  shield  to  protect  yourself  from 
the  lime  dust. 


If  lime  comes  in  contact  with  your  skin  or  eyes,  immediate- 
ly flush  the  affected  areas  with  water  and  consult  a  physician 
if  necessary.  Do  not  rub  your  eyes  if  they  are  irritated  with 
lime  dust  because  rubbing  make  the  irritation  worse. 
Keep  any  hme  burns  cohered  with  a  banddge  during  healing 
to  prevent  infection. 

After  handling  lirne,  you  should  take  a  shower.  If  your 
clothes  are  covered  with  dust,  or  splattered  with  a  lime 
slurry,  take  them  off  and  have  them  washed.  If  possible, 
wear  clean  clothes  on  every  shift. 

For  additional  information  regarding  lime,  contact  the 
National  Lime  Association,  Washington,  D.C.  20016,  and 
request  a  copy  of  their  publication,  LIME  HANDLING,  AP- 
PLICATION. A,'^n  r^TORAGE  IN  TREATMENT  PROC- 
ESSES. Lime,  as  well  as  other  water  treatment  chemicals, 
should  comply  with  the  Standards  of  the  American  Water 
Works  Association. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  109. 

14  3N  How  IS  lime  delivered  to  plants  where  the  daily 
requirements  are  small? 

14.30  Why  should  quicklime  be  kept  dry'? 

1 4  3P  What  types  of  chemical  feeders  are  used  to  apply  dry 
lime? 


14.4   INTERACTIONS  WITH  COAGULANTS 

Coagulation  is  discussed  in  detail  in  Chapter  4,  "Coagula- 
tion and  Flocculation."  However,  the  interactions  of  lime  and 
soda  ash  with  metallic  coagulants  such  as  alum,  iron  salts 
(fernc  chloride,  ferric  sulfate  and  ferrous  sulfate),  sodium 
aluminate,  and  many  polymers  are  important. 

Alum  and  iron  salto  are  acidic  and  react  with  the  alkalinity 
in  water  to  cause  a  demand  the  same  way  that  fiee  carbon 
o.oxide  will.  Therefore,  this  acidic  condition  must  be  met 
before  softening  can  occur.  In  other  words,  extra  lime  will  be 
required  as  the  alum  or  iron  feed  rate  goes  up  and  therefore, 
less  hme  will  be  required  as  the  alum  or  iron  feed  rate  is 
reduced.  Cationic  polymers  are  not  very  pH  sensitive  and 
are  often  used  as  coagulant  aids  in  softening  plants  rather 
than  alum  or  iron  salts. 

On  the  other  hand,  when  sodium  aluminate  (a  basic  rather 
than  an  acidic  compound)  is  the  coagulant,  the  lime  required 
to  achieve  a  specific  hardness  reduction  will  be  less,  and  will 
vary  the  opposite  of  alum  or  iron  salts. 

The  proportion  of  lime  required  in  either  instance  is 
directly  related  to  the  coagulant  dosage  as  well  as  the 
hardness  removal  desired.  Approximate  relationships  can 
be  calculated;  however,  experimentation  is  in  order  since 
plant  equipment  and  source  water  variations  are  primary 
factors  in  the  efficiencies  of  each  waterworks.  Jar  tests  are 
discussed  later  in  Section  14.9. 

If  you  are  treating,  highly  colored  waters,  these  waters 
must  be  coagulated  for  color  removal  at  low  pH  values.  Alum 
IS  a  good  coagulai.t  under  these  conditions.  Ozone,  perman- 
ganate and  chlorine  may  be  tried  along  with  alum  to  oxidize 
color.  The  high  pH  values  required  during  softening  tend  to 
"set"  the  color  which  then  becomes  very  difficult  to  remove. 


Softening  83 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  109. 

14.4A  What  happens  to  the  lime  dose  when  the  alum  do*^,3 
IS  increased  for  coagulation'^ 

14.4B  How  can  color  be  removed  from  water'^ 

14.5  STABILITY 

In  nature,  most  waters  are  more  or  less  stable.  That  is, 
they  are  in  chemical  balance.  When  lime  is  added,  the 
chemical  balance  is  changed.  The  calcium  carbonate 
(CaCOg)  formed  m  lime  treatment  is  scale  forming  unless  the 
exact  chemical  balance  is  achieved,  which  is  seldom  the 
case. 

Under  most  conditions,  a  slight  excess  of  lime  is  fed  to 
cause  a  caustic  condition  to  insure  complete  reactions  and 
achieve  the  desired  results  In  order  to  prevent  scale  forma- 
tion on  the  filter  sand,  dii*ribution  mains,  and  .household 
plurnuing,  the  excess  caustiC  and  unprecipitated  carbonate 
ions  (pin  floe)  must  be  converted  to  soluble  forms.  Recar- 
bonation  is  the  mobi  common  way  to  do  this  Again,  as  with 
all  chemical  treatment,  recarbonation  must  be  controlled  to 
achieve  the  desired  results. 

Recarbonation  lowers  the  pH  to  about  8.8  and  thus 
converts  some  of  the  carbonate  (00^~)  back  to  the  original 
bicarbonate  (HCO3")  that  existed  in  the  source  water.  Recar- 
bonation can  be  accomplished,  to  a  degree,  by  using  thp 
source  water  in  the  split  treatment  mode  discussed  earlier. 
Usually  this  is  not  adequate  so  further  recarbonation  is 
required.  One  reason  for  using  source  water  as  a  neutraliz- 
ing agent  is  that  the  recarbonation  process  is  much  less 
costly  than  if  a  high  caustic  water  (high  pH)  is  neutralized  by 
chemical  addition. 

Usft  of  carbon  dioxide  gas  is  the  most  common  method  of 
recarbonation.  The  reactions  are: 

1.  Ca(0H)2  +  CO2  +  HgO     Ca(HC03)2  and 

2.  CaCOg  +  CO2  +  Hp  Ca(HC03)2. 

These  reactions  may  be  looked  at  as  lime  softening  in 
r  'verse  and  will  increase  the  hardness  slightly.  In  these 
r<jactions  you  are  producing  bicarbonate  ions  which  were 
removed  in  softening  as  carbonate  hardness.  This  process 
tends  to  move  the  water  back  toward  its  original  state,  thus 
rendenng  it  more  stable. 

The  use  of  acids  such  as  sulfuric  or  hydrochloric  instead 
of  recarbonation  with  carbon  dioxide  (CO2)  does  nci  pro- 
duce the  same  results.  When  carbon  dioxide  is  added  to  a 
water  containing  calcium  ions  (Ca^*)  and  hydroxide  ions 
(OH"),  a  calcium  carbonate  (CaCOg)  precipitate  will  f-^rm  and 
the  water  will  be  saturated  (or  supersaturated)  with  calcium 
carbonate.  If  a  strong  acid  is  added  to  neutralize  the 
softened  water  which  is  highly  basic,  these  reactions  will  not 
take  place. 

The  marble  test  is  the  simplest  method  of  measuring 
stability  in  the  laboratory.  Run  the  marble  test^^  as  outlined 
below: 

1 .  Collect  a  sample  of  tap  water  that  has  been  softened  and 
stopper  the  sample  bottle  (avoid  splashing  into  the  flask). 


2.  To  an  identical  sample,  add  one  gram  of  powdered 
calcjum  carbonate.  Mix  and  let  stand  for  an  hour  or  so. 

3  Filter  both  samples  (so  they  are  both  exposed  to  the 
same  conditions). 

4.  Run  pH  and  alkalinity  tests  on  both  samples. 

5.  The  goal  is  to  have  the  sample  of  softened  tap  water  as 
nearly  matched  lo  the  softened  sample  treated  with 
calcium  carbonace  as  possible.  Then  stability  is  near.  The 
plant  treatment  must  be  controlled  to  permit  this  condi- 
tion to  exist.  If  the  pH  and  alkalinity  in  the  softened 
sample  are  higher  than  in  the  softened  sample  treated 
with  calcium  carbonate,  ycu  are  probably  over-treating 
your  supply  and  have  scale-forminq  water.  But,  if  the  pH 
and  alkalinity  in  your  untreated  softened  sample  are 
lower  than  in  the  treated  one  (calcium  carbonate  added), 
you  are  undertreating  your  supply.  If  they  are  similar,  then 
stability  is  near. 

Another  way  to  check  your  water  is  to  suspend  a  couple  of 
nails  on  strings  in  your  filter.  ODssrve  the  nails  occasionally 
to  if  they  are  rusting  or  scaling  up.  Tc  further  protect  the 
distnbution  system  as  well  as  prevent  scale  formation  in  the 
filter  bed,  0.7  \o  1.0  mg/L  polyphosphate  could  be  fed  ahead 
of  the  filters  at  such  a  d'stance  to  allow  mixing  before  it  goes 
on  to  the  filters.  Addition  of  polyphosphate  can  PREVENT 
THE  FORMATION  OFSCALEon  filter  media  and  in  distribu- 
tion system  mains,  but  polyphosphate  does  NOT  prevent 
corrosion.  The  Langelier  Index  (see  pages  357  to  360  in 
Volume  I)  IS  another  approach  to  determining  the  corrosivity 
of  water. 


Caution  should  be  exercised  when  using  polyphosphate 
compounds.  If  they  are  converted  to  the  orthophosphate 
form,  they  will  lose  their  effectiveness.  With  the  addition  of 
phosphorous  to  water,  there  could  be  an  increase  in  bacte- 
iial  growths  in  the  distribution  system.  Also  some 
wastewater  treatment  plants  have  phosphorous  discharge 
limitations  and  polyphosphates  added  to  drinking  water  can 
cause  wastewater  treatment  plants  to  violate  their  discharge 
requirements. 


For  additional  information  on  the  marble  test,  see  Chapter  21,  ''Advanced  Laboratory  Procedures,"  Test  Procedure  9,  Marble  Test. 

ERIC  ;r  9^ 


84  Water  Treatment 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  109. 

1 4.5A  What  problems  are  sometimes  created  when  a  slight 
excess  of  lime  is  fed  during  softening  to  cause  a 
caustic  condition  to  insure  complete  reactions'? 

14.5B  How  can  excess  caustic  and  unprecipitated  carbon- 
ate ions  (pin  floe)  be  removed  from  softened  water? 

14.5C  What  test  is  used  to  determine  if  a  water  is  stable? 

14.5D  How  can  nails  be  used  to  determine  if  a  water  is 
stable? 


14.6  SAFETY 

When  quicklime  reacts  with  water  in  the  slaking  process 
(Figure  147),  it  gets  hot  enough  to  cause  serious  burns. 
Also,  being  caustic  in  nature,  it  can  harm  your  eyes  and  skin. 
ALWAYS vjear  goggles  or  a  face  shield  when  working  with 
lime  that  has  been  or  is  in  the  process  of  slaking.  Flush  with 
water  if  exposed  to  lime.  Seek  medical  attention  if  it  gets  in 
your  eyes.  As  for  hands  or  face  burns,  immediately  wash  the 
affected  areas  and  consult  a  physician  if  the  burns  appear 
serious. 

Feeding  equipment  has  moving  parts.  All  moving  machin- 
ery IS  a  potential  safety  hazard.  A  paste-type  slaker  is 
particularly  dangerous.  This  type  of  slaker  will  "eat  you 
alive  "  Never  put  your  hand  In  or  near  the  slaker  paddles 
while  the  slaker  is  running.  Use  wooden  paddles  as  cleaning 


tocis  on  any  slaker  in  operation.  A  metal  tool  will  damage  the 
slaker  and  could  even  injure  the  operator  if  dropped  by 
accident  However,  a  wooden  paddle  is  less  likely  to  damage 
the  equipment  or  the  operator. 

Types  of  equipment  vary  greatly.  Usually  the  operator  has 
little  or  no  input  in  this  area.  Engineers  usually  design  a  plant 
and  specify  the  type  of  chemical  feed  equipment. 

Equipment  suppliers  are  usually  quite  cooperative  in  ad- 
vising any  ope'-ator  in  the  use  and  care  of  their  equipment  in 
your  treatment  plant. 

Detailed  startup  and  shutdown  and  maintenance  proce- 
dures are  available  in  the  equipment  manuals. 

Another  important  safety  precaution  is  to  avoid  using  the 
same  conveyor  or  uin  for  alternately  handling  both  quicklime 
and  one  of  the  coagulants  containing  water,  such  as  alum, 
ferric  sulfate  or  copperas.  This  water  may  be  withdrawn  by 
the  quicklime  and  could  generate  enough  heat  to  cause  a 
fire  Explosions  have  been  reported  to  have  been  caused  by 
lime-alum  mixtures  in  enclosed  bins.  Therefore,  always 
clean  facilities  before  switching  from  one  chemical  to  an- 
other 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  109. 

14  6A  Why  should  wooden  paddles  be  used  as  cleaning 
tools  on  any  slaker  in  operation? 

14.6B  Where  would  you  look  for  information  on  how  to 
safely  maintain  equipment? 


ERLC 


Fig,  14  J  Ume-siakmg  system 

(Permission  of  Wallace  &  T:ernan  Division.  Pennwait  Corporation) 


Softening  85 


147   SLUDGE  RECIRCULATION  AND  DISPOSAL 


Considerable  sludge  may  be  produced  by  the  lime  and 
lime-soda  softening  processes.  When  calcium  and  magne- 
sium hardness  are  converted  from  soluble  lorms  to  insolu- 
ble precipitates  (calcium  carbonate  and  magnesium  hydrox- 
ide), these  precipitates  form  sludge.  This  sludge  is  removed 
from  the  bottom  of  settling  basins  and  may  be  recirculated 
or  must  be  disposed  of  by  an  acceptable  procedure. 

in  some  instances,  sludge  is  recirculated  back  into  the 
primary  mix  area  of  conventional  plants  to  help  "seed"  the 
process.  The  advantages  are  (1)  recirculation  speeds  up  the 
precipitation  process  and  (2)  some  reduction  of  chemical 
requirements  may  result.  One  disadvantage  is  that  an  in- 
crease m  magnesium  could  result.  Only  trial  and  error  wili 
really  dete''mine  »^  sludge  •'ecrculation  will  serve  a  useful 
purpose  in  your  plant. 

Sludge  disposal  is  a  problem  everywhere.  Perhaps  the 
most  common  method  is  landfill  disposal.  This  is  accom- 
plished by  dewatering  the  sludge  (drying  beds  or  mechanical 
means)  and  then  hauling  the  sludge  to  landrill  sites  devel- 
oped solely  for  sludge  disposal  or  sanitary  landfills.  General- 
ly, a  sludge  with  a  Ca  Mg  ratio  of  less  than  2.1  will  be  difficult 
to  dewater,  whereas  r.  sludge  with  a  Ca  Mg  ratio  of  greater 
than  5:1  will  dewater  relatively  easily.  The  less  water  in  the 
sludge,  the  less  volume  to  transport  to  the  disposal  site  and 
the  less  space  required  in  the  landfill. 

To  a  lesser  degree,  sanitary  sewer  disposal  is  sometimes 
used.  This  only  moves  ihe  sludge  to  another  location  for 
someone  else  to  deal  with.  Some  work  has  also  been  done 
with  land  application  as  a  substitute  for  agriculture  lime  to 
increase  the  pH  of  highly  acid  soils.  The  lime  sludge  is 
applied  at  a  rata  which  will  produce  the  'optimum  soil  pH  for 
the  crops  to  be  planted.  For  additional  information  on  sludge 
disposal,  see  Chapter  17,  Handling  and  Disposal  of  Proc- 
ess Wastes." 

14.8  RECORDS 

Records  should  be  kept  on  the  amounts  of  chemicals 
ordered  and  the  amounts  fed  Laboratory  results  should  be 
recorded  in  a  permanent  lab  book.  See  Chapter  18,  "Mainte- 
nance," for  details  on  how  to  keep  equipment  maintenance 
schedules  and  records. 


Again,  every  plant  is  different.  However,  records  will  help 
a  good  operator  be  a  better  operator 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  109. 

14.7A  What  \$  a  disadvantage  of  recirculating  sludge  back 
to  the  primary  mix  area'^ 

14.7B  How  could  you  determine  if  sludge  recirculation  will 
serve  a  useful  purpose  in  your  planf? 

14.8A  What  types  of  records  should  be  kept  regarding 
treatment  plant  chemicals? 

14.9   JAR  TESTS 

14.90  Typical  Procedures 

Approximate  amounts  of  chemicals  required  can  be  calcu- 
lated (see  Section  14.316,  "Calculation  of  Chemical  Dos- 
ages"), however,  the  best  method  of  determining  the  proper 
dosages  is  by  the  use  of  the  jar  test.  See  Chapter  11, 
"Laboratory  Procedures,"  for  details  on  the  equipment  and 
procedures  required  to  run  jar  tests. 

Cnem;cal  reagents  may  be  made  up  by  adding  one  gram 
of  reagent  to  a  liter  of  water.^^  This  will  produce  a  0.1 
percent  chemical  solution.  When  1.0  gram/liter  of  lime,  soda 
ash  or  coagulant  Is  made  up  as  the  stock  solution,  one  mL  of 
the  stock  solution  in  a  one  liter  sample  of  water  equals  one 
mg/L  dosage.  If  large  doses  of  lime  are  required,  add  10 
grams  of  lime  per  liter.  With  this  stock  solution,  one  m/.  of 
stock  solution  in  a  one  liter  sample  of  water  equals  ten  mg/L 
dosage 

Set  up  6  samples  and  estimate  the  dosage  required  by 
adding  varying  amounts  to  each  sample.  Trial  and  error  will 
put  you  in  the  "ball  park."  To  refine  the  dosage,  pick  the  best 
looking  sample  from  the  settling  properties  of  the  floe  to 
establish  the  optimum  lime  dose.  Then  do  the  same  with 
varying  amounts  of  soda  ash,  leavin^  the  Isme  dosage 
constant.  By  running  pH,  alkalinity,  and  hardness  tests  you 
can  find  the  optimum  dosages  that  give  the  desired  softened 
water  results. 

The  exact  procedures  used  to  soften  water  by  chemical 
precipitation  using  the  lime-soda  ash  process  depend  on  the 
hardness  and  other  chemical  characteristics  of  the  water 
being  treated.  A  series  of  jar  tests  are  commonly  used  to 
determine  optimum  dosages.  In  many  cases,  the  feed  rates 
dete''mmed  by  jar  tests  do  not  produce  the  exact  same 
results  in  an  actual  plant.  This  is  because  of  differences  in 
v^'ater  temperature,  size  and  shape  of  jar  as  compared  with 
plant  basins,  mixing  equipment,  and  influence  of  coagulant 
(a  heavy  alum  feed  will  neutralize  more  of  the  lime).  You 
must  remember  that  jar  test  results  are  a  starting  point.  You 
may  have  to  make  additional  adjustments  to  the  chemical 
feeders  in  your  plant  based  on  actual  analyses  of  the  treated 
water. 

Convert  the  jar  tei,t  results  to  plant  feed  rates  Always  feed 
enough  chemical  to  achieve  the  desired  results,  but  don't 
overfeed.  Over  .  .ing  is  a  waste  of  money  and  quality 
control  will  suffer. 


^5  Some  operators  add  10  grams  of  reagent  to  a  l\tei  f  water,  rhis  wn  produce  a  one  percent  solution.  One  mL  of  the  stock  solution  in  one 
liter  will  produce  a  ten  mg/L  dosage. 


86  Water  Treatment 


14.91  Examples 

Let's  set  up  some  jar  tests  to  determine  the  optimum 
dosages  for  lime  or  lime-soda  treatment  to  remove  hardness 
from  a  municipal  water  supply.  To  get  started,  add  10.0 
grams  of  hydrated  lime  to  a  one-liter  graduated  cylinder  or 
flask  and  fill  to  the  one-liter  mark  with  tap  water.  Thoroughly 
mix  this  stock  solution  in  order  to  thoroughly  suspend  all  of 
the  lime.  One  mL  of  this  solution  (which  has  t>een  thoroughly 
mixed)  in  a  liter  of  water  is  the  same  as  a  lime  dose  of  ten 
mg/L,  or  0.5  mLin  500  mL  is  still  the  same  as  a  ten  mg/L  hme 
dose. 

Set  up  a  series  of  hardness  tests  by  adding  5.0  mL,  10.0 
mL,  15.0  mL,  20.0  mL.  25.0  mL.  30.0  mL,  35.0  mL  and  40.0 
m  L  to  one-liter  (1 000  mL)  beakers  or  jars,  r  ;||  the  beakers  to 
the  1000  mL  mark  with  the  water  being  tested.  Mix  thor- 
oughly for  as  long  as  normal  mixing  will  occur  in  your  plant. 
Allow  the  precipitate  to  settle  (20  minutes  if  this  is  the  settling 
time  in  your  plant)  and  measure  the  hardness  remaining  in 
the  water  above  the  precipitate.  A  plot  of  the  hardness 
remaining  against  the  lime  dosage  will  reveal  the  optimum 
dosage.  Examination  of  Figures  14.8,  14.9  and  14.10^® 
reveals  that  the  water  of  all  three  cities  responded  differently 
to  the  increasing  lime  dosage.  City  1  (Figure  14.8)  should  be 
providing  a  lime  dose  of  100  mg/L.  The  cost  of  increasing 
the  dosage  to  150  mg/L  is  not  worth  the  slight  reduction  in 
hardness  from  110  to  100  mg/L  as  CaCOg.  Note  that  an 
overfeed  of  lime  will  actually  Increase  the  hardness. 

City  2  (Figure  14.9)  should  be  providing  a  lime  dose  of  200 
mg/L  A  dose  of  300  mg/L  will  reduce  hardness,  but  tho 
increase  in  lime  costs  is  too  great.  City  3  (Figure  14.10) 
should  be  dosing  lime  between  200  and  250  mg/L.  Note  that 
the  greater  the  lime  dose,  the  less  the  hardness,  but  the 
greater  the  quantities  of  sludge  that  must  be  handled  and 
disposed  of. 

If  lime  added  to  the  water  does  not  remove  sufficient 
hardness,  select  the  optimum  lime  dose  and  then  add 
varying  amounts  of  soda  ash.  From  Figure  14.9  we  found 
that  the  optimum  lime  dose  was  200  mg/L  (300  mg/L  would 
have  reduced  the  hardness  slightly).  Let's  take  six  one-liter 
containers  and  add  20  mL  of  our  lime  stock  solution  (a 
dosage  of  200  mg/L).  Prepare  a  stock  solution  of  soda  ash 
similar  to  our  lime  solution  by  adding  10  grams  of  soda  ash 
to  a  one-liter  container,  fill  with  distilled  water  and  mix 
thoroughly.  Add  zero,  2.5  mL  (25  mg/L  dose),  5  mL,  7.5  mL, 
1 0  mL  and  12.5  mL  to  the  one-liter  containers.  Mix  thorough- 
ly, allow  the  precipitate  to  settle  and  measure  the  hardness 
remaining  In  the  water  above  the  precipitate.  A  plot  of 
hardness  remaining  against  the  soda  ash  dosage  will  reveal 
the  desired  dosage.  We  would  like  the  final  hardnes:;  to  be  in 
the  80  to  90  mg/L  as  CaCOg  range  in  this  example. 

To  select  the  optimum  doses  of  lime  and  soda  ash. 
consider  the  items  discussed  below. 

1  Optimum  dosage  of  lime  was  based  on  increments  of  50 
mg/L.  You  should  refine  this  test  by  trying  at  least  two-10 
mg/L  increments  above  and  below  the  optimum  dose. 
From  Figure  14.8  we  found  that  100  mg/L  was  the 
optimum  dose.  Try  lime  doses  of  80,  90, 100, 110  and  120 
mg/L. 

2  Optimum  dosage  of  soda  ash  can  be  refined  by  trying 
smaller  increments  also. 


3  Try  slightly  increasing  the  actual  lime  dose  in  your  plant  to 
see  if  there  is  any  decrease  in  the  remaining  hardness.  Is 
the  decrease  in  hardness  worth  the  increobt?  in  lime 
costs? 

4.  Try  slightly  increasing  and  decreasing  both  lime  and  soda 
ash  dosages  at  your  plant  one  at  a  time,  and  evaluate  the 
results. 

5.  If  yoj  are  treating  well  water  or  a  water  of  constant 
quality,  all  you  have  to  do  to  maintain  proper  treatment  Is 
to  make  minor  adjustments  to  keep  the  system  fine 
tuned. 

6.  If  you  are  treating  water  from  a  lake  or  a  river  and  the 
water  quality  (including  temperature)  changes,  you'll  have 
to  repeat  these  procedures  whenever  the  raw  water 
quality  changes.  Water  quality  changes  of  concern  in- 
clude raw  water  hardness,  alkalinity,  pH,  turbidity  and 
temperature. 

7.  REMEMBER,  you  do  not  want  to  produce  water  of  zero 
hardness.  If  you  can  get  the  hardness  down  to  around  80 
to  90  mg/L,  that  usually  will  be  low  enough  for  most 
domestic  consumers.  When  selecting  a  target  hardness 
level  for  your  plant,  consider  the  uses  of  your  softened 
water  and  the  cost  of  softening. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  109. 

14  9A  What  items  should  be  considered  when  determining 
the  hardness  of  the  treated  water  from  a  water 
softening  plant? 

14.9B  If  lime  added  to  water  does  not  reduce  the  hardness 
of  a  water  sufficiently,  what  would  you  do? 


14.92  Calculation  of  Chemical  Feeder  Settings 

After  chemical  doses  have  been  calculated  or  determined 
from  jar  tests,  convert  the  results  to  plant  chemical  feed 
rates.  Depending  on  the  type  of  chemical  feeder,  you  may 
have  to  calculate  the  feed  rates  in  pounds  per  day,  pounds 
per  hour  or  pounds  per  m  nute.  Always  feed  enough  chemi- 
cal to  achieve  the  desired  results,  but  don't  over  feed  Over 
treating  is  a  waste  of  money  and  quality  control  will  suffer. 

EXAMPLE  4 

The  optimum  lime  dosage  from  the  jar  tests  is  230  mg/L.  If 
t;ie  flow  to  be  treated  is  6  MGD,  what  is  the  feeder  setting  in 
pounds  per  day  and  the  feed  rate  in  pounds  per  minute? 


16  These  figures  were  adapted  from  an  article  titled,  "Use  of  Softening  Curve  for  Lime  Dosage  Control, '  by  Michael  D  Curry  °  E  vhich 
appeared  in  THE  DIGESTER/OVER  THE  SPILLWA  Y,  published  by  the  Illinois  Environmental  Protection  Agency.  '  ' 

ERIC  98 


90  Water  Tri^atment 


Known  Unknown 
Lime  Dose.  mg/L  =  230  mg/L     1 .  Feeder  Setting,  lbs/day 
Flow,  MGD         =  6  MGD        2.  Feed  Rate,  Ibs/min 

1 .  Calculate  the  feeder  setting  In  pounds  per  day 

''Ibs/da^y^^^'"^'  =         MGD)(L,me.  mg/L)(8.34  Ibs/gal) 
-  (6  MGD)(230  mg/L)(8.34  ibs/gal) 
=  11,509  lbs/day 

2.  Calculate  the  feod  rate  in  pounds  per  minute. 
Feed  Rate.      ^Feeder  Setting,  lbs/day 

(6u  min/hr)(24  hr/day) 

n. 509  lbs/day 
(60  min/hr)(24  hr/day) 
=  8.0  Ibs/min 

When  the  calculated  feed  rate  of  e^ght  pounds  of  lime  per 
minute  is  put  into  the  plant  process,  observations  and  tests 
will  determine  if  optimum  levels  are  met.  In  many  instances, 
jar  tests  and  actual  plant  feed  rates  do  not  agree  exactly. 
This  Is  because  of  temperature,  size  and  shape  of  jars  vs. 
size  and  shape  of  plant  facilities,  mixing  time,  and  Influence 
of  the  coagulant  (a  heavy  alum  feed  would  neutralize  more 
of  the  lime).  Jar  tests  are  merely  Indicators  or  a  point  of 
beginning. 

If  underfeeding  results,  reactions  will  not  be  complete  and 
the  results  will  be  undertreated  water  having  a  hardness 
higher  than  that  desired. 

If  overfeeding  results,  chemicals  are  being  wasted.  Also,  it 
IS  quite  possible  to  have  excessive  calcium  in  the  water  This 
results  in  unstable  conditions  which  cause  buildup  on  the 
sand  grains  and  the  interior  of  the  water  mams.  This  is 
where  the  stability  test  enters  the  p  jture  (refer  to  Section 
14.5.  "Stability"). 

The  above  discussion  has  cealt  with  establishing  the 
proper  lime  feed.  The  same  process  would  be  used  to 
determine  the  soda  ash  requirements  if  you  are  removing 
noncarbonate  hardness  Set  up  the  lime  feeds  as  discussed. 
Pick  the  optimum  dosage.  Then  set  up  another  series  of  jars 
using  the  same  lime  feed  rate  in  all  jars.  Now,  vary  the  soda 
ash  feed  rate. 

EXAMPLE  5 

How  much  soda  ash  is  required  (pounds  per  day  and 
pounds  per  minute)  to  remove  50  mg/L  noncarbonate  hara- 
ness  as  CaC03  from  a  flow  of  6  MGD'? 


Known 


Unknown 


Noncarbonate  Hardness       ^  cq         l  Feeder  Setting,  lbs/ 

Removed.  mg/L  as  CaC03  ^'  day 

Flow.  MGD  -  6  MGD    2  Feed  Rate,  lbs/mm 

1  Calculate  the  soda  ash  dose  in  milligrams  per  liter.  See 
Section  14  316.  "Calculation  of  Chemical  Dosages"  for 
the  following  formula. 

Soda  Ash.  ^ ,  Noncarbonate  Hardness,  wi/,"iinn\ 
mg/L       ^       mg/LasCaC03  Mi^Wiuuj 

=  (50  mg/L)(106/l00) 
=  53  mg/L 

2.  Determine  the  feeder  setting  in  pounds  per  day. 

^^Ibs/da^^"'"^'  "         MGD)(Soda  Ash,  mg/L)(8.34  ibs/gal) 
-  (6  MOD)  53  mg/L){8.34  Ibs/gal) 
=  2652  lbs/day 

3  Calculate  the  soda  ash  feed  rate  m  pounds  per  minute. 
Feed  Rate.  ^  Feeder  Setting,  lbs/day 
Ibs/min  min/hr)(24  hr/day) 

2652  lbs/day 


ERIC 


105 


(60  min/hr)(24  hr/day) 
=  1.8  Ibs/min 

After  you  determine  the  proper  feed  rates  and  implement 
them,  if  you  are  treating  well  water  or  other  water  of 
constant  quality,  all  you  have  to  do  to  maintain  proper 
treatment  is  make  minor  adjustments  to  keep  the  system 
fine  tuned. 

On  the  other  hand.  If  you  treat  a  river  or  lake  supply 
subject  to  constant  and  frequent  changes  in  water  quality. 
It's  an  entirely  different  set  of  circumstances.  Until  you  learn 
from  experience  to  judge  the  chemical  changes  necessary 
by  the  fluctuations  in  raw  water  hardness,  alkalinity  and 
tujfc.dity.  you  almost  nave  to  check  yourself  daily  by  the  jar 
test  method. 

When  your  treatment  process  does  not  work  properly,  the 
first  thing  to  check  is  whether  or  not  the  feeder  is  feeding 
properly  If  it  is.  the  next  step  is  to  check  your  source  water 
quality  Generally,  one  of  these  two  will  be  the  cause  of  your 
problem 

QUESTIONS 

Write  your  answers  ir.  a  notebook  and  thrn  compare  your 
answers  with  those  on  page  109. 

14  90  Why  should  the  overfeeding  of  chemicals  be  avoid- 
ed'? 

14  9D  What  should  be  the  lime  feeder  setting  in  pounds  per 
day  to  treat  a  flow  of  ?  MGD  when  the  optimum  lime 
dose  IS  160  mg/L'? 

14  9E  How  much  soda  ash  is  required  in  pounds  per  day  to 
remove  40  mg/L  of  noncarbonate  hardness  from  a 
flow  of  2  MGD'? 


Softening  91 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  14.  SOFTENIN^G 

(Lesson  1  of  2  Lessors) 


At  the  eno  of  each  lesson  in  this  chapter  you  will  find  some 
discussion  and  review  questions  that  you  Siiculd  work 
before  continuing.  The  purpose  of  these  questions  is  to 
indicate  to  you  how  veil  you  understand  the  material  in  the 
lesson.  Write  the  answers  to  these  questions  in  your  note- 
book before  continuing 

1.  Why  should  water  be  softened'? 

2.  What  are  the  benefits  of  softening  water  in  addition  to 
hardness  removal? 

3  Why  IS  settlea  water  recarbonated  after  the  precipitation 
of  calcium  carbonate? 

4  What  are  the  advantages  of  using  liquid  caustic  to 
soften  water? 

Why  should  quicklime  never  be  stored  close  to  cor.nbus- 
tible  material? 

6.  How  can  operators  protect  themselves  from  lime'? 

7.  Why  IS  the  stability  of  a  water  important? 

8.  Why  IS  a  p,iSte-type  slaker  dangerous? 

9.  Why  should  you  avoid  using  the  same  conveyor  or  bin 


for  alternately  handling  both  quicklime  and  one  of  the 
coagulants  containing  water,  such  as  alum? 

10  Why  IS  sludge  sometimes  recirculated  back  into  the 
primary  mix  area  of  conventional  plants? 

1 1  When  running  jar  tests,  how  would  you  deterr.iine  the 
optimum  dosage  for  a  coagulant,  lime  and  soda  ash? 

12  When  your  lime-soda  ash  softening  plant  does  not 
perform  properly,  what  is  the  first  thing  you  should 
check'? 


CHAPTER  14.  SOFTENING 

ion  Exchange  Softening  by  Marty  Reynolds 

(Lesson  2  of  2  Lessons) 


14.10   DESCRIPTION  OF  ION  EXCHANGE  SOFTENING 
PROCESS 

The  lerm  "Zeolite"  is  most  often  associ  ited  with  sodium 
lon  exchangers  and  snould  be  considered  lO  mean  the  same 
as  the  term  ion  exchange.  Most  ion  exchange  units  in  use 
today  use  sulfonated  polystyrene  resins  as  the  exchange 
media,  lon  exchange  softening  can  be  defined  as  exchang- 
ing hardness-causing  ions  (calcium  and  magnesium)  for  the 
sodium  ions  that  are  attached  to  the  ion  exchange  resins  to 
create  a  soft  water. 


The  treatment  plant  operator  should  be  aware  of  the  three 
basic  types  of  softeners  on  the  market. 

1  An  upflow  unit  in  which  the  water  enters  from  the  bottom 
and  flows  up  through  the  ion  exchange  bed  a^J  out  the 
top 

2  A  unit  which  is  constructed  and  operated  like  a  gravity 
rapid  sand  filter  The  water  enters  the  top,  flows  down 
through  the  ion  exchange  bed  and  out  the  bottom. 

3.  The  pressure  downflow  ion  exchange  softener,  which  is 
the  most  common  will  be  covered  by  this  chapter.  See 
Figures  14  11  and  14.12.  Pressure  filters  m../  be  either 
horizontal  or  vertical  units.  Vertical  units  are  preferred 
because  there  is  less  chance  of  short-circuiting. 

To  help  explain  the  construction  and  activity  that  occurs  in 
an  ion  exchanger,  let's  compare  it  to  a  pressure  filter.  The 
water  enters  the  unit  through  an  inlet  distributor  located  m 
the  top;  it  IS  forced  (usually  pumped)  down  through  a  bed  of 
some  type  of  media  into  an  underdrain  structure.  From  the 
underdrain  structure,  the  treated  water  flows  out  of  the  unit 
and  into  storage  or  into  the  distribution  system. 

The  flow  pattern  through  a  filler  and  r  ftener  are  similar, 
the  key  difference  being  the  action  that  takes  place  in  the 
media  or  bed  of  each  unit.  The  filter  bed  may  be  considered 

1^G 


92  Water  Treatment 


VERTICAL  SOFTENER  TANK 

 "  DIAMETER 

 "  SIDE  SHELL  HEIGHT 

  R&l  WR 


AIR  RELEASE  LINE 


"  FILTER  SAND.  SIZE  TO  MM. 

"  GRADED  GRAVEL.  SIZE  l/4"x*l0 
"  GRADED  GRAVEL.  SIZE  1/2" x  1/4" 
"  GRADED  GRAVEL.  SIZE  3/4"  x  1/2" 
"GRADED  GRAVEL,  SIZE  1 1/2" X 3/4" 


UK">ERDRAIN 


STANDARD  SOFTENER 


UNDERDRAIN:- 

RWDLY    SUPPORTED    PLATE    OVER     ICO  % 
FLTER  AREA    WITH    STAINLESS  STEEL 
BAFFLE  ASSEMBLIES. 


ZEOLITE- 


.CUBIC  FEET. 


SUPPORTING  GRAVEL:-. 


'GRADED. 


STAINLESS  STEEL 
BAFFLE  ASSEMBLY 


Figure  14. 1 1  Pressure  downflow  ion  exchange  softener 

(Permission  ol  General  Filter  Company) 


ERIC 


107 


j  POWER  SUPPLY 
tllO  VOLT  60  CYCLE 
l-PHASE  SERVICE 


CONTROL  PANEL 
CYCLE  TIMERS 

INTERLOCK 
BRINE  CONTROL 


-  DIAPHRAGM  VALVE 
CONTROL  LINES 


ERLC 


08 


Figure  14, 12  Semhautomatic  controls  for  ion  exchanger 

(Permission  of  General  Filter  Company) 


in;) 


0) 

o 

;» 

3* 

U3 


94  Water  Treatment 


an  adsorption  and  mechanical  straining  dev.ce  used  to 
remove  suspended  solids  from  the  water.  The  bed  usually 
consists  of  sand,  anthracite  (crushed  coal)  or  a  combination 
of  both.  Once  the  bed  becomes  saturated  with  the  insoluble 
material  (usually  clay,  suspended  solids  and  iron  manga- 
nese hydroxide),  the  filter  is  taken  out  of  service,  back- 
washed  and  returned  to  service.  This  pressure  filter  will 
continue  to  operate  until  the  condition  reoccurs  and  the 
procedure  is  repeated. 

The  bed,  media  or  resin  in  an  ion  exchange  softener, 
however,  is  much  more  complex.  This  resm  serves  as  a 
medium  In  which  an  ion  exchange  takes  place.  As  hard 
water  is  oassed  through  the  resin,  the  sodium  ions  on  the 
resin  are  exchanged  for  the  calcium  and  magnesium  ions  (in 
the  case  of  sodium  exchange  re^^insi).  The  sodium  ions  are 
released  from  the  exchange  resin  and  remain  in  the  water 
which  flows  out  of  the  softener.  The  calcium  and  magnesium 
ions,  however,  are  retained  by  the  resin.  The  softener 
effluent  is  free  from  calcium  and  magnesium  ions  and 
therefore  Is  softened  (Figure  14.13). 


Once  a  softener  has  exchanged  all  of  its  sodium  ions  and 
the  res.n  is  saturatef^  with  calcium  end  magnesium,  it  will  no 
longer  produce  SDft  water.  At  this  time  the  unit  must  be 
taken  out  of  service,  the  calcium  and  magnesium  removed 
trom  the  res'n  by  exchange  with  sodium  ions.  This  process 
IS  referred  to  as  a  regeneration  cycle. 

In  a  regeneration  cycle,  the  calcium  and  magnesium  ions 
that  have  been  retained  by  the  resin  must  be  removed  and 
the  sodium  ions  restored.  In  order  for  the  exchange  to  take 
place,  the  resm  must  hold  all  ions  loosely.  If  the  calcium  and 
magnesium  ions  cannot  be  removed,  the  resm  will  not 
accept  the  addition  of  new  sodium  ions  that  are  necessary 
for  additional  softening 

Salt  in  the  form  of  a  concentrated  brme  solution  is  used  to 
regenerate  (recharge)  the  ion  exchange  resm.  When  salt  is 
added  to  water  it  changes  into  or  ionizes  to  form  sodium 
cation  (Na"*")  and  chloride  anions  (Cl~).  When  the  brme 
solution  IS  fed  into  the  resm,  the  sodium  cations  are  ex- 
changed for  calcium  and  magnesium  cations.  As  the  brine 


PLUG  FLOW-PISTON  EFFECT 
HARDNESS  APPLIED 

Ca^+  Mg++ 


PLUG  FLOW-PISTON  EFFECT 
HARDNESS  APPLIED 
Ca^+  Mg+^ 


Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na- 

Na^ 

[1] 

EXCHANGE  RESIN 
PRIOR  TO  SOFTENING 
(AFTER  REGENERATION) 


Ca^^ 

Mg^^ 

Ca^^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

Na^ 

[2] 

Na^  AND  SOFT  WATER  EXCHANGE 
RESIN  AFTER  START  OF  SOFTENING  CYCLE 


Ca^^ 

Mg++ 

Ca^^ 

Ca^^ 

Ca^^ 

Mg^^ 

Mg^^ 

Ca^^ 

Ca^^ 

Ca^^ 

Na^ 

Ca^^ 

Na^ 

Na^ 

Na^ 

[3] 

Na^  AND  SOFT  WATER  EXCHANGE 
RESIN  DURING  SOFTENING  CYCLE 


Mg** 

Ca** 

Ca** 

Ca** 

Mg** 

Mg** 

Ca** 

Ca** 

Ca** 

Mg** 

Mg** 

Ca** 

Ca** 

Mg** 

[4] 

EXCHANGE  RESIN  EXHAUSTED 
(ALL  SOFTENING  CAPACITY  LOST- 
READY  TO  REGENERATE.  SEE  [1]) 


ERIC 


Fig.  14.13  Ion  exchange  resin  condition  during  softening  cycle 

110 


Softening  95 


solution  travels  down  through  the  resm,  the  sodium  cations 
are  attached  to  the  resin  while  the  calcium,  magnesium  and 
chloride  (from  the  salt)  ions  flows  to  waste  After  the 
regeneration  has  taken  place,  the  bed  if  ready  to  be  placed 
in  service  again  to  remove  calcium  and  magnesium  by  »on 
exchange. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answeis  with  those  on  page  110. 

14.1  OA  List  the  three  basic  types  of  softeners  on  the 
market. 

14  10B  What  happens  during  tfie  regeneration  cycle  of  an 
ion  exchange  sofiener? 


14.11  OPERATIONS 

Many  factors  influence  the  procedures  usee  to  operate  an 
ion  exchange  unit  and  the  efficiency  of  the  softening  proc- 
ess. These  factors  include- 

1.  Characteristics  of  the  ion  exchange  resin, 

2.  Quality  of  the  source  v^ater. 

3.  Rate  of  flow  applied  to  the  softener, 

4.  Salt  dosage  during  regenerjtion, 

5.  Bnne  concentration,  and 

6.  Brine  contact  time. 

Each  ion  exchange  softener,  regardless  of  manufacturer, 
will  have  at  least  four  common  stages  of  operation.  These 
stages  are  listed  below  and  will  be  explained  as  each  occurs 
in  the  softener  operation  (see  Figure  14.14). 

1.  Service. 

2.  Backwash. 

3.  Brine,  and 

4.  Rinse. 


14.110  Service 

The  service  stage  of  each  unit  is  where  the  actual  soften- 
ing of  the  water  occurs.  Hard  water  is  forced  into  the  top  of 
the  unit  and  allowed  to  flow  down  through  the  exchange 
resin.  As  this  takes  pla  je.  the  calcium  and  magnesium  ions 
exchange  with  sodium  on  the  reoin.  The  sodium  ions  are 
released  into  the  water  and  the  exchange  capacity  of  the  unit 
IS  slowly  exhausted. 


The  length  of  each  service  stage  is  dependent  on  several 
factors,  source  water  hardr.ess  is  a  mam  consideration.  The 
harder  the  water,  the  more  calcium  and  magnesium  must  be 
removed  to  reach  a  level  of  zero  hardness.  Simply  stated, 
the  harder  the  water,  the  less  water  you  can  treat  before  the 
resin  becomes  exhausted.  As  long  as  the  design  flow  for  the 
ion  exchange  unit  is  not  exceeded,  changes  in  the  hardness 
of  the  source  water  may  be  automatically  adjusted  for  in  the 
ton  exchange  unit.  The  effluent  from  the  unit  usually  will  have 
zero  hardness  until  the  unit  needs  regeneration.  If  the  total 
dissolved  solids  (TDS)  in  the  water  supply  is  fairly  high 
(above  500  mg/L).  there  may  be  some  leakage.  If  a  high  TDS 
water  has  a  high  sodium  content,  the  sodium  may  hinder  the 
process  by  causing  a  local  exchange  on  the  media  of 
calcium  and  magnesium  (hardness  leakage)  for  some  of  the 
sodium  The  amount  of  hardness  leakage  depends  on  the 
TDS  and  the  salt  dosage  (percent  salt)  used  for  regenera- 
tion. 

Other  factors  involved  are  the  size  of  the  softener  and  the 
exchange  capacity  of  the  resin  Softeners  can  vary  in  size 
from  a  few  cubic  feet  to  several  hundred  cubic  feet.  The  size 
of  the  unit  will  generally  be  consistent  with  regard  to  the 
overall  treatment  plant  design.  In  other  words,  the  softener 
should  be  capable  of  producing  enough  softened  water  so 
that  the  mix  or  blend  of  softened  and  upsoftened  water  will 
produce  a  treated  water  with  the  desired  level  of  hardness. 

The  exchange  resin  will  also  vary  in  its  removal  capacity. 
There  are  many  types  of  strong  acid  cation  exchange  resins 
on  the  market  today.  Most  will  range  in  capacity  from  20.000 
to  30.000  grains  of  hardness  removal  per  cubic  foot  (0.01 1  to 
0.016  kg/cu  m)  resin.  The  removal  ability  of  the  resin  is 
usually  expressed  in  grains  of  hardness  removal  per  cubic 
foot  of  material  or  resin. 

The  source  water  hardness,  size  and  the  removal  capacity 
of  the  resin  will  determine  the  amount  of  water  that  can  be 
treated  before  the  softener  must  be  regenerated.  Vith  a  few 
Simple  calculations,  an  operator  can  determine  the  softening 
capacity  of  the  units.  Calculations  and  examples  will  be 
given  at  the  end  of  the  chapter.  See  Example  8  in  Section 
14  18,  "Ion  Exchange  Arithmetic." 

14.111  Backwash 

The  second  stage  of  the  ion  exchange  softener  process  Is 
the  backwash.  In  this  stage,  the  unit  is  taken  out  of  service 
and  the  flow  pattern  through  the  unit  is  reversed.  The 
purpose  of  this  is  to  expand  and  clean  the  resin  particles  and 
also  to  free  any  material  such  as  iron,  manganese  and 
particulates  that  might  have  been  rem  )ved  during  the  soft- 
ening stage.  The  backwash  water  entering  the  softener  at 
the  beginning  of  this  stage  should  be  applied  at  a  slow 
steady  rate  If  the  water  enters  the  unit  too  quickly,  it  could 
create  a  surge  in  the  resin  and  wash  it  out  of  the  unit  with  the 
water  going  to  waste. 

Ideal  bed  expansion  dunng  the  softener  backwash  snould 
be  75  to  100  percent.  In  other  words,  when  the  unit  is 
backwashed.  the  resm  should  expand  to  occupy  a  volume 
from  75  to  100  percent  greater  than  when  in  normal  service. 
An  example  of  this  would  be  an  ion  exchange  softener  with 
24  inches  (60  cm)  of  resm  whi'e  in  service.  When  the  unit  is 
backwashed.  the  resin  should  expand  to  48  inches  (120  cm) 
for  a  1 00  percent  expansion  of  the  bed.  As  the  bed  expands 
a  shearing  action  due  to  the  backwash  water  and  some 
scrubbing  action  will  free  any  material  that  might  have 
formed  on  the  resm  particles  during  the  softening  stage. 

During  the  backwash  a  small  amount  of  resm  could  be 
lost.  This  ^mount,  however,  should  be  minimal  and  you 


96  Water  Treatment 


OPERATIOM 

VALVE  NUMBER 

1 

2 

3 

4 

5 

6 

7 

SERVICE 

OPEN 

CLOSE 

CLOSE 

OPEN 

CLOSE 

CLOSE 

CLOSE 

BACK  WASH 

CLOSE 

OPEN 

CLOSE 

CLOSE 

OPEN 

CLOSE 

CLOSE 

BRINE 

CLOSE 

CLOSF 

OPEN 

CLOSE 

CLOSE 

OPEN 

CLOSE 

RINSE 

OPEN 

CLOSE 

CLOSE 

CLOSE 

CLOSE 

CLOSE 

OPEN 

Fig.  14.14   Valve  positions  for  each  stage 
of  ion  exchange  softener  operation 

(Permission  of  General  Filter  Company) 

^  •  112 


Softening  97 


should  cfieck  the  backwash  effluent  at  different  intervals  to 
insure  that  the  resin  is  not  being  lost.  A  glass  beaker  can  be 
used  to  catch  a  sample  of  ilie  effluent  while  the  unit  is 
backwashing  A  trace  amount  of  resin  should  cause  no 
alarm,  but  a  steady  loss  of  resm  could  indicate  a  probi->m  m 
the  unit  and  the  cause  should  be  located  and  corrected  as 
soon  as  possible.  Too  much  loss  of  resin  may  be  caused  by 
an  improper  freeboard  on  the  tank  or  wash  troughs. 

The  backwash  duration  and  flow  rate  will  vary  depending 
on  the  manufacturer  and  the  type  ar  j  size  of  resin  used  and 
the  water  temperature 

14.112  Brine 

The  third  stage  is  most  often  termed  the  regeneration  or 
brine  stage  At  this  point,  the  sodium  ion  concentration  of  the 
resm  is  recharged  by  pumping  a  concentrated  brine  solution 
onto  the  resm.  The  solution  is  allowed  to  circulate  through 
the  unit  and  displace  all  water  from  the  resm  in  order  to 
provide  full  contact  between  the  brine  solution  and  the  resm. 

Most  treatment  plants  use  a  bnne  solution  to  regenerate 
their  softening  units.  The  optimum  brine  concentration  com- 
mg  in  contact  v/ith  the  ion  exchange  resm  is  around  10  to  14 
percent  sodium  chloride  solution  Concentrated  bnne  is  only 
used  when  the  water  v  thin  the  softener  tank  serves  as  the 
dilution  water  A  26  percent  bnne  solution  (fully  concentrated 
or  saturated)  causes  too  great  of  an  osmotic  shock  on  the 
■on  exchange  resm  and  can  cause  it  to  break  up.  The  salt 
dosage  used  to  prepare  the  brine  solution  is  one  of  the  most 
important  factors  affecting  the  ion  exchange  capacity  and 
ranges  nom  5  to  15  pounds  of  salt  per  cubic  foot  (80  to  240 
kg/cu  m)  of  resm.  See  EXAMPLE  10  on  page  104  for 
procedures  on  how  to  calculate  the  salt  dosage  and  gallons 
of  brine  solution  required.  Brine  concentrations  less  than 
saturated  require  longer  contact  time  and  more  solution 
must  be  applied  to  the  unit  to  achieve  a  successful  regenera- 
tion. 

The  regeneration  stage  of  the  softener  is  very  important 
and  the  operator  should  be  certain  it  is  properly  carried  out. 
In  the  regeneration  stage,  the  sodium  ions  present  in  the 
bnne  solution  are  exchanged  with  the  calcium  and  magne- 
sium .ons  on  the  resm.  The  ions  on  the  resm  were  ex- 
changed during  the  service  or  softening  stage.  The  regen- 
eration rate  is  usually  one  to  two  GPM  per  cubic  foot  (2.2  to 
4  4  liters  per  second  per  cubic  meter)  of  resm  for  the  first  53 
minutes  and  then  three  to  five  GPM  per  cubic  foot  (6.6  to  1 1 
liters  per  second  per  cubic  meter)  for  the  last  five  minutes  of 
fast  dram.  If  the  regeneration  process  is  performed  correct- 
ly, the  result  is  a  oed  that  is  completely  recharged  with 
sodium  ions  and  will  again  soften  water  when  the  unit  is 
returned  to  service 


ERLC 


14.113  Rinse 

The  fourth  and  final  stage  of  softener  operations  is  ♦he 
nnse  stage  After  adequate  contact  time  has  been  allowed 
between  the  brine  solution  and  resm,  a  clear  rinse  is  applied 
from  the  top  of  the  unit  to  remove  the  waste  products  and 
excess  brine  solution  from  the  softener.  The  flow  pattern  is 
very  similar  to  the  service  stage  except  that  the  softener 
effluent  goes  to  waste  instead  of  storage.  The  waste  dis- 
charge contains  high  concentrations  of  calcium  and  magne- 
sium chloride  Most  rinse  stages  will  last  between  20  and  40 
minutes,  depending  on  the  size  of  the  unit  and  the  manufac- 
ture See  Section  14. 14.  "Disposal  of  Spent  Brine,"  for 
procedures  on  how  to  oispose  of  the  waste  discharge. 

Again,  the  operator  should  pay  close  attention  to  the 
softener  while  it  rinses  The  rinse  must  be  long  enough  to 
remove  the  heavy  concentration  of  waste  from  the  unit.  If  the 
rinse  is  not  of  the  correct  length  and  the  unit  returns  to 
service,  g  salty  taste  will  be  very  noticeable  in  the  softener 
effluent  Taste  the  waste  effluent  near  the  end  of  the  nnse 
stage  to  determine  if  the  majority  of  chloride  ions  have  been 
removed.  The  chloride  lon  concentration  may  also  be  meas- 
ured by  titration  as  outlined  in  Chapter  21,  "Advanced 
Laboratory  Procedures  or  by  measunng  the  conductivity  of 
the  water  If  the  water  still  has  a  strong  salty  taste  or 
excessive  chloride  ions  are  present,  check  the  nnse  rate  and 
timer  settings.  The  unit  may  need  adjustment  to  increase  the 
duration  of  the  nnse  stage 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  11^. 

14  11A  What  IS  the  mam  consideration  in  determining  the 
length  of  the  service  stage  of  an  ion  exchange 
softener'^ 

14  11B  What  IS  the  purpose  of  the  backwash  stage  of  an 
ion  exchange  softener'? 

14  lie  How  are  ion  exchange  softeners  regenerated'? 

14  11D  Where  does  the  softener  effluent  go  dunng  the 
nnse  stage'? 

14.12   CONTROL  TESTING  OF  ION  EXCHANGE 
SOFTENERS 

In  most  small  treatment  plants,  the  operator  has  to  per- 
form many  jobs  and  may  not  always  have  time  to  monitor  the 
softening  units  js  they  should  be  monitored.  If  a  few  simple 
test  procedures  are  learned  and  carried  out  on  a  regular 
basis  the  operator  can  ^eel  confident  the  ion  exchange  units 
are  operating  properly.  Control  tests  the  operator  should 
perform  are  listed  in  this  section. 

1.  Softener  Influent 

Be  aware  of  the  iron  and  manganese  levels  entering 
the  softener.  These  levels  should  be  kept  to  a  minimum  to 
prevent  fouling  of  the  media  bed  as  the  unit  will  remove  a 
certain  amount  of  iron  and  manganese  before  becoming 
plugged.  Insoluble  particles  of  iron  and  manganese  will 
plug  the  filter  media.  Soluble  ionic  iron  (Fe^^)  and  manga- 
nese (Mn^^)  will  exchange  onto  the  media  and  will  not  be 
fully  removed  by  regeneration.  If  the  source  water  enter- 
ing the  plant  is  high  in  iron  and  manganese,  proper 
oxidation  and  filtration  of  the  water  BEFORE  the  softener 
should  reduce  the  levels  and  prevent  problems  from 
developing  in  the  softeners. 

t  1'3 


98  Water  Treatment 


Monitor  source  water  hardness  on  a  routine  basis. 
Generally,  hardness  will  not  vary,  but  if  it  changes,  you 
Will  need  to  adjust  the  amount  of  water  treated  by  each 
softener  before  the  media  becomes  exhaustec'  and  the 
unit  must  be  regenerated 

2.  Softener  Effluent 

At  the  end  of  a  regeneration  stage,  as  the  unit  goes 
back  into  service,  check  the  effluent  for  hardness  This 
one  test  will  tell  you  if  the  regeneration  of  the  softener  has 
been  properly  conducted.  Allow  a  few  minutes  to  ensure 
that  all  of  the  rinse  vater  in  the  unit  has  been  purged 
(removed).  Run  a  hardness  test  on  the  effluent  side  of  the 
unit.  The  results  should  indicate  a  water  of  zero  hard- 
ness. Several  test  kits  are  available  on  the  market  today 
that  are  fairly  quick  ar.i  simple  to  use  to  measure  water 
hardness. 

14.13    LIMITATIONS  CAUSED  BY  IRON  AND 
MANGANESE 

Ion  exchange  units  are  very  versatile.  The  primary  pur- 
pose of  the  unit  is  to  remove  calcium  and  magnesium  from 
the  water  thus  making  the  water  soft.  Ion  exchange  soften- 
ers, however,  will  also  remove  iron  and  manganese  in  either 
the  soluble  or  precipitated  form.  If  this  occurs,  the  iron  and 
manganese  will  seriously  affect  the  life  of  the  exchange 
capacity  of  the  resin.  If  water  high  in  iron  and  manganese  is 
applied  to  the  ion  exchange  resin  for  very  long,  iron  fouling 
or  the  loss  of  exchange  capacity  will  result. 

When  *he  softeners  remove  iron  in  the  ferrous  (soluble)  or 
ferric  (solid)  form,  the  two  problems  discussed  below  could 
result 

1  If  water  with  iron  In  the  ferrous  form  is  applied  to  the 
softener,  the  resin  will  remove  the  iron  from  the  water. 
The  iron  can  be  retained  on  the  surface  of  the  resin  or  is 
sometimes  captured  deep  inside  the  resin  itself.  As  this 
happens,  the  resin  or  bed  will  develop  an  orange  or  rusty 
appearance.  I.'  the  resin  becomes  iron  coated,  the  effi- 
ciency of  the  softener  will  bP  reduced  greatly. 

2.  The  second  problem  associated  with  high  iron  levels  is  a 
plugging  or  clogging  of  the  resin  bed.  When  water  con- 
taining iron  in  the  ferric  form  (solid)  is  applied  to  the  unit,  it 
will  act  like  a  filter  and  strain  the  iron  from  the  water, 
leaving  the  iron  trapped  in  the  bed.  If  high  iron  loadings 
continue,  the  upper  layer  of  the  bed  could  become 
plugged,  forcing  the  water  to  channel  or  short-circuit 
through  the  bed.  The  result  is  incomplete  contact  be- 
tween the  water  and  media  thus  creating  hardness  leak- 
age and  loss  of  softening  efficiency. 

IRON  AND  MANGANESE  MUST  BE  REDUCED  TO 
THEIR  LOWEST  POSSIBLE  LIMITS  BEFORE  APPLYING 
WATER  TO  THE  SOFTENER.  Oxidation  of  iron  and 
manganese  (see  Chapter  12.  "Iron  and  Manganese  Con- 
trol") BEFORE  applying  water  to  ion  exchange  units  is 
very  helpful.  You  should  also  be  aware  of  the  chlorine 
levels  applied  to  the  softening  units  Normal  chlorine 
dosages  will  not  present  a  problem,  but  high  residuals 
could  damage  the  resin  and  reduce  its  life  span. 


14.14    DISPOSAL  OF  SPEN"^  BRINE 

One  of  the  larg'^st  problems  associated  with  the  design 
and  operation  of  ion  exchange  softening  plants  is  the 
disposal  of  the  softener  waste. 


The  waste  discharge  from  softeners  consists  mostly  of 
calcium,  magnesium  and  sodium  chlorides.  These  by-prod- 
ucts are  corrosive  to  material  they  contact  and  possess 
varying  ;oxic  levels  in  relationship  to  the  environment. 

Many  water  treatment  plants  discharge  spent  brine  into 
nearby  sewers  This  procedure  may  be  approved  if  the 
downstream  wastewater  treatment  plant  and  receiving  wa 
ters  can  handle  the  brine.  Usually  the  water  treatment  plant 
must  have  some  type  of  holding  tank  to  store  the  spent 
bnne  The  brine  is  slowly  discharged  into  the  sewer  at  a  rate 
which  will  not  upset  (or  be  toxic  to)  the  biological  treatment 
processes  at  the  wastewater  treatment  plant  Also  the  salt 
level  in  the  effluent  from  the  wastewater  treatment  plant 
must  not  adversely  impact  the  aquatic  life  in  the  receiving 
waters  nor  cause  a  violation  of  the  wastewater  treatment 
plant's  NPDES  PERMlT^"^ 

Some  water  treatment  plants  mcy  be  issued  an  NPDES 
Permit  to  discharge  spent  brine  into  receiving  waters.  This 
could  happen  only  if  the  flow  in  the  receiving  waters  was 
very  high  (plenty  of  dilution)  and  the  flow  of  spent  brine  was 
very  low  A  holding  tank  would  be  needed  for  the  spent  brine 
and  the  bnne  could  be  discharged  very  slowly.  The  receiving 
waters  would  have  to  be  monitored  to  be  sure  that  the 
discharge  of  bnne  will  not  cause  a  significant  increase  m  the 
level  of  bnne 

Sanitary  landfills  also  may  be  an  acceptable  means  of 
disposing  of  spent  bnne  See  Chapter  17.  'Handling  and 
Disposal  of  Process  Wastes."  for  additional  information. 

Each  lon  exchange  treatment  plant  probably  has  only  one 
approved  method  of  waste  disposal.  Very  few  options  are 
available  to  plants  discharging  this  type  of  waste.  Alternate 
waste  disposal  methods  available  for  spent  bnne  are  cov- 
ered in  Chapter  17.  "Handling  and  Disposal  of  Process 
Wastes  ' 


^7  NPDES  Permit,  national  Pollutant  Discharge  Bhmination  System  permit  is  the  regulatory  agency  document  issued  by  either  a  federal  or 
state  agency  which  is  designed  to  control  all  discharges  of  pollutants  from  point  sources  m  U,S,  waterways,  NPDES  permits  regulate 
discharges  into  navigable  waters  from  all  point  sources  of  pollution,  including  industries,  municipal  treatment  plants,  large  agricultural 
^  feed  lots  and  return  irrigation  flows. 

ERIC 


Softening  99 


The  operator  needs  to  ',2  aware  of  the  seriousness 
involved  with  softener  waste.  If  a  problem  develops  at  the 
treatment  plant,  the  operator  should  be  working  with  the 
agency  in  the  area  that  governs  waste  disposal  as  several 
considerations  must  be  studied  when  changsng  a  disposal 
method 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
ansvi/ers  with  those  on  page  110. 

14  12A  Which  water  quality  indicators  should  be  monitored 
in  the  effluent  of  an  ion  exchange  softener*? 

14  13A  What  happens  when  high  chlorine  residual  levels 
are  applied  to  the  softening  units'? 

14.14A  Why  is  the  disposal  of  spent  brine  a  problem*? 

14.15  MAINTENANCE 

Most  of  the  ion  exchange  water  softening  equipment  on 
the  market  today  is  fully  automated  (Figure  14.12).  The 
reason  for  most  of  this  automation  is  to  reduce  the  time  an 
operator  must  spend  with  each  unit.  Automation  is  fine  for 
operational  control,  but  it  does  not  mean  a  unit  is  mainte- 
nance free.  Systems  like  this  have  a  tendency  to  lead 
operators  astray.  A  smail  routine  maintenance  item  can  go 
unnoticed  until  it  becomes  a  full  scale  problem  if  the  opera- 
to*  does  not  run  a  regular  maintenance  schedule  on  the 
equipment.  For  example,  most  valves  on  ion  exchange  units 
arc  pneumatic  or  are  equipped  witn  some  type  of  self- 
operating  device  (valve  actuators).  This  does  not  mean, 
however,  the  valve  will  operate  each  time  it  is  required  to  do 
so  A'.thout  a  regular  examination  and  overhaul.  The  operator 
must  check  the  equipment  to  insure  it  is  always  in  proper 
working  order  One  valve  that  fails  to  open  or  to  close  dunng 
a  regeneration  stage  could  mean  trouble  (a  storage  tank  full 
of  salty  water  or  no  brine  at  all;. 

The  components  of  an  ion  exchange  softening  system 
that  should  receive  constant  attention  are  the  brine  pumps 
and  piping.  A  saturated  brine  solution  is  very  corrosive  and 
will  attack  any  unprotected  metallic  surface  it  comes  iri 
contact  with.  Try  to  keep  the  system  as  tight  as  possible.  An 
uncontained  brine  leak  will  only  get  worse. 

If  you  must  change  the  pipe  work  in  the  brine  system,  give 
serious  consideration  to  installing  PVC  pipe.  The  material  is 
much  cheaper  than  bronze  and  will  outlast  steel  or  galva- 
nized pipe  when  properly  installed  and  supported.  Future 
repairs  are  also  much  easier  to  make  if  PVC  pipe  is  used. 

The  pun^p  on  the  brine  system  is  most  often  made  of 
brass  which  offers  some  additional  protection  from  the  bnne 
solution.  The  impeller  should  be  bron7e  and  the  shaft 
stainless  steel.  A  strainer  or  screen  oevice  should  be  in- 
stalled ahead  of  the  pump  on  the  suction  side. 

Most  treatment  plants  buy  salt  to  make  their  brine  solution 
in  bulk  form.  Regardless  of  the  salt  supplier,  a  certain 
amount  of  insoluble  material  will  accompany  each  bulk 
delivery  This  insoluble  material  will  consist  of  rocks,  coal, 
sand  and  other  particles  that  can  clog  or  destroy  an  impeller 
if  they  reach  the  pump.  Check  the  strainer  assembly  on  the 
brine  pumps  quite  often  and  keep  spare  parts  on  hand  in 
case  replacement  is  required. 

The  use  of  packing  on  the  pumps  is  recommended  over 
mechanical  seals.  Regardless  of  how  well  the  strainers 
perform,  a  small  amount  of  sand  will  usually  end  up  in  the 


pump  The  combination  of  sand  and  mechanical  seals  will 
most  often  result  in  high  repair  and  mu"^tenance  costs 
Packing  is  v^heaper  and  easier  to  install  and  maintain  than 
mechanical  seals  and  packing  wil!  usually  outlast  mechani- 
cal seals  in  this  type  of  mstanation 

The  brine  pump  motor  should  have  a  'heavy  duty  "  rat'rig 
and  a  body  made  of  cast  iron  is  preferable.  Aluminum  or  mild 
steel  motor  housings  do  not  hold  up  as  well  as  cast  iron 
when  subjected  to  the  corrosive  environment  around  the 
brine  pumpmg  station. 

An  f.rea  most  often  neglected  until  problems  arise  is  the 
bulk  brine  storage  area  of  the  treatment  plant.  Most  storage 
areas  are  underground  pits  equipped  with  rock  or  gravel 
strainers  above  some  type  of  underdram  collection  system. 
Over  a  period  of  time,  the  strainers  will  si;t  in  with  sand  and 
impunties  received  with  salt  deliveries.  The  best  way  to 
prevent  this  from  occurring  is  to  regularly  shut  down,  dram 
and  replace  the  strainer  systems  in  the  pit.  This  is  a  great 
deal  of  work,  but  it  is  a  necessity  if  the  brine  system  is  to  stay 
in  operation. 

Some  brine  storage  areas  have  become  so  clogged  that 
the  bnne  solution  could  not  penetrate  the  strainer  media  and 
reach  the  underdram  system.  Like  the  head  loss  on  a  filter, 
the  strainers  can  become  so  clogged  that  the  solution 
cannot  seep  through  to  the  underdram  system.  If  this 
happens  and  the  system  cannot  be  shut  down  for  cleaning,  a 
pipe  can  be  driven  down  through  the  sand  and  impurities 
into  the  gravel  layers.  If  enough  holes  are  driven  through  the 
zones  of  impurities,  the  solution  will  eventually  seep  into  the 
underdrains  and  caii  be  pumped  into  the  softeners.  This  is  a 
temporary  repair  measure  only  and  th"*  storage  area  should 
be  cleaned  as  soon  as  possib'<?. 

Inspect  the  brine  solution  make-up  water  line  while  the 
storage  area  is  shut  down.  This  line  must  be  kep*  in  good 
working  order  because  it  provides  potable  wate^  to  the  salt 
supply  This  water  makes  the  saturated  brine  solution  that  is 
used  to  regenera'i^  the  softener  PVC  pipe  would  provide 
excellent  service  in  a  corrosive  environment  such  as  a 
storage  area. 


Wet  salt  storage  bnne  tanks  are  another  location  at  a 
water  treatment  plant  where  sanitary  defects  may  develop. 
The  make-up  water  line  must  have  a  free  fall  or  air  gap 
someplace  in  the  system  to  prevent  the  backflow  of  a  brine 
solution  into  the  potable  water  supply.  The  brine  tanks  must 
be  protected  from  contamination  just  like  any  other  water 
storage  facility.  The  cover  and  access  hatches  must  be  of 
the  raised-lip,  overlapplng-cover  type.  All  vents  must  be 
properly  screened  to  keep  out  insects,  birds,  and  rodents. 

I  t  fr 
1  *  i) 


100  Water  Treatment 


All  areas  of  maintenance  tn  an  ion  exchange  softenmg 
plant  cannot  be  covered  here  because  each  plant  will  differ 
With  the  type  of  equipment  used  and  its  method  of  operation 
Set  up  a  maintenance  routine  that  is  characteristic  of  your 
treatment  plant  The  objective  of  the  maintenance  routine 
must  be  to  keep  the  plant  operating  and  hold  repair  costs  to 
a  minimum 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  110. 

14  ISA  What  could  happen  if  a  valve  fails  to  open  or  close 
during  a  regeneration  stage'? 

14  15B  Why  should  the  brme  pumps  and  piping  receive 
constant  aiteiit'on'? 

14  15C  Why  IS  packing  on  bnne  pumps  recommended  over 
mechanical  seals'? 


14.16  TROUBLESHOOTING 

14.160  Test  Units 

Ion  exchange  softeners,  if  properly  operated  and  main- 
tained, will  usually  provide  years  of  trouble-free  service.  If 
problems  ansa  however,  the  operator  should  be  able  to 
identify  and  correct  the  situation  without  a  great  deal  of 
difficulty. 

The  best  way  to  insure  that  a  softener  will  continue  to 
operate  properly  is  to  occasionally  test  the  unit  during 
various  stages  of  operation  Learn  to  recognize  minor 
problems  as  they  develop  and  make  the  necessary  repairs 
before  a  full  scale  problem  exists 

Items  an  operator  shcjid  check  on  in  each  stage  are 
discussed  in  this  section 

14.161  Service  Stage 

In  the  service  stage,  while  the  unit  is  producing  soft  water, 
hardness  tests  shoulc'  be  run  on  the  softener  effluent  to 
insure  the  water  has  a  hardness  of  zero.  One  grain  hardness 
per  gallon  of  water  (17  1  mg/L)  showing  up  in  the  effluent 
should  not  cause  alarm,  but  concentrations  of  hardness 
higher  than  one  gram  hardness  per  gallon  signal  the  need  to 
investigate  the  softener  s  operation  more  closely. 

14.182  Backwash  Stage 

Check  the  backwash  stage  for  adequate  flow  rates  and 
full  extent  of  the  time  required  to  complete  the  stage  Unless 
the  rate  is  high  enough  to  remove  trapped  turbidity  particles 
and  other  insoluble  matenal  that  is  trapped  in  the  resin,  a 
loss  of  softener  efficiency  could  result 

Check  the  timer  on  the  backwash  star  ..to  make  sure  the 
unit  IS  washed  for  the  required  length  of  time. 

If  high  iron  concentrations  have  been  applied  to  the 
softener,  check  the  condition  of  the  resin  by  visually  inspect- 
ing the  top  layer  of  the  bed  Color  is  a  key  factor  to  watch  for 
in  units  beginning  to  show  signs  of  an  iron-fouled  resin.  The 
resin  will  be  an  orange,  rusty  color,  while  the  backwash 
effluent  will  appear  a  light  orange  at  the  end  of  the  backwash 
stage  Also,  the  head  loss  on  the  unit  will  run  higher  than 
normal  as  the  bed  becomes  plugged  with  iron. 

If  iron  fouling  appears  to  be  a  problem,  the  length  of  the 
backwash  stage  should  be  increased  to  wash  as  much  of 


the  particulate  matter  from  t'  )  resin  as  possible.  A  means  of 
surface  washing  the  resin  must  be  provided  for  this  proce- 
dure to  be  effective  Avoid  exceeding  recommended  manu- 
facturer s  flow  rates  to  prevent  washing  resin  from  ihe  unit 

A  chemical  cleaner  can  be  used  to  remove  heavy  iron 
coalings  from  the  resin  itself.  These  cleaners  are  mostly 
sodium  bisulfite  and  can  be  mixed  in  solution  form  and 
poured  into  the  softener.  The  bisulfite  could  also  be  added  to 
the  resin  during  the  regeneration  stage  by  dumping  a 
concentrated  powder  form  in  with  the  bnne  solution.  Consult 
the  resin  supplier  or  manufacturer  before  using  any  cleaner 
on  the  resin 


14.163  Rinse  Stage 

The  nnse  stage  of  the  softener  should  be  checked  when 
tests  indicate  problem*^  are  developing.  The  rinse  rate  is  a 
key  factor  in  keeping  th,.  soft^^er  functioning  properly.  If  the 
nnse  starts  too  soon,  the  bnne  solution  could  be  forced  out 
of  the  unit  before  adequate  contact  time  has  elapsed.  If  the 
nnse  rate  is  too  low.  all  the  waste  matenal  might  not  be 
removed  from  the  unit  before  it  goes  into  the  service  stage. 

The  rate  settings  on  the  unit  should  be  compared,  on  all 
stages,  against  the  actual  manufacturer  s  recommended 
settings  As  equipment  ages,  it  wears.  Over  a  penod  of  time, 
valves  might  need  adjustment  to  keep  the  unit  operating 
within  the  manufacturer's  guidelines. 

14.164  Brine  Injection  Stage 

The  bnne  injection  stage  of  the  softener  sequence  must 
be  correctly  applied  or  the  unit  will  not  perform  satisfactorily 
when  It  returns  to  service.  If  the  resin  is  not  regenerated 
dunng  this  stage,  there  will  be  no  sodium  ions  to  exchange 
with  the  hardness  ions  in  the  water  when  the  water  is  applied 
to  the  unit 

The  bnne  storage  area  should  always  contain  enough  salt 
to  provide  a  bnne  so'ution  when  make-up  water  is  added. 

Also  check  the  amount  of  salt  solution  that  is  pumped  into 
the  softener  This  is  usually  done  with  a  meter  that  is  preset 
to  deliver  the  exact  amount  of  bnne  solution  required  to 
regenerate  the  softener.  If  a  bnne  solution  is  less  than 
saturated,  longer  contact  time  is  required  between  the 
media  and  the  solution 


1 


Softeninc  101 


The  required  amount  of  solution  must  be  delivered  consis- 
tently to  achieve  a  successful  regeneration  of  the  unit.  If 
hardness  leakage  appears  early  in  the  service  or  softening 
stage,  check  the  amount  and  saturation  of  bnne  solution  in 
the  bnne  system  since  these  are  the  mam  reasons  for 
hardness  leakage. 

If  hardness  leakage  is  excessive  Immediately  following  a 
regeneration  stage,  shut  the  unit  down  and  check  the  media 
level.  The  bed  could  bP  disrupted  from  excessive  backwash 
or  rinse  rates.  Iron  fouling  could  also  cause  a  channeling 
condition  to  occur  and  cause  the  water  to  short-circuit 
through  the  media  without  contacting  the  corrplete  bed 
volume. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  110. 

14.16A  What  IS  the  maximum  hardness  level  expected  in 
the  effluent  of  a  properly  operating  ion  exchange 
softener  before  the  operator  should  investigate  the 
operation? 

14.16B  What  IS  the  purpose  of  the  backwash  sta^e  of  an 
ion  exchange  softener  operation? 

1 4.1 6C  What  problems  may  occur  If  the  nnse  rate  starts  too 
soon  or  is  too  slow? 

14  16D  What  would  you  do  if  hardness  leakage  is  exces- 
sive immediately  following  a  regeneration  stage? 


14.17   STARTUP  AND  SHUTDOWN  OF  UNIT 

At  times  It  becomes  necessary  to  shut  a  unit  down  and 
take  It  out  of  service  for  repairs  or  inspection.  If  the  operator 
will  follow  common  sense  guidelines,  no  problems  should 
arise  from  unit  shutdowns. 

When  dealing  with  these  units,  drain  and  fill  them  slowly. 
This  will  prevent  surging  of  the  media  v/hich  will  either  wash 
it  out  of  the  unit  or  disrupt  it,  thus  making  the  media  uneven 
and  creating  channeling  problems.  If  you  suspect  problems 
with  a  unit,  the  last  thing  you  want  to  do  is  make  the  situation 
worse  by  rapidly  backfilling  or  backwashing  the  softener. 

Most  units  are  equipped  with  automatic  air  release  valves 
(Figure  1 4.1 5).  Be  certain  these  valves  are  operating  proper- 
ly, because  the  venting  of  trapped  a'r  is  an  Important  step  in 
filling  a  unit  after  it  has  been  shut  down. 

During  unit  shutdown,  make  a  complete  visual  inspection. 
Now  is  the  time  to  detect  and  correct  minor  problems  that 
might  otherwise  develop  into  bigger  ones.  Check  the  brine 
inlet  distnbutors  while  the  unit  is  down.  They  should  be 
visible  from  the  top  hatch  on  most  softeners. 

Make  sure  the  pipe  work  is  level  and  the  nozzles  or 
openings  are  not  clogged.  The  distnbutors  play  an  important 
role  In  the  regeneration  stage  by  applying  the  brine  solution 


evenly  to  the  top  of  the  resin  bed  If  the  pipe  work  is 
deteriorating  from  the  bnne  solution.  PVC  pipe  should  be 
used  as  a  replacement. 

If  the  resin  and  gravel  support  material  is  removed  from 
the  softener,  check  the  underdrain  structures  in  the  unit  and 
repair  any  problems  you  discover.  In  filling  the  unit  with 
gravel  and  resin,  each  zone  of  the  bed  should  be  leveled  and 
Sized  according  to  manufacturer's  specifications. 

The  procedure  for  filling  a  unit  with  water  after  a  total 
shutdown  is  very  important.  The  flow  into  the  unit  should  be 
from  the  bottom  at  a  slow,  controlled  rate-  This  is  done  by 
putting  the  unit  in  the  backwash  position,  running  water  into 
the  unit  from  the  bottom  and  out  the  ba;Kwash  effluent 
valve.  The  purpose  of  this  procedure  is  to  fill  the  unit  with 
water  and  purge  the  air  that  was  trapped  in  the  resin  and 
softener  during  the  replacement  process. 

After  the  unit  is  filled  the  backwash  rate  should  be 
increased  to  normal  and  continued  until  the  effluent  is  clear. 
Again,  care  should  be  taken  when  bnnging  the  rates  up  to 
the  manufacturer's  recommendations,  to  prevent  disrupting 
or  displacing  resin  from  the  bed. 

Once  the  unit  has  been  satisfactorily  backwashed,  the  bed 
should  be  regenerated.  This  can  be  accomplished  by  run- 
ning the  softener  through  a  normal  brine  and  rinse  proce- 
dure before  it  is  retumed  to  service.  Run  a  hardness  test  on 
the  effluent  to  insure  all  stages  have  performed  correctly 
and  the  unit  is  softening  water. 

QUESTIONS 

Write  your  answers  \[t  a  notebooK  and  then  compare  your 
answers  with  those  on  page  110. 

14.1 7A  Why  must  ion  exchange  softeners  be  drained  and 
filled  slowly  during  startup  and  shutdown? 

14.178  What  should  be  done  if  the  pipe  work  in  an  ion 
exchange  softener  is  detenorating  from  the  bnne 
solution? 


14.18   ION  EXCHANGE  ARITHMETIC 

Hardness  is  usually  expressed  as  mg/L  of  CaCOj.  In  ion 
exchange  softening,  however,  hardness  is  most  often  ex- 
pressed in  terms  of  grains  per  gallon  or  grains  of  hardness 
removed  from  the  water  being  treated. 


The  exchange  capacity  of  most  softeners  is  expressed  as 
kilograms  (1000  grams)  of  hardness  removed  per  each  cubic 
foot  of  resin. 

1\7 


102  Water  Treatment 


AIR  RELEASE  ASSEMBLY 


Pressure  aeration  and  pressure  filtration  type  filtei-  plants  require  an  automatic  air  release 
assembly  to  prevent  accumulation  of  an  excessive  volume  of  air  :n  the  pressure  filter  tanks. 
This  air  release  assembly  consists  of  an  automatic  air  release  valve,  and  necessary  pine, 
valves  and  fittings  to  install  on  filter  tank.    The  air  release  valve  is  a  float  operated  type  and 
must  be  installeJ  with  center  hne  of  valve  level  with  or  above  top  oi  filter  tank.    Air  from  top 
of  filter  enters  air  release  valve  at  top  connection  and  water  from  filter  inlet  pipe  enters 
valve  at  bottom  connection.    Excessive  air  from  filter  fills  valve  body  with  air  forcing  water 
level  down  and  thereby  allowing  float  to  drop,    Dowu/i^rd  movement  of  float  allows  excessive 
air  to  escape  through  the  needle  valve  until  an  air-water  pressure  balance  is  restored. 

In  normal  operation  valves  1  and  3  are  open  and  valve  2  is  closed.    To  flush  air  release  valve 
close  valve  1  and  open  valve  2  which  allows  water  from  top  of  filter  to  flush  down  through  the 
valve  to  the  drain.    Valve  3  is  left  open  at  all  times  unless  it  is  necessary  to  remove  air  re- 
lease valve. 


Figure.  14. 15  Air  release  assembly 

f'*ermission  of  General  Filter  Company) 


m  ■  lis 


Softening  103 


Salt  in  solution  form  is  used  to  regenerate  ion  exchange 
softeners.  The  theoretical  salt  requirement  is  0.17  pounds  of 
salt  for  1000  grains  of  hardness  removed.  Most  regenera- 
tions, however,  require  0.3  to  0.5  pounds  of  salt  per  1000 
grains  of  hardness  removal. 

In  this  section  you  will  learn  how  to  calculate  the  volume  of 
the  brine  solution  required  to  regenerate  the  softening  unit 
as  well  as  the  pounds  of  salt  required  for  regeneration.  The 
concentration  of  brine  solution  used  at  each  treatment  plant 
may  vary.  Table  14.6  lists  the  pounds  of  salt  present  in  the 
percentage  of  brine  solution  being  used. 

FORMULAS  AND  CONVERSION  FACTORS 

Hardness  is  usually  expressed  as  milligrams  of  hardness 
per  liter  of  water  as  CaCOj. 

Treatment  for  hardness  Is  often  discussed  as  grains  of 
hardness  per  gallon  of  water. 

1  gram  per  gallon  =  17.i  milligrams  per  liter 

or  1  gpg  =  17.1  mg/L 

7000  grains  =  1  pound 

To  convert  grains  per  gallon  to  milligrams  per  liter, 

Hardness,  mg/L  =  (Hardness,  grains/gallon)(17.1  mg/L) 

1  gpg 

To  convert  milligrams  per  liter  to  grains  per  gallon, 

Hardness,       ^(Hardness,  mg/L)(1  gpg) 
grains/gallon  17.1  mg/L 

To  find  the  exchange  capacity  of  a  softener,  you  need  to 
know  the  removal  capacity  of  the  softener  in  grains  per  cubic 
foot  of  resin  or  in  kilograins  per  cubic  foot  of  resin  and  the 
volume  of  the  resin  in  cubic  feet. 

TABLE  14.6   SALT  SOLUTION  CHARACTERISTICS 


Percent  NaCI 
or  grams  per 


Lb$NaCI  LbsNaCI 


0  grams  of 

Specific  Gravity 

Salameter 

per 

per 

solution 

at15**C  or  59**F 

Degree 

U.S.  gal 

Cu  Ft 

1.0 

1.0073 

4 

0.084 

0.63 

20 

1.0140 

8 

0.169 

1.27 

3.0 

1  0217 

11 

0.255 

1.91 

4.0 

1.0290 

15 

0  343 

2.57 

5.0 

1  0362 

19 

0  432 

3.23 

6.0 

1.0437 

23 

0.522 

3.90 

70 

1.0511 

27 

0.612 

4.59 

8.0 

1.0585 

30 

0.705 

5.28 

90 

1.0659 

34 

0.799 

5.98 

100 

1.0734 

38 

0.874 

6.69 

11.0 

1.0810 

42 

0.990 

7.41 

120 

1  0885 

45 

1.09 

8.14 

13.0 

1.0962 

49 

1.19 

8.83 

14.0 

1.1038 

53 

1  29 

9.63 

15.0 

1.1115 

67 

1.39 

10.4 

16.0 

1.1194 

60 

1  49 

11.2 

170 

1.1273 

65 

1.60 

12.0 

18.0 

1.1352 

68 

1.70 

12.7 

19.0 

1.1432 

72 

1.81 

13.5 

20.0 

1.1511 

76 

1.92 

14.4 

21.0 

1.1593 

80 

2.03 

15.2 

22.0 

1.1676 

84 

2.14 

16.0 

23  0 

1  1758 

87 

2.25 

16.9 

24.0 

1.1840 

91 

2.37 

17.7 

25.0 

1.1923 

95 

2.48 

18.6 

26.0 

1.2010 

99 

2.60 

19.5 

26.4 

1.2040 

100 

2.65 

19.8 

^gralns^^  ^^^^^  '^  ^  (Removal  Capacity,  grams/cu  ft)  (Media  Vol,  cu  ft) 

water  Treated  Exchange  Capacity,  grams 

9a'  Hardness  Removed,  grams/gal 

Operating  Time,  hr    (Water  Treated,  gal)  (24  hr/day) 

ZIbZ::^   ^  AveDa.,yF.ow.ga,/.ay 

generation) 

To  deternme  the  amount  of  salt  required  for  regeneration, 
you  need  to  know  the  pounds  of  salt  per  1000  grains 
required  for  regeneration.  To  calculate  the  gallons  of  brine 
required  for  regeneration,  you  need  to  know  the  percent 
brine  solution  or  the  pounds  of  salt  per  gallon  of  brine. 


Salt  Needed 
lbs 

erme. 
gallons 


(Salt  Required,  lbs/1000  gr)  (Hardness  Removed,  gr) 
Salt  Needed,  lbs 


Salt  Solution,  lbs  salt/gallon  of  brine 


EXAMPLE  6 

How  many  milligrams  of  hardness  per  liter  are  there  In  a 
water  with  16  grains  of  hardness  per  gallon  of  water? 

Known  Unknown 

Hardness,  gpg  =  16  gpg  Hardness,  mg/L 

1  Calculate  the  hardness  of  the  water  in  milligrams  per  liter. 

(Hardness,  grams/gallon)  (17.1  mg/L) 

Hardness.  mg/L=-  :  ; —  

1  gram/gallon 

06  grams/gallon)  (17  1  mg/L) 

1  grain/gallon 

"  274  mg/L 

EXAMPLE  7 

Convert  the  hardness  of  a  water  at  290  mg/L  to  grains  per 
gallon 

Known  Unknown 

Hardness.  mg/L  =  290  mg/L       Hardness,  grams/gallon 

1.  Convert  the  hardness  from  milligrams  per  liter  to  grains 
per  gallon 

Hardness,      ^  (Hardness  mg/L)  (1  gram/gallon) 
grams/gallon  17.1  mg/L 

^  (290  mg/L)  (1  grain/gallon) 

17.1  mg/L 
=  17  grams/gallon 

EXAMPLE  8 

An  ion  exchange  softener  contains  50  cubic  feet  of  resin 
with  a  hardness  removal  capacity  of  20  kilograins  per  cubic 
foot  of  resin.  The  water  being  treated  has  a  hardness  of  300 
mg/L  as  CaCOj.  How  many  gallons  of  water  can  be  softened 
before  the  softener  will  require  regeneration? 


Known 


Resin  Volume, 
cu  ft 


ERLC 


Removal  Capacity, 
gr/cu  ft 

Hardness.  mg/L 

I!, 9 


50  cu  ft 
20,000  grains/cu  ft 
300  mg/L 


Unknown 

Water  Treated,  gal 


104  Water  Treatment 


1  Convert  the  hardness  from  mg/L  to  grains  per  gallon 
Hardness.      ^  (Hardness  mg/L)  (1  gram/gallon) 

grams/gallon  ^7  ^  ^g^^ 

_  (300  mgIL)  (1  grain/gailon) 

17.1  mg/L 
-  17  5  grams/gallon 

2  Calculate  the  exchange  capacity  of  the  softener  in  grams 

fc.  change    (Resm  Vol  cu  ft)  (Removal  Capacity  grams/cu  ft) 
grau^s'^^     (50  cu  it)  (20  000  grams/cu  ft) 

1 .000  000  grains  of  removal  capacity 

3  Calculate  the  volume  of  water  in  gallons  that  may  be 
treated  before  regeneration 

water  Treated,  qal  =  ^^change  Capacity,  grams 


4.  rmd  the  length  of  time  the  softeners  can  run  before 
requiring  regeneration. 


Hardness,  grams/gallon 
1.000.000  grams 


17.5  grams/gallon 

-  57.143  gallons 

Therefore.  57.C00  gaiions  of  water  with  17.5  grams  of 
hardness  per  gallon  of  water  can  be  treated  before  the  resm 
becomes  exhausted 

EXAMPLE  9 

An  ion  exchange  softening  plant  has  two  softeners  that 
are  eight  feet  in  diameter  and  the  units  have  a  resin  depth  of 
SIX  feet.  The  resin  has  a  20  kilogram  removal  aUiiity.  How 
many  gallons  of  water  can  be  treated  if  the  hardness  is  14 
grains  per  gallon?  If  the  flow  rate  to  the  softeners  is  500 
gallons  per  minute,  how  long  will  they  operate  before 
regeneration  is  required'? 

Known  Unknown 

Nuiiiber  of  Softeners  =  2  Softeners  i.  Water 
Diameter,  ft            =  8  ft  Treated,  gal 

Resin  Depth,  ft         =  6  ft  2.  Operating 

Exchange  Capacity,  =  20,000  grams/cu  ft 
gr/cu  ft 

Hardness,  =  14  grams/gallon 
grain/gallon 

Flow,  gallons/mm     =  5OO  gallons/mm 

1.  Calculate  the  total  volume  of  softener  media 

Resm  Vol.  =  (0.7b5)(Diameter.  ft)2(Depth.  ft)(No.  Softeners) 
cu  ft 

=  (0.785)(8  ft)2(6  ftX2  Softeners) 
=  603  cu  ft 

2.  Calculate  the  total  exchange  capacity  of  the  two  soften- 
ers in  grains. 

Exchange   =  (Resm  Vol,  cu  ft)(Removal  Capacity,  grams/cu  ft) 
Capacity, 

grams       (603  cu  ft)(20.000  grams/cu  ft) 

=  12,060.000  grams,  removal  capacity  of  the  beds 

3.  Calculate  the  volume  of  water  in  gallons  that  may  be 
treated  before  the  resin  is  exhausted. 

Water  Treated,  .Exchange  Capacity,  grains 

Hardness,  grains/gallon 

^12,060,000  grains 

14  grains/gallon 

=  861.429  gallons  can  be  treated  before 
resin  is  exhausted 


ERIC 


operating  Time, 
hr 


(V\/ater  Treated,  gal) 


(Ave  Daily  Flow.  gal/min)(60  min/hr) 

(861.429  gal) 
(500  gal/min)(60  min/hr) 

^  28  7  hours  of  operation  before  regeneration 
IS  required 


EXAMPLE  10 

An  ion  exchange  soften<3r  will  remove  1.000,000  grams  of 
hardness  before  the  resm  becomes  exhausted.  If  0.3 
pounds  of  salt  are  required  per  1000  grains  of  hardness, 
how  many  pounds  of  salt  are  needed'?  If  a  15  percent  salt 
solution  IS  used  to  regenerate  the  unit,  how  many  gallons  of 
brir  e  are  required?  Table  14.6  indicates  that  1.39  pounds  of 
salt  is  present  in  each  gallon  of  15  percent  brin^  solution. 


Unknown 

1  Salt  Needed,  lbs 

2  Brme.  gal 


Known 

Hardness  Removal,  ^  1,000,u00  grams 
grains 

Salt  Required.        =  c.3  lbs/1000  gr 
lbs/1000  gr 

Salt  Solution.         -  1.39  lbs/gal 
lbs/gal 

1  Determine  the  pounds  of  calt  needed  for  regeneration. 

Salt  Neoded-  =  (Salt  Required,  lbs/1000  gr)(Hardness  Removed,  gr) 
lbs 

^  (0  C  lbs  Sait)( 1,000.000  grams) 

(1000  grains) 
^  300  lbs  of  salt 
2.  Find  the  gallons  of  brine  solution  required. 


Brine,  gal  =. 


Salt  Needed,  lbs 


Salt  Solution,  lbs/gallon  of  brine 

=  300  lbs  of  Salt 

1 .39  lbs  of  falt/gallon  of  brine 

=  216  gallons  of  brine 

(15  percent  salt  solution) 


120 


Softening  105 


EXAMPLE  11 

Use  the  same  information  as  in  Example  10,  except  use  a 
12  percent  brine  solution.  Table  14.6  mdicates  that  1.09 
pounds  of  salt  aie  present  in  each  gallon  of  12  percent  brine 
solution.  Three  hundred  pounds  of  salt  are  naeded  for 
regeneration.  How  many  gallons  of  1 2  percent  brine  solution 
IS  required'? 

Known  Unknown 

Salt  Needed.     300  lbs  Bnne,  gal 

lbs 

Salt  Solution,  =  1 .09  lbs/gal 
lbs/gal 

1.  Find  the  gallons  of  brine  solution  required. 

Salt  Needed,  lbs 


Brine,  gal  =_ 


Salt  Solution,  lbs/gallon  of  brine 
^    300  lbs 

1.09  lbs/gal 
=  275  gallons  of  12  percent  bnne  solution 

NOTE:  More  gallons  of  bnne  solution  are  required  when 
using  a  12  percent  bnne  solution  than  when  using  a 
15  percent  solution.  The  weaker  concentration  re- 
quires more  gallons  to  achieve  the  same  results. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  110. 

14.18A  A  source  water  has  a  hardness  of  150  mg/L  as 
CaCOj.  What  is  the  hardness  in  grains  per  gallon'? 


1 4  1 88  An  ion  exchange  softener  contains  60  cubic  feet  of 
resin  with  a  hardness  removal  capacity  of  25  kilo- 
grams per  cubic  foot  of  resin.  The  water  being 
treated  has  a  hardness  of  250  mg/z.  as  CaCOj.  How 
many  gallons  of  water  can  be  softened  before  the 
softaner  will  require  regeneration'^ 

14.19  BLENDING 

Ion  exchange  softeners  will  produce  a  water  with  zero 
hardness  Water  with  zero  hardness  must  not  be  sent  into  a 
distribution  system.  Water  with  zero  hardness  is  very  corro- 
sive and  ovjr  a  period  of  time  will  attack  steel  pipes  m  the 
system  and  create  red  water  problems.  Also,  to  provide  a 
water  supply  with  zero  hardness  water  would  be  very 
expensive. 

At  most  softening  plants,  the  zero  hardness  effluent  from 
the  softeners  is  mixed  with  filtered  water  having  a  known 
hardness  concentration.  In  other  words,  a  certain  amount  of 
water  the  treatment  plant  produces  will  bypass  the  softening 
units  (sp»it  treatment).  This  water  has  a  known  hardness 
concentration  and  is  mixed  in  various  proportions  with  the 
softener  effluent  to  arrive  at  a  desired  level  of  hardness  In 
the  finished  water  (Figure  14.16). 

An  example  would  be  a  treatment  plant  that  has  a  filtered 
water  hardness  of  16  grams/gallon.  If  the  desired  plant 
effluent  hardness  is  8  grams/gallon,  fifty  percent  of  the  plant 
influent  must  be  softened  and  tne  other  fifty  percent  would 
be  filtered  water  mixed  together  with  the  softener  effluent. 
The  result  would  be  water  that  has  a  hardness  of  8  grains 
per  gar  jn. 

The  blending  of  water  is  very  simple  and  is  usually 
controlled  by  a  valve  and  meter.  The  operator  adjusts  the 
exact  gallons  per  minute  bypassing  the  softener  to  produce 
the  desired  hardness 


UNSOFTENED  WATER 


Si 


FLOW  CONTROLLER 


BY  PASS  METER 
OPTIONAL 


ADJUSTABLE 


ORIFICE 


SOFTENER 


CONTROL 
LINE 


41 


BLENDED  WATER 


FIXED 
ORIFICE 

Fig,  14, 16  Automatic  softener  bypass 

(Permission  of  Goneral  Filter  Company) 


106  Water  Treatment 


FORMULAS 

To  calculate  the  bypass  flow  in  gallons  per  day  to  blend 
water,  determine  the  total  flow,  the  filtered  water  hardness 
and  the  desired  effluent  hardness. 

The  softener  capacity  in  gallons  and  both  the  softener  and 
bypass  flows  In  gallons  per  day  are  needed  to  determine  the 
volume  of  bypass  water. 

The  total  flow  produced  by  the  plant  before  legeneration 
IS  the  sum  of  the  (lows  through  the  softener  and  the  bypass 
flow. 

Bypass  Flow,  GPn  =  C'o^Q^  ^'o^.  GPD)(Piant  EffI  Hardness,  gpg) 

Filtered  Hardness,  gpg 

Bypass  Water,  gal  ^  (Softener  Capacity.  gaQjBypass  Flow.  GPP) 

Softener  Flow.  GPD 
Total  Flow,  gal      -  Softene*-  Capacity,  gal  -f  Bypass  Water,  gal 

EXAMPLE  12 

A  softener  plant  treats  120,000  gallons  per  day.  The 
filterea  water  has  a  hardness  of  .5  grains  per  gallon  (256 
mg/L)  and  the  desired  hardness  in  the  plant  effluent  is  5 
grains  per  gallon  (86  mg/L)  How  much  water  in  gallons  per 
day  must  bypass  the  softener  to  produce  the  desired  level  of 
hardness'? 


Known  Unknown 

Total  Flow.  GPD         =  120,000  GPD  Bypass  Flow, 

Filtered  Hardness,  gpg  =  15  gpg  GPD 
EffI  Hardness,  gpg      =  5  gpg 

1.        Calculate  tne  bypass  flow  in  gallons  per  day. 

Bypass  Flow,  GPD    (Total  Flow.  GPD)(Piant  Effi  Hardness,  gpg) 
Filtered  Hardness,  gpg 
^  (120.000  GPD){5  gpg) 

05  gpg) 

=  40.000  GPD 


EXAMPLE  13 

Using  the  information  in  Example  12,  how  many  gallons  of 
water  will  be  bypassed  before  the  softener  requires  regen- 
eration? The  softener  has  the  capacity  to  treat  105,000 
gallons.  From  Example  12  the  bypass  flow  is  40.000  GPD 
and  the  total  flow  is  120,000  GPD.  Therefore  the  softener 
flow  IS  80.000  GPD  (120,000  GPD  -  40,000  GPD).  What  is 
the  total  flow  produced  by  th<5  plant  per  regeneration? 

Known  Unknown 

Softener  Capacity.  =  105,000  gal    1.  Bypass  Water,  gal 
gal 

2.  Total  Flow,  gal 

Softener  Flow.  GPD  =  80,000  GPD 

Typass  Flow,  GPD  =  40.000  GPD 

1,  Calculate  the  gallons  of  water  that  will  be  bypassed 
before  the  softener  requires  regeneration. 

Bypass  Water. _  (Softener  Capacity,  gal) (Bypass  Flow.  GPD) 
93'  "  (Softener  Flow.  GPD) 

(105.QCJ  gal)  (40.000  GPO) 
80,000  GPD 
=  52.500  gallons 

o 

ERIC 


2  Determine  the  total  flow  produced  by  the  plant  per 
regeneration. 

Total  Flow,  gal  =  Softener  Capacity,  gal  h  Bypass  Water,  gal 
=  105.000  gal  +  52,500  gal 
-  157.500  gallons 

14.20  RECORDKEEPING 

Keeping  correct  and  up-to-date  records  is  as  important  as 
performing  scheduled  maintenance  on  a  regular  routine.  The 
recordkeeping  system  should  be  set  up  to  record  data  on  a 
daily  basis.  Record  the  total  flow  through  the  softener  each 
day,  along  with  the  blend  rates  and  gallons  that  have 
bypassed  the  unit.  The  total  gallons  of  brine  used  each  day, 
along  with  the  pounds  of  salt  used  to  keep  the  ion  exchange 
softener  in  good  working  order  should  be  recorded.  Records 
of  the  tests  performed  on  the  softeners  should  be  kept  up- 
to-date  in  order  to  warn  the  operator  of  any  problems  that 
might  be  developing  with  the  softening  unit.  Good  records 
are  an  impclant  part  of  a  successful  treatment  plant  oper- 
ation Many  problems  can  be  avoided  or  solved  with  an 
adequate  recordkeeping  system  if  you  review  your  daily 
records  and  compare  them  with  the  normal  recoids  to 
determine  operating  problems. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  111. 

14.19A  Why  is  source  water  blended  with  the  effluent  from 
an  ion  exchange  softener'? 

14.20A  What  records  should  be  koDt  by  the  operator  of  an 
ion  exchange  softening  plant'? 

14.21  ARITHMETIC  ASSIGNMENT 

Turn  to  the  Appendix  at  the  back  of  this  manual  on  "How 
to  Solve  Water  Treatment  Plant  Arithmetic  Problems."  In 
Section  A.52,  "Softening,"  read  the  material,  work  the  exam- 
ple problems  and  check  the  arithmetic  using  your  calculator. 

14.22  ADDITIONAL  READING 

1  NEW  YORK  MANUAL  Chapter  1 1 ,  "Softening." 

2  TEXAS  MANUAL,  Chapter  1 1 ,  Special  Water  Treatment 
(Softening  and  Ion  Exchange). 

3  /VOTES  ON  WATER  CHEMISTRY,  prepared  for  "Ad- 
vanced Water  Works  Operations,"  by  Michael  D.  Curry. 
P  E  ,  President  Curry  and  Associate  Engineers,  Inc.,  P.O. 
Box  246,  Nashville,  Illinois  62263. 


K3 


Softening  107 


14.23  ACKNOWLEDGMENTS 

Portions  of  the  materia!  discussed  on  ion  exchange  soft- 
ening came  from  the  sources  listed  below. 

1.  Bowers,  Eugene,  "Ion  Exchange  Softening"  in  WATER 
QUALITY  AND  TREATMENT  3rd  Ed.,  American  Water 
Works  Association,  Computer  Services,  6666  W.  Quincy 
Ave.,  Denver,  Colorado  80235.  Order  No.  10008.  Price, 
members,  $41.00;  nonmembers,  $51.00 

2.  Lipe,  LA.  and  M.D.  Curry,  "Ion  Exchange  Water  Soften- 
ing," a  discussion  for  v  /ter  treatment  plant  operators, 


1974-75  seminar  series  sponsored  by  Illinois  Environ- 
mental Protection  Agency,  and 

3.  Riehl,  Merrill  L.,  WATER  SUPPLY  AND  TREATMENT, 
National  Lime  Association,  3601  North  Fairfax  Drive, 
Arlington,  Virginia  22201.  Price,  $10.00. 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  14.  SOFTENING 

(Lesson  2  of  2  Lessons) 


Write  the  answers  to  these  questions  in  your  notebook 
before  continuing  with  the  Objective  Test  on  page  111.  The 
problem  numbering  continues  from  Lesson  1. 

13.  What  happens  in  the  resin  or  media  in  an  ion  exchange 
softener  during  the  softening  stage? 

14.  How  would  you  insure  that  large  amounts  of  resin  are 
not  being  lost  during  ihe  backwash  stage'^ 

15.  How  would  you  determine  if  an  ion  exchange  softener 
rinse  stage  has  been  successful 

16.  What  happens  if  an  ion  exchange  softener  removes  iron 
■n  the  ferrous  (soluble)  or  ferric  (solid)  form? 


17.  What  types  of  insoluble  material  may  be  found  in  salt? 
What  problems  can  be  caused  by  this  ma'enal  and  how 
can  these  problems  be  prevented'^ 

18.  How  would  you  prevent  the  strainers  under  the  bulk 
brine  sto'age  area  from  silting  in  with  sand  and  impuri- 
ties'? 

19.  How  would  you  determine  if  iron  has  fouled  the  resin  of 
an  ion  exchange  softener'? 

20.  How  are  ion  exchange  units  filled  with  water  after  total 
shutdown'? 

21  Why  IS  water  with  zero  hardness  not  delivered  to 
consumers'? 


SUGGEST 

Chapter  1 


ANSWERS  TO  QUESTIONS  IN  LESSON  1 

Answers  to  questions  on  page  72. 

14  OA  Hardness  is  caused  mainly  by  the  calcium  and  mag- 
nesium ions  in  water. 

14 1A  Excessive  hardness  is  undesirable  because  it 
causes  the  formation  of  soap  curds,  increased  use  of 
soap,  deposition  of  scale  in  boilers,  damage  in  some 
industrial  processes,  and  sometimes  may  cause  ob- 
jectionable tastes  in  drinking  water. 

14.1^  Limitations  of  the  ion  exchange  softening  process 
include  (1)  an  increase  in  the  sodium  content  of  the 
softened  water  and  (2)  ultimate  disposal  of  spent 
brine  and  rinse  waters. 

Answers  to  questions  on  page  75. 

14.2A  Hardness  is  commonly  measured  by  titration.  Individ- 
ual divalent  cations  may  be  measured  by  using  an 
atomic  adsorption  (AA)  spectrophotometer. 

ERLC 


I  ANSWERS 

SOFTENING 


14  2B  Determine  the  total  hardness  as  CaC03  for  a  sample 
of  water  with  a  calcium  content  of  25  mg/L  and  a 
magnesium  content  of  14  mg/L 

Known  Unknown 

Calcium,  mg/L  =  25  mg/L  Total  Hardness, 
Magnesium,  mg/L  =  14  mg/L         mg/L  as  CaCOj 

Calculate  the  total  hardness  as  milligrams  per  liter  of 
calcium  carbonate  equivalent. 

Total  Hardness.^  Catcium  Hardness.^  Magnesium  Hardness, 
mg/L  as  CaC03"^  mg/L  as  CaC03       mg/L  as  CaCOo 

=  2  50  (Ca,  mg/L)  f  4  12  (Mg.  mg/L) 

-  2  50  (25  mg/L)  +  4  12  (14  mg/L) 

=  62,5  mg/L  +  57,7  mg/L 

=  120  2  mg/L  as  CaCOa 

14.2C  Water  treatment  chemicals  which  lower  the  pH  when 
added  to  water  include  alum,  carbon  dioxide,  chlo- 
rine (CIg),  ferric  chloride,  hydrofluosilicic  acid  and 
sulfuric  acid. 

loo 

1  O 


108  Water  Treatment 


14.2D  Results  from  alkalinity  titrations  on  a  sample  of  water 
were  as  follows: 

Known 

Sample  Size,  mL  =100  mL 

mL  titrant  used  to  pH  8  3,  A  =  1 .2  mL 
Total  mL  of  titrant  used,  B  =  5  6  mL 
Acid  normality,  N  =  0.02  N  H^SO^ 

Unknown 

1.  Total  Alkalinity,  mg/L  as  CaCOj 

2.  Bicarbonate  Alkalinity,  mg/L  as  CaCOj 
3  Carbonate  Alkalinity,  mg/L  a^  CaCOj 
4.  Hydroxide  Alkalinity,  mg/L  as  JaCOj 


14.3D  The  pH  is  increased  because  calcium  and  magne- 
sium become  less  soluble  as  the  pH  increases. 
Therefore,  calcium  and  magnesium  can  be  removed 
from  water  as  insoluble  precipitates  at  high  pH 
levels. 

1 4  3E  After  the  chemical  softening  process,  the  scale  form- 
ing tendencies  of  water  are  reduced  by  bubbling 
carbon  dioxide  (recarbonation)  through  the  water. 

14  3F  Caustic  soda  softening  might  be  used  in  place  of 
soda  ash  The  decision  to  use  caustic  soda  rather 
than  soda  ash  depends  on  the  quality  of  the  source 
water  and  the  delivered  costs  of  various  chemicals. 


1 .  Calculate  the  phenolphthalein  alkalinity  in  mg/L  as 


CaCOj. 

Phenotphthaiein 
Alkalinity. 
mg/L  as  CaC03 


A  X  N  X  50.000 


inL  of  sample 
(1  2mL)x  (0  02  N)  x  50.000 
100  mL 
-  12  mg//.as  CaC03 

2.  Calculate  the  total  alkalinity  in  mg/L  as  CaC03. 

Total  Alkalinity.  ^  B  x  N  x  50.000 
mg//.  as  CaCOs    mL  of  sample 

(5  6mL)x(0  02N)  X  (50.000) 
100  mL 
=  56  mg/L  as  CaCQ3 

3.  Refer  to  Table  14.3  for  alkalinity  constituents. 

From  Table  1 4.3  we  want  the  second  row  because 
P  =  12  mg/L  which  is  less  than  V2T[(V2)  (56  mg/L) 
=  28  mg/L]. 

Therefore, 

a.  Bicarbonate  Alkalinity  =  T  -  2P 

=  56  mg/L -2(12  mg/L) 
-  32  mg/L  as  CaCOg 

b.  Carbonate  Alkalinity   =  2P 

=  2  (12  mg/L) 

=  24  mg/L  as  CaCOg 

c.  Hydroxide  Alkalinity    =  0  mg/L  as  CaCOj 

Answers  to  questions  on  page  75. 

14.3A  The  minimum  hardness  that  can  be  achieved  by  the 
lime-soda  ash  process  is  around  30  to  40  mg/L  as 
CaCOj. 

14.3B  Benefits  that  could  result  from  the  lime-soda  soften- 
ing process  in  addition  to  softening  include: 

1.  Removnl  of  iron  and  manganese, 

2.  Reduction  of  solids, 

3.  Removal  and  inactivation  of  bacteria  and  virus 
due  to  high  pH, 

4.  Control  of  corrosion  and  scale  formation  with 
proper  stabilization  of  treated  water,  and 

5.  Removal  of  excess  fluoride. 


Answers  to  questions  on  page  77. 

1 4.3C  The  addition  of  lime  to  water  increases  the  hydroxide 
concentration,  thus  increasing  the  pH. 


Answers  to  questions  on  page  78. 

1 4.3G  Calculate  the . .ydrated  lime  (Ca(0H)2)  with  90  percent 
purity  soda  ash,  and  carbon  dioxide  dose  require- 
ments in  milligrams  per  liter  for  the  water  shown 
below. 


ERLC 


124 


Known 

Constituents 

CO2.  mg/L 

Total  Alkalinity,  mg/L 

Total  Hardness.  mg/L 

Mg2+.nig/L 

pH 

Lime  Purity.  % 


Softened  Water 
After  Recarbonetion 
Source  Water  and  Filtration 

5  mg/L  =  0  mg/L 

1 50  mg/L  as  CaC03  =  20  mg/L  as  CaC03 

240  mg/L  as  CaC03  ^  50  mg/L  as  CaC03 

=  16  mg/L  =  2  mg/L 

=74  =88 

=  90% 


Unknown 

Hydrated  Lime.  mg/L 
Soda  Ash.  mg/L 
Carbon  D»ox»de.  mg/L 

1  Calculate  the  hydrated  lime  (Ca(0H)2)  required  in 
milligrams  per  liter. 

A  =  (CO2  mg/L)  (74/44) 

=  (5  mg/L)  (74/44) 

=^  8  mg/L 
B  =  (Alkalinity,  mg/L)  (74/100) 

=  (150  mg/L)  (74/100) 


=  111  mg/L 
C  =0 

D  -  (Mg2^.  mg/L)  (74/24  3) 
-(16  mg/L)  (74/24  3) 
-  49  mg/L 

Hydrated  Lime  (A  +  B  +  C  +  D)  1  15 

(Ca(0H)2)  Feed. 
mg/L 


Hydroxide  Alkalinity  =  0 


Purity  of  Lime,  as  a  decimal 
(8  mg/L  +  111  mg/L  +  0  +  49  mg/L)  1 


0  90 


(168  mg/L)  (1  15) 
090 
^  215  mg/L 


Calculate  the  soda  ash  required  in  milligrams  per 
liter. 

Noncarbonate       jotal  Hardness.     Carbonate  Hardness. 
Hardness.        -  rng/L  as  CaCOs  ~  mg/L  as  CaC03 
mg/L  as  CaCOs 

240  mg/L  -  150  mg/L 
=  90  mg/L  as  CaC03 


Soda  Ash 
(Na2C03)  = 
Feed.  mg/L 


,  Noncarbonate  Hardness.,  /-nc/mm 
<mg/LasCaC03  )  006/100) 

=  (90  nr^g/L)  (106/100) 
=  95  mg/L 


Softening  109 


3.  Caculate  the  dosage  of  carbon  dioxide  required 
for  recarbonation. 

Excess  Lime,_  (A  +  B  +  C  +  D)  (0  15) 
mg/L 

=  (8mg/t  +  111  mg/L  +  0  +  49mg/L)(0l5) 
=  (168  mg/L)  (0  15) 
=  25  mg/L 

Total  CO2     ^  (Ca(0H)2  excess.  mg/L)  (44/74) 
Feed,  mg/1  +  (Mg'^2  residual.  mg/L)  (44/24  3) 

=  (25  mg/L)  (44/74)  +  (2  mg/L)  (44/24  3) 

=  15  mg/L  +  4  mg/L 

=  19  mg//. 


Answers  to  questions  on  page  81 . 

14.3H  In  the  lime  softening  process,  calcium  is  precipitated 
out  as  calcium  carbonate  and  magnesium  hydroxide. 

14.31  Partial  lime  softening  (no  magriesium  removal)  re- 
moves hardness  caused  by  calcium  ions.  This  may 
be  referred  io  as  calcium  hardness. 

14.3J  In  split  lime  treatment,  a  portion  of  the  water  is 
treated  with  excess  lime  to  remove  the  magnesium  at 
a  high  pH.  Tne  source  water  (the  remaining  portion) 
is  added  in  the  next  basin  to  neutralize  (lower  the  pH) 
the  excess-lime-treated  portion. 

14.3K  Recarbonation  is  a  process  in  which  carbon  dioxide 
is  bubbled  into  the  water  being  treated  to  convert 
carbonate  ions  to  bicarbonate  ions  to  stabilize  the 
->lu*ion  against  the  precipitation  of  carbonate  com- 
pounds. The  pH  may  also  be  lowered  by  the  addition 
of  acid. 


Answers  to  questions  on  page  82. 

14.3L  Lime-soda  ash  softening  is  used  when  lime  alone  will 
not  remov-i  enough  hardness. 

14.3M  Noncarbonate  hardness  is  removed  by  the  addition 
of  soda  ash  in  the  chemical  precipitation  softening 
process. 

Answers  to  questions  on  page  82. 

14  3N  Where  the  daily  requirements  tor  lime  are  small,  lime 
IS  usual'y  delivered  to  the  wrter  treatment  plant  in 
bags. 

14.30  Considerahle  heat  is  generat(5d  if  quicklime  acciden- 
tally gets  wet. 

1 4.3P  Lime  may  be  applied  by  dry  foeding  techniques  using 
volumetric  or  gravimetnc  feaders. 

Answers  to  questions  on  page  83. 

14.4 A  When  the  alu:n  dose  i'lcreases  for  coagulation,  the 
lime  dose  rr<ust  be  increased  also. 

14.4B  Color  can  be  removed  from  water  by  coagulation 
with  alum  at  'ow  pH  values.  The  high  pH  values 
required  during  softening  tend  to  "set"  the  color 
which  then  becomes  very  difficult  to  remove. 


Answers  to  questions  on  page  84. 

14.5A  A  slight  excess  of  lime  can  cause  a  scale  to  form  on 
the  filter  sand,  distribution  mains,  and  household 
plumbing. 


ERIC 


14.5B  Excess  caustic  and  unprecipitated  carbonate  ions 
(pin  floe)  can  be  removed  from  softened  water  by 
recarbonation.  Recarbonation  is  the  bubbling  of  car- 
bon dioxide  through  the  water  being  treated  to  lower 
the  pH.  Recarbonation  can  be  accomplished,  to  a 
degree,  by  using  source  water  in  the  split  treatment 
mode. 

14.5C  The  marble  test  is  used  to  deter.nine  if  a  water  is 
stable.  The  Langelier  Index  is  also  used  to  determine 
the  corrosivity  of  water. 

14  5D  Suspending  a  couple  of  nails  on  strings  in  a  filter  can 
indicate  if  the  water  is  stable.  If  the  nails  are  rusting, 
the  water  is  corrosive.  If  a  scale  forms  on  the  nails, 
then  scale  is  forming  on  your  filter  media  and  in  your 
distribution  system. 


Answers  to  questions  on  page  84. 

1 4.6A  Wooden  paddles  should  be  used  as  cleaning  tools  on 
any  slaker  in  operation.  A  metal  tool  will  damage  the 
slaker  and  could  even  injure  the  operator  if  dropped 
by  accident.  However,  a  wooden  paddle  will  likely  be 
broken  up  with  no  damage  to  the  equipment  or 
operator. 

14.6B  Information  on  how  to  safely  maintain  equipment 
may  be  found  in  equipment  manuals  provided  by 
equipment  suppliers  and  manufacturers. 


Answers  to  questions  on  •^age  85. 

14.7A  A  disadvantage  <  recirculating  sludge  back  to  the 
primary  mix  area  is  that  an  increase  in  magnesium 
could  result. 

1478  Only  trial  and  error  will  really  determine  if  sludge 
recirculation  will  serve  a  useful  purpose  in  your  plant. 

1 4.8A  Records  should  be  kept  on  the  amounts  of  treatment 
plant  chemicals  ordered  and  the  amounts  fed. 


Answers  to  questions  on  page  86. 

14.9A  When  selecting  the  target  hardness  for  a  water 
softening  plant,  consider  the  uses  of  the  softened 
water  and  the  cost  of  softening. 

14.98  If  lime  added  to  water  does  not  reduce  the  hardness 
of  a  water  sufficiently,  use  the  optimum  lime  do^'e 
and  run  jar  tests  with  varying  soda  ash  doses.  Select 
the  soda  ash  dose  that  will  produce  a  water  with  a 
softness  of  around  80  to  90  mg/L. 

Ar  .vers  to  questions  on  page  90. 

14.9C  The  overfeeding  of  chemicals  is  a  waste  of  money 
and  quality  control  will  suffer. 

14.9D  What  should  be  the  lime  feeder  setting  in  pounds  per 
day  to  treat  a  flow  of  2  MOD  when  the  optimum  Tme 
dose  IS  160  mg/L'? 

Known  Unknown 

Flow.  MGD         =  2  MGD  Feeder  Setting. 

Lime  Dose.  mg/L  =  16O  mg/L  lbs/day 

Calculate  the  lime  feeder  setting  in  pounds  per  day. 

^Ibs/day^^"'"^'"  (Flow.  MGD)  (Lime.  mg/L)  (8.34  lbs/gal) 
=  (2  MGD)  (160  mg/L)  (8.34  lbs/gal) 
=  2669  lbs/day 

.  125 


110  Water  Treatment 


1 4  9E  How  much  soda  ash  s  required  m  pounds  per  day  to 
remove  40  mg//.  hardness  from  a  flow  of  2  MGD'^ 

Known  Unknown 
Flow.  MGD  =  2  MGD      Feeder  Setting. 

Hardness  Removed,  mg/t  =  40  mg/L  lbs/day 

1  Calculate  the  soda  ash  dose  in  milligrams  per  liter. 
Soda  Ash,  mg/l  =  (1.1)  (Hardness  Removed,  mg/l) 

-  (1  1)(40  mg/L) 
=  44  mg/l 

2  Determine  the  soda  ash  feeder  setting  in  pounds 
per  day. 

^Ibs/da^^"'"^  ~  (Flow,  MGD)  (Soda  Aoh.  mg/L)  (8  34  lbs/gal) 

-  (2  MGD)  (44  mg/L)  (8  34  IbS/gal) 

-  734  lbs/day 


14.14A  The  disposal  of  spent  brine  is  a  problem  because 
the  brine  is  very  corrosive  and  toxic  to  many  living 
things  in  the  environment. 


Answers  to  questions  on  page  100. 

14.15A  One  valve  that  fails  to  open  or  close  during  a 
regeneration  stage  could  mean  a  sto^'age  tank  full 
of  salty  water  or  no  brine. 

14  15B  Brine  pumps  and  piping  must  receive  constant 
attention  because  a  saturated  bnne  solution  Is  very 
corrosive.  An  uncontained  brine  leak  will  only  get 
worse, 

1 4.1 5C  Packing  is  recommended  over  mechanical  seals  on 
bnne  pumps  because  sand  in  mechanical  seals  will 
result  in  high  repair  and  maintenance  costs. 


ANSWERS  TO  QUESTIONS  IN  LESSON  2 

Answers  to  questions  on  page  95. 

14  10A  The  three  basic  types  of  softeners  on  the  market 
are: 

1 .  An  upflow  unit, 

2  A  gravity  flow  unit,  and 

3  A  pressure  downflow  unit  (tht?  most  common). 

14.108  Dunng  the  regeneration  cycle  the  softener  is  taken 
out  of  service.  Salt  in  the  form  of  a  concentrated 
brine  solution  is  used  to  r-^generate  (recharge)  the 
ion  exchange  media.  When  the  brine  solution  is  fed 
into  the  media,  the  sodium  cations  are  exchanged 
for  calcium  and  magnesium  cations  As  the  brine 
solution  travels  down  through  the  media,  the  sodi- 
um cations  are  attached  to  the  media  while  the 
calcium,  magnesium  and  chloride  (from  the  salt) 
ions  How  to  waste.  After  the  regeneration  has  taken 
place,  the  bed  is  ready  to  be  placed  in  service  again 
to  remove  calcium  and  magneslun.  by  ion  ex- 
change. 


Answers  to  questions  on  page  97. 

14.11  A  The  source  water  hardness  is  the  main  consider- 
ation in  determining  the  length  of  the  service  stage 
of  an  ion  er'^hange  softener. 

14.1  IB  The  purpose  of  the  backwash  stage  is  to  expand 
and  clean  the  media  or  resin  particles  and  also  to 
free  any  material  such  as  iron  and  manganese  that 
might  have  been  removed  dunng  the  softening 
stage. 

14.1 1C  Ion  excoange  soiteners  are  regenerated  by  the  use 
of  a  saturated  bnne  solution 

1 4.1 1 D  During  the  rinse  stage  the  softener  effluent  goes  to 
waste. 


Answers  to  questions  on  page  99. 

14.12A  Hardness  should  be  monitored  in  the  effluent  from 
an  ion  exchange  softener. 

14.13A  High  chlorine  residual  levels  applied  to  softening 
units  could  damage  the  resin  and  reduce  its  life 
5;pan. 


Answers  to  questions  on  page  101. 

14.16A  The  maximum  expected  hardness  level  in  the  efflu- 
ent from  an  ion  exchange  softener  should  not 
exceed  one  grain  hardness  per  gallon  (17.1  mg/L). 

14.16B  The  purpose  of  the  backwash  stage  is  to  remove 
trapped  turbidity  particles  and  other  insoluble  mate- 
nal  that  is  trapped  in  the  resin, 

14.16C  If  the  rinse  rate  starts  too  soon,  the  brine  solution 
could  be  forced  out  of  the  unit  before  adequate 
contact  time  has  elapsed.  If  the  rinse  rate  is  too  low, 
all  the  waste  matenal  might  not  be  removed  from 
the  unit  before  it  goes  into  the  service  stage. 

14.16D  If  hardness  leakage  is  excessive  immediately  fol- 
lowing a  regeneration  stage,  shut  the  unit  down  and 
check  the  media  level.  The  bed  could  be  disrupted 
from  excessive  backwash  or  nnse  rates.  Iron  foul- 
ing could  also  cause  a  channeling  condition  to 
occur  and  cause  the  water  to  short-circuit  through 
the  media  without  contacting  the  complete  bed 
area. 


Answers  to  questions  on  page  101. 

14.17A  Ion  exchange  softeners  must  be  drained  and  filled 
slowly  during  startup  and  shutdown  to  prevent 
surging  of  the  media  which  w'll  either  wash  it  out  of 
the  unit  or  disrupt  it,  thus  making  the  media  uneven 
and  creating  a  channeling  problem. 

14.178  If  the  pipe  work  is  deteriorating  from  the  brine 
solution,  PVC  pipe  should  be  used  as  a  replace- 
ment. 


Answers  to  questions  on  page  105. 

14  18A  A  source  water  has  a  hardness  of  150  mg/L  as 
CaCOg.  What  is  the  hardness  in  grains  per  gallon? 

Known  Unknown 

Hardness,  mg/l  =  150  nig/l    Hardness,  grams/gallon 

Calculate  the  source  water  hardness  in  grains  per 
gallon. 

Hardness,      ^  (Hardness,  mg/L)  (1  gpg) 
grams/gallon  17.1  mg/L 

_  (150  mg/L)(1  gpg) 

17.1  mg/L 
=  8.8  grams/gallon 


ERIC 


126 


Softening  111 


1 4.1 8B  An  ion  exchange  softener  contains  60  cubic  feet  of 
resin  with  a  hardness  removal  capacity  of  25  kilo- 
grains  per  cubic  foot  of  media.  The  water  being 
treated  has  a  hardness  of  250  mg/L  as  CaCOj.  How 
many  gallons  of  water  can  be  softened  before  the 
softener  will  require  regeneration*? 

Kno^n  Unknown 
Resm  Vol.  cu  ft     =  60  cu  ft  Water  Treated,  gal 

Removal  Capacity.  =  25.000  gr/cu  ft 
g^fcu  ft 

Haidness.  mg/l     =  250  mg/l 

1.  Convert  the  '  ardness  from  mg/L  to  grains  per 
gallon. 

Hardness.     _  (Hardness.  mg/L)  (1  gram/gallon) 
grams/gallon"  17.1  mg/L 

^250  mg/L)(l  grarn/gailon) 
17.1  mg/L 
=  14.6  grams/gallon 

2.  Calculate  the  exchange  capacity  of  the  softener 
in  grains. 

Exchange 

Capacity."  (Resin  Vol.  cu  ft)  (Removal  Capacity,  gr/cu  ft) 
grams     .  (60  cu  ft)  (25.000  grams/cu  ft) 

-  1 .500.000  grams  of  hardness  removal  capacity 


3  Calculate  the  volume  of  water  .n  gallons  that 
may  be  treated  before  regeneration 

Water  Treated.  ^  Exchange  Capacity,  grains 

9a'  Hardness,  grains/gallon 

_  1.500.000  grams 

14  6  grams/gallon 

=  102.700  gallons 

Therefore.  102.700  gallons  of  water  with  14.6 
grains  of  hardness  per  gallon  of  water  can  be 
treated  before  the  resm  becomes  exhausted. 

Answers  to  questions  on  page  106. 

14  19A  Source  water  is  blended  with  the  effluent  from  an 
ion  exchange  softener  so  the  consumers  will  re- 
ceive water  with  an  acceptable  hardness.  Deliver- 
ing water  with  zero  hardness  is  very  expensive  and 
the  water  is  very  corrosive. 

14  20A  Records  that  should  be  kept  by  the  operator  of  an 
ion  exchange  softening  plant  include: 

1  T  jtal  daily  flow  through  unit. 

2.  Blend  rates. 

3  Total  daily  gallons  that  have  bypassed  unit, 

4  Gallons  of  brine  used  each  day, 

5.  Pounds  of  salt  used  each  day,  and 

6.  Results  of  tests  performed  on  source  water, 
softener  effluent  and  blended  water 


OBJECTIVE  TEST 

Chapter  14.  SOFTENING 


Please  write  your  name  and  mark  the  correct  answers  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1 .  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
questions. 

TRUE-FALSE 

1  Most  of  the  hardness  in  water  is  caused  by  iron. 

1  True 
2.  False 

2  Some  industrial  processes  require  softer  water  than  is 
produced  by  municipal  water  treatment  plants  which 
soften  water 

1.  True 

2.  False 

3  The  lime-soda  ash  softening  process  produces  water 
with  zero  hardness. 

1.  True 

2.  False 

4,  Water  having  a  hardness  caused  by  calcium  and  mag- 
nesium bicarbonate  ion  can  usually  be  softened  to  an 
acceptable  level  using  lime  only. 

1.  True 

2.  False 


5  Recarbonation  is  a  process  which  causes  the  precipita- 
tion of  calcium  carbonate 

1  True 
2.  False 

6  Water  which  cannot  be  softened  by  lime  contains  car- 
bonate hardness 

1  True 
2.  False 

7  Noncarbonate  hardness  requires  the  addition  of  a  com- 
pound containing  carbonate  to  soften  the  water. 

1.  True 

2.  False 

8  The  addition  of  caustic  soda  to  water  can  remove  both 
carbonate  and  noncarbonate  hardness. 

1  True 
2.  False 

9.  Carbonate  hardness  is  caused  by  the  presence  of 
sulfate  and  chloride  ions. 

1.  True 


112  Water  Treatment 


10  All  three  forms  of  alkalinity  can  exist  at  once  in  a  sample  23.  The  ion  exchange  softener  regeneration  and  bnne 
of  water  stages  are  two  different  stages. 

1  True  1  True 

2.  False  2.  False 


1 1  Quicklime  should  never  be  stored  close  to  combustible 
materials. 

1.  True 

2.  False 


24.  During  the  rinse  stage  the  softener  effluent  goes  to 
storage. 

1  True 
2.  False 


12  Do  not  rub  your  eyes  if  they  become  irritated  with  lime 
dust. 

1.  True 

2.  False 

13  When  the  alum  dose  is  decreased  for  coagulation,  the 
lime  dose  for  softening  can  be  

1.  Decreased 

2.  Increased. 

1 4  Recarbonation  will  actually  increase  the  hardness  of  the 
water  slightly. 

1.  True 

2.  False 

15.  Always  wear  goggles  or  a  face  shield  when  working 
with  hme  that  has  been  or  ts  in  the  process  of  slaking. 

1.  True 

2.  False 

16  Records  will  help  a  good  operator  to  be  a  better 
operator 

1.  True 

2.  False 

17.  An  overfeed  of  lime  to  some  waters  will  actually  in- 
crease the  hardness. 

1  True 
2.  False 

18.  Ion  exchange  water  softening  is  a  process  in  which  the 
hardnass-causing  sodium  ions  are  replaced  by  calcium 
and  magnesium  ions. 

1.  True 

2.  False 


25  Ion  exchange  softening  will  remove  iron  and  manga- 
nese in  either  the  soluble  or  precipitated  form. 

1  True 
2.  False 

20  A  oaturated  brine  solution  will  attack  any  unprotected 
metallic  surface  it  comes  in  contact  with. 

1.  True 

2  False 

27  The  use  of  mechanical  seals  on  brine  pumps  is  recom- 
mended over  packing. 

1.  True 
2  False 

28  The  brine  tanks  must  be  protected  from  contamination 
just  like  any  other  water  storage  facility. 

1.  True 

2.  False 

29.  If  iron  fouling  appears  to  be  a  problem  with  an  ion 
exchange  softener,  the  duration  of  the  backwash  stage 
should  be  decreased. 

1.  True 

2.  False 

30.  If  the  rinse  rate  of  an  ion  exchange  softener  is  too  low, 
all  of  the  waste  material  might  not  be  removed  from  the 
unit  before  it  goes  into  the  service  stage. 

1.  True 

2.  False 


19  Hard  water  has  an  adverse  effeci  on  health. 

1,  True 

2.  False 

20.  Lime  softening  will  remove  noncarbonate  hardness. 

1  True 
2.  False 

21.  Changes  in  the  hardness  of  the  source  water  are 
automatically  treated  by  an  ion  exchange  unit. 

1.  True 

2.  False 

22.  At  the  beginning  of  the  backwash  stage,  the  backwash 
water  should  be  applied  at  a  slow  steady  rate. 

1.  True 

2.  False 

ERIC 


MULTIPLE  CHOICE 

31.  Carbonate  hardness  is  caused  by 

1.  Calcium  chlonde. 

2.  Calcium  sulfate. 

3.  Magnesium  bicarbonate. 

4.  Magnesium  chloride. 

5.  Magnesium  sulfate. 

32.  The  two  basic  methods  of  softening  a  municipal  water 
supply  are 

1.  Ion  exchange  and  chemical  precipitation. 

2.  Ion  exchange  and  lime. 

3.  Ion  exchange  and  excess  lime. 

4.  Lime  and  soda  ash. 

5.  Lime-soda  ash  and  caustic  soda. 


28 


Softening  113 


33.  Regardless  of  the  method  used  to  soften  water,  con- 
sumers usually  receive  a  softened  water  with  a  hard- 
ness of  around  

1.  30  to  40  mg/L. 

2.  50  to  60  mg/L. 

3.  80  to  90  mg/L. 

4.  140  to  150  mg/L 

5.  150  to  200  mg/L 


41  The  chemical  feed  rates  produced  by  jar  tests  may  not 
produce  the  exact  same  results  in  an  actual  plant 
because  of  differences  in 

1  Coagulant  feed 

2  Mixing  equipment. 

3  Sizes  and  shapes  of  jars  and  basins. 

4  Water  quality. 

5  Water  temperature. 


34.  Removal  of  noncarbonate  hardness  by  chemical  pre- 
cipitation requires  the  addition  of  a  compound  contain- 
ing 

1.  Bicarbonate 

2.  Calcium. 

3.  Carbonate. 

4.  Chloride. 

5.  Sulfate. 

35.  Items  to  be  cons'dered  when  deciding  whether  to  use 
caustic  soda  or  tne  lime-soda  ash  process  to  soften 
water  include 

1.  Amounts  of  sludge  produced. 

2.  Costs. 

3.  Disposal  of  sludge. 

4.  Handling  and  feeding  of  chemicals. 

5.  Source  water  characteristics. 

36.  Alkalinity  exists  as 

1.  Bicarbonate. 

2.  Carbonate. 

3.  Hydroxide. 

4.  pH. 

5.  Sulfate. 

37.  How  frequently  should  alkalinity  be  measured  if  the 
source  water  for  a  lime-soda  ash  process  is  subject  to 
change?  Every 

1.  2  hours. 

2.  4  hours. 
3-  8  hours. 

4.  16  hours. 

5.  24  hours. 


42.  Source  water  quality  changes  of  concern  to  the  opera- 
tor of  a  lime-soda  ash  softening  plant  include  changes  in 

1.  Alkalinity 

2.  Hardness. 

3.  pH. 

4  Temperature. 

5  Turbidity. 

43.  A  soft  to  moderately  hard  water  will  have  a  haraness  of 
 nrig/L  as  calcium  carbonate. 

1 .  0  to  45 

2.  46  to  90 

3.  91  to  130 

4.  131  to  170 

5.  171  to  250 

44.  The  common  stages  of  operation  of  an  ion  exchange 
softener  include 

1.  Backwash 

2  Brtne. 

3  Recarbonation. 

4.  Rinse. 

5.  Service 

45.  Most  ion  exchange  resins  on  the  market  will  raitce  \n 

exchange  capacity  from    grains  of  hardr.ess 

removed  per  cubic  foot  of  resin. 

1.  100  to  500 

2.  500  to  1000 

3.  1000  to  5000 

4.  5000  to  20,000 

5.  20,0C0  to  30,000 


38.  Which  of  the  following  protective  devices  could  be  used 
to  protect  you  from  lime? 

1.  Filter  mask 

2.  Gloves 

3  Long-sleeved  shirt 

4.  Safety  glasses 

5.  Skin  cream 

39.  How  can  the  pH  of  softened  water  be  lowered  after  lime 
softening?  By  the  use  of 

1.  Carbon  dioxide  gas. 

2.  Caustic  soda. 

3.  Hydrochloric  acid. 

4.  Source  water. 

5.  Sulfuric  acid. 


46  The  backwash  duration  and  flow  rate  of  an  ion  ex- 
change softener  will  vary  depending  on  the 

1.  Amount  of  alkalinity  being  removed. 

2.  Amount  of  hardness  being  removed. 

3.  Manufacturer. 

4.  Temperature  of  the  water. 

5.  Type  of  resin  used. 

47  Which  water  quality  indicators  should  be  monitored  in 
the  influent  to  an  ion  exchange  softener? 

1  Alkalinity 

2  HardnpGS 

3  Iron  and  manganese 

4.  pH 

5.  Temperature 


40.  The  most  common  method  of  sludge  disposal  is . 
disposal. 

1.  Drying  bed 

2.  Land  application 

3.  Landfill 

4.  Sewer 

5.  Sludge  recirculation 


ERIC 


48  Whal  type  of  pipe  ma.^nal  should  be  used  in  a  brine 
system'^ 

1.  Boron 

2.  Galvanized 

3.  Iron 

4.  PVC 

5.  Stoel 


on 


114  Water  Treatment 


49  What  can  the  operator  do  if  iron  fouling  appears  to  be  a 
problem  on  an  ion  exchange  softener'^ 

1 .  Apply  a  chemical  cleaner  such  as  sodium  bisulfate 

2.  Decrease  the  strength  of  the  brine  used  in  the 
regeneration  stage 

3.  Increase  backwash  flow  rates 

4.  Increase  duration  of  backwash  stage 

5.  Increase  duration  of  service  stage 

50  Hardness  may  be  expressed  as 

1 .  Grains  per  gallon. 

2.  Milligrams  per  liter 

3.  Milliliters  per  liter. 

4.  Pounds  per  day. 

5.  Pounds  per  million  gallons 


51  How  many  gallons  of  water  vMth  a  hardness  of  14  grains 
per  gallon  may  be  treated  by  an  ion  exchange  softener 
with  an  exchange  capacity  of  20,000  kilograms'? 

1  OJO  M  Gal 

2  1  07  M  Gat 
3.  1  24  M  Gal 

4  1.43  M  Gal 

5  1.67  fv^  Gal 

52.  How  many  hours  will  an  ion  exchange  softening  unit 
operate  when  treating  an  average  flow  of  500  GPW 
The  unit  is  capable  of  softening  1,500,000  gallons  of 
water  before  requiring  regeneration 

1  25  hours 

2.  30  hours 

3.  35  hours 

4.  40  hours 

5.  50  hours 


o 

ERIC 


130 


CHAPTER  15 

TRIHALOMETHANES 

by 

Mike  McGuire 


13 


116  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  15.  Trihalomethanes 


OBJECTIVES 


GLOSSARY  

15.0  The  Trihalomethane  (THM)  Problem  . 

15.1  Feasibility  Analysis  Process  

15.2  Problem  Definition  

15.20  Sampling  

15.21  THM  Calculations  

15.22  Chemistry  of  THM  Formation . 

15.3  Control  Strategies  

15.4  Existing  Treatment  Processes  


Page 
.  117 
.  118 
.  119 
.  121 
121 
121 
122 
123 
124 
124 


15.5  Treatment  Process  Research  Study  Results   ^24 

15.50  Consider  Options  

15.51  Remove  THMs  After  They  Are  Formed   ^25 

15.52  Remove  THM  Precursors  

15.53  Alternate  Disinfectants  

15.6  Selection  and  Implementation  of  a  Cost-Effective  Alternative  

15.7  Regulatory  Update  

15.8  Summary  and  Conclusions  

15.9  Arithmetic  Assignment  

15.10  Additional  Reading  

Suggested  Answers  

Objective  Test  


126 
128 
128 
129 
129 
130 
130 
131 
132 


ERIC 


132 


Trihalomethanes  117 


OBJECTIVES 


Chapter  15.  TRIHALOMETHANES 


Following  completion  of  Chapter  15,  you  should  be  able 
to: 

1.  Describe  how  trihalomethanes  are  formed, 

2.  Explain  why  trihalomethanes  are  a  problem  in  drinking 
water, 

3.  Collect  samples  for  trihalomethane  analysis, 

4.  Identify  control  strategies  for  trihalomethanes, 

5.  Describe  treatment  processes  capable  of  controlling  tri- 
halomethanes, and 

6.  Select  and  implement  a  cost-effective  means  of  control- 
ling trihalomethanes. 


118  Water  Treatment 


GLOSSARY 

Chapter  15.  TRIHALOMETHANES 

CARCINOGEN  (car-SlN-o-jen)  CARCINOGEN 
Any  substance  which  tends  to  produce  a  cancer  in  an  organism. 

MAXIMUM  CONTAMINANT  LEVEL  (MCL)  MAXIMUM  CONTAMINANT  LEVEL 

The  largest  allowable  amount.  MCLs  for  various  water  quality  indicators  are  specified  in  the  National  Interim  Primary  Dnnkinq 
Water  Regulations  (NIPDWR).  ^  ^ 

PRECURSOR,  THM  (pre-CURSE-or)  PRECURSOR.  THM 

Natural  organic  compounds  found  in  all  surface  and  groundwaters.  These  compounds  MAY  read  with  halogens  (such  as  chlo- 
rine)  to  form  tnhalomethanes  (try-HAL-o-METH-hanes)  (THMs),  they  MUST  be  present  in  order  for  THMs  to  form. 

REPRESENTATIVE  SAMPLE  REPRESENTATIVE  SAMPLE 

A  portion  of  matenal  or  water  that  is  as  nearly  identical  in  content  and  consistency  as  possible  to  that  in  the  larqer  body  of 
material  or  water  being  sampled. 

TRIHALOMETHANES  (tri-HAL-o-METH-hanes)  TRIHALOMETHANrS 
Derivatives  of  methane,  CH^,  in  which  three  halogen  atoms  (chlorine  or  bromine)  are  substituted  for  three  of  the  hydrogen 
atoms  Often  formed  during  chlorination  by  reactions  with  natural  organic  matenals  in  the  water.  The  resultant  compounds 
(THMs)  are  suspected  of  causing  cancer. 

VOLATILE  (VOL-uh-tull)  VOLATILE 

A  substance  that  is  capable  of  being  evaporated  or  easily  changed  to  a  vapor  at  relatively  low  temperatures.  For  example  aas- 
oline  IS  a  highly  volatile  liquid  ^  ^ 


ERJC 


Trihalomethanes  119 


CHAPTER  15.  TRIHALOMETHANES 


15.0   THE  TRIHALOMETHANE  (THM)  PROBLEM 

For  the  past  few  decades  water  utilities  have  been  con- 
cerned about  the  presence  of  organic  compounds  in  drink- 
ing water.  The  analytical  methods  for  detecting  Inorganic 
compounds  such  as  calcium,  magnesium,  and  iron  have 
been  known  for  many  decades.  However,  the  ability  to 
analyze  for  organic  compounds  in  water  has  been  devel- 
oped only  recently.  What  are  organic  compounds'^  Organic 
compounds  are  defined  as  those  compounds  that  contain  a 
carbon  atom.  Carbon  is  one  of  the  baric  chemical  elements. 
Examples  of  organic  compounds  include:  proteins,  carbohy- 
drates, fats,  vitamins,  and  a  wide  variety  of  compounds  that 
modern  technology  has  created. 


EQUATION  1 


In  1 974.  researchers  with  the  U.S.  Environmental  Protec- 
tion Agency  (EPA)  and  in  the  Netherlands  published  their 
findings  that  trihalomethanes  are  formed  in  dnnking  water 
when  free  chlorine  comes  in  contact  with  naturally  occurring 
organic  compounds  (THM  PRECURSORS^).  Trihalometh- 
anes are  a  class  of  organic  compounds  where  there  has 
been  a  replacement  of  three  hydrogen  atoms  in  the  methane 
molecule  with  three  halogen  atoms  (chlonne  or  bromine) 
The  four  most  commonly  found  THMs  are  chloroform, 
bromodichloromethane,  dibromochloromethane,  and  bro- 
moform  (Figure  15.1).  While  it  is  theoretically  possible  to 
form  lodlne-substituted  THMs,  they  are  rarely  found  in 
treated  water  and  they  are  not  regulated  at  this  time.  In 
general,  methane  is  not  involved  in  the  THM  reaction.  The 
production  of  THMs  can  generally  be  shown  as: 


Free 
Chlorine 


Natural 
+  Organics  Bromide 
(precursor) 


THMs  + 


Other 
Products 


Free  chlorine  is  added  to  drinking  water  as  a  disinfectant. 
The  naturally  occurring  organics  get  into  water  when  the 
water  partially  dissolves  organic  materials  from  algae, 
leaves,  bark.  wood,  soil  and  other  similar  matenals.  This 
dissolved  action  is  similar  to  what  happens  when  a  teabag  is 
placed  in  hot  water;  the  water  dissolves  those  parts  of  the 
tea  leaves  which  are  soluble  organic  and  inorganic  com- 
pounds. While  It  IS  possible  to  form  THMs  by  reactions 
between  chlorine  and  industrial  organic  chemicals,  the  over- 
whelming bulk  of  THM  precursors  in  water  are  from  natural 
organic  compounas 

One  source  of  bromide  is  sea  water.  Water  agencies 
whose  supplies  are  subject  to  sea  water  intrusion  can 
expect  THMs  in  their  treated  water  to  have  high  levels  cf 
bromide.  Bromide  reaction  products  can  be  found  in  most 
surface  waters,  even  where  bromide  concentrations  are  low. 
The  "other  products"  formed  in  this  reaction  are  very  poorly 
understood  and  are  not  regulated  at  this  time. 

After  THMs  were  discovered  in  drinking  waters  around  the 
country,  several  studies  were  made  of  the  possible  health 
effects  of  THMs  in  general  and  chloroform  (a  THM)  in 
particular.  The  results  of  these  tests  indicated  that  chloro- 
form caused  cancer  in  laboratory  animals  (rats  and  mice) 
and  was  suspected  of  causing  cancer  in  humans.  Further 
studies  coniparing  people  who  used  different  sources  of 
drinking  water  suggested  that  there  may  be  a  link  between 
the  presence  of  man-made  organic  compounds  like  THMs 
and  increased  levels  of  cancer.  Animal  feeding  experiments 
and  population  studies  are  not  definite  proof  that  THMs  in 
dnnking  water  cause  cancer.  Under  the  Safe  Drinking  Water 
Act.  EPA  may  pass  a  regulation  for  any  contaminant  which 
MAY  HAVE  any  adverse  health  '  feet. 

On  November  29,  1979,  the  THM  regulations  were  pub- 
lished in  the  FEDERAL  REGISTER.  These  regulations  wf  re 
amended  on  February  28. 1983  (see  Section  15.7,  "Regula- 
tory Update").  The  details  of  the  regulation  are  covered  in 
Chapter  22.  "Dnnking  Water  Regulations,"  and  general  as- 
pects of  the  regulation  are  outlined  below: 

MAXIMUM  CONTAMINANT  LEVEL:  O.lO  mg/L  total  triha- 
lomethanes (TTHMs)  —  sum  of  the  concentrations  of 
chloroform,  bromodichloromethane,  dibromochloro- 
methane. and  bromoform. 


'  Precursors,  THM  (pre-CURSE-ors).  Natural  organic  compounds  found  in  all  surface  and  groundwaters  These  compounds  MA  Y  react 
with  halogens  (such  as  chlorine)  to  form  trihalomethanes  (try-HAL-o-METH-anes)  (THMs)  they  MUST  be  present  in  order  for  THMs  to 
form. 


form. 

ERIC  jn- 


120  Water  Treatment 


H 


H 


H 


CI 


CI 


H 

Methane,  CH^ 


CI 

Chloroform,  CHCI, 


H 


Br  C  Br 


Br 

Bromoform,  CHBr- 


Ci 


H 


-C 
I 

I 

CI 


Br 


CI 


H 


Br 


Br 


Bromodichloromethane,  CHBrCI, 


Dibrcmochloromethane,  CHBrjCI 


Fig.  15. 1   Methane  and  THMs 


ERIC 


Trihalomethanes  121 


APPLIES  TO-  All  community  water  systems  that  add  a 
disinfectant  to  their  water  supply  which  serve  a  popula- 
tion greater  than  10,000  persons. 

MONITORING  REQUIREMENTS:  Monitoring  compliance 
based  on  an  annual  running  TTHM  (total  trihalometh- 
ane)  average  of  four  quarters  of  data.  Schedule,  loca- 
tions, and  numbers  of  samples  depends  on  system  size 
and  to  be  worked  out  with  State  or  EPA. 

ENSURING  MICROBIOLOGICAL  QUALITY:  State  or  EPA 
must  be  notified  of  significant  modifications  to  treatment 
processes  to  remove  TTHMs  in  order  to  ensure  micro- 
biological quality  of  the  treated  water. 

The  MCL  for  TTHMs  was  not  established  on  the  basis  of 
the  health  effects  data,  but  was  set  as  a  feasible  level  for 
compliance.  The  supporting  material  for  the  regulation 
states  very  clearly  that  the  MCL  may  be  lowered  in  the  future 
to  0.025  mg/L  -:.  perhaps  as  low  as  0.010  mg/L 

The  rest  of  this  chapter  is  devoted  to  a  discussion  of  how 
to  collect  samples  for  THM  analysis  and  how  a  utility  can 
evaluate  the  many  alternatives  available  to  control  THMs  <n 
its  system.  This  discussion  is  presented  in  outline  form.  A 
much  more  detailed  treatment  of  control  techniques  for 
THMs  IS  presented  in  an  EPA  publication  entitled  TREAT- 
MENT TECHNIQUES  FOR  CONTROLLING  TRIHALO- 
METHANES IN  DRINKING  WATER,  by  J.M.  Symons,  et  j., , 
September  1981  A  large  part  of  this  chapter  is  a  summary 
of  matenal  from  that  source. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  131. 

15  OA  What  are  THM  precursors'^ 

15  OB  Why  IS  free  chlonne  added  to  drinking  water'^ 

15  OC  What  IS  one  source  for  bromide  in  drinking  water'? 

15.0D  How  are  trihalomethanes  formed'^ 

15.1    FEASIBILITY  ANALYSIS  PROCESS 

In  any  problem  solving  process,  it  is  useful  to  follow  a 
senes  of  prescribed  steps  that  will  lead  you  to  the  most  cost- 
effective  solution.  Table  15  1  lists  the  stages  of  a  feasibility 
analysis  process  that  has  been  use^  to  solve  a  water  utility's 
THM  problem.  However,  the  process  outlined  in  Table  15  1 
IS  very  general  and  can  also  be  applied  to  solving  other 
treatment  or  operational  problems. 


TABLE  15.1    FEASIBILITY  ANALYSIS  PROCESS 

1  Determine  extent  of  THM  problem 

a  Monitor  THM  levels 

b  THM  chemistry  (time  of  formation) 
2.  Evaluate  control  strategies 

a  Change  sources  of  supply 

b  Treatment  options 

(1)  Remove  THMs 

(2)  Remove  precursors 

(3)  Adjust  or  modify  the  chlorine  application  points 

(4)  Use  alternate  disinfectants 

3  Evaluate  existing  treatment  processes 

4.  Examine  studie3  of  proposed  treatment  processes 
(Bench-,  pilot-  and  full-scale) 

5  Select  a  cost-eftective  option 

6  Implement  the  cnosen  option 


15.2    PROBLEM  DEFINITION 

In  order  to  determine  the  extent  of  a  THM  problem  in  a 
system,  a  reliable  analytical  technique  must  be  used  THM 
analytical  services  may  be  developed  by  the  utility  or  may  be 
purchased  from  a  contract  laboratory.  A  discussion  of  the 
THM  analytical  methods  will  not  be  made  here;  rather,  the 
reader  is  referred  to  the  FEDERAL  REGISTER  publication  of 
the  regulation  or  to  the  EPA  document  prepared  by  J.M. 
Symons  which  was  previously  discu*^sed 

15.20  Sampling 

To  determine  the  extent  of  the  THM  problem,  collect 
REPRESENTATIVE  SAMPLES^  from  the  distribution  sys- 
tem of  the  water  utility  and  analyze  them  according  to  an 
approved  method  to  determine  if  the  utility  is  in  compliance 
with  the  THM  regulation.  Of  course,  four  quarters  of  data  are 
needed  to  make  a  definite  judgment  on  the  MCL.  However, 
even  one  quarter  of  data  can  show  how  close  the  system  will 
be  to  complying  with  the  MCL  See  Section  15.21,  "THM 
Calculations."  Exarples  1  and  2  for  procedures  on  how  to 
calculate  quarterly  average  TTHM  levels  and  annual  TTHM 
running  averages. 

To  collect  samples  to  determine  THM  levels,  use  the 
following  procedures* 

1  A  minimum  of  four  samples  per  quarter  (every  three 
months)  must  be  taker,  on  the  same  day  for  each  treat- 
ment plant  in  the  distribution  system. 

2.  Twenty-five  percent  of  these  samples  must  be  collected 
from  the  extremities  of  the  distribution  system  (the  points 
farthest  from  each  treatment  plant),  and 

3  Seventy-five  percent  of  the  five  samples  must  be  repre- 
sentative of  the  population  served  by  the  distribution 
system. 


^Available  from  Computer  Services,  AWWA,  6666  West  Qumcy  Avenue,  Denver,,  Colorado  60235.  Catalog  Number  20221.  Prue  to 

members,  $16.00;  nonmembers,  $20.00. 
3  Representative  Sample   A  portion  of  matenal  or  water  that  ts  as  nearly  identical  in  content  and  consistency  as  possible  to  that  in  the 

larger  body  of  material  or  water  being  sampled. 


ERLC 


122  Water  Treatment 


Do  not  collect  samples  from  swivel  faucets,  faucets  with 
aerators,  or  faucets  with  hoses  because  of  the  possibility  of 
contaminating  the  sample  or  loss  of  THMs 

To  collect  samples  for  THM  analysis,  use  a  narrow-mouth 
screw-cap  glass  sample  bottle  that  can  hold  at  least  25  mL 
of  water  Use  a  polytetrafluorethylene  (PTFE)-faced  silicon- 
septia  bottle-cap  Imer  to  provide  an  airtight  sea!  over  the 
sample  bottle.  The  bottle  cap  must  screw  tightly  on  the 
sample  bottles 

Some  sample  bottles  will  contain  a  small  amount  of  a 
chemical  reducing  agent  (usually  sodium  thiosulfate  or  soo. 
um  sulfite).  The  reducing  agent  will  stop  the  chemical 
reaction  that  occurs  between  chlorine  and  the  THM  precur- 
sors (humic  and  fluvic  acids).  By  stopping  this  chemical 
reaction,  THMs  will  not  continue  to  form  in  the  sample  after  it 
has  been  collected  from  thedistnbution  system.  When  using 
sample  bottles  that  contain  a  reducing  agent,  do  not  rinse 
out  the  reducing  agent  before  collecting  the  sample. 

Some  sample  bottles  will  not  contain  a  reducing  agent. 
Water  samples  from  these  bottles  will  be  tested  for  the 
maximum  -oncencration  of  TTHMs  that  can  form  over  an 
extended  period  of  time.  These  tests  cannot  be  performed  If 
a  reducing  agent  has  been  added  to  the  sample.  When  using 
sample  bottles  that  do  not  contain  a  reducing  ^gent,  do  not 
add  any  chemicals  to  the  bottles. 

When  collecting  water  samples  for  THM  analysis,  use  the 
following  procedures. 

1 .  Turn  on  the  sampling  tap, 

2.  Allow  sufficient  time  (about  five  minutes)  for  .he  water 
temperature  to  become  constant. 

3.  Fill  the  sample  bottle  until  it  begins  to  overflow, 

4.  Set  the  bottle  on  a  level  surface  and  place  the  bottle-cap 
liner  on  top  of  the  bottle, 

5.  Screw  the  bottle  cap  tightly  on  the  bottle  and  turn  the 
bottle  upside  down, 

6.  The  sample  is  properly  sealed  if  no  air  bubbles  are 
present,  and 

7.  If  air  bubbles  are  present,  remove  the  bottle  cap  and 
bottle-cap  liner,  turn  on  the  sampling  tap  and  add  a  small 
amount  of  water  to  the  sample  in  the  bottle,  and  repeat 
steps  4  through  6. 

A  good  practice  is  to  collect  two  samples  at  each  location. 
This  procedure  allows  the  laboratory  to  double  check  test 
results  and  if  a  sample  bottle  is  broken,  there  will  be  another 
sample  available  for  testing. 

Each  sample  bottle  must  include  a  label  on  which  impor- 
tant information  is  recorded.  Be  sure  to  write  on  the  label  the 
sample  location,  date,  and  name  of  person  collecting  the 
sample.  Samples  should  be  sent  to  the  laboratory  immedi- 
ately after  they  are  collected  and  should  be  analyzed  within 
14  days.  When  sending  samplas  to  the  lab,  be  sure  to 
include  the  complete  name  and  address  of  the  person  to 
whom  the  test  results  are  to  be  returned.  Samples  do  not 
have  to  be  refrigerated  during  storage.  Do  not  use  dry  ice 
when  shipping  or  storing  samples  because  the  water  in  the 
bottles  may  freeze  and  break  the  sample  bottles. 

15.21   THM  Calculations 

FORMULAS 

In  order  to  calculate  the  average  of  a  group  of  measure- 
id 

ERLC 


ments,  sum  up  the  m.easurements  and  divide  the  total  by  the 
number  of  measurements. 


Average  =- 


Sum  of  Measurements 
Number  of  Measurements 


To  calculate  the  running  annual  average,  sum  up  the 
average  measurements  for  each  quarter  and  divide  the  total 
by  the  number  of  quarters. 


Running  Average  = 


Sum  of  Averages  for  Each  Quarter 
Number  of  Quarters 


Whenever  data  for  a  new  quarter  becomes  available,  the 
newest  quarterly  average  replaces  the  oldest  quarterly  aver- 
age and  the  running  annual  average  is  recalculated. 

EXAMPLE  1 

A  water  utility  collected  and  analyzed  eight  samples  from  a 
water  distribution  system  or  iiie  same  day  for  TTHMs.  The 
results  are  shown  below. 

Sample  No.  1  2  3  4  5  6  7  8 
TTHM,  ^g/L  80    50    70    110    90    120    80  90 

What  was  the  average  TTHM  for  the  day? 

Known  Unknown 


Results  from  analys'S  of 
8  TTHM  samples 


Average  TTHM  level  for  the 
day. 


Calculate  the  average  TTHM  level  in  micrograms  per  liter. 

Ave  TTHM.    Sum  of  Measurements. /ig/L 
^9/^  Number  of  Measurements 

80  ngfL  +  50  ^g|L  ^  70  ng/L  f  11 0  ng/L  +  90  ng/L 
=  120  M9//.  *  80  ag/L  +  90  ^g/L 

8  measurements 

690  ^g/L 
8 

=  86  ng/L 
EXAMPLE  2 

The  results  of  the  quarterly  average  TTHM  measurements 
for  two  years  are  given  below  Calculate  the  running  annual 
average  of  the  four  quarterly  measurements  in  micrograms 
per  liter. 

Quarter  1      2     3     4     1      2       3  4 

Ave  Quarterly  87    72    99    82    62    111    138  89 
TTHM,  fiQ/L 


Known 


Unknown 


Results  from  analysis  of         Running  annual  average 
2  years  of  TTHM  samples       of  quarterly  TTHM 

measurements 

Calculate  the  running  annual  average  of  the  quarterly  TTHM 
measurements. 

Annual  Running  TTHM_  Sum  of  Ave  TTHM  for  Fou*^  Quarters 
Average,  ng/L  ~  Number  of  Quarters 

Quarters  7,  2,  3,  and  4 

Annual  Running  TTHM^  87  ng/L    72  ng/L    99  ng/L  -f  82  ng/L 
Average.  ng/L         "  4 

340  figfL 
A 

*  85  ^g/L 


138 


Trihalomethanes  123 


Quarters  2.  3,  4,  and  1 

Annual  Running  TTHM  72  ^gfL  99  ^g/L  -  82  ^g/L  f  62  ^g/L 
Average,  ^g/L         '  4 

3l5  /^y/L 


-  79  ^Q|L 

Quarters  3.  4.  7  and  2 

Annual  Runn-ng  TTHM_  99  ^ g/L  +  82  ^g/L  +  62  ^g/L  M 1 1  ^g/L 
Average.  ng/L  4 

354  /ig/L 
4 

=  89  /.g/L 

Quarters  4.  7.  2  and  3 

Annual  Running  TTHM    82  /ig/L  ^  62  /ig/L  ^111  pg/f.  -  1 38  ^g/L 
Average.  ng/L  ~  4 

393  /ig/L 
4 

-  98  ,ig/L 

Quarters  1,2,3,  and  4 

Annual  Running  TTHM    62  ng(L  +  111  ^ig/L  t  1 38  ^g/L  +  89  ng/L 
Average.  ng(L  ~  4 

400  ^g/L 
4 

-  100  ng/L 

SUMMARY  OF  RESULTS 

Quarter  1     2    3    4    1     2      3  4 

Ave.  Quarterly 

TTHM,A^g/L         87  72  99  82  62  111   138  89 


Annual  Running 
TTHM  Ave.,  ^g/L 


85  79    89    98  100 


15.22   Chemistry  of  THM  Formation 

An  understanding  of  the  chemistry  of  THM  formation  is 
crucial  if  a  water  utility  is  to  solve  a  THM  'jroblem.  Equation  1 
shown  in  Section  15.0.  "The  Trihalomeihane  (THM)  Prob- 
lem," descnbes  the  overall  mechanism.  Very  i»ttle  is  known 
about  the  specific  reactions  that  free  :hlOiine  and  natural 
organics  (precursors)  undergo.  In  general,  the  effects  of 
time,  temperature,  pH  and  concentrat'ons  of  the  chemicals 
on  the  production  of  THMs  have  been  t*'icjied  by  various 
investigators  and  are  fairly  well  understood. 

Depending  on  the  type  of  natural  organics  present  in  the 
water,  the  time  it  takes  for  0.10  mg/L  (100  fxg/L)  of  THMs  to 
form  may  range  from  minutes  to  days.  Set  up  a  THM 
monitoring  program  on  the  source  water(s)  of  the  utility  to 
measure  the  production  of  THMs  over  an  appropriate  time 
period  (time  from  when  chlorine  is  first  added  to  water  until 
water  is  consumed).  A  plot  of  the  THMs  produced  against 
time  will  giv  >  you  an  idea  of  the  TTHM  (Total  TriHaloMeth- 
anes)  formation  potential  (TTHMFP)  of  each  source  water. 
For  many  systems,  a  large  par^  of  the  production  of  THMs 
will  take  place  after  the  water  leaves  the  treatment  plant. 

The  higher  the  temperature,  the  faster  the  THMs  will  be 
produced.  As  might  be  expected,  a  dependence  on  tempera- 
ture will  probably  show  up  as  a  seasonal  effect  —  higher 
JHK*  levels  in  the  summer  than  in  the  winter.  Temperature 


may  not  be  the  only  controlling  factor,  however;  higher  levels 
may  show  up  in  the  winter,  as  they  have  in  California. 

The  higher  the  pH  of  the  water,  the  faster  the  production 
of  THMs  For  most  water  utilities  this  will  not  be  a  concern; 
however,  utilities  raising  the  pH  of  treated  water  by  caustic 
soda  or  by  lime  for  corrosion  control  (Langelier  Index)  or 
using  lime  softening  should  he  aware  that  free  chlorine  in 
contact  with  natural  organics  at  a  pH  of  10.5  or  higher  will 
produce  THMs  much  faster  than  if  the  pH  were  near  7.0. 

The  higher  the  concentrations  of  free  chlorine  and  natural 
organics  in  the  water,  the  more  THMs  wii|  be  produced.  In 
the  past,  the  amount  of  f.-ee  chlorine  that  utilities  used  was 
only  limited  by  economics  and  possible  taste  and  odor 
complaints  from  consumers.  Careful  use  of  chlonne  may 
help  a  utility  to  lower  the  THMs  in  its  system.  However, 
because  of  the  danger  of  using  too  little  chlorine  (inadequate 
disinfection)  in  a  system,  the  THM  regulation  specifically 
requires  State  or  EPA  approval  of  major  treatment  changes 
to  meet  the  regulation. 

The  concentration  of  precursors  in  water  is  as  important 
as  the  type  of  precursors  that  are  found  in  water.  Some 
naturally  occurring  organic  compounds  can  produce  10  or 
100  times  the  THMs  on  an  equivalent  basis  as  organics  from 
another  source.  Also,  some  types  of  precursors  will  produce 
THMs  faster  than  others.  For  this  reason  it  is  important  to 
evaluate  the  TTHMFP  of  each  source  of  supply  as  a  possible 
THM  control  measure. 


The  effect  of  higher  bromide  concentrations  on  THM 
production  is  not  as  clear  as  the  effects  of  temperature  and 
pH  The  more  bromide  present,  the  more  bromide-contain- 
ing THMs  will  be  formed.  .  ree  chlorine  selectively  attacks 
the  bromide  ion  and  changes  it  to  bromine,  which  reacts 
quickly  with  precursors  to  form  bromoform,  dibromochloro- 
methane,  and  bromodichloromelhane.  The  usual  result  of 
high  bromide  levels  is  higher  THM  levels  because  the  higher 
molecular  weights  of  these  compounds  mean  more  mole- 
cules are  available  for  these  chemical  reactions. 

Now  that  some  of  the  basics  of  THM  chemistry  are 
understood  and  a  THM  problem  can  be  properly  defined,  it  is 
time  to  look  at  some  of  the  possible  control  strategies. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  131. 

15  1 A  List  the  major  steps  that  a  water  utility  could  take  to 
solve  a  THM  problem. 

15.1B  List  the  possible  control  strategies  that  could  be 
evaluated  tc  control  a  THM  problem. 


ERIC 

Mgr  ^   


133 


124  Water  Treatment 


15  2A  What  important  facturs  influence  the  production  of 
trihalomethanes'? 

15  2B  How  does  lime  used  for  softening  influence  the 
production  of  THMs'? 


15.3  CONTROL  STRATEGIES 

Assuming  that  a  utility  discovers  a  THM  problem  in  its 
system,  there  are  two  ways  to  control  it*  change  the  source 
of  supply  or  provide  some  type  of  treatment.  Changing  the 
source  of  supply  can  consist  of  an  entire  range  of  alterna- 
tives such  as  shifting  between  wells  of  different  quality, 
drawing  water  from  different  levels  in  a  reservoir,  or  aban- 
doning a  surface  supply  altogether  during  part  of  the  year. 
Since  most  utilities  do  not  have  the  flexibility  to  abandon  a 
source  of  supply,  this  alternative  will  have  limited  applica- 
tion. 

The  three  treatment  options  available  to  control  THMs  are 
as  follows: 

1 .  Remove  THMs  after  they  are  formed, 

2.  Remove  THM  precursors  before  chlorine  is  added,  and 

3.  Use  a  disip%ctant  other  than  free  chlorine. 

A  later  section  will  examine  each  of  these  options  and  the 
processes  associated  with  them.  At  this  point  It  is  useful  to 
discuss  overall  treatment  strategies.  The  general  equation 
for  forming  THMs  ilh  ^trates  how  each  of  the  three  options 
can  work. 


EQUATION  1 


Free 
Chlorine 


Natural 
+  Organlcs 
(precursor) 


+  Bromide  —  THMs  + 


Other 
Products 


Removing  THMs  after  they  are  formed  is  generally  not  the 
strategy  of  choice  unless  there  is  a  particular  circumstance 
at  the  utility  that  warrants  its  evaluation.  Since  precursors 
are  not  necessarily  removed  when  THMs  are  removed,  there 
is  the  problem  of  continued  THM  formation,  especially  in  the 
distribution  system. 

Removing  precursors  before  free  chlorine  is  added  has 
some  major  advantages,  particulariy  if  the  precursors  can  be 
removed  by  a  fairly  inexpensive  process.  Also,  removing 
precursors  allows  the  continued  use  of  free  chlonne  as  a 
disinfectant,  which  has  been  proven  to  be  an  effective 
barrier  against  disease  for  many  decades.  As  the  above 
equation  shows,  fewer  precursors  also  means  the  formation 
of  fewer  ''other  products."  These  other  products  consist  of 
hiqh-molecular-welght  organic  compounds  that  contain 
chlorine  and  b.^ominb.  The  health  significance  of  these  other 
products  is  not  known,  but  concern  has  been  raised  by 
regulatory  agencies. 


Using  a  disinfectant  other  than  free  chlonne  has  a  number 
of  advantages  and  disadvantages  that  must  be  evaluated  on 
a  case-by-case  basis.  Abandoning  free  chlorine  is  a  senous 
move  in  view  of  its  superior  performance  as  a  disinfectant. 
However,  if  the  alternate  disinfectants  are  the  lowest  cost 
alternative,  they  must  be  given  careful  consideration. 

15.4   EXISTING  TREATMENT  PROCESSES 

Before  beginning  a  complex,  expensive  research  pro- 
gram, II  is  valuable  to  examine  how  well  existing  treatment 
processes  can  control  the  formation  of  THMs.  The  following 
sections  cover  the  potential  of  individual  processes  for  THM 
control;  however,  some  generalizations  can  be  made  with 
regard  to  existing  unit  processes.  Aeration-unit  processes 
are  sometimes  available  in  water  treatment  plants  to  control 
tastes  and  odors.  The  same  process  may  show  measurable 
removals  of  THhAs  after  they  are  formed.  Oxidation  of  tastes 
and  odors  with  chlorine  dioxide  (ClOg)  and  potassium  per- 
manganate are  common  unit  processes  available  in  water 
treatment  plants.  Chlorine  dioxide  does  not  form  THMs. 
Permanganate  sometimes  can  be  used  to  oxidize  THM 
precursors  if  they  are  affected  by  this  kind  of  treatment. 

Coagulation/sedimentation/filtration  and  softening  pro- 
cesses can  remove  THM  precursors  depending  on  the  types 
that  are  present  in  the  water  supply.  Studies  at  many  water 
treatment  plants  have  revealed  that  a  significant  reduction  of 
total  organic  carbon  (TOC)  In  source  water  by  chemical 
coagulation  often  shows  very  little  effect  on  total  trihalo- 
methane  (TTHM)  formation  (which  is  a  disappointment). 
Powdered  activated  carbon  and  granular  activated  carbon 
used  for  taste  and  odor  control  can  have  a  limited  impact  on 
the  removal  of  both  THMs  and  THM  precursors. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  tho^e  on  page  131. 

15.3A  If  a  utility  discovers  a  THM  problem,  what  are  two 
ways  to  control  the  problem? 

15.3B  Why  is  abandoning  the  use  of  free  chlorine  consid- 
ered a  serious  move? 

15.4A  List  the  water  treatment  processes  that  can  be  usei 
to  control  THMs. 


15.5   TREATMENT  PROCESS  RESEARCH  STUDY 
RESULTS 

15.50  Consider  Options 

There  is  a  long  list  of  treatment  options  that  can  be 
investigated  for  the  control  of  THMs.  Since  a  large  number 
of  them  have  already  been  studied  and  reported  on,  it  is  not 
necessary  for  every  utility  to  repeat  this  work.  A  careful 
evaluation  of  the  results  published  by  the  U.S.  EPA  will  help 
a  utility  focus  on  the  treatment  processes  that  should  be 
looked  at  on  a  bench-,  pilot-,  or  full-scale  basis. 

Most  feasible  treatment  options  include  the  removal  of 
precursor  materials  prior  to  the  formation  of  a  THM;  the 
avoidance  of  generation  of  a  THM  by  use  of  an  alternate 
disinfectant;  or  the  actual  removal  of  a  THM  via  aeration  or 
carbon  adsorption.  Also  the  geographic  and  climatologtcai 
conditions  can  have  a  very  important  influence  on  the  choice 
of  the  most  desirable  process.  For  example,  aeration  is  not  a 
desirable  method  of  treatment  where  severe  cold  weather  is 
common. 


er|c 


140 


Trihalometha  nes   1 25 


15.51   Remove  THMs  After  They  Are  Formed 

There  are  three  treatment  processes  available  to  remove 
THMs  after  they  have  been  formed: 

1.  Oxidation 

a.  Ozone 

b.  Chlorine  dioxide 

c  Ozone/ultravioiel  light 

2.  Aeration 

a.  Open  storage 

b.  Diffused  air 

c.  Towers 


3.  Adsorption 

a.  Powdered  activated  carbon 

b.  Synthetic  resins 

OXIDATION.  Oxidation  of  THMs  using  any  one  of  the 
three  oxidants  listed  above  has  not  been  very  successful. 
The  combination  of  ozone/ultraviolet  light  showed  some 
promise,  however,  the  cost-effectiveness  of  the  process  has 
yet  to  be  demonstrated. 

AERATION.  In  contrast,  aeration  Is  an  effective  process 
for  removing  THMs  from  water,  although  the  Individual 
THMs  are  removed  at  different  efficiencies.  THM  removal 
efficiencies  by  aeration,  ranging  from  the  easiest  to  most 
difficult,  are  from  chloroform  to  bromodichloromethane  to 
dibromochloromethane  and  to  bromoform.  Allowing  water 
containing  THMs  to  stand  uncovered  will  uK'mately  result  in 
the  THMs  leaving  the  water,  since  they  a;e  VOLATIIE^ 
compounds  that  are  poorly  soluble  in  water.  In  other  words, 
THMs  have  a  natural  tendency  to  migrate  from  water  into  the 
atmosphere  if  given  the  chance.  Because  of  this  tendency, 
ThM  reductions  may  be  noticeable  in  effluents  fr^m  open, 
finished  water  reservoirs  after  a  significant  detention  time 
(days). 

More  efficient  removal  of  THMs  can  be  accomplished  if 
energy  is  put  into  the  aeration  process.  A  convenient  way  to 
put  energy  into  aeration  is  by  bubbling  air  into  water.  Many 


water  treatment  plants  currently  have  an  aeration  process  of 
some  kind  to  help  control  tastes  and  odors  in  the  source 
water  The  efficiencies  of  these  existing  processes  would 
not  be  expected  to  be  very  great  for  THM  removal. 

Operators  should  realize  that  aeration  of  treated  water 
can  cause  a  significant  amount  of  contamination.  Air  in  many 
areas  may  contain  large  amounts  of  dust,  dirt,  bacteria  and 
other  contaminants  which  can  contaminate  treated  water 
and  also  lead  to  operation  and  maintenance  problems. 

In  the  research  results  that  are  currently  available, 
counter-current  tower  aeration  (Figure  15.2)  has  produced 
tne  highest  removals  of  THMs  with  alr-to-water  ratios  (the 
ratio  of  the  volume  of  air  added  to  the  voluiTie  of  water 
treated)  in  the  20  to  1  to  50  to  1  range.  Treatment  efficiencies 
greater  than  90  percent  removal  have  been  demonstrated 
with  some  aeration  towers  on  some  types  of  wat^r.  Counter- 
current  aeration  towers  are  designed  so  that  the  water  and 
air  pass  over  a  packing  material  countercurrent  to  each 
other  (in  opposite  directions).  A  significant  amount  of  theo- 
retical work  has  been  done  on  the  possible  tower  designs 
for  any  given  set  of  treatment  conditions.  Pilot-scale  testing 
is  usually  recommended  before  a  full-scale  plant  is  con- 
structed. Aeration  is  most  effective  on  the  more  volatile 
chemicals.  Chlorofcm  i?  the  most  volatile  of  the  THMs  and 
IS  generally  the  most  easily  removed  by  aeration.  Bromo- 
form, on  the  other  hand.  Is  the  least  volatile  THM  and 
consequently  is  the  hardest  to  remove  by  aeration.  If  the 
TTHM  content  of  the  water  contains  significant  amounts  of 
bromoform,  aeration  may  not  be  the  most  desirable  tech- 
nique to  investigate. 

ADSORPTION.  THMs  can  be  removed  by  a  wide  variety  of 
activated  carbons  and  synthetic  resins.  The  adsorption 
process  involves  the  individual  THM  compounds  leaving  the 
water  and  becoming  attached  to  the  surface  of  the  carbon  or 
resin.  THMs  are  generally  considered  difficult  to  adsorb  on 
any  surface.  The  efficiency  by  adsorption  from  easiest  to 
most  difficult  is  bromoform,  dibromochloromethane,  bromo- 
dichloromethane, and  chloroform. 

Powdered  activated  carbon  (PAC)  is  usually  added  as  a 
treatment  chemical  in  the  rapid-mix  process  or  in  the  sedi- 
mentation basin  effluent.  PAC  is  normally  used  in  water 
treatment  for  taste  and  odor  control  at  dosages  of  less  than 
20  mg/L  Studies  have  shown  that  PAC  dosages  of  100  mg/ 
L  or  more  are  necessary  to  get  significant  removals  of 
THMs  Chloroform  is  particularly  difficult  to  remove  w.  .1 
PAC. 


*  Volatile  (VOL-uh-tull)    A  substance  that  is  capable  of  being  evaporated  or  easily  changed  to  a  vapor  at  relatively  low  temperatures.  For 
example,  gasoline  is  a  highly  volatile  liquid. 


ERIC 


141 


126  Water  Treatment 


Synthetic  resins  such  as  XE-340  hava  been  demonstrated 
to  be  effective  in  removing  THMs  from  water,  however, 
economics  must  be  taken  into  consiG2ration,  since  the  cost 
of  the  resins  is  high  m  comparison  w:th  other  alternatives 
Regeneration  of  the  resins  has  not  been  worked  out  satis- 
factorily Pilot-scale  studies  show  some  promise,  but  full- 
scale  applications  are  not  available. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  131 . 

1 5  5A  Which  IS  the  better  process  for  removing  THMs  after 
they  are  formed,  oxidation  or  aeration? 

1 5  5B  How  does  the  storage  of  water  in  uncovered  reser- 
voirs affect  THM  levels'? 

1 5  5C  How  does  the  adsorption  process  work*? 


I  15.52   Remove  THM  Precursors 

I  A  variety  of  treatment  processes  have  been  investigated 

I  to  remove  THM  precursor's  before  they  come  in  contact  with 

I  chlonne.  These  include: 

I         1 .  Aeration 

2.  Oxidation 
a  Ozone 

b.  Chlorine  dioxide 

c.  Permanganate 

d  Ozone/ultraviolet  light 
e  Hydrogen  peroxide 

3.  Clarification 

a  Coagulation/sedimentation/filtration 
b.  Softening 

4.  Adsorption 

a.  Powdered  activated  carbon 

b.  Granular  activated  carbon 

c.  Synthetic  resins 

5.  Ion  Exchange 

AERATION.  Since  THM  precursors  are  not  volatile  com- 
pounds, it  Is  not  surprising  that  aeration  is  ineffective  in 
removing  them  from  water. 

OXIDATION.  All  of  the  oxidants  listed  above  have  some 
effect  on  removing  or  modifying  THM  precursors.  Since 
THM  precursors  vary  so  much  between  locations,  it  is 
difficult  to  generalize  on  the  effectiveness  of  any  of  the 
oxidants.  In  fact,  some  studies  have  demonstrated  that  the 
formation  potential  for  THMs  can  INCREASE  vjWh  the  appli- 
cation of  certain  dosages  of  ozone  and  potassium  perman- 
ganate. In  general,  it  Is  necessary  for  bench-  and/or  pilot- 
!  scale  studies  to  be  performed  on  the  water  In  question 
I  before  the  usefulness  of  any  of  these  oxidants  can  be 
considered.  The  U.S.  EPA  is  also  concemed  with  the  pro- 
duction of  potentially  harmful  byproducts  that  could  result 
from  the  use  of  any  of  these  oxidants.  Once  again,  studies 
on  the  water  to  be  treated  are  necessary  to  determine 
whether  or  not  this  is  a  problem. 

ERIC 


In  the  Southeastern  United  States  in  the  warmer  and 
highly  organic  waters,  controlled  oxidation  levels  with  smalt 
doses  of  ozone  can  actually  coagulate  organic  matenal  and 
make  it  more  efficient  for  conventional  sedimentation.  Too 
much  ozont  cm  break  the  organics  down  to  be  more 
reactive  with  chlorine.  However,  small  controlled  doses  of 
ozone  may  be  a.i  effective  microflocculant  and  may  be 
added  to  conventional  water  treatment  plants  to  improve  the 
physical  removal  of  THM  precursors  to  the  point  that  pre- 
chlorination disinfection  is  possible. 

CLARIFICATION  The  clarification  process  used  in  water 
treatment  plants  has  the  potential  for  removing  significant 
amounts  of  THM  precursors.  Dozens  of  studies  by  the  U  S. 
EPA  have  demonstrated  widely  varying  removal  efficiencies 
(0  to  iOO  percent)  because  of  the  highly  variable  nature  of 
THM  precursors  from  place  to  place.  The  use  of  this  process 
to  remove  THM  precursors,  which  is  available  in  most  water 
treatment  plants,  holds  great  promise  for  an  economical 
solution  to  any  THM  problem.  Moving  the  addition  of  free 
chlorine  to  a  point  following  the  clarification  process  is  the 
key  to  success  for  this  approacn.  Many  water  utilities  have 
adopted  this  approach  to  solve  their  problem. 

ADSORPTION.  The  use  of  PAC  and  GAG  are  effective  in 
removing  THM  precursors;  however,  the  economics  of 
these  processes  must  be  carefully  evaluated.  Dozens  of 
studies  have  reported  a  wide  variety  of  THM  precursor 
removal  efficiencies.  Because  of  the  high  cost  of  PAC  and 
GAC,  their  use  as  THM  control  methods  will  be  restncted  to 
those  cases  where  no  other  alternatives  are  available. 
Synthetic  resins  showed  limited  removal  potential  for  THM 
precursors.  Effective  regeneration  of  the  resins  for  addition- 
al precursor  removal  has  not  been  demonstral  1. 

ION  EXCHANGE.  Anion  exchange  resins  can  be  effective 
for  removing  THM  precursors  which  generally  have  a  nega- 
tive charge.  Both  strong-base  and  weak-base  anion  ex- 
change resins  have  been  investigated.  As  with  the  activated 
carbons  discussed  above,  anion  exchange  resins  will  only 
find  a  role  in  controlling  THMs  if  the  economics  of  the 
treatment  process  for  a  particular  site  are  favorable.  Dispos- 
al of  the  spent  regenerant  liquid  may  be  a  problem. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compaie  your 
answers  with  those  on  page  131. 

15.5D  List  the  major  treatment  processes  that  have  been 
investigated  to  remove  THM  precursors  before  they 
come  in  contact  with  chlorine. 

15.5E  What  is  the  key  to  the  success  cf  using  clarification 
to  remove  THM  precursors  from  tne  water  being 
treated? 

142 


Trihalomethanes  127 


INFLUENT 


^  ^  /N  /N 

AIR  AIR 


AIR 

i 


AIR 


1 


t 


t 


FAN 


SPRAY 


 <^  EFFLUENT 


Fig.  15.2  Countercurrent  aeration  tower 


ERIC 


143 


128  Water  Treatment 


15.S3  Alternate  Disinfectants 

Removing  free  chlorine  from  the  chiorine/bromide/precur- 
sor  reaction  will  stop  the  formation  of  any  significant 
amounts  of  THMs.  however,  free  chlonne  has  been  an 
effective  barrier  between  people  and  disease-causing  bacte- 
ria Since  the  beginning  of  this  century,  and  abandoning  its 
use  IS  a  very  senous  step  There  are  other  disinfectants  tnat 
can  be  used  instead  of  free  chlorine,  but  the  advantages 
and  disadvantages  of  each  alternative  must  be  carefully 
evaluated 

The  most  commonly  considered  alternate  disinfectants 
are  ozone,  chlorine  dioxide,  and  chloramines.  Ozone  is  a 
gas  that  is  produced  by  passing  oxygen  through  an  electri- 
cal discharge  While  ozone  is  a  highly  effective  disinfectant. 
It  IS  very  expensive,  it  must  be  generated  on  site,  and  it  does 
not  leave  a  residual  in  the  treated  water.  Chlorine  dioxide  is  a 
gas  produced  by  the  reaction  o*  free  chlorine  and  sodium 
chlorite.  Chlorine  dioxide  is  a  very  effective  disinfectant 
which  does  leave  a  residual  in  the  treated  water:  however, 
there  are  some  concerns  regarding  the  health  implications 
of  the  inorganic  breakdown  products,  chlonte  and  chlorate. 
The  THM  regulation  recommended  a  0.5  mg/L  limit  for  the 
total  concentration  of  chlorine  dioxide,  chlorite,  and  chlorate 
in  water  after  chlorine-dioxide  treatment 

Chloramines  are  produced  in  water  by  the  reaction  be- 
tween free  chlorine  and  ammonia.  Chloramines  are  weaker 
disinfectants  than  free  chlorine,  ozone,  or  chlorine  dio)  de, 
bu  the  residuals  remain  much  longer  than  froe  chlorine  and 
they  have  been  used  successfully  by  dozens  of  water 
utilities  for  many  years.  The  effectiveness  of  monochlora- 
mlnes  as  a  disinfectant  depends  on  water  temperature,  pH, 
and  biological  quality,  as  well  as  the  proper  ratio  of  ammonia 
to  chlorine.  For  example,  the  City  of  Denver  has  used 
chloramines  for  many  years.  The  use  of  chloramines  can 
also  cause  problems  in  a  utility's  system  unless  proper 
precautions  are  taken.  Chloramines  must  be  removed  from 
the  water  before  it  is  used  in  kidney  dialysis  machines. 
Chloramines  m  water  can  pass  through  kidney  dialysis 
machines  and  into  a  patient's  blood  where  the  ammonia  will 
decrease  the  oxygen  carrying  capacity  of  the  blood.  In 
addition,  chloramines  are  toxic  to  fish  in  home  aquanums, 
and  they  must  be  removed  from  water  before  it  comes  in 
contact  with  them.  Dechlorination  of  water  with  activated 
carbon,  ascorbic  acid,  or  sodium  thio&ulfate  will  prevent  any 
of  these  problems  if  the  removal  of  chloramines  is  properly 
CO  Tolled.  Any  oxidants  that  are  present  in  drinking  water 
can  cause  problems  with  kidney  dialysis  machines  and  fish 
in  home  aquariums.  However,  chloramines  are  somewhat 
more  difficult  to  remove  than  the  other  alternate  disinfec- 
tants. 

Before  an  alternate  disinfectant  is  applied  to  any  system, 
the  source  of  the  water  supply,  water  quality  and  treatment 
effectiveness  for  bacteriological  control  must  be  evaluated. 
For  example,  the  use  of  a  weaker  disinfectant  such  as 
chloramines  may  not  be  appropriate  for  a  surface  water 
supply  that  is  highly  contaminated  with  discharges  from 
municipal  and  industrial  wastew.iter  treatment  plants  unless 
an  extra  high  dosage  and  a  lonn  contact  time  are  provided. 
Also,  many  of  the  conventional  water  treatment  processes 
are  capable  of  removing  bactena ,  viruses  and  protozoa  from 
the  water  (for  example,  softening  and  coagulation/sedimen- 
tation/filtration).  These  conventional  processes  may  help  to 
provide  the  required  disinfection  barner  between  a  contami- 
nated supply  and  the  population  served,  which  could  allow 
the  use  of  a  less  potent  disinfectant  in  the  distribution 
system. 

Upgraded  monitoring  of  the  distribution  system  before 

ERIC 


and  after  a  disinfectant  change  must  be  provided  by  the 
utility  The  THM  regulation  specifies  guidelines  that  the 
states  must  use  in  establishing  such  a  monitoring  program. 
Guidelines  describing  conforms,  standard  plate  count,  t^ir- 
bidity,  and  nutrients  are  included  in  the  suggested  montor- 
ing  list  With  "before  and  after"  monitoring  by  the  water  "jtility, 
it  will  be  possible  to  determine  if  there  is  any  significant 
degradation  of  the  bacteriological  quality  in  the  distnbution 
system  Control  of  THMs  m:ist  not  be  accomplished  at  the 
expense  of  a  higher  risk  of  D^-r^^erial  and  viral  diseases 
among  the  population  that  is  being  served.  Therefore,  a 
decision  to  use  a  disinfectant  other  than  free  chlorine  must 
be  based  on  a  carefully  considered  plan  A  utility  that  rushes 
into  the  use  of  an  alternate  disinfectant  without  the  required 
studies  IS  likely  to  experience  many  problems  that  are  easily 
avoided  with  proper  planning 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  131. 

15.5F  What  items  must  be  considerea  before  an  alternate 
disinfectant  is  applied  to  any  system? 

15  5G  What  type  of  distribution  system  monitoring  must  be 
provided  by  a  utility  before  and  after  a  disinfectant 
change'? 

15  5H  What  water  quality  indicators  should  be  monitored 
before  and  after  a  disinfectant  change? 

15.6   SELECTION  AND  IMPLEMENTATION  OF  A 
COST-EFFECTIVE  ALTERNATIVE 

A  detailed  evaluation  of  the  comparative  economics  of  the 
many  treatment  processes  described  above  is  outside  the 
scope  of  this  chapter  In  many  cases,  a  utility  will  commis- 
sion a  special  cost-effectiveness  study  that  will  be  accom- 
plished in  house  or  by  an  outside  consultant.  The  U.S.  EPA 
THM  treatment  manual  presents  a  detailed  look  at  cost 
estimates  for  various  alternatives  with  equivalent  THM  con- 
trol levels  however,  this  data  is  not  current  and  should  be 
updated  to  reflect  current  economic  conditions  whenever 
cost  studies  are  conducted. 

If  existing  processes  are  not  capable  of  solving  a  utility's 
THM  problem,  the  least-cost  solution  will  probably  be  an 
alternate  disinfectant.  While  no  statistics  are  currently  avail- 
able, evidence  from  discussions  with  consultants  and  utility 
managers  suggests  that  alternate  disinfectants,  especially 
chloramines,  are  the  overwhelming  least-cost  solution  for 
water  utilities  with  a  THM  problem.  However,  the  use  of 
chloramines  may  cause  problems  for  persons  using  kidney 
dialysis  machines. 

Implementation  of  a  THM  control  strategy  requires  a 
numbei  ?A  well  defined  steps- 

1.  Full-scale  design, 

2  Construction, 

3  Startup,  and 

4  Operation. 

The  length  of  time  required  to  complete  these  sieps  will 
depend  on  the  comolexity  of  the  control  strategy  chosen  and 
the  availability  of  engineering  services  to  complete  the 
assigned  tasks.  Throughout  the  implementation  phase,  it  is 
important  that  the  bench-,  pilot-,  and  full-sc^le  tests  initiated 
in  the  feasibility-analysis  phase  be  continued  so  that  the 


144 


Trihalomethanes  1 29 


chosen  strategy  can  be  refined  and  optimized.  For  example, 
a  pilot  plant  can  be  used  to  tram  treatment  plant  operators  to 
use  the  new  technology  that  will  soon  be  on-line. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  131. 

15.6A  If  existing  water  treatment  processes  are  not  capa- 
ble of  solving  a  THM  problem,  what  is  the  most  likely 
least-cost  solution? 

15.6B  What  appears  to  be  the  most  popular  alternate 
disinfectant? 

15.7  REGULATORY  UPDATE 

On  February  28,  1983.  the  U.S.  EPA  published  in  the 
FEDERAL  REGISTER  (page  8406)  an  amendment  to  the 
THM  regulation  originally  published  on  November  29, 1979. 
The  amendment  specifies  the  treatment  alternatives  that  a 
utility  must  consider  or  investigate  m  detail  before  it  can 
apply  for  and  receive  a  variance  from  meeting  the  MCL  as 
defined  under  the  regulation.  The  U.S.  Environmental  Pro- 
tection Agency  or  the  state  may  require  a  community  water 
system  to  use  a  "generally  available"  technology  before 
granting  a  variance.  "Generally  available"  or  Group  1  treat- 
ment techniques  are: 

1.  Use  of  chloramines  or  chlorine  dioxide  as  an  alternative 
or  supplement  to  chlorine  for  oxidation  and  disinfection, 

2.  Use  of  chloramines,  chlorine  dioxide,  or  potassium  per- 
manganate as  an  alternative  to  chlorine  for  preoxidaticn, 

3.  Moving  the  point  of  chlorination  in  order  to  reduce  THM 
formation, 

4.  Improvement  of  existing  clarification,  and 

5.  Use  of  powdered  activated  carbon  (PAC),  intermittently 
as  necessary,  to  reduce  TTHM  or  THM  precursors.  The 
dosage  of  PAC  is  not  to  exceed  an  annual  average  of  10 
mg/L. 

Any  of  these  technologies  may  be  required  in  the  variance 
unless  the  regulatory  agency,  USEPA  or  the  state,  deter- 
mine that  "such  treatment  method  ...  is  not  available  and 
effective  for  TTHM  control  for  the  system."  The  rule  allows 
exemption  from  the  use  of  a  technique  if  the  method  would 
not  be  technically  appropriate  and  technically  feasible  for  the 
system  or  If  the  method  would  result  in  only  a  marginal 
reduction  in  TTHM. 


The  rule  also  allows  the  regulator  to  require  the  study  of 
Group  2  technologies  by  water  systems  where  Group  1 
technologies  are  not  appropriate  or  sufficient  in  meeting  the 
MCL.  If  a  Group  2  technology  indicates  that  it  would  be 
technically  feasible  and  economically  reasonable  and  result 
in  Significant  TTHM  reductions  in  line  with  the  cost  of 
treatment,  then  '.he  regulator  can  require  the  use  of  a  Group 
2  technology 

The  listed  Group  2  technologies  are  introduction  of  off-line 
water  storage,  aeration,  introduction  of  clarification,  alterna- 
tive sources  of  raw  water,  and  the  use  of  ozone  as  an 
alternative  or  supplement  to  chlonne  for  disinfection  or 
oxidation. 

The  February  28,  1983,  amendment  to  the  THM  regula- 
tions does  not  mention  granular  activated  carbon  (GAC)  or 
biological  activated  carbon  (BAC)  as  treatment  alternatives 
that  must  be  considered.  These  two  treatment  methods 
were  judged  to  be  too  expensive  and  to  not  have  sufficient 
US  expeiience  to  warrant  their  evaluation  for  THM  control. 
In  general,  the  amendment  is  designed  to  reduce  the  eco- 
nomic impact  of  the  THM  regulation  on  those  utilities  that 
have  THM  problems  and  limited  resources  to  drastically 
modify  their  treatment  procedures. 

Utilities  that  may  be  affected  by  THM  regulations  are 
advised  to  follow  future  developments  in  the  FEDERAL 
REGISTER. 


15.8    SUMMARY  AND  CONCLUSIONS 

1 .  Trihalomethanes  are  produced  wh^n  free  chlorine,  which 
IS  added  as  a  disinfectant,  reacts  with  naturally  occurring 
bromide  and  organic  compounds. 

2.  A  trihalomethane  regulation  is  now  in  effect  which  has 
established  a  0.10  mg/L  maximum  contaminant  level  and 
monitoring  requirements. 

3.  A  feasibility-analysis  process  is  a  series  of  logical  steps 
to  arnve  at  a  cost-effective  solution  to  a  THM  problem: 

1.  Determine  the  extent  of  THM  problem 

a.  Monitor 

b.  THM  chemistry 

2.  Evaluate  control  strategies 

a.  Change  sources  of  supply 

b.  Treatment  options 

(1)  Remove  THMs 

(2)  Remove  precursors 

(3)  Use  alternate  disinfectants 


145 


130  Water  Treatment 


3  Evaluate  existing  treatment  processes 

4  Research  studies  of  treatment  processes 
a.  Bench-,  pilot-,  and  full-scale 

5.  Select  a  cost-effective  option 

6.  Implement  chosen  option 

4  There  are  three  treatment  options  available  to  control 
THMs: 

1.  Remove  THMs  after  they  are  formed. 

2  Remove  THM  precu^'scrs  before  chloiine  is  added, 
and 

3.  Use  a  disinfectant  other  than  free  chlorine. 

5  A  water  utility  must  not  create  a  possible  health  problem 
by  ignonng  bacteriological  safeguards  m  an  attempt  to 
solve  a  THM  problem 

6.  An  amendment  to  the  THM  regulation  specifies  ti  v^atment 
techniques  that  must  be  evaluated  before  a  utility  may 
receive  a  variance  Since  this  amendment  affects  a  utili- 
ty's feasibility  analysis  procedure,  the  steps  outlined  in 
the  amendment  should  be  followed. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  131. 

15  7A  What  treatment  processes  must  utilities  evaluate 
before  applying  for  and  receiving  a  variance'^ 


15.7B  If  treatment  processes  are  not  technically  feasible 
nor  economically  reasonable,  then  what  should  utili- 
ties consider'^ 

15.9  ARITHMETIC  ASSIGNMENT 

Turn  to  the  Appendix  at  the  back  of  this  manual  and  read 
Section  A  33.  "Trihalomethanes  "  Work  all  of  the  problems 
on  your  pocket  calculaior.  You  should  be  able  to  get  the 
same  answers. 

15.10  ADDITIONAL  READING 

1.  TREATMENT  TECHNIQUES  FOR  CONTROLLING  TRI- 
HALOMETHANES IN  DRINKING  WATER  by  James.  M. 
Symons,  Alan  S.  Stevens,  Robert  M.  Clark,  Edwin  E. 
Geldreich,  0.  Thomas  Love,  Jr.,  and  Jack  DeMarco. 
Drinking  Water  Research  Division,  Municipal  Environ- 
mental Research  Laboratory,  Office  of  Research  and 
Development,  U.S.  Environmental  Protection  Agency, 
Cincinnati,  Ohio  45268.  EPA-600/2-81-156.  September 
1981.  Available  from  Data  Processing  Department, 
AWWA,  6666  West  Quincy  Avenue,  Denver,  Colorado 
80235.  Catalog  Number  20221.  Price  to  members, 
$16.00;  nonmembers,  $20.00 

2.  CHLORAMINATION  FOR  THM  CONTROL:  PRINCIPLES 
AND  PRACTICES.  AWWA  Computer  Services,  6666  W. 
Quincy  Ave.,  Denver,  Colorado  80235.  Order  No.  20181. 
Price,  members,  $12.50;  nonmembers,  $15.50. 

3.  STRATEGIES  FOR  THE  CONTROL  OF  TRIHALOMETH- 
ANES. AWWA  Computer  Services,  6666  W.  Quincy  Ave., 
Denver,  Colorado  80235.  Order  No.  20174.  Price,  mem- 
bers, $12.50;  nonmembers,  $15.50. 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  15.  TRIHALOMETHANES 


Work  these  discussion  and  review  questions  before  con- 
tinuing with  the  Objective est  on  page  132  The  purpose  of 
those  questions  is  to  indicate  to  you  how  well  you  under- 
stand the  material  in  this  chapter.  Write  the  answers  to  these 
qijestions  in  your  notebook. 

1.  How  are  trihalomethanes  formed  in  drinking  water'? 

2.  On  what  basis  was  the  Maximum  Contaminant  Level 
(MCL)  for  total  trihalomethanes  (TTHMs)  established'? 

3.  What  is  the  mfluencG  of  higher  temperatures  ari  pH  on 
the  production  of  trihalomcmanes  (THMs)? 

4.  What  are  some  of  the  options  if  a  water  utility  decides  to 
investigate  changing  the  source  of  the  water  supply? 


5  What  are  the  advantages  of  removing  precursors  before 
free  chlorine  is  added? 

6  Why  might  ozone  be  used  prior  to  clarification  and 
filtration'? 

7  List  the  three  alternative  disinfectants  to  free  chlorine  and 
the  advantages  and  limitations  to  each  one. 

8  What  Items  must  be  considered  before  an  alternate 
disinfectant  is  applied  to  any  system'? 

9  What  are  the  advantages  of  using  a  n.lot  plant  in  the 
implementation  of  a  THM  control  strategy? 


Irinalomethanes  131 


SUGGESTED  ANSWERS 

Chapter  15.  TRIHALOMETHANES 


Answers  to  questions  on  page  121. 

15.0A  THM  precursors  are  defined  as  natural  organic  com- 
pounds found  in  all  surface  and  groundwaters  The 
THM  precursors  react  with  halogens  (such  as  chlo- 
nne)  to  form  trihalomethanes  (THMs);  they  must  be 
present  in  order  for  THMs  to  form. 

15.0B  Free  chlorine  is  added  to  drinking  water  as  a  disin- 
fectant. 

15.0C  One  source  of  bromide  is  sea  water. 

15.0D  Trihalomethanes  are  formed  by  the  reactions  of 
natural  organic  compounds  with  halogens  (such  as 
chlorine). 

Answers  to  questions  on  page  123. 

15.1  A  The  major  steps  that  a  water  utility  could  take  to 
solve  a  THM  problem  include 

1.  Determine  extent  of  THM  problem. 

2.  Evaluate  control  strategies, 

3.  Evaluate  existing  treatment  processes, 

4.  Examine  research  studies  of  treatment  proc- 
esses, 

5.  Select  most  cost-effective  option,  and 

6.  Implement  selected  option. 

15  1 B  Control  strategies  that  could  be  evaluated  to  control 
a  THM  problem  include: 

1.  Change  sources  of  supply,  and 

2.  Treatment  options 

(a)  Remove  THMs, 

(b)  Remove  precursors,  and 

(c)  Use  alternate  disinfectants 

15  2A  Important  factors  that  influence  the  production  of 
trihalomethanes  include  the  effects  of  time,  tempera- 
ture, pH  and  the  types  and  concentrations  of  chemi- 
cals. 

15.28  Those  utilities  that  use  lime  softening  should  be 
aware  that  free  chlonne  in  contact  with  natural  or- 
ganics  at  a  pH  of  10.5  or  higher  will  produce  THMs 
fastei  than  if  the  pH  were  near  7.0. 

Answers  to  questions  on  page  124. 

15.3A  The  two  types  of  controlling  a  THM  problem  are  (1) 
change  the  source  of  supply  or  (2)  provide  some  type 
of  treatment. 

15,38  Abandoning  the  use  of  free  chlorine  is  a  serious 
move  in  view  of  its  superior  performance  as  a 
disinfectant. 

15.4A  Water  treatment  processes  that  can  be  used  to 
control  THMs  include: 

1.  Aeration, 

2.  Oxidation  with  potassium  permanganate, 

3.  Coagulation,  flocculation  and  filtration, 

4.  Softening  processes,  and 

5.  Powdered  activated  carbon  applications. 

Answers  to  questions  on  page  126. 

15.5A  Aeration  is  a  much  more  effective  process  than 
oxidation  for  removing  THMs  after  they  have  been 
formed. 


15.58  THM  concentrations  should  be  reduced  in  waters 
which  have  been  stored  in  uncovered  reservoirs 
because  of  loss  to  the  atmosphere. 

15  5C  The  adsorption  process  involves  the  individual  THM 
compounds  leaving  the  water  and  becoming  at- 
tached to  the  surface  of  the  carbon  or  resin. 

Answers  to  ques*'ons  on  page  126. 

15  5D  The  major  treatment  processes  that  have  been  in- 
vestigated to  remove  THM  precursors  before  they 
come  in  contact  with  chlorine  include: 

1.  Aeration, 

2  Oxidation  (including  ozone  oxidation  prior  to  co- 
agulation and  clarification). 
3.  Clarification, 
4  Adsorption,  and 
5.  Ion  exchange. 

15. 5E  Moving  the  addition  of  free  chlorine  to  a  point  follow- 
ing the  clarification  process  is  the  key  to  success 
when  using  clarification  to  remove  THM  precursors. 

Answers  to  questions  on  page  128. 

15.5F  8efore  an  alternate  disinfectant  is  applied  to  any 
system,  the  source  of  the  water  supply,  water  quality 
and  treatment  effectiveness  for  bactenological  con- 
trol must  be  evaluated. 

15.5G  Upgraded  monitoring  (more  samples  and  tests)  of 
the  distribution  system  before  and  after  a  disinfec- 
tant change  must  be  provided  by  a  utility. 

15. 5H  8efore  and  after  a  disinfectant  change,  the  distribu- 
tion system  monitoring  program  should  include  con- 
forms, standard  plate  count,  turbidity  and  nutrients. 

Answers  to  questions  on  page  129. 

15  6A  If  existing  water  treatment  processes  are  not  capa- 
ble of  solving  a  THM  problem,  the  least  cost  solution 
will  probably  be  an  alternate  disinfectant. 

15  68  Apparently  the  most  popular  alternate  disinfectant  is 
chloramineo. 


Answers  to  questions  on  page  130. 

15-7A  Treatment  processes  which  utilities  must  evaluate 
before  applying  for  and  receiving  a  variance  include: 

1.  Use  of  chloramines  or  chlonne  dioxide  as  an 
alternative  or  supplement  to  chlorine  for  oxidation 
and  disinfection, 

2.  Use  of  chloramines,  chlorine  dioxide,  or  potas- 
sium permanganate  as  an  alternative  to  chlorine 
for  preoxidatlon, 

3.  Moving  the  point  of  chlorlnation  in  order  to  reduce 
THM  formation, 

4.  Improvement  of  existing  clarification,  and 

5.  Use  of  powdered  activated  carbon  (PAC),  inter- 
mittently as  necessary  to  reduce  TTHM  or  THM 
precursors.  The  dosage  of  PAC  is  not  to  exceed 
an  annual  average  of  10  mg/L 


147 


132  Water  Treatment 


15  7B  If  treatment  processes  are  not  technically  feasible 
nor  economically  reasonable,  then  utilities  must  con- 
sider- 

1.  Off-line  storage  for  precursor  reduction, 

2.  Aeration  where  appropriate. 


3  Introduction  of  clarification  where  not  practiced, 

4  Alternative  sources  of  raw  water,  and 

5  Use  cf  ozone  as  an  alternative  or  supplement  to 
chlorine  for  disinfection  or  oxidation 


OBJECTIVE  TEST 

ChaptenS.  TRIHALOMETHANES 


Please  write  your  name  and  mark  the  correct  answers  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1 .  There 
n.?y  be  more  than  one  correct  answer  to  the  multiple  choice 
questtoiib. 

TRUE-FALSE 

1 .  Trihalomethanes  are  formed  in  drinking  water  when  free 
chlorine  comes  in  contact  with  naturally  occurring  or- 
ganic compounds. 

1.  True 

2.  False 

2  The  trihalomethane  regulations  apply  to  all  community 
water  systems  that  add  a  disinfectant  to  their  water 
supply. 

1.  Tru« 

2.  False 

3.  The  Maximum  Contaminant  Level  (MCL)  for  total  tri- 
halomethanes (TTHMs)  was  established  solely  on  the 
basis  of  health-effects  data 

1.  True 

2.  False 

4.  Depending  on  the  type  of  natural  organics  present  in  the 
water,  the  time  it  takes  ior  0.10  mg/L  of  THMs  to  form 
may  range  from  minutes  to  days. 

1.  True 

2.  False 

5.  ^^ost  THM  precursors  enter  source  waters  from  indus- 
trial organic  chemicals. 

1.  True 

2.  False 

6.  The  concentration  of  precursors  in  water  is  as  important 
as  the  types  of  precursors  that  are  found  in  v/ater  for  the 
production  of  THMs. 

1.  True 

2.  False 


8.  Removal  of  THMs  after  they  are  formed  using  oxidants 
has  been  very  successful. 

1.  True 
2  False 


9  Aeration  is  an  effective  process  for  removing  THMs 
from  v/ater. 

1.  True 
2  False 


10  Aeration  is  an  effective  means  for  removing  THM  pre- 
cursors 

1  True 
2.  False 

11.  THM  precursors  vary  considerably  between  locations. 

1  True 
2,  False 

12.  Removing  free  chlorine  from  the  chlorine/bromide/pre- 
cursor  reaction  will  stop  the  formation  of  any  significant 
amounts  of  THMs 

1.  True 

2  False 

13.  A  chemical  reducing  agent  is  added  to  THM  sample 
bottles  to  stop  the  chemical  reaction  between  chlorine 
and  the  THM  precursors. 

1.  True 
2  False 

14  Tnhalomethanes  are  produced  when  free  chlorine 
reacts  with  naturally  occurring  bromide  and  organic 
compou.nds. 

1  True 

2.  False 


All  types  of  precursors  will  produce  THMs  at  the  same  15.  A  water  utility  may  apply  for  a  variance  from  the  THM 
''3te.  regulations. 

1.  True  1.  True 

2.  False  2.  False 


er|c 


148 


Trihalomethanes  133 


IViULTiPLE  CHOICE 

1 6  Examples  of  organic  compounds  include 

1.  Calcium. 

2  Carbohydrates. 

3.  Fats. 

4.  Trihalomethanes 

5.  Vitamins 

17.  Naturally  occurring  organics  get  into  water  when  the 
water  partially  dissolves  organic  materials  from 

1.  Algae. 

2.  Leaves 
3-  Rocks. 

4.  Salts. 

5.  Soils. 

18.  The  total  tnhalomethanes  in  water  are  the  sum  of  the 
concentrations  of 

1.  Bromodichloromethane. 

2.  Bromoform 

3  Chloroform. 

4.  Dibromochloromethane. 

5.  Methane. 

1 9.  The  Maximum  Contaminant  Level  (MCL)  for  total  trihal- 
omethanes (TTHMs)  IS 

1.  0.01  mg/L 

2.  0  03  mg/L 
3  0.05  mg/L. 

4.  0.10  mg/L 

5.  0.20  mg/L. 

20.  Important  factors  that  influence  the  production  of  trihal- 
omethanes include 

1 .  Concentration  of  chemicals. 

2.  Location  of  chlorine  application. 

3.  pH. 

4.  Temperature. 

5.  Time. 

2 1 .  Treatment  techniques  available  to  control  THMs  include 

1   Drawing  water  from  different  levels  in  a  reservoir. 

2.  Removing  THM  precursors  before  chlorine  is  added 

3.  Removing  THMs  after  they  are  formed. 

4.  Shifting  to  a  different  source. 

5.  Using  a  disinfectant  other  than  free  chlonne. 

22  Which  of  the  following  treatment  processes  are  effec- 
tive in  removing  THM  precursors? 

1.  Aeration 

2.  Coagulation,  flocculation  and  filtration 

3.  Open  storage 

4.  Potassium  permanganate 

5.  Softening  processes 

23  Which  of  the  following  treatment  processes  are  effec- 
tive in  removing  THMs  after  they  have  been  formed? 

1.  Adsorption 

2.  Aeration 

3.  Coagulation,  flocculation  and  filtration 

4.  Oxidation 

.5.  Softening  processes 


24  Oxidation  treatment  processes  include 

1  Chlorine  dioxide. 

2.  Granular  activated  carbon 

3.  Ozone. 

4  Powdered  activated  carbon 

5  Synthetic  resins 

25.  The  most  commonly  considered  alternate  disinfectants 
to  free  chlorine  are 

1.  Chloramines 

2.  Chlorine  dioxide. 

3.  Hydrochloric  acid 

4  Hypochlonte. 

5  Ozone 

26.  Dechlorination  of  water  containing  chloramines  can  be 
accomplished  by  the  use  of 

1.  Activated  carbon. 

2.  Ammonia. 

3  Ascorbic  acid. 

4.  Hypochlorite. 

5  Sodium  thiosulfate. 

27.  Water  quality  indicators  which  should  be  monitored  in 
the  distribution  system  before  and  after  a  disinfectant 
change  include 

1.  Chloride. 

2.  Coliforms. 

3.  Nutrients. 

4.  Standard  plate  count 
5  Turbidity. 

28  The  results  of  the  quarterly  average  TTHM  measure- 
ments for  one  year  are  given  below.  Calculate  the 
running  annual  average  for  the  fou^'th  quarter. 

Quarter  12      3  4 

Ave  Quarterly  TTHM,  ^g/L  63    89    121  72 

1  43^g/L 

2  68^g/L 
3.  86^g/L 

4  93^g/L 

5  95  ^g/L 


[1 


140 


CHAPTER  16 

DEMINERALIZATION 


by 


ERIC 


136  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  16  Demineralization 
(Removal  of  Dissolved  Minerals  by  Membrane  Processes) 

Page 

OBJECTIVES                                         ....    ^3g 

GLOSSARY   ^3g 

LESSON  1 

16.0  Sources  of  Mineralized  Waters  

16.1  Demineralizmg  Processes   -I42 

16.2  Reverse  Osmosis  

16.20  What  IS  Reverse  Osmosis?   142 

16.21  Reverse  Osmosis  Membrane  Structure  and  Composition   145 

16.22  Membrane  Performance  and  Properties   I45 

16.23  Def.nition  of  Flux   14g 

16.24  Mineral  Rejection    -I4g 

16  25    Effects  of  Feedwater  Temperature  and  pH  on  Membrane  Performance   147 

16  25  Recovery  

LESSON  2 

16.3  Different  Types  of  Reverse  Osmosis  Plants    153 

16.4  Operation    15g 

16.40  Pretreatment   15g 

16.41  Removal  of  Turbidity  and  Suspended  Solids    156 

16.42  pH  and  Temperature  Control   156 

16.43  Other  Potential  Sealants   156 

16.44  Microbiological  Organisms   157 

16.45  RO  Plant  Operation   157 

16.46  Typical  RO  Plant  Operations  Checklist   157 

16.47  Membrane  Cleaning   I61 

16.48  Safety   1^2 

16.480  Use  of  Proper  Procedures   162 

16.481  Chemmals   162 

16.482  Hydraulic  Safety   I62 

16.483  Electrical  Safety   162 

ERIC  151 


Demineralization  137 

LESSON  3 

16.5    Electrodialysis    ....      163 

16.e    Principles  of  Electrodialysis  . .      165 

16.60  Anions  and  Cations  in  Water     165 

16.61  Effects  of  Direct  Current  (D.C.)  Potential  on  Ions   165 

16.62  Ar.ion  and  Cation  Membranes  and  Three-Cell  Unit   165 

16.63  Multi-compartment  Unit     165 

16.7  Parts  of  an  Electrodialysis  Unit    168 

16 JO    Flow  Diagram       168 

16  71     Pretreatment         168 

16.72  Pumping  Equipment  and  Piping   168 

16.73  D.C  Power  Supply   168 

1 6  74    Membrane  Stack    1 68 

16.75    Chemical  Flush  System   168 

16.8  Routine  Operating  Procedures   ...  168 

16.80  Design  Specifications  for  Feedwater   168 

16.81  Detailed  Operating  Procedures   171 

16.9  Safety  Precautions   171 

16.10  Anthmetic  Assignment   173 

16.11  Additional  Reading   173 

Suggested  Answers    174 

Objective  Test   176 


1  - 


Water  Treatment 


OBJECTIVES 

Chapter  16.  DEMINERALIZATION 

Following  completion  of  Chapter  16,  you  should  be  able 

to 

1  Describe  the  various  demineralizing  processes, 

2  Explain  how  the  reverse  osmosis  process  works, 

3.  Operate  and  maintain  a  reverse  osmosis  demineraliza- 
tion  plant, 

4  Explain  the  principles  of  electrodialysis, 

5.  Identify  and  describe  the  parts  of  an  electrodialysis  plant. 

6.  Operate  and  maintain  an  electrodialysis  plant,  and 

7.  Safoly  perform  your  duties  around  reverse  osmosis  and 
elecirodialysis  plants. 


153 


Demineralization  139 


GLOSSARY 

Chapter  16.  DEMINERALIZATION 


ANGSTROM  (ANG-strem)  ANGSTROM 

A  unit  of  length  equal  to  one  tenth  of  a  nanometer  or  one  ten-billionth  of  a  meter  (1  Ai.^strom  -  0.000  000  000  1  meter).  One 
Angstrom  Is  the  approximate  diameter  of  an  atom. 

CHELATION  (key-LAY-shun)  CHELATION 

A  chemical  complexlng  (forming  or  joining  together)  o.  .tallic  cations  (such  as  copper)  with  certain  organic  compounds,  such 
as  EDTA  (ethylene  diamine  tetracetic  acid).  Chelation  is  used  to  prevent  the  precipitation  of  metals  (copper).  Also  see 
SEQUESTRATION. 

COLLOIDS  (CALL-loids)  COLLOIDS 

Very  small,  finely  divided  solids  (particles  that  do  not  dissolve)  that  remain  dispersed  in  a  liquid  for  a  long  time  due  to  their  small 
Size  and  electrical  charge  When  most  of  the  particles  in  water  have  a  negative  electrical  charge,  they  tend  to  repel  each  other. 
This  repulsion  prevents  the  particles  from  clumping  together,  becoming  heavier  and  settling  out. 

CONCENTRATION  POLARIZATION  CONCENTRATION  POLARIZATION 

The  ratio  of  the  salt  concentration  in  the  membrane  boundary  layer  to  the  salt  concentration  in  the  water  being  treated.  The 
most  common  and  serious  problem  resulting  from  concentration  polarization  15  the  increasing  tendency  for  precipitation  of 
sparingly  soluble  salts  and  the  deposition  of  particulate  matter  on  the  membrane  surface. 

DEMINERALIZATION  (DEE-MIN-er-al-uh-ZAY-shun)  DEMINERALIZATION 
A  treatment  process  which  removes  dissolved  minerals  (salts)  from  water. 

ENZYMES  (EN-zinres)  ENZYMES 

Organic  substances  (produced  by  living  organisms)  which  cause  or  speed  up  chemical  reactions.  Organic  catalysts  and/or  bio- 
chemical catalysts. 

ESTER  (ESS-ter)  ESTER 
A  compound  form<^d  by  the  reaction  between  an  acid  and  an  alcohol  with  the  elimination  of  a  molecule  of  water. 

FEEDWATER  FEEDWATER 
The  water  that  is  fed  to  a  treatment  process;  the  water  that  is  going  to  be  treated. 

FLUX  FLUX 
A  flowing  or  flow. 

HYDROLYSIS  (hi-DROLL-uh-sis)  HYDROLYSIS 
Chemical  reaction  in  which  a  compound  is  converted  into  another  compound  by  taking  up  water. 

OSMOSIS  (oz-MOE-sis)  OSMOSIS 

The  passage  of  a  liquid  from  a  weak  solution  to  a  more  concentrated  solution  across  a  semipermeable  membrane.  The  mem- 
brane allows  the  passage  of  the  water  ^solvent)  but  not  the  dissolved  solids  (solutes).  This  process  tends  to  equalize  the  condi- 
tions on  either  side  of  the  membrane. 

PERMEATE  (PURR-me-ate)  PERMEATE 
The  demlneralized  water. 

REVERSE  OSMOSIS  (oz-MOE-sis)  REVERSE  OSMOSIS 

The  application  of  pr?<isure  to  a  concentrated  solution  which  causes  the  passage  of  a  liquid  from  the  concentrated  solution  to  a 
weaker  solution  across  a  semipermeable  membrane.  The  membrane  allows  the  passage  of  the  water  (solvent)  but  not  the  dis- 
olved  solids  (solutes).  The  liquid  produced  is  a  demineralized  water.  Also  see  OSMOSIS. 


er|c  -^^"^ 


140  Water  Treatment 


SALINITY  SALINITY 

(1)  The  relative  concentration  of  d'ssolved  salts,  usually  sodium  chloride,  in  a  given  water. 

(2)  A  measure  of  the  concentratiui  of  dissolved  mineral  substances  in  water. 

SEQUESTRATION  (SEE-kwes-TRAY-shun)  SEQUESTRATION 

A  chemical  complexing  (forming  or  joining  together)  of  metallic  cations  (such  as  iron)  with  certain  inorganic  compounds,  such 
as  phosphate.  Sequestration  prevents  the  precipitation  of  the  metals  (iron).  Also  see  CHELATION. 

SPECIFIC  CONDUCTANCE  SPECIFIC  CONDUCTAiM^E 

A  rapid  method  of  estimating  the  dissolved-solids  content  of  a  water  supply.  The  measurement  indicates  the  capacity  of  a  sam- 
ple of  water  to  carry  an  electrical  current,  which  is  related  to  the  concentration  of  ionized  substances  m  the  wate  Also  called 
CONDUCTANCE. 

TOTAL  DISSOLVED  SOLIDS  (TDS)  TOTAL  DISSOLVED  SOLIDS  (TDS) 

All  of  the  dissolved  solids  in  a  water.  TDS  is  measured  on  a  sample  of  water  that  has  passed  through  a  very  fine  mesh  filter  to 
remove  suspended  solids.  The  water  passing  through  the  filter  is  evaporated  and  the  residue  represents  the  dissolved  solids. 
Also  see  SPECIFIC  CONDUCTANCE. 


FR?C  -  ^5 


Demineralization  141 


Chapter  16.  DEMINERALIZATION 

(Removal  of  Dissolved  Minerals  by  Membrane  Processes) 


(Lesson  1  of  3  Lessons) 


16.0    SOURCES  OF  iVIINERALIZED  WATERS 


As  our  country's  population  continues  to  grow,  so  does 
our  demand  for  more  water  resources.  Traditionally,  water 
supplies  have  been  obtained  from  "fresh  water"  sources. 
This  constantly  increasing  need  for  water  has  started  to 
deplete  the  available  fresh  water  supplies  in  some  areas  of 
the  country, 

Faced  with  potential  shortages,  water  planners  must  now 
consider  new  treatment  technologies  which  until  recently 
were  not  considered  tc  economically  feasible.  Since  most 
of  the  earth's  water  supplies  are  saline  (the  ocean  is  high  in 
dissolved  minerals)  rather  than  fresh,  these  impurities  must 
be  removed.  One  process  receiving  considerable  attention 
IS  demineralization,  Demineralization  is  the  process  which 
removes  dissolved  minerals  (salts)  from  water. 

All  available  water  supplies  can  be  classified  according  to 
their  mineral  quality.  All  waters  contain  various  amounts  of 
TOTAL  DISSOLVED  SOLIDS  (TDS)\  Including  fresh  water. 
A  majority  of  the  dissolved  materials  are  inorganic  r'inerals 
(salts)  Minerals  are  con  ^unds  commonly  found  in  nature 
which  consist  of  positive  netallic  ions  (such  as  calcium. 


sodium)  bonded  to  negative  ions  (such  as  chloride,  sulfate, 
carbonate)  Many  of  these  compounds  are  soluble  in  water 
and  come  from  the  weathering  and  erosion  of  the  earth's 
surface. 

Fresh  water  supplies,  which  have  been  the  major  sources 
of  water  developed  in  the  past,  usually  contain  less  than 
1000  mg/L  of  total  dissolved  solids.  Secondary  drinking 
water  standards  recommend  500  mg/L  TDS  as  the  limit 
Waters  containing  slightly  higher  concentrations  can  b^i 
used  without  adverse  effects. 

Brackish  water  contains  from  lOOO  to  10,000  mg/L  TDG 
(sea  water  has  35,000  mg/L  TDS).  Most  brackish  water  is 
found  in  groundwater.  Figure  16.1  shows  that  over  one  half 
of  the  United  States  overlays  groundwater  containing  TDS 
levels  ranging  from  1000  to  3000  mg/L.  To  date,  brackish 
water  has  not  been  widely  used  for  municipal  drinking  water 
supplies  because  of  its  highly  mineralized  taste  and  associ- 
ated problems  such  as  scaling  in  pipes.  With  the  advent  of 
new  treatment  technologies,  however,  demineralization  of 
brackish  waters  (including  reuse  of  wastewater)  has  great 
potential  for  further  development. 


HP 


Groundwottr  contoining  1,0CX>  ppm 
>^  Of  more  of  minerols 


^  Mintrolized  woter  ct  dtpth$ 
^   of  tnort  thon  500  ft 


Fig.  16. 1   Map  of  the  conterminous  United  States  showing 
depth  to  and  quality  of  shallowest  groundwater  containing 
more  than  1,000  mg/L  dissolved  solids 

(from  paper  by  Gill  Katz.  'Treating  Brackish  Water  for  Community  Supplies.'  published 
in  Proceedings  in  *Roie  of  Desalting  Technology."  a  series  of  Technology  Transfer 
Workshops  presented  by  the  Office  of  Water  Research  and  Technology) 


^  Total  Dissolved  Solids  (TDS)  All  of  the  dissolved  solids  in  a  water.  TDS  is  measured  on  a  sample  of  water  that  has  passeo  through  a 
very  fme  mesh  filter  to  remove  suspended  solids.  The  water  passing  through  the  filter  is  evaporated  and  the  residue  represents  the  dis- 
solved solids.  Also  see  SPECIFIC  CONDUCTANCE. 


1  t;  r\ 
I -JO 


1 42  Water  Treatment 


The  largest  available  source  of  water  in  terms  of  qualir/  is 
classified  as  sea  water,  which  usually  contains  more  than 

35.000  mg/L  TDS.  While  sea  water  may  be  an  important 
future  water  resource  because  of  its  seemingly  unlimited 
availability  In  coastal  areas,  It  is  more  expensive  to  treat  than 
brackish  water  because  of  Its  greater  TDS  concentration. 

The  purpose  of  this  chapter  is  to  introduce  and  familiarize 
the  water  treatment  plant  operator  with  the  newer  treatment 
processes  which  have  been  developed  to  remove  the  dis- 
solved minerals  (TDS)  from  water.  The  development  of  the 
membrane  demineralization  processes  have  significantly 
reduced  the  cost  of  demineralization.  This  savings,  com- 
bined with  diminished  fresh  water  supplies,  will  increase  the 
use  of  demineralization  treatment  processes.  The  large 
quantities  of  mineralized  groundwater  and  the  increased 
SALINITY^  of  many  rivers  and  lakes  due  to  waste  dis- 
charges, agricultural  runoff  and  other  uses  will  increase  the 
need  for  demineralization. 

Some  areas  of  the  United  States,  such  as  the  Florida  Gulf 
Coast,  are  already  tuming  to  demineralization.  A  report  by 
the  Office  of  Water  Research  and  Technology  indicates  the 
worldwide  capacity  of  brackish  water  demineralization 
plants  has  increased  from  zero  m  1962  to  over  100  MGD 
(380  MLD  or  megaliters  per  day)  by  1977.  Thus,  it  is 
important  that  the  water  treatment  plant  operator  become 
more  knowledgeable  concerning  the  methods  used  to  de- 
mineralize  water. 

QUESTIONS 

Write  your  ans^'ers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  174. 

16.0A  What  is  demineralization? 

16.0B  Why  is  sea  water  more  expensive  to  treat  than 
brackish  water? 

16.1  DEMINERALIZING  PROCESSES 

Methods  of  removing  minerals  from  water  can  be  divided 
into  two  classes:  (1)  those  that  use  a  phase  change  such  as 
freezing  or  distillation,  and  (2)  non-phase  change  methods 
such  as  reverse  osmosis,  electrodialysis  and  ion  exchange. 

Deminerallzing  processes  have  pnmarily  been  used  to 
remove  dissolved  inorganic  material  (TDS)  from  industrial 
water  and  wastewater,  municipal  water  an  J  wastewater,  and 
sea  water.  However,  some  processes  will  also  remove 
suspended  material,  organic  material,  bacteria  and  viruses. 
Application  of  the  various  deminerallzing  processes  is  par- 
tially dependent  upon  the  total  dissolved  solids  (TDS)  con- 
centration of  the  water  to  be  treated.  Figure  16.2  illustrates 
the  approximate  "DS  range  for  use  of  two  phase  change 
processes  (distillation  and  freezing)  and  three  non-phase 
change  processes  (reverse  osmosis,  electrodialysis  and  Ion 
exchange). 

The  selection  of  a  deminerallzing  process  for  a  particular 
application  depends  upon  several  factors  including: 


1.  Mineral  concentration  in  FEEDWATER^  (brackish  water 
supply), 

2  Product  water  quality  required, 
3.  Bnne  disposal  facilities, 
4  Pretreatment  required, 

5.  Need  to  remove  other  material  such  as  bacteria  and  virus, 
and 

6.  Availability  of  energy  and  chemicals  required  for  the 
process. 

The  basic  system  is  similar  for  all  deminerallzing  pro- 
cesses and  includes  the  processes  shown  in  Figure  16.3. 

Since  freezing  and  distillation  apply  pnmarily  to  sea  water 
deminerallzing  and  their  widespread  use  seems  unlikely, 
these  processes  will  not  be  discussed.  Neither  will  ion 
exchange  because  of  its  limited  use  for  brackish  water  (1000 
to  3000  mg/L  TDS).  Currently,  activity  within  the  water 
industry  is  focused  primarily  on  the  membrane  demineraliz- 
ing  processes,  known  as  revprse  osmosis  and  electrodialy- 
sis. 

QUESTIONS 

Write  your  answers  m  a  notebook  and  then  compare  your 
answers  with  those  on  page  174. 

1 6  1 A  List  the  two  classes  of  methods  of  removing  minerals 
from  water. 

16.1B  List  the  common  membrane  deminerallzing  pro- 
cesses. 

16.2    REVERSE  OSMOSIS 

16.20  What  is  Reverse  Osmosis? 

Osmosis  can  be  defined  as  the  passage  of  a  liquid  from  a 
weak  solution  to  a  more  concentrated  solution  across  a 
semipermeable  membrane.  The  membrane  allows  the  oas- 
sage  of  the  water  (solvent)  but  not  the  dissolved  solids 
(solutes). 

Osmosis  plays  a  vital  role  in  many  biological  processes. 
Nutrient  and  waste  minerals  are  transported  by  osmosis 
through  the  cells  of  animal  tissues,  which  show  varying 
degrees  of  permeability  to  different  dissolved  solids.  A 
stnking  example  of  a  natural  osmotic  process  is  the  behav- 
ior of  blood  cells  placed  in  pure  water.  Water  passes  through 
the  cell  walls  to  dilute  the  solution  inside  the  cell.  The  cell 
swells  and  eventually  bursts,  releasing  its  red  pigment.  If  the 
blood  cells  are  placed  in  a  concentrated  sugar  solution,  the 
reverse  process  occurs;  the  cells  shrink  and  shrivel  up  as 
water  moves  out  into  the  ^ugar  solution. 


The  bottom  half  of  Figure  16.4  illustrates  osmosis.  The 
transfer  of  the  water  (solvent)  from  the  fresh  side  of  the 
membrane  continues  until  the  level  (shown  in  shaded  area) 
r  ses,  and  the  head  or  pressure  is  large  enough  to  prevent 


2  Salinity   ( 1)  The  relative  concentration  of  dissolved  salts,  usually  sodium  chloride,  m  a  given  water.  (2)  A  measure  of  the  concentration 
of  dissolved  mineral  substances  in  water. 

3  Feedwater.   Tne  water  that  is  fed  to  a  treatment  process:  the  water  that  is  going  to  be  treated. 


Deminerafization 


I 

ION  EXCHANGE 


ELECTRODIALYSIS 


REVERSE  OSMOSIS 
 f  


-"1 
 I 


FR 

EEZtNG 

DIST 

ILLATION 

to 


100  1000  10,000 

TDS    CONCENTRATION,  mg/L 


100,000 


NOTE:  The  dashed  lines  indicate  a  feasible  range  of  oper- 
ation, but  not  typical  range. 

Fig.  16.2  Demineralization  processes  versus 
feedwater  TDS  concentrations 


BRACKISH 


WATER  SUPPLY 


PRETREATMENT 


PUMP 


DESALTING 
PROCESS 


PRODUCT. 


WATER 


BRINE  TO  V?A5T£ 


Fig.  16.3  Basic  system  for  demmeralizing  processes 


144  Water  Treatment 


REVERSE  OSMOSIS-FLOW  REVERSED  BY  APPLICATION  OF 
PRESSURE  TO  HIGH  CONCENTRATION  SOLUTION 


PRESSURE 


SEMIPERMEABLE 
MEMBRANE 


I 


CONCENTRATED 
SOLUTION 


i 


FRESH  WATER 


OSMOSIS-NORMAL  FLOW  FROM  LOW  TO  HIGH 
CONCENTRATION 


OSMOTIC 
PRE&SURE 


SEMIPERMEABLE 
MEMBRANE 


CONCENTRATED 
SOLUTION 


i 


1 


FRESH  WATER 


Fig.  16.4   Rows  through  a  semipermeable  membrane 


ERIC 


15  J 


Demineralization   1 45 


any  net  transfer  of  the  solvent  (water)  to  the  .nore  concen- 
trated solution.  At  equilibrium,  the  quantity  of  water  passing 
in  either  direction  is  equal,  the  difference  in  water  level 
between  the  two  sides  of  the  membrane  is  defined  as  the 
osmotic  prt.*^sure  of  the  solution. 

If  a  piston  IS  placed  on  the  more-concentrated  solution 
Side  of  the  semipermeable  membrane  (Figure  16.4)  and  a 
pressure,  P,  is  applied  which  is  greater  than  the  osmotic 
pressure,  water  flows  from  the  more  concentrated  solution 
to  the  "fresh"  water  side  of  the  membrane.  This  condition 
illustrates  the  process  of  reverse  osmosis. 

16.21   Reverse  Osmosis  Membrane  Structure  and 
Composition 

Many  materials  have  been  studied  and  characterized  for 
possible  value  as  membranes  for  water  purificat'on  The 
best  general-purpose  membrane  developed  to  date  is  sim- 
ply described  as  a  modified  cellulose  acetate  film.  The 
techniques  for  preparing  these  membranes  were  discovered 
by  Loeb  and  Sourirajan  at  UCLA.  Table  16.1  lists  the 
important  characteristics  of  the  common  types  of  mem- 
branes. 


TABLE  16.1    CHARACTERISTICS  OF  MEMBRANE  TYPES 

A.  CELLULOSE  ACETATE  CLASS 

(cellulose  diacetate,  cellulose  triacetate  and  blended  cel- 
lulose diacetate/triacetate) 

1.  Membrane  must  be  wetted  in  storage. 

2.  Membrane  is  susceptible  to  hydrolysis  at  high  and  low 
pH. 

3.  Membrane  is  susceptible  to  deterioration  in  the  pres- 
ence of  microorganisms  capable  of  cellulose  enzyme 
production. 

4.  Membrane  is  subject  to  compaction  and  loss  of  pro- 
ductivity with  time. 

5.  Membrane  can  withstand  prolonged  maximum  oxidant 
concentration  of  one  milligram  per  liter. 

B.  POLY  AMIDE.  .EMBRANE 

1.  Membrane  is  not  subject  to  biological  degradation. 

2.  Membrane  is  extremely  sensitive  to  oxidants. 

3.  Membrane  can  operate  in  a  pH  range  of  4  to  11 
without  hydrolysis. 

4.  Membrane  can  operate  at  higher  temperatures  with- 
out degradation. 

C  THIN  FILM  COMPOSITE 

1.  Membrane  is  wet-dry  stable. 

2.  Membrane  has  a  thin  semipermeable  barrier  which 
results  in  a  high  flux. 

3.  Membrane  has  a  high  selectivity. 

4.  Membrane  has  an  improved  resistance  to  compaction 
and  bacterial  attack. 

5.  Membrane  has  improved  stability  at  high  tempera- 
tures. 

6.  Membrane  is  stable  m  acidic  (p  i  2)  and  caustic  feed 
(pH  12). 

7.  Membrane  is  sensitive  to  oxidants. 


The  modified  cellulose  acetate  membrane  in  general  use 
today  IS  approximately  100  m  thick  (that  is,  100  microns  or 
0  004  in.).  The  membrane  is  asymmetnc  (one  side  different 
from  the  other),  having  on  one  surface  a  relatively  dense 
layer  approximately  2000  A  (1  cm  1  x  10®  A  or  100  million 
Angstroms)  or  0.2  micron  thick  which  serves  as  the  rejecting 
surface.  The  remainder  of  the  film  is  a  relatively  spongy 
porous  mass,  the  membrane  currently  in  use  contains 
approximately  two-thirds  water  by  weight,  and  generally 
must  be  maintained  wet  at  all  times. 

In  recent  years,  progress  m  developing  new  polymenc 
materials  superior  ♦o  cellulose  acetate  membrane  have 
produced  a  family  of  new  materials  consisting  of  aromatic 
polyamids  and  polyimides.  Although  not  widely  available  on 
a  commercial  scale  yet,  these  thin-film  composite  mem- 
branes appear  to  have  several  advantages  over  the  old 
cellulose  type  and  are  considered  to  be  the  membrane  of  the 
future 


16.22   Membrane  Performance  and  Properties 

The  bZoic  behavior  of  semipermeable  cellulose  acetate 
reverse  osmosis  membranes  can  be  described  by  two 
equations.  The  product  water  flow  through  a  semipermeable 
membrane  can  be  expressed  as  shown  in  Equation  1. 


EQUATION  1 

-  A(AP  -  A;:) 

Where 

=  Water  FLUX^  (gm/sq  cm  -  sec), 

A  =  Water  permeability  constant  (gm/sq  cm  -  sec  atm^), 

aP  =  Pressure  differential  applied  across  the  membrane 
(atm). 

Att  =  Osmotic  pressure  differential  across  the  membrane 
(atm) 


Note  that  the  water  flux  is  the  flow  of  water  in  grams  per 
second  through  a  membrane  area  of  one  square  centimeter. 
Think  of  this  as  similar  to  the  flow  through  a  rapid  sand  filter 
in  gallons  per  minute  through  a  filter  area  of  one  square  foot 
(GPM/sq  ft). 

The  mineral  (salt)  flux  (mineral  passage)  through  the 
membrane  can  be  expressed  as  shown  in  Equation  2. 


EQUATION  2 

Fs  -  B(C,  -  C2) 

Where 

Fg  ^  Mineral  flux  (gm/sq  cm  -  sec), 

B  ^  Mineral  permeability  constant  (cm/sec), 

-  C2  ^  Concentration  gradient  across  the  niembrane 
(gm/cu  cm). 


The  water  permeability  (A)  and  mineral  permeability  (B) 
constants  are  characteristics  of  the  particular  membrane 
which  IS  used  and  the  processing  which  it  has  received. 


ERIC 


^  Flux.  A  flowing  or  flow. 

5  atm,   Ttie  abbreviatioii  fot  atmosphere.  One  atmosptiere  is  equal  to  a  pressure  of  14.7 psi  or  101  kPa 


160 


1 46  Water  Treatment 


An  examination  of  Equations  (1)  and  (2)  shows  that  the 
water  flux  (the  rate  of  water  flow  through  the  membrane)  is 
dependent  upon  the  applied  pressure,  WHILE  THE  MINER- 
AL FLUX  IS  NOT  DEPENDENT  ON  PRESSURE.  As  the 
pressure  of  the  feedwater  is  increased,  the  flow  of  water 
through  the  membrane  increases  while  the  flow  of  minerals 
remains  essentially  constant.  Therefore,  both  the  quantity 
and  the  quality  of  the  purified  product  should  increase  with 
increased  pressure.  This  occurs  because  there  is  more 
water  to  dilute  the  same  amount  of  mineral. 

The  water  flux  DECREASES  (F J  as  the  mineral  content  of 
the  feed  increases  because  the  osmotic  pressure  contribu- 
tion increases  (Att)  with  increasing  mineral  content.  In  other 
words,  Since  Att  increases,  the  term  (aP  -  Att)  decreases 
which  results  in  a  decrease  in  F^^,  the  water  flux.  Further,  as 
more  and  more  feed  water  passes  through  the  membrane, 
the  mineral  content  of  the  feedwater  becomes  higher  and 
higher  (more  concentrated).  The  osrotic  pressure  contribu- 
tion (Att)  of  the  concentrate  increases,  resulting  in  a  lower 
water  flux. 

Finally,  since  the  membrane  rejects  a  constant  percentage 
of  mineral,  product  water  quality  decreases  with  increased 
feedwater  concentration.  Also  note  that  Equation  2  reveals 
that  the  greater  the  concentration  gradient  (C,  -  Cp)  across 
the  membrane,  the  greater  the  mineral  flux  (miner  i  flow). 
Therefore,  the  greater  the  feed  concentration,  the  greater 
the  mineral  flux  and  also  mineral  concentration  in  the 
product  water. 

Water  treatment  plant  operators  must  have  a  basic  under- 
standing of  these  mathematical  relationships  which  describe 
RO  (reverse  osmosis)  membrane  performa«.s.r.  To  help 
develop  a  better  understanding  of  the  interrelationships  of 
flux,  rejection,  time,  temperature,  pH,  and  recovery,  further 
explanation  of  these  variables  continues  in  the  next  section. 


EXAMPLE  1 

Convert  a  water  fiux  of  5  x  10"**  gm/sq  cm  -  sec  to 
gallons  per  day  per  squa^'e  foot. 


Known 


Unknown 


^^rl^cn'""'      =5xi0-''gm/cm-sec«    F'ow,  GPD/sq  ft 
gm/sq  cm-sec  ^  ' 

Convert  the  water  flux  from  gm/sq  cm  -  sec  to  flow  in  GPD/ 
sq  ft. 

Water  Flux, 

F'ow.  (gm/sq  cm-secH1  liter)  (1  Gat)  (100  cm)2  (3600  sec)  (24  hr) 

^^1^  (1000  gm)  (3.785  L)  (3  28  ft)2  (1  hr)  (1  day) 

(0  0005  gm/sq  cPTsec)(1  Liter)(1  Gat)(l00cm)2  (3600  sec)  ^24  hr) 
(1000  gm)  (3  785  L)  (3  28  It)^  (1  hr)  (1  day) 
-  106QPO/sqft 


QUESTIONS 

Write  your  answer*^  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  174. 

16  2A  What  is  the  osmotic  pressure  of  a  solution? 

1 6.2B  What  type  of  semipermeable  membrane  is  commonly 
used  today? 

16.2C  What  Is  the  meaning  of  water  flux  and  of  mineral 
flux'?  What  units  are  used  to  express  measurement 
of  these  quantities? 

16  2D  When  additional  pressure  is  applied  to  the  side  of  a 
membrane  with  a  concentrated  solution,  what  hap- 
pens? 

16.2E  When  higher  mineral  concentrations  occur  in  the 
feedwater,  what  happens  to  the  product  water? 

16.23   Definition  of  Flux 

The  term  flux  is  the  expression  used  to  describe  the  rate 
of  water  flow  through  the  semipermeable  membrane.  Flux  is 
usually  expressed  in  gallons  per  day  per  square  foot  of 
membrane  surface  or  in  grams  per  second  per  square 
centimeter. 

Even  under  ideal  conditions  (pure  feedwater  and  no 
fouling  of  the  membrane  surface),  there  is  a  decline  in  water 
flux  with  time.  This  decrease  in  flux  is  due  to  membrane 
compaction.  This  phenomenon  is  considered  comparable  to 
"creep"  observed  in  other  plastics  or  even  metals  when 
subjected  to  compressing  stresses  (pressure;. 

The  term  "flux  decline"  is  used  to  lescribe  the  loss  of 
water  flow  through  the  membrane  due  to  compaction  plus 
fouling.  In  the  real  world,  feedwaters  are  never  "pure"  and 
contain  suspended  solids,  dissolved  organics  and  inorgan- 
ics, bactena,  and  other  potential  foulants.  These  impurities 
can  be  deposited  or  grow  on  the  membrane  surface,  thus 
hindenng  the  flow  of  water  through  the  membrane. 


16.24  Mineral  Rejection 

The  purpose  of  demineralization  is  to  separate  minerals 
from  water  and  the  ability  of  the  membrane  to  reject  minerals 
IS  called  the  mineral  rejection.  Mineral  rejection  is  cJefined  as: 

EQUATIONS 

^  .         ^  Product  Concentration 

Reje^/ion,  %  =  (1  -  - — ;  )  x  100% 

Feedwater  Concentration 


6  5  X  10-*  IS  the  same  as  0.0005. 


ERLC 


16.1 


Demineralization  147 


Mineral  rejections  can  be  determined  by  measuring  the  TDS 
and  using  the  above  equation.  Rejections  also  may  be 
calculated  for  individual  constituents  in  the  solution  by  using 
their  concentrations. 

The  basic  equations  which  describe  the  performance  of  a 
reverse  osmosis  membrane  indicate  that  rejection  de- 
creases as  feedwater  mineral  concentration  increases.  Re- 
member, this  IS  because  the  higher  mineral  concentration 
increases  the  osmotic  pressure.  Figure  16.5  illustrates  the 
rejection  performance  for  a  typical  RO  (reverse  osmosis) 
membrane  operating  en  three  different  feedwater  solutions 
This  figure  shows  that  as  feed  mineral  concentration  in- 
creases (TDS  in  mg/L),  rejection  decreases  at  a  given  feed 
pressure.  Notice  also  that  rejection  improves  as  feed  pres- 
sure increases. 

Typical  rejection  for  most  commonly  encountered  dis- 
solved inorganics  is  usually  between  92  to  95  percent. 
Divalent  ions  like  calcium  and  sulfate  are  better  rejected  than 
monovalent  ions  such  as  sodium  or  cnloride.  Table  16.2  lists 
the  typical  rejection  of  an  RO  membrane  operating  on  a 
brackish  feedwater. 


TABLE  16.2  TYPICAL  REVERSE  OSMOSIS  REJECTIONS 
OF  COMMON  CONSTITUENTS  FOUND  IN  BRACKISH 
WATER 


Known  Unknown 

Feedwater  TDS.  mg/L  =  1500  mg/L    Mineral  Rejection,  % 
Product  Water  TDS.    =  150  mg/L 
mg/L 

Calculate  the  mineral  rejection  as  a  percent. 

Product  TDS.  mg/L 


Mineral  Rejeciion.  %  =  (1 
-  (1 


Feed  TDS,  mg/L 
150  mg/L, 


)(100%) 


)(100%) 


1500  mq/L 
=  (1  -  0.1)(100%) 

=  90% 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  174. 

16.2F  Water  flux  is  usually  expressed  in  what  units? 

16.2G  What  IS  "flux  decline"? 

16.2H  How  is  mineral  rejection  measured? 


Contamination 

Units 

Feedwater 

Percent 

Concentration 

Remova* 

EC^ 

^mhos 

1400 

92 

TDS^ 

mg/L 

900 

92 

Calcium 

mg/L 

100 

99 

Chloride 

mg/L 

120 

92 

Sulfate 

mg/L 

338 

99 

Sodium 

mg/L 

158 

92 

Ammonia 

mg/L 

22.5 

94 

Nitrate 

mg/L 

2.9 

55 

COD^ 

mg/L 

12.5 

95 

TOC^ 

mg/L 

6.0 

88 

Silver 

Mg/L 

1.2 

88 

Arsenic 

Mg/L 

<5.0 

Aluminum 

Mg/L 

71.0 

93 

Banum 

Mg/L 

24.0 

96 

Beryllium 

<1.0 

Cadmium 

Mg/L 

3.4 

98 

Cobalt 

Mg/L 

4.6 

>90 

Chromium 

Mg/L 

3.6 

80 

Copper 

Mg/L 

12.7 

63 

Iron 

Mg/L 

24.0 

91 

Mercury 

Mg/L 

0.8 

41 

Manganese 

Mg/L 

1.0 

85 

Nickel 

Mg/L 

2.5 

88 

Lead 

Mg/L 

<1.0 

Selenium 

Mg/L 

<5.0 

Zinc 

Mg/L 

<100.0 

a  EC.  Electrical  Conductivity;  TDS,  Total  Dissolved  Solids.  COD, 
Chemical  Oxygen  Demand.  andTOC.  Total  Organic  Carbon 

EaAMPLE2 

Estimate  the  ability  of  a  reverse  osmosis  plant  to  reject 
minerals  by  calculating  the  mineral  rejection  as  a  percent. 
The  feedwater  contains  1500  mg/L  TDS  and  the  product 
water  TDS  is  150  mg/L. 


16.25  Effects  of  Feedwater  Temperature  and  pH  on 
Membrane  Performance 

In  reverse  osmosis  operation,  feedwater  temperature  has 
a  significant  effect  on  membrane  performance  and  must 
therefore  be  taken  into  account  in  system  design  and 
operation.  Essentially,  the  value  of  the  water  permeation 
constant  is  only  constant  for  a  given  temperature.  As  the 
temperature  of  the  feedwater  increases,  flux  increases. 
Usually,  flux  is  reported  at  some  standard  temperature 
reference  condition,  such  as  25°C.  Figure  16,6  illustrates  the 
increase  in  flux  for  a  standard  RO  module  over  a  range  of 
operating  temperatures  when  400  psi  (2758  kPa  or  28  kg/sq 
cm)  net  operating  pressure  is  applied. 

You  must  remember  that  the  membrane  is  an  ESTER'^  and 
therefore  sub;jct  to  long-term  HYDROLYSIS^.  Hydrolysis 
results  in  a  lessening  of  mineral  rejection  capability.  The  rate 
of  hydrolysis  is  accelerated  by  increased  temperature,  and 
IS  also  a  function  of  feed  pH  (Figure  16.7).  Slightly  acidic  pH 
values  (5  to  6)  insure  a  lower  hydrolysis  rate,  as  do  cooler 
temperatures.  Therefore,  to  insure  the  longest  possible 
lifetime  of  the  membrane  and  to  slov.  hydrolysis,  acid  is 
added  as  a  pretreatment  step  before  demineralization.  Table 
16,3  indicates  the  relative  time  for  mineral  passage  to 
increase  200  percent  at  different  feedwater  pH  levels. 


TABLE  16,3  TIME  REQUIRED  TO  ACHIEVE  A  200 
PERCENT  INCREASE  IN  MINERAL  PASSAGE  AT  l^^'C 
AT  VARIOUS  pH  LEVELS 


pH  5.0 
6.0 
7.0 
8.0 
9.0 


6  years 
3.8  years 
1  year 

0.14  year  =  51  days 
0.01  year  =  3.6  days 


7  Ester  (E^S'ter).  A  compound  formed  by  the  reaction  between  an  acid  and  an  alcohol  with  the  elimination  of  a  molecule  of  water 

8  Hydrolysis  (hi'DROLL-uh-sis).  Chemical  reaction  in  which  a  compound  is  converted  into  another  compound  by  taking  up  water 


ERIC 


148  Water  Treatment 


2 
O 

& 

LU 
"5 
LU 
C 
-J 
< 

cc 

LU 

:e 


82 


80 


3 

1000 
H  5000 
1 10,000 

1 

! 

— Jl  

i 
1 

— r  

1 

i 
1 

j 
j 

i 

i 

1 

1 

» 

1 
i 
1 

SODIUM  CI 

APPL 
STANDA 

'  1  

HLORIDE  REJECTION 
VS 

lED  PRESSURE 
RD  FLUX  MODULE 

200 


400 


600 


800 


1000 


1200 


1400 


FEED  PRESSURE,  psi 


ERLC 


Fig,  16.5   Typical  RO  rejection  for  three  different  feedwater  concentrations  of  TDS  in  mg/L 

(Source  REVERSE  OSMOSIS  PRINCIPLES  AND  APPLICATIONS  by  Fluids  Systems.  D.v.s.on  of  HOP.  October  1970) 

163 


!:eri'i»neraii^?iiion    *  4? 


50  60  70  80  90 


FEEDWATER  TEMP.  F*^ 


Fig.  16.6  Effect  of  temperature  on  water  flux  rate,  cellulose  acetate 
membrane  operating  pressure  at  400  psi  (2758  kPa  or  28  kg/sq  cm)  net 

{Source  REVERSE  OSMOSiS  PRINCIPLES  AND  APPLICATIONS  by  Ftuids  Systems.  Division  of  UOP.  October  1970 


er|c  ^^^'l 


ISO  Water  Treatment 


Demineralization  151 


16.26  Recovery 

Recovery  is  defined  as  the  percentage  of  feed  flow  which 
IS  recovered  as  product  water.  Expressed  mathematically, 
recovery  can  be  determined  by  Equation  4 

EOUATION  4 

Product  Flow  ^  ^ 

Reco*  ary,  %,  =  (1 007o) 

Feed  Flow 

The  recovery  rate  is  usually  determined  or  limited  by  two 
considerations.  The  first  is  the  desired  product  water  quality. 
Since  the  amount  of  mineral  passing  through  the  membrane 
IS  influenced  by  the  concentration  differential  between  the 
brine  and  product,  there  is  a  possibility  of  exceeding  product 
quality  criteria  with  excessive  recovery.  The  second  consid- 
eration concerns  the  soluoility  limits  of  minerals  in  the  brine. 
One  should  not  concentrate  the  bnne  to  a  degree  that  would 
precipitate  minerals  on  the  membrane.  This  effect  is  com- 
monly referred  to  as  concentration  polarization. 

THE  MOST  COMMON  AND  SERIOUS  PROBLEM  RE- 
SULTING FROM  CONCENTRATION  POLARIZATION  IS 
THE  INd^EASING  TENDENCY  FOR  PRECIPITATION  OF 
SPARINGLY  SOLUBLE  SALTS  AND  THE  DEPOSITION  OF 
PARTICULATE  MATTER  ON  THE  MEMBRANIl  SURFACE. 

In  any  flowing  hydraulic  system,  the  fluid  near  a  solid 
surface  travels  more  slowly  than  the  main  stream  of  the  fluid. 
In  other  words,  there  is  a  liquid  boundary  layer  at  the  solid 
surface.  This  is  ai'^o  true  at  the  su.  face  of  the  membrane  in  a 
spiral  wound  eleme  .t  or  in  any  other  membrane  packaging 
configuration.  Since  water  is  transmitted  through  the  mem- 
brane at  a  much  more  rapid  rate  than  minerals,  the  concen- 
tration of  *...e  minerals  builds  up  in  the  boundary  layer  and  it 
is  necessary  for  the  minerals  to  diffuse  back  into  the  flowing 
stream.  The  ratio  of  the  mineral  concentration  in  the  bound- 
ary layer  (layer  of  water  next  to  membrane)  to  the  mineral 
concentration  in  the  flowing  water  is  defined  as  concentra- 
tion polanzation.  Polarization  will  reduce  both  the  flux  and 
rejection  of  a  reverse  osmosis  system.  Since  it  is  impractical 
to  totally  eliminate  the  polarization  effect,  it  is  necessary  to 
minimize  it  by  good  design  and  operation. 

The  boundary  layer  effect  can  be  minimized  by  increased 
water  flow  velocity  and  by  promoting  turbulence  within  the 
RO  elements.  Brine  flow  rates  can  be  kept  high  as  product 
water  is  removed  by  staging  (reducing)  the  module  pressure 
vessels.  This  is  popularly  referred  to  as  a  "Christmas  Tree" 
crangement.  Typical  flow  arrangements  such  as  4  units  -  2 


units  -  1  unit  (85  percent  recovery)  or  2  units  -  1  unit  (75 
percent  recovery)  are  used  most  often  (Figure  16.8). 

These  configurations  consist  of  feeding  water  to  a  series 
of  pressure  vessels  in  parallel  where  about  50  percent  of  the 
water  is  separated  by  the  membrane  as  product  water  and 
50  percent  of  the  water  is  rejected  The  reject  is  then  fed  to 
half  as  many  vessels  in  parallel  where  again  about  50 
percent  is  product  water  and  50  percent  rejected.  This  reject 
becomes  the  feed  for  the  next  set  of  vessels.  By  arranging 
the  pressure  vessels  in  the  4-2-1  arrangement,  it  is  possible 
to  recover  over  85  percent  of  the  feedwater  as  product 
water  and  to  maintain  adequate  flow  rates  across  the 
membrane  surface  to  minimize  polanzation.  For  example,  a 
system  consisting  of  a  total  of  35  vessels  would  have  a 
configuration  of  20-1 0-5  pressure  vecsel  arrangement  for  an 
85  percent  recovery. 


EXAMPLES 

Estimate  the  percent  recovery  of  a  reverse  osmosis  unit 
with  a  4-2-1  arrangement  if  the  feed  flow  is  5.88  MGD  and 
the  product  flow  is  5.0  MGD. 


Known 

Product  Flow,  MGD  =  5.0  MGD 
Feed  Flow,  MGD     =  5.88  MGD 
Calculate  the  recovery  as  a  percent 

(Product  Flow,  MGD)  (100%) 


Unknown 

Recovery,  % 


Recovery,  %  ■■ 


(Feed  Flow,  MGD) 
(5.0  MGD)  (1C0%) 


(5.88  MGD) 


=  857o 


QUESTIONS 

Wnte  your  answerf  'n  a  notebook  and  then  compare  your 
a.iswers  with  those  on  page  174 

16.21   How  will  an  increase  in  feedwater  temperature  influ- 
ence the  water  flux? 

16.2J  How  does  hydrolysis  influence  the  mineral  rejection 
capability  of  a  membrane? 

16.2K  How  IS  recovery  defined? 

16.2L  Recovery  rate  is  usually  limited  by  what  two  consid- 
erations? 

16  2M  Define  concentration  polarization. 


ERIC 


152  Water  Treatment 


FOUR 
PRESSURE 
VESSELS 


TWO 
PRESSURE 
VESSELS 


ONE 
PRESSURE 
VESSEL 


FEED  WATER 


BRINE  TO 
WASTE 


NOTES:  1.  BRINE  FLOWS  OUT  OF  PRESSURE 
VESSELS  TO  NEXT  VESSEL. 
2.  PRODUCT  WATER  IS  NOT  SHOWN. 

PRODUCT  WATER  FLOWS  OUT  OF  EACH 
VESSEL  INTO  A  COMMON  HEADER. 


Fig.  16.8   Typical  4-2-1  ■'Christmas  Tree"  arrangement 


ERIC 


16*7 


Demineraiization  153 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  16.  DEMINEFIALIZATION 

(Lesson  1  of  3  Less  ^s) 


At  the  end  of  each  lesson  in  this  chapter  you  will  f...d  some 
discussion  and  review  questions  that  you  should  work 
before  continuing.  purpose  of  these  questions  is  to 
•ndicate  to  you  how  well  >?'j  understand  the  material  in  the 
lesson.  Write  the  answers  to  these  questions  in  your  note- 
book before  continuing. 

1.  Why  has  brackish  water  not  been  widely  used  for 
municipal  drinking  water  supplies? 

2.  What  IS  reverse  osmosis'? 

3.  Indicate  what  will  happen  to  both  the  water  flux  and 
mineral  flux  when: 

1.  Pressure  differential  applied  across  the  membrane 
(AP)  increases, 


2.  Osmotic  pressure  differentia!  across  the  membrane 

(Itt)  increases,  and 
3  Concentration  gradient  across  the  membrane  (C,  - 

Cg)  increases. 

4.  What  usually  happens  to  water  flux  with  time  and  why? 
5  How  does  fouling  develop  on  membranes? 

6.  What  factors  influence  the  rate  of  hydrolysis  of  a  mem- 
brane and  how? 

7.  What  is  the  most  common  and  serious  problem  result- 
ing from  concentration  polarization? 

8.  Why  do  demineraiization  plants  use  a  pressure  vessel 
Christmas  tree  configuration'? 


CHAPTER  16.  DEM:NERALIZATI0N 

(Lesson  ^  of  3  Lessons) 


16.3   DIFFERENT  TYPES  OF  REVERSE  OSMOSIS 
PLANTS 

Operating  plants  use  the  RO  principle  in  several  different 
process  designs  and  membrane  configurations.  There  are 
three  types  of  commercially  available  membrane  systems 
which  have  been  used  in  operating  plants: 

1.  Spiral  wound, 

2.  Hollow  fine  fiber,  and 

3.  Tubular. 

The  spiral-wound  RO  module  was  developed  by  Gulf  Envi- 
ronmental Systems  Company  (now  Fluid  Systems  Division, 
UOP)  under  contract  to  ♦'.e  U.S.  Office  of  Saline  Water.  This 
RO  unit  was  conceived  as  a  method  of  obtaining  a  relatively 
high  ratio  of  'Membrane  area  to  pressure  vessel  volume.  The 
membrane  is  supported  on  both  sides  of  a  backing  material 
and  sealed  with  g''ie  on  3  of  the  4  edges  of  the  laminate.  The 
laminate  is  also  sealed  to  a  central  tube  which  has  been 
drilled  to  allow  the  demineralized  vvater  to  enter.  The  mem- 
brane surfaces  are  separated  by  a  screen  material  which 
acts  as  a  bnne  spacer.  The  entire  package  is  then  rolled  into 
a  spiral  configuration  and  wrapped  in  a  cylindrical  form.  The 
membrane  modules  are  ludrfed,  end  to  end,  into  a  pressure 
vessel  as  shovvn  m  Figure  16.9.  Feed  flow  is  parallel  to  the 
central  tube  while  PERMEATE^  flows  through  the  mem- 
brane toward  the  central  tube.  Plants  using  this  type  of 


system  include  the  brackish  water  dcmineralizing  plants  at 
Key  Largo,  Florida  and  Kashima,  Japan;  the  wastewater 
demineralizing  plants  in  California;  and  the  sea  water  demin- 
eralizing  plant  at  Jeddah  m  Saudi  Arabia. 

The  hollow  fiber  type  of  membrane  was  developed  by 
DuPont  and  Dow  Chemical.  The  membranes  manufactured 
by  DuPont  are  made  of  aromatic  polyamide  fibers  about  the 
size  of  a  human  hair  with  an  inside  diameter  of  about  0.0016 
inch  (0.04  mm).  In  thi?3e  very  small  diameters,  fibers  can 
withstand  high  pressures.  In  an  operating  process  the  fibers 
are  placed  in  a  pressure  vessel;  one  end  of  each  fiber  is 
sealed  and  the  other  end  protrudes  outside  the  vessel.  The 
brackish  water  is  under  pressure  on  the  outside  of  the  fibers 
and  product  water  flows  inside  of  the  fiber  to  the  open  end.  A 
DuPont  module  is  illustrated  in  Figure  16.10.  For  operating 
plants,  the  membrane  modules  are  assembled  in  a  config- 
uration Similar  to  the  spiral  wound  unit.  Municipal  demineral- 
izing plants  (manufactured  by  DuPont)  in  Greenfield,  Iowa 
and  in  ^londa  and  sea  water  demineralizing  plants  m  the 
Middle  East  use  this  type  of  membrane. 

Tubular  membrane  processes  operate  on  much  the  same 
principle  as  the  hollow  fine  fiber  except  that  the  tubes  are 
much  larger  in  diameter,  on  the  order  of  0.5  inch  (12  mm). 
Use  of  this  type  of  membrane  system  is  usually  limited  to 
special  situations  suf'h  as  for  wastewater  with  high  sus- 
pended solids  concentration.  The  tubular  membrane  proc- 
ess IS  net  economically  competitive  with  other  available 
systems  for  treatment  of  most  waters. 


5  Permeate  (PURR-me-ate). 


The  desalted  water.  This  /s  the  water  that  has  passed  through  the  membrane. 

163 


Water  Treatment 


EDGES  AND  TO  CENTER  TUBE) 


SPIRAL-WOUND  REVERSE  OSMOSIS  MODULE 


-PRODUCT  WATER 
OUTLET 


FEED  CONNECTION-, 


z:jl: 


-CONCENTRATE 
OUTLET 


^HYDRAUL 


IC 


TUBE 


SEAL" 


-MODULE 


PRESSURE    VESSEL  ASSEMBLY 


Fig,  16.9  Spiral-wound  reverse  osmosis  module  (as  manufactured  by  UOP) 


(From  paper  by  Mack  Wesrter.  'Desanirtg  Process  and  Pretreatment.-  published  m  Proceedings  on  -Role  of  Oesalt.ng  Technology  * 
a  series  oi  Technology  ^  /^ansfer  workshops  presented  by  the  Office  of  Water  Research  and  Technology) 


Demineralization  155 


FIBER   CROSS  SECTION 


SNAP  RING 

/ 

POROUS  FEED 
DISTRIBUTION  TUBE 


Fig,  16. 10  Hollow  fiber  reverse  osmosis  module  (as  manufactured  by  DuPont) 

(From  paper  by  Mack  Wesrier.  'Desalting  Process  and  Pretreatment.*  published  in  Proceedings  on  'Roto  of  OesaUmg  Techoology.' 
a  series  of  Tech'  Mogy  Transfer  Workshops  presented  by  the  Off^  of  Water  Research  and  TechrK>Jogy) 


170 


156  Water  Treatment 


QUESTiONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  175. 

16.3A  LfSt  the  three  types  of  commercially  available  mem- 
brane systems  which  have  been  used  in  operating 
plants. 

16  3B  What  type  of  membrane  process  is  used  to  treat 
wastewater  with  a  high  suspended  solids  concentra- 
tion? 

16.4  OPERATION 

16.40  Pretreatment 

Water  to  be  demineralized  always  contains  impurities 
which  should  be  removed  by  pretreatment  to  protect  the 
membrane  and  to  assure  maximum  efficiency  of  the  reverse 
osmosis  process.  Depending  on  the  water  to  be  demineral- 
ized, it  is  usually  necessary  to  treat  the  feedwater  to  remove 
materials  and  conditions  potentially  harmful  to  the  RO  proc- 
ess such  as: 

1.  Remove  turbidity/suspended  solids, 

2.  Adjust  pH  and  temperatures, 

3.  Remove  materials  to  prevent  scaling  or  fouling,  and 

4.  Disinfect  to  prevent  biological  growth. 

16.41  Removal  of  Turbidity  and  Suspended  Solids 

In  general,  the  feedwater  should  be  filtered  to  protect  the 
reverse  osmosis  system  and  its  accessory  equipment. 
When  the  water  source  is  a  groundwater  or  previously 
treated  municipal  or  industrial  wjpply,  this  may  be  accom- 
plished by  a  simple  screening  procedure.  However,  such  a 
procedure  may  not  be  adequate  when  the  source  is  an 
untreated  surface  water.  The  amount  of  suspended  matter 
in  surface  waters  may  vary  by  several  orders  of  magnitude 
and  may  change  radically  in  character  and  composition  In  a 
very  short  time.  In  such  cases,  in  addition  to  the  mechanical 
action  of  the  filter,  the  operator  may  have  to  introduce 
chemicals  for  coagulation  and  flocculation  and  use  filtration 
equipment  in  which  the  media  can  be  washed  or  renewed  at 
low  cost.  Pressure  and  gravity  sand  filters  and  diatoma- 
ceous  earth  filters  may  be  required,  particularly  for  large 
installations.  Where  the  particulates  approach  or  are  COL- 
LOIDAL,^^  chemical  treatment  and  filtration  are  almost 
essential. 

Cartridge  filters  function  as  a  particle  safeguard  and  not 
as  a  primary  particle  removal  device.  In  general,  the  influent 
turbidity  to  a  cartridge  filter  should  be  less  than  one  TU. 
Typical  cartridge  filter  sizes  range  from  5  to  20  microns  and 
loading  rates  vary  from  2  to  4  GPM  sq  ft  (1 .4  to  2.8  mm/sec). 

16.42  pH  and  Temperature  Control 

As  previously  discussed,  an  important  limiting  factor  in  the 
life  of  cellulose  acetate  membranes  in  reverse  osmosis  is 
the  rate  of  membrane  hydrolysis.  Cellulose  acetate  will 
break  down  (hydrolyze)  to  ceilulose  and  acetic  acid.  The  rate 
at  which  this  hydrolysis  occurs  is  a  function  of  feedwater  or 


source  water  pH  and  temperature.  As  the  membrane  hydro- 
lyzes,  both  the  amount  of  water  and  the  amount  of  solute 
which  permeate  the  membrane  increase  and  the  quality  of 
the  product  water  deteriorates.  The  rate  of  hydrolysis  is  at  a 
minimum  at  a  pH  of  about  4.7,  and  it  increases  with  both 
increasing  and  decreasing  pH.  Thus  it  is  standard  practice  to 
inject  acid,  usually  sulfuric  acid,  to  adjust  feedwater  pH  to 
5.5  Not  only  does  pH  adjustment  minimize  'he  effect  of 
hydrolysis,  but  it  is  also  essential  in  controlling  precipitation 
of  scale-forming  or  membrane-fouling  minerals. 

Calcium  carbonate  and  calcium  sulfate  are  probably  the 
most  common  scaling  salts  encountered  in  natural  waters 
and  are  certainly  the  most  common  cause  of  scale  in  reverse 
osmosis  systems.  The  addition  of  a  small  amount  of  acid  can 
reduce  the  pH  to  a  point  where  the  alkalinity  is  reduced;  this 
shifts  the  equilibnum  to  the  point  where  calcium  bicarbon- 
ate, which  is  much  more  soluble.  Is  present  at  all  points 
within  the  reverse  osmosis  loop.  Neutralization  of  75  percent 
of  the  total  alkalinity  usually  provides  sufficient  pH  adjust- 
ment to  achieve  calcium  carbonate  scale  control  and  bring 
the  membrane  into  a  reasonable  part  of  the  hydrolysis  curve. 
The  pH  reached  by  75  percent  neutralization  is  about  5.7. 
Calcium  carbonate  precipitation  is  also  inhibited  by  the 
control  procedure  used  for  calcium  sulfate. 

Calcium  sulfate  is  relatively  soluble  in  water  in  comparison 
to  calcium  carbonate.  Again,  however,  as  **pure''  or  product 
water  is  removed  from  a  feed  solution  containing  calcium 
and  sulfate,  these  chemicals  become  further  concentrated  in 
the  feed  water.  When  the  limits  of  saturation  are  eventually 
exceeded,  precipitation  of  calcium  sulfate  will  occur.  Since 
calcium  sulfate  solubility  occurs  over  a  wide  pH  range,  the 
scale  control  method  used  to  inhibit  calcium  sulfats  precipi- 
tation is  a  threshold  treatment^^  with  sodium  hexametapiiuD- 
phate  (SHMP).  This  precipitation  inhibitor  represses  both 
calcium  carbonate  and  calcium  sulfate  by  interfering  with  the 
crystal  formation  process.  Other  polyphosphates  may  also 
be  used  but  are  not  as  effective  as  the  hexametaphosphate. 
Generally  2  to  5  mg/L  of  SHMP  are  added  to  the  feedwater 
to  decrease  precipitation  of  calcium  sulfate. 


16.43  Other  Potential  Sealants 


The  oxides  or  hydroxides  most  commonly  found  in  water 
are  those  of  iron,  manganese,  and  silica.  The  oxidized  and 
precipitated  forms  of  iron,  manganese  and  silica  can  be  a 
serious  problem  to  any  demineralization  scheme  because 
they  can  coat  the  reverse  osmosis  membrane  with  a  tena- 
cious (difficult  to  remove)  film  which  will  affect  performance. 
The  scale  inhibitor  most  frequently  used  is  sodium  hexame- 
taphosphate. 


^0  Colloids  (CALL-loifls).    Very  small,  finely  divided  solids  (particles  that  do  not  dissolve)  that  remain  dispersed  in  a  liquid  for  a  long  time 
due  to  their  smail  size  and  electrical  charge.  When  most  of  the  particles  in  water  have  a  negative  electrical  charge,  they  tend  to  repel 
each  other.  This  repulsion  prevents  the  particles  from  clumping  together,  becoming  heavier,  and  settling  out. 
Threshold  treatment  refers  to  the  practice  of  using  the  least  amount  of  chemical  to  produce  the  desired  effect. 

ERIC 


Demineralization  157 


16.44  Microbiological  Organisms 

Reverse  osmosis  modules  provide  a  large  surface  area 
*or  the  attachment  and  growth  of  bacterial  slimes  and  molds. 
These  organisms  may  cause  membrane  fouling  or  even 
module  pluglng.  There  is  also  some  evidence  that  occasion- 
ally the  enzyme  systems  of  sonr>e  organisms  will  attack  the 
cellulose  acetate  membrane.  The  continuous  application  of 
chlorine  to  produce  a  1  ♦  2  mg/L  chlorine  residual  will  help 
inhibit  or  retard  the  growth  of  most  of  the  organisms 
encountered.  However,  caution  must  be  exercised  since 
continuous  exposure  of  the  membrane  to  nigher  chlorine 
residuals  will  impair  membrane  efficiency.  Shock  concentra- 
tions of  up  to  10  mg/L  of  chlorine  are  applied  from  time  to 
time.  When  an  oxidant  intolerant  polyamide  type  membrane 
IS  used,  cholonnation  must  be  followed  with  dechlorination. 
One  of  the  dechlorination  agents,  sodium  bisulfite  is  also 
known  to  be  a  disinfectant.  Another  disinfection  option  is  the 
use  of  ultraviolet  disinfection  which  leaves  no  oxidant  resid- 
ual In  the  water. 

QUESTiONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  175. 

16.4A  How  are  tu'  idity  and  suspended  solids  re^noved 
from  feedwater  to  the  reverse  osmosis  system? 

16.4B  How  are  colloidal  particulates  removed  from  feed- 
water  to  the  reverse  osmosis  system? 

16.40  What  happens  to  the  product  water  as  an  acetate 
membrane  hydrolyzes? 

16.4D  How  Is  the  precipitation  of  calcium  sulfate  prevent- 
ed? 

16.4E  How  Is  biological  fouling  on  membranes  controlled? 


16.45  RO  Plant  Operation 

Following  proper  pretreatnnent,  the  water  to  be  demlneral- 
ized  Is  pressurized  by  high  pressiire  feed  pumps  and 
delivered  to  the  RO  pressur"  assel  membrane  asseml>lies. 
An  example  of  a  typical  RC  int  layout  is  given  in  Figure 
16.11.  The  membrane  assemblies  consist  of  a  series  of 
pressure  vessels  (usuaHy  fiberglass-reinforced  plastic)  ar- 
ranged ir  the  'Christmas  Tree  layout"  deperxling  on  the 
desired  recovery.  Typical  operating  pressure  for  brackish 
water  demineralizing  varies  from  400  to  500  '^si  (2760  to 
3450  kPa  or  28  to  35  kg/sq  cm).  A  control  valve  on  the 
influent  manifold  regulates  the  operating  pressure.  The 
volumes  of  feed  flow  and  of  product  water  are  also  moni- 
tored. The  demineralized  water  is  usuatty  called  permeate, 
and  the  reject,  brine.  The  recovery  rate  Is  controlled  by 
increasing  teed  flow  (increase  operating  pressure)  and  con- 
^*^ng  the  br\r\e  or  reject  with  a  preset  brine  control  valve. 

ERIC 


The  operator  must  properly  maintain  and  control  all  flows 
and  recovery  rates  to  avoid  pos*^ible  damage  to  the  mem- 
branes from  scaling. 

You  must  remember  that  the 

flow  vm/€6 

Should  they  be  accidentally  closed  during  operation,  100 
percent  recovery  will  result  in  almost  certain  damage  to  the 
membranes  due  to  precipitation  of  inorganic  salts  (CaSO^). 
Product  or  permeate  flow  is  not  regulated  and  varies  as 
feedwater  pressure  and  temperature  change  as  previously 
discussed. 

Most  RO  systems  are  designed  to  operate  automatically 
and  require  a  minimum  of  operator  attention.  However,  the 
continuous  monitoring  of  system  performance  is  an  impor- 
tant aspect  of  operation.  An  example  of  a  typical  operation 
log  for  monitoring  the  Orange  County  Water  District's  5 
MOD  (19  MLD)  RO  plant  is  given  in  Table  16.4. 

QUESTiONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  175. 

16.4F  How  IS  the  operating  pressure  on  a  reverse  osmosis 
unit  regulated? 

16.4G  The  deminerahzed  water  Is  usually  called  ,  the 

reject  

16.4H  How  does  the  product  or  permeate  flow  vary  or 
change? 

16.46  Typical  RO  Plant  Operations  Checklist 

1.  Check  cartridge  filters.  Properly  installed  filters  Insure 
additional  removal  of  suspended  solids  that  could  dam- 
age either  the  high  pressure  feed  pumps  or  foul  the 
membrane  elements.  Cartridge  filters  should  be  replaced 
whenever  head  loss  exceeds  manufacturer's  recommen- 
dations or  effluent  turbidity  exceeds  one  TU. 

2.  Start  up  and  check  scale  inhibitor  feeding  equipment  and 
adjust  feed  rate  to  desired  dose  (2  to  5  mg/L).  Most  RO 
systems  should  not  be  operated  without  the  addition  of  a 
scale  inhibitor  to  protect  memt^ranes  from  precipitation  of 
calcium  sulfate  or  other  Inorganics.  The  scale  inhltntor 
most  frequently  used  is  sodium  hexametaphosphate. 

3.  If  chlorine  is  used  to  prevent  btological  fouling,  start 
chlorine  feed  and  adjust  dose  to  produce  a  chlorine 
residual  of  t)etween  1  and  2  mg//.. 

4.  Start  up  and  adjust  acid  feed  system  to  correct  feedwater 
pH  to  a  level  between  5.0  and  6.0  to  protect  memt>rane$ 
from  possible  damage  due  to  hydrolysis.  Note,  feedwater 
shoukj  always  be  bypassed  unt»(  the  pH  is  properly 
adjusted. 

5.  Most  RO  systems  are  designed  with  automatic  controls 
and  various  shutdown  alarms.  These  alarms  prevent 
startup  or  running  of  the  unit  until  proper  operating 
conditions  are  reacf>ed.  After  satisfying  these  conditions, 
h»gh  pressure  feed  pumps  can  be  started  and  water 
delivered  to  the  RO  units.  A  control  valve  is  used  to 
reguiaie  feedwater  pressure.  Typical  operating  pres- 
s  jres  vary  from  350  to  500  psi  (2400  to  3400  kPa  or  25  to 
33  kg/sq  cm). 

17  Z 


SCALE 
INHIBITOR 
FEEDER 


CLEANING 
TANK 


CHLORINATOR 


ACID 
STORAGE 
TANK 


ACID 
TRANSFER 
PUMPS 


ACID  ACID 
DAY  INJECTION 
TANK  PUMPS 


ACID 
DILUTION 
PUMPS 


FLUSH 
TANK 


BLOWER 

DECARBONATOR 


00 


I 


3 

9 


PRODUCT 
WATER 


173 

Fig.  16.11  RO  flow  diagram 


17i 


ERIC 


Pf  etfCtUmoni 

Cdftndgj?  Filieis 

Pumf)  2  Disch 

CI 

//  *. 

Turb 

Temp 
op 

Feed  Cond 

A 

B 

C 

TIME 

Dsia 

PSIQ 

psiq 

psicT 

NTU 

jumhos/cm 

pH 

psig 

0400 

1200 

2000 

RO  Unit 

1 

ROUnil  2 

T  0 

I  a  1  Brine 

Total    P  f  o  <1  u  c  I 

TIME 

Feed 
PS>9 

Feed  Flow 
MGD 

Product 
Cond  lu) 

Feed 
P5jg 

*^ccd  Flow 
MGD 

Product 
Cond.  Cui 

Flow 

MGD 

pH 

Conductivity 
juumhos/cm 

KVVH 
Ton 

pH 

Conductivity 
>umhos/cm 

Flow 
MGD 

0400 

120. 

2000 

TIME 

ROUnil  1 

Section  lA-Product  EC 

Section  IB-Product  EC 

Section  iC-Product  EC 

Feed 

A  P 

Product 

gpm 

Brine 

MGD 

Feed 

Product 
qpm 

Brine 
MGD 

Feed 
psig 

A  P 

Prod-:: 

apm 

MGD 

ps«g 

1st 

2nd 

3rd 

1st 

2nd 

3rd 

1st 

2nd 

3rd 

0400 

1200 

2000 

S 

oo 
o> 

-5! 

1^ 

Sx 

So 

m  > 
3  z 

0)  o 
m  m 

OO 
0)  o 
Sc 

m  30 


RO  Unit  2 

Section  2A-Product  EC 

Section  2B-Product  EC 

Section  2C 

-Product  rr 

TIME 

Feed 

A  P 

Product 

Brirtc 

Feed 

Produrt 

Brine 

Feed 

P 

Product 

Bt  IMP 

1st 

2nd 

3rd 

gpm 

MGD 

ps«g 

1st 

2nd 

3rd 

MGD 

psiq 

1st 

2n(i 

3rd 

arm. 

mc;d 

0400 

1200 

2000 

17  u 


o 
(P 
3 

5' 
(p 

n' 
fii 

o 

3 


4  W 


160  Water  Treatment 


Shift 

Operator 

TABLE  16.4  (Continued)  DATA  SHEET  ORANGE  COUNTY 
WATER  DISTRICT  5.0  MGD  (19  MLD)  REVERSE  OSMOSIS 
SYSTEM 


Date 


24  Hour  Totalizer 

TIME 

Feed  Flow 
MGD 

Bypass  Flow 
MGD 

Total  Product 

MGD 

Total  Brine 
MGD 

(A)2400<'n 

SHMP 

ACID 

ELAPSED  TIME 

P0V7ER 

2400 ^^IJ 

lbs 

qal 

RO  #1 

RO  #2 

2400(11) 

2400^^) 

2400^^^ 

REMARKS: 


ERIC 


177 


Demineralization  161 


6.  AOjj^^t  feed  and  brine  flow  to  estGOlish  the  desired 
recovery  rate 

7.  Once  flow  has  be^n  established,  check  t*^  .ifferential 
pressure  (AP)  across  the  RO  unit  wh'ch  is  jy  indicat- 
ed by  a  meter  and  recorded.  The  impoi  nee  of  AP 
relates  to  cleaning.  When  the  elements  become  fouled, 
AP  usually  Increases,  thus  indicating  the  nee/  for  clean- 
ing. The  AP  should  not  exceed  70  to  100  psi  (483  to  690 
kPa  or  5  to  7  kg/sq  cm)  because  of  possible  damage  to 
the  RO  modules. 

8.  With  the  system  on-line,  monitor  the  performance.  Rely 
on  flow  measurements,  product  water  quality,  and  var- 
ious pressure  indications.  A  sample  of  a  typical  log  sheet 
is  shown  In  Table  16.4. 

16.47  Membrane  Cleaning 

Periodically  the  performance  of  the  RO  system  will  de- 
cline. This  is  usually  observed  when  either  the  product  water 
flow  rate  (flux)  decreases,  or  salt  removal  (rejection)  de- 
creases. Table  16.5  summarizes  common  causes  of  mem- 
brane damage  or  loss  of  performance.  Note  that  in  Cases  III 
and  IV  the  corrective  action  requires  c'-^aning  of  the  element. 
Provisions  for  the  periodic  cleaning  of  the  reverse  osmosis 
elements  are  usually  included  in  the  system  design.  I'his 
makes  it  possible  to  clean  impurites  off  the  membrane 
surface  and  restore  -..ormal  flow  rates  without  removing  the 
elements  from  the  pressure  vessels.  Element  cleaning 
should  be  performed  at  regular  intervals  to  assure  as  low  an 
operating  pressure  as  practical.  The  elements  should  be 
cleaned  when  the  pressure  required  to  maintain  the  rated 
capacity  has  either  been  increased  by  15  percent  (or  a  15 
percent  decrease  in  product  water  flow  has  occurred  at 
constant  pressure),  or  a  rise  of  15  percent  in  the  system 
differential  pressure  has  been  observed. 

Most  RO  systems  are  provided  with  in-place  cleaning 
systems.  This  includes  tanks,  pumps,  valves  an',  piping  for 
mixing  and  pumping  cleaning  solutions  through  the  mem- 
brane elements.  For  cleaning,  the  unit  is  shut  down  and 
cleaning  solutions  are  pumped  through  the  vessels  in  a 


manner  similar  to  feedwater  Typically,  cleaning  solutions 
are  passed  through  the  pressure  vessels  at  low  pressure 
and  at  flow  rates  where  the  AP  does  not  exceed  60  psi  (414 
kPa  or  4.2  kg/sq  cm)  to  avoid  damaging  the  elements.  The 
cleaning  solutions  are  returned  to  clean  tanks  at  the  end  of  a 
cleaning  cycle  which  usually  lasts  about  one  hour.  Different 
cleaning  solutions  are  available  for  use  depending  upon  the 
type  of  fouling.  Membranes  are  typically  cleaned  for  ap- 
proximately 45  minutes  after  which  the  cleaning  solution  is 
spent. 


To  remove  inorganic  preen  'tates,  use  an  acid  flush  of 
citnc  acid.  For  biological  or  organic  fouling,  various  solutions 
of  detergents,  sequesfants,  chelating  agents,  bactericides, 
and  enzymes  are  available.  Examples  include  sodium  tri- 
polyphosphate,  B13,  Triton  X-100,  and  EDTA. 

To  improve  the  long-term  performance  of  an  RO  system, 
the  membranes  should  be  flushed  with  flush  water  during 
periods  of  shutdown  to  remove  raw  feed  water  and  concen- 
trate. If  raw  water  is  allowed  to  remain  in  the  unit,  precipita- 
lion  may  occur.  Flushing  is  also  done  after  cleaning  to 
remove  the  cleaning  solution  prior  to  system  startup.  In 
some  cases,  where  the  system  is  shutdo.  n  for  long  periods 
of  time,  formaldehyde  may  be  added  to  the  flush  water  to 
inhibit  biOiogical  growth. 


TABLE  16.5   SUMMARY  OF  COMMON  CAUSES  OF  MEMBRA^'E  DAMAGE 
 Symptoms    Case   Restoration  Procedures 

Case  I   1 .  Lower  product  water  flow  rate    Membrane  compaction  ■  accelerated         None,  Requires  element  replacement 
2.  Higher  salt  rejection  by  operating  pressure  greater  than  when  product  water  flow  rate  reaches 

500  psi  (3450  kPa  or  35  kg/sq  cm).  an  unacceptable  level. 


Case  II  1 .  Higher  product  level 
flow  rate 
2.  Lower  salt  rejection 


Membrane  hydrolysis 

1.  pH  outside  operating  limits 

2.  Bacteria  degradation 
0.  Temperature  outside 

operating  limits. 

Membrane  fc  ling. 


Membrane  fouling. 


Injection  of  colloid  189  (size)  or 
element  replacement. 


Eleh<ent  clerning. 
Element  cleaning. 


Case  III  1.  Lowor  product  water 
flow  rate 
2.  Lower  salt  rejection 

Case  IV  1 .  Lower  product  water 
flow  rate 

2.  High  AP 

3.  High  operating  pressure 

*  Membrane  Cc^oaction.  Prr^uci  water  flow  rate  declines  with  operational  time  in  addition  to  fouling  of  the  membrane  surface  due  to 
other  factors.  v«ater  flow  rate  plotted  versus  time  on  log-log  paper  will  yield  a  straight  line  (flow  rate  decline). 


c 


178 


162  Water  Treatment 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  wit^^  those  on  page  175. 

16  4!   Why  is  chlonne  added  to  the  feedwater  to  a  rev-orse 
osmosis  un\V> 

16  4.'  Why  must  the  operator  chack  the  differential  pres- 
sure (AP)  across  the  unif? 

16  4K  When  should  the  reverse  osmosis  elements  be 
cleaned'? 


16.48  Safety 

16,480  Use  Proper  Procedures 

As  in  any  water  treatment  plant,  there  are  forces  and 
chemicals  used  in  a  reverse  osmosis  plant  which  must  be 
handled  properly  to  Insure  the  safety  and  protection  of 
perse  -el.  Safety  necJs  for  deminerallzatlon  plants  can  be 
divided  into  threo  general  groups  consisting  of  chemicals, 
electnccl,  and  hydraulics. 

16A81  Chemicals 

Operation  of  an  RO  plant  requires  the  use  of  a  wide  variety 
of  chemicals.  Whenever  you  must  handle  chemicals,  follow 
the  p'-oper  procedures  for  each  chemical.  Manufacturer's 
recommendations  for  use  of  each  chemical  must  be  ob- 
se  ved.  A  list  of  the  commonly  used  chemicals  requiring 
spe  iai  handling  found  in  an  RO  plant  operation  include: 

1.  Acid, 

2.  Chlorine, 

3.  Sodium  hexametaphosphate, 

4.  Formaldehyde, 

5.  Citric  acid,  and 

6.  Numerous  cleaning  agents. 

See  Chapter  20,  "Sa'aty,"  for  more  detailed  procedures  on 
the  safe  use  of  hazardous  chemicals. 


16.432  Hydraulic  Safety 

For  tht  reverse  osmos»s  proce;so  ,o  function  properly, 
hydraulic  pressure  in  excess  of  the  solution's  aveiage 
osmotic  pressure  (tt)  is  required.  Within  the  plant,  therefore, 
most  of  the  pipes,  tubmn,  vessels,  and  their  associated 
equipment,  along  with  the  substances  inside  these  items 
operate  under  varying  levels  of  hydraulic  pressure  (200  tu 
500  psi,  1380  to  3450  kPa,  or  14  to  35  kg/sq  cm).  Therefore, 
prior  to  iAA/V  repairs,  modifications,  or  work  of  any  kind,  NO 
MATTER  HOW  MINOR,  know  the  substances  contained, 
isolate  the  p'^ce  of  equipment  and  equalize  pressure  levels 
to  atmospheric  pressure. 

After  being  repaired,  any  piece  of  equipment  should  be 
purged  of  >ALL  foreign  substances  BLrOHE being  restarted. 
vVhen  bnnging  a  piece(s)  of  equipment  on-line,  increase  the 
hydraulic  pressures  slowly.  Keep  all  personnel  in  a  safe  area 
to  maximize  their  personal  safety. 

16  483  Electrical  Safety 

An  RO  plant  consists  a  series  of  electrically  powered 
pumps  and  mechanical  equipment.  Electric  shocks  due  to 
the  use  cf  electrical  equipment  occur  without  warning  and 
are  usually  serious.  The  average  individual  thinks  of  the 
hazards  of  electric  shock  in  terms  of  high  voltage  and  does 
not  always  realize  that  it  is  primarily  the  current  that  kills,  not 
the  voltage.  Consequently,  persons  who  work  around  low- 
voltage  equipment  do  not  always  have  the  same  healthy 
respect  for  current  as  they  do  for  high  voltage.  Whenever 
working  around  electrically  operated  equipment,  strictly  ob- 
serve all  applicable  rules  of  the  National  Electrical  Safety 
Code.^2 


QUESTIONS 

Wnte  your  ansv.'ers  m  k  Dtebook  and  then  compare  your 
answers  with  those  on  page  175. 

16.4L  List  the  three  general  groups  of  safety  needs  for  a 
demineralization  plant. 

16.4M  What  type  of  electrical  equipment  is  used  around 
reverse  osmosis  plants? 


^2  NATIONAL  ELECTRICAL  SAFETY  (  *  '^E.  Available  from  Institute  of  Electrical  and  Electronic  Engineers,  Inc.,  IEEE  Service  Csnter 
PO  Box  1331,  445  Hoes  Lane,  Pischu,  jy,  NJ  08855-1331. 


179 


Demineralization  163 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  16.  DEMINERAUZATiON 

(Lesson  2  of  3  Lessons) 


Write  the  answers  to  tiese  questions  in  your  notebook 
before  continuing  The  problem  numbering  continues  from 
Lesson  1 

9.  Why  does  water  to  be  demineralized  require  pretreat- 
ment? 

10.  What  problems  are  created  for  demineralization  pro- 
cesses by  the  oxidized  and  precipitated  forms  of  iron, 
manganese  and  silica? 

1 1 .  How  does  the  operator  of  a  reverse  osmosis  plant  avoid 


possible  damage  to  the  membrane  from  scaling'^ 

12.  What  will  happen  in  a  reverse  osmosis  plant  if  the  brine 
flow  valves  are  accidentally  closed  during  operation? 

1 3.  What  IS  the  purpose  of  cartridge  filters  and  when  should 
they  be  replaced? 

14.  How  can  the  operator  determine  if  the  performance  of 

ie  RO  system  is  declining'? 

15.  What  does  hydraulic  safety  consist  of  around  a  leverse 
osmosis  process? 


CHAPTER  16.  DEMINERALIZATION 

(Lesson  3  of  3  Lessons) 


16.5  ELECTRODIALYSIS 

Electrodiaiysis  (ED)  is  a  well  developed  process  with  a 
history  of  many  years  of  operation  on  brackish  well  water 
supplies.  A  650,000  GPD  (2.5  MLD)  ED  plant  manufactured 
by  Ionics,  Inc.,  Watertown,  Massachusetts,  began  operation 
on  well  water  at  Buckeye,  Arizona  in  September  1972  and 
has  been  in  continuous  operation  to  date.  ED  plants  are  also 
in  operation  demineralizing  municipal  water  supplies  in 
Siesta  Key,  Florida;  Sanibel  Island,  Florida;  Sorrento 
Shores,  F(orida  and  at  the  Foss  Reservoir  in  Oklahoma.  The 
process  is  also  used  for  industrial  water  demineralizing. 

Typical  removals  of  inorganic  salts  from  brackish  water  by 
ED  range  from  25  to  40  percent  of  dissolved  solids  per  stage 
of  treatm3nt.  Higher  removals  require  treatment  by  multiple 
stages  in  series.  Less  than  20  percent  of  the  organics 
rf  aining  in  activated  carbon  treated  secern  ^ary  effluent  are 
<oved  by  electrodiaiysis.  Energy  required  for  ED  is  about 
V.2  to  0.4  kilowatt-hours  per  1000  gallons  (kWh/1000  gal)  for 


each  100  ng/L  dissolved  solids  removed,  plus  2  to  3  kWh/ 
1000  gal  for  pumping  feedwater  and  brine.  Advantages  of 
the  ED  process  include:  (1)  well  developed  technology, 
including  equipment  and  membranes;  (2)  efficient  removal  of 
most  incqanic  constituents;  and  (3)  waste  brine  contains 
only  saltw  'emoved  plus  a  small  amount  of  acid  used  for  pH 
control  in  some  ED  applications. 

in  the  ED  process  brackish  water  flows  between  alternate 
ing  cation-permeable  and  anion-penneable  membranes  r3 
illustrated  in  Figure  16.12.  A  direct  electric  current  provides 
the  motive  force  cause  ions  to  migrate  through  the 
membranes.  Many  alternating  cation  and  anion  membranes, 
each  separated  bv  a  plastic  spacer,  are  a5;sembled  into 
membrane  stacks.  spacers  (about  0.04  inches  or  one 
mm  thick)  contain  the  water  streams  within  the  stack  and 
direct  the  flow  of  water  through  a  tortuous  path  across  the 
exposed  faces  of  the  membranes.  Membrane  thicknesses 
generally  range  between  0.005  and  0.025  inches  or  0.125  to 
0.625  mm. 


ISO 


164  Water  Treatment 


C  CATION-PERMEABLE  MEMB.^ANE 
A     ANION-PERMEABLE  MEMBRANE 


FEEDWATER  IN 
 ^ 


CATHODE 


No 


CI- 


'71 


CI- 


7 


CON  NTRATED 
BRINE  WATER 


r 


Nq 


CI- 


V 


No- 


el- 


7 


TO  NEGATIVE  n  |i|  C  HI  A  HI  C  |i|  A  HI  C  11 

POLE  OF     

ELECTRICAL 
SUPPLY 


Na  + 


Cl~ 


Li,      TO  POSITIVE 
POLE  OF 
ELECTRICAL 
SUPPLY 


+ 

ANODE 


FRESH   PRODUCT  WATER 


Fig.  16.12  Electrodialysis  aeminerahzation  process 

(From  STANDARD  OPERATION  INSTRUCTION  PLAN  FOR  ELECTRODIALYSIS.  prepared  by  IONICS.  Inc.) 


Physically,  the  equipment  takes  the  form  of  a  plate- and- 
frame  assembly  similar  to  ihat  of  a  filter  press.  The  spacers 
determine  the  thickne^^s  of  the  solution  compartments  and 
also  define  the  flow  paths  of  the  water  over  the  membrane 
surface.  Several  hundred  membranes  and  their  separating 
spacers  are  usually  assembled  between  a  single  set  of 
electrodes  to  form  a  membrane  stack.  End  plates  and  tie 
rods  complete  the  assembly.  When  a  membrane  is  placed 
between  two  salt  solutions  and  subjected  to  the  passage  of 
a  direct  electric  current,  most  of  the  current  wiP  be  carried 
through  the  membrane  by  ions,  hence  the  membrane  is  said 
to  be  ion  selective.  Typical  selectivities  arc  greater  than  90 
percent.  When  the  passage  of  current  is  continued  for  a 
sufficient  length  of  time,  the  solution  on  the  side  of  the 
membrane  that  is  furnishing  the  Ions  becomes  partially 
desalted,  and  the  solution  adjacent  to  the  other  side  of  the 
membrane  becomes  more  concentrated.  These  desalting 
and  concentrating  phenomena  occur  In  thin  layers  of  solu- 
tion immediately  adjacent  fc  the  membrane  resulting  in  the 
desalting  of  the  bulk  of  tne  solution. 

Passage  of  water  between  the  membranes  of  a  single 
stack,  or  stage,  usually  requires  10  to  20  seconds,  during 
which  time  the  entering  minerals  in  the  feedwater  are 
removed.  The  actual  percentage  removal  that  Is  achieved 
varies  with  water  temperatun^  type  and  amounts  of  ic  is 
present,  flow  rate  of  the  watei  and  stack  design.  Typical 
removals  per  stage  range  from  25  to  40  percent  and 
systems  use  one  to  six  stages.  An  ED  system  will  operate  at 
temoeratures  up  to  1 10  degrees  Fahrenheit  (110**F  or  ASX) 

ERIC 


and  the  removal  efficiency  increases  with  increasing  tem- 
perature. Ion-selective  membranes  in  commercial  electro- 
dialysis  equipment  are  commonly  guaranteed  for  as  long  as 
5  years  and  experience  has  demonstrated  an  effective  life  of 
over  10  years. 

The  most  commonly  encountered  problem  in  ED  oper- 
ation is  scaling  (or  fouling)  of  the  membranes  by  both 
organic  and  Inorganic  materials.  Alkaline  scales  are  trouble- 
some in  the  concentrating  compartments  when  the  diffusion 
of  ions  to  the  surface  of  the  anion  membrane  in  the  diluting 
cell  is  insufficient  to  carry  the  current.  Water  Is  then  electro- 
lyzed  and  hydroxide  Ions  pass  through  the  membrane  and 
raise  the  pH  in  the  cell.  This  Increase  is  often  sufficient  to 
caune  precipitation  ^1  materials  such  as  magnesium  hydrox- 
ide or  calcium  carL  nate.  The  accumulation  of  particulate 
matter  increases  the  electrical  resistance  of  the  membrane; 
this  may  damage  or  destroy  the  membranes.  This  condition 
can  be  offset  by  feeding  acid  to  the  concentrate  water 
stream  to  maintain  a  negative  Langeller  Index  to  assure 
scale-free  operation. 

Ionics,  Inc.,  has  developed  a  type  of  ED  unit  which  does 
not  require  the  addition  of  acid  or  other  chemicals  for  scale 
control.  This  system  reverses  the  DC  current  direction  and 
the  flow  path  of  the  dilution  and  concentrating  streams  every 
15  minutes.  The  electrodes  reverse  by  switching  the  polarity 
of  the  cathodes  and  anodes.  The  stream  flo»  paths  also 
exchange  their  source  every  15  minutes.  Motor-operated 
valves  controlled  by  timers  switch  the  streams  so  that  the 


181 


Demin  ralization  165 


flow  path  that  was  previously  the  diluting  stres-^  becomes 
the  concentrating  stream  and  the  flow  path  tnat  was  pre- 
viously the  concentrating  stream  becomes  the  diluting 
stream.  This  reversing  polarity  system  is  commonly  referred 
to  as  electrodiaiysis  polarity  reversal  (EDR). 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  175. 

16.5A  What  are  the  typical  removals  of  inorganic  salts  from 
brackish  water  by  eiectrodialysis  (ED)  per  stage  of 
treatment? 

16.5B  What  is  a  membrane  stack  in  an  electrodiaiysis  unif? 

16.5C  V'hat  is  the  most  commonly  encountered  problem  in 
ED  operation? 

16.6   PRINCIPLES  OF  ELECTRODIALYSIS 

16.60  Anions  and  Cations  in  Water 

When  most  common  salts,  minerals,  acids,  and  alkalis  are 
dissolved  in  water,  each  molecule  splits  into  two  oppositely 
charged  particles  called  Ions.*'  All  positively  charged  ions 
are  known  as  "cations"  and  all  negatively  charged  ions,  as 
"anions."  For  instance,  when  common  table  salt  (sodium 
chloride  or  NaCI)  is  dissolved  in  water,  it  separates  into 
positive  sodium  ions  (Na"*^)  and  negative  chloride  ions  (CI"). 
The  following  ions  are  in  sea  water  or  brackish  water  in 
appreciable  quantities. 


16.61   Effect  of  Direct  Current  (D.C.)  Potential  on  Ions 


If  a  D.C.  potential  is  applied  across  a  solution  of  salt  in 
water  by  means  of  insertion  of  two  electrodes  in  the  solution, 
the  cations  will  move  towards  a  negative  electrode,  which  is 
known  as  the  "cathode,"  and  the  anions  will  move  towards 
the  positive  electrode,  which  is  known  as  the  "anode."  In 
Figure  16.13  (A)  we  have  a  solution  of  sodium  chloride  in 
water.  The  ca*.ons  (Na*)  and  anions  (CI")  are  moving  about 
at  random.  In  Figure  16.13  (B)  a  D.C.  potential  has  been 
introduced  in  the  solution  and  the  anions  move  toward  the 
positive  electrode  and  the  cations  move  toward  the  negative 
electrode. 

16.62  Anion  and  Cation  Membranes  and  Three-Cell  Unit 

Advantage  could  be  taken  of  this  movement  of  ions  if 
proper  barriers  were  available  to  isolate  the  purified  zone  in 
Figure  16.3  (B)  so  as  to  prevent  remixing.  There  are  two 
types  of  membranes  which  can  be  used  as  such  barriers: 

1 .  Cation  Membranes  —  Permit  only  the  passage  of  cations 


(positively  ci.arged  ions);  and 

2.  Anion  Membranes  —  Permit  only  the  passage  of  anions 
(negatively  charged  ions). 

Introduction  of  a  cation  membrane  and  anion  membrane 
into  a  salt  solution  to  form  three  water-tight  compartments 
(Figure  1 6.1 3  (C))  followed  by  a  direct  electric  current  into  the 
water  (Figure  16.13  (D))  will  result  in  the  demineralization  of 
the  central  compartment. 

In  the  three-cell  unit  shown  in  Figure  16.13  (C)  and  (D).  "1" 
IS  the  anode  (positive  electrode),  "2"  is  the  anion  membrane, 
•*3"  IS  ih3  cation  membrane,  and  "4"  is  the  cathode  (negative 
electrode).  In  Figure  16.13  (C)  there  is  no  electric  flow  so  the 
ions  move  at  random  'n  the'r  respective  compartments.  In 
Figure  16.13  (^ ,  the  ...Production  of  a  D.C.  potential  gives 
these  ions  direction:  the  cations  (Na^)  move  toward  the 
cathode  and  the  anions  (CI")  toward  the  anode.  The  follow- 
ing occurs: 

1.  Na*  from  compartment  A  cannot  pass  through  anion 
membrane  (2)  into  compartment  B, 

2.  Cr  from  compartment  A  reacts  at  the  anode  (1)  to  give  off 
chlorine  gas, 

3.  Na"^  from  compartment  B  passes  through  cation  mem- 
brane (3)  into  compartment  C, 

4.  CI"  from  compartment  B  passes  through  anion  mem- 
brane (2)  into  compartment  A, 

5.  Na""  from  compartment  C  reacts  at  the  cathode  to  give  off 
hydrogen  gas  and  hydroxyl  ions  (OH"),  and 

6.  CI"  from  compartment  C  cannot  pass  through  cation 
membrane  (3)  into  compartment  B. 

This  descnption  indicates  how  the  overall  effect  has 
produced  a  demineralization  of  the  central  compartment. 

1 6.63  Multi-compartment  Unit 

Figure  16.14  presents  a  multi-compartment  unit  similar  in 
principle  to  a  stack.  Letter  "A"  designates  the  anion  mem- 
branes; letter  "C"  the  cation  membranes;  the  sign  the 
anode;  the "-"  sign  the  cathode.  A  salt  solution  of  Na"^  and 
CI"ions  flows  between  the  membrane.  On  application  of  the 
D.C.  potential,  the  overall  effect  will  be  as  shown,  a  move- 
ment of  ions  from  the  compartments  bounded  by  an  anion 
membrane  on  the  left  and  a  cation  membrane  on  the  right 
into  the  adjacent  compartments.  The  compartments  losing 
salt  are  labeled  "dilute"  and  those  receiving  the  transferred 
salt,  "brine."  Two  electrode  compartments  are  also  found  in 
the  drawing.  Each  is  bordered  by  a  cation  membrane  and  the 
electrode.  At  the  anode,  a  reaction  takes  place  evolving 
chlorine  and  oxygen  gases;  at  the  cathode,  hydrogen  gas  is 
produced  and  hydroxyl  ions  (OH")  are  left  in  the  solution. 
Hydroxyl  ions  are  alkaline. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  175. 

16.6A  What  happens  if  a  D.C.  potential  is  applied  across  a 
solution  of  salt  in  water  by  means  of  insertion  of  two 
electrodas  in  the  solution? 

16.6B  What  type  ot  ions  can  pass  through  cation  mem- 
bra.ies? 

16.6C  In  a  multi-compartment  ED  unit,  the  compaiiments 

losing  salt  are  labeled  and  those  receiving 

the  transferred  salt,  


182 


166  Water  Treatment 


M  + 

Na 

CI 

Na"*" 

Na"*" 

cr 

i 


© 


cr 

CI' 

cr 


0 


^  Q 


a 


Na 


B 


-O  O- 


2  3  4 

C  (NO  CURRENT  FLOW) 


■  © 

GAS 

^GAS 

Na^ 

-  r\ 

cr 

^Na-^ 

cr^ 

r 

A 

2  3  4 

D  (CURRENT  FLOW) 


ERIC 


F/p.  75  73  Influence  of  current  flow 

(From  STANDARD  OPERATION  INSTRUCTION  PLAN  FOR  ELECiPODIALYSiS.  prepared  by  IONICS.  Inc ) 


183 


NoCi  SOLUTION 


GAS. 


PI 

/ 

/ 
/ 
/ 

/ 
/ 

/ 
/ 
/ 
/ 
/ 
/ 
/ 
/ 
/ 
/ 
/ 
/ 
/ 

/. 


CI" 


\ 


T7^ 


\ 


ELECfROOe 


\rrrF7777 


OILUTC 


\ 


\ 


CI" 


/ 


\ 


\ 


cr 

/ 


DILUTE 


ZZZZ22Z^ZZZ 


A 
I 


cr 


\ 


W4 

/ 


C.ullTE 


No' 


\ 


?  c 


No' 

\ 


cr 


/ 


7777 


DILUTE 


77-r> 


(OH) 


cr 


/ 
\ 


777" 


DILUTE 


GAS 


PI 

/ 

/ 
/ 
/ 

/ 
/ 
/ 
/ 
/ 

/ 
/ 
/ 
/ 
/ 
/ 

/ 


/ 
/ 
/ 

/ 
/ 


BHINE 


BRINE 


BRINE 


BRINE 


BRINE 


ELECTRODE 


F\g.  16,14  Multi-compartment  ED  stack 

(From  STANDARD  INSTRUCTION  PLAN  FOR  BLECTRODIALYSIS,  prtp«r«d  by  IONICS.  Inc) 


185 


168  Water  Treatment 


16.7  PARTS  OF  AN  ELECTRODIALYSIS  UNIT 

16.70  Flow  Diagram 

The  basic  electrodialysis  unit  consists  of: 

1.  Pretreatment  equipment, 

2.  Pumping  equipment  (feed,  brine  and  recirculation) 

3.  D.C.  power  supply. 

4.  Membrane  and  electrodes,  and 

5.  in-place  cleaning  system. 

Figure  16.15  shov;s  a  typical  flow  diagram  and  Figure 
16.16  a  photo  of  an  electrodialysis  unit. 

16.71  Pretreatment 

A  certain  degree  of  pretreatment  of  the  feedwater  supply 
is  necessary  in  order  to  prepare  it  for  demlneralization  In  the 
stacks.  Pretreatment  depends  on  the  specific  water  being 
treated,  but  it  usually  includes  the  removal  of  suspended  or 
dissolved  solids  which  could  adversely  affect  the  surface  of 
the  membranes  or  mechanically  block  the  narrow  passage- 
ways in  the  individual  cells.  Cartridge  filters  are  used  as  a 
particle  safeguard  before  the  ED  unit.  Before  development 
of  the  electrodialysis  polariiy  reversal  (EDR)  unit,  acid  addi- 
tion to  prevent  carbonate  scaling  was  always  practiced.  With 
the  electrodialysis  reversal  process,  the  requirement  for  acid 
addition  is  reduced  or  eliminated.  Removal  of  specific  mate- 
rials such  as  iron.  n.  ,ganese,  or  chlorine  residual  if  re- 
quired is  included  in  pretreatment. 

16.72  Pumping  Equipment  and  Piping 

In  the  electrodialysis  process  the  water  pump(s)  is  used 
only  for  circulation  of  the  water  through  the  stack.  The  herd 
loss  for  this  circulation  varies  with  the  construction  of  the 
stscks,  number  of  stages,  stacks,  and  piping,  but  generally  a 
pumping  pressure  of  only  about  50  to  75  psi  (345  to  517  kPa 
or  2.5  to  5.3  kg/sq  cm)  is  needed. 

Since  only  low  operating  pressures  compared  to  RO  are 
required.  ED  systems  are  constructed  with  common  materi- 
als found  in  most  water  treatment  applications.  This  has 
allowe*^  the  use  of  a  great  deal  of  standard  plastic  pipe  and 
fittings.  The  use  of  plastic  pipe  produces  benefits  regarding 
lower  cost  (compared  to  stainless  steel),  high  resistance  to 
corrosion  in  a  *-.aline  environment,  and  ease  of  construction. 

16.73  D.C.  f  ower  Supply 

The  rectifier  provides  the  D.C.  power  to  the  membrane 
stack  assembly.  The  input  (alternating  current,  A.C.)  is 
converted  by  the  rectifier  to  direct  current  which  is  applied  to 
the  electrodes  on  each  side  of  the  membrane  stack  to 
remove  the  ions  from  the  feed  stream.  This  equipment  also 
includes  a  control  module  for  periodic  reversal  of  the  current 
every  15  to  30  minutes  on  all  new  electrodialysis  polarity 
reversal  (EDR)  models. 


16.74  Membrane  Stack 

The  menr  orane  "stack"  is  so  called  because  it  is  composed 
of  a  large  number  of  stacked  pieces,  like  a  deck  of  cards. 
Half  of  these  pieces  are  spacers  and  half  are  membranes 
which  alternate  from  the  bottom  to  the  top  of  the  stack.  In 
other  words,  if  one  examines  any  portion  of  the  stack,  you 
will  find  a  membrane  above  and  below  every  spacer  (except 
at  the  electrodes)  and  a  spacer  above  and  below  every 
membrane.  Two  membranes  or  two  spacers  should  never 
occur  together. 

Each  membrane  stack  constitutes  one  stage  of  demlner- 
alization and  is  a  separate  hydrauli'*  and  electrical  stage. 
The  total  number  of  stacks  In  the  unit  will  be  arranged  in 
either  one  line  or  two  lines  running  in  parallel  (each  with  an 
equal  number  of  stacks).  Since  all  the  stacks  In  a  line  are 
connected  in  a  series,  the  number  of  stacks  per  line  will 
equal  the  number  of  stages  of  demineralization. 

The  membranes  and  spacers  in  the  main  section  of  the 
stack  make  up  the  number  of  cell  pairs  noted  In  the  stack 
specifications.  A  cell  pair  consists  of  one  anion  membrane, 
one  cation  membrane  and  two  Inter-membrane  spacers  and 
is  the  basic  deminerallzing  element.  The  metal  electrodes 
located  at  the  ends  of  the  stack  apply  the  D.C.  electrical 
power  required  for  demlneralization. 

16.75  Chemical  Flush  System 

ED  units  are  equipped  with  a  Clean-ln-Place  (CIP)  flush 
system  to  allow  periodic  flushing  of  the  membrane  stacks 
and  associated  piping  with  acid  solutions  down  to  pH  1  or 
with  brine  solutions  up  to  10  percent  sodium  chloride. 

The  two  chemical  solutions  which  are  used  most  often  for 
stack  cleaning  are  a  five  peraent  solution  of  hydrochloric 
acid  (for  removal  of  scale  and  normal  cleaning),  and  a  five 
percent  salt  solution  which  has  caustic  soda  added  to  adjust 
the  pH  to  between  12  and  13  (for  imoval  of  organic  fouling 
or  slime). 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  175. 

16.7A  What  must  be  removed  by  pretreatment  of  the  feed- 
water  supply  to  the  electrodialysis  unit? 

16.7B  What  Is  the  purpose  of  the  rectifier  in  an  electrodialy- 
sis unit? 

16.8   ROUTINE  OPERATING  PROCEDURES 

16.80  Desi0i;  Specifications  lor  Feedwater 

The  electrodialysis  desalting  unit  will  produce  demlneral- 
Ized  water  at  a  rate  dependent  on  water  temperature  and 
mineral  composition  of  feedwater.  The  quality  of  the  feed- 
water,  and  its  ionic  composition  is  extremely  important  and 
the  design  of  the  ED  unit  Is  based  on  these  conditions. 


CLEANING  TANK 


CLEANING  PUMP 


RAW  FEEDWATER 

1 1 


CARTRIDGE 
FILTER 


SPECIAL 
PRETREATMENT 
(IF  REQUIRED) 


LOW- 
PRESSURE 
CIRCULATION 
PUMP 


MEMBRANE 
STACK 

 1 


PRODUCT 
WATER 


AC  POWER 
SOURCE 


>=-- — 4 

DC  POWER 

SUPPLY 

(RECTIFIER) 

BRINE 
RECIRCULATION 
PUMP 


CONCENTRATE 
DISCHARGE 
TO 
WASTE 


Fig.  16. 15  Typical  flow  diagram 


o  187 

ERIC 


188 


I 
I 

N 
O 


CO 


HYDRAULIC 
CONTROL  PANELS 


ELECTRICAL 
PANEL 


MEMBRANE 
STACKS 


PRETREATMENT 
(FEEDWATER  FILTERS) 


ERLC 


CIRCULATION 
PUMP 


DC  POWER 

SUPPLY 
(RECTIFIER) 


ELECTRODES 


F/flf.     16  Basic  parts  of  an  electrodialysis  unit 

(Courtesy  of  IONICS  tNCORPORATEO) 


18 


r  ^ 


Deminerdlization  171 


ERIC 

few- 


The  ions  most  often  encountered  in  feedwater  are: 
Cations  Anions 

1.  Calcium  1.  Bicarbonate 

2.  Iron  2.  Chloride 

3.  Magnesium  3.  Sulfate 

4.  Silica 

5.  Sodium 

An  excessive  concentration  of  any  of  these  coristituents 
could  lead  to  chemical  fouling  due  to  scaling,  iron  in  the 
feedwater  will  cause  certain  process  problems;  obove  0.1 
mg/L  certain  precautions  have  to  be  taken.  One  of  the 
effects  of  excess  iron  in  feedwater  is  the  deposit  of  an 
orange  film  onto  the  membrane  surface  which  increases  the 
electrical  resistance  of  th'?  membrane  stack.  Concentrations 
of  iron  in  excess  of  j.3  mg/L  should  be  removed  by 
pretreatment. 

There  are  other  important  considerations  regarding  feed- 
water  quality.  These  include  pH,  biological,  and  bacteriolog- 
ical quality  of  the  feed.  To  prevent  biological  fouling  of  the 
cation  and  anion  membranes,  the  feedwater  should  be  free 
of  bacteria.  Proper  control  of  feedwater  pH  is  also  important, 
particularly  in  terms  of  corrosion  control  in  piping  and 
plumbing  equipment.  Because  chlorine  attacks  the  ED  mem- 
brane, the  feedwater  cannot  contain  any  chlorine  residual. 
If  prechlorination  is  practiced,  the  feedwater  must  be  de- 
chlorinated  before  entering  the  ED  unit.  Generally  the  unit 
should  A/or  be  operated  when  the  feedwater  contains  any 
of  the  following: 

1.  Chlorine  residual  of  any  concentration, 

2.  Hydrogen  sulfide  of  any  concentration, 

3.  Calgon  or  other  hexametaphosphates  in  excess  of  10 
mg/L, 

4.  Manganese  in  excess  of  0.1  mg/L,  and 

5.  Iron  in  excess  of  0.3  mg/L. 

16.81   Detailed  Operating  Procedures 

Detailed  operating  procedures  vary  from  one  system  to 
the  next.  Most  ED  or  EDR  units  come  designed  with  fully 
automatic  control  systems.  A  typical  operating  log  used  to 
monitor  an  ED  system  is  given  in  Table  16.6. 

The  detailed  specifications  for  any  plant  will  give  the 
proper  setting  for  the  various  controls  on  the  unit.  These 
control  settings  should  be  checked  and  recoroed  at  least 
once  every  24  hours  using  the  sample  log  sheet  given  in 
Table  16.6.  Any  action  needed  to  keep  the  plant  running 
according  to  the  specifications  should  be  taken  immediately. 

In  addition  to  checking  the  specifications,  the  routine 
maintenance  schedule  outlined  below  should  be  followed 
closely  in  order  to  reduce  the  risk  of  lengthy  and  expensive 
down  times.  Any  process  problems  discovered  must  be 
acted  upon  immediately. 

Daily 

1 .  Fill  out  log  sheet, 

2.  Verify  that  electrodes  are  bumping  and  flowing  properly, 

3.  Inspect  stacks  for  excess  external  leakage  (greater  than 
10  gallons  per  hour  or  38  liters  per  hour  per  stack),  and 


4.  Check  the  pressure  drop  across  the  cartridge  filter  and 
change  the  cartridges  whenever  the  pressure  drop 
reaches  10  psi  (69  kPa  or  0.7  kg/sq  cm). 

Weekly 

1 .  Voltage  prooe  the  membrane  stacks, 

2.  Check  the  oil  level  on  pumps  fitted  with  automatic  oilers, 

3.  Inspect  all  piping  and  skid  components  for  leaks,  and 

4.  Twice  per  week,  measure  all  electrode  waste  flows. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  175. 

16.8A  List  the  ions  most  often  encountered  in  the  feedwater 
to  an  electrodialysis  unit. 

16.8B  What  items  must  be  considered  to  prevent  biological 
fouling  of  the  cation  and  anion  membranes? 

16.8C  Generally  the  electrodialysis  unit  should  NOT  be 
operated  when  the  feed  water  contains  (list  the 
appropriate  water  quality  constituents). 

1 6.8D  List  the  recommended  daily  activities  for  the  operator 
of  an  electrodialysis  unit. 


16.9  SAFETY  PRECAUTIONS 

1.  Grounding.  The  entire  unit,  including  the  stacks,  must 
be  connected  to  an  electrical  ground  of  each  potential. 
AT  THE  TIME  OF  INSTALLATION  IT  IS  NECESSARY 
TO  GROUND  THE  SKID  OR  THE  CONTROL  PANEL 
CABINET,  EITHER  BY  A  METAL  CONDUIT  OR  A  SEPA- 
RATE GROUNDING  WIRE. 

Each  time  the  unit  is  moved  or  dismantled,  check  the 
ground  connections  before  turning  on  the  power.  The 
skid,  power  supply  cabinet,  and  stack(s)  must  always  be 
firmly  connected  to  the  building  ground  cr  other  suitable 
ground. 

2.  Check  the  ELECTRODE  TAB  connecting  bolts  and  be 
sure  these  are  tight  and  there  is  no  corrosion.  Loos<* 
connections  at  these  points  will  cause  overheating 
which  could  result  in  serious  damage  to  the  membrane 
stack. 

3.  Do  not  touch  wet  stack  sides  or  electrode  tabs  when  the 
D.C.  power  is  on. 

4.  Always  wear  rubber  gloves  when  voltage  probing  the 
membrane  stack. 

5.  When  washing  down  the  area,  never  direct  a  hose  on 
the  membrane  stack  wnen  the  D.C.  power  is  on. 

6.  Never  operate  a  dry  centrifugal  pump,  even  when 
checking  rotation. 

7.  Never  apply  D.C.  voltage  to  the  membrane  stack  with- 
out water  flowing  through  the  stack. 

8.  Expect  the  D.C.  amperage  to  DROP  when  the  feed 
water  temperature  DROPS,  Never  increase  the  D.C. 
stack  voltage  as  the  water  temperature  drops  in  an 
attempt  to  raise  currents  to  those  recorded  at  the  higher 
temperatures  unless  you  have  received  specific  instruc- 
tions to  do  so  from  the  manufacturer. 


190 


172  Water  Treatment 


TABLE  16.6   TYPICAL  OPERATING  LOG  SHEET  FOR  ED  UNIT 


Date 

Polarity 



Feed  Temp  (®F) 

Feed  TDS  (mg/L) 

Product  TDS  (malL) 

Product  Conductivity 

Dilute  Flowrate  (GPM) 

Brine  Make-up  (GPM) 

PRESSURES 

Stack  Inlet 

Stack  Outlet 

Differential  In 

Differential  Out 

Before  Filter 

After  Filter 

Electrode  Inlet 

Stage  1  Volts 

Line  1 

Line  2 

Stage  1  Amps 

Line  1 

Line  ^ 

Stage  2  Volts 

Line  1 

Line  2 

Stage  2  Amps 

Line  1 

Line  2 

Stage  3  Volts 

Line  1 

Line  2 

Stage  2  Amps 

Line  1 

Line  2 

Stage  4  Volts 

Line  1 

Line  2 

Stage  4  Amps 

Line  1 

Line  2 

Stages  Volts 

Line  1 

Line  2 

Stage  5  Amps 

Line  1 

Line  2 

Stage  6  Volts 

Line  1 

Line  2 

Stage  6  Amps 

Line  1 

Line  2 

ERJC  19.1 


Demineralization  173 


9.  Expect  the  D.C.  amperage  to  RISE  when  the  feedwater 
temperature  RISES.  As  this  happens,  the  D.C.  stack 
voltages  must  be  lowered  until  the  D.C.  amperage 
retums  to  the  normal  setting.  This  conserves  power  and 
prevents  damage  to  the  stack. 

10.  Never  allow  oil,  organic  solutions,  solvents,  detergents, 
wastewater,  chlorine,  nitric  acid,  strong  bleach  or  other 
oxidizing  agents  to  come  in  contact  with  the  membranes 
and  spacers  unless  directed  to  do  so  by  the  manufactur- 
er. Membranes  can  be  <^amaged  by  a  feedwater  con- 
taining even  0.1  rrig/L  free  chlorine. 

11.  Always  keep  the  membranes  wet.  Store  in  the  mem- 
brane tube  supplied  or  in  the  original  plastic  bags 
provided  the  seals  are  not  broken. 

12.  Do  not  smoke  or  use  exposed  flames  or  sparks  in  the 
gas  separator  tank  area  due  to  the  presence  of  poten- 
tially explosive  gases. 

13.  Do  not  service  the  gas  separator  tank  when  the  unit  is  in 
operation.  Especially  avoid  the  vent  lines  where  toxic 
and  explosive  gases  can  be  present.  If  it  is  necessary  to 
service  the  tank,  operate  the  unit  for  30  minutes  without 
D.C.  pov;er,  then  wait  an  additional  hour  before  begin- 
ning work  or  ventilate  with  fans  to  ensure  complete 
dispersion  of  dangerous  gases. 

14.  If  it  is  necessary  to  troubleshoot  any  of  tJie  electric 
panels,  be  extremely  careful  of  the  live  panel  voltages. 
This  maintenance  should  be  done  only  by  someone 
familiar  with  the  circuits  and  wiring.  The  unit  should 
never  be  operated  with  the  panel  doors  open,  except  for 
maintenance  purposes,  and  only  by  experienced  per- 
sonnel. 

1 5.  Should  shorting  occur  from  a  metal  end  plate  across  the 
plastic  end  block  to  the  electrode,  IMMEDIATELY  turn 
off  the  rectifier.  Try  to  eliminate  the  cause  of  the 
shorting  by  wiping  excess  moisture  off  the  block.  Also 
be  sure  to  completely  remove  the  black  carbon  that  has 
formed  at  the  point  of  shorting.  If  this  is  not  effectively 
done,  the  shorting  will  recur  when  the  rectifier  is  turned 
back  on. 

16.  Feedwater  containing  Calgon  or  other  hexametaphos- 
phates  will  cause  high  membrane  stack  resistance. 
Avoid  operation  when  these  are  present. 

17.  Red  warning  lamps  are  mounted  on  the  wire  way  for  the 
stack  power  connections.  The  lamps  are  lit  when  the 
D.C.  power  is  applied  to  the  stacks. 


1 8.  When  the  plant  is  on  automatic,  the  plant  is  controlled  by 
the  product  water  tank's  level  switch.  Therefore,  when 
working  on  the  equipment,  the  plant  should  be  switched 
to  manual  operation  and  locked  out,  thus  avoiding  the 
possibility  of  an  unexpected  startup. 

19.  Use  of  the  "STOP"  switch  or  "STOP/START"  switch 
activates  an  automatic  flushing  cycle  and  therefore 
does  NOT  immediately  stop  operation  of  all  compo- 
nents of  the  unit.  If  the  operation  of  the  entire  unit  must 
be  stopped  immediately,  the  MAIN  BREAKER  should  be 
switched  off. 


Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  176. 

16  9A  What  problems  can  be  created  by  loose  connections 
at  the  electrode  tab  connecting  bolts'^ 

16.9B  What  happens  to  the  D.C.  amperage  when  the  feed 
water  temperature  drops? 

16  9C  How  can  shorting  be  prevented  from  the  metal  end 
plate  across  the  plastic  end  block  to  the  electrode? 

16.9D  How  can  the  operation  of  the  entire  electrodialysis 
unit  be  stopped  immediately? 

16.10  ARITHMETIC  ASSIGNMENT 

Turn  to  the  Appendix  at  the  back  of  this  manual.  Read  and 
work  the  problems  in  Section  A.34,  "Demineralization."  You 
should  be  able  to  get  the  same  answers  on  your  pocket 
calculator. 

16.11  ADDITIONAL  READING 

1 .  TEXAS  MANUAL  Chapter  1 1 ,  "Special  Water  Treatment 
(Desalting)." 


19,? 


174  Water  Treatment 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  16.  DEMir4ERALIZATI0N 

(Lesson  3  of  3  Lessons) 


Write  the  answers  to  these  questions  in  your  notebook 
before  continuing  with  the  Objective  Test  on  page  176.  The 
problem  numbering  continues  from  Lesson  2. 

16.  How  does  an  electrodialysis  unit  demineralize  brackish 
water? 

17.  What  are  the  basic  parts  of  an  electrodialysis  unif? 

18.  What  are  the  benefits  of  using  plastic  pipe  in  an  electro- 
dialysis plant? 

19.  What  is  the  purpose  of  the  chemical  flush  system  in  an 
electrodialysis  unit? 

20.  An  excessive  concentration  of  any  specific  ion  in  the 
feedwater  to  an  electrodialysis  unit  can  cause  what 
problem? 


21.  When  should  you  check  to  be  sure  that  an  electrodialy- 
sis unit  IS  properly  grounded'^ 


SUGGESTED  ANSWERS 

Chapter  16.  DEMINHRALIZATION 


ANSWERS  TO  QUESTIONS  IN  LESSON  1 

Answers  to  questions  on  page  142. 

16.0A  Demineralization  is  the  process  which  removes  dis- 
solved minerals  (sails)  from  water 

16.0B  Sea  water  is  more  expensive  to  treat  than  brackish 
water  becauses  of  its  much  higher  TDS  concentra- 
tion. 

Answers  to  questions  on  page  142. 

16.1  A  Methods  of  removing  minerals  from  water  can  be 
divided  into  two  classes: 

1.  Those  that  use  a  phase  change  such  as  freezing 
and  distillation,  and 

2.  Non-phase  change  methods  such  as  reverse  os- 
mosis, eiectrodialysis  and  ion  exchange. 

16.1B  The  common  membrane  demineralizing  processes 
are  reverse  osmosis  and  electrodialysis. 

Answers  to  questions  on  page  146. 

16.2A  The  osmotic  pressure  of  a  solution  is  the  difference 
in  water  level  on  both  sides  of  a  membrane. 

16.2B  The  modified  cellulose  acetate  membrane  is  com- 
monly used  today. 

16.2C  The  water  flux  is  the  flow  of  water  in  grams  per 
second  through  a  membrane  area  of  one  square 
centimeter  (or  gallons  per  day  per  square  foot)  while 
the  mineral  flux  is  the  flow  of  mineral.*;  in  grams  per 
second  through  a  membrane  area  of  one  square 
centimeter. 


ERIC 


16  2D  When  additional  pressure  is  applied  to  the  side  of  a 
membrane  with  a  concentrated  solution,  the  water 
flux  (rate  of  water  flow  through  the  membrane)  will 
increase,  but  the  mineral  flux  (rate  of  flow  of  miner- 
als) will  remain  constant. 

16  2E  When  higher  mineral  concentrations  occur  in  the 
feedwater,  the  mineral  concentrations  will  increase  in 
the  product  water 

Answers  to  questions  on  page  147. 

16  2F  Water  flux  is  usually  expressed  in  gallons  per  day  per 
square  foot  (or  grams  per  second  per  square  centi- 
meter) of  membrane  surface. 

16.2G  The  term  "flux  decline"  is  used  to  descnbe  the  loss  of 
water  flow  through  the  membrane  due  to  compaction 
plus  fouling. 


16,2H  Mineral  rejection  is  defined  as 

Product  Concentration 


Rejection,  %  =  (1 


Feedwater  Concentration 


)(100%) 


Mineral  rejection  can  be  determined  by  measuring 
the  TDS  and  using  the  above  equation.  Rejections 
also  may  be  calculated  for  individual  constituents  in 
the  solution  by  using  their  conCv;ntrations. 

Answers  to  questions  on  page  151. 

16  21   An  increase  m  feedwater  temperature  w'll  increase 
the  water  flux. 

i6.2J  Hydrolysis  of  a  membrane  results  in  a  lessening  of 
mineral  rejection  capability. 


133 


Demineralization  175 


16.2K  Recovery  is  defined  as  the  percentage  feed  flow 
which  Is  recovered  as  product  water 


Recovery,  %  = 


(Product  Flow)  (100%) 
Feed  Flow 


16.2L  Recovery  rate  is  usually  limited  by  (1)  desired  prod- 
uct water  quality  and  (2)  the  solubility  limits  of  miner- 
als In  the  brine. 

16.2M  Concentration  pc^rization  is  the  ratio  of  the  mineral 
concentration  in  tho  membrane  boundary  layer  to  the 
mineral  concentration  in  the  flow  stream. 


ANSWERS  TO  QUESTIONS  IN  LESSON  ^ 

Answers  to  questions  on  page  156. 

16.3a  The  three  types  of  commercially  available  membrane 
systems  which  have  been  used  in  operating  plants 
are  (1)  spiral  wound,  (2)  hollow  fine  fiber,  and  (3) 
tubular. 

16.38  The  tubular  membrane  process  is  used  to  treat 
wastewater  with  a  high  suspended  solids  concentra- 
tion. 

Answers  to  questions  on  page  157. 

16.4A  To  protect  the  reverse  osmosis  system  and  its  ac- 
cessory equipment,  the  feedwater  should  be  fiitered. 
When  the  water  source  is  a  groundwater  or  a  pre- 
viously treated  municipal  or  industrial  supply,  filtra- 
tion may  be  accomplished  by  a  simple  screening 
procedure.  An  untreated  surface  water  will  probably 
require  coagulation,  flocculation,  sedimentation  and 
filtration. 

1 6.4B  Colloidal  particulates  are  removed  from  feedwater  by 
chemical  treatment  and  filtration. 

16.4C  As  an  acetate  membrane  hydrolyzes,  both  the 
amount  of  water  and  the  amount  of  solute  which 
permeate  the  membrane  increase  and  the  quality  of 
the  product  water  deteriorates. 

16.4D  The  scale  control  method  which  is  used  to  inhibit 
calcium  sulfate  precipitation  is  a  threshold  treatment 
with  2  to  5  mg/L  of  sodium  hexametaphosphate 
(SHMP). 

16.4E  A  1  to  2  mg/L  chlorine  residual  is  maintained  to 
control  biological  fouling. 

Answers  to  questions  on  page  157. 

16.4F  Operating  pressure  on  a  reverse  osmosis  unit  is 
regulated  by  a  control  valve  on  the  influent  manifold. 

16.4G  The  demineralized  water  is  usually  calied  PERME- 
ATE, the  reject  BRINE. 

16.4H  Product  or  permeate  flow  is  not  regulated  and  varies 
as  feedwater  pressure  and  temperature  change. 

Answers  to  questions  on  page  162. 

1 6.41  Chlorine  is  added  to  the  feedwater  to  prevent  biologi- 
cal fouling. 

16.4J  The  operator  must  check  the  differential  pressure 
across  the  RO  unit  to  know  when  to  clean  the 
elements.  When  the  elements  become  fouled,  AP 
usually  Increases,  thus  indica  ting  the  need  for  clean- 
ing. 


16.4K  The  reverse  osmosis  elements  should  be  cleaned 
when  the  operator  observes  (1)  lower  product  w^,,r 
flow  rate,  (2)  lower  salt  rejection,  (3)  higher  differen- 
tial pressure  (AP),  and  (4)  higher  operating  pressure. 

Answers  to  questions  on  page  162. 

16  4L  Safety  needs  for  demineralization  plants  can  be 
divided  into  three  general  groups  consisting  of 
chemicals,  electrical  and  hydraulics. 

16.4M  Electrical  equipment  used  around  reverse  osmosis 
plants  consists  of  a  series  of  electrically  powered 
pumps. 

ANSWERS  TO  QUESTIONS  IN  LESSON  3 

Answers  to  questions  on  oage  165. 

16.5A  Typical  removals  of  inorganic  salts  from  brackish 
water  by  ED  range  from  25  to  40  percent  of  dissolved 
solids  per  stage  of  treatment. 

16.5B  A  membrane  stack  in  an  electrodialysls  unit  consists 
of  several  hundred  membranes  and  their  separating 
spacers  assembled  between  a  single  set  of  elec- 
trodes. End  plates  and  tie  rods  complete  the  assem- 
bly. 

16.5C  The  most  commonly  encountered  problem  In  ED 
operation  is  sealing  (or  fouling)  of  the  membranes  by 
both  organic  and  inorganic  materials.  Alkaline  scales 
are  troublesome  in  the  concentrating  compartments 
when  the  diffusion  of  ions  to  the  surface  of  the  anion 
membrane  in  the  diluting  cell  is  insufficient  to  carry 
the  current. 

Answers  to  questions  on  page  165. 

16.6A  If  a  D.C.  potential  is  applied  across  a  solution  of  salt 
in  v/ater  by  means  of  insertion  of  two  electrodes  In 
the  solution,  the  cations  will  move  towards  a  negative 
electrode,  which  is  known  as  the  "cathode**,  and  the 
anions  will  move  towards  the  positive  electrode, 
which  Is  known  as  the  **anode." 

16.6B  Only  cations  (positively  charged  Ions)  can  pass 
through  cation  membranes. 

16.6C  In  a  multi-compartment  ED  unit,  the  compartments 
losing  salt  are  labeled  "dilute"  and  those  receiving  the 
transferred  salt,  "brine." 

Answers  to  questions  on  page  168. 

16.7A  Iron,  manganese  and  chlonne  residual  must  be  re- 
moved from  the  feedwate*'  supply  to  the  electrodiely- 
sis  unit. 

16.7B  The  rectifier  provides  the  D.C.  power  to  the  mem- 
brane stack  assembly.  The  input  (alternating  current, 
A.C.)  is  converted  by  the  rectiiiei  to  D.C.  which  is 
applied  to  the  electrodes  on  each  side  of  the  mem- 
brane stack  to  remove  the  ions  from  the  feed  stream. 

Answers  to  questions  on  page  171. 

1 6.8A  The  Ions  most  often  encountered  in  the  feedwater  to 
an  electrodialysls  unit  include: 

Cations  Anions 


1.  Calcium 

2.  Iron 

3.  Magnesium 

4.  Silica 

5.  Sodium 


1.  Bicarbonate 

2.  Chloride 

3.  Sulfate 


176  Water  Treatment 


16  8B  To  prevent  biological  fouling  of  the  cation  and  anion 
membranes,  the  operator  mui't  control  feed,  pH, 
biological  and  bactenological  quality. 

16.8C  Generally  the  electrodlalysis  un.t  should  NOT  be 
operated  when  the  feedwater  contains  any  of  the 
following: 

1.  Chlorme  residual  in  any  concentration, 

2.  Hydrogen  sulfide  of  any  concentration, 

3.  Calgon  or  other  hexrmetaphospha»es  in  excess 
of  10  mg/L, 

4.  Manganese  iti  excess  of  0.1  mg/L,  and 

5.  Iron  in  excess  of  0.3  mg/L. 

16.8D  The  recommended  daily  activities  for  the  operator  of 
an  electrodialysis  unit  include. 

1 .  Fill  out  log  sheet, 

2.  Verify  that  electrodes  are  bumping  and  flowing 
properly. 


3.  Inspect  stacks  for  excess  external  leakage,  and 

4.  Check  the  pressure  drop  across  the  cartridge 
filter  and  change  the  cartridges  whenever  the 
pressure  drop  re'  .hes  10  psi. 

Answers  to  questions  on  page  173. 

16.9A  Loose  connections  at  the  electrode  tab  connecting 
bolf  will  cause  overheating  which  could  result  in 
serious  damage  to  the  membrane  stack. 

16.9B  Expect  the  D.C.  amperage  to  D/iOP  when  the  feed- 
water  temperature  DROPS. 

16.9C  Should  shorting  occur  from  a  metal  end  plate  across 
the  plastic  end  block  to  the  electrode,  IMMEDIATELY 
turn  off  the  rectifier.  Try  to  eliminate  the  cause  of  the 
shorting  by  wiping  excess  moisture  off  the  block. 
Also,  be  sure  to  completely  remove  the  black  carbon 
that  has  formed  at  the  point  of  shorting. 

16.9D  If  the  operation  of  the  '^ntire  unit  must  be  stopped 
immediately,  the  M/  j  BREAKER  should  be 
switched  off. 


OBJECTIVE  TEST 

Chapter  16.  DEMINERALIZATION 


Please  write  your  name  and  mark  the  correct  answers  on 
the  cnswer  sheet  as  directed  at  the  end  of  Chapter  1 .  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
answers. 


TRUE-FALSE 

1.  Most  of  the  earth's  water  supplies  are  fresh  water 

1.  True 

2.  False 

2.  All  fresh  waters  contain  total  dissolved  solids  (TDS). 

1.  True 

2.  False 

3.  The  development  of  the  membrane  demineralizmg 
processes  has  significantly  increased  the  cost  of  demin- 
eralizing  water. 

1.  True 

2.  False 

4.  Osmosis  is  the  passage  of  a  liquid  from  a  concentrated 
to  a  dilute  solution  across  a  semipermeable  membrane. 

1.  True 

2.  False 

5.  Semipermeable  RO  membranes  generally  must  oe 
maintained  wet  at  all  times. 

1.  True 

2.  False 

6.  When  the  pressure  differential  applied  across  the  mem- 
brane increases,  the  salt  flux  will  increase. 

1.  True 

2.  False 

ERIC 


7.  Water  flux  throuah  a  membrane  over  time  tends  to 
increase  because  of  membrane  erosion. 

1.  True 

2.  False 

8.  Mineral  rejection  by  a  reverse  osmosis  membrane  in- 
creases as  feedwater  mineral  concentration  Increases. 

1.  True 

2.  False 

9.  The  value  of  the  water  permeation  constant  is  only 
constant  for  a  given  temperature. 

1.  True 

2.  False 

10.  Minerals  are  transmitted  through  the  membrane  at  a 
much  more  rapid  rate  than  water. 

1.  True 

2.  False 

11.  Water  to  be  demineralized  always  contains  impurities 
which  must  be  removed  by  pretreatment. 

1.  True 

2.  False 

12.  The  rate  of  acetate  membrane  hydrolysis  is  at  its 
minimum  at  about  a  pH  of  4.7,  and  the  rate  increases 
with  both  increasing  and  decreasing  pH. 

1.  True 

2.  False 

13.  Reverse  osmosis  modules  provide  a  large  surface  area 
for  the  attachment  and  growth  of  bacterial  slimes  and 
molds. 

1.  True 

2.  False 


Demineralization  177 


14.  The  operator  of  a  reverse  osmosis  plant  must  properly 
maintain  and  control  all  flows  and  recovery'  rates  to 
avoid  possible  damage  to  the  membranes  from  scaling. 

1.  True 

2.  False 

15.  The  brine  flov;  valves  in  a  reverse  osmosis  plant  must 
never  be  fully  closed. 

1.  True 

2.  False 

16.  To  properly  operate  a  reverse  osmosis  plant,  the  prod- 
uct or  permeate  flow  must  be  regulated. 

1.  True 

2.  False 

17.  Most  RO  systems  should  be  operated  with  the  addition 
of  a  scale  inhibitor  to  protect  membranes  from  precipita- 
tion of  calcium  sulfate  c*^  other  inorganics. 

1.  True 

2.  False 

18.  When  starting  up  a  reverse  osmosis  unit,  the  feedwater 
should  always  be  bypassed  until  the  ph  i?  properly 
adjusted. 

1.  True 

2.  False 

19.  To  clean  the  elements  of  a  reverse  osmosis  unit,  the 
elements  must  be  removed  from  the  pressure  vessel. 

1.  True 

2.  False 

20.  When  working  around  electrical  equipment,  shut  off  and 
lock  out  electrical  circuits  if  you  are  not  a  qualified 
electrician. 

1.  True 

2.  False 

21.  The  removal  efficiency  of  ED  units  increases  with  de- 
creasing temperature. 

1.  True 

2.  False 

22.  If  a  D.C.  potential  is  applied  across  a  solution  of  salt 
water,  the  cations  will  move  towards  a  negative  elec- 
trode. 

1.  True 

2.  False 

23.  The  negative  electrode  is  known  as  the  anode. 

1.  True 

2.  False 

24.  Electrodialysis  requires  much  higher  operating  pres- 
sures than  reverse  osmosis. 

1.  True 

2.  False 

25.  The  quality  of  the  feedwater  to  an  electrodialysis  unit 
and  Its  ionic  composition  are  extremely  important. 

1.  True 

2.  False 


26.  A.ways  wear  rubber  gloves  when  voltage  probing  the 
membrane  stack  of  an  electrodialysis  unit. 

1.  True 

2.  False 

27.  Always  keep  the  electrodialysis  membranes  dry  when 
not  In  use. 

1.  True 

2.  False 

28.  The  gas  separator  tank  on  electrodialysis  units  should 
be  serviced  when  the  unit  is  in  operation. 

1.  True 

2.  False 

29.  Feeawater  containing  Calgon  or  other  hexametaphos- 
phates  will  lower  membrane  stack  resistance. 

1.  True 

2.  False 

30.  When  an  electrodialysis  plant  is  operating  on  automatic 
controls,  the  plant  is  controlled  by  the  product  water 
tank's  level  switch. 

1.  True 

2.  False 


MULTIPLE  CHOICE 

31.  The  need  for  demineralizing  treatment  processes  is 
increasing  due  to 

1.  Agricultural  runoff  into  rivers. 

2.  Increased  demands  for  water. 

3.  Increased  mineral  content  of  many  rivers. 

4.  Large  quantities  of  mineralized  groundwater. 

5.  Weather  modification  programs. 

32.  Demineralizing  processes  include 

1.  Distillation. 

2.  Electrodialysis. 

3.  Ion  exchange. 

4.  Mineralization. 

5.  Reverse  osmosis. 

33.  Materials  that  can  be  removed  by  some  demineralizing 
processes  include 

1.  Bactena. 

2.  Organic  material. 

3.  pH. 

4.  Suspended  solids. 

5.  Viruses. 

34.  The  selection  of  a  demineralization  process  for  a  par- 
ticular application  depends  on 

1.  Availability  of  energy  and  chemicals. 

2.  Brine  disposal  facilities. 

3.  Mineral  concentration  in  feedwater. 

4.  Pretreatment  required. 

5.  Product  water  quality  required. 


ERLC 


3. 


178  Water  Treatment 


35.  )Nha\  happens  when  the  osmotic  pressure  differential 
across  a  membrane  decreases? 

1.  Mineral  flux  does  not  change. 

2.  Mineral  flux  will  decrease. 

3.  Water  flux  decreases. 

4.  Water  flux  does  not  change. 

5.  Water  flux  increases. 

36.  Fouling  on  RO  membranes  can  be  caused  by 

1.  Bacteria. 

2.  Dissolved  inorganics. 

3.  Dissolved  organics. 

4.  Grovirths  on  membrane  surfaces. 

5.  Suspended  solidc;. 

37.  To  insure  the  longest  possible  lifetime  of  a  membrane 

and  to  slow  hydrolysis  is  added  as  a  pretreat- 

ment  step  before  demlneralization. 

1.  Ado 

2.  Alkalinity 

3.  Caustic 

4.  Lime 

5.  Polymer 

38.  Feedwater  should  be  pretreated  to  remove  materials 
and  change  conditions  potentially  harmful  to  the  RO 
process  such  as 

1.  Adjust  pH. 

2.  Adjust  temperature. 

3.  Disinfect  to  prevent  biological  growth 

4.  Remove  or  prevent  scaling  or  fouling. 

5.  Remove  turbidity /suspended  solids. 

39.  Why  is  sulfuric  acid  usually  added  to  the  feedwater? 

1.  To  control  precipitation  of  membrane  fouling  materi- 
als. 

2.  To  control  precipitation  of  scale-forming  minerals. 

3.  To  improve  the  alkalinity  of  the  feedwater. 

4.  To  Increase  pH. 

5.  To  prevent  corrosion. 

40.  What  problems  may  be  caused  in  the  reverse  osmosis 
process  by  microbiological  organisms? 

1.  Deterioration  of  cellulose  acetate  membrane 

2.  Increase  in  conforms  in  proQuct  water 

3.  Membrane  fouling 

4.  Module  plugging 

5.  Reduction  of  organic  matter 

41.  Typical  operating  pressures  for  brackish  water  demin- 
erallzlng  reverse  osmosis  processes  vary  from 

1.  20  to  40  psi. 

2.  70  to  100  osi. 

3.  150to350psl. 

4.  400  to  500  psi. 

5.  1000  to  2000  psi. 

42.  Which  of  the  following  chemicals  are  used  in  the  oper- 
ation of  a  reverse  osmosis  unit? 

1.  Caustic 

2.  Chlorlns 

3.  Lime 

4.  Sodium  hexametaphosphate 

5.  Sulfuric  acid 

43.  The  differential  pressure  (AP)  across  the  RO  unit  should 

not  exceed  because  of  possible  damage  to  the 

RO  modules. 

O 

ERIC 


1.  20to4C  psi 

2.  70  to  100  psi 

3.  100  to  250  psi 

4.  150  to  500  psi 

5.  1000  to  2000  psi 

44.  What  rypes  of  cleaning  s'^'utions  a  e  used  to  remove 
biological  or  organic  fouling  from  an  RO  membrane? 

1.  Bactericides 

2.  Chelating  agents 

3.  Citric  acid 

4.  Detergents 

5.  Sequestrants 

45.  Advantages  of  the  electrodialysis  process  include 

1.  Efficient  removal  of  most  inorganic  constituents. 

2.  Low  costs. 

3.  Low  energy  requirements. 

4.  Waste  brine  contains  only  salts  removed  from  feed- 
water. 

5.  Well  developed  technology. 

46.  The  actual  percentage  removal  of  mine.als  by  an  ED 
unit  varies  with 

1.  Flow  rate  of  the  water. 

2.  pH. 

3.  Stack  design. 

4.  Types  and  amounts  of  Ions  present. 

5.  Water  temperature. 

47.  Which  of  the  following  ions  must  be  lowered  or  removed 
Ly  pretreatment  of  the  feedwater  supply  to  the  electro- 
dialysis  unit? 

1.  Chlorine  residual 

2.  Hydrogen 

3.  Hydroxyl 

4.  Iron 

5.  Manganese 

48.  Which  of  the  following  tasks  should  be  performed  dally 
by  the  operator  on  an  electrodialysis  unit? 

1.  Check  the  oil  level  on  pumps  fitted  with  automatic 
oilers. 

2.  Fill  oul  log  sheet. 

3.  Inspect  stacks  for  excess  external  leakage. 

4.  Verify  that  electrodes  are  bump'ng  and  flowing  prop- 
erly. 

5.  Voltage  probe  the  membrane  stacks. 

49.  Estimate  the  ability  of  a  reverse  osmosis  plant  to  reject 
minerals  by  calculating  the  mineral  rejection  as  a  per- 
cent. The  teed  water  contains  1700  mg/L  TDS  and  the 
proJjct  water  is  140  mg/L. 

1.  85% 

2.  87% 

3.  90% 

4.  92% 

5.  95% 

50.  Estimate  the  percent  recovery  or  a  reverse  osmosis  unit 
with  a  4-2-1  arrangement  if  the  feed  flow  is  4.5  MGD  and 
the  product  *lov/  is  3.9  MGD. 

1.  85% 

2.  87% 

3.  90% 

4.  1^5% 

5.  95% 

19/ 


CHAPTER  17 

HANDLING  AND  DISPOSAL  OF  PROCESS  WASTES 

by 

George  Uyeno 


180  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  17.   Handhng  and  Disposal  of  Process  Wastes 


Page 

OBJECTIVES  

  181 

GLOSSARY  

  182 

17.0  Need  for  Handling  and  Disposing  of  Process  Wastes   ^33 

17.1  Sources  of  Treatment  Process  Wastes    ^33 

17.2  Process  Sludge  Volumes   ^o>. 

  io4 

17.3  Methods  of  Handling  and  Disposing  of  Process  Wastes   ^35 

17.4  Draining  and  Cleaning  of  Tanks   ^oc 

  1  oo 

17.5  Backwash  Recovery  Ponds  (Solar  Lagoons)   ^37 

17.6  Sludge  Dewatering  Processes  

17.60  Solar  Drying  Lagoons  

17.61  Sand  Drying  Beds   ^g^ 

17.62  Belt  Filter  Presses   ^g^ 

17.63  Centrifuges   ^g^ 

17.64  Filter  Presses   ^g^ 

17.65  Vacuum  Filters   ^g^ 

17.7  Discharge  Into  Collection  Systems  (Sewers)    ^gg 

17.8  Disposal  of  Sludge   ^g^ 

17.9  Equipment  

^    200 

17.90  Vacuum  Trucks   200 

17.91  Sludge  Pumps   

17.10  Plant  Drainage  Waters   202 

17.11  Monitoring  and  Reporting  

17.12  Additional  Reading   202 

Suggested  Answers   203 

Objeciiv*  Test   204 


ERIC 


Process  Wastes  181 


OBJECTIVES 

Chapter  17.   HANDLING  AND  DISPOSAL  OF  PROCESS  WASTES 


Following  completion  of  Chapter  17,  you  should  be  able 


1.  Outline  the  need  for  handling  and  disposal  of  process 
wastes, 

2.  Identify  the  sources  of  water  treatment  plant  wastes, 

3.  Drain  and  clean  sedimentation  tanks, 

4.  Discharge  process  wastes  to  collection  systems  (sew- 
ers), 

5.  Operate  and  maintain  backwash  recovery  ponds  (la- 
goons) and  sludge  drying  beds. 

6.  Dispose  of  process  wastes, 

7.  Safely  operate  and  maintain  sludge  handling  and  dispos- 
al equipment,  and 

8.  Monitor  and  report  on  the  disposal  of  process  wastes. 


to: 


ERIC 


£00 


1 82  Water  Treatment 


GLOSSARY 

Chapter  17.   HANDLING  AND  DISPOSAL  OF  PROCESS  WASTES 


CENTRIFUGE  CENTRIFUGE 
A  mechanical  device  that  uses  centrifugal  or  rotational  forces  to  separate  solids  from  liquids. 

CONOmONING  CONDITIONING 
Pretreatment  of  sludge  to  facilitate  removal  of  water  in  subsequent  treatment  processes. 

DECANT  ^^^^^^ 
To  draw  off  the  upper  layer  of  liquid  (water)  after  the  heavier  material  (a  solid  cr  another  liquid)  has  settled. 
DEWATER  DEWATER 
To  remove  or  separate  a  portion  of  the  water  present  in  a  sludge  or  s!urry.  To  dry  sludge  so  it  can  be  handled  and  disposed  of. 

SLUDGE  (sluj)  SLUDGE 
The  settleable  solids  separated  from  water  during  processing. 

SUPERNATANT  (sue-per-NAY-tent)  SUPERNATANT 

Uquid  removed  from  settled  sludge.  Supernatant  commonly  refers  to  the  liquid  between  the  sludge  on  the  bottom  and  the  water 
surface  of  a  basin  or  container. 

THICKENING  THICKENING 
Treatment  to  remove  water  from  the  sludge  mass  to  reduce  the  volume  that  must  be  handled. 


20} 


ERIC 


Process  Wastes  183 


CHAPTER  17.    HANDLING  AND  DISPOSAL  OH  PSOCESS  WASTES 


17.0   NEED  FOR  HANDLING  AND  DISPOSAL  OF 
l^'ROCESS  WASTES 

The  need  for  handling  and  disposal  of  potable  water 
treatment  plant  wastes  is  a  problem  tnat  must  be  faced  by  all 
plant  operators.  Many  articles  and  books  have  been  pub- 
lished on  potable  water  treatment  processes.  Their  empha- 
sis is  usually  on  producing  wholesome  and  pure  water  for 
human  consumption  in  compliance  with  EPA,  state  and  local 
health  department  regulations,  but  very  few  mention  sludge 
handling  and  disposal  in  any  great  detail.  In  response  to  a 
growing  population  and  increasing  concern  about  polluiion 
of  natural  water  sources,  pollution  control  a^jencies,  health 
departments,  and  fish  and  game  departments  established 
programs  to  enforce  rules  to  prevent  any  waste  discharge 
that  would  tend  to  discolor,  pollute  or  generally  be  harmful  to 
aquatic  or  plant  life  or  the  environment. 

The  law  which  restricts  or  p.-ohibits  the  discharge  of 
process  wastes  from  water  treatment  plants  is  Public  Law 
92-500,  the  Water  Pollution  Control  Act  Amendments  of 
1972.  This  Act  clearly  includes  treatment  plant  wastes  such 
as  sludge  from  a  wator  treatment  plant  These  wastes  are 
considered  an  industrial  waste  which  requires  compliance 
with  the  provisions  of  the  Act.  Under  the  National  Pollutant 
Discharge  Elimination  System  (NPDES)  provisions,  a  permit 
must  be  obtaineo  In  order  to  discharge  wastes  from  a  water 
treatn^.ent  plant.  Water  treatment  plants  are  classified  into 
three  categories. 

Category  1  Plants  that  use  one  of  the  following  three  pro- 
cesses: (1)  coagulation,  (2)  oxidative  iron  and 
manganese  removal,  or  (3)  direct  filtration. 

Category  2  Plants  that  use  only  chemical  softening  pro- 
cesses. 

Category  3  Plants  that  use  combinations  of  coagulation  and 
chemical  softening,  or  oxidative  iron-manga- 
nese removal  and  chemical  softening. 

Enforcement  of  PL  92-500  is  the  responsibility  of  each 
state.  Many  NPDES  permits  have  been  issued  by  the  stales 
to  water  treatment  plants  using  state  standards  applicable  to 
the  local  conditions  at  the  time  the  permits  were  issued. 
Water  quality  indicators  for  which  waste  discharge  lln^'  a- 
tions  have  been  issued  include  pH,  total  suspended  solids, 
settleable  solids,  total  iron  and  manganese,  flow  rate,  total 
dissolved  solids  (TDS),  BOD,  turbidity,  total  residual  chlo- 
rine, temperdture,  floating  solids  and  visible  forms  of  waste. 

Water  treatment  plants  can  no  longer  simply  discharge 
dirty  backwash  water  or  settled  sludge  into  lakes,  rivers, 
streams  or  tributaries  as  was  done  in  the  past.  Current 
regulations  require  daily  monitoring  of  any  discharge  and 
analysis  of  such  water  quality  indicators  as  pH,  turbidity, 
TDS,  settleable  solids  or  other  harmful  materials.  The  results 
of  the  analyses  must  be  logged  and  reported  frequently  to 

ERIC 


the  proper  authorities  and  must  conform  to  their  rigid 
standards.  For  these  reasons,  it  is  absolutely  necessary  to 
make  provisions  for  facilities  to  handle  these  wastes  on  a 
routine  basis.  While  the  most  important  part  of  an  operator's 
job  is  still  the  end  product,  good  potable  water,  an  opera- 
tor's duties  are  not  complete  until  all  by-products  and 
wastes  are  disposed  of  in  an  acceptable  and  documented 
manner. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  203. 

1 7.0A  Wh^  are  strict  laws  needed  regarding  the  disposal  of 
process  wastes? 

17.0B  If  a  discharge  results  from  the  disposal  of  procass 
wastes,  what  water  quality  indicators  may  require 
monitoring? 

17.1    SOURCES  OF  TREATMENT  PROCESS  WASTES 

Although  there  are  many  types  of  water  treatment  plants 
and  methods  for  treating  water,  most  of  them  probably 
operate  in  the  follcwing  general  manner.  Alum  or  polymers 
are  applied  to  the  water  in  a  rapid  mix  chamber,  agitated  by 
mechanical  means  or  through  a  cylinder  designed  for  hy- 
draulic flash  mixing  for  coagulation.  Following  this,  the  water 
passes  through  mechanical  flocculators  or  a  series  of  baf- 
fles for  flocculation.  The  water  then  moves  into  the  sedimen- 
tation tank  where  the  floe  is  allowed  to  settle  out  before  the 
water  moves  to  the  filters.  The  sedimentation  tanks  may  be 
of  various  shapes  and  depths;  however,  they  are  most 
commonly  rectangular  or  circular.  Many  large  plants  are 
equipped  with  either  mechanical  rakes  or  scrapers  which 
periodically  remove  sludge  from  a  hopper  or  with  a  vacuum- 
type  sludge  removal  device.  The  sludge  is  continuously 
scraped  into  the  hopper.  The  hopper  is  emptied  from  one  to 
three  times  per  day  for  20  to  30  minutes  each  time  depend- 
ing on  the  size  of  the  hopper  and  the  density  of  the  sludge. 


Sludge  is  then  usually  moved  to  drying  beds.  The  smaller 
and  older  plants  may  not  have  these  sludge  handling  facili- 


202 


184  Water  Treatment 


ties  available.  Many  new  wator  treatment  plants  are 
equipped  with  sludge  collection  headers  with  squeegees. 
This  system  does  not  need  any  sludge  hoppers.  The  collec- 
tion headers  are  supported  by  a  travelling  bridge  or  floats. 
The  sludge  is  pumped  out  of  the  bottom  of  the  basin  and  into 
a  sludge  channel  on  the  walkway  level.  This  system  is 
described  in  Chapter  5,  "Sedimentation." 

Anolher  type  of  plant  similar  to  the  one  above  contains  an 

upflow  solids-contact  unit  with  clarlflers.  The  clanfiers  are 
usually  circular  In  shape  and  have  sludge  draw-off  levels 
which  must  be  monitored;  the  solids  are  then  drawn  off 
periodically  as  sludge. 

For  small  plants  and  in  areas  where  water  must  be 
pumped,  pressure  filters  may  be  used  and  the  coagulant  is 
applied  directly  to  the  filter.  Sedimentation  tanks  or  clarifiers 
may  occasionally  accompany  the  use  of  pressure  filters  but 
this  Is  not  usualh'  the  case  if  the  quality  of  the  source  water 
Is  good. 

In  another  type  of  plant  layout  (not  too  commonly  used), 
the  sedimentation  tank  also  functions  as  the  backwash 
recovery  area.  In  this  case  the  backwash  wastewater  is 
pumped  back  to  the  head  of  the  plant.  Most  of  the  solids  will 
settle  out  when  the  water  flows  through  the  sedimentation 
basin.  This  method  does  eliminate  the  need  for  backwash 
recovery  ponds  or  lagoons. 

Diatomaceous  earth  filtration  is  different  from  all  other 
types  of  filtration  in  its  method  of  operation.  There  Is  usually 
no  pretreatment  of  the  water.  Disposal  of  backwash  wastes 
is  still  a  problem.  Table  17.1  summarizes  the  various 
sources  of  treatment  process  wastes  and  the  methods  of 
collecting,  handling  and  disposal  of  these  wastes. 


TABLE  17.1   COLLECTON,  HANDLING  AND  DISPOSAL 
OF  PROCESS  WASTES 

SOURCES  OF  WASTES 

1.  Trash  racks 

2.  Grit  basins 

3.  Alum,  ferric  hydroxide  or  polymer  sludges  from  sedimen- 
tation basins 

4.  Filter  backwash 

5.  Lime-soda  softening 

6.  Ion  exchange  brine 

COLLECTION  OF  SLUDGES 

1.  Mechanical  scrapers  or  vacuum  devices 

2.  Manual  (hoses  and  squeegees) 

3.  Pumps  (into  tank  trucks  or  dewatering  facilities) 

DEWATERING  OF  SLUDGES 

1.  Solar  drying  lagoons 

2.  Sand  drying  beds 

3.  Centrifuges^ 

4.  Belt  presses 

5.  Filter  presses 

6.  Vacuum  filters 

DISPOSAL  OF  SLUDGES  AND  BRINES 

1 .  Wastewater  collection  systems  (sewers) 

2.  Landfills  (usually  dewatered  sludges) 
o.  Spread  on  land 


■  Mechanical  devices  that  use  centrifugal  or  rotational  forces  to 
separate  solids  from  liquids  (sludge  from  water). 

ERiC 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  203. 

17,1  A  How  is  sludge  removed  from  sedimentation  tanks? 

17.1  B  How  is  sludge  removed  from  an  upflow  solids-con- 
tact type  of  unit? 


17.2  PROCESS  SLUDGE  VOLUMES 

All  of  the  different  methods  of  sludge  collection  require 
some  type  of  facilities  for  handling  processed  waste.  The 
possibilities  here  include  sedimentation  tanks,  backwash 
recovery  ponds,  drying  beds,  lagoons,  ponds,  holding  tanks, 
adequate  land,  access  to  sewer  systems  or  vacuum  trucks 
or  s.milar  equipment  for  removal  and  disposal  of  the  waste 
nr.aterial. 

The  amount  of  sludge  accumulation  depends  on  the  type 
and  amount  of  suspended  matter  In  the  source  water  being 
treated  as  well  as  on  the  level  of  dosage  and  the  tv^s  of 
coagulant  urod.  As  an  example,  let's  examine  sludge  pro- 
duction at  two  5  MGD  (19  MLD)  plants.  The  annual  water 
production  at  each  was  800  to  900  million  gallons  (3000  to 
3400  megaliters).  Plant  One  had  no  source  water  stabilizing 
reservoir  and  the  raw  water  turbidity  ranged  from  3  units 
during  the  summer  months  to  over  100  units  during  the 
winter,  with  an  annual  average  alum  dosage  of  11  mg/L. 
Yearly  sludge  accumulation  was  approximately  500,000 
gallons  (1.9  megaliters).  Plant  Two  with  a  15  million  gallon 
(56.8  megaliters)  source  water  stabilizing  reservoir  treated 
raw  ater  which  never  exceeded  20  turbidity  units  at  the 
intake  with  an  average  alum  dosage  of  8  mg/L.  The  annual 
sludge  accumulation  was  approximately  300,000  gallons 
(1.14  megaliters).  In  both  cases,  non-ionic  polymer  was  used 
for  filte''  aid  at  approximately  15  ppb.  The  scarce  water 
stabilizing  reservoir  provided  water  to  be  treated  with  a 
red'jced  turbidity  level  with  a  more  constant  quality  of  water 
which  required  less  alum  and  produced  less  sludge. 

Organic  polymers  may  be  used  instead  of  alum  to  reduce 
the  quantity  of  sludge  produced.  Polymer  sludges  are  rela- 
tively denser  and  easier  to  dewater  for  subsequent  handling 
and  disposal.  Not  all  waters  can  be  treated  by  polymers 
instead  of  using  alum. 

For  plants  without  sludge  collection  devices,  the  volume  of 
sludge  produced  and  the  frequency  of  cleaning  the  sedimen- 
tation tank  IS  affected  by  several  factors.  Items  to  consider 
include: 

1.  Water  demand, 

2.  Suspended  solios  loads  and  when  peak  demands  occur, 

3.  Water  temperature  (as  the  temperature  of  the  water 
increases,  the  settling  rate  of  the  solids  will  increase), 

4.  Detention  time  (as  the  detention  time  increases,  the 
amount  of  solids  that  settle  out  will  increase), 

5.  Volume  of  sludge  deposited  in  basin  (as  the  volume  of 
sludge  increases,  the  detention  time  decreases  as  well  as 
the  efficiency  of  the  basin), 

6.  Volume  of  treated  water  storage  for  the  system  (the 
greater  the  volume  of  treated  water  storage,  the  more 
time  is  available  for  sludge  removal), 

7.  Time  required  to  clean  and  make  any  necessary  repairs 
during  the  shutdown,  and 

203 


Process  Wastes  185 


8.  Availability  of  adequate  drying  beds,  lagoons,  landfill,  a 
vacuum  tank  truck,  pumps  or  equipment,  and  adequate 
help  with  all  necessary  safety  equipment  and  procedures. 

Sedimentation  tanks;  should  be  drained  and  cleaned  at 
least  twice  a  year  and  more  often  if  the  sludge  buildup 
interferes  with  the  treatment  processes  (filtration  and  disin- 
fection). Alum  or  polymer  sludge  solids  content  is  only  0.5  to 
1  percent  for  continuous  sludge  removal  and  2  to  4  percent 
when  the  sludge  is  allowed  to  accumulate  and  compact. 
Therefore,  the  sludge  can  V-^^i  readily  in  pipes  or  be 
pumped,  esp'^'^ially  wi^n  waste.,   ir-type  pumps. 

QUESTiONS 

Write  your  answers  in  a  notebook  r  d  then  compare  your 
answers  with  those  on  page  203. 

17.2A  How  can  a  source  water  stabilizing  reservoir  reduce 
the  volume  of  sludge  handled'^ 

17.2B  If  a  p'ant  does  not  have  sludge  drying  beds  or 
lagoons,  how  is  the  raw  or  wet  sludge  handled'^ 


» 


17.3   METHODS  OF  HANDLING  AND  DISPOSING  OF 
PROCESS  WASTES  (Figure  17.1) 

Various  methods  are  used  to  handle  and  dispose  of 
process  wastes.  The  facilities  at  your  plant  will  depend  on 
when  the  plant  was  built,  thb  region  where  the  plant  is 
located  (topography  and  climate),  the  sources  of  sludge  and 
the  methods  of  ultimate  disposal. 

An  effective  method  of  handling  sludge  is  to  regularly 
during  the  day  remove  sludge  from  sedimentation  tanks  to  a 
drying  bed.  When  one  drying  bed  is  full  of  sludge,  the  sludge 
IS  allowed  to  dry  while  the  other  drying  beds  are  being  filled. 
A  key  to  speedy  drying  is  the  regular  removal  of  the  water  on 
top  of  the  sludge. 

Some  plants  require  that  portions  of  the  facilities  be  shut 
down  twice  a  year,  the  tanks  drained  and  the  sludge 
removed.  This  is  an  excellent  time  to  inspect  the  tanks  and 
equipment  and  perform  any  necessary  maintenance  and 
repairs. 

Backwash  recovery  ponds  or  lagoons  are  used  to  sepa- 
rate the  water  from  the  solias  after  the  filters  have  been 
backwashed.  The  water  is  usually  returned  or  recycled  to 
the  plant  headworks  for  treatment  with  the  source  water. 
These  ponds  also  may  be  used  to  concentrate  or  thicken 
sludges  from  sedimentation  tanks.  Sludges  from  the  lime- 
soda  softening  process  are  usually  stored  in  lagoons.  The 
drainage  water  is  removed  and  the  sludge  may  be  covered 


or  hauled  off  to  a  disposal  site.  Lime  softening  sludges  may 
be  applied  to  agricultural  lands  to  achieve  the  best  soil  pH 
for  optimum  crop  yields. 

Larger  plants  or  plants  that  produce  large  volumes  of 
sludge  may  use  THICKENING,^  CONDITIONING^  and 
DEWATERING^  processes  to  reduce  the  volume  of  sludge 
that  must  be  handled  and  ultimately  disposed  of.  Sometimes 
polymers  are  added  to  sludges  for  conditioning  prior  to 
dewatering.  Belt  filter  presses,  centrifuges,  solar  lagoons 
and  drying  beds  are  some  of  the  processes  used  to  dewater 
sludges. 

Ultimately  process  wastes  such  as  trash,  gnt,  sludge  and 
brine  must  be  disposed  of  in  a  manner  that  will  not  harm  the 
environment.  Trash  and  grit  may  be  disposed  of  in  landfills. 
Sometimes  sludge  and  brine  are  discharged  into  wastewater 
collection  systems  (sewe''c-'  however,  this  procedure  may 
cause  operational  problems  ror  the  wastewater  treatment 
plant  operator.  To  avoid  upsetting  wastewater  treatment 
plants,  discharges  to  sewers  must  be  made  very  slowly  to 
take  advantage  of  the  dilution  provided  by  the  wastewater. 
Sludges  are  commonly  disposed  of  by  spreading  o"  'and  or 
dumping  in  landfills.  The  method  used  will  derjno  on  the 
volume  of  the  sludge,  sludge  moisture  content,  land  avail- 
able, and  distance  from  the  plant  to  the  ultimate  disposal 
site. 

"he  remainder  of  *  s  chapter  will  discuss  the  detailed 
operational  procedures  that  an  operator  must  consider 
when  handling  and  disposing  of  process  wastes.  Sections 
are  also  provided  on  equipment  operation  and  maintenance 
as  well  as  on  monitoring  and  reporting. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  203. 

17.3A  List  the  methods  that  may  be  used  to  dewater 
sludge. 

17.3B  Whc.^  should  sedimentation  tanks  be  inspected  and 
repaired? 

17.4   DRAINING  AND  CLEANING  OF  TANKS 

Plants  without  mechanical  sludge  collectors  will  require 
the  use  of  manual  labor  to  remove  the  sludge  once  or  twjce  a 
year.  When  two  or  more  sedimentation  tanks  are  designed 
into  a  plant,  the  job  of  cleaning  is  made  easier.  While  one 
sedimentation  tank  s  down,  the  other(s)  can  remain  in 


^  Thickening.   Treatment  to  remove  water  from  the  sludge  mass  to  reduce  the  volume  that  must  be  handled. 

2  Conditioning.   Pretreatment  of  sludge  to  facilitate  removal  of  water  in  subsequent  treatment  processes. 

3  Dewatering.    Treatment  which  removes  or  separates  a  portion  of  the  water  present  in  a  sludge  or  slurry.  To  dry  sludge  so  it  can  be  han- 
dled and  disposed  of. 


ERIC 


2U4 


SLUDGE  SOURCE: 


SEDIMENTATION 


FILTRATION 


SANITARY 
SEWER 


CONCENTRATION: 


WASH  WATEr^ 
TREATMENT  PLANT 


I 


DEVVATERING: 


THICKENER 


I 


RECLAMATION 
3ASIN 


BELT  PRESS 


T 


CENTRIFUGE 


I 


FILTER  PRESS 


I 


VACUUM 
FILTER 


I 


SOLAR 
LAGOON 


I 


SAND  BED 


J 


ULTIMATE 

LANDFILL 

ON-SITE 

DISPOSAL- 

2 


Fig.  17. 1   Sludge  processing  alternatives 


Process  Wastes  187 


operation.  The  cleaning  of  sedimentation  tanks  should  be 
done  prior  to  and/or  after  peak  demand  months.  Generally, 
early  spring  and.  the  fad  of  the  year  are  the  better  times  to 
take  some  facilities  out  of  service  for  cleaning. 

Before  draining  any  tank,  always  determine  the  level  of  the 
water  table.  If  the  water  table  is  high,  an  empty  tank  could 
float  like  a  cork  on  the  water  surface  and  cause  considerable 
damage  to  the  tank  and  piping.  A  properly  designed  tank  will 
have  provisions  to  dram  high  water  tables  or  will  contain 
other  protective  features  (bottorii  pressure-relief  discs  to  let 
groundwater  into  tank  to  prevent  damage). 

After  any  necessary  Intake  valve(s)  o*'  gate(s)  changes  are 
made,  drain  the  water  down  to  the  sludge  blanket  by  partially 
opening  the  dram  valve  from  the  sedimentation  tank  into  tne 
lagoon  or  drying  bed.  After  the  first  few  minutec  (if  the  yalve 
is  not  wide  open),  the  water  will  become  clear.  This  portion 
of  the  water  can  'je  diverted  from  the  lagoon  or  drying  bed,  if 
proper  plumbing  is  available,  and  returned  to  the  source  to 
be  reprocessed.  Most  drying  beds  will  not  handle  this  great 
a  volume  of  water  unless  this  draining  process  is  extended 
over  a  penod  of  a  few  days.  Pump(s)  can  be  used  tr  transfer 
the  settled  water  to  another  sedimentation  tank  that  is  still  in 
operation. 

As  the  water  gets  down  to  the  sludge,  fully  open  the  drain 
valve  into  the  drying  bed(s).  A  large  quantity  of  the  sludge 
will  drain  by  itself.  As  shown  In  Figure  17.2,  the  tank  wall  is 
10  feet  (3  m)  high  with  the  sludge  level  showing  about  five 
feet  (1.5  m)  from  the  top.  When  the  level  drops  down  to 
about  two  feet  (0.6  m)  of  depth  by  the  drain  opening,  the 
sludge  will  have  to  be  assisted  by  an  operator  with  a 
squeegee  (Figure  17.3). 

During  the  draining  stages,  the  walls  and  all  the  equipment 
should  be  completely  hosed  down  and  inspected  for  dam- 
age. All  necessary  repairs  should  be  made  at  this  time.  Once 
sludge  dries  on  any  coated  surface,  it  is  difficult  to  remove 
so  it  is  important  to  hose  everything  down  during  the 
process  of  draining  and  while  the  sludge  Is  still  wet.  All 
gears,  sprockets,  and  moving  parts  should  be  lubricated 
immediately  after  hosing  down  to  prevent  "freeze  up"  result- 
ing from  exposure  to  the  air  during  inspection  and  repair.  By 
using  drying  beds  and  drying  bed  DECANT^  pumps,  ample 
amounts  of  water  may  be  used  for  cleaning  and  assisting 
draining  of  the  sludge.  Under  these  conditions,  two  to  three 
operators  can  clean  cut  one  sedimentation  tank  for  a  plant 
of  5  to  1 0  MGD  (1 9  to  38  MLD)  in  one  day.  Additional  time  Is 
required  for  initial  draw  down,  gathering  up  c*  tools  and 
equipment,  final  cleanup  and  any  repairs  that  tvay  be 
needed. 

Sludge  that  settles  out  near  the  entrance  to  the  sedimen- 
tation lank  is  more  dense,  especially  when  a  polymer  is  used 
for  flocculatlon  aid.  Therefore,  the  dram  should  be  located  in 
the  headworks  area.  Once  the  sludge  ceases  to  flow  freely, 
even  with  the  dilution  water,  then  operators  will  have  to  push 
it  towards  the  drain  with  squeegees  (Figure  17.4). 

The  volume  of  sludge  can  vary  with  the  size  of  the  basm  or 
clarifier,  the  quality  of  the  source  water  being  treated,  the 
use  of  alum,  polymer  or  combinaticns  of  both,  and  the 
frequency  of  cleaning.  This  volume  may  range  from  100,000 
to  200.000  gallons  (0.38  to  0.76  ML),  depending  on  the  size 
of  the  basin  and  how  long  the  sludge  has  accumulated  m  the 
basin. 


Caution  must  be  exercised  whenever  operators  are  in  any 
closed  tank  (confined  space): 

1.  Do  not  operate  gasoline  engines  in  the  tank, 

2.  Provide  adequate  ventilation  of  clean  air  at  all  times, 

3  Provide  a  source  of  water  to  clean  off  boots  and  tools 
where  the  operators  come  out  of  the  tank,  and 

4  Use  the  buddy  system.  Someone  must  be  outside  the 
tank  and  watching  anyone  inside  the  tank. 

Before  filling  the  tank,  thoroughly  inspect  and  repair  all 
equipment  and  valves.  Wash  everything  down  with  clean 
water  or  a  solution  of  200  mg//.  chlorine  to  disinfect  the 
basm  If  a  chlorine  wash  solution  is  not  used,  fill  the  tank  10 
percent  full  with  a  50  mg/L  chlorine  solution  and  then  finish 
filling  It  with  clean  water  from  the  plant.  The  final  free 
chlorine  residual  should  not  be  so  high  that  water  with  a  free 
chlorine  residual  greater  than  0.5  mg/L  reaches  the  consum- 
ers. 

Although  manually  draining  and  cleaning  tanks  requires 
more  operator  hours  and  plant  down  time  than  mechanical 
sludge  removal,  it  does  have  its  advantages.  A  more  sani- 
tary condition  in  the  tank  is  obtained  by  cleaning  up  algae 
buildups  or  other  deposits  that  are  not  picked  up  by  me- 
chanical collectors  and  regular  inspection  of  equipment  can 
eliminate  many  potential  breakdown  conditions.  Even  basins 
with  continuous  sludge  collection  systems  should  be 
drained  once  a  year  for  inspection  and  maintenance. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  203. 

17.4A  How  can  sludge  be  removed  from  tanks  without 
mechanical  or  ;acuum-type  sludge  collectors? 

17.4B  When  draining  a  sedimentation  tank,  what  should  be 
done  with  the  settled  water  above  the  sludge? 

17  40  What  precautions  must  be  exercised  whenever  an 
operator  enters  a  closed  tank  (confined  space)'? 

17.5   BACKWASH  RECOVERY  PONDS  (SOLAR 
LAGOONS) 

Because  of  water  pollution  control  legislation  enacted 
since  the  1960s,  many  recently  constructed  water  treatment 
plants  now  have  backwash  recovery  ponds  (Figure  17.5).  In 
many  instances  these  ponds  can  serve  a  dual  purpose.  In 
addition  to  their  primary  function  as  backwash  recovery 
ponds,  they  can  also  be  used  to  collect  the  sludge  from 
sedimentation  tanks  and  clanfiers  with  a  few  modifications. 
While  these  modified  ponds  are  capable  of  performing  both 
functions  at  the  same  time,  it  would  be  preferable  to  pay 
particular  attention  to  timing  these  operations  so  that  they 
do  not  overlap.  Water  for  hosing  down  the  sedimentation 
basin  and  assisting  the  flow  of  sludge  should  be  used 
foaringly.  Also,  the  backwash  recovery  pump  suction  p'ipe 
should  be  floated  near  the  surface,  by  use  of  a  flexible  hose 
and  tire  tube  or  any  similar  float,  so  that  any  excess  water 
can  be  recycled  without  also  drawing  out  sludge.  This  will  be 
very  important  if  the  filters  must  be  backwashed  at  the  same 
time  sludge  is  being  cleaned  out  of  the  backwash  recovery 
ponds. 


*  Decant. 


To  draw  off  ttie  upper  layer  of  liquid  (water)  after  the  heavier  material  (a  solid  or  another  liquid)  has  settled. 

20  V 


188  Water  Treatment 


Process  Wastes  189 


190  Water  Treatment 


A  vacuum  tank  truck  will  be  needed  to  move  the  wet 
sludge  (a  vacuum  tank  truck  is  shown  in  Figure  17.4).  The 
capacity  of  the  vacuum  truck's  tank  in  the  picture  is  5000 
gallons  (19  cu  m)  and  it  has  a  6-inch  (150  mm)  suction  hose. 
About  15  minutes  are  required  to  fill  up  the  tank  if  sludge  ts 
fed  to  the  suction  end  constantly  without  b''eakmg  the 
vacuum.  A  lift  of  12  feet  (3.6  m)  can  be  obtained  without  too 
much  difficulty. 

Sludge  is  sometimes  applied  to  land  as  a  soil  conditioner. 
Polymer  sludges  are  suitable  as  a  soil  conditioner.  Sludges 
produced  by  direct  filtration,  without  coagulants,  usually 
make  excellent  soil  conditioners  both  with  and  without 
polymers.  The  sludge  may  be  applied  either  wet  or  dry. 
Because  commercial  soil  conditioner  is  becoming  more 
expensive,  sale  of  sludge  as  a  sol!  conditioner  can  help  to 
offset  sludge  handling  and  disposal  costs. 


Most  plants  that  use  the  lime-soda  ash  softening  process 
collect  the  sludge  and  dewater  the  sludge  In  a  lagoon.  A 
variable  length  riser  or  discharge  pipe  is  used  to  draw  off  the 
water  that  Is  separated  from  the  sludge.  When  the  lagoon  is 
full  and  the  sludge  is  dried,  the  surface  may  be  covered  with 
soil  as  in  a  landfill  operation.  In  some  plants  where  space  is 
scarce,  the  dried  sludge  is  hauled  off  to  a  landfill  and  the 
lagoon  refilled.  Lime  softening  sludges  also  can  be  disposed 
of  by  application  to  agricultural  soils  to  ac^just  the  pH  for 
optimum  crop  yields. 

Discharge  of  lime-soda  sludges  to  the  waterwater  collec- 
tion system  (sewers)  is  a  poor  practice  because  (1)  the 
sewers  could  become  plugged  regularly,  and  (2)  the  opera- 
tor at  the  wastewater  treatment  plant  will  have  to  handle  and 
dispose  of  the  sludge.  However,  the  lime-soda  sludge  may 
help  the  wastewater  treatment  plant  operator  by  (1)  adjust- 
ing the  pH,  or  (2)  serving  as  a  coagulant  aid  in  treating  the  in- 
coming wastewater. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  204. 

17.5A  Why  is  timing  critical  if  backwash  recovery  ponds  are 
used  to  handle  sludge  from  sedimentation  basins'^ 

17.5B  Why  must  the  suction  pipe  for  the  backwash  recov- 
ery pump  be  floated  near  the  surface  of  the  pond? 

17.5C  How  can  lime-soda  softening  sludge  be  disposed  of 
ultimately? 


17.6   SLUDGE  DEWATERING  PROCESSES^ 

17.60  Solar  Drying  Lagoons 

Solar  drying  lagoons  are  shallow,  small-volume  storage 
ponds  in  which  treatment  process  sludge  (sometimes  con- 
centrated) Is  stored  for  extended  time  penods.  Sludge  solids 
settle  to  the  bottom  of  the  lagoon  by  plain  sedimentation 
(gravity  settling)  and  the  clear  SUPERNATANT^  water  is 
skimmed  off  the  top  with  the  aid  of  an  outlet  structure  that 
drains  the  clear  surface  waters.  Evaporation  removes  addi- 
tional water  and  the  solar  drying  process  proceeds  until  the 
sludge  reaches  a  concentration  of  from  30  to  50  percent 
solids.  At  this  point,  the  sludge  can  be  disposed  of  on-site  or 
at  a  sanitary  landfill.  Obviously,  the  solar  drying  process  is 
dependent  on  environmental  conditions  (weather)  and  may 
take  many  months  to  complete.  For  this  reason,  several 
lagoons  should  be  provided  (a  minimum  of  three)  so  that 
sludge  loading  and  drying  can  bQ  rotated  from  one  lagoon  to 
another. 

17.61  Sand  nrying  Beds 


Sand  drying  beds  have  been  used  extensively  in  municipal 
wastewater  treatment  where  high  solids  volumes  are  han- 
dled. Sand  drying  beds  are  similar  in  construction  to  a  sand 
filter,  and  consist  of  a  layer  of  sand,  a  support  gravel  layer, 
an  underdrain  system,  and  some  means  for  manual  or 
mechanical  removal  of  the  sludge  (see  Figures  17.6,  17.7 
and  17.8).  They  are  built  with  underdrains  covered  with 
gradations  of  aggregate  and  sand.  The  drains  discharge  into 
a  sump  where  recovery  pumps  can  return  the  water  drained 
from  the  sludge  back  to  the  plant  to  be  reprocessed. 
Frequently,  three  beds  are  used  so  one  can  be  dried  out 
while  one  is  being  filled  from  the  draw-down  of  wet  sludge 
from  the  sedimentation  tanks.  The  third  bed  contains  dried 
sludge  which  is  being  hauled  out. 

The  efficiency  of  the  sand  drying  bed  dewatering  process 
can  be  greatly  improved  by  preconditioning  the  process 
sludge  with  chemical  coagulants.  The  drying  time  can  vary 
from  days  to  weeks,  depending  on  weather  conditions  and 
the  degree  of  preconditioning  of  the  sludge.  The  frequency 
of  removal  of  dried  sludge  will  vary  with  different  plants 
depending  on  the  volume  of  sludge  produced,  size  of  drying 
beds,  and  drying  conditions  (weather). 

Sludge  has  a  un'que  characteristic  about  it  that  once  it  has 
even  partially  dried,  it  will  not  expand,  therefore,  layer  after 
layer  of  wet  sludge  can  be  added  over  a  period  of  time.  This 


Portions  of  this  section  were  prepared  by  Jim  Beard, 

Supernatant  (sue-per-NAY-tent)  Liquid  removed  iron,  settled  sludge  Supernatant  commonly  refers  to  ttie  liquid  between  the  sludge 
on  the  bottom  and  the  water  surface  of  a  basin  or  container. 


Process  Wastes  191 


17.6  Photo  of  sludge  drying  beds 


procedure  will  work  as  long  as  the  solids  content  of  the 
applied  sludge  is  at  least  2  to  3  percent.  When  drying  this 
type  of  sludge,  large  cracks  and  checks  will  develop  on  the 
surface  and  extend  down  through  the  sludge  to  the  sand. 
The  proper  time  to  remove  this  dried  sludge  is  when  no  more 
than  one  foot  (0.3  m)  has  accumulated  and  dried  into  a 
checkered  pattern  A  piece  of  dry  sludge  can  then  be  picked 
up  off  the  sand.  The  dned  sludge  can  easily  be  removed  with 
a  front-end  loader  onto  a  dump  truck  and  be  hauled  off  to  a 
landfill.  However,  the  operator  must  e-xercise  extrervie  cau- 
tion so  that  only  the  dned  sludge  is  picked  up  with  the 
minimum  possible  disturbance  to  the  sand  and  aggregate. 
The  loader  bucket  should  be  operated  carefully  since  there 
may  be  only  about  ten  inches  (36  cm)  of  sand  cover  over  the 
underdrains.  The  loader  bucket  capacity  should  be  limited  to 
one  or  two  cubic  yards  of  sludge.  Concrete  tracks  should  be 
provided  for  larger  equipment  to  collect  the  dried  sludge. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  204. 

17.6A  What  is  the  minimum  recommended  number  of  solar 
drying  beds? 

Er|c 


17.6B  Describe  a  typical  sludge  drying  bed. 

17.6C  When  is  the  proper  time  to  remove  dried  sludge  from 
the  drying  bed? 

17.6D  What  precautions  must  be  exercised  when  operating 
a  front-end  loader  to  remove  sludge  from  a  drying 
bed? 

17.62  Belt  Filter  Presses 

Continuous-belt  filter  presses  are  popular  because  of  the'r 
relative  ease  of  operation,  low  energy  consumption,  small 
land  requirements,  and  their  ability  to  produce  a  relatively 
dry  filter  cake  (material  removed  from  the  filter  press  has 
about  35  to  40  percent  solids).  There  are  two  primary 
mechanisms  by  which  free  water  is  separated  from  the 
sludge  solids  in  a  belt  press: 

1.  Gravity  drainage,  and 

2,  Pressure  dewatering. 

Sludge  is  conveyed  and  dewatered  between  two  endless 
belts  (Figure  17.9)  After  the  sludge  is  initially  mixed  w.th  a 
polymer  in  a  rotary  drum  conditioner,  it  is  dewatered  in  three 
distinct  zones: 

1.  A  horizontal  zone  for  gravity  drainage, 

2  A  vertical  sandwich  draining  zone,  and 

3  A  final  dewatenng  zone  containing  an  arrangement  of 
staggered  rollers  which  produce  a  multiple-shear  force 
action  which  squeezes  out  the  remaining  free  water. 

Each  belt  is  washed  with  a  high  pressure/low  volume 
water  spray. 

17.63  Centrifuges 

Centrifuges  have  been  used  to  dewater  municipal  sludges 
for  some  time.  Problems  with  the  earlier  units  included 
erosion  of  surfaces  hit  by  high  speed  particles,  and  poor 

211 


lO 


fil 
7 


TOP  OF  SAND 
ELEV.  825.5 


-NO.  .00  X  NO.  4  SAND 
AGGREGATE 


3 


1/8  IN.  X  3/8  IN.  GRADED 
AGGREGATE 

3/8  IN.  X  3/4  IN.  GRADED 
AGGREGATED 


BOTTOM 
ELEV.  824.0 


NOTE: 

DIMENSIONS  AND 
ELEVATIONS  ARE 
TYPICAL  FOR  BOTH 
SLUDGE  BEDS 


21'?- 


2 


Fig.  17.7  Sludge  drying  beds 


ERIC 


Fig.  17.8  Sectional  view  of  sludge  drying  bed 


ERIC 


214 


194   Water  Treatment 


Fig.  17.9  Flow  diagram  of  Winklepress 

(Permission  of  Ashbrook-Simon-Hartley) 


er|c  ^-^ 


PrDcess  Wastes  195 


performance  capacity  Design  improvements  and  the  use  of 
polymers  have  generally  eliminated  these  problems.  The 
pnncipal  advantage  of  this  dewatenng  technique  is  that  the 
density  of  the  sludge  cake  can  be  varied  from  a  thickened 
liquid  slurry  to  a  dry  cake.  The  major  limitation  of  using 
centrifuges  is  high  energy  consumption. 

There  are  two  basic  types  of  centrifuges.  Ihe  scroll  type 
and  the  basket  type.  The  scroll  centrifuge  operates  continu- 
ously, while  the  basket  centrifuge  is  a  batch  type  unit  Solids 
capti  .e  IS  generally  greater  with  the  basket  centrifuge. 

In  the  scroll  centrifuge  (Figure  17.10),  sohds  are  intro- 
duced horizontally  into  the  center  of  the  unit.  The  spinning 
action  forces  the  solids  against  the  outer  wall  of  the  bowl, 
where  they  are  trajisported  to  the  discharge  end  by  a 
rotating  screw  conveyor.  Clear  supernatant  liquid  is  dis- 
charged over  an  adjustable  weir  on  the  opposite  end  of  the 
unit. 

In  the  basket  centrifuge  (Figure  17.11),  sludge  is  intro- 
duced vertically  into  the  bottom  of  the  bowl  and  the  superna- 
tant is  discharged  over  a  weir  at  the  top  of  the  bowl.  When 
the  solids  concentration  in  the  supernatant  becomes  too 
high,  the  operation  is  stopped  and  the  dense  solids  cake  is 
removed  by  a  knife  unloader. 

17.64  Filter  Presses 

Filter  presses  have  been  successfully  used  to  process 
difficult-to-dewater  sludges  (alum  sludges).  These  machines 
are  best  suited  for  sludges  with  a  high  specific  resistance 
(the  internal  resistance  of  a  sludge  cake  to  the  passage  of 
water).  Filter  presses  produce  very  dry  cakes,  a  clear  filtrate, 
and  have  a  very  high  solids  capture. 

A  filter  press  consists  of  a  series  of  vertical  plates  covered 
with  cloth  which  supports  and  retains  the  filter  cake  (Figure 
17.12).  These  plates  are  rigidly  held  in  a  frame.  Sludge  is  fed 
into  the  press  at  increasing  pressures  for  about  half  an  hour. 
The  plates  are  then  pressed  together  for  one  to  four  hours  at 
pressures  as  high  as  225  psi  (15.8  kg/sq  cm  or  1,551 
kiloPascals).  Water  passes  through  the  cloth  while  the  solids 
are  retained,  forming  a  cake  which  is  removed  when  the 
press  is  depressurized. 


QUESTIONS 

Write  your  answers  m  a  notebook  and  then  compare  your 
answers  with  those  on  page  204. 

17.6E  List  the  methods  available  for  dewatenng  sludges. 

17.6F  List  the  major  advantages  and  limitations  of  using 
centrifuges  to  dewater  sludges. 

1 7.6G  When  is  a  precoat  of  diatomaceous  earth  required  on 
vacuum  filters? 

17,7.    DISCHARGE  INTO  COLLECTION  SYSTEMS 
(SEWERS) 

The  easiest  method  of  sludge  disposal  would  be  to  send 
the  s*'Jdge  down  the  wastewater  collection  (sewer)  system. 
This  does  create  some  complications  even  if  the  wastewater 
treatment  plant  has  the  capacity  to  handle  the  load.  The  fees 
charged  by  the  wastewater  treatment  plant  could  be  prohibi- 
tive. The  charges  are  usually  based  upon  annual  fow, 
chemical  or  biochemical  oxygen  demand,  suspended  solics, 
and  peak  and  average  discharge.  There  are  also  increased 
monitoring  requirements  and  costs  associated  .\/ith  a  sewer 
discharge.  The  water  treatment  plant  must  have  a  holding 
tank  so  that  the  sludge  can  be  released  at  a  uniform  rate 
throughout  the  day  or  released  only  dunng  the  wastewater 
treatment  plant's  low-flow  period. 

Brine  from  ion  exchange  units  may  be  discharged  into 
wastewater  collection  systems.  Usually  the  brine  is  dis- 
charged during  the  day  to  take  advantage  of  high  flows  fc. 
dilution.  When  you  plan  such  a  discharge,  notify  the  operator 
of  the  downstream  wastewater  treatment  plant  to  be  sure 
you  won't  create  any  unnecessary  problems. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  204. 

17.7A  What  are  the  complications  of  discharging  sludge  to 
sewers? 

17.7B  When  is  brine  from  ion  exchange  units  usually  dis- 
charged into  wastewater  collection  systems? 


17.65  Vacuum  Filters 

Vacuum  filtration  was  once  the  main  chemical  sludge 
dewatering  process.  However,  its  use  has  declined  due  to 
development  of  devices  such  as  the  belt  press  which  con- 
sumes less  energy,  is  less  sensitive  to  polymer  dosage,  and 
does  not  require  use  of  a  precoat  (a  substance  applied  to  the 
filter  tjefore  applying  sludge  for  dewatering). 

A  vacuum  filter  consists  of  a  cylindrical  drum  which 
rotates  partially  submerged  in  a  tank  of  chemically  condition- 
ed sludge  (Figure  17.13).  As  the  drum  slowly  rotates,  a 
vacuum  is  applied  under  the  filter  medium  (belt)  to  form  a 
cake  on  the  surface.  As  the  belt  rotates  suction  is  main- 
tained to  promote  additional  dewatering.  As  the  belt  passes 
the  top  of  the  drum,  it  separates  from  the  drum  and  passes 
over  a  small-diameter  roller  for  discharge  of  the  cake.  The 
belt  is  then  washed  before  it  re-enters  the  vat.  A  precoat  of 
diatomaceous  earth  is  required  to  dewater  gelatinous  alum 
sludge. 


17,8    DISPOSAL  OF  SLUDGE^ 

Sludge  is  commonly  disposed  of  in  sanitary  landfills.  Other 
methods  of  ultimate  disposal  include  land  application  and 
sanitary  sewers.  The  method  of  disposal  depends  or  the 
source  and  type  of  sludge,  as  well  as  economic  and  environ- 
mental considerations.  ^/j 


ERLC 


7  Portions  of  this  section  were  obtained  from  ILLINOIS  EPA  SLUDGE  REGULATION  GUIDANCE  DOCUMENT,  Illinois  Environmental 
Protection  Agency,  2220  Churchill  Road,  Springfiled,  Illinois  62706. 


196  Water  Treatment 


Process  Wastes 


Slurry 
mfUicnt 


Feed  pipe  - 

Skimmer  for 
slurry  discharge 

Font  accelerator- 


Drive  assembly 


Sludge 
influent 


KotJtion 


Access  door 


Knife  cake  untoader 


Centrate  effluent 


Discharge  of 
dense  cake 


Rotjdon 


(  entrate 


Plastic 
Lake 


Skimmer 


Feed  cycle 


Knife 


Dense  cake 


Discharge  cycle 


Fig.  17.11   Imperforate  basket  centrifuqe 

(Pormisston  of  Sharples-StoKes  Division.  Pemwalt  Division) 


ERIC 

5jjr  


21 


198   Water  Treatment 


Process  Wastes  199 


200  Water  Treatment 


Water  treatment  plant  lime  sludge  is  an  excellent  liming 
agent  for  agricultural  purposes.  Lime  sludge  must  be  ap- 
plied at  a  rate  to  achieve  the  best  soil  pH  for  optimum  crop 
yield.  Optimum  levels  of  nitrogen  and  phosphorus  are  also 
Important  to  achieve  high  crop  yields. 

The  application  of  nitrogen  fertilizers  cause  a  reduction  in 
soil  pH.  If  optimum  soil  pH  conditions  do  not  exist,  crop 
yields  will  be  reduced.  Therefore,  suf^ic^ent  quantities  of  lime 
must  be  applied  as  a  means  of  counteracting  the  fertilizer 
applications. 

Lime  softening  sludges  can  also  aid  in  the  reclamation  of 
spoiled  lands  by  neutralizing  acid  soils.  Disposal  of  lime 
softening  sludge  on  stnp  mine  land  will  help  minimize  the 
discharge  of  acidic  compounds  and  low  pH  drainage  waters. 

Although  most  lime  softening  sludges  are  an  excellent 
liming  agent  for  agricultural  and  land  reclamation  purposes, 
some  lime  softening  sludges  must  be  disposed  of  In  a 
sanitary  landfill  due  to  the  lack  of  availability  of  agricultural 
land  or  excessive  costs.  Landfilling  of  lime  softening  sludge 
is  a  practical  alternative  where  this  method  is  cost-effective 
(minimum  cost  of  disposal). 

Alum  sludge  has  a  tendency  to  cause  soils  to  harden  and 
does  not  provide  any  beneficial  value.  For  this  reason  water 
treatment  plant  alum  sludge  must  not  be  applied  to  agricul- 
tural land.  The  sludge  may  be  applied  to  a  dedicated  land 
disposal  site.  The  sludge  Is  applied  to  the  land  and  disked 
into  the  soil.  Landfilling  is  another  method  of  ultimate  dis- 
posal of  alum  sludge 

Some  water  treatment  plants  use  a  slow  sand  filter  or 
settling  pond  for  the  treatment  of  Iron  filter  backwash 
wastewater.  The  slow  sand  filter  must  be  cleaned  occasion- 
ally by  removing  the  top  2  to  3  inches  (50  to  75  mm)  of  sand 
and  iron  sludge.  The  material  removed  must  be  disposed  of 
in  a  sanitary  landfill. 

Water  treatment  plants  which  soften  water  by  the  Ion 
exchange  (zeolite)  softening  method  produce  a  waste* vater 
which  has  high  concentrations  of  total  dissolved  solids  and 
chloride  compounds.  Ion  exchancie  softening  vvastes  should 
not  be  discharged  untreated  into  low  flow  streams.  The 
wastewater  treatment  processes  capable  of  reducing  tlie 
total  dissolved  solids  and  chloride  concentrations  to  accept- 
able levels  are  very  energy  consumptive  and  expensive.  Ion 
exchange  softener  regeneration  wastewater  may  bf;  very 
carefully  and  slowly  discharged  Into  a  sanitary  sewor  sys- 
tem. The  operator  at  the  vyast'^water  treatment  plant  must 
be  notified  in  advance. 

If  a  sanitary  sewer  system  is  not  available  for  the  dis;posal 
of  ion  exchange  softening  wastes,  holding  tanks  should  be 
installed  to  store  the  liquid  from  the  regeneration  arid  rinse 
cycles.  This  liquid  should  be  ultimately  disposed  of  in  a 
sanitary  landfill. 

Filter  backwash  wastewater  may  be  recycled  through  the 
water  treatment  plant,  placed  in  wastewater  storage  ponds 
for  additional  treatment  and  disposal  or  discharged  into  a 
sanitary  sewer.  The  remainder  of  this  .section  discusses 
some  of  the  procedures  used  by  oper'jtors  to  dispose  of 
sludges. 

Wet  sludge  can  be  disposed  of  in  an  open  field  by  use  of 
spray  bars  or  dumped  out  for  landfill  (Figure  17.14).  When 
releasing  the  wet  sludge  at  one  spot,  the  back  of  the  truck 
should  face  downhill  so  it  will  drain  faster  and  be  emptied  out 
completely  (Figure  17.15).  This  practice  will  also  reduce  the 
chances  of  the  truck  getting  stuci<  In  the  sludge.  Usually  it 
takes  about  10  minutes  to  empty  a  truck. 


Sometimes  individuals  will  request  the  sludge  for  fill  and 
some  contractors  have  used  the  sludge  to  mix  with  decom- 
posed granite  (DG)  (a  type  of  rock  found  in  some  regions)  for 
fill  purposes. 

Sludge  drying  beds  for  sedimentation  tank  wastes  also 
can  be  used  to  dry  sludge  from  nearby  backwash  recovery 
ponds,  but  this  requires  the  sludge  to  be  handled  for  a 
second  time.  An  open  field  spray  bar  application  is  o  le 
method  for  disposing  of  backwash  recovery  sludges  be- 
cause after  a  few  weeks,  the  residual  is  hardly  noticeable. 
PVC  pipe  may  be  used  to  dispose  of  backv;ash  recovery 
sludges  instead  of  using  a  spray  bar. 

Where  sludge  is  repeatedly  spread  In  a  single  landfill  site, 
bo  prepared  to  disc  the  sludge  in  with  the  native  soil  because 
It  js  unsightly.  Obviously  a  location  as  close  to  the  plant  as 
possible  would  be  the  most  cost-effective  solution. 

In  plants  with  a  size  range  from  5  to  10  MGD  (19  to  38 
MLD),  it  will  take  four  operators  approximately  two  days  to 
complete  the  job  of  draining  and  cleaning  a  sedimentation 
tank  or  a  backwash  recovery  pond  and  disposing  of  the 
sludge 

In  plants  where  a  backwash  pond  Is  not  available,  the 
sludge  can  be  moved  to  a  sump.  A  smaller  suction  hose 
must  be  used  to  empty  small  sumps;  instead  of  the  6  inch 
(1 50  mm)  hose,  use  either  a  3  or  4  inch  (75  or  1 00  mm)  hose. 
With  a  smaller  suction  hose.  It  will  take  25  minutes  or  more 
to  fill  the  vacuum  tank.  Five  or  six  operators  will  be  needed 
to  keep  the  sump  filled.  Of  course,  during  the  time  that  the 
truck  Is  on  the  road  to  the  dump  site  and  back  again,  the 
operators  are  standing  by  and  the  sludge  r^innot  be  moved. 
If  two  trucks  were  used,  this  disadvante  could  be  over- 
come, but  the  cost  may  also  increase.  Obviously,  the  larger 
the  sump  and  the  truck's  tank,  the  cheaper  the  operation 
from  the  standpoint  of  labor  costs. 

Plants  of  one  MGD  (3.8  MLD)  capacity  may  be  able  to  use 
some  of  the  local  septic  tank  pumpers  or  vacuum  trucks  to 
an  advantage.  Such  companies  usually  have  made  arrange- 
ments for  the  use  of  dump  sites  that  may  be  used  to  dispose 
of  the  sludge  they  pump. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  204, 

17.8A  List  the  methods  of  ultimate  sludge  disposal. 

17.8B  Why  should  sludge  be  disposed  of  as  close  as 
possible  to  the  water  treatment  plant? 


17.9  EQUIPMENT 

17.90  Vacuum  TrucKs 

The  use  of  a  vacuum  truck  is  highly  recommended  be- 
cause these  trucks  develop  the  fewest  problems  with  clog- 
ging. The  larger  the  suction  pipe  the  better.  Any  object 

221 


er|c 


Process  Wastes  201 


202   Water  Treatment 


smaller  than  the  hose  size  can  be  readily  sucked  through 
unless  there  are  too  many  objects  in  the  sludge.  Wedging  of 
several  rocks  or  sticks  can  occur,  slowing  up  the  process  of 
sludge  removal  Obviously  any  object  that  is  sighted  should 
be  removed  by  hand  picking  and  tossed  out.  Any  well 
operated  plant  should  oe  void  of  these  solids,  but  they  are 
sometimes  accidentally  dropped  in  or  thrown  in  by  vandals. 
Leaves  and  other  small  objects  that  nay  get  by  the  plant 
inlet  screens  are  not  too  much  of  a  problem  unless  an 
excessive  amount  exists.  Under  these  conditions,  the  heav- 
ily accumulated  portions  should  be  scooped  out  to  prevent 
any  clogging  of  dram  pipes  or  suction  hoses. 

17.91   Sludge  Pumps 

Many  small  treatment  plants  exist,  especially  m  rural 
areas,  where  disposal  of  sludge  would  appear  less  trouble- 
some. A  couple  of  thousand  gallons  of  sludge  can  be  moved 
by  gravity  or  pumped  out  to  an  open  field  and  disked.  Even  a 
quarter  of  an  acre  can  handle  many  years  of  dried  sludge 
from  a  small  plant.  Unfortunately,  most  of  these  plants  do 
not  have  the  land  available,  so  the  sludge  in  its  wet  form 
must  be  hauled  out  to  a  disposal  site  or  a  small  lagoon  or 
pond  must  be  excavated  for  sludge  collection  If  sludge  must 
be  moved  wet,  use  a  sludge  pump^  to  pump  it  into  a  tank  or 
hire  a  septic  tank  pumper.  Septic  tank  pumps,  especially  the 
suction  hose,  must  be  thoroughly  rinsed  and  disinfected 
before  use  in  any  water  treatment  plant  facilities.  This 
applies  also  to  all  tools  and  equipment  used. 

A  sludge  pump  can  be  an  advantage  over  a  self-priming 
centrifugal  pump  because  of  its  i^rge  suction  and  discliarge 
hose  (usually  three  inches  (75  w.rr.)  in  diameter).  These 
pumps  are  rated  at  about  60  GPM  (3.8  L/sec)  and  can  handle 
.Tiore  solids.  However,  there  are  also  self-priming  types  of 
wastewater  pumps  available  that  are  designed  so  that  solids 
do  not  actually  pass  through  the  impellers.  These  pumps 
may  be  used  to  pump  sludges  from  water  treatment  plants. 
In  either  case,  an  excessive  amount  of  foreign  solids  other 
than  sludgb  itself  can  cause  some  pumping  prcbi^ms. 

Wet  sludge  from  a  sedimentation  tank  will  flow  through 
pipes  by  gravity  even  if  there  are  some  ups  and  downs  in  the 
line  provided  the  sludge  is  under  some  head.  If  difficulty 
arises,  add  some  water  for  dilution  or  raise  the  end  of  the 
suction  hose  closer  to  the  surface  of  the  sump  where  the 
sludge  is  more  diluted. 

Because  of  the  differences  in  volume  between  wet  and 
dried  sludge,  it  is  always  preferable  to  contain  the  wet 
sludge  a*  the  plant  for  drying.  If  tht  ^lant  water  source  is  a 
canal  or  reservoir  close  to  the  site,  construct  a  omall  pond 
parallel  to  it  and  return  the  supernatant  to  tha  source  for 
recycling  by  removing  baffle  boards.  Only  fresh  backwash 
wastewater  should  be  recycled.  Water  separated  or  drained 
from  old  sludge  can  cause  serious  problems  if  recycled .  This 
water  is  likely  to  be  septic  and  could  cause  taste  and  odor 
problems.  Also  this  water  will  contain  millions  of  bacteria 
and  microorganisni3  which  should  not  be  recycled  through  a 
water  treatment  plant. 

If  necessary,  semi-dry  or  dried  sludge  can  be  hauled  out 
of  the  pond. 


8  Types  of  sludge  pumps  include  types  of  diaphragm,  nonclog, 
^  and  progre  s  sive  ca  vity  pumps. 

ERIC 


17.10  PLANT  DRAINAGE  WATERS 

There  are  several  sources  of  drainage  waters  in  a  water 
treatment  plant  which  must  be  properly  handled  and  dis- 
posed of  These  sources  incUde  the  laboratory,  shops  ana 
plant  drainage  water  from  leaks  and  spills.  If  continuous 
sampling  pumps  provide  the  lab  with  continuous  flowing 
water  from  vanous  plant  processes,  this  water  could  be 
discharged  to  a  sewer.  Any  reagents,  toxics  or  potentially 
pathogenic  wastes  from  the  lab  must  be  properly  treated 
and  packaged  before  ultimate  disposal  in  landfills.  Drainage 
waters  from  leaks  and  other  sources  in  the  plant  may  be 
discharged  to  sewers.  These  drainage  waters  may  be  recy- 
cled through  the  plant;  however,  extreme  caution  must  be 
exercised  at  all  times  to  avoid  contributing  to  taste,  odor,  or 
health  hazards  as  well  as  operational  problems. 

17.11  MONITORING  AND  REPORTING 

The  location  of  the  water  treatment  plant  and  the  methods 
used  to  ultrmately  dispose  of  the  process  wastes  will  dictate 
the  monitv»ring  and  reporting  requirements.  Thesa  reporting 
requirements  may  be  established  by  local  or  state  health  or 
pollution  control  agencies.  Monitoring  and  reporting  will 
usually  involve  measuring  and  recording  volumes  of  sludges 
or  brines,  percent  solids  and  other  measurements  which  will 
prove  that  these  processes  are  not  creating  any  adverse 
environmental  impacts. 

17.12  ADDITIONAL  READING 

1.  PROCESSING  W/  TER  TREATMENT  PLANT  SLUDGES. 
AWWA  Computer  Services,  6666  W.  Qumcy  Ave.,  Den- 
ver, Colorado  80235.  Order  No.  20108.  Price,  members, 
$10.50;  nonmembers,  $13.00. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  204 

17.9A    How  do  objects  that  plug  sludge  suction  hoses  get 
into  water  treatment  plants'? 

1 7.9B    What  type  of  pump  can  be  used  to  pump  sludge  into 
a  tank  on  a  truck? 

17.1  OA  List  the  sources  of  plant  drainage  waters. 

17.11  A  What  factors  will  dictate  your  monitoring  and  re- 
porting requirements  for  your  sludge  disposal  pro- 


Process  Wastes  203 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  17.   HANDLING  AND  DISPOSAL  OF  PROCESS  WASTES 


Work  these  discussion  and  review  questions  before  con- 
tinuing with  the  Objective  Test  on  page  204.  The  purpose  of 
these  questions  is  to  indicate  to  you  how  well  you  under- 
stand the  material  in  the  chapter.  Wnte  the  answers  to  these 
questions  in  your  notebook. 

1 .  The  amount  of  sludge  produced  by  a  conventional  water 
filtration  plant  depends  on  what  factors? 

2.  What  items  should  be  considered  when  determining  the 
frequency  of  cleaning  a  sedimentation  basin? 

3.  What  happens  to  the  water  separated  from  sludges  in 
backwash  recovery  ponds  or  lagoons? 

4.  Why  are  at  least  three  sludge  drying  beds  installed  at 
water  treatment  plants? 


5.  What  precautions  must  be  taken  before  draining  a  tank? 

6.  What  duties  should  be  performed  by  operators  as  the 
sludge  is  being  drained  from  a  sedimentation  tank? 

7.  How  would  you  fill  a  sedimentation  tank  after  the  tank 
has  been  emptied,  inspected  and  the  necessary  repairs 
completed? 

8.  How  is  sludge  from  the  lime-soda  softening  process 
dewatered? 

9.  Why  should  the  back  of  the  sludge  truck  face  downhill 
when  releasing  wet  sludge  at  one  polnf^ 

10  What  is  the  purpose  of  monitoring  and  reporting  for  a 
sludge  disposal  progran-,"? 


SUGGESTED  ANSWERS 

Chapter  17.   HANDLING  AND  DISPOSAL  OF  PROCESS  WASTES 


Answers  to  questions  on  page  183. 

17  OA  Strict  laws  are  needed  regarding  the  disposal  of 
process  wastes  to  prevent  rivers  and  streams  from 
becoming  more  polluted.  These  laws  are  designed  to 
prevent  any  waste  discharge  that  could  discolor, 
pollute  or  generally  be  harmful  to  aquatic  or  plant  life 
or  the  environment. 

17. OB  If  a  discharge  results  from  the  disposal  of  process 
wastes,  such  water  quality  Indicators  as  pH,  turbidity, 
TDS,  settleable  solids  and  any  other  harmful  materi- 
als may  require  monitonng. 

Answers  to  questions  on  page  184. 

17.1  A  Sludge  Is  removed  from  sedimentation  tanks  by 
mechanical  rakes  or  scrapers  whch  periodically 
draw  out  sludge  from  a  hopper  or  a  vacuum-^^'oe 
sludge  removal  device  may  be  used. 

17.1B  Sludge  is  removed  from  upflow  solids-contact  units 
through  sludge  drawoff  lines  which  must  be  moni- 
tored. 

Answers  to  questions  on  page  185. 

17.2A  A  source  water  stabilizing  reservoir  can  reduce  the 
volume  of  sludge  handled  by  reducing  the  turbidity  in 
the  water  being  treated.  Lower  turbidities  reduce  the 
amount  of  alum  required  and  thus  the  volume  of 
sludge  that  settles  out. 

17.28  If  a  plant  does  not  have  sludge  drying  beds  or 
lagoons,  the  raw  or  wet  sludge  can  be  pumped  into  a 
vacuum  tank  truck  and  hauled  to  a  site  where  the 
sludge  can  be  spread  out  on  land  to  dry  or  du  mped  in 
a  landfill. 


Answers  to  questions  on  page  185. 

17.3A  Sludge  may  be  dewatered  by  the  use  of  belt  presses, 
centrifuges,  filter  presses,  vacuum  filters,  solar  la- 
goons and  sand  drying  beds. 

17  38  Sedimeniation  tanks  should  be  inspected  and  re- 
paired (if  necessary)  when  the  tanks  are  drained  and 
cleaned. 


Answers  to  questions  on  page  187. 

17.4A  Sludge  must  be  removed  manually  from  tanks  with- 
out mechanical  or  vacuum-type  sludge  collectors. 
The  tanks  must  ba  drained  and  then  -roerators  must 
push  the  sludge  to  the  dram  lines  with  5>  queegees  or 
the  sludge  must  be  pumped  out  into  tanK  trucks. 

1 7.48  When  draining  a  sedimentation  tank,  do  not  drain  the 
settled  water  above  the  sludge  to  the  lagoons  or 
sludge  drying  beds.  Divert  or  pump  this  water  to 
sedimentation  tanks  that  are  in  operation,  to  tne 
headworks  for  reprocessing,  or  return  the  water  to 
the  source. 

1 7  40  Whenever  an  operator  enters  a  closed  tank  (confined 
space),  be  sure  that: 

1 .  No  gasoline  engines  are  operated  in  the  tank, 

2.  Adequate  ventilation  of  clean  air  is  provided  at  ^11 
times. 

3-  Clean  running  water  is  available  to  wash  down 
boots  and  equipment  when  leaving  the  tank,  and 

4.  Use  the  buddy  system  Someone  must  be  outside 
the  tank  and  watching  anyone  inside  the  tank. 


204  Water  Treatment 


Answers  to  questions  on  page  1 90. 

17.5A  Time  is  critical  if  backwash  recovery  ponds  are  used 
to  handle  sludge  from  sedimentation  basins,  be- 
cause you  want  to  avoid  having  to  backwash  the 
filters  while  you  are  draining  a  sedimentation  tank. 

17.5B  The  suction  pipe  for  the  backwash  recovery  pump 
must  be  floated  near  the  surface  of  the  pond  so  that 
any  excess  water  can  be  recycled,  but  the  sludge  will 
not  be  pumped  out  of  the  pond. 

17.5C  Lime-soda  softening  sludge  can  be  disposed  of 
ultimately  by 

1.  Covenng  the  lagoon  with  soil, 

2.  Hauling  the  dried  sludge  to  a  landfill,  or 

3.  Spreading  on  agncultural  soils  to  adjust  the  pH  for 
optimum  crop  yields. 

Answers  to  questions  on  page  191. 

17  6A  The  minimum  recommended  number  of  solar  drying 
lagoons  is  three. 

17.6B  Sludge  drying  beds  are  made  with  underdralns  cov- 
ered with  gradations  of  aggregate  and  sand.  The 
drains  terminate  into  a  sump  where  recovery  pumps 
can  return  the  water  drained  from  the  sludge  back  to 
the  plant  to  be  reprocessed. 

17.6C  The  proper  time  to  remove  sludge  from  the  drying 
bed  is  when  one  foot  of  sludge  has  accumulated  and 
a  checkered-shaped  piec^  of  dry  sludge  can  be 
picked  up  off  the  sand. 

17.6D  When  operating  a  front-end  loader  to  remove  sludge 
from  a  drying  bed.  be  careful  so  only  the  dried  sludge 
Is  picked  up  with  a  minimum  of  disturbance  to  the 
sand  and  aggregate.  The  loader  oucket  capacity 
should  be  limited  to  one  or  two  cubic  yards  of  sludge 
because  there  may  be  only  about  14  inches  of  sand 
cover  over  the  underdrains. 

Answers  to  questions  on  page  1 95. 

17.6E  Sludges  may  be  dewatered  using:  (1)  solar  lagoons, 
(2)  sand  drying  beds,  (3)  belt  presses,  (4)  centnfuges, 
(5)  filter  presses,  and  (6)  vacuum  filters. 

17.6F  The  principal  advantage  of  using  centrifuges  to 
dewater  sludges  is  that  the  density  of  the  sludge 
cake  can  be  varied  from  a  thickened  liquid  slurry  to  a 


dry  cake.  The  major  limitation  of  using  centrifuges  is 
high  energy  consumption. 

17.6G  A  precoat  of  diatomaceous  earth  is  required  to 
dewater  gelatinous  alum  sludge. 

Answers  to  questions  on  page  195. 

17  7A  The  complications  of  discharging  sludge  to  sewers 
include: 

1.  Fees  charged  by  wastewater  treatment  plants 
could  be  very  high, 

2.  Increased  monitonng  requirements  and  costs, 

3.  A  holding  tank  may  be  necessary  so  the  sludge  is 
released  at  a  uniform  rate. 

4.  Possibility  of  causing  a  sewer  blockage,  and 

5.  Wastewater  treatment  plant  will  have  to  handle 
and  dispose  of  sludge. 

^1  7B  Brine  from  ion  exchange  units  is  usually  discharged 
into  wastewater  collections  during  the  day  to  take 
advantage  of  high  flows  for  dilution. 

Answers  to  questions  on  page  200. 

17  8A  Methods  of  ultimate  sludge  disposal  include: 

1 .  Wet  sludge  can  be  disposed  of  on  open  fields, 

2.  Wet  or  dry  sludge  can  be  dumped  in  landfills,  and 
3  Lime  softening  sludges  may  be  sold  to  improve 

the  pH  of  agricultural  soils 

1 7.8B  Sludge  should  be  disposed  of  as  close  as  possible  to 
the  water  treatment  plant  to  reduce  hauling  costs. 

Answers  to  questions  on  page  202. 

17  9A  Objects  that  plug  sludge  suction  hoses  get  into 
water  treatment  plants  by  being  accidentally 
dropped  m  or  thrown  in  by  vandals. 

17.9B  A  diaphragm  pump  can  be  used  to  pump  sludge 
into  a  tank  on  a  truck. 

17.10A  Sources  of  plant  drainage  waters  include  the  labo- 
ratory, shops  and  plant  drainage  water  from  leaki 
and  spills. 

17,1 1 A  Monitonng  and  reporting  requirements  for  a  sludge 
disposal  program  are  dictated  by  the  location  of 
your  water  treatment  plant  and  the  methods  used  to 
ultimately  dispose  of  your  process  wastes. 


OBJECTIVE  TEST 

Chapter  17.   HANDLING  AND  DISPOSAL  OF  PROCESS  WASTES 


Please  write  your  name  and  mark  the  correct  answers  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1 .  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
questions. 

TRUE-FALSE 

1.  Many  articles  and  books  have  been  written  on  sludge 
handling  and  disposal. 


1.  True 

2.  False 


ERIC 


Frequently  water  treatment  plants  will  use  a  seciimenta- 
tion  tank  as  a  backwash  recovery  area 


True 
False 


Ultimately  process  wastes  must  be  disposec*  of  m 
manner  that  will  not  harm  the  environment. 

1  True 

2  False 


2 


9': 


Process  Wastes  205 


4  Wet  sludge  can  easily  be  removed  from  drying  beds  by 
a  front-end  loader. 

1.  True 

2.  False 

5.  After  draining  a  sedimentation  tank,  allow  the  sludge  to 
dry  on  the  equipment  so  the  sludge  can  be  easily 
removed. 

1.  True 

2.  False 

6.  Sludge  that  settles  out  near  the  entrance  to  the  sedi- 
Tientation  tank  is  more  dense  than  the  rest  of  the 
sludge. 

1  True 
2.  False 

1.  The  sale  of  lime  sludge  as  an  agricultural  liming  agent 
can  help  offset  sludge  handling  and  disposal  costs. 

1.  True 

2  False 

8.  Brine  from  ion  exchange  units  is  usually  discharged  into 
sewers  at  night  during  low  flow  periods. 

1.  True 

2.  False 

9  Wet  sludge  from  a  sedimentation  tank  can  flow  through 
pipes  by  gravity. 

1.  True 

2.  False 

10.  Wet  sludge  should  be  dewatered  or  dried  at  the  plant 
before  being  hauled  away. 

1.  True 
2  False 


MULTIPLE  CHOICE 

11.  Sources  ^f  process  wastes  include 

1.  Disinfjction. 

2.  Filter  backwash. 

3.  Grit  basins 

4.  Ion  exchange  softening. 
5  Lime-soda  softening. 

12.  Sludges  may  be  dewaterr  J  by 

1.  Centnfuging. 

2.  Drying. 

3.  Filter  pressing. 

4.  Flocculating. 

5.  Lagooning. 

13.  Sludges  and  brines  may  be  ultimately  disposed  of  in 

1.  Lakes. 
2  Landfills. 

3.  Rivers. 

4.  Streams. 

5.  Wastewater  collection  systems. 


14  The  frequency  of  draining  and  cleaning  a  sedimentation 
tank  will  depend  on 

1.  Backwash  rate  of  rapid  sand  filters. 

2.  Detention  time  in  sand  filters, 

3.  Time  required  to  drain  and  clean  tank. 

4.  Volume  of  sludge  in  tank. 

5  Volume  of  treated  water  in  distribution  system  pipes. 

15  How  freqently  are  sedimentation  tanks  usually  drained 
and  cleaned'? 

1.  Weekly 

2.  Monthly 

3.  Quarterly 

4.  Semi-annually 

5.  Annually 

16.  Treatment  processes  used  in  water  treatment  plants  to 
reduce  the  volume  of  sludge  that  must  be  handled  and 
ultimately  disposed  of  include 

1.  Conditioning. 

2.  Dewatering. 

3.  Digesting. 

4.  Flocculating. 

5.  Thickening. 

17.  Methods  of  ultimate  sludge  disposal  will  depend  on 

1.  Distance  to  disposal  site. 

2.  Land  available. 

3.  Quality  of  product  water. 

4.  Sludge  moisture  content 

5.  Volume  of  sludge. 

1 8.  The  frequency  of  removal  of  dried  sludge  will  depend  on 

1.  Drying  conditions  (weather). 

2.  Number  of  operators  at  the  plant. 

3.  Size  of  drying  beds. 

4.  Time  available  for  operators  to  do  job. 

5.  Volume  of  sludge  produced. 

19.  When  draining  a  sedimentation  tank,  the  settled  water 
above  the  sludge  should  be 

1.  Diverted  to  the  clear  well. 

2  Diverted  to  the  headworks  for  reprocessing. 

3  Emptied  onto  the  sludge  drying  beds. 

4,  Pumped  to  a  sedimentation  tank  in  operation. 
5  Recycled  to  the  solar  drying  ponds. 

20.  The  easiest  way  to  dispose  of  sludge  from  a  sedimenta- 
tion tank  IS  to 

1.  Discharge  sludge  to  the  sewer. 

2  Divert  sludge  to  backwash  recovery  ponds. 

3.  Haul  sludge  to  landfill. 

4.  Pump  sludge  to  drying  beds. 

5.  Spread  sludge  over  land. 

21.  When  releasing  wet  sludge  at  one  point,  the  back  of  the 
sludge  truck  should  face  downhill  so  the 

1.  Spray  bars  will  not  become  plugged. 

2.  Tank  will  empty  completely, 

3.  Tank  will  empty  faster. 

4.  Truck  will  not  become  stuck  in  the  sludge. 

5.  Water  will  flow  out  before  the  sludge. 


^  '•f  o 


CHAPTER  18 

MAINTENANCE 

by 

Parker  Robinson 


208  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  18  Maintenance 

Page 

OBJECTIVES  213 

GLOSSARY  214 

LESSON  1 

18.0  Treatment  Plant  Maintenance  —  General  Program  218 

18.00  Preventive  Maintenance  Records  218 

18.01  Library  of  Manufacturers'  Operation  and  Parts  Manuals  218 

18.02  Emergencies  220 

18.1  Electrical  Equipment  220 

1*8.10  Beware  of  Electricity   220 

18.100  Attention  220 

18.101  Recognize  Your  Limitations  221 

18.11  Electrical  Fundamentals  221 

18.110  Introduction  221 

18.111  Volts   221 

18.1 12  Direct  Current  (D.C.)  223 

18.113  Alternating  Current  (A.C.)  223 

18.114  Amps  224 

18.115  Watts  224 

18.116  Power  Requirements  225 

18.1 17  Conductors  and  Insulators  225 

18.12  Tools,  Meters  and  Testers   225 

18.120  Voltage  Testing  225 

18.121  Ammeter  227 

18.122  Megger  229 

18.123  Ohm  Meters  230 

18.13  Switch  Gear  230 

18.130  Equipment  Protective  Devices  230 

18.131  Fuses   230 

18.132  Circuit  Breakers  230 

18.133  Overload  Relays  231 

18.134  Motor  Starters   231 

ERLC 

228 


Maintenance  209 


18  14  Electric  Motors  234 

18  140  Classifications  234 

18.141  Troubleshooting   236 

18.142  Recordkeeping  236 

18.15  Auxiliary  Electrical  Power  244 

18.150  Safety  First  244 

18.151  Stanc    Power  Generation  244 

18.152  Emergency  Lighting   245 

18.153  Batteries  245 

18.16  High  Voltage  246 

18.160  Transmission   246 

18.161  Switch  Gear  246 

1 8. 1 62  Power  Distribution  Transformers  247 

18.17  Electrical  Safety  Check  List  247 

18.18  Additional  Reading  247 

LESSON  2 

18.2    Mechanical  Equipment  249 

18.20  Repair  Shop  249 

18.21  Pumps  249 

18.210  Centrifugal  Pumps  249 

1 8.21 1  Let's  Build  a  Pump  249 

18.212  Horizontal  Centrifugal  Pumps  257 

18.213  Vertical  Centrifugal  Pumps  257 

18.214  Reciprocating  or  Piston  Pumps  257 

18.215  Progressive  Cavity  (Screw-Flow)  Pumps  257 

18.216  Chemical  Metering  Pumps   258 

18.22  Lubrication  262 

1 8.220  Purpose  of  Lubrication  262 

1 8.221  Properties  of  Lubricants  262 

18.222  Lubrication  Schedule  262 

18.223  Precautions  263 

18.224  Pump  Lubrication  263 

18.225  Equipment  Lubrication  263 

LESSON  3 

18.23  Pump  Maintenance  265 

18.230  Section  Format  285 

18  231   Preventive  Maintenance  265 

1.  Pumps,  General  265 

2.  Reciprocating  Pumps,  General  272 

ER?C  229 


210  Water  Treatment 


3.  Propeller  Pumps,  General  273 

4.  Progressive  Cavity  Pumps,  Genera!   273 

5  Pump  Controls   273 

5.  Electric  Motors   274 

7  Belt  Drives  .  .    274 

8  Cham  Drives    277 

9.  Variable  Speed  Belt  Drives    278 

10  Couplings   27s 

11.  Shear  Pins   280 

18.24  Pump  Operation     282 

18.240  Starting  a  New  Pump .    282 

18.241  Pump  Shutdown   282 

18  242   Pump-Driving  Equipment   282 

18.243  Electrical  Controls   282 

18.244  Operating  Troubles    283 

18.245  Starting  and  Stopping  Pumps   284 

18.2450  Centrifugal  Pumps   284 

18.2451  Positive  Displacement  Pumps   286 

LESSON  4 

18  25  Compressors   287 

18.26  Valves     289 

18.260  Uses  of  Valves   289 

18.261  Gate  Valves    289 

18.262  Maintenance  of  Gate  Valves   291 

12.  Gate  Valves   29i 

18  263  Globe  Valves   292 

18.264  Eccentric  Valves   292 

18.265  Butterfly  Valves   292 

18.266  Check  Valves   296 

18.267  Maintenance  of  Check  Valves    305 

13.  Check  Valves    3Q5 

18.268  Automatic  Valves   3Q5 

LESSON  5 

18.3    Internal  Combustion  Engines   ^oj 

18.30  Gasoline  Engines   307 

18.300  Need  to  Maintain  Gasoline  Engines  ^07 

18.301  Maintenance   ^Qj 

18.302  Starting  Problems   3O7 

O 

ERLC 


230 


Maintenance  211 


18.303  Running  Problems      307 

18.304  How  to  Start  a  Gasoline  Engine   ...   308 

18.3040  Smali  Engines    308 

18.3041  Large  Engines  308 

18.31  Diesel  Engines  309 

18  310  How  Diesel  Engines  Work   309 

18.311   Operation  309 

18  312  Fuel  System     311 

18  313  Water-cooled  Diesel  Engines  .     311 

18.314  Air-cooled  Diesel  Engines  311 

1 8.31 5  How  to  Start  Diesel  Engines  311 

18  316  Maintenance  and  Troubleshooting    311 

18  32  Cooling  Systems  313 

18  33  Fuel  Storage   315 

18.330  Code  Requirements   315 

18.331  Diesel   315 

18.332  Gasoline  315 

18.333  Liquified  Petroleum  Gas  (LPG)   316 

18  334  Natural  Gas  316 

18.34  Standby  Engines  316 

18.4  Chemical  Storage  and  Feeders  316 

18.40  Chemical  Storage   316 

18.41  Drainage  from  Chemical  Storage  and  Feeders   317 

18.42  Use  of  Feeder  Manufacturer's  Manual  317 

18.43  Solid  Feeders   317 

18.44  Liquid  Feeders    317 

18.^0  Gas  Feeders  317 

18.46  Calibration  of  Chemical  Feeders     317 

1 8.460   Large-Volume  Metering  Pumps  317 

18  461    Small-Volume  Metering  Pumps  317 

1 8  462  Dry-Chemical  Systems  317 

18.47  Chlorinators  320 

18.5  Tanks  and  Reservoirs  321 

18.50  Scheduling  Inspections  321 

18.51  Steel  Tanks  ....321 

18.52  Cathodic  Protection  321 

18.53  Concrete  Tanks  321 

18.6  Building  Maintenance   321 

ERIC  231 


112  Water  Treatment 


18.7  Arithmetic  Assignment 

18.8  Additional  Reading 

18.9  Acknowledgments  . 
Suggested  Answers 
Objective  Test   


322 
322 
322 
323 
327 


er|c 


Maintenance  213 


OBJECTIVES 

Chapter  18.  MAINTENANCE 


Following  completion  of  Chapter  18,  you  should  be  able 
to: 

1  Develop  a  maintenance  program  for  your  plant,  includ- 
ing equipment,  buildings,  grounds,  channels,  and  tanks; 

2.  Start  a  maintenance  recordkeeping  system  that  wiil 
provide  you  with  information  to  protect  equipment  war- 
ranties, to  prepare  budgets,  and  to  satisfy  regulatory 
agencies; 

3.  Schedule  maintenance  of  equipment  at  proper  time 
intervals; 

4.  Perform  maintenance  as  directed  by  manufacturers; 

5.  Recognize  symptoms  that  indicate  equipment  is  not 
performing  properly,  identify  the  source  of  the  problem, 
and  take  corrective  action; 

6.  Recognize  the  serious  consequences  that  could  occur 
when  inexperienced,  unqualified  or  unauthorized  per- 
sons attempt  to  troubleshoot  or  repair  electnca!  panels, 
controls,  circuits,  wiring  or  equipment; 

7.  Communicate  with  electricians  by  indicating  possible 
causes  of  problems  in  electrical  panels,  controls,  cir- 
cuits, wiring,  and  motors; 

8  Properly  select  and  use  the  following  pieces  of  equip- 
ment (if  qualified  and  authorized): 

a.  Voltage  tester. 

b.  Ammeter, 

c.  Megger,  and 

d.  Ohm  meter; 

9.  Safely  operate  and  maintain  auxiliary  electrical  equip- 
ment, including  during  standby  and  emergency  situa- 
tions; 

10.  Descnbe  how  a  pump  is  put  together; 

11.  Discuss  the  application  or  use  of  different  types  of 
pumps; 

12.  Star*  and  stop  pumps; 

13.  Maintain  the  various  types  of  pumps; 

14.  Operate  and  maintain  a  compressor; 

15.  Develop  and  conduct  an  equipment  lubrication  pro- 
gram; and 

16.  Start  up,  operate,  maintain  and  shut  down  gasoline 
engines,  diesel  engines,  heating,  ventilating  and  air 
conditioning  systems. 

NOTE:  Special  maintenance  information  is  given  in  the  pre- 
vious chapters  on  treatment  processes  where  appro- 
pnate. 

^  Jo 


214  Water  Treatment 


GLOSSARY 

Chapter  18.  MAINTENANCE 


AIR  GAP 

A.i  open  vertical  drop,  or  vertical  empty  space,  that  sepa- 
rates a  drinking  (potable)  water  supply  to  be  protected  from 
another  system  in  a  water  treatment  plant  or  other  location. 
This  open  gap  prevents  the  contamination  of  drinking  water 
by  backsiphonage  or  backflow  because  there  is  no  way  raw 
water  or  any  other  water  can  reach  the  drinking  water. 


DRINKING 
WATER 


AIR  GAP 


ALTERNATING  CURRENT  (A.C.] 


ALTERNATING  CURRENT  (A.C.] 


An  electric  current  that  reverses  its  direction  (positive/negative  values)  at  regular  intervals. 
AMPERAGE  (AM-purr-age)  AMPERAGE 

The  strength  of  an  electric  current  measured  in  amperes.  The  amount  of  electric  current  flow,  similar  to  the  flow  of  water  in  gal- 
lons per  minute.  ^ 

AMPERE  (AM-pesr)  AMPERE 

The  unit  usee  to  measure  current  strength  The  current  produced  by  an  electromotive  force  of  one  volt  acting  through  a  resis- 
tance of  one  ohm.  ^  ^ 

AMPLITUDE  AMPLITUDE 
The  maximum  strength  of  an  alternating  curren.  dunng  its  cycle,  as  distinguished  from  the  mean  or  effective  strength. 

AXIAL  TO -MPELLER  AXIAL  TO  IMPELLER 

The  direc'fjn  in  which  materia!  being  pumped  flows  around  the  impeller  or  parallel  to  the  impeller  shaft. 

AXIS  OF  IMPELLER  AXIS  OF  IMPELLER 

An  imaginary  line  running  along  the  center  of  a  shaft  (such  as  an  impeller  shaft). 

BRINELLING  (bruh-NEL-ing)  BRINELLING 
Tiny  indentations  (dents)  high  on  the  shoulder  of  the  bearing  race  or  bearing.  A  type  of  beanng  failure. 

CATHODIC  PROTECTION  (ca-THOD-ick)  CATHODIC  PROTECTION 

An  electrical  system  ior  prevention  of  rust,  corrosion,  and  pitting  of  metal  surfaces  which  are  in  contact  with  water  or  soil.  A 
low-voltage  current  is  made  to  flow  through  a  liquid  (water)  or  a  soil  in  contact  with  the  metal  in  such  a  manner  that  the  external 
electromotive  force  renders  the  metal  structure  cathodlc.  This  concentrates  corrosion  on  auxiliary  anodic  parts  which  are  delib- 
erately allowed  to  corrode  instead  of  letting  the  structure  corrode. 


CAV;  ."ATION  (CAV-uh-TAY-shun) 

The  formation  and  collapse  of  a  gas  pocket  or  bubble  on  the  blade  of  an  impeller  or  the  gate  of  a  valve.  The  collapse  of  this  qas 
pocket  or  bubble  drives  water  into  the  impeller  or  gate  with  a  terrific  force  that  can  cause  pitting  on  the  impeller  or  gate  surface 
Cavitation  is  accompanied  by  loud  noises  that  sound  like  someone  is  pounding  on  the  impeller  or  gate  with  a  hammer. 

C'RCU'T  CIRCUIT 

The  complete  path  of  an  electric  current,  including  the  generating  apparatus  or  other  source,  or,  a  specific  segment  or  section 
of  the  complete  pith.  " 


■Jit 


CAVITATION 


Maintenance  215 


CIRCUIT  BREAKER  CIRCUIT  BREAKER 

A  safety  device  in  an  elBCtrica!  circuit  that  automatically  shuts  off  the  circuit  when  it  becomes  overloaded.  The  device  can  be 
manually  reset. 

CONDUCTOR  CONDUCTOR 
A  substance,  body,  device  or  wire  that  readily  conducts  or  carries  electrical  current. 

COULOMB  (COO-lahm)  COULOMB 

A  measurement  of  the  amount  of  electncal  charge  conveyed  by  an  electnc  current  of  one  ampere  in  one  second.  One  coulomb 
equals  about  6.25  x  10^^  electrons  (6,250,000,000,000,000,000  electrons). 

CROSS-CONNECTION  CROSS-CONNECTION 

A  connection  between  a  drinking  (potable)  water  system  and  an  unr^pprovea  water  supply.  For  example,  if  you  have  a  pump 
moving  non-potable  water  and  hook  into  the  drinking  water  system  to  supply  water  for  the  pump  seal,  a  cross-connection  or 
mixing  between  the  two  water  systems  can  occur.  This  mixing  may  lead  to  contamination  of  the  drinking  water. 

CURRENT  CURRENT 

A  movement  or  flow  of  electricity.  Water  flowing  in  a  pipe  is  measured  in  gallons  per  second  past  a  certain  point,  not  by  the 
number  of  water  molecules  going  past  a  point.  Electric  current  is  measured  by  the  number  of  coulombs  per  second  flowing  past 
a  certain  point  in  a  conductor.  A  coulomb  is  equal  to  about  6.25  x  10^®  electrons  (6,250,000,000,000,000,000  electrons).  A  flow 
of  one  coulomb  per  second  is  called  one  ampere,  the  unit  of  the  rate  of  flow  of  current. 

CYCLE  CYCLE 
A  complete  alternat;on  of  voltage  and/or  current  in  an  alternating  current  (A.C.)  circuit. 

DATEOMETER  (day-TOM-uh-ter)  DATEOMETER 

A  small  calendar  disc  attached  to  motors  and  equipment  to  indicate  the  year  in  which  the  last  maintenance  service  was  per- 
formed. 

DIRECT  CURRENT  (D.C.)  DIRECT  CURRENT  (D.C.) 

Electrical  current  flowing  in  one  direction  only  a"d  essentially  free  from  pulsation. 

ELECTROLYTE  (ee-LECK-tro-LIGHT)  ELECTRo^  HE 

A  substance  which  dissociates  (separates)  into  two  or  more  ions  when  it  is  dissolved  in  v/ater. 

ELECTROMOTIVE  FORCE  (E.M.F.)  ELECTROMOTIVE  FORCE  (E.M.F.) 

The  electrical  pressure  available  to  cause  a  i\o/j  of  current  (amperage)  when  an  electrical  circuit  is  closed.  See  VOLTAGE. 

ELECTRON  ELECTRON 
An  extremely  small,  negatively-charged  particle,  the  part  of  an  atom  that  determines  its  chemical  properties, 

END  BELLS  END  BELLS 

Devices  used  to  hold  the  rotor  and  stator  of  a  motor  in  position. 

FUSE  FUSE 

A  protective  device  having  a  strip  or  wire  of  fus.b(ci  metal  which,  when  placed  in  a  circuit,  will  melt  and  break  the  electrical  circuit 
if  heated  too  much.  High  temperatures  v/iH  develop  in  ..he  fuse  when  a  current  flows  through  the  fuse  in  excess  of  that  which  the 
current  will  carry  safely. 

GROUND  GROUND 

An  expression  representing  an  electrical  connection  to  earth  or  a  large  conductor  which  is  at  the  earth's  potential  or  neutral 
voltage. 

HERTZ  (HUR^S)  HERTZ 

The  number  of  complete  electromagnetic  cycles  or  waves  in  one  second  of  an  electncal  or  electronic  circuit.  Also  called  the  fre- 
quency of  the  current.  Abbreviated  Hz. 

HYGROSCOPIC  (HI-grow-SKOP-ick)  HYGROSCOPIC 
Absorbing  or  attracting  moisture  from  the  air. 

JOGGING  JOGGING 
The  frequent  etarting  and  stopping  of  an  electric  motor. 


23-.; 


216  Water  Treatment 


LEAD  (LEE-d)  LEAD 
A  wire  0.  conductor  that  can  carry  electricity. 

MANDREL  (MAN-drill)  MANDREL 
A  special  tool  used  to  push  beanngs  in  or  to  pull  sleeves  out. 

MEG  I^EG 

A  procedure  used  for  checking  the  insulation  resistance  on  motors,  feeders,  buss  bar  systems,  grounds,  and  branch  circuit  wir- 
ing. Also  see  MEGGER. 

MEGGER  (from  megohm)  MEGGER 

An  instrument  used  for  checking  the  insulation  resistance  on  motors,  feeders,  buss  bar  systems,  ground,  and  branch  circuit 
wiring.  Also  see  MEG 

MEGOHM  MEGOHM 
Meg  means  one  million,  so  5  megohms  means  5  million  ohms.  A  megger  reads  in  millions  of  ohms. 

MULTI-STAGE  PUMP  MULTI-STAGE  PUMP 

A  pump  that  has  more  than  one  impeller.  A  single-stage  pump  has  one  Impeller. 

OHM  OHM 
The  unit  of  electrical  resjstance  The  resistance  of  a  conductor  in  which  one  volt  produces  a  current  of  one  ampere. 

POLE  SHADER  POLE  SHADER 

A  copper  bar  circling  the  laminated  Iron  core  inside  the  coil  of  a  magnetic  starter. 

POWER  FACTOR  pOWER  FACTOR 

The  ratio  of  the  true  power  passing  through  an  electric  circuit  to  the  prodj'-t  of  the  voltage  and  amperage  in  the  circuit.  This  is  a 
measure  of  the  lag  or  load  of  the  current  with  respect  to  the  voltage.  In  altemating  current  the  voltage  and  ampere'  are  not 
always  in  phase;  therefore,  the  true  power  may  be  slightly  less  than  that  determined  by  the  direct  product. 

PRUSSIAN  BLUE  PRUSSIAN  BLUE 

A  blue  paste  or  liquio  (often  on  a  paper  like  carton  paper)  used  to  show  a  contact  area.  Used  to  determine  if  gate  valve  seats  fit 
properly. 

RADIAL  TO  IMPELLER  RADIAL  TO  IMPELLER 

Perpendicular  to  the  impeller  shaft.  Material  being  pumped  flows  at  rinht  angle  to  the  impeller. 

RESISTANCE  RESISTANCE 

That  property  of  a  conductor  or  wire  that  opposes  the  passage  of  a  current,  thus  causing  electrical  energy  to  be  transformed 
into  heat. 

ROTOR  ROTOR 
The  rotating  part  of  a  machine.  The  rotor  is  surrounded  by  the  stationary  (non-moving)  parts  (stator)  of  the  machine. 

SEIZE  UP  SEIZE  UP 

Seize  up  occurs  when  an  engine  overheats  and  a  part  expands  to  'he  point  where  the  engine  will  not  run.  Also  called  "freezing." 

SHEAVE  (SHE-v)  SHEAVE 
V-belt  drive  pulley  which  is  commonly  made  of  cast  iron  or  steel. 

SHIM  SHIM 

Thin  metal  sheets  wnich  are  inserted  between  two  surfaces  to  align  or  space  the  surfaces  correctly.  Shims  can  be  used  any- 
where a  spacer  is  needed.  Usually  shims  are  0.001  to  0.020  inches  tnick. 

SINGLE-STAGE  PUMP  SINGLE-STAGE  PUMP 

A  pump  that  has  only  one  impeller.  A  multi-stage  pump  has  more  than  one  impeller. 

STATOR  STATOR 
That  portion  of  a  machine  which  contains  the  stationary  (non-moving)  parts  that  surround  the  moving  parts  (rotor). 


Maintenance  217 


STETHOSCOPE  STETHOSCOPE 
An  instrument  used  to  magnify  sounds  and  convey  them  to  the  ear. 

VOLTAGE  VOLTAGE 

The  electrical  pressure  available  to  cause  a  flow  of  current  (amperage)  when  an  electrical  circuit  is  closed.  See  ELECTROMO- 
TIVE FORCE  (E.M.F.). 

WATER  HAMMER  WATER  HAMMER 

The  sound  like  someone  hammering  on  a  pipe  that  occurs  when  a  valve  is  opened  or  closed  very  rapidly  When  a  valve  position 
IS  changed  quickly,  the  water  pressure  in  a  pipe  will  increase  and  decrease  back  and  forth  very  quickly.  This  rise  and  fall  in 
pressure  can  do  serious  damage  to  the  system. 


237 


218  Water  Treatment 


I 


9 


CHAPTER  18.  MAINTENANCE 

(Lesson  1  of  5  Lessons) 


1 8.0   TREATMcNT  PLANT  MAINTENANCE  —  GENERAL 
PROGRAM 

A  water  treatment  plant  operator  has  many  duties.  Most  of 
them  have  to  do  with  the  efficient  operation  of  the  plan.  An 
operator  has  the  responsibility  to  produce  a  water  that  will 
meet  all  the  requ  -ements  established  for  the  plant.  By  doing 
this,  the  operator  develops  a  good  working  relationship  with 
the  regulatory  agencies,  water  users,  and  plant  neighbors. 

Another  duty  an  operator  has  is  that  of  PLANT  MAINTE- 
NANCE. A  good  maintenance  program  is  a  must  in  order  to 
maintain  successful  operation  of  the  plant.  A  successful 
maintenance  program  will  cover  everything  from  mechanical 
equipment  to  the  care  of  the  plant  grounds,  buildings,  and 
structures, 

Mechanical  maintenance  is  of  prime  importance  as  the 
equipment  must  be  kept  in  good  operating  ccr.Jitlon  in  order 
for  the  plant  to  maintain  peak  performance.  Manufacturers 
provide  information  on  the  mechanical  maintenance  of  their 
equipment.  You  should  thoroughly  read  their  literature  on 
your  plant  equipment  and  UNDERSTAND  the  procedures. 
Contact  the  mar  ifacturer  or  the  local  representative  if  you 
have  any  questions  Follow  the  instructions  very  carefully 
when  performing  maintenance  on  equipment.  You  also  must 
recognize  tasks  that  may  be  beyond  your  capabilities  or 
repair  facilities,  and  you  should  request  assistance  when 
needed. 

For  a  successful  maintenance  program,  your  supervisors 
must  understand  the  need  for  and  benefits  from  equipment 
that  operates  continuously  as  intended  Disabled  or  improp- 
erly working  equipment  is  a  threat  to  the  quality  of  the  plant 
output,  and  repair  costs  for  poorly  maintained  equipment 
usually  exceed  the  cost  of  maintenance. 

18.00  Preventive  Maintenance  Record 

Preventive  programs  help  operating  personnel  keep 
equipment  in  satisfactory  operating  condition  and  aid  in 
detecting  and  correcting  malfunctions  before  they  develop 
into  major  problems. 

A  frequent  occurrence  in  a  preventive  maintenance  pro- 
gram is  the  failure  of  the  operator  to  record  the  work  after  it 
is  completed.  When  this  happens  the  operator  must  rely  on 
memory  to  know  when  to  perform  each  preventive  mainte- 
nance function.  As  days  pass  into  weeks  and  months,  the 
preventive  maintenance  program  Is  lost  in  the  turmoil  of 
everyday  operation. 

The  only  way  an  operator  can  keep  track  of  a  preventive 
maintenance  program  is  by  GOOD  RECORDKEEPING. 
Wh.'  ever  record  system  is  used,  it  should  be  kept  up  to  date 
on  aily  basis  and  not  left  to  memory  for  some  other  time. 
Equipment  service  record  cards  (Figure  1 8.1 )  are  easy  to  set 
up  and  require  little  time  to  keep  up  to  date. 

ERIC 


An  EQUIPMENT  SERVICE  CARD  (master  card)  should  be 
filled  out  for  each  piece  of  equipment  in  the  plant.  Each  card 
should  have  the  equipment  name  on  it,  such  as  Raw  Water 
Intake  Pump  No.  1 

1  List  each  required  maintenance  service  with  an  item 
number, 

2  List  maintenance  services  in  order  of  frequency  of  per- 
formance. For  instance,  show  daily  service  as  Items  1,2, 
and  3  on  the  card;  weekly  items  as  4  and  5;  mof  ithly  items 
as  6,  7,  8,  and  9;  and  so  on. 

Describe  each  type  of  service  under  work  to  be  done. 

Make  sure  all  necessary  inspections  and  services  are 
shown.  For  reference  data,  list  paragraph  or  section  num- 
bers as  shown  in  the  pump  maintenance  section  of  this 
lesson  (Section  18.23,  p.  265)  Also  list  frequency  of  service 
as  shown  in  the  time  schedule  columns  of  tl  j  same  section. 
Under  time,  enter  day  or  month  service  is  due.  Service  card 
information  may  be  changed  to  fit  the  needs  of  your  plant  or 
particular  equipmen'  as  recommended  by  the  equipment 
manufacturer.  Be  oure  the  information  on  the  cards  is 
complete  and  correct. 

The  SERVICE  RECORD  CARD  should  have  the  date  and 
work  done,  listed  by  item  number  and  signed  by  the  operator 
who  p<^rformed  the  service.  Some  operators  prefer  to  keep 
both  cards  clipped  together, -while  otners  place  the  service 
record  card  near  the  equipment. 

When  the  service  record  is  filled,  it  should  be  filed  for 
future  reference  and  a  new  card  attached  to  the  master  card. 
The  EQUIPMENT  SERVICE  CARDXeWs  what  should  be  done 
and  when,  while  the  SERVICE  RECORD  CARDis  a  record  of 
what  you  did  and  when  you  did  it. 

1 8.01   Library  of  Manufacturers*  Operation  and  Parts 
Manuals 

A  plant  library  can  contain  helpful  information  to  assist  in 
plant  operation.  Material  m  the  library  should  be  cataloged 
and  filed  for  easy  use.  Items  in  the  library  should  include: 


238 


Maintenance  219 


EQUIPMENT  SERVICE  CARD 

EQUIPMENT.  #1  Raw  Water  Intake  Pump 

Item  No. 

Work  to  be  Done 

Reference*^ 

Time 

1 

Check  water  seal  and  packing  qiand 

Par.  1 

Daily 

2 

Listen  for  u  jsuai  noises 

Par.  6 

Daily 

3 

Operate  pump  alternately 

Par.  1 

Wppklv 

1 VI  ^1  ivjcx  y 

4 

Inspect  pump  assembly 

Par.  1 

Weekly 

Wednesday 

5 

Inspect  and  lube  bearings 

Par.  1 

Quarterly 

1-4-7-10^ 

6 

Check  operating  temperature  of  bearings 

Par.  1 

Quarterly 

1-4-7-10^ 

7 

Check  alignment  of  pump  and  motor 

Par.  1 

Semi-Ann. 

4  &10 

8 

Inspect  and  service  pumps 

Par.  1 

Semi-Ann. 

4  &  10 

9 

Dram  pump  before  shutdown 

Par.  1 

SERVICE  RECORD  CARD 

EQUIPMENT:  #1  Raw  Water  Intake  Pump 

Date 

Work  Done 
(Item  No.) 

Signed 

Date 

Work  Done 
(Item  No.) 

Signed 

1-5-84 

1-2-3 

J.B. 

1-6-84 

1-2 

J.B. 

1-7-84 

1-2-4-5-6 

R.W. 

a  Par.  1  refers  to  Paragraph  1  in  Section  18.23  of  this  manual  Par.  6  is  also  in  Section  18.23. 

b  1-4-7-10  represent  the  months  of  the  year  when  the  equipment  should  be  serviced  —  1 -January,  4-April,  7-July.  and  10-October. 


^  Fig.  18. 1   Equipment  service  card  and  service  record  card 

ERIC 


'^3  J 


220  Water  Treatment 


1.  Plant  operation  and  maintenance  instruction  manuals, 

2.  Plant  plans  and  specifications, 

3.  Manufacturers'  instructions, 

4.  Reference  books  on  water  treatment, 

5.  Professional  journals  and  publications, 

6.  First-aid  book, 

7.  Reports  from  other  plants,  and 

8.  A  dictionary. 

18.02  Emergencies 

If  your  plant  has  not  developed  procedures  for  handling 
potential  emergencies,  do  it  NOW.  Emergency  procedures 
must  be  established  for  operators  to  follow  when  emergen- 
cies are  caused  by  the  release  of  chlorine,  hazardous  or 
toxic  chemicals  into  the  raw  water  supply,  power  outages  or 
broken  transmission  lines  or  distribution  mains.  These  pro- 
cedures should  include  a  list  of  emergency  phone  numbers 
located  near  a  telephone  that  is  unlikely  to  be  affected  by  the 
emergency. 

1.  Police 

2.  Fire 

3.  Hospital  and/or  Physician 

4.  Responsible  Plant  Officials 

5.  Local  Emergency  Disaster  Office 

6.  CHEMTREC  (800)  424-9300 

7.  Emergency  Team  (if  your  plant  has  one) 

The  CHEMTREC  toll-free  number  may  be  called  at  any 
time.  Personnel  at  this  number  will  give  information  on  how 
to  handle  emergencies  created  by  hazardous  materials  and 
will  notify  appropriate  emergency  personnel. 

An  emergency  team  for  your  plant  may  be  trained  and 
assigned  the  task  of  responding  to  SPECIFIC  EMERGEN- 
CIES such  as  chlorine  leaks.  This  emergency  team  must 
meet  the  following  strict  specifications  at  all  times. 

1 .  Team  personnel  must  be  physically  and  mentally  quali- 
fied. 

2.  Proper  equipment  must  be  available  at  all  times,  includ- 
ing: 

a.  Protective  equipment,  including  self-contained  breath- 
ing apparatus, 

b.  Repair  kits,  and 

c.  Repair  tools. 

3.  Proper  training  must  take  place  on  a  regular  basis  and 
include  instruction  about: 

a.  Properties  and  detection  of  hazardous  chemicals, 

b.  Safe  procedures  for  handling  and  storage  of  chemi- 
cals, 

c.  Types  of  containers,  safe  procedures  for  shipping 
containers,  and  container  safety  de*-ices,  and 

d.  Installation  of  repair  devices. 

4.  Team  members  must  be  exposed  regularly  to  simulated 
field  emergencies  or  practice  dnils.  Team  response  must 

ERIC 


be  carefully  evaluated  and  any  errors  or  weaknesses 
corrected 


5  Emergency  team  performance  must  be  reviewed  annually 
on  a  specified  date.  Review  must  include: 

a.  Training  program, 

b.  Response  to  actual  emergencies,  and 

c.  Team  physical  and  mental  examinations. 

WARNING.  One  person  should  never  be  permitted  to  at- 
tempt an  emergency  repair  alone.  Always  wait 
for  trained  assistance.  Valuable  time  could  be 
lost  rescuing  a  foolish  Individual  rather  than 
repairing  or  correcting  a  serious  emergency. 

For  additional  information  on  emergencies,  see  Chapter  7, 
Disinfection,  Section  7.52,  "Chlorine  Leaks,"  Chapter  10, 
Plant  Operation,  Section  10.9,  "Emergency  Conditions  and 
Procedures,"  and  Chapter  23,  Administration,  Section  23  3, 
"Contingency  Planning  for  Emergencies."  Chapter  23  con- 
tains information  on  what  to  do  if  a  toxic  substance  gets  into 
your  water  supply. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  323. 

18.0A  Why  should  you  plan  a  gov-d  maintenance  program 
for  your  treatment  plant? 

18.0B  What  general  items  would  you  include  in  your  mainte- 
nance program? 

18.0C  Why  should  you  have  a  good  recordkeeping  system 
for  your  maintenance  program*? 

18.0D  What  is  the  difference  between  an  EQUIPMENT 
SERVICE  CARD  and  SERVICE  RECORD  CARD? 

18  OE  Prepare  a  lis\    emergency  phone  numbers  for  your 
treatment  plant. 

18  OF  What  Items  should  be  included  in  the  training  pro- 
gram for  an  emergency  team? 

18.1    ELECTRICAL  EQUIPMENT 

18.10  Beware  of  Electricity 

18,100  Attention 

A.  DO  NOT  ATTEMPT  TO  INSTALL,  TROUBLESHOOT, 
MAINTAIN,  REPAIR  OR  REPLACE  ELECTRICAL  EQUIP- 

2-io 


Maintenance  221 


MENT,  PANELS,  CONTROLS,  WIRING  OR  CIRCUITS 
UNLESS  YOU 

1   KNOW  WHAT  YOU  ARE  DOING, 

2.  ARE  QUALIFIED,  AND 

3.  ARE  AUTHORIZED. 

Sect.on  1811,  Electrical  Fundamentals,  is  presented  to 
provide  you  with  an  understanding  and  awareness  of 
electricity.  THE  PURPOSE  OF  THE  SECTION  IS  TO 
HELP  YOU  PROVIDE  ELECTRICIANS  WITH  THE  INFOR- 
MATION THEY  WILL  NEED  WHEN  YOU  CONTACT 
THEM  AND  REQUEST  THEIR  ASSISTANCE.  YOU  MUST 
BE  EXTREMELY  FAMILIAR  WITH  ELECTRICITY  BE- 
FORE  ATTEMPTING  ANY  MAJOR  REPAIRS. 

B.  Due  to  the  wide  variety  of  equipment  and  manufacturers, 
in  the  water  treatment  field,  detailed  procedures  for  the 
maintenance  of  some  types  of  equipment  were  very 
difficult  to  include  in  this  chapter.  Also  manufacturers  are 
continually  improving  their  products  and  some  details 
would  soon  be  out  of  date  FOR  DETAILS  CONCERNING 
THE  OPERATION,  MAINTENANCE  AND  REPAIR  OF  A 
PARTICULAR  PIECE  OF  EQUIPMENT  REFER  TO  THE 
O  &  INSTRUCTIONS  MANUAL  OR  CONTACT  THE 
MANUFACTURER. 

C  Effective  equipment  maintenance  is  the  key  to  successful 
system  performance.  The  better  your  maintenance,  the 
better  your  facilities  will  perform.  Abuse  your  equipment 
and  facilities  and  they  will  abuse  you  Everyone  must 
realize  that  if  the  equipment  can't  work,  no  one  can  work 

18. 101  Recognize  Your  Limitations 

In  the  water  departments  of  all  cities,  there  is  a  need  for 
maintenance  operators  to  know  something  about  electricity. 
Duties  could  range  from  repairing  a  tail  light  on  a  trr'ler  or 
vehicle  to  repairing  complex  pump  controls  and  motors 
VERY  FEW  MAINTENANCE  OPERATORS  DO  THE  ACTU- 
AL ELECTRICAL  REPAIRS  OR  TROUBLESHOOTING  BE- 
CAUSE THIS  IS  A  HIGHLY  SPECIALIZED  FIELD  AND 
UNQUALIFIED  PEOPLE  CAN  SERIOUSLY  INJURE  THEM- 
SELVES AND  DAMAGE  COSTLY  EQUIPMENT.  For  these 
reasons,  you  must  be  familiar  with  electricity,  KNOW  THE 
HAZARDS,  and  RECOGNIZE  YOUR  OWN  LIMITATIONS 
when  you  must  work  with  electrical  equipment. 


1^ 


Most  municipalities  employ  electncians  or  contract  with  a 
commercial  electrical  company  that  they  call  when  major 
problems  occur.  However,  the  maintenance  operator  should 
be  able  to  EXPLAIN  HOW  THE  EQUIPMENT  IS  SUPPOSED 
TO  WORK  AND  WHAT  IT  IS  DOING  OR  IS  NOT  DOING 
WHEN  IT  FAILS.  Aftfir  studying  this  section,  you  should  be 
able  to  tell  an  electrician  what  appears  to  be  the  problem 
with  electrical  panels,  controls,  circuits  and  equipment. 

The  need  for  safety  should  be  apparent.  If  proper  safe 
procedures  are  not  followed  in  operating  and  maintaining 
the  various  electrical  equipment  used  in  water  treatment 
facilities,  accidents  can  happen  that  cause  injuries,  perma- 
nent disability,  or  loss  of  life.  Some  of  the  serious  accidents 
that  have  happened  and  could  have  been  avoided  occurred 
when  machinery  was  not  shut  off,  locked  out,  and  tagged 
properly  (Figure  18.2)  Possible  accidents  include: 

1.  Maintenance  operator  could  be  cleaning  pump  and  have 
It  start,  thus  losing  an  arm,  hand,  or  finger, 

2  Electrical  motors  or  controls  not  properly  grounded  could 
lead  to  possible  severe  shock,  paralysis,  or  death,  and 

3  Improper  circuits  such  as  a  wrong  connection,  safety 
devices  jumped,  wrong  fuses,  or  improper  wiring  can 
cause  fires  or  injuries  due  to  incorrect  operation  of 
machinery 

Another  consideration  for  having  a  basic  working  knowl- 
edge of  electricity  is  to  prevent  financial  losses  resulting 
from  motors  burning  out  and  from  damage  to  equipment, 
machinery  and  control  circuits.  Additional  costs  result  when 
damages  have  to  be  repaired,  including  payments  for  out- 
side labor 

 .     WARNING  I  


PiNlC^^UTfMHAT  VOU  C?^MT  ^hi^Wl  fi^^^UT 


QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  cr-^pare  your 
answers  v^ith  those  on  page  323 

18.10A  Why  must  unqualified  or  inexperienced  people  be 
extremely  careful  when  attempting  to  Iroubleshoot 
or  repair  electrical  equipment*? 

1 8. 1 0B  What  could  happen  when  machinery  is  not  shut  off, 
locked  out,  and  tagged  properly? 

18.11   Electrical  Fundamentals 

18.110  introduction 

This  section  contains  a  basic  Introduction  to  electrical 
terms  and  information  plus  directions  on  how  to  trouble- 
shoot  problems  with  electrical  equipment. 

Most  electrical  equipment  used  in  water  treatment  plants 
IS  labeled  with  name  plate  information  indicating  the  proper 
voltage  and  allowable  current  In  amps. 

18.111  Volts 

Voltage  (E)  Is  also  known  as  Electromotive  Force  (E.M.F.), 
and  IS  the  electrical  pressure  available  to  couse  a  flow  of 


ERIC 


24.1 


222  Water  Treatment 


DANGEK 


MAN 
WORKING 
ON  LINE 


DO  NOT  CLOSE  THIS 
SWITCH  WHILE  THIS 
TAG  IS  DSSPLAYED 

SIGNATURE 

This  IS  the  ONLY  person  authorized  to  remove  this  tag 


Note:  Tag  also  should  include:  TIME  OFF 

DATE  


Fig.  16.2  Typical  warning  tag 

(Source  industrial  Indemnity/industrial  Underwnters/lnsurance  Cos  ) 

ER?C  242 


Maintenance  223 


current  (amperage)  when  an  electrical  circuit  is  closed.^  This 
pressure  can  be  compared  with  the  pressure  or  force  that 
causes  water  to  flow  in  a  pipe  Some  pressure  in  a  water 
pipe  IS  required  to  make  the  water  move  The  same  is  true  of 
electricity.  A  force  is  necessary  to  push  electricity  or  electnc 
current  through  a  wire  This  force  is  called  voltage.  There 
are  two  types  of  current  Direct  Current  (D  C )  and  Alternat- 
ing Current  (A.C.). 

18. 1 12  Direct  Current  (D,C,) 

Direct  Current  (D.C )  flows  in  one  direction  only  and  is 
essentially  free  from  pulsation.  Direct  current  is  seldom  used 
in  water  treatment  plants  except  m  electronic  equipment, 
some  control  components  of  pump  dnves  and  stand-by 
lighting  Direct  current  is  used  exclusively  i  automotive 
equipment,  certain  types  of  welding  equipment,  and  a  vari- 
ety of  portable  equipment.  Direct  current  is  found  in  various 
voltages  such  as  6  volts,  1 2  volts,  24  volts,  48  volts,  and  1 1 0 
volts  All  batteries  are  direct  current.  D.C.  voltage  can  be 
measured  by  holding  the  positive  and  negative  leads  of  a 
D  C  voltmeter  on  the  corresponding  terminals  of  the  D.C. 
device  such  as  a  battery.  Direct  current  usually  is  not  found 
in  higher  voltages  (over  24  volts)  around  plants  except  in 
motor-generator  sets.  Care  must  be  taken  when  installing 
battery  cables  and  wiring  that  Positive  (-f )  and  Negative  (-) 
poles  are  connected  properly  to  wires  marked  (-f )  and  (-).  If 
not  properly  connected,  you  could  get  an  arc  of  electricity 
across  the  unit  that  could  cause  an  explosion 

18. 1 13  Alternating  Current  (A.C.) 

An  alternating  current  circuit  Is  one  in  which  the  voltage 
and  current  periodically  change  direction  and  AMPLITUDE.^ 
In  other  words,  the  current  goes  from  zero  to  maximum 
strength,  back  to  zero  and  to  the  same  strength  in  the 
opposite  direction.  Most  A.C.  circuits  have  a  frequency  of  60 
CYCLES^  per  second.  "Hertz"  Is  the  term  we  use  to  describe 
the  frequency  of  cycles  completed  per  second  so  our  A.C. 
voltage  would  be  60  Hertz  (Hz). 

Alternating  current  is  classified  as: 

a.  Single  phase, 

b.  Two  phase,  and 

c  Three  phase,  or  polyphase. 

The  most  common  of  these  are  single  phase  and  three 
phase.  The  various  voltages  you  probably  will  find  on  your 
job  are  1 1 0  volts,  120  volts,  208  volts,  220  volts,  240  volts, 
277  volts,  440  volts,  480  volts,  2400  volts  and  4160  volts. 


Single-phase  power  is  found  in  lighting  systems,  small 
pump  motors,  various  portable  tools  and  throughout  our 
homes  This  power  is  usually  120  volts  and  sometimes  240 
volts  Single  phase  means  that  only  one  phase  of  power  is 
supplied  to  the  mam  electrical  panel  at  240  volts  and  has 
three  wires  or  leads.  Two  of  these  leads  have  120  volts 
each,  the  other  lead  is  neutral  and  usually  is  coded  white. 
The  neutral  lead  is  grounded.  Many  appliances  and  power 
tools  have  an  extra  ground  (commonly  a  green  wire)  on  the 
case  for  additional  protection. 

Thiee-phase  power  is  generally  used  with  motors  and 
transformers  found  in  water  treatment  plants,  and  usually  is 
208,  220,  240  volts,  or  440,  460,  480  and  550  volts.  Higher 
voltages  are  used  in  sone  pump  stations.  T^  ree  phase  is 
used  when  higher  power  requirements  or  larger  motors  are 
used  because  efficiency  is  usually  higher  and  motors  require 
less  maintenance.  Generally  speaking,  all  motors  above  two 
horsepower  are  three  phase  unless  there  is  a  problem  with 
the  power  company  getting  three  phase  to  the  installations. 
Three-phase  power  usually  is  brought  in  to  the  point  of  use 
with  three  leads.  There  is  power  on  all  three  leads  and  the 
fuse  switches  will  generally  appear  as  shown  in  Figure  18.3. 


Fig.  16.3  Fuse  switches 

(Courtesy  of  Consolidated  Electrical  Distributors,  inc ) 


When  making  voltage  measurements  on  three-phase 
power  circuits,  take  three  readings:  (1)  between  lead  1  and 
lead  2,  (2)  between  1  and  3,  and  (3)  between  2  and  3.  The  im- 
balance between  readings  should  not  exceed  five  percent  of 
the  average  of  the  three  readings  and  the  average  should 
not  be  below  the  nominal  voltage  (20P  220,  240,  460)  nor 
should  It  exceed  the  nominal  voltage  by  more  than  five 
percent.  Voltages  that  do  not  meet  these  limits  will  place 
undue  stress  on  electrical  equipment,  especially  motors. 


^  Electnaans  often  talk  about  .:oS'ng  an  electrical  circuit.  This  means  they  are  closing  a  switch  that  actually  connects  circuits  together  so 
electricity  can  flow  through  the  circuit.  Closing  an  electrical  circuit  is  like  opening  a  valve  on  a  water  pipe. 

2  Amplitude    The  maximum  strength  of  an  alternating  current  during  its  cycle,  as  distinguished  from  the  mean  or  effective  strength. 

3  Cycle.  A  complete  alternation  of  voltage  and/or  current  in  an  alternating  current  (A.C.)  circuit. 


243 


224  Water  Treatment 


When  there  is  power  in  threp  leads  and  a  fourth  lead  is 
brought  in,  it  is  a  neutral  lead  Incoming  power  goes  through 
a  metar  and  then  some  type  of  disconnecting  switch  This 
switch  could  be  a  fuse  switch  or  a  circuit  breaker  The 
purpose  of  the  disconnect  switch  is  to  open  whenever  a 
short  or  fault  occurs  and  thus  protect  both  the  electrical 
circuits  and  electncal  equipment. 

Circuit  breakers  (Figure  18.4)  are  used  to  protect  electrical 
Circuits  from  overloads.  Most  circuit  breakers  are  metal 
conductors  that  de-energize  the  mam  circuit  when  excess 
current  passes  through  a  metal  stnp  causing  it  to  overheat 
and  open  the  mam  circuit. 


Fig.  16.4   Circuit  breakers 

(Courtesy  oi  Consolidated  EiectrrCdl  Distributors  inc ) 


These  equations  are  used  by  electrical  engineers  for 
calculatmg  circuit  charactenstics  If  you  memorize  the  fol- 
lowmg  relationship,  you  can  always  figure  out  the  correct 
formula 


To  use  the  above  triangle  you  cover  up  the  term  you  don't 
know  or  are  trying  to  find  out  with  your  finger.  The  relation- 
ship between  the  other  two  known  terms  will  indicate  how  to 
calculate  the  unknown.  For  example,  if  you  r  s  trying  to 
calculate  the  current,  cover  up  I.  The  two  knowns  (E  and  R) 
are  shown  in  the  triangle  as  E/R.  Therefore,  I  =  E/R.  The 
same  procedure  can  be  used  to  find  E  when  I  and  R  are 
known  or  to  find  R  when  E  and  I  are  known. 


Two-phase  systems  will  not  be  discussed  oecause  they 
are  seldom  found  m  water  treatment  facilities. 

18.114  Amps 

An  Ampere  (I)  is  the  practical  unit  of  electric  current.  This 
IS  the  current  produced  by  a  pressure  of  one  volt  in  a  circuit 
having  a  resistance  of  one  ohm.  Amperage  is  the  measure- 
ment of  current  or  electron  flow  and  is  an  indication  of  work 
being  done  or  "how  hard  the  electricity  is  working." 

In  order  to  understand  amperage,  one  more  term  must  be 
explained.  The  OHM  is  the  practical  unit  of  electrical  resis- 
tance (R).  "Ohm's  Law"  states  that  in  a  given  electrical  circuit 
the  amount  of  current  (I)  in  amperes  is  equal  to  the  pressure 
in  volts  (E)  divided  by  the  resistance  (R)  In  ohms.  The 
followmg  three  formulas  are  given  to  provide  you  with  an 
indication  of  the  relationships  among  current,  resistance  and 
EMF  (electromotive  force). 


BMP.  Volts 

Current,  amps=  r  :  :: — 

Resistance,  ohms 


EMF.  Volts     =  (Current,  amps)  (Resistance,  ohms)    (  E  -  IR  ) 


Resistance, 
ohms 


EMF,  Volts 
Current,  amps 


E 

(R  =  -) 


ERIC 


18.115  Watts 

Watts  (W)  and  kilowatts  (kW)  are  the  units  of  measurement 
of  the  rate  at  which  power  is  being  used  or  generated.  In 
D.C.  circuits,  watts  (W)  equal  the  voltage  (E)  multiplied  by  the 
current  (I). 

Power,  watts  -  (Current,  amps)  (Electromotive  Force,  volts) 

or  P,  v^/atts    =  (I.  amps)  (E,  volts) 

In  A  C  polyphase  circuits  the  formula  becomes  more 
complicated  because  of  the  inclusion  of  two  additional 
factors.  First,  there  is  the  square  root  of  3,  for  three-phase 
circuits  which  is  equal  to  1.73.  Secondly,  there  is  the  power 
factor  which  is  the  ratio  of  the  true  or  actual  power  passing 
through  an  electncal  circuit  to  the  product  of  the  voltage 
times  the  amperage  m  the  circuit,  '^or  standard  three-phase 
induction  motors  the  power  factor  will  be  somewhere  near 
0.9.  The  formula  for  power  input  to  a  three-phase  motor  is: 


Power,  kilowatts 


(E  volts)  (I.  amps)  (Power  Factor)  (1  73) 
1000  watts/kilowatt 


Since  0  746  kilowatts  equal  1 .0  horsepower,  then  the  power 
output  of  a  motor  is 


Power  Output 
horsepower 


(Power  Input,  kilowatts)  (Efficiency,  %) 
(0.746  kilowatts/horsepower)  (100%) 


244 


Maintenance  225 


18. 1 16  Power  Requirements 

Power  requirements  (Pr)  are  expressed  in  kilowatt  hours 
500  watts  for  two  hours  or  one  watt  for  1000  hours  equals 
one  kilowatt  hour  The  power  company  charges  so  many 
cents  per  kilowatt  hour. 

Power  req.,  kW-hr  =  (Power,  kilowatts)  (Time,  hours) 
P?.kW-hr  -  (P,  kVV)  (T,  r.r) 

18.117  Conductors  and  Insulators 


A  material,  like  copper,  which  permits  the  flow  of  electrical 
current  k>  called  a  conductor  Material  which  will  not  permit 
the  flow  ot  electricity,  like  rubber,  is  called  an  insulator.  Such 
material  when  wrapped  or  cast  around  a  wire  is  called 
insulation.  Insulation  is  commonly  used  to  prevent  the  loss 
of  electrical  flow  by  two  conductors  coming  into  contact  with 
each  other. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  323. 

18.11  A  What  are  two  types  of  current? 

18.1  IB  Amperage  is  a  measurement  of  what? 

18.1 1C  How  can  you  determine  the  proper  voltage  and 
allowable  current  in  amps  for  a  piece  of  equipment*? 


Be  sure  the  voltage  tester  that  you  are  using  has  sufficient 
range  to  measure  the  voltage  you  would  expect  to  find.  In 
other  words  do  not  use  a  tester  with  a  limit  of  600  volts  on  a 
circuit  that  normally  is  energized  at  2300  volts.  With  the 
voltage  tester  you  can  tell  If  the  current  is  A.C.  or  D.C.  and 
the  intensity  or  voltage  which  will  probably  be  one  of  the 
following:  120,  207,  230,  460,  2400,  or  4160. 

Do  not  \A'0.*'k  on  sny  6!9Ctr!C3l  circuits  unless  you  are 
qualified  and  authorized.  Use  a  voltage  tester  and  other 
Circuit  testers  to  determine  if  a  circuit  is  energized,  or  if  all 
voltage  is  off.  This  should  be  done  after  the  mam  switch  is 
turned  off  to  make  sure  it  is  safe  to  work  inside  the  electrical 
pa.iel.  Always  be  aware  of  the  possibility  that  even  if  the 
disconnect  to  the  unit  you  are  working  on  is  off,  the  control 
circuit  may  still  be  energized  if  the  circuit  onginates  at  a 
different  distribution  panel.  Also  a  capacitor  in  the  unit  may 
have  sufficient  energy  stored  to  cause  considerable  harm  to 
an  operator,  such  as  a  power  factor  correction  capacitor  on 
a  motor.  Test  for  voltage  both  before  and  during  the  time  the 
switch  IS  pulled  off  to  have  a  double  check.  This  procedure 
ensures  that  the  voltage  tester  is  working  and  that  you  have 
good  continuity  to  your  tester.  Use  circuit  testers  to  measure 
voltage  or  current  characteristics  to  a  given  piece  of  equip- 
ment and  to  make  sure  that  you  have  or  do  not  have  a  live" 
circuit. 

Besides  using  the  voltage  tester  for  checking  power,  it  can 
be  used  to  test  for  open  circuits,  blown  fuses,  single  phasing 
c'  Mors,  grounds,  and  many  other  uses.  Some  examples 
are  illustrated  in  the  following  paragraphs. 

In  the  Circuit  shown  below  (Figure  18.5),  test  for  power  by 
holding  one  lead  of  the  tester  on  point  "A,"  and  the  other  at 
point  "B."  If  no  power  is  indicated,  the  switch  Is  open  or 
faulty.  Sketch  shows  switch  in  "open"  position. 


Light 

Switch 


Ground 


18.12  Tools,  Meters  and  Testers 


 1^  

NieveC  ^MT&C  AN  eu&CT(2lCALPAMeL 
Qe(PM(2  ASii^  p\BCJ^  Of  BlBCmc/Kl^ 

MMH0(Z\7BrP. 


18.120  Voltage  Testing 

In  order  to  maintain,  repair,  and  troubleshoot  electrical 
equipment  and  circuits,  the  proper  tools  a^'e  required.  You 
will  need  a  VOLTAGE  TESTER  to  check  for  voltage.  There 
are  several  types  on  the  market  and  all  of  them  work.  They 
are  designed  to  be  used  on  energized  circuits  and  care  must 
be  exercised  when  testing.  By  holding  one  lead  on  ground 
and  the  other  on  a  power  lead,  you  can  determine  if  the 
circuit  is  energized. 

ERLC 


Fig.  18.5   Single-phase  circuit  (switch  in  open  position) 


To  test  for  power  at  Point  "A"  and  Point  "B"  in  Figure  18.6, 
open  the  switch  as  shown.  Using  a  volt  meter  or  voitage 
tester,  connect  a  lead  on  Line  1  and  a  lead  on  Line  2,  at 
points  A  and  B,  between  the  fuses  and  the  load.  Bring  the 
voltage  tester  and  leads  out  of  the  panel  and  close  the  panel 
door  as  far  as  possible  without  cutting  or  damaging  the 
meter  leads.  Some  switches  cannot  be  closed  if  the  panel 
door  IS  open.  The  panel  door  is  closed  when  testing  because 
hot  copper  sparks  could  seriously  injure  you  when  the  circuit 
IS  energized  and  the  voltage  is  high.  Close  the  switch. 

1.  Voltage  tester  should  register  at  220  volts.  If  there  is  no 
reading  at  points  "A"  and  "B,"  the  fuse  or  fuses  could  be 
blown. 

2.  Move  voltage  tester  to  LI  and  L2.  If  there  is  still  no 
reading  on  the  voltage  tester,  check  for  an  open  switch  in 
another  location,  or  call  the  power  company  to  find  out  if 
power  is  out. 


24H 


226  Water  Treatment 


LINE 


NEUTRAL 


L2 


/ 


INCOMING 
SINGLE  PHASE  220  VOLT 
(110  VOLTS  FROM  N  TO  LI  AND 
110  VOLTS  FROM  N  TO  L2 
220  VOLTS  FROM  LI  TO  L2 
OR  A  TO  B) 


SWITCH 


FUSES 


B 


LOAD 


Fig,  18.6  Single-phase,  three  lead  circuit 


3.  If  a  220  volt  reading  is  registered  at  LI  and  12,  move  the 
test  leads  to  pent  "A,"  and  the  "neutral"  lead  If  a  reading 
of  110  volts  is  observed,  the  fuse  on  line  "A"  is  okay.  If 
there  isn't  a  voltage  reading,  the  fuse  on  line  "A"  could  be 
"blown."  Move  the  lead  from  line  "A"  to  line  "B."  Observe 
the  reading.  If  110  volt  power  is  not  observed,  the  fuse  on 
line  "B"  tould  be  "blown."  Another  possibility  to  consider 
IS  that  the  neutral  line  could  be  brohan.  Under  these 
conditions,  if  there  is  voltage  on  line  "A"  and  the  fuse  on 
line  "B"  is  blown,  voltage  may  appear  on  line  "B." 


WARNING 

TURN  OFF  POWER  AND  BE  SURE  THA  T  THERE  IS 
NO  V^LT^GE  IN  EITHER  POWER  LINE  BEFORE 
CHANGIN3  FUSES.  Use  a  FUSE  PULLER.  Test  circuit 
again  in  the  same  manner  to  make  sure  fuses  or  circuit 
breakers  are  okay.  220  volts  power  or  voltage  should 
be  present  between  points  "A"  and  "B."  If  fuse  or  circuit 
breaker  trips  again,  shut  off  and  determine  the  source 
of  the  problem. 


Referring  to  Rgure  18.7,  test  for  voltage  in  three-phase 
circuits  as  follows  —  with  the  switch  closed  and  the  load 
disconnected,  check  for  voltage  (probably  either  220  or  440) 
between  points  A3-B3,  A3-C3,  and  between  B3-C3.  A  zero 
voltage  reading  on  any  or  all  of  the  three  tests  indicates  a 
problem  ahead  of  this  location  that  could  be  at  another 


switch  or  a  power  company  problem.  Assuming  normal 
readings  were  found  at  A3,  B3,  and  03,  repeat  the  three 
readings  at  points  A2,  B2,  and  02  with  the  switch  closed. 
Any  zero  voltage  readings  are  an  indication  of  a  defective 


ER?C 


24i> 


Maintenance  227 


FUSES 


A1 


B1 


C1 


L1 


L2 
LOAD 


L3 


Fig.  18.7  Three-phase  circuit,  220  volts 


switch.  Assummg  normal  readings  were  found  at  A2,  B2, 
and  C2,  repeat  the  three  readings  at  points  A1 ,  B1 ,  and  C1 
with  the  switch  closed.  If  any  two  voltage  readings  are  zero, 
one  fuse  is  blown  and  it  will  be  the  one  in  the  line  that  was 
common  to  the  two  zero  readings.  If  aii  three  voltage 
readings  are  zero,  either  two  or  three  fuses  are  blown.  To 
determine  which  fuses  are  blown,  refer  to  Table  18.1.  Note 
that  a  zero  voltage  reading  indicates  a  blown  fuse. 


TABLE  18.1    LOCATING  A  BLOWN  FUSE 
Blown  Fuse  In  Line  Use  Either  Test 

LI  A1-B2or  A1-C2 

L2  B1-A2  or  B1-C2 

L3  C1-A2orC1-B2 


Another  way  of  checking  the  fuses  with  the  load  connect- 
ed on  this  three-phase  circuit  would  be  to  take  your  voltage 
tester  and  place  one  lead  on  the  bottom  and  one  lead  on  the 
top  of  each  fuse.  You  should  NOT  get  a  voltage  reading  on 
the  voltmeter.  This  is  because  electricity  takes  the  path  of 
least  resistance.  If  you  get  a  reading  across  any  of  the  fuses 
(top  to  bottom),  that  fuse  is  bad. 

ALWAYS  MAKE  SURE  THAT  WHEN  YOU  USE  A  VOLT- 
METER IT  IS  SET  FOR  THE  PROPER  VOL  TAGE.  IF  VOLT- 


AGE IS  UNKNOWN  AND  THE  METER  HAS  DIFFERENT 
SCALES  THAT  ARE  MANUALLY  SET,  ALWAYS  START 
WITH  THE  HIGHEST  VOLTAGE  RANGE  AND  WORK 
DOWN.  Otherwise  the  voltmeter  could  be  damaged.  Look  at 
the  equipment  instruction  manual  or  name  plate  for  the 
expected  voltage.  Actual  voltage  should  not  be  much  higher 
than  given  unless  someone  goofed  when  the  equipment  was 
v^ired  and  inspected. 

18. 121  Ammeter 

Another  meter  used  in  electrical  maintenance  and  testing 
IS  the  AMMETER.  The  ammeter  records  the  current  or 
"amos"  flowing  in  the  circuit.  There  are  several  types  of 
ammeters,  but  only  two  will  be  discussed  in  this  section.  The 
ammbt^^r  generally  used  for  testing  is  called  a  "clamp  on" 
type.  The  term  "clamp  on"  means  that  it  can  be  clamped 
around  a  wire  supplying  a  motor,  and  no  direct  electrical 
connection  need  be  made.  Each  "leg"  or  lead  on  a  three- 
phase  motor  must  be  individually  checked. 

The  first  step  should  be  to  read  the  motor  name  plate  data 
and  find  what  the  amperage  reading  should  be  for  the 
particular  motor  or  device  you  are  testing.  After  you  have 
th's  infornr.atlon,  set  the  ammeter  to  the  proper  scale.  Set  it 
on  a  higher  scale  than  necessary  if  the  expected  reading  is 
close  (o  the  top  of  the  meter  scale.  Place  the  clamp  around 
one  lead  at  a  time.  Record  each  reading  and  compare  with 
the  name  plate  rating.  If  the  readings  are  not  similar  to  the 


24'; 


228  Water  Treatment 


name  plate  rating,  find  the  cause,  such  as  low  voltage,  bad 
bearings,  poor  connections  or  excessive  load.  If  the  amme- 
ter readings  are  higher  than  expected,  the  high  current  could 
produce  overheating  and  damage  the  equipment.  Try  to  find 
the  problem  and  correct  it. 

Current  imbalance  is  undesirable  because  it  causes  un- 
even heating  in  a  motor  that  can  shorten  the  life  expectancy 
of  the  insulation.  However,  a  small  amount  of  current 
imbalance  is  to  be  expected  in  the  leads  to  a  three-phase 
motor.  This  Imbalance  can  be  caused  by  either  peculiarities 
in  the  motor  or  by  a  power  company  imbalance.  To  isolate 
the  cause,  make  the  following  test.  Note  that  this  test  should 
be  done  by  a  qualified  electrician.  Refer  to  Figure  18.8. 


If  the  current  on  Lines  L1,  L2,  and  L3  are  about  the  same 
both  before  and  after  the  winng  change,  this  is  an  indication 
that  the  imbalance  is  being  caused  by  the  power  company 
and  they  should  be  asked  to  make  adjustments  to  correct 
the  condition.  However,  if  the  current  reading  followed  the 
motor  terminal  (T)  numbers  rather  than  the  power  line  (L) 
numbers,  the  problem  is  within  the  motor  and  there  isn't 
much  that  can  be  done  except  contact  the  motor  manufac- 
turer for  a  possible  exchange. 

When  using  a  clamp  on  ammeter,  be  sure  to  set  the  meter 
on  a  high  enough  range  or  scale  for  the  starting  current  if 
you  are  testing  during  startup.  Starting  currents  range  from 
500  to  700  percent  higher  than  running  currents  and  using 


LINE 


L1  L2 

o  6 


MOTOR 
STARTER 


L3 


Q 


9 

T1  T2 


T3 


Ftg.  18.8  Determination  of  current  imbalance 

1.  With  the  motor  wired  to  its  starter,  L1  to  T1,  L2  to  T2  and 
L3  to  Y3,  measure  and  record  the  amperage  on  L1  L2 
and  L3. 

2.  De-energIze  the  circuit  and  reconnect  the  motor  as  fol- 
lows: L1-T3,  L2-T1,  L3-T2.  This  wiring  change  will  not 
change  the  direction  of  the  rotation  of  the  motor. 

3.  Start  up  the  motor  and  again  measure  and  record  the 
amperage  on  L1 ,  L2,  L3. 


243 


Maintenance  229 


too  low  a  range  can  rum  an  expensive  and  delicate  instru- 
ment Newer  clamp  on  ammeters  automatically  adjust  to  the 
proper  range  and  can  measure  both  starting  or  peak  current 
and  normal  running  current. 

Another  type  of  ammeter  is  one  that  is  connected  m  line 
With  the  power  lead  orieads  Generally  they  are  not  portable 
and  are  usually  installed  in  a  panel  or  piece  of  equipment 
They  require  physical  connections  to  put  them  in  series  with 
the  motor  or  apparatus  being  tested  Current  transformers 
(CT)  are  commonly  used  with  this  type  of  ammeter  so  that 
the  meter  does  not  have  to  conduct  the  full  motor  current 
These  ammeters  are  usually  more  accurate  tha*^.  the  clamp 
on  type  and  are  used  in  motor  control  centers  and  pump 
panels 

18. 122  Megger 

A  MEGGER  is  a  aevice  used  for  checking  the  insulation 
resistance  on  motors,  feeders,  buss  bar  systems,  grounds, 
and  branch  circuit  winng. 

 —  j    WAKMNG  I  


There  are  three  general  types  of  meggers  crank  operat- 
ed, battery  operated,  and  instrument  There  are  two  leads  to 
connect  One  lead  is  clamped  to  a  ground  leac  md  the  other 
to  the  lead  you  are  testing  The  readings  on  uie  megger  will 
range  from  0"  (ground)  to  Infinity  (perfect),  depending  on  the 
condition  of  your  circuit. 

The  megger  is  usually  connected  to  a  motor  terminal  at 
the  starter,  and  the  other  lead  to  the  ground  lead.  Results  of 
this  test  indicate  if  the  insulation  is  deteriorating  or  cut 

Insulation  resistance  of  electrical  equipment  is  affected  by 
many  variables  such  as  the  equipment  design,  the  type  of 
insulating  material  used,  including  binders  and  impregnatmg 
compounds,  the  thickness  of  the  insulation  and  its  area, 
cleanliness  (or  uncleanliness),  moisture,  and  temperature 
For  insulation  resistance  measurements  to  be  conclusive  in 
analyzing  the  condition  of  equipment  being  tested,  these 
variables  must  be  taken  into  consideration. 

Such  factors  as  the  design  of  the  equipment,  the  kind  of 
insulating  material  used,  and  its  thickness  and  area  cease  to 
be  vanables  after  the  equipment  has  been  put  into  service, 
and  minimum  insulation  resistance  values  can  be  estab- 
lished within  reasonable  tolerances.  The  vanables  that  must 
be  considered  after  the  equipment  has  been  put  into  service, 
and  at  the  time  that  the  ir'sulation  resistance  measurements 
are  being  made,  are  uncloanliness,  moisture,  temperature, 
and  damage  such  as  fractures 

The  most  important  requirements  in  the  reliable  operation 
of  electrical  equipment  are  cleanhness  and  the  elimination  of 
moi:*'ire  penetration  into  the  insulation.  This  is  merely  good 
housekeeping  but  »t  is  essential  in  the  maintenance  of  all 
types  of  electrical  equipment.  The  very  fact  that  insulation 
resistance  is  affected  by  moisture  and  dirt,  with  due 
allowances  for  temperature,  makes  the  'megger"  insulation 
test  the  valuable  tool  which  it  is  in  electncal  maintenance. 


The  test  is  an  indication  of  cleanliness  and  good  housekeep- 
mg  as  well  as  a  detector  of  deterioration  and  impending 
trouble 

Several  cr.iaria  for  "minimum  values'  of  insulation  resis- 
tance have  been  developed.  These  values  should  be  pro- 
vided by  the  equipment  manufacturer  and  should  serve  as  a 
guide  for  equipment  m  service.  However,  penodic  tests  on 
equipment  in  service  will  usually  reveal  readings  consider- 
ably higher  than  the  suggested  minimum  safe  values  Rec- 
ords of  penodic  tests  must  be  kept,  because  persistent 
downward  trends  m  insulation  resistance  usually  give  fair 
warning  of  impending  trouble,  even  though  the  actual  values 
may  be  HIGHER  than  the  suggested  minimum  safe  values. 

Also,  allowances  must  be  made  *or  equipment  in  service 
showing  penodic  test  values  LOWER  than  the  suggested 
minimum  safe  values,  so  long  as  the  values  remain  stable  or 
consistent  In  such  cases,  after  due  consideration  has  been 
given  to  temperature  and  humid»ty  conditions  at  the  time  of 
the  test,  there  may  be  no  need  for  concern.  THIS  CONDI- 
TION MAY  BE  CAUSED  3Y  UNIFORMLY  DISTRIBUTED 
LEAKAGES  OF  A  HARMLESS  NA  TURE.  AND  MAY  NOT  BE 
THE  RESULT  OF  A  DANGEROUS  LOCALIZED  WEAK- 
NESS Here  again,  records  of  insulation  resistance  tests 
over  a  penod  of  time  reveal  changes  which  may  justify 
investigation.  The  "trend  of  the  curve"  may  be  more  signifi- 
cant than  the  numerical  values  themselves 

For  many  years  ONE  MEGOHM"^  has  been  widely  used  as 
a  fair  allowable  lower  limit  for  insulation  resistance  of 
ordinary  industrial  electrical  equipment  rated  up  to  1000 
volts.  This  value  is  still  recommended  for  those  who  may  not 
be  too  familiar  with  insulation  resistance  testing  practices,  or 
who  may  not  wish  to  approach  the  problem  from  a  more 
technical  point  of  view 

For  equipment  rated  above  1000  volts,  the  "one  megohm" 
rule  IS  usually  stated.  "A  minimum  of  one  megohm  per 
thousand  volts'  Although  this  rule  is  somewhat  arbitrary. 


and  may  be  criticized  as  u  .mg  an  engmeenng  foundation. 
It  has  stood  the  test  of  a  good  many  year.i  of  practical 
experience.  This  rule  gives  some  assurance  that  equipment 
IS  not  too  wet  or  not  too  dry  and  has  saved  many  an 
unnecessary  breakdown. 

More  recent  studies  of  the  problem,  however,  have  result- 
ed m  formulas  for  minimum  values  of  insulation  resistance 
that  are  based  on  the  kind  of  insulating  matenal  used  and 
the  electncal  and  physical  dimensions  of  the  types  of 
equipment  under  consideration ' 


^  Megohm    Meg  means  one  mtHion,  so  5  megohms  means  5  million  ohms  A  megger  reads  in  millions  of  ohms 

5  Portions  of  the  preceding  paragraphs  were  taken  from  INSTRUCTION  MANUAL  FOR  MEGGER  INSULATION  TESTERS,  No 

pages  42  and  43,  published  by  Biddle  Instruments,  c/o  Advertising  Department,  510  Township  Line  Road,  Blue  Bell  Pennsylvania 

19422.  For  additional  information  see  Biddle's  publication,  A  STITCH  IN  TIME,  price  $2.00 


ERIC 


24.9 


230  Water  Treatment 


Motors  and  wirings  should  be  megged  at  least  once  a 
year,  and  twice  a  year  if  possible.  The  readings  taken  should 
be  recorded  and  plotted  in  some  manner  so  that  you  can 
determine  when  insulation  is  creaking  down.  Meg  motors 
and  wirings  after  a  pump  station  has  been  flooded.  If 
insulation  is  wet,  excessive  current  could  be  drawn  and 
cause  pump  motors  to  "kick  out " 

18,123  Ohm  Meters 

OHM  MEIERS,  sometimes  called  circuit  testers,  are  valu- 
able tools  used  for  checking  electrical  circuits.  An  ohm  meter 
IS  used  only  when  the  electrical  circuit  is  OFF,  or  de- 
energized  The  ohm  meter  supplies  its  own  p'^wer  by  using 
batter  es  An  ohm  meter  is  used  to  measure  the  resistance 
(ohms)  in  a  circuit  These  are  most  often  used  in  testing  the 
control  circuit  components  such  as  coils,  fuses,  relays, 
resistors,  and  switches.  They  are  used  also  to  check  for 
continuity  An  ohm  meter  has  several  scales  which  can  be 
jsed  Typical  scales  are:  R  a  1 ,  R  ^  10.  R  a  i  ,000,  and  R  x 
1 0,000.  Each  scale  has  a  level  of  sensitivity  for  measuring 
different  resistances.  To  use  an  ohm  meter,  set  the  scale, 
start  at  the  low  point  (R  x  1).  and  put  the  two  leads  across 
the  part  of  the  circuit  to  be  tested  such  as  a  coil  or  resistor 
and  "ead  the  resistance  In  ohms.  A  reading  of  infinity  would 
indicate  an  ^pen  circuit,  and  a  "0"  would  read  no  resistance. 
These  usually  would  be  used  only  by  skilled  technicians 
because  they  are  very  delicate  instruments. 

All  meters  should  be  kept  in  good  working  order  and 
calibrated  periodically  They  are  very  delicate,  susceptible  to 
damage,  and  should  be  well  protected  during  transportation. 
When  readings  are  taken,  they  should  always  be  recorded 
on  a  machinery  history  card  for  future  reference.  Meters  are 
a  good  way  to  determine  pump  and  equipment  perform- 
ance. NEVER  USE  A  METER  UNLESS  QUALIFIED  AND 
AUTHORIZED. 

QUESTIONS 

Write  your  answers  m  a  notebook  and  then  compare  your 
answers  with  those  on  page  323. 

1812A  How  can  you  determine  if  there  is  voltage  in  a 
circuit 

18.12B  What  are  some  of  the  uses  of  a  voltage  tester'^ 

18.12C  What  precautions  should  be  aken  before  attempt- 
ing to  change  fuses'? 

18.12D  How  do  you  test  for  voltage  with  a  voltmeter  when 
the  voltage  is  unknown? 

1 8.12E  What  could  be  the  cause  of  amp  readings  different 
from  the  name  plate  rating? 

18.12F  How  often  should  motors  and  wirings  be  megged*? 

18  12G  An  ohm  meter  is  used  to  check  the  ohms  of 
resistance  in  what  control  circuit  components? 


18.13  Switch  Gear 

18. 130  Equipment  Protective  Devices 

Electricity  needs  safety  devices  to  protect  operators  and 
equipment  Water  systems  have  pressure  valves,  pop  offs 
and  different  safety  equipment  to  protect  the  pipes  ant- 
equipment.  So  must  electricity  have  safety  devices  to  con- 
tain the  voltage  and  amperage  that  r^omes  in  contact  with  the 
wiring  and  equipment.  The  first  piece  J  equipment  which 
must  be  protected  is  the  main  electrical  panel  or  control  unit 


where  the  power  enters.  Thjs  protection  is  provided  by 
either  fuses  or  a  circuit  breaker 

18.131  Fuses 

Let  s  start  with  fuses  The  power  company  has  installed 
fuses  on  their  power  noles  to  protect  ^heir  equipment  from 
damage  We  also  must  insta'i  something  to  protect  the  mam 
control  panel  and  wiring  from  damage  due  to  excessive 
voltage  or  amperage 

A  FUSE  IS  a  protective  device  having  a  stnp  or  wire  of 
fusible  metal  which,  when  placed  in  a  circuit,  will  melt  and 
break  the  electnca!  circuit  when  subjected  to  an  excessive 
temperature  This  temperature  will  develop  in  the  fuse  when 
a  current  flows  through  the  fuse  in  excess  of  what  the  circuit 
will  carry  safely  This  means  that  the  fuse  must  be  capable  of 
de-energizing  the  circuit  before  any  damage  is  done  to  the 
wiring  it  is  safely  protecting.  Fuses  are  used  to  protect 
operators,  mam  circuits,  branch  circuits,  heaters,  motors, 
an^  arious  other  electrical  equipment. 

I  cie  are  several  types  of  fuses,  each  being  used  for  a 
certain  type  of  protection.  Some  of  these  are: 

1  CURRENT-LIMITING  FUSES.  These  fuses  open  so 
quickly  while  cleanng  a  short-circuit  current  that  the 
potential  fault  current  is  not  allowed  to  reach  its  peak. 
They  are  used  to  protect  power  distribution  circuits. 

2  DUAL-ELEMENT  FUSES:  These  fuses  provide  a  time 
delay  in  the  low  overload  range  and  a  fast  acting  element 
for  short-circuit  protection.  These  fuses  are  used  for 
motor  protection  circ  jits. 

There  are  many  other  types  of  fuses  used  for  special 
application,  but  the  above  are  the  most  common. 

A  fuse  must  NEVER  be  by-passed  or  jumped.  This  is  the 
only  protection  the  circuit  has;  without  it,  senous  damage  to 
equipment  and  possible  injury  to  operators  can  occur.  Make 
sure  that  all  fuses  are  replaced  with  the  proper  size  and  type 
mdicated  for  that  circuit.  If  you  have  any  doubt,  check  the 
electrical  pnnts  or  contact  your  electrical  engineer. 


18, 132  Circuit  Breakers 

The  CIRCUIT  BREAKER  (Figure  18.4)  is  another  safety 
device  and  is  used  in  the  same  place  as  a  fuse.  Most  circuit 
breakers  consist  of  a  switch  that  opens  automatically  when 
the  current  or  the  voltage  exceeds  or  falls  below  a  certain 
limit.  Unlike  a  fuse  that  has  to  be  replaced  each  time  it 
"blows,"  a  Circuit  breaker  can  be  reset  after  a  short  delay  to 
allow  time  for  cooling.  This  is  done  by  moving  the  handle  to 
the  "off"  position  or  slightly  past,  and  then  moving  it  back  to 
the  "on"  position.  Also,  unlike  a  fuse,  a  circuit  breaker  can  be 
visually  inspected  to  find  out  if  it  has  been  tripped.  The 

2i)0 


ERiC 


Maintenance  231 


handle  will  be  at  the  mid  position  between  'on"  and  off/ 
Several  different  types  of  circuit  breakers  are  being  used 
today  and  each  one  is  selected  for  a  ^  jcial  protective 
purpose. 

18. 133  Overload  Relays 

Three-phase  motors  are  usually  protected  by  OVERLOAD 
relays.  This  is  accomplished  by  having  heater  strips,  bimetal, 
or  solder  pots  which  open  on  current  rise  (overheating),  and 
open  the  control  circuit.  This  in  tum  opens  the  power  control 
Circuit,  which  de-energizes  the  starter  and  stops  power  to 
the  motor.  Such  relays  are  also  known  as  heaters  or 
thermal  overloads.  Sizing  of  these  overloads  is  very  cntical 
and  should  co'ncide  with  the  name  plate  rating  on  the  motor. 
Sizing  depends  on  the  servic  ?  factor  of  the  electnc  motor. 
Usually  they  range  from  100  to  110  percent  of  the  motor 
name  plate  ratings  and  should  never  exceed  125  percent 
("sually  1 15  percent)  of  the  motor  rating.  For  example,  if  the 
motor  IS  rated  for  10  amps,  the  overloads  should  be  sized 
from  10  to  11  amps. 

Again.  NEVER  INCREASE  ^-iE  RATING  OF  THE  OVER- 
LOAD  HEATERS  BECAUSE  OF  TRIPPING,  YOU  SHOULD 
FIND  THE  PROBLEM  AND  REPAIR  IT.  There  are  many 
other  protective  devices  for  electricity  such  as  motor  wind- 
ing thermostats,  phase  protectors,  low  voltage  protectors, 
and  ground  fault  protectors.  Each  has  its  own  special 
applications  and  should  never  be  tampered  with  or  jammed. 

GROUND  IS  an  expression  representing  an  electrical 
connection  to  earth  or  a  large  conductor  which  is  at  the 
earth's  potential  or  neutral  voltage.  Motor  frames  and  all 
electrical  tools  and  equipment  enclosures  should  be  con- 
nected to  ground.  This  is  generally  referred  to  simply  as 
grounding,  or  equipment  ground. 

The  third  prong  on  cords  from  electric  hand  tools  is  the 
equipment  ground  and  must  never  be  removed.  When  an 
adapter  is  used  with  a  two-prong  receptacle,  the  green  wire 
on  the  adapter  should  be  connected  Uiider  the  center  screw 
on  the  receptacle  cover  plate.  Many  times  equipment 
grounding,  especially  at  home,  is  achieved  by  connecting 
onto  a  water  pipe  or  drain  rather  than  a  rod  driven  into  the 
ground.  This  practice  generally  is  not  recommended  when 
pk^stic  pipes  and  other  non-conducting  pipe  matenals  are 
used  unless  it  is  known  that  the  piping  is  all  metal  and  not  in- 
terrupted. Also  corrosion  can  be  accelerated  pipes  of 
different  metals  are  used.  A  rod  dnven  into  dry  ground  isn't 
very  effective  as  ?  ^round. 

18.134  Motor  Starters 

A  motor  starter  is  a  device  or  group  of  devices  which  are 
used  to  connect  the  electrical  power  to  a  motor.  These 
starters  can  be  either  manually  or  automatically  controlled. 

Manual  and  magnetic  starters  range  in  complexity  from  a 
single  "on-off"  switch,  to  a  sophisticated  automatic  device 
using  timers  and  coils.  The  simplest  motor  starter  is  used  on 
single-phase  motors  where  a  circuit  breaker  is  turned  on 
and  the  motor  starts.  This  type  of  starter  also  is  used  on 
three-phase  motors  of  smaller  horsepower.  These  are  used 
on  fan  motors,  machinery  motors,  and  several  others  where 
It  isn't  necessary  to  have  automatic  control. 

MAGNETIC  STARTERS  (Figures  18.9  and  18.10)  are 
commonly  used  to  start  pumps,  compressors,  blowers,  and 
anything  where  automatic  or  remote  control  is  desired.  They 
permit  low  power  circuits  to  energize  the  starter  of  equip- 
ment at  a  remo\e  location  or  to  start  larger  starters  (Figure 
18.11).  A  magnetic  starter  is  operated  by  electromagnetic 

O 

ERIC 


action  This  starter  has  contractors  and  tney  operate  by 
energizing  a  coil  which  closes  the  contact,  thus  starting  the 
motor  The  circuit  which  energizes  the  starter  is  called  the 
control  Circuit  and  it  may  operate  on  a  lower  voitage  (115 
volts)  than  the  motor.  Whenever  a  starter  is  used  as  a  part  of 
an  integrated  circuit  (such  as  *or  flow,  pressure  or  tempera- 
ture control),  a  magnetic  starter  or  controller  is  necessary. 

Magnetic  starters  are  sized  for  their  voltage  and  horse- 
power ratings  These  are  divided  into  classes  The  nosi 
cc  nmon  starts*-  is  Class  "A."  A  Class  "A"  starter  is  an 
Alternating  Current  air-break  and  oil  immersed  ma  iual,  or 
magnetic  controller  for  service  on  600  volts  or  le*>s.  It  is 
capable  of  interrupting  operating  overloads  up  to  and  .pclud- 
ing  10  tinpes  their  normal  motor  rating,  but  not  short  circuits 
or  faults  beyond  operating  overloads." 

Additional  class  information  can  be  found  in  electrical 
catalogs,  manuals  and  manufacturers'  brochures. 

There  are  a  number  of  different  types  of  three-phase 
magnetic  motor  starters  available.  The  simplest  and  most 
common  is  the  "across-the-line"  full  voltage  starter.  This 
starter  consists  of  three  contacts,  a  magnetic  actuating 
device,  and  overload  detection.  This  starter  subjects  the 
power  system  to  the  full  surge  current  on  startup  and  may 
cause  the  lights  in  the  treatment  plant  to  dim  momentarily. 

To  reduce  the  in-rush  current  when  starting  polyphase 
motors,  a  number  of  other  types  of  starters  are  available. 

1 .  Auto-Transformer  Type  Reduced  Voltage  Starters.  These 
begin  the  motor  start  sequence  by  applying  a  reduced 
voltage  to  the  motor  for  a  few  seconds.  The  voltage  is 
controlled  by  a  time  delay  relay  within  the  starter.  The 
reduced  voltage  is  obtained  from  transformers  that  are  a 
part  of  the  starter.  These  transformers  are  designed  to 
operate  for  only  a  few  seconds  at  a  time  and  can  easily  be 
burned  out  if  the  motor  is  started  too  frequently. 

2  Solid  State  Reduced  Voltage  Starters.  These  starters  do 
the  same  job  as  the  auto-transformer  type  reduced 
voltage  starters  but  they  do  not  need  transformers  be- 
cause the  voltage  and  current  are  electrically  controlled. 

3  Part  Winding  Starters.  These  starters  are  used  with 
special  motors  that  have  two  separate  sets  o^  windings 
on  the  same  motor  frame.  By  energizing  the  windings 
about  one  second  apart,  the  in-rush  current  is  limited  to 
about  half  that  of  a  normal  motor  with  a  full  voltage 
starter. 

4.  Wye-Delta  Starters.  These  starters  are  used  with  motors 
that  have  all  leads  brought  out  to  the  terminal  box.  The 
motor  IS  first  started  with  wye  connected  coils  and 
switched  over  to  a  aelta  connection  for  running,  "^he 
result  IS  the  same  as  if  you  used  a  reduced  voltuge 
starter. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  323. 

1 8  1 3A  What  are  two  types  of  safety  devices  found  in  main 
electrical  panels  or  control  units'' 

18.13B  What  are  fuses  used  to  protect? 

18.13C  Why  must  a  fuse  never  be  by-passed  or  jumped? 

18.1 3D  How  does  a  circuit  breaker  work? 

18.13E  How  are  motor  starters  controlled? 

18.13F  When  are  magnetic  starters  used? 


232  Water  Treatment 


Maintenance  233 


Fig.  18.10  Wiring  diagram  of  three-phase  magnetic  starter 


Fig.  18. 1 1   Application  of  magnetic  starter 


253 


234  Water  Treatment 


18.14  Electric  Motors 

18.140  Classification 

Electric  motors  are  the  machines  most  commonly  used  to 
convert  electrical  energy  into  mechanical  energy.  A  motor 
usually  consists  of  a  STATOR,^  ROTOR  J  END  BELLS,^  and 
windings.  The  rotor  has  an  extending  shaft  which  allows  a 
machine  to  be  coupled  to  it. 

Motors  are  of  many  different  types  (Figure  1 8. 1 2),  such  as, 
squirrel  cage  induction  motors,  wound  rotor  motors,  syn- 
chronous motors  and  many  others.  The  most  common  of 
these  IS  the  squirrel  cage  induction  motor.  Some  pumping 
stations  use  wound  rotor  induction  motors  when  speed 
control  IS  nieded 

Three-phase  electric  motors  are  used  for  operating 
pumps,  compressors,  fans  and  other  machinery.  Motors  are 
generally  trouble  free  and,  when  lubricated  properly,  cause 
very  few  problems  The  amperage  and  voltage  readings  on 
motors  should  be  taken  periodically  to  insure  proper  oper- 
ation 

Motors  are  classified  by  NEMA  (National  Electrical  Manu- 
facturers Association)  with  code  letters  from  A  through  V 
With  "A"  having  the  lowest  starting  torque  and  in-rush  current 
and  "V  having  the  highest  starting  torque  and  in-rush 
current  The  most  commonly  available  motors  have  codv.- 
letters  from  "F"  through  "L"  which  have  in-rush  currents  on 
start  of  from  500  to  1000  percent  of  full  load. 

Another  important  consideration  in  selecting  a  motor  is 
the  class  of  insulation.  This  determines  how  hot  a  motor  may 
operate  and  is  listed  as  degree  rise  on  the  motor  nameplate 
(Figure  18.13). 

Motor  insulation  classt^  are  as  follows: 


Class 

Temperaturing  Rating 

A 

105°C  (221  °F) 

B 

130°C  (266°F) 

F 

155°C  (31  rF) 

H 

180°C  (356°F) 

At  pre'^ent  most  motors  are  Class  B  insulated.  Try  to  keep 
the  actual  operating  temperature  below  the  temperature 
rating  or  limit  in  order  to  prolong  the  life  of  the  insulation. 

All  of  this  information  can  be  found  on  the  motor  name 
plate  and  should  be  taken  Into  consideration  when  evaluat- 
ing a  motor.  Most  of  the  trouble  encountered  with  electrical 
motors  results  from  bad  bearings,  shorted  windings  due  to 
insulation  breakdown  or  excessive  moisture. 

All  of  the  information  on  the  motor  name  plate  (Figure 
18.13)  should  be  recorded  and  placed  in  n  file  for  future 
reference.  Many  times  the  name  plate  is  painted,  corroded 
or  missing  from  the  unit  when  the  information  is  needed  to 
repair  the  motor  or  replace  parts.  Also  record  the  date  of 
installation  and  service  startup.  See  Section  18.142.  "Rec- 
ordkeeping.*' for  a  typical  data  sheet  for  recording  the 
essential  information.  This  information  also  should  be  on  the 
manufacturer's  data  sheet  and  in  the  instruction  manual. 
Compare  the  information  for  consistency  and  file  in  an 
appropriate  location.  Be  sure  you  have  the  correct  serial 
and/or  model  numbers. 


QUESTIONS 

Wnte  you*-  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  324. 

18  14A  How  IS  electncal  energy  converted  into  mechanical 
energy*? 

18.14B  What  are  the  important  parts  of  an  electnc  motor? 

18  14C  How  can  motors  be  kept  trouble  free? 

18.14D  What  should  be  done  with  motor  name  plate  data*? 

18. 14 1  Troubleshooting 

Practical  stop-by-step  procedures  combined  with  a  com- 
mon sense  approach  is  the  key  to  effective  troubleshooting. 

A.  Gather  preliminary  information.  The  first  step  in  trouble- 
shooting any  motor  control  which  has  developed  trouble 
IS  to  understand  the  circuit  operation  and  other  related 
functions.  In  other  words,  what  is  supposed  to  happen, 
operate,  and  so  forth  when  it's  working  right?  Also,  what 
IS  It  doing  now?  The  qualified  maintenance  operator 
should  be  able  to  do  the  following: 

1 .  KNOW  WHAT  SHOULD  HAPPEN  WHEN  A  SWITCH  IS 
PUSHED:  V^hen  switches  are  pushed  or  tripped,  know 
what  coils  go  in,  contacts  close,  relays  operate,  and 
motors  run. 

2.  EXAMINE  ALL  OTHER  FACTORS:  What  other  unusual 
things  are  happening  in  the  plant  now  that  this  circuit 
doesn't  work  properly?  Lights  dimmed,  other  pumps 


stor  ed,  lights  went  out  when  it  broke,  everything  was 
flooded,  operators  were  hosing  down  area,  and  many 
other  possible  factors. 

3.  ANALYZE  WHAT  YOU  KNOW:  What  part  of  it  is 
working  correctly?  Is  switch  arm  tripped?  Is  it  a 
mechanical  failure  or  an  electrical  problem  caused  by 
a  mechanical  failure? 

4.  SELECT  SIMPLE  PROCEDURES:  To  localize  the 
problem,  select  logical  ways  that  can  be  simply  and 
quickly  accomplished. 

5.  MAKE  A  VISUAL  INSPECTION:  Look  for  bumed 
wires,  loose  wires,  area  full  of  water,  coil  burned, 
contacts  loose,  or  strange  smells. 


«  Stator    That  portion  of  a  machine  which  contains  the  stationary  (non-moving)  parts  that  surround  the  moving  parts  (rotor) 

liotor  The  rotating  part  of  a  machine.  The  rotor  is  surrounded  by  the  stationary  (non-moving)  parts  (stator)  of  the  machine 
»  End  Bells.  Devices  used  to  hold  the  rotor  and  stator  of  a  motor  in  position. 


er|c 


254 


Maintenance  235 


DRIP  PROOF 


ITEM 
NO. 

PART  NAME 

1 

Wound  Stator  w/  Frame 

2 

Rotor  Assembly 

3 

Rotor  Core 

4 

Shaft 

5 

Bracket 

6 

Bearing  Cap 

7 

Bearings 

8 

Seal,  Labyrinth 

9 

Thru  Bolts/Caps 

10 

Seal,  Lead  Wire 

11 

Terminal  Box 

12 

Terminal  Box  Cover 

13 

Fan 

14 

Deflector 

15 

Lifting  Lug 

TOTALLY  ENCLOSED  FAN  COOLED 


ITEM 
NO. 

PART  NAME 

1 

Wound  Stator  w/  Fvame 

2 

Rotor  Assembly 

3 

Rotor  Core 

4 

Shaft 

5 

Brackets 

6 

Bearings 

7 

beal.  Labyrinth 

8 

Thru  Bolts /Caps 

9 

Seal,  Lead  Wire 

10 

Terminal  Box 

11 

Terminal  Box  Cover 

12 

Fan,  Inside 

13 

Fan,  Outside 

.4 

Fan  Grill 

15 

Fan  Cover 

16 

Fan  Cover  Bolts 

17 

Lifting  Lug 

Fig.  18. 12   Typical  rr.^tors 

"curtesy  of  Sterling  Power  Systems.  Inc  ; 

Er|c  2^l\ 


236  Water  Treatment 


Sterlii 


£/7/^  VARIABLE  SPEED 


SERIAL  NO.  B-961Q283 


1 


DESIGN  B 


FRAME 


215 


MAX 
AM8 


55 


CLASS 


ABFK 


DUTY  Continuous 


40 


oc! 


TYPE 


NOTE- 1.  The  motor  for  this  unit  is  rated  at  1750  RPM  and 
the  maximum  speed  for  the  vanable  drive  unit  is 
1200  RPM. 

2.  The  40°C  rating  is  V\e  allowable  operating  tem- 
perature above  ambient  tempera'ure. 


Fig.  18. 13  Typical  nameplate 

(Courtesy  of  Sterling  Power  Systems.  Inc.) 


6  CONVERGE  ON  SOURCE  OF  TROUBLE:  Mechanical 
or  electrical.  Motor  or  control,  whatever  it  might  be 
Electncal  problems  result  from  some  type  of  mechani- 
cal failure. 

7  PINPOINT  THE  PROBLEM.  Exactly  where  is  the  prob- 
lem and  what  do  you  need  for  repair? 

8.  FIND  THE  CAUSE.  What  caused  the  problem*?  Mois- 
ture, wear,  poor  design,  voltage,  or  overloading. 

9.  REPAIR  THE  PROBLEM  AND  ELIMINATE  THE 
CAUSE  IF  POSSIBLE.  If  the  problem  is  inside  switch 
gear  or  motors,  call  an  electrician.  Give  the  electrician 
the  information  you  have  regarding  the  equip'^ent.  Do 
not  attempt  electrical  repairs  unless  qualified  and 
authorized,  otherwise  you  could  cause  excessive 
damage  to  yourself  and  to  the  equipment. 

B  Some  of  the  things  to  look  for  when  troubleshooting  are 
given  in  the  remainder  of  this  section, 

ERIC 


18. 142  Recordkeeping 

Records  are  a  very  important  part  of  electncal  mainte- 
nance They  must  be  accurate  and  complete.  Whenever 
something  is  changed,  repaired,  or  tested,  it  should  be 
recorded  on  a  material  history  Cc ''d  of  some  type.  Pages  242 
and  243  are  examples  of  typical  record  sheets 

%: 

QUESTIONS 

Write  your  answers  m  a  notebook  and  then  compare  your 
answers  with  those  on  page  324. 

18  14E  What  IS  the  key  to  effective  troubleshooting*? 

18.14F  What  are  some  of  the  steps  that  should  be  taken 
when  troubleshooting  electrical  equipment? 

18  14G  What  kind  of  information  should  be  recorded  re- 
garding electncal  equipment? 


Maintenance  237 


ELECTRIC  MOTOR  TROUBLESHOOTING 
1.  Contacts 

Trouble  Possible  Causes 

Contact  chatter  1 .  Broken  POLE  SHADER  ^ 

2.  Poor  contact  in  contro!  circuit. 

3.  Low  voltage 

Welding  or  freezing  1.  Abnormal  surge  of  current. 

2.  Frequent  JOGGING:^ 

3.  Insufficient  contact  pressure. 


Short  contact  hfe  or  overheating 
of  tips 


Coil,  overheated 


4.  Contacts  not  positioning  properly. 

5.  Foreign  matter  preventing  magnet 
from  seating. 

6.  Short  cir^  Jit 

1-  Contacts  poorly  aligned,  spaced  or 
damaged. 


3.  Excessive  starting  and  stopping  of 
motor. 

4.  Weak  contact  pressure. 

5.  Dirty  contacts. 

6.  Loose  connections. 

1.  Starting  coil  may  not  kick  out 

2.  Overload  won't  let  moior  reach  mini- 
mum speed. 

3.  Over  voltage  or  high  ambient  tem- 
perature. 

4.  Incorrect  cor' 

5.  Shorted  turns  caused  by  mechanical 
damage  or  corrosion. 

6.  Undervoltage,  failure  of  magnet  to 
seal  It. 

7.  Dirt  or  rust  on  pole  faces  increasing 
air  gap. 


Remedy 

1.  Replace 

2.  Improve  contact  or  use  holding  circuit 
Interlock 

3.  Correct  voKage  condition.  Check  mo- 
mentary voltage  dip. 

1.  Use  larger  contactor  and  check  for 
grounds,  shorts,  or  excessive  motor 
load  current. 

2.  Install  larger  device  rated  for  jogging 
service  or  caution  operator. 

3.  Replace  contact  spnng;  check  contact 
carrier  for  damage. 

4.  Check  for  voltage  dip  during  startup. 

5.  Clean  contacts. 

6.  Remove  short  fault  and  check  that 
fuse  or  breaker  are  right. 

1.  Do  not  file  silver-faced  contacts. 
Rough  spotfi  or  discoloration  will  not 
harm  contacts. 

2.  Install  larger  device.  Check  for 
grounds,  shorts,  *r  excessive  motor 
currents. 

3.  Caution  operators.  Check  operating 
controls. 

4.  Adjust  or  replace  contact  spnngs. 

5.  Clean  with  approved  solvent. 

6.  Check  terminals  and  tighten. 

1.  Repair  coil. 

2.  Remove  overload. 

3.  Check  application  and  circuit. 

4.  Check  rating  and  if  incorrect,  replace 
with  proper  coil. 

5.  Replace  coil. 

6.  Correct  system  voltage. 

7.  Clean  pole  faces 


2.  EA^s:"<5'vely  high  currents. 


9  Poie  Shader.   A  copper  bar  circling  the  laminated  iron  core  inside  the  coil  of  a  magnetic  starter. 
Jogging.   The  frequent  starting  and  stopping  of  an  electric  motor. 


238  Water  Treatment 


ELECTRIC  MOTOR  TROUBLESHOOTING  ('Continued) 
Trouble  Possible  Causes 

Overload  relays  tripping  1  Sustained  overload 


Failure  to  tnp  overload  relay 


2.  Loose  connection  on  all  or  any  load 
wires. 

3  Incorrect  heater 

4.  Fatigued  heater  blocks. 

1.  Mechanical  binding,  dirt,  or  corrosion. 

2.  Wrong  heater,  or  heaters  omitted  and 
jumper  wires  used 

3.  Motor  and  relay  in  different  tempera- 

tUicG 


2.  Magnetic  and  Mechanical  Parts 
Noisy  magnet  (humming) 


Failure  to  pick  up  and  seal 


1  Broken  shading  coil. 

2.  Magnet  faces  not  mating. 

3.  Dirt  or  rust  on  magnet  faces. 

4.  Low  voltage. 

1 .  Low  voltage 

2.  Coil  open  or  shorted. 

3.  Wrong  coil. 

4.  Mechanical  obstruction 


Failure  to  drop  out  1 .  Gummy  substance  on  pole 

2.  Voltage  not  removed  from  coil. 

3.  Worn  or  rusted  parts  causing  binding. 

4.  Residual  magnetism  due  to  lack  of  air 
gap  in  magnet  path. 

5  Welded  contacts. 


Remedy 

1.  Check  for  grounds,  shorts  or  exces- 
sive motor  currents  Mechanical  over- 
load 

2  Check,  clean,  and  tighten. 

3.  Replace  with  correct  size  heater  unit. 

4.  Inspect  and  replace 
1  Clean  or  replace. 

2.  Check  ratings  Apply  heaters  of  prop- 
er rating. 

3.  Adjust  relay  rating  accordingly,  or  in- 
stall temperature  compensating  re- 
lays. 

1.  Replacing  shading  coil. 

2.  Replace  magnet  assembly  or  realign 

3  Clean  and  realign. 

4.  Inspect  system  voltage  and  voltage 
dips  during  starting. 

1  Inspect  system  voltage  and  correct. 

2.  Replace. 

3.  Check  coil  number  and  voltage  rating. 

4.  With  power  otf.  check  for  free  move- 
ment of  contact  and  armature  assem- 
bly. Repair. 

1.  Clean  with  solvent. 

2.  Check  coil  Circuit. 

3.  Replace  or  clean  parts  as  necessary. 

4.  Replace  worn  magnet  parts  or  align  if 
possible. 

5  Replace  contacts. 


ERIC 


253 


Maintenance  233 


TROUBLESHOOTING  GUIDE  FOR  ELECTRIC  MOTORS 


Symptoms 

Cause 

Result* 

Remedy 

'i  Motor  ^oes  not 
start.  (Switch  is  on 
and  not  defective ) 

a  Incorrectly  connected. 

a  Burnout. 

a  Connect  correctly  per  diagram 
on  motor 

b.  Incorrect  power  supply. 

b  Burnout 

b  Use  only  with  correctly  rated 
power  supply. 

c.  Fuse  out.  loose  or  open  con- 
nection. 

c  Burnout 

c  Correct  open  circuit  condition. 

1 

1 

d  Rotating  parts  of  motor  may 
be  jammed  mechanically 

d.  Burnout 

d.  Check  and  coirect: 

1.  Bent  shaft. 

2.  Broken  housing. 

3.  Damaged  beanng. 

d   FnrPinn  matprial  in  motor 

e.  Driven  machine  may  be 
jammed. 

e.  Burnout 

e  Correct  jammed  condition. 

! 

f.  No  power  supply. 

f.  None. 

f  Check  for  voltage  at  motor  and 
work  back  to  power  supply. 

! 
1 

g.  Internal  circuitry  open. 

g  Fiurnout. 

g.  Correct  open  circuit  condition. 

i  2  Motor  starts  but 

a.  Same  as  1-a,  b,  c  above. 

a.  Burnout. 

a.  Same  as  1-a,  b,  c  above. 

ooes  not  come  up 
to  speed 

b  Overload. 

b.  Burnout. 

b.  Reduce  load  to  bring  cunent  to 
rated  limit.  Use  proper  fuses 
and  overload  protection. 

c.  One  or  more  phases  out  on 
a  3  phase  motor. 

c.  Burnout. 

c.  Look  for  open  circuits. 

1  3  Motor  noisy  electri- 
!  cally. 

a.  Same  as  1-a,  b,  c  above. 

a.  Burnout 

a.  Same  as  1-a,  b,  c  above. 

r 

!  4.  Motor  runs  hot  (ex- 
j     ceeds  rating). 

i 

a.  Same  as  1-a.  b,  c  above. 

a.  Burnout. 

a.  Same  as  1-a,  b,  c  above. 

b.  Overload. 

b.  Burnout. 

b.  Reduce  load. 

c.  Impaired  ventilation. 

c.  Burnout. 

c  Remove  obstruction. 

1 

d.  Frequent  start  or  stop 

d.  Burnout 

d.  1.  Reduce  number  of  starts  or 
reversals. 
2.  Secure  proper  motor  for  this 
duty. 

e.  Misalignment  between  rotor 
ana  c^ator  laminations. 

e.  Burnout 

e.  Realign. 

5  Noisy 

(mechanically) 

a.  Misalignment  of  coupling  or 
sprocket. 

a.  Bearing  failure, 
broken  shaft,  stator 
burnout  due  to  motor 
drag. 

a.  Correct  misalignment. 

b.  Mechanical  unbalance  of  ro- 
tating parts. 

b.  Same  as  5-a. 

b.  Find  unbalanced  part,  then  bal- 
ance. 

c.  Lack  or  improper  lubricant. 

c.  Bearing  failure 

c.  Use  correct  lubricant,  replace 
parts  as  necessary. 

d.  Foreign  material  in  lubricant. 

d.  Same  as  5-c. 

d.  Clean  out  and  replace  bear- 
ings. 

e.  Overload. 

e.  Same  as  5-c. 

e.  Remove  overload  condition. 
Replace  damaged  parts. 

f.  Shock  loading. 

f.  Same  as  5-c. 

f.  Correct  causes  and  replace 
damaged  parts. 

g.  Mounting  acts  as  amplifier 
of  normal  noise. 

g.  Annoying. 

g.  Isolate  motor  from  base. 

h.  Rotor  dragging  due  to  worn 
bearings,  shaft  or  bracket. 

h.  Burnout. 

h.  Replacing  bearings,  shaft  or 
bracket  as  needed. 

0  Dcdriny  laiiure 

a.  oame  as  o^a,  u,  c,  a,  e. 

a.  ~UriiUUl,  UaiTldycU 

shaft,  damaged  hous- 
ing. 

a    Qonl^r^o  hparlt^riQ  AnH  fnllnuu 
a.  riCUiOiUc?  ucai  li  IU9  ciiivJ  iwii^w 

a,  b,  c,  d,  e. 

b.  Entry  of  water  or  foreign  ma- 
tenal  into  beanng  housing. 

b.  Same  as  6-a. 

b.  Replace  beorings  and  seais 
and  shield  against  entry  of  for- 
eign material  (water,  dust,  etc.). 
Use  proper  motor. 

*  Many  of  these  conditions  should  trip  protective  devices  rather  than  burn  out  motors. 


240  Water  Treatment 


TROUBLESHOOTING  GUIDE  FOR  ELECTF     MOTORS  (continued) 


Symptom 

Caused  By 

A/'pearance 

1  Shorted  motor  winding 

a  Moisture,  chemicals,  foreign  material  in 
motor,  damaged  winding. 

a.  Black  or  burned  with  remainder  of  winding 
good. 

2  All  windings  completely 
burned 

a.  Overload. 

b.  Stalled. 

c.  impaired  ventilation. 

d.  Frequent  reversal  or  starting 

e.  Incorrect  power. 

a.  Burned  equally  all  around  winding 

b    Burned  Pnurlllv  rill  ArmmH  wmHinn 

c.  Burned  equally  all  around  winding 
d  Burned  equally  all  around  winding, 
e.  Burned  equally  all  around  winding. 

3  Single  phase  cond  '  n 

a  Open  circuit  in  one  line.  The  most  common 
causes  are  loose  connection,  one  fuse 
out,  loose  contact  in  switch. 

a.  If  1 800  RPM  motor  —  four  equally  burned 
groups  at  90^  intervals. 

b.  If  1200  RPM  motor  —  six  equally  burned 
groups  at  60**  intervals 

c.  If  3600  RPM  motor  —  two  equally  burned 
groups  at  180^ 

NOTE:  If  Y-connected  each  burned  group 
will  consist  of  two  adjacent  phase  groups. 
If  delta-connected  each  burned  group  will 
consist  of  one  phase  group. 

4  Other 

a.  Improper  connection 
b  Ground. 

a  Irregularly  burned  groups  or  spot  burns. 

Many  burnouts  occur  within  a  short  period  c .  time  after  motor  is  started  up  This  does  not  necessarily  indicate  that  the  motor  was  defec- 
tive, but  usually  is  due  to  one  or  more  of  the  above  mentioned  causes  The  most  common  of  these  are  improper  connections,  open  circuits 
in  one  hne,  incorrect     wer  supply  or  overload 


Maintenance  241 


TROUBLE-REMEDY  CHART  FOR  INDUCTION  MOTORS 


A.  Motor  will  not  start. 

Overload  control  tripped.  Waic  for  overload  to  cool,  then 
try  to  start  again.  If  motor  still  does  not  start,  check  for  the 
causes  outlined  below. 

1.  Open  fuses:  test  fuses. 

2.  Low  voltage-  check  name  plate  value*}  against  power 
supply  characteristics.  Also  rheck  voltage  at  motor 
terminals  when  starting  moi  r  under  load  to  check 
for  allowable  voltage  drop. 

3.  Wrong  control  connections:  check  connections  with 
control  wiring  diagram. 

4.  Loose  terminal-lead  connection:  turn  power  off  and 
tighten  connections. 

6.  Drive  machine  locked:  disconnect  motor  from  load.  If 
motor  starts  satisfactorily,  check  dnven  machine. 

6.  Open  Circuit  in  stator  or  rotor  winding:  check  for  open 
Circuits. 

7.  Short  circuit  in  stator  winding:  check  for  short. 

8.  Winding  grounded:  test  for  grounded  wiring 

9.  Bearing  stiff:  free  bearing  or  replace. 
10.  Overload:  reduce  load. 

8  Motoi  noisy. 

1.  ';;»ree-phase  motor  running  on  single  phase,  stop 
motor,  then  try  to  start.  It  will  not  start  on  single 
phase.  Check  for  open  circuit  in  one  of  ♦  j  lines. 

2.  Electrical  load  unbalanced:  check  current  balance. 

3.  Shaft  bumping  (sleeve-bearing  motor):  check  align- 
ment and  conditions  of  belt.  On  pedestal-mounted 
bearing  check  cord  play  and  axial  centering  of  rotor. 

4.  Vibratiori:  driven  machine  may  U3  unbalanced.  Re- 
move motor  from  load  If  motor  is  still  noisy,  re- 
balance. 

5.  Air  gap  not  uniform:  center  tr  .  rotor  arid  if  necessary 
replace  bearings. 

6  Noisy  ball  bearing:  check  lubrication.  Replace  bear- 
ings if  noise  is  excessive  and  persistent. 

7.  Rotor  rubbing  on  stator:  center  the  rotor  and  replace 
bearings  if  necessary. 

8.  Motor  loose  on  foundation:  tighten  hold-down  bolts. 
Motor  may  possibly  have  to  be  realigned. 

9.  Coupling  loose:  insert  feolers  at  four  places  in  cou- 
pling joint  before  pulling  up  bolts  to  check  alignment. 
Tighten  coupling  bolts  securely. 

C.  Motor  at  higher  than  no*'mal  temperature  or  smoking. 
(Measure  temperature  with  thermometer  or  thermister 
and  compare  with  name  plate  value.) 

1.  Overload:  measure  motor  loading  with  ammeter. 
Reduce  load. 

2.  Electrical  load  unbalance:  check  for  voltage  unbal- 
ance or  single-phasing. 

3.  Restricted  ventilation,  clean  air  passage  and  wind- 
ings.  


4.  Incorrect  voltage  and  frequency:  check  name  plate 
values  with  power  supply.  Also  check  voltage  at 
motor  terminals  with  motor  under  full  load. 

5.  Motor  stalled  by  driven  tight  bearings:  remove  power 
from  motor.  Check  machine  for  cause  of  stalling. 

6.  Stator  winding  shorted  or  grounded:  test  windings  by 
standard  method. 

7.  Rotor  winding  with  loose  connection:  tighten,  if  pos- 
sible, or  replace  with  another  rotor. 

8.  Belt  too  tight:  remove  excessive  pressure  on  bear- 
ings. 

9.  Motor  used  for  rapid  reversing  service,  replace  with 
motor  designed  for  this  service. 

D.  Bearings  hot. 

1.  End  shields  loose  or  not  replaced  properly:  make 
sure  end  shields  fit  squarely  and  are  properly  tight- 
ened. 

2.  Excessive  belt  tension  or  excessive  gear  side  thrust: 
reduce  belt  tension  or  gear  pressure  and  realign 
shafts.  See  that  thrust  is  not  being  transferred  to 
motor  bearing. 

3.  Bent  shaft:  straighten  shaft  or  senci  to  motor  repair 
shop. 


E.  Sleeve  baarings. 

1.  Insufficient  oil:  a^d  oil  —  if  supply  is  very  low,  drain, 
flush,and  refill. 

2.  Foreign  matenal  in  oil  or  poor  grade  of  oil:  dram  oil, 
flush,  and  relubricate  using  industrial  lubricant  rec- 
omrr'  :ded  by  a  reliable  oil  manufacturer. 

3.  Oil  rings  rotating  slowly  or  not  rotating  at  all:  oil  too 
heavy;  dram  and  replace.  If  oil  ring  has  worn  spot, 
replace  with  new  ring. 

4.  Motor  tilted  too  far:  level  motor  or  reduce  tilt  and 
realign  if  necessary. 

5.  Rings  bent  or  otherwise  damaged  in  reassembling: 
replace  rings. 

6.  Rings  out  of  slot  (oil-ring  retaining  clip  out  of  place): 
adjust  or  replace  retaining  clip. 

7.  Defective  bearings  or  rough  shaft:  replace  bearings. 
Resurface  shaft 

F.  Bail  bearings. 

1.  Too  much  grease:  remove  relief  plug  and  let  motor 
run.  If  excess  grease  does  not  come  out,  flush  and 
relubncate. 

2.  Wrong  grade  of  grease:  flush  bearing  and  relubncate 
with  correct  amount  of  proper  grease. 

3.  Insufficient  grease:  remove  relief  plug  and  grease 
bearing. 

4.  Foreign  material  .i  grease:  flush  bearing,  relubricate: 
make  sure  grease  supply  is  clean  (keep  can  covered 
when  not  in  use).   


ERIC 


261 


242  Water  Treatment 


NAHE 


TYPE 


PUMP  RECORD  CARD 

_MAKE  

SIZE 


MODEL 


SERIAL  # 


ORDER  NUMBER 


SUPPLIER 


DATE  PURCHASED 


DATE  INSTALLED 


APPLICATION 


PLANT  # 


Naroe  Plate  Data  and  Pump  Info  Stuffing  Box  Data  Motor  Data 

  Diameter  ^Depth  Name  Serial  #_ 

TOH  

RPM 


Jype_ 


Gage   Press  Disc_ 

Gage  P'-ess  Sue 

Shut  off  Press 

Suction  Head 
Rotation 

Impeller  Type  

Impeller  Dia. 


Impeller  Clear 


Coupl  Type  &  Size 

Front  Brg  I  

Rear  Brg  #  


Lub  Interval 
Lubricant 


Wearing  Rings 


Shaft  Sleeve  Size 

Pump  Shaft  Size  

Pump  Keyway  


Other  Related  Information; 


ERIC 


Pack.  Size_ 
Length  No.  Rings 


H.P. 


Speed 


JLantern  Ring  Flushed 


_Amb1ento_ 
RPM 


Mech.  Seal  Name 


Type_ 


Pump  Materials 


Shaft 


_Wearing  Rings  Casing 


JJearing  Rings  Impeller 


Shaft  Sleeve 


JSlinger 


Shims 


_Gaskets_ 
"0"  Rings 


_Brg.-  Seals  Front_ 
Rear 


asing  Wear  Ring  Size  ID_ 
OD 


z  W1dth__ 
Impeller  Wear  Ring  ID_ 
0D_ 
Width, 


Frame 


Size  Volts 


_Amps_ 


Phase 


jCycle^ 


Shaft  Size 


Key 


_Bear1ng  Front^ 
Rear 


Code 


Typt 


J\mps  (?  Max.  Speed 


Jmps  (?  Shut  Off 


Control  Data  Info 


Starter 


MENA  Size 


Cat.  § 


Heater  Size 


Rated  (? 


J^ontrol  Voltage 


^Variable  Speed 
Typa_ 

Jpeed  Max   


JSpeed  Miri_^ 


Maintenance  243 


MOTOR  STARTERS 


Number 


Title:. 
Mfg.:_ 


Style:. 
Type:_ 


Style_ 
Amps 


Mfg:. 


Style: 


Cat.  No. 


TITLE_ 
Mfg:_ 
HP: 


Phase: 


Cycl  es :. 

Code:  

S0# 


Fonii 


Address 


Class 


Size 


O.L.  HEATERS 
Code 


Mfg:. 


O.L.  TRIP  UNITS 
 Style :_ 


Type: 


Amps  Range: 


CIRCUIT  BREAKER 


Address 


Frame: 


_Volts; 
Amps: 


RPM: 


S.F.: 


Spec. 


50  Cycle  Data_ 


Volts 


Amps  Setting_ 


MOTOR 


Number 


Address 


Ser.  No. 


Duty: 


Frame: 


Temp: 


Jype_ 


Class; 


Model 


Spec . ; 


Style: 


CSA  App:_ 


Shft.  Brg. 


Rear  Brg. 


Suitable  for  208V  Network:   Connection  Diagram 

Additional  data  (6)  (5)  (4)  (6)  (5)  (4) 

  (7)  (8)  (9)  (7)  (8)  (9) 

(1)  (2)  (3)  (1)  (2)  (3) 


ERIC 


244  Water  Treatment 


18.15  Auxiliary  Electrical  Power 
18.150  Safety  First 

Always  remember  that  a  QUALIFIED  ELECTRICIAN 
should  perform  most  of  the  necessary  maintenance  and 
repair  of  electrical  equipment.  If  you  don't  know  the  how, 
why,  and  when  of  the  job,  don't  do  it.  You  could  endanger 
your  life  as  well  as  your  fellow  operators.  Never  attempt 
work  that  you  are  not  qualified  to  do  or  are  not  authonzed  to 
perform. 


18, 15 1  Standby  Power  Generation 

There  are  three  ways  of  providing  standby  power.  One  is 
by  providing  the  treatment  plant  with  an  engine  driven 
generator  set.  The  limit  of  how  much  power  can  be  produced 
IS  determined  only  by  the  size  of  the  generator.  The  second 
possibility  for  standby  power  is  batteries.  Battenes  should 
only  be  considered  for  low  power  consumption  uses  such  as 
emergency  lighting,  communication,  and  possibly  some  con- 
trol and  instrumentation  functions.  The  other  possibility  for 
standby  power  is  a  connection  to  an  alternate  power  source, 
such  as  a  different  substation  or  another  power  company. 

Because  the  treatment  of  water  is  considered  a  critical 
service,  it  is  important  to  be  able  to  provide  drinking  water 
even  with  the  loss  of  commercial  power.  A  power  outage  of 
a  short  duration  probably  will  not  have  adverse  effects  on 
plant  operation.  The  question  you  must  ask  yourself  is,  "Can 
my  plant  meet  the  needs  of  the  public  if  a  'brown  out*  or 
catastrophic  event  eliminates  commercial  power  for  an 
extended  length  of  time?"  If  the  answer  is  "no,"  then  perhaps 
a  form  of  standby  power  generation  should  be  cc  idered. 

The  following  six  conditions  must  be  analyzed  to  deter- 
mine the  need  for  and  size  of  standby  power  generation. 

1.  Frequency  of  power  outages  in  last  10  to  15  years. 

2.  Duration  of  the  power  outage  ir.  each  occurrence. 

3.  Availability  of  additional  source  of  power  supply  from  a 
different  substation  in  the  vicinity. 

4.  Method  by  which  raw  water  reaches  plant  (is  flow  by 
gravity  or  by  a  raw  water  pumping  station*?). 

5.  Total  storage  capacity  of  reservoirs  in  the  distribution 
system. 

6.  Possibility  of  obtaining  a  potable  water  supply  from 
adjacent  cities  (is  there  a  reasonably  sized  pipe  connec- 
tion between  your  system  and  the  distribution  system  of 
an  adjacent  city?). 

If  the  frequency  of  power  outages  is  once  or  twice  a  year 
with  a  10  to  30  minute  duration,  the  capacity  of  a  standby 
power  generator  can  be  relatively  small.  The  minimum  size 
of  a  standby  power  generator  may  require  sufficient  capac- 
ity to  operator  essential  equipment  such  as: 

1.  Coagulant  and  chlorine  feeders, 

2.  One-third  of  flocculators, 

3.  Major  electric  valve  operators  and  plant  control  system, 

4.  One-third  of  pumping  capacity  (if  necessary),  and 

5.  Minimum  lighting. 

er|c 


Where  do  you  begin?  You  have  to  consider  whether  you 
would  like  to  have  all  of  your  facility  operating  or  whether 
just  the  vital  or  key  equipment  would  be  sufficient.  Since  the 
characteristics  and  operating  conditions  of  every  p.ant  are 
different,  it  is  extremely  difficult  to  make  specific  sugges- 
tions. 

For  the  sake  of  illustration,  let  us  pose  a  hypothetical 
situation.  Consider  a  10  MGD  (38  MLD)  capacity  plant  with 
an  average  flow  rate  of  6  MGD  (23  MLD).  Prepare  a  list  of 
needs  that  must  be  met  to  insure  minimal  operation: 

1.  Raw  water  pumping, 

2.  Clanfication, 

3.  Clear  water  pumping, 

4.  Chlorination,  and 

5.  Minimal  lighting. 

Calculate  the  maximum  horsepower  or  total  kilowatts 
necessary  to  maintain  the  limited  operation: 

1.  Raw  Water  Pump  —  75  horsepower 

2.  Clanfication  —  2V2  horsepower 

3.  Clear  Water  Pump     40  horsepower 
4  Chlonnation  —  15  horcepower 
5.  Lighting 


56.00  kW 
2.24  kW 
30.00  kW 
11.20  kW 
5.00  kW 
104.44  kW 

The  minimum  power  required  is  104.44  kW.  When  sizing  a 
generator  for  emergency  power,  you  have  to  make  sure  that 
the  operator  will  be  able  to  start  the  needed  motors.  Since 
the  locked  rotor  current  of  the  75  horsepower  induction 
motor  on  the  raw  water  pump  is  approximately  four  times 
running  current,  then  the  generator  must  be  able  to  handle 
224  kW  at  that  instant.  Size  the  generator  not  only  by  total 
load,  but  also  for  the  highest  horsepower  motor  being 
started.  Consider  the  sequence  in  which  motors  will  be 
started.  The  starting  of  all  the  motors  simultaneously  (with- 
out sequence  starting)  wculd  be  nearly  impossible.  Consult 
experts  in  power  generation  for  answers  to  your  specific 
questions  regarding  your  plant  because  each  plant  has 
different  needs  If  you  are  considering  standby  power,  shop 
around  and  get  ideas  from  the  equipment  manufacturers. 
You  may  be  able  to  reduce  the  size  of  the  generator  by  using 
reduced  voltage  starters  on  the  larger  motors. 

After  you  have  determined  the  size  or  generator  needed, 
you  must^be  able  to  connect  it  to  ycjr  power  distribution 
system.  This  may  require  some  sophisticated  switch  gear. 
Besides  the  mechanical  functions  necessary  in  connecting 
the  emergency  power  with  your  normal  system,  it  is  impor- 
tant that  the  two  systems  cannot  be  electrically  coupled. 
(Two  electrical  systems  must  be  "in  phase"  v/ith  each  other 


264 


Maintenance  245 


before  parallel  coupling.)  For  this  reason,  mechanical  inter- 
locks are  used  to  insure  that  one  circuit  is  always  open.  A 
"kirk-key"  system,  where  one  key  is  used  for  two  locks, 
locking  one  sw'tch  open  before  the  other  can  be  closed,  is 
sometimes  used.  The  manufacturers  of  most  packaged 
motor-generator  systems  can  provide  automatic  transfer 
switches  that  will  automatically  start  the  generator  when  a 
power  failure  occurs  and  connect  the  generated  power  into 
the  plant  power  aistribution  wiring. 

Looking  back  at  the  plant  described,  a  generator  of  125 
kW  with  intermittent  overload  capabilities  should  handle  the 
load.  (Note:  This  is  an  assumption.  Actual  calculation  may 
indicate  a  different  size.)  An  engine-generation  system  of 
this  size  could  handle  your  minimal  power  needs.  If  your 
water  distribution  system  has  ample  capacity,  it  may  be 
possible  to  cut  the  plant  production  rate  to  reduce  power 
requirements  to  what  can  be  handled  with  a  smaller  capacity 
generator. 

If  you  do  not  have  standby  power  generation  at  your 
facility,  talk  to  others  in  the  water  treatment  field  who  do  and 
obtain  ideas  and  information.  After  due  consideration,  take 
the  necessary  steps  to  insure  yourself  against  interrupted 
power. 

Standby  power  generators  should  be  operated  on  a 
regular  basis  (once  a  week)  to  be  sure  they  wih  operate 
properly  when  needed.  Be  sure  to  operate  your  generator  at 
full  load  for  at  least  an  hour.  Commercial  power  into  your 
plant  must  be  shut  off  to  operate  standby  power  at  full  load. 

18. 152  Emergency  Lighting 

The  most  practical  form  of  emergency  lighting  in  most 
instances  is  that  provided  by  battery-powered  lighting  units. 
Because  they  are  used  primarily  for  exit  lighting,  they  are 
more  economical  than  engine-driven  power  sources.  If  you 
have  a  momentary  power  outage,  the  system  responds 
without  an  engine-generator  start-up.  All  emergency  lighting 
unit  equipment  is  basically  the  same  and  consists  of  a 
rechargeable  battery,  a  battery  charger,  low  voltage  flood 
lights,  and  test  monitoring  and  control  accessories.  Proper 
selection  of  a  unit  for  a  particular  location  requires  careful 
consideration  of  the  following  itens: 

1.  Initial  cost, 

2.  Types  of  batteries, 

3.  Maintenance  requirements,  and 

4.  Lighting  requirements. 

The  three  types  of  batteries  most  commonly  used  are: 
lead  acid,  lead  calcium,  and  nickel  cadmium  Because  poor 
battery  maintenance  is  quite  common  in  emergency  lighting 
systems,  "maintenance  free"  batteries  are  becoming  in- 
creasingly popular.  These  batteries  can  have  a  gelatin  or 
acid  (wet)  ELECTROLYTES  The  gelatin  type  is  completely 
spillproof  and  can  be  handled  safely  without  the  dangers  of 
acid  spills.  These  batteries  have  a  shorter  life  span  than  the 
wet  type.  Since  all  batteries  undergo  evaporation,  the  gelatin 
electrolyte  wui  be  exhausted  before  that  of  a  battery  contain- 
ing liquid.  Wet-lype  maintenance  free  batteries  require  no 
refilling  and,  when  handled  properly,  acid  spillage  Is  minimal. 

In  terms  of  cost,  the  maintenance-free  battery  is  more 
expensive:  but  when  you  consider  the  human  factor,  they 
may  be  more  reliable  and  cheaper  in  the  long  run.  Most 
systems  use  a  battery  charger  that  monitors  the  battery 
voltage.  When  required,  the  charger  then  charges  the  batter- 


ies. In  earlier  designed  units,  a  trickle  charger  was  used 
This  constant  charging  resulted  in  inoperative  batteries  in  a 
short  time  because  of  overcharging 

The  lamps  used  are  normally  6  to  12  volt  sealed-beam  25- 
watt  lamps  The  light  pattern  provided  is  most  effective  when 
Illuminating  a  work  area.  A  rule  of  thumb  is  that  one  lamp  will 
be  sufficient  for  about  1.000  square  feet,  providing  that  the 
full  light  pattern  can  be  used.  Consult  emergency  light  level 
codes  (Table  18.2)  for  your  particular  application. 

W'len  selecting  an  emergency  lighting  system,  check  it 
very  thoroughly  to  insure  that  it  will  give  you  the  protection 
needed.  If  it  fails  to  work  ./hen  the  chips  are  down  and  the 
mar  oower  is  out,  you've  wasted  your  money. 

18.153  Batteries 

This  section  will  discuss  wet  storage  batteries  since  they 
are  the  most  prevalent.  Automotive  and  equipment  batteries 
are  usually  of  the  lead-acid  type.  This  indicates  that  the 
dissimilar  plates  are  made  of  two  types  of  lead  and  the 
electrolyte  is  sulfuric  acid.  Wet-type  batteries  can  also  be 
mckel  cadmium  or  nickel  iron. 

Most  batteries  are  a  series  of  cells  enclosed  in  a  common 
case.  Each  of  these  cells  develops  a  potential  (voltage)  of 
2  3  volts  per  cell  when  fully  charged.  Hence,  a  six-volt 
battery  contains  three  cells  and  a  12-volt  battery  has  six 
cells.  The  voltage  output  of  a  12-volt  battery  is  13.8  volts 
when  fully  charged.  Once  a  lead-acid  battery  has  been 
placed  in  service,  the  addition  of  sulfuric  acid  is  not  neces- 
sary. The  water  portion  of  the  electrolyte  solution  evapo- 
rates as  the  battery  is  charged  and  discharged.  Lost  watDr 
must  be  replaced.  Deionized  or  distilled  water  should  be 
used.  Tap  water  contains  impurities  that  shorten  the  life 
span  of  a  battery  if  used  to  replace  lost  water.  These  minute 
particles  become  attached  to  the  lead  plates  and  co  not 
allow  the  battery  to  rejuvena.    self  fully  when  charged. 

When  batteries  are  placed  on  charge,  remove  the  cell 
covers  to  allow  the  gas  (hydrogen)  caused  by  charging  to 
escape  and  not  to  build  excessive  pressure  in  the  battery.  A 
battery  on  charge  is  as  lethal  as  a  small  bomb  if  you  ignite 
the  gas.  Do  not  smoke  or  cause  electrical  arcing  near  the 
battery.  Do  not  breath  the  gas  and  make  sure  that  the  area 
where  a  battery  is  being  charged  is  well  ventilated. 

The  keys  to  prolonged  life  of  a  battery  are  to  '<eep  the 
electrolyte  level  above  the  cell  plates,  to  keep  the  battery 
fully  charged,  and  above  all,  to  keep  the  terminals  and  top 
clean.  When  dirt  and  residue  accumulate  on  the  top  of  a 
battery,  it  forms  a  path  for  current  to  flow  between  the 
negative  and  positive  posts.  Take  a  multimeter,  connect  cne 
lead  to  the  proper  post  (it  will  cause  up-scale  deflection)  and 
s'owly  slide  the  other  lead  across  the  top  of  the  battery 
toward  the  other  post.  If  the  top  is  dirty,  the  meter  will  deflect 
mc?  as  you  proceed  across  the  top. 


ti  Electrolyte  (ee-LECK-tro-LlGHT),  A  substance  which  dissociates  (separztes)  into  two  or  more  ions  when  it  is  dissolve  '  in  water 


ERIC 


246  Water  Treatment 


Hazard  requiring  visual 
detection 

NORMAL 
ACTIVITY 
LEVEL* 

Areas 


TABLE  18.2   lES  RECOMMENDED  EMERGENCY  LIGHT  LEVELS^ 

Slight  High 


LOW 

Conference  rooms 
Reception  rooms 
Exterior  floodlighting 
Closets 


Footcandles 
Dekalux 


0.5 
0.54 


HIGH 

Lobbies 

Corridors 

Concourse 

Restrooms,  washrooms 
Telephone  switchboard 

rooms 
Exterior  entrance 
Exterior  floodlighting 


1.0 
1.1 


LOW 

Elevators  (freight) 
File  rooms 
Mail  rooms 
Offices 
Stairways 
Stockrooms 
Exterior  entrance  with 
stairs 


2.0 

2.2 


HIGH 

Elevators 
Escalators 
Computer  rooms 
Drafting  rooms 
Offices 
Stairways 
Transformer  vaults 
Engine  rooms 
Electrical,  mechanical, 
plumbing  rooms 

5.0 

2.2 


Minimum  illumination  for  safety  of  personnel,  absolute  minimum  at  any  time  and  at  any  location  on  any  plane  where  safety  is  related  to 
seeing  conditions.  ' 

•  Special  conditions  may  require  different  levels  of  illumination.  In  some  cases  higher  levels  may  be  required  as  for  example  where  securi- 
ty IS  a  factor  In  some  other  cases  greatly  reduced  levels  of  illumination,  including  total  darkness,  may  be  necessary  specifically  in  situa- 
tions involving  manufacturing,  handling,  use.  or  processing  of  light-sensitive  materials  (notably  in  connection  with  photographic 
products).  In  these  situations  alternate  methods  of  insuring  safe  operation  must  be  relied  upon. 
EMERGENCY  LIGHT  LEVEL  codes  and  standards  vary  widely  throughout  the  country  Recommended  minimurr  lighting  levels  of  the  Illu- 
minating engineering  Society  are  being  considered  as  a  possible  standard  by  ANSI  and  the  Life  Safety  Code.  These  are  minimum  liqhtinq 
levels  recommended  for  safety  of  personnel. 

a  Reprinted  from  December  1978  issue  Electrical  Cor.struction  and  Maintenance.  Copyright  1978  McGraw-Hill.  Inc  All  rights  reserved. 


To  Clean  the  battery,  use  a  stiff-bristled  brush  (not  a  wire 
brush)  and  remove  the  heavy  material.  Then  wash  with  a 
solution  of  baking  soda  and  water  (four  teaspoons  of  baking 
soda  to  one  quart  of  water).  This  will  remove  the  acid  film 
from  the  top  and  neutralize  corrosion  on  the  battery  termi- 
nals. Rmse  with  fresh  water  and  dry  the  top  with  a  dry, 
lintless  cloth.  Remove  cell  caps  and  wipe  between  them, 
then  replace.  At  this  time  check  to  be  sure  that  the  battery 
terminals  are  clean  and  tight.  If  a  battery  is  charged,  but  the 
terminals  are  loose,  proper  voltage  and  current  cannot  be 
delivered. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  t/,ose  on  page  32^». 

18  15A  Why  should  a  qualified  electrician  perform  most  of 
the  necessary  maintenance  and  repair  of  electrical 
equipment? 

18.15B  What  is  the  purpose  of  a  "kirk-key"  system? 

18  15C  Why  are  battery-powered  lighting  units  considered 
better  than  engine-driven  power  sources? 

18.15D  Why  should  the  water  lost  from  a  lead-acid  battery 
be  replaced  with  deionized  or  distilled  water? 

18.16  High  Voltage 

18.160  Transmls^f'cn 

In  general  terrr'j,  high  voltage  is  the  voltage  transmitted  to 
the  plant  site  by  the  utility  company.  The  voltage  level  can 
vary,  but  12,000  volts  is  quite  common.  After  the  power 

Er|c 


reaches  *i  b  plant,  it  is  transformed  down  to  a  useable 
voltage  (  .0  to  480  volts)  either  through  utility-owned  or 
customer-owned  transformers.  The  NEC  (National  Electrical 
Code)  denotes  high  voltages  as  those  over  600  volts. 

Why  have  high  voltage?  Since  current  (amperes)  vanes 
inversely  with  voltage,  a  load  of  500  amps  on  the  low  voltage 
side  of  the  transformer  would  create  a  20  amp  load  on  the 
high  voltage  side  of  a  12,000  volts/480  volt  transformer. 
Transmission  lines  would  have  to  be  enormous  in  order  to 
carry  the  load  if  a  lower  voltage  were  used.  Where  high 
voltage  cables  terminate  at  a  transformer  or  switch  gear, 
certain  conditions  must  be  adhered  to.  If  outdoor  transform- 
ers are  used  that  have  high  voltage  wires  exposed,  an  eight- 
foot  (2.4  m)  high  fence  is  required  to  prevent  accessibility  by 
unqualified  or  unauthorized  persons.  Signs  attached  to  the 
fence  must  indicate  "High  Voltage."  Specifications  for  clear- 
ances, grounding,  access,  and  enclosures  vary  with  installa- 
tions. Any  modification  or  repair  work  must  be  completed  by 
qualified  people  oniy. 

18.161   Switch  Gear 

When  we  see  the  term  "switch  gear,"  it  is  usually  associat- 
ed with  the  equipment  used  in  the  interruption,  transfer,  or 
disconnecting  of  voltages  over  600  ^/oWs.  The  enclosure  is 
designed  and  manufactured  to  safely  control  high-voltage 
switching.  Most  distribution  systems  have  a  load-interrupt- 
ing switch  that  is  capable  of  disconnecting  high  voltage  lines 
that  are  unde,  load.  Because  of  the  arc  that  is  caused  in 
breaking  the  circuit,  special  "arc  shoes'*  (arc-suppressant 
devices)  are  used  to  ensure  that  the  contact  points  are  not 
p  tted.  A  keyed  lock  system  is  used  to  prevent  opening  of  the 
enclosure  in  the  eneigized  state. 


26'6 


Maintenance  247 


Probably  the  best  preventive  maimenance  that  a  treat- 
ment plant  operator  can  provide  for  switch  gear  is  to  keep 
the  exterior  and  its  surroundings  clean  if  you  encounter 
difficulties  in  the  course  of  operating  the  switches,  please 
obtain  qualified  help  to  do  the  inspection  or  lepairs  needed 
Check  with  your  particular  manufacturer  to  determine  what 
IS  needed  and  when  this  has  to  be  done  to  keep  your  system 
functioning  as  designed.  If  your  equipmeiit  is  in  a  corrosive 
atmosphere,  it  may  be  necessary  to  remove  it  from  service 
and  expoxy  paint  the  internal  buses.  All  pivoting  points 
should  be  lubricated  with  a  lubricant  specified  by  the  manu- 
facturer. 

18. 162  Power  Distribution  Transformers 

If  the  high  voltaje  transformers  are  owned  by  the  utility, 
the  inspection  and  maintenance  is  earned  out  by  the  utility. 
Any  peculiar  changes,  smells,  or  noises  should  be  reported 
to  the  utility.  When  transformers  are  customer  owned,  a 
regular  inspection  program  should  be  established. 

Most  transformers  use  an  oil  to  insulate  as  well  as  to  cool 
the  windings.  As  heat  is  generated  in  the  windings,  it  is 
transferred  to  the  oil.  The  oil  is  then  cooled  by  air  passing  the 
cooling  fins  of  the  transformer.  The  prinnary  requirements 
of  the  oil  are: 

1.  High  dielectric  strength; 

2.  Freedom  from  inorganic  acid,  alkali,  and  sulfur  to  prevent 
injury  to  insulation  and  conductors; 

3.  Low  viscosity  to  provide  good  heat  transfer:  and 

4.  Freedom  from  sludging  under  normal  operation  condi- 
tions. 

The  principal  causes  of  deterioratio..  of  insulating  oil  are 
water  and  oxidation.  The  oil  may  be  exposed  to  moisture 
through  condensation  of  moist  air  due  to  "breathing"  of  the 
transformer,  especially  v^hen  the  transformer  is  not  continu- 
ously in  service.  The  moist  air  condenses  on  the  surface  of 
the  oil  and  on  the  inside  of  the  tank.  Oxidation  causes 
sludging.  The  amount  of  sludge  formed  in  a  given  oil 
depends  upon  the  temperature  and  the  time  of  exposure  of 
the  oil  to  the  air.  Excessive  operating  temperatures  may 
cause  sludging  of  any  transformer  oil.  Check  with  the 
manufacturer  to  determine  how  often  the  oil  should  oe 
tested.  Oil  can  be  revitalized  by  a  cleaning  procedure  that  is 
accomplished  at  the  transformer  site. 

Any  symptoms  such  as  unusual  noises,  high  or  low  oil 
levelc.  oil  leaks,  or  high  operating  temperatures  should  be 
investigated  at  once.  If  your  transformer  has  a  thermometer. 
It  IS  of  the  alcohol  type  and  should  be  replaced  with  that  type 
only.  A  mercury-type  thermometer  could  cause  insulation 
failures  by  reason  of  proximity  of  a  metallic  substance, 
regardless  of  whether  it  is  intact  or  broken. 

The  tank  of  every  power  transformer  should  be  grounded 
to  eliminate  the  possibility  of  obtaining  static  shocks  from  it 
or  from  being  injured  by  accidental  grounding  of  the  winding 
to  the  case. 

If  repairs  are  indicated,  u3e  the  expertise  of  a  qualified 
person  to  ensure  that  the  repairs  are  made  safely  as  well  as 
correctly.  Your  life  and  the  lives  of  others  may  depend  on  the 
use  of  qualifiea  people. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  cortipare  your 
answers  with  those  on  page  324. 

ERIC 


18  ISA  Why  IS  electricity  transmitted  at  h'gh  voltage'' 

18  16B  What  precautions  must  be  taken  if  outdoor  trans- 
formers have  exposed  high  voltage  wires'' 

16  i6C  'vVhdl  Kind  of  rnainlenance  should  a  treatment  plant 
operator  perform  on  switch  gear'' 

18  16D  What  symptoms  indicate  that  a  power  distribution 
transformer  may  be  m  need  of  maintenance  or 
repair'' 

18.17  Electrical  Safety  Check  List 

Throughout  this  manual  and  throughout  this  cnapter  the 
need  for  electrical  safety  is  always  being  stressed.  This 
section  contains  an  electncal  safety  check  list  which  is 
provided  to  help  you  ensure  that  you  have  minimized  electri- 
cal hazards  m  your  plant.  This  list  is  piovided  to  make  you 
asr.are  of  potential  electrical  hazards.  You  should  add  to  the 
list  additional  electrical  hazards  that  could  in|ure  someone  at 
your  water  treatment  plant. 

1  Are  there  any  conduits  rusted  to  the  point  where  they 
might  have  lost  their  explosion  proof  integrity'' 

2.  Are  there  any  elect-ical  conduit  hangers  that  are  rusted 
so  bad  that  they  are  allowing  the  conduit  to  sag? 

3  Are  there  any  fasteners  on  the  conduit  hangers  that  are 
rusted  and  allowing  the  conduit  to  hang  by  the  wires? 

4  Do  all  of  the  extension  cords  and  power  tools  meet  code 
requirements  for  use  in  wet  areas? 

5.  Does  the  age.'icy  or  utility  have  a  policy  covering  the 
proper  placement  of  portable  ventilation  equipment  whcr^ 
operators  work  inside  enclosed  tanks,  vaults  and  other 
confined  spaces'' 

6.  Does  the  agency  use  proper  grounding  units  (ground 
fault  interruptor3)  when  working  in  wet  areas? 

7.  Is  the  g-ounding  of  electrical  equipment  and  systems 
inspected  regularly? 

8  Are  electrical  breakers  and  controls  clearly  marked'' 

9  Is  there  a  formal  program  for  lock.ng  out,  tagging  and 
blockout  of  electncal  devices? 

If  you  can  answer  these  questions  properly,  you  are 
working  in  the  nght  Oirection  to  minimize  electrical  hazards 
in  your  water  treatment  plant. 

QUESTIONS 

Write  your  answers  m  a  notebook  and  then  compc  'e  your 
answers  v^rith  those  on  page  324. 

18.17A  Why  are  rusted  conduits  of  concern  to  a  water 
treatment  plant  operator'' 

18.17B  What  is  the  purpose  of  an  electrical  safety  check 
'•sf 

18.18  Additional  Reading. 

1.  BASIC  ELECTRICITY  by  Van  Valkenburgn,  Nooger  & 
Neville.  Inc.  Obtain  from  The  Brolet  Press,  33  Gold  Street, 
New  York.  N.Y.  10038.  $39.95  for  combined  Edition  of  all 
five  volumes. 

a.  Volume  1.  Price  $10.50. 
Where  Electricity  Comes  From 
Electncity  in  Action 
Current  Flow,  Voltage,  Resistance 
f^agnetism.  DC  [Meters 


248  Water  Treatment 


b.  Volume  2.  Price  $10.50 
Direct  Current 

Ohm's  and  Kirchoff  s  Law 
Electric  Power 

c.  Volume  3.  Price  $10.50. 
Alternating  Current 

Resistance.  Inductance.  Capacitance  m  AC 

Reactance 

AC  Meters 

d.  Volume  4.  Price  $10.60. 
Impedance. 

Alternating  Current  Circuits 
Series  and  Parallel  Resonance 
Transformers 

e.  Volume  5.  Price  $10.50. 
DC  Generators  and  Motors 
Alternators  and  AC  Motors 
Power  Control  Devices 

NOTE'  For  an  additional  S2  00  per  volume,  you  can 
obtain  an  "interactive  Self-Learning  Package.' 

f   Other  Training  Programs 
Bas«c  Electronics.  6  Volumes 
Basic  Industrial  Electricity.  2  Volumes 

2  "Maintenance"  by  Stan  Wuiton.  Volume  II.  Chapter  15  in 
OPERATION  OF  WASTEWATER  TREATMENT  PLANTS, 
Kenneth  D.  Kern.  California  State  University.  Sacramen- 
to. 6000  J  Street.  Sacramento.  CA  95819.  Price  for 
Volume  II.  $25.00. 

3.  "Instrumentation"  by  George  Ghara,  Chapter  8,  in  AD- 
VANCED WASTE  TREATMENT  Kenneth  D.  KerrI,  Cali- 
fornia State  University,  Sacramento.  6000  J  Street,  Sac- 
ramento, CA  95819.  Price,  $20.00. 


4  ELECTRICITY  PRINCIPLES  AND  PRACTICES  by  Ad- 
ams. McGraw-Hill  Book  Company  817^  Redwood  High- 
way Novato.  CA  94547  Price  S24.95. 

5.  "Electrical  and  Automation,"  Chapter  XII  in  WATER  DIS- 
TRIBUTION OPERATOR  TRAINING  HANDBOOK,  by  LE. 
Nichols  and  B.W.  Jex.  Obtain  from  American  Water 
Works  Association,  6666  W.  Quincy  Ave.,  Denver,  Colo- 
rado 80235.  Order  No.  20103.  Price  $14.50  for  members 
of  AWWA,  $17.50  for  others. 

6.  MAINTENANCE  ENGINEERING  HANDBOOK  by  Higglns, 
McGraw-Hill  Book  Company,  PO  Box  402,  Highstown, 
New  Jersey  08520.  Price  $79.50. 

7.  ELECTRICITY  FOR  WATER  AND  WASTEWATER 
TREATMENT  PLANT  OPERATORS.  Available  from  Na- 
tional Environmental  Training  Association,  8687  Via  de 
Ventura,  Suite  214,  Scottsdale,  AZ  85258.  Price  $181.50. 

8.  MECHANICAL  MAINTENANCE  FOR  WATER  AND 
WASTEWATER  TREATMENT  PLANT  OPERATORS. 
Available  from  National  Environmental  Training  Associ- 
ation, 8687  Via  de  Ventura,  Suite  214,  Scottsdale,  AZ 
85?58.  Price  $156.50. 


6 fid  c(  IC^OK  1     5  Ic^^ 

MAINTCNANJe 


Please  answer  the  discussion  and  rt  view  questions  be- 
fore continuing  with  Lesson  2. 


DISCUSSION  AND  REVIhW  QUESTIONS 

ChaptenS.  MAINTENANCE 

(Lesson  1  of  5  Lessons) 


At  the  end  of  each  lesson  in  this  chapter  you  will  find  some 
discussion  and  review  questions  that  you  should  work 
before  continuing.  The  purpose  of  these  questions  is  to 
indicate  to  you  how  well  you  understand  the  material  in  the 
lesson. 

Write  the  answers  to  these  questir  '  in  your  notebook. 

1  Why  should  operators  thoroughly  »cad  and  understand 
manufacturers'  literature  before  attempting  to  maintain 
plant  equipmenf^ 

2  Why  must  administrators  or  supervisors  be  made  aware 
of  the  need  for  an  adequate  maintenance  program'^ 

3.  What  IS  the  purpose  of  a  maintenance  recordkeeping 
program? 

4.  What  Items  should  be  included  in  a  plant  library'? 

5-  Why  should  your  plant  have  an  emergency  team  to 
repair  chlorine  leaks'? 


B  Why  should  one  person  never  be  permitted  to  repair  a 
chlorine  leak  alone'? 

7  Why  should  inexperienced,  unqualified  or  unauthorized 
persons  and  even  qualified  and  authorized  persons  be 
extremely  careful  around  electrical  panels,  circuits,  wir- 
ing and  equipmenf? 

8  What  protective  or  safety  devices  are  used  to  protect 
operators  and  equipment  from  bemq  harmed  by  elec- 
tric y'? 

9  Why  must  motor  name  pi.-'te  data  be  recorded  and  filed? 

10  What  might  be  the  cause  ot  a  pump  motor  failing  to 
start? 

11  Why  should  a  water  treatment  plant  have  standby 
power'? 

12  How  would  you  deterrnme  the  capacity  of  standby 
generation  equipmenf? 


Maintenance  249 


CHAPTER  18.  MAINTENANCE 

(Lesson  2  of  5  Lessons) 


18.2   MECHANICAL  EQUIPMENT 

Mechan-cal  equipment  commonly  lised  in  water  treatment 
plants  is  describa;  and  d  3c  jssea  in  this  section.  Equipment 
used  with  specific  treatme'il  processes  such  as  flocculation 
and  filtration  is  not  discussed.  You  must  be  familiar  with 
equipment  and  understand  what  it  is  intended  to  do  before 
developing  a  preventive  maintenance  program  and  main- 
taining equipment. 

18.20  Repair  Shop 

Many  large  plants  have  fully  equipped  mach;ne  shops 
staffed  with  competent  mechanics.  But  for  smaller  plants, 
adequate  macnine  shop  facilities  often  can  be  found  in  the 
community.  In  addition,  most  pump  manufacturers  maintain 
pump  repair  departments  where  pumps  can  be  fully  recondi- 
tioned. 

The  pump  repair  shop  ir  a  large  plant  commonly  includes 
such  items  as  welding  equipment,  lathes,  drill  press  and 
drills,  power  hacksaw,  flame-cutting  equipment,  microme- 
ters, calipers,  garss,  portable  electric  tools,  grinders,  a 
forcing  press,  metal-spray  equipment,  and  sand-blasting 
equipment,  ^'ou  must  determine  what  repair  work  you  can 
anf^  should  do  and  when  you  need  to  request  assistance 
from  an  expert. 

Some  agencies  have  their  own  repair  shops  or  local 
machine  shops  rebuild  parts  rather  than  buying  direct  from 
manufacturers.  Many  agencies  try  to  select  equipment  on 
the  basis  the  reputations  of  distributors  for  supplying 
repair  parts  when  needed.  A  parts  inventory  is  essential  for 
key  pieces  c  .quipment. 

18.21  Pumps 

Pumps  serve  many  purposes  in  water  treatment  plants. 
They  may  be  classified  by  the  character  of  tht  material 
handled,  such  as  raw  or  filtered  v^ater.  Or,  they  may  relate  to 
the  conditions  of  pumping:  high  lift,  low  lift,  or  high  capacity. 
They  may  be  further  classified  by  principle  of  operation, 
such  as  centrifugal,  propeller,  reciprocating,  and  turbine 
(Figure  18.14). 

The  type  of  material  to  be  handled  and  the  function  or 
required  performance  of  the  pump  vary  so  widely  that  the 
designing  engineer  must  use  great  care  in  preparing  specif»- 
cations  for  the  pump  and  its  controls.  Similarly,  the  operator 
must  conduct  a  maintenance  and  management  program 
adapted  to  the  peculiar  characteristics  of  the  equipment. 

18.210  Centrifuga!  Pumps 

A  centrifugal  pump  is  basically  a  very  simple  device;  an 
impf-'ier  rotating  in  a  casing.  The  impeller  is  supported  on  a 
shaft  which  is,  in  turn,  supported  by  bearings.  Liquid  coming 
in  at  the  center  (eye  of  the  impeller  (Fipure  18.15))  is  picked 
up  by  the  vanes  and  by  the  rotation  of  tne  impeller  and  then 
is  thrown  out  by  centrifugal  force  nto  the  discharge. 

To  help  you  understand  how  pumps  work  and  the  purpose 
of  the  various  parts,  a  section  titled  "Let's  Build  a  Pump"  has 
been  included  the  followinq  pages.  This  material  has 
been  repririied  with  \he  permission  of  Allis-Chalmers  Corpo- 


ration, Milwaukee,  Wisconsin,  Industrial  Pump  Division,  Nor- 
wood. Ohio.  Originally,  the  material  was  printed  in  Allis- 
Chalmers  Bullei.  08X62568. 

18.211   Let's  Build  a  Pump! 

A  student  of  medicine  spends  long  years  learning  exactly 
how  the  human  body  is  built  before  attempting  to  prescribe 
for  Its  care.  Knowledge  of  PL^/WP anatomy  is  equally  basic  in 
caring  for  centrifugal  pumps! 

But  whereas  the  medical  student  must  take  a  body  apart 
to  learn  its  secrets,  it  will  be  far  more  instructive  to  us  if  we 
put  a  pump  TOGETHER  (on  paper,  of  course).  Then  we  can 
start  at  the  beginning  —  adding  each  new  part  as  we  need  it 
in  logical  sequence. 

As  we  see  WHAT  each  part  does,  HOlVit  does  it . . .  we'll 
see  how  it  must  be  CARED  FOR! 

Another  analogy  between  medicine  and  maintenance: 
there  are  various  types  of  human  bodies,  but  if  you  know 
basic  anatomy,  you  understand  them  all.  The  same  is  true  of 
centrifugal  pumps.  In  building  one  oasic  type,  we'll  learn 
about  ALL  types. 

Part  of  this  will  be  elementary  to  some  maintenance 
people  ...  but  they  will  find  it  a  valuable  "refresher"  course, 
and,  after  all,  maintenance  just  can't  be  too  good. 

So,  with  a  glance  at  the  centrifugal  principle  on  page  252, 
let's  get  on  with  building  our  pump  . . . 

FIRST  WE  REQUIRE  A  DEVICE  TO  SPIN  LIQUID  AT  HIGH 
SPEED  . . . 

That  paddle-wheel  device  is  called  the  "impeller" . . .  and 
It's  the  heart  of  our  pump. 

Note  that  the  blades  curve  out  from  its  hub.  As  the  impeller 
spins,  liquid  between  the  blades  is  impelled  outward  by 
centrifugal  force. 


2IJ3 


PUMPS 


PUWPS 


DYNAMIC 


— 'OlSPLACEMFNT 


CENTRIFUGAL 


—  AXIAL  FLOW 


SINGLE  STAGE -IT  CLOSED  IMPELLER 

H  pFlXCD  PITCH 

J  u        -  -»  ' 


MULTISTAGE 


•OPEN  IMPELLErH 


-VARIABLE  PITCH 


MIXED  FLOW. 
RADIAL  FLOW 


SINGLE 
SUCTION 

.  00'J8LE 
SUCTiON 


f-  SELF -PRIMING  -i 
NONPRIMING  — 
SINGLE  STAGE 
MULTISTAGE  — ' 


OPEN 
IMPELLER 

,  SEMI-OPEN 
IMPELLER 

CLOStD 
IMPELLER 


PERIPHE.'JAL 


p  Single  staget  tSElf-priming 


MULTISTAGE 


SPECIAL  EFFECT 


NONPRIMING 

JET (EDUCTOR) 

-  GAS  LIFT 

-  HYDRAULIC  RAM 

-  ELF.CTROMAGNETIC 


Dynamic  types  of  pumps 


r  DISPLACEMENT 


DYNAMIC  j 


-  RECIPROCATING 


2V" 


PISTON. 
PLUNGER 


r-  STEAM -DOUBLE  ACTING 


SIMPLEX 
DUPLEX 


POWER 


SINGLE  ACTING  -i 
DOUBLE  ACTING  J~ 


-  SIMPLEX 

I- DUPLEX 
-  TRIPLEX 
^  MULTIPLEX 


DIAPHRAGM 


|—  SIMPLEX  -I  - 
1- MULTIPLEX  -i  L 


-  FLUID  OPERATED 


MECHANICALLY  OPERATED 


ROTARY 


SINGLE  ROTOR 


-  VANE 

-  PISTON 

Flexible  member 


MUL'^IPLE  ROTOR 


-  SCREW 

-  PERISTALTIC 
p  GEAR 

-  LOBE 

-  CIRCUMFERENTIAL  PISTON 

-  SCREW 


Displacement  types  of  pumps 


Fig.  18, 14  Classification  of  pumps 


Maintenance  251 


Refer  to  Fig.  18.18,  pages  258  and  259,  for  location  of  impeller  in  pump 


Fig.  18. 15  Diagram  showing  details  of  centrifugal  pump  impeller 

(Source  CENTRIFUGAL  PUMPS  by  Karasstk  and  Curter  of  Worthtngton  Corporation) 


Note,  too,  that  our  impeller  is  open  at  the  center  —  the 
••eye."  As  liquid  in  the  impeller  moves  outward,  it  will  suck 
more  liquid  in  behind  it  through  this  eye  . . .  PROVIDED  IT'^^ 
NOT  CLOGGED! 


That  brings  up  Maintenance  Rule  No.  1;  if  there's  any 
danger  that  foreign  matter  (sticks,  refuse,  etc.)  may  be 
sucked  into  the  pump  —  clogging  or  wearing  the  impeller 
unduly  —  PROVIDE  THE  INTAKE  END  OF  THE  SUCTION 
PIPING  WITH  A  SUITABLE  SCREEN. 


NOW  WE  NEED  A  SHAFT  TO  SUPPORT  AND  TURN  THE 
IMPELLER . . . 

Our  shaft  looks  heavy  —  and  it  IS.  It  must  maintain  the 
impeller  in  precisely  the  right  place. 

But  that  ruggedness  does  A/07  protect  the  shaft  from  the 
corrosive  or  abrasive  effects  of  the  liquid  pumped  ...  so  we 
must  protect  it  with  sleeves  slid  on  from  either  end. 

ERLC 


271 


Water  Treatment 


ALL  AA0VIN6  BOOiCS  TEHOTOTRAVeLINASrRAHHT 
UNE.WHCN  FORCED  TO  TRAVEL  IN  ACURVEflHCY 
CONSTANTLY  TRY  TO  TRAVEL  ON  ATANOCNT.^ 


Otntriiugai  force  pushes  dummy  planes  smmg' 
in  a.  eirde        /rom  center  cj^iritation.. 


...  /Af^ 


Centrifugal  fsrec  tends  to  putfi  swirling  wiler 
outvMrd.,.  forming vorteicin center. 


272 


Maintenance  253 


What  these  sleeves  —  and  the  impeller,  too  —  are  made 
of  depends  on  the  nature  of  the  liquid  we're  to  pump. 
Generally  they're  bronze,  but  various  other  alloys,  ceramics, 
glass,  or  even  rubber-coating  are  sometimes  required. 

Maintenance  Rule  No.  2:  NEVER  PUMP  A  LIQUID  FOR 
WHICH  THE  PUMP  WAS  NOT  DESIGNED. 

Whenever  a  change  in  pump  application  is  contemplated 
and  there's  any  doubt  as  to  the  pump's  ability  to  resist  the 
different  liquid,  CHlCK  WITH  YOUR  PUK:P  MANUFAC- 
TURER! 


WE  MOUNT  THE  SHAFT  ON  SLEEVE,  BAuL  OR  ROLLER 
BEARINGS  . . . 

As  we'll  see  later,  clearances  between  moving  parts  of  our 
pump  are  QUITE  SMALL. 

If  beanngs  supporting  the  turning  shaft  and  impeller  are 
allowed  to  wear  e^^^^ssively  and  lower  the  turning  units 
within  a  pump's  closely-fitted  mechanism,  the  life  and  effi- 
ciency of  that  pump  will  be  seriously  threatenec 


Maintenance  Rule  No.  3:  KEEP  THE  RIGHT  AMOUNT  OF 
THE  RIGHT  LUBRICANT  IN  BEARINGS  AT  ALL  TIMES. 
FOLLOW  YOUR  PUMP  MANUFACTURER'S  LUBRICATION 
INSTRUCTIONS  TO  THE  LETTER. 

Mam  points  to  keep  in  mind  are  . . . 

1.  Although  too  much  oil  won't  harm  sleeve  bearings,  too 
much  grease  in  antifriction  type  bearings  (ball  or  roller) 
will  PROMOTE  friction  and  heat.  Main  job  of  grease  in 
antifriction  bearings  is  to  protect  steel  elements  against 
corrosion,  not  friction. 

2.  Operating  conditions  vary  so  widely  that  no  one  rule  as  to 
frequency  of  changing  lubricant  will  fit  all  pumps.  So  play 
safe:  if  anything,  change  lubricant  BEFORE \Vs  too  worn 
or  too  dirty. 


TO  CONNECT  WITH  THE  MOTOR,  WE  ADD  A  COUPLING 
FLANGE . . . 

Some  pumps  are  built  with  pump  and  motor  on  one  shaft, 
of  course,  and  offer  no  alignment  problem. 

But  our  pump  is  to  be  driven  by  a  separate  motor . . .  and 
we  attach  a  flange  to  one  end  of  the  shaft  through  which 
bolts  will  connect  with  the  motor  flange. 

ERIC 


Maintenance  Rule  No.  4:  SEE  THAT  PUMP  AND  MOTOR 
FLANGES  ARE  PARALLEL  VERTICALLY  AND  AXIALLY . . . 
AND  THAT  THEY'RE  KEPT  THAT  WAY' 

If  shafts  are  eccentnc  or  meet  at  an  angle,  every  revolution 
throws  tremendous  extra  load  on  bearings  of  both  pump  and 
motor.  Flexible  couplings  will  A/Or  correct  this  condition  if 
excessive. 

Checking  alignment  should  be  regular  procedure  In  pump 
maintenance.  Foundations  can  settle  unevenly,  piping  can 
change  pump  position,  bolts  can  loosen.  Misalignment  is  a 
MAJOR  cause  of  pump  and  coupling  wear. 

NOW  WE  NEED  A  "STRAW"  THROUGH  WHICH  LIQUID 
CAN  BE  SUCKED . . . 

Notice  two  things  about  the  suction  piping:  1)  the  horizon- 
tal piping  slopes  UPWARD {ov^ar6  the  pump;  2)  any  reducer 
which  connects  between  the  pipe  and  pump  intake  nozzle 
should  be  horizontal  at  the  top  —  {ECCENTRIC,  not  concen- 
tnc). 


AllOWCD  Br  wOWM  SiO'IN&PlT>i   Allowed  By  TAPCT^DBrCUCI'R 


273 


254  Water  Treati?ent 


This  up-sloping  prevents  air  poc»<eting  in  the  top  or  the 
pipe  which  air  might  be  d  awn  into  the  p'lmp  and  cause 
loss  of  suction. 

Maintenance  Rule  No.  5:  ANY  DO\vNSLOPING  TOWARD 
THE  PUMP  IN  SUCTION  PIPING  (AS  EXAGGERATED  IN 
THE  DIAGRAMS  ABOVE)  SHOULD  BE  CORRECTED, 

This  rule  is  VERY  important.  Loss  of  suction  greatly 
endangers  a  pump  .  .  as  we'll  see  shortly. 

WE  contmIn  and  direct  the  spinning  liquid  with  a 

CASING  . . . 

We  got  a  little  ahead  of  our  story  in  the  previous  para- 
graphs . . .  because  we  didn  t  yet  have  the  casing  to  which 
the  suction  piping  bolts.  And  the  manner  in  which  it  is 
attached  is  of  great  importance. 

Maintenance  Rule  No.  6:  SEE  THAT  PIPING  PUTS  ABSO- 
LUTELY NO  STRAIN  ON  THE  PUMP  CASING. 


T«C  WClSMTOF  -PlPlNvJ  CAN 
EASILY  T»UIW  A  PUMP/ 


When  thr  original  installation  is  made,  all  piping  should  be 
in  place  arid  self-supporting  before  connection.  Openings 
should  m'^et  with  no  force.  Otherwise  ine  casing  is  apt  to  be 
c  ?cked  ...  or  sprung  enough  to  allow  closely-fittec  oump 
Parts  to  ruL. 

It's  good  practice  to  check  the  piping  supports  regulaHy  to 
see  that  loosening,  or  settling  ')f  the  building,  hasn't  put 
strains  on  ^he  casing. 

NOW  OUR  PUMP  IS  ALMOST  COMPLETE,  BUT  IT  WOULD 
LEAK  •  'XE  A  SIEVE  . . . 

We're  far  enough  along  now  to  trace  the  flow  of  water 
through  our  pump.  5'<'s  not  easy  to  show  suction  piping  in  the 
cross-section  view  above,  so  im?5qini3  it  stretching  fr^^m  your 
Gve  to  the  lower  center  of  the  p.  np. 


ERIC 


Our  pump  happens  to  be  a  "double  suction"  pump,  which 
means  th^*t  water  flow  is  divided  inside  the  pump  casing  . . . 
reaching  t!  ^  eye  of  the  impeller  from  either  side 


/liquid  socs 


•UT50Mf  Of  IT  LEAKS 


^AClC<f  ROM  fRESSURE  10  SUCTION  I 


As  water  is  sucked  into  the  spinning  impeller,  centrifugal 
force  causes  it  to  flow  outward  .  . .  building  up  high  pressure 
at  the  outside  of  the  pump  (which  will  force  water  OUT)  and 
creating  low  pressure  at  the  center  of  the  pump  (which  will 
suck  water  IN.)  This  situation  is  diagrammed  m  the  upper 
half  of  the  pump,  above. 

So  tar  so  good  . . .  except  that  water  ten  '  to  be  sucked 
back  from  pressure  to  suction  through  the  s\,  ice  between 
impeller  and  casing  —  as  diagrammed  in  the  lower  l-.alf  of 
the  pump,  above  —  and  our  next  step  must  be  to  plug  this 
leak,  if  our  pump  is  to  be  very  efficient! 

SO  WE  ADD  WEARING  RINGS  TO  PLUG  INTERNAL  LIQUID 
LEAKAGE  . . . 

You  might  ask  why  we  didn't  build  our  parts  closer  fitting 
m  the  first  place  —  instead  of  narrowing  the  gap  between 
them  by  inserting  wearing  rings. 


The  answer  is  that  those  rings  are  removable  r.nd  RE- 
PLACEABLE . . .  when  wear  enlarges  the  tiny  gap  between 
them  and  the  impeller.  (Sometimes  nngs  are  attached  to 
impeller  rather  than  casing  —  or  rings  are  attached  to  BOTH 
so  they  face  each  other.) 


^57 


A  LOT  X>EPEhOS  on 


27i 


Maintenance  255 


Maintenance  Rule  No.  7.  NEVER  ALLOW  A  PUMP  TO 
RUN  DRY  (either  through  lack  of  proper  priming  when 
Gtarting  or  through  loss  suction  when  operating).  Water  is 
a  LUBRICANT  bexv^een  rings  and  impeller. 

Maintenance  Rule  No.  8.  EXAMINE  WEARING  RINGS  AT 
REGULAR  INTERVALS.  When  seriously  worn,  their  replace- 
ment will  g»'eatly  improve  pump  efficiency. 


TO  KEEP  AIR  FROM  BEING  SUCKED  IN,  WE  USE  STUFF- 
ING BOXES  . . . 

We  have  two  good  reasons  for  wanting  to  keep  air  out  of 
our  Dump:  1)  we  want  to  pump  water,  not  air;  2)  air  leakage  is 
apt  to  cause  our  pump  to  lose  suction. 

Each  stuffing  box  we  use  cc.isists  of  a  casing,  rings  of 
packing  and  a  gland  at  the  oUiSide  end. 


Maintenance  Rule  No.  9:  PACKING  SHOULD  BE  RE- 
PLACED PERIODIC  ALL  Y  —  DEPENDING  ON  CONDITIONS 
—  USING  THE  PACKING  RECOMMENDED  BY  YOUR 
PUMP  MANUFACTURER.  Forcing  in  a  ring  or  two  of  new 
packing  instead  of  replacing  worn  packing  is  BAD  PRAC- 
TICE. It's  apt  to  displace  the  seal  cage  (see  next  column). 

Put  each  ring  of  packing  in  separately,  seating  it  firmly 
jiore  adding  the  next.  Stagger  adjacent  rings  so  the  points 
where  their  ends  meet  do  not  coincide. 

Maintenance  Rule  No.  10:  NEVER  TIGHTEN  A  GLAND 
MORE  THAN  NECESSARY ...  as  excessive  pressure  will 
wear  shaft  sleeves  unduly. 

Maintenance  Rule  No.  11:  IF  SHAFT  SLEEVES  ARE 
BADLY  SCORED,  REPLACE  OR  REPAIR  THEM  IMMEDI- 
ATELY ...  or  packing  life  will  be  entirely  too  short. 


TO  WAKE  PACKING  MORE  AIR-TIGHT,  WE  ADD  WATER 
SEAL  PIPING... 

In  the  center  of  each  stuffing  box  is  a  "seal  cage."  By 
connecting  it  with  piping  to  a  point  near  the  impeller  rim,  we 
bring  liquid  UNDER  PRESSURE  \o  th3  stuffing  box. 

This  liquid  acts  both  to  block  out  air  intake  and  to  lubricate 
the  packing.  It  makes  both  packing  and  shaft  sleeves  wear 
longer .  .  .  PROVIDING  ITS  CLEAN  LIQUID' 


Maintenance  Rule  No.  12:  IF  THE  LIQUID  BEING 
PUMPED  CONTAINS  GRIT,  A  SEPARATE  SOURCE  OF 
SrALING  LIQUID  SHOULD  BE  OBTAINED  (e.g.,  it  may  be 
possible  to  direct  some  of  the  pumped  liquid  into  a  container 
and  settle  the  grit  out). 

To  control  liquid  flow,  draw  up  the  gland  just  tight  enough 
so  a  THIN  stream  flows  from  the  stuffing  box  during  pump 
operation. 

DISCHARGE  PIPING  COMPLETES  THE  PUMP  INSTALLA- 
TION —  AND  NOW  WE  CAN  ANALYZE  THE  VARIOUS 
KORCES  WE'RE  DEALING  WITH  .  . . 


) 


.  ERIC 


27  o 


256  Water  Treatment 


SUCTION  At  least 75%  of  centrifugal  pump  troubles  trace 
to  the  suction  side.  To  minimize  them  . . 

1 .  Total  suction  lift  (distance  between  center  line  of  pump 
and  liquid  level  whr  pumping,  plus  friction  losses)  gen- 
erally should  not  exceed  15  feet. 

2.  Piping  should  be  at  least  a  size  larger  than  pump  suction 
nozzle. 

3.  Friction  in  piping  should  be  minimized  . .  use  as  few  and 
as  easy  bends  as  possible  . . .  avoid  scaled  or  corroded 
pipe. 

DISCHARGE  lift,  plus  suction  lift,  plus  friction  in  the  piping 
from  the  point  where  liquid  enters  the  suction  piping  to  the 
end  of  the  discharge  piping  equals  total  head. 

PUMPS  SHOULD  BE  OPERATED  NEAR  THEIR  RATED 
HEADS. 

Otherwise,  pump  is  apt  to  operate  under  unsatisfactory 
and  unstable  conditions  which  reduce  efficienc*'  and  operat- 
ing life  of  the  unit. 

Note  the  description  of  "cavitation"  below  —  and  direc- 
tions for  figuring  the  head  your  pumps  are  working  against. 


PUMP  CAPACITY  generally  is  measured  in  gallons  per 
minute  A  new  pump  is  guaranteed  to  deliver  its  rating  in 
capacity  and  head. 

But  whether  a  pump  RETAINS  its  actual  capacity  depends 
to  a  great  extent  on  its  maintenance. 

Weanng  nngs  must  be  replaced  when  necessary  —  to 
keep  internal  leakage  losses  down. 

Friction  must  be  minimized  in  bearings  and  stuffing  boxes 
by  proper  lubrication  . . .  and  misalignment  must  not  be 
allowed  to  force  scraping  between  closely-fitted  pump  parts. 

POWER  of  the  driving  motor,  like  capacity  of  the  pump, 
will  not  remain  at  constant  level  without  proper  mainte- 
nance.. (If  you  us  electric  motors,  by  all  means  send  for 
Allis-Chalmers  free  "Guide  to  Care  of  Electric  Motors!") 

Starting  load  on  mot^^rs  can  be  reduced  by  throttling  or 
closing  the  pump  discharge  valve  (NEVER  the  suct'on  valve!) 

. .  but  the  pump  must  not  be  operated  for  lon^  vith  the 
discharge  valve  closed.  Power  then  is  converted  into  friction 
—  overheating  the  water  with  serious  consequences. 


^Ay£  A  ^^^^rTiBsPEcrpoP  cAViVArtof^i 

IF  PWMP  CATACITT,  8TtCl>,«EAT>,  AMD  ^UCTIOM  1.1  Fr  ' 
A^EN'r  FIGURED  PROPERir,  CAVITATV  N  CAR  EAT  A|/ 
IMmi^  AWAY  ^Jl  A  tABoHATORY  WATCR- 
.HAMMCe  INDICATES  tT'^SER031VE  F0RCF». 


3  ci.p^i.s 

CAVrTY-HATI  ft  fMKMQ 


2 '^•^•ucfi  tmtvt 


ERIC 


276 


Maintenance  257 


Cavitation  is  a  condition  that  can  cause  a  drop  in  pump 
efficiency,  vibration,  noise  and  rapid  damage  to  the  impeller 
of  a  pump.  Cavitation  occurs  due  to  unusually  low  pressures 
within  a  pump.  These  low  pressures  can  develop  when 
pump  inlet  pressures  drop  below  the  design  inlet  pressures 
or  when  the  pump  is  operated  at  flow  rates  considerably 
higher  than  design  flows.  When  the  pressure  within  the 
flowing  water  drops  very  low,  the  water  starts  to  boil  and 
vapor  bubbles  form.  These  bubbles  then  collapse  with  great 
force  which  knocks  metal  particles  off  the  pump  impeller. 
This  same  action  can  and  does  occur  on  pressure  reducing 
valves  and  partially  closed  gate  and  butterfly  valves. 

18.212  Horizontal  Centrifugal  Pumps 

Horizontal  centrifugal  pumps,  like  the  one  we  just  con- 
structed on  paper  in  the  last  section,  are  available  in  a 
number  of  configurations.  The  one  we  built  is  best  descnbed 
as  a  single-stage,  horizont^.,  double-suction,  split-case  cen- 
trifugal pump.  The  pump  is  a  single-stage  pump  because  it 
has  only  one  impeller.  Some  horizontal  pumps  have  two 
impellers  that  are  working  in  series  to  create  higher  heads 
than  can  readily  be  obtained  with  only  one  impeller.  Our 
paper  pump  was  double  suction  in  that  water  entered  the 
impeller  from  both  sides.  The  advantage  of  this  design  Is 
that  the  longitudinal  thrust  fro.<t  the  water  entenng  the 
impeller  is  balanced.  This  greaiiy  reduces  the  thrust  load 
that  the  pump's  bearings  must  carry.  The  split  case  designa- 
tion indicates  that  the  pump  case  is  made  In  two  halves. 
Some  centnfugal  pumps  have  a  single  suction  in  line  with  the 
shaft.  These  are  oescribed  as  single  stage  end  sucuon 
centrifugal  pumps. 

18.213  Vertical  Centrifugal  Pumps  {Figures  1 8.16, 1 8.17 
and  18.18) 

Another  common  configuration  for  centnfugal  pumps  is 
t  vertical  suction  cased  centrifugal  pump.  This  is  an 
adaptation  of  the  deep  well  turbine  pump  for  booster  pump 
service.  They  are  very  flexible  in  design  as  the  engineers  can 
specify  either  single  or  multi-stage  in  a  wide  variety  of  sizes 
and  characteristics. 

Besides  the  usual  lubrication  or  the  electric  motor,  the  only 
routine  maintenance  required  is  to  adjust  and  repair,  as 
needed,  the  single  packing  gland. 


Adjusting  Nut 
Drive  Key 

Vertical  Hollow 
Shaft  Motor 

Top  Shaft 

Deflector  Rin^ 

Packing  Gland 

Packing 

Lantern 

Packing  Box 

Discharge  Head 

Packing  Box  Bushing 

Dram  Line 

Top  Column  Flange 

Shaft  Couphng 

Column  Pipe 

Bowl  Shaft 

Discharge  Case  Cap 

Discharge  Case  Coupling 

Discharge  Case 

Discharge  Care  Bearing 

Impeiicf 

Intermediate  Bowl 
Imoeller  Lock  Collet 
Intermediate  Bowl  Bearing 
Bowl  We^r  Ring 

Suction  Case  Bearing 

Suction  Flange 


18.214  Reciprocating  or  Piston  Pumps 

The  word  "reciprocating"  means  moving  back  and  forth, 
so  a  reciprocating  pump  is  one  that  moves  a  liquid  by  a 
piston  that  moves  back  and  forth.  A  simpla  reciprocating 
pump  IS  shown  In  Figure  18.19.  If  the  piston  Is  pulled  to  the 
left.  Check  Valve  A  will  be  open  and  the  liquid  wi"  3nter  the 
pump  and  fill  the  casing.  When  the  piston  reacnes  the  end  of 
its  travel  to  the  left  and  is  pushed  back  to  the  right,  Check 
Valve  A  wi'l  close.  Check  Valve  B  will  open,  and  the  liquid  will 
be  forced  out  the  exit  line. 

A  piston  pump  is  a  positive-displacement  pump.  Never 
operate  it  against  a  closed  discharge  valve  or  the  pump, 
valve,  and/or  pipe  could  be  darTJ?^ged  by  excessive  pres- 
sures. Also,  the  suction  valve  should  be  open  when  the 
pump  is  started.  Otherwise  an  excessive  suction  or  vacuum 
could  develop  and  cause  problems. 

18.215  Progressive  Cavity  (Screw-Flow)  Pumps 

(Figure  18.20) 

The  progressive  cavity  pump  consists  of  a  screw-shaped 
rotor  sniiqly  enclosed  In  a  non-moving  stator  or  housing 
(Figure  18.2  J).  The  threads  of  the  screw-like  rotor  (common- 
ly manufactured  of  chromed  steel)  make  contact  along  the 


Fig,  18.16   Vertical  centnfugal  pump  (multistage) 

(Permission  of  Aurora  Pump  Company) 


m  m 


Fig.  18.17  Vertical  centrifugal  pump  (single  sta.  i) 

(Permission  of  Aurora  F'ump  Company) 

277 


258  Water  Treatment 


walls  of  the  stator  (usually  made  of  synthetic  ruhber).  me 
gaps  between  the  rotor  threads  are  called  "cavities/'  When 
water  Is  pumped  through  an  inlet  valve,  it  enters  the  cavity 
As  the  rotor  turns,  the  material  is  moved  along  until  it  leaves 
the  conveyor  (rotor)  at  the  discharge  end  of  the  pump.  The 
size  of  the  cavities  along  the  rotor  determines  the  capacity  of 
the  pump. 


All  progressive  cavity  pumps  operate  on  the  basic  pnnci- 
pie  descnbed  above.  To  further  increase  capacity,  some 
models  have  a  shaped  inside  surface  of  the  stator  (housing) 
with  a  similarly  shaped  rotor.  In  addition,  some  models  use  a 
rotor  that  moves  up  and  down  Inside  the  stator  as  well  as 
turning  on  its  axis  (Figure  18.21).  This  allows  a  further 
increase  in  the  capacity  of  the  pump. 


Progressive  cavity  pumps  are  recommended  for  materials 
which  contain  higher  concentrations  of  suspended  solids. 
They  are  commonly  used  to  pump  sludges.  Progressive 
cavity  pumps  should  NEVER  be  operated  dry  (without  liquid 
in  the  cavities),  nor  should  they  be  run  against  a  closed 
discharge  valve. 


18.216  Chemical  Metering  Pumps 

Many  chemical  metering  pumps  are  a  type  of  positive 
displacement  pump  Fo.  information  on  chemical  metering 
pumps,  see  Chapter  13,  Fluoridation,  Section  13.30,  "Chemi- 
cal Feeders;'  and  Section  18.4,  "Chemical  Feeders,"  in  this 
Chapter. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  324. 

18.20A  List  tfit;  pieces  of  equipment  and  special  tools 
commonly  found  in  a  pump  rpoair  shop. 

18.21  A  What  is  the  purpose  oi  a  pump  impeller? 

18.21B  Why  should  the  intake  end  of  suction  piping  have  a 
suitable  screen? 

18.21C  Why  must  suction  piping  always  be  up-sloping? 

18.21D  What  IS  cavitation? 

18.21E  What  IS  an  advantage  of  having  a  DOUBLE'SUC- 
TION  pump  over  a  SINGLE'SUCTfON  pump? 


1.  Motor  frame 

2.  Impeller 

3.  Oil  seal 

4.  Mechanical  seal 

5.  Frame 

6.  Casing 


7.  Shaft  sleeve 

8.  Back  pull-out 

9.  Lubrication  fittings 

10.  Shaft 

11.  Impeller 

12.  Bearings 


13.  Shaft  sleeve 

14.  Close  coupled  motor  support 

15.  Impeller 

16.  Wearing  ring 

17.  Oil  reservoir 

18.  Rear  support  foot 


Fig.  18.18  Centrifugal  pvmp  parts 

(Permisston  of  Aurora  Pump  Company) 


278 


Maintenance  259 


1.  Motor  frame  7.  Shaft  sleeve  13.  Shaft  sleeve 

2.  Impeller  8.  Back  pull-out  14.  Close  coupled  motor  support 

3.  Oil  seal  9.  Lubrication  fittings  15.  Impeller 

4.  Mechanical  sea'  10.  Shaft  16.  Wearing  ring 

5.  Frame  11.  Impeller  17.  Oii  reservoir 

6.  Casing  12.  Bearings  18.  Rear  support  foot 


Fig.  16. 16  Centrifugal  pump  parts  (contii  d) 


PISTON 


FLOW  IN 


Fig.  16,19  S.mple  reciprocating  pump 


o> 
o 


0 

o 
3 

(D 


280 


Fig.  18.20  Progressive  cavity  (screw-llow)  pump 

(Permisspon  o)  Moyno  Pump  Division.  Robbins  S  Meyer,  Inc ) 


2Si 


Maintenance  261 

Pumping  principle 


0° 


Fig.  18.21  Pumping  principle  of  a  progressive  cavity  pump 

(Permission  of  Atfweiler  Pumpi,  Inc ) 


28?. 


262  Water  Treatment 


18.22  Lubrication 

18.220  Purpose  of  Lubrication 

Lubrication  of  equipment  is  probably  one  of  the  most 
important  phases  of  a  maintenance  operator  s  job.  Wrthout 
proper  lubrication,  the  tools  and  equipment  used  for  operat- 
ing and  maintaining  water  treatment  plants  would  fail.  Prop- 
er lubrication  of  tools  and  equipment  is  probably  one  of  the 
maintenance  operator's  easiest  jobs,  but  often  is  the  most 
neglected. 


The  purpose  of  lubrication  is  to  reduce  friction  between 
two  surfaces-  luorication  also  removes  heat  that  is  caused 
by  friction.  Solid  fr.ction  of  two  dry  surfaces  in  contact  is 
changed  to  a  fluid  friction  of  a  separating  layer  of  liquid  or 
liquid  lubricant.  Actually,  water  is  a  lubricant,  although  not  a 
good  lubricant. 

18.221  Properties  of  K  ubricants 

A  good  lubricant  must  have  the  following  properties: 

1.  Form  a  slippery  coating  on  contacting  surfaces  so  they 
can  slide  freely  past  each  other,  and 

2-  Exert  sufficient  pressure  to  keep  the  surfaces  apart  when 
running. 


Tc  be  a  good  lubncant  for  a  particular  job.  the  lubricant 
used  must  have  the  following  qualities: 

1  -  Thickiiess  of  the  lubricant  layer  must  be  sufficient  to  keep 
the  roughness  of  the  metal  parts  from  touching. 

2.  Lubricity  (slipperiness)  must  be  sufficient  to  allow  mole- 
cules lo  slide  freely  past  each  other,  and 

3.  Viscosity  (resistance  to  flow)  must  be  sufficient  to  bu..d 
up  a  Pr<issure  necessary  to  keep  the  surfaces  apart.  If 
viscosity  alone  cannot  provide  enough  pressure,  an  ex- 
ternal pressure  must  be  supplied  by  a  pump. 


^2  SSU.  Staf.dard  Saybolt  Units. 

ERIC 


Viscosity  in  the  United  States  is  the  number  of  seconds  it 
takes  60  cubic  centimeters  (cc)  of  an  oil  to  flow  through  the 
standard  orifice  of  a  Saybolt  Universal  Viscometer  at  100, 
130.  or  210  degrees  Fahrenheit.  A  300  -  SSU^^  @  130  oii 
means  that  it  took  300  seconds  for  60  cc  to  flow  through  a 
Saybolt  Universal  Viscometer  at  130  degrees  Fahrenheit. 
Viscosity  decreases  with  temperature  rise  because  oil  be- 
comes thinner  The  specific  gravity  of  an  oil  is  measured  by 
comparing  the  weight  of  oil  with  an  equal  volume  of  water, 
both  at  60  degrees  Fahrenheit. 

Some  other  important  information  to  know  about  lubri- 
cants IS  the:--  "Pour  Point."  "Flash  Point,"  and  Tire  Point." 
"Pour  Point"  is  the  temperature  at  which  a  lubricant  refuses 
to  run.  This  is  important  in  low  temperature  work.  "Flash 
Point"  is  the  temperature  at  which  oil  vaporizes  enough  to 
ignite  momentarily  when  near  a  flame.  A  low  flash  point 
means  that  oil  evaporates  more  readily  in  service.  "Fire 
Point''  IS  the  temperatuie  at  which  oil  vaporizes  enough  to 
keep  on  burning.  Oils  in  service  tend  to  become  acid  and 
may  cause  corrosion,  deposits,  sludging  and  other  prob- 
lems. This  condition  may  not  be  visible  when  you  look  at  the 
oil.  Therefore,  do  not  extend  the  time  for  an  oil  change 
because  the  oil  looks  clean. 

To  detect  acid  conditions  in  oils,  the  neutralization  number 
of  an  oil  is  ijsed.  The  neutralization  number  is  the  weight  in 
milligrams  of  potassium  hydroxide  required  to  nei  'alize 
one  gram  of  oil.  This  is  used  by  laboratories  which  te^t  the 
oil  on  large  engines,  turbines,  compressors,  and  other 
equipment  which  have  large  volume  oil  reservoirs  to  deter- 
mine when  cil  changes  or  additives  are  needed. 

Most  lubricants  in  gei  eral  use  are  fluid  at  room  tempera- 
ture. Mostly,  these  are  petroleum  base,  but  others  are  used. 
Greases  are  mixtures  of  petroleum  products  with  soaps 
such  as  lime,  soda,  aluminum,  and  metallic.  Metallic  soaps, 
forms  of  calcium,  sodium,  potassium,  and  lithium,  have  good 
'-etention  in  bearings  and  can  withstand  high  temperatures 
and  pressures.  A  sodium  base  grease  has  sodium  as  the 
soap  mixed  with  the  petroleum. 

Solid  materials  such  as  graphite,  finely  ground  mica,  and 
yarn  are  sometimes  used  as  lubricants.  Some  recently 
developed  silicon  compounds  (silicones)  work  very  well 
under  heavy  loads  and  widely  varying  temperatures. 

Thore  are  many  oil  additives  on  the  market  today  and  they 
are  worth  investigating.  Oil  additives  are  chemical  com- 
pounds added  to  an  oil  to  improve  certain  chemical  or 
physical  properties  such  as  stability,  lubricity  and  foaming. 
They  are  used  to  prevent  rust  or  deposits  and  many  other 
items  that  could  cause  problems. 

18.222  Lubrication  Schedule 

To  have  proper  lubrication  you  must  first  set  up  a  lubrica- 
tion schedule.  This  can  be  a  sii.;ple  check-off  sh'^et  or  card 
system  or  an  elaborate  computer  system.  The  first  thing  to 
do  IS  make  a  list  of  everything  that  needs  lubrication  down  to 
the  smallest  item  including  chains,  rollers,  and  sprockets. 
After  you  have  listed  every  item  on  paper,  go  through  the 
manufacturer's  instruction  books  to  determine  the  frequen- 
cy and  type  of  lubrication  required.  Is  the  frequency  daily, 
weekly,  monthly,  semi-annual,  or  annually?  The  manufactur- 
er's literature  usually  lists  several  different  name  brands  of 
lubricants  which  are  equal.  If  you  need  help  determining  the 
type  of  lubricant  or  cross-referencing  it  to  your  particular 
brand,  contact  your  supplier.  Most  oil  distributors  have  a 
service  representative  who  will  come  to  your  facility  and  go 
over  the  individual  equipment  and  specify  which  lubricants 

283 


Maintenance  263 


you  should  use.  Next,  determine  the  amount  of  each  lubri- 
cant required.  This  is  achieved  by  counting  the  number  of 
grease  fittings  Determine  the  locations  of  fill  plugs,  dram 
piMgs,  oil  levels,  sight  glasses,  dip  sticks  and  other  important 
items.  To  find  these  locations,  physically  inspect  each  piece 
of  equipment  thoroughly  and  look  for  all  lubrication  points. 
Also  the  manufacturer's  maintenance  manual  should  shov^^ 
the  lubrication  points  for  each  piece  of  equipm-int. 

When  you  have  gathered  all  this  information,  transfer  it  to 
the  equipment  history  cards  for  future  reference.  From  this 
information  you  can  make  up  a  lubrication  chart  or  form. 

As  stated  earlier,  use  whatever  type  of  lubrication  form 
you  prepare,  but  follow  it.  Always  record  each  lubrication  job 
when  completed  and  have  the  operator  who  did  the  job  initial 
the  record  card.  Always  keep  your  lubrication  schedules  up 
to  date.  If  there  are  failures  due  to  the  wrong  or  insufficient 
lubricant,  change  or  increase  the  lubrication  frequency  on 
the  schedule.  Also,  new  equipment  must  be  added  and 
discarded  equipment  removed  fnm  the  schedule.  Someone 
must  be  assigned  to  take  care  of  the  lubrication  and  records. 
Assign  more  than  one  operator  or  rotate  this  job  so  if  an 
individual  is  off  work  or  leaves  the  crew,  there  is  a  continuity 
in  tha  lubrication  schedule. 

18,223  Precautions 

When  handling  or  storing  oils  and  greases,  some  special 
precautions  must  be  followed.  Make  sure  the  storage  area 
does  not  create  a  fire  hazard.  Most  all  lubricants  are  highly 
flammable  and  shouldn't  be  stored  wh?re  there  is  an  open 
flame.  "NO  SMOKING"  signs  must  be  posted  outside  the 
building.  Be  sure  to  Keep  any  spills  wiped  up  and  make  sure 
that  all  the  lids  are  tight  on  their  containers. 


Keep  materials  and  containers  clean.  Sand,  grit,  and  other 
substances  can  contaminate  lube  supplies  and  create  an 
equipment  failure  that  lubrication  maintenance  is  intended  to 
prevent.  Another  good  idea  is  to  direct  the  first  shot  of 
grease  from  a  gun  into  a  waste  can. 

18.224  Pump  Lubrication 

Pumps,  motors,  and  drives  should  be  oiled  and  greased  in 
strict  accordance  with  the  recommendations  of  the  manu 
facturer.  Cheap  lubricants  may  often  be  the  most  expensive 
in  the  end.  Oil  should  not  be  put  in  the  housing  while  the 
pump  shaft  is  rotating  because  the  rotary  action  of  the  ball 

ERIC 


bearings  ptck  up  and  retain  a  considerable  amount  of  oil 
When  the  unit  comes  to  rest,  an  overflow  of  oil  around  the 
shaft  or  out  of  the  oil  cup  will  result. 

Greased  bearings  should  be  lubricated  as  follows: 

1.  Shut  off  the  unit  if  moving  parts  that  might  be  a  safety 
hazard  are  close  to  the  grease  fitting  oi  orain  plugs. 

2.  Remove  the  dram  plug  from  the  bearing  housing. 

3  Remove  the  grease  fitting  protective  cap  and  wipe  off  the 
grease  fitting.  Be  sure  that  you  do  not  force  dirt  into  the 
bearing  housing  along  with  the  clean  grease. 

4  Pump  in  clean  grease  until  the  g^'case  coming  out  of  the 
dram  hole  is  clean.  Don't  pump  grease  into  a  bearing  with 
the  dram  plug  in  place.  This  could  easily  build  up  enough 
pressure  to  blow  out  the  seals. 

5.  Put  the  protective  cap  back  on  the  grease  fitting. 

6.  With  the  dram  plug  still  removed,  put  the  unit  back  in 
service.  As  the  bearing  warms  up,  excess  grease  will  be 
expelled  from  the  dram  hole.  After  the  unit  has  been 
running  for  a  few  hours,  the  dram  plug  may  be  put  back  m 
place.  Special  drain  plugs  with  spring  loaded  check 
valves  are  recommended  because  they  will  protect 
against  further  buildup. 

7  Unless  you  intend  to  be  very  careful,  we  recommend  that 
bearing  grease  be  p  ^chased  in  cartridge  form  to  mini- 
mize the  chance  of  geumg  dirt  into  the  lubricant. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  324. 

18.22A  What  is  the  purpose  of  lubrication? 

18.22B  What  happens  to  oils  in  service'^ 

18.220  What  should  be  done  to  insure  prope^  lubrication  of 
equipment? 

18.225  Equipment  Lubrication 

Different  authorities  may  make  conflicting  lube  recom- 
mendations for  essentially  the  same  item;  however,  general 
reference  material  is  available  to  help  select  the  correct 
lubricant  for  a  specific  application. 

Grease  is  graded  on  a  number  scale,  or  viscosity  index,  by 
the  National  Lubricating  Grease  Institute.  For  example.  No.  0 
IS  very  soft.;  No.  6  is  quite  stiff.  A  typical  grease  for  most 
treatment  plant  applications  might  be  a  2  lithium  or 
sodium  compound  grease,  which  is  used  for  operating 
temperatures  up  to  250°F  (120°C). 

Generally,  the  time  between  flushing  and  repacking  for 
greased  bearings  should  be  divided  by  2  for  every  25°F 
(15°C)  above  150*^  (65°C)  operating  temperature.  Also, 
generally,  the  time  between  lubrications  should  not  be 
allowed  to  exceed  48  months,  since  lube  component  sepa- 
ration and  oxidation  can  become  significant  after  this  period 
of  time,  regardless  of  amount  of  use. 

Another  point  worth  noting  is  that  grease  is  normally  not 
suitable  for  moving  elements  w'th  speeds  exceeding  12  000 
in./min  (5  m/s).  Usually,  oil-lubricating  systems  are  used  for 
higher  speeds.  Lighter  viscosity  oils  are  recommended  for 
high  speeds,  and,  within  the  same  speed  and  temperature 
range,  a  roller  bearing  will  normally  require  one  grade 
heavier  viscosity  than  a  ball  bearing. 

284 


264  Water  Treatment 


A  good  rule  of  thumb  is  to  change  and  flush  oil  completely 
at  the  end  of  600  hours  of  operation  or  3  months,  whichever 
occurs  first.  More  specific  procedures  for  flushing  and 
changing  lubricants  are  outlined  by  most  equipment  manu- 
facturers. 

Every  operator  should  be  aware  of  the  dangers  of  overfill- 
ing with  either  grease  or  oil.  Overfilling  can  result  in  high 
pressures  and  temperatures,  and  ruined  seals  or  other 
components.  It  has  been  observed  that  more  antifriction 
bearings  are  ruined  by  over-greasing  than  by  neglect. 

A  thermometer  can  tell  a  great  deal  about  the  condition  of 
a  bearing.  Ball  bearings  are  generally  in  trouble  above  ISO^'F 
(80*^0).  Grease-packed  bearings  typically  run  10  to  50  de- 
grees above  ambient. 

Forclanfier  drive  units,  which  are  almost  always  located 
outdoors,  condensation  presents  a  dangerous  problem  for 
the  lubrication  system.  Most  units  of  current  design  have  a 
condensate  bailing  system  to  remove  water  from  the  gear 
housing  by  displacement.  These  units  should  be  checked 
often  for  proper  operation,  particularly  during  seasons  of 
wide  air  temperatu'-e  fluctuation. 

Pumps  incoroorate  many  types  of  seals  and  gaskets 
constructed  of  combinations  of  elastomers  and  metals.  As 


for  lubricants,  conflicting  advice  can  be  obtained  A  file 
containing  data  on  general  properties  of  materials  used  can 
help  in  the  choice  of  lubricant. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  324. 

18  22D  Does  a  soft  grease  have  a  high  or  low  viscosity 
index  as  compared  with  a  hard  grease? 

18.22E  Is  oil  or  grease  used  with  higher  speeds'? 

1 8.22F  What  problems  can  result  from  overfilling  with  oil  or 
grease? 


OVl 

Please  answer  the  discussion  and  review  questions  be- 
fore continuing  with  Lesson  3. 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  18.  MAINTENANCE 

(Lesson  2  of  5  Lessons) 


Write  your  answers  to  these  questions  in  your  notebook 
before  continuing  The  question  numbering  continues  trom 
Lesson  1. 

13.  What  is  the  purpose  of  a  purnp  shaft? 

14.  What  is  the  purpose  of  pump  sleeves'^ 


15.  Why  should  a  pump  never  be  allowed  to  run  dry'' 

16.  How  would  you  develop  a  lubrication  schedule  for  a 
pump? 

17.  Why  is  cleanliness  important  in  the  storing  and  use  of 
lubricants? 


ERLC 


28r, 


Maintenance  265 


CHAPTER  18.  MAINTENANCE 

(Lesson  3  of  5  Lessons) 


18.23  Pump  Maintenance 

16.230  Section  Format 

The  format  of  this  section  differs  from  the  other  chapters. 
This  format  was  designed  specifically  to  assist  you  in 
planning  an  effective  preventive  maintenance  program.  The 
paragraphs  are  numbered  for  easy  reference  when  ycu  use 
the  Equipment  Service  Cards  and  Service  Record  Cards 
mentioned  in  Section  18.00,  page  219,  and  shown  in  Figure 
18.1. 

An  entire  book  could  be  w  'tten  on  the  topics  covered  in 
this  section.  Step-by-step  -tails  for  maintaining  equipment 
are  not  provided  because  manufacturers  are  continually 
improving  their  products  and  these  details  could  soon  be  out 
of  date.  You  are  assumed  to  have  some  familiarity  with  the 
equipment  being  discussed.  FOR  DETAILS  CONCERNING 
A  PARTICULAR  PIECE  OF  EQUIPMENT,  YOU  SHOULD 
CONTACT  THE  MANUFACTURER.  This  section  indicates  to 
you  the  kinds  of  maintenance  you  should  include  in  your 
program  and  how  you  could  schedule  your  work.  Carefully 
read  the  manufacturer's  instructions  and  be  sure  you  clearly 
understand  the  material  before  attempting  to  maintain  and 
repair  equipment.  If  you  have  any  questions  or  need  any 
help,  do  not  hesitate  to  contact  the  manufacturer  or  your 
local  representative. 

A  glossary  is  not  provided  in  this  section  because  of  the 
large  number  of  technical  words  that  require  familiarization 
with  the  equipment  being  discussed.  The  best  way  to  learn 
the  meaning  of  these  new  words  is  from  manufacturers' 
literature  or  from  their  representatives.  Some  new  words  are 
described  in  the  lessons  where  necessary. 


18.231  Preventive  Maintenance 

The  following  paragraphs  list  some  general  preventive 
maintenance  services  and  indicate  frequency  of  perform- 
ance. There  are  many  makes  and  types  of  equipment  and 
the  wide  variation  of  functions  cannot  be  included;  therefore, 
you  will  have  to  use  some  judgment  as  to  whether  the 
services  and  frequencies  will  apply  to  your  equipment.  If 
something  goes  wrong  or  breaks  in  your  plant,  you  may 
have  to  disregard  your  maintenance  schedule  and  fix  the 
problem  now. 


NOTE:  If  you  need  to  shut  a  unit  down,  make  sure  it  is  also 
locked  out  and  tagged  properly.  (Figure  18.22) 


 cope-  


Paragraph  1:  Pumps,  General 

This  paragraph  lists  some  general  preventive  mainte- 
nance services  and  indicates  frequency  of  performance. 
Typical  centrifugal  pump  sections  are  shown  in  Figure  18.18. 

Frequency 
of 
Service 


D  1.  CHECK  WATER-SEAL  PACKING  GLANDS 
FOR  LEAKAGE.  See  that  the  packing  box  is 
protected  with  a  clear-water  supply  from  an 
outside  source,  make  sure  that  water  seal 
pressure  is  at  least  5  psi  (35  kPa  or  0.35  kg/ 
sq  cm)  greater  than  maximum  pump  suction 
pressure.  See  that  there  are  no  CROSS- 
CONNECTIONS.^^  Check  packing  glands 
for  leakage  during  operation.  Allow  a  slight 
seal  leakage  when  pumps  are  running  to 
keep  packing  cool  and  in  good  condition. 
The  proper  amount  of  leakage  depends  on 
equipment  and  operating  conditions.  Sixty 
drops  of  water  per  minute  is  a  good  rule-of- 
thumb.  If  excessive  leakage  is  found,  HAND 
TIGHTEN  glands*  nuts  evenly,  but  not  too 
tight.  After  adjusting  packing  glands,  be 
sure  shaft  turns  freely  by  hand.  If  serious 
leakage  continues,  renew  packing,  shaft,  or 
shaft  sleeve. 

D  2.  CHECK  GREASE-SEALED  PACKING 
GLANDS.  When  grease  is  used  as  a  packing 
gland  seal,  maintain  constant  grease  pres- 
sure on  packing  during  operation.  When  a 
spring-loaded  grease  cup  is  used,  keep  it 
loaded  with  grease.  Force  grease  through 
packing  at  a  rate  of  about  one  ounce  (30  gm) 
per  day.  When  water  is  used,  adjust  seal 
pressure  to  5  p3i  (35  kPa  or  0.35  kg/sq  cm) 
above  maximum  pump  suction  pressure. 
Never  allow  the  seal  to  run  dry. 

W  3.  OPERATE  PUMPS  ALTERNATELY.  If  two 
or  more  pumps  of  the  same  size  are  in- 
stalled, alternate  their  use  to  equalize  weai, 
keep  motor  windings  dry,  and  distribute 
lubricant  in  bearings. 


^3  Cross-Connection.  A  connection  between  a  drinking  (potable)  water  system  and  an  unapproved  water  supply  For  example,  if  you 
have  a  pump  moving  nonpotable  water  and  hook  into  the  ^rinkmg  water  system  to  supply  water  fc  the  pump  seal,  a  cross-connection 
or  mixing  between  the  two  water  systems  can  occur.  This  mixing  may  lead  to  contamination  of  the  drinking  water. 


266  Water  Treatment 


MAN 
WORKING 
ON  LINE 


DO  NOT  CLOSE  THIS 
SWITCH  WHILE  THIS 
TAG  IS  DISPLAYED 

SIGNATURE  .  

This  IS  the  ONLY  person  authorized  to  remove  (his  tag 


NOTE:  Tag  also  should  include:  TIME  OFF 

DATE   


Fig.  18.22  Typical  warning  tag 

(Source-  Industrial  Indemnity/Industrial  UiKierwnters/irjsuiance  Cos  ) 


287 


Maintenance  267 


Frequency 
of 

Service 
W 


D 
W 


4.  INSPECT  PUMP  CONTROL  Inspect  the 
pump  controls  to  see  that  the  pump  re- 
sponds properly  to  changes  In  tne  control- 
ling variable.  This  variable  may  be  either  a 
pressure  or  a  water  level.  This  check  could 
be  done  physically  or  by  analyzing  recording 
gage  records. 

5.  CHECK  MOTOR  CONDITION.  See  Para- 
graph 6:  Electric  Motors. 

e  CHECK  PACKING  GLAND  ASSEMBLY. 
Check  packing  gland,  the  unit's  most 
abused  and  troublesome  part.  If  stuffing 
box  leaks  excessively  when  gland  is  pulled 
up  with  miid  pressure,  remove  packing  and 
examine  shaft  sleeve  carefully.  Replace  or 


repair  grooved  or  scored  shaft  sleeve  be- 
cause packing  cannot  be  held  in  stuffing 
box  with  roughened  shaft  or  shaft  sleeve. 
Replace  the  packing  a  stnp  at  a  time,  tamp- 
ing each  stnp  thoroughly  and  staggering 
joints.  (See  Fig.  18.23.)  Position  lantern  ring 
(water-seal  ring)  properly.  If  grease  sealing 
IS  used,  completely  fill  lantern  ring  with 
grease  before  putting  remaining  rings  of 
packing  in  place.  The  type  of  packing  used 
(Fig.  18.24)  IS  less  important  than  the  man- 
ner in  which  packing  is  placed.  Never  use  a 
continuous  strip  of  packing.  This  type  of 
packing  wraps  around  and  scores  the  shaft 
sleeve  or  is  thrown  out  against  outer  wall  of 
stuffing  box.  allowing  water  to  leak  through 
and  score  the  shaft.  The  proper  size  of 
packing  should  be  available  in  your  plant's 
equipment  files.  See  Fig.  18.25  for  illustrat- 
ed steps  on  how  to  pack  a  pump. 


Fig.  18.23  Method  of  packing  shaft 

(Sourco  war  Department  Tochntcal  Manual  TM5'666) 

288 


ERIC 


268  Water  Treatment 


Teflon  Packing 


Graphite  Packing 


Fiy.  18.24  Packing 

(Courtesy  A  w  Chesteron  Co ) 

Er|c  28  ^ 


Maintenance  269 


LJ 

r 

J 

r 

-^T7 

1  Remove  oil  old  pocking.  Akn  pocking 
*  hook  ot  bor«  of  th0  box  keep  from 
scrotching  the  shoft.  Otsn  box  thor- 
oughly so  the  new  pocking  won't  hong  up 


2 


Check  7or  bent  rod,  grooves  or  shoul- 
d'*rs.  If  the  neck  bushing  clearance 
in  bottom  of  box  is  great,  use  stfffer 
bottom  ring  or  reploce  the  neck  bushb>g 


3 Revolve  rotory  shaft.  If  the  Indlcotor 
runs  out  over  0.003-in.,  straighten 
shoft,  r  check  bearings,  or  bakince 
rotor.  Gyroting  shoft  beats  out  pocking 


Wrong 


6 Cutting  off  rings  while  pocking  Is 
¥rrapped  around  shoft  will  give  you 


rings  with  parallel  ends, 
important    if   packing  is 


fhis  is  very 
to    do  job 


7 11  you  cut  pocking  while  stretched  out  straight,  the  ends  will  be  at  on  angle. 
With  gap  at  angle,  packing  on  either  skle  squeezes  into  top  of  gap  ond  ring, 
cannot  close.  This  brings  up  the  questton  otout  gap  for  expansion.  Mo&  pocktngs 
need  none.  Channel-type  packing  with  lead  core  may  need  slight  gap  for  exponsK>n 


HOW 

TO  PACK 

A  PUMP 

(Editor's  Note:  This  step-by-step  il- 
lustration of  a  basic  maintenance 
duty  was  brought  to  our  attention 
by  Anthony  J.  Zigment,  Director, 
Municipal  Training  Division,  De- 
partment of  Community  Affairs.) 


wrong 


11  Open  ring  joint  sidewise,  especkslly 
II  lead-filled  and  metallic  types.  This 
prevents  distorting  molded  circumfer- 
ence— breaking  the  ring  opposite  gap 


10  Use  split  wooden  bushing.  Install 
1^  first  turn  of  pocking,  then  force 
into  bottom  of  box  by  tightening  gland 
cgoinst  bushing.  Seot  each  turn  this  way 


Doss  expansion  Sectional  Diagonal 


1C  Always  install  cross-exponskm  pocking  so  plies  slope  toward  the  fluid  pres- 
Iv  sure  from  housing.  Place  sectkinol  rings  so  slope  between  inside  and  outskie 
ring  is  toward  the  pressure.  Dkigonal  rings  must  riso  hove  slope  toward  the  fluid 
pressure.  Wotch  these  details  for  best  results  when  installing  new  packing  in  o  box 


ERIC 


fig.  18.25  How  to  pack  a  pump 

(Source  Water  Pollution  Control  Assoctatton  of  Pennsylvania  Magazine.  January-February.  1976) 

23-) 


270  Water  Treatment 


J   To  find  the  right  size  of  packing  to  C  Wind  pocking,  needed  for  filling  stuffing  box,  snugly  around  rod  (for  sorne  size 

t   instoll,  meosure  stuffing-box  bore  ond  v  shoft  held  in  vise)  ond  cut  through  eoch  turn  while  coiled,  Js  shown.  If  the 

subtrocr    rod   diometer,   divide   by   2.  pockmg  is  slightly  too  lorge,  never  flotten  with  o  hommer.  Place  each  turn  on 

Pocking  js  too  critical  for  guesswork,  o  cleon  newspoper  ond  then  roll  out  with  pipe  as  you  would  ¥  ith  a  rolling  pin 


8 Install  fotl'wropped  pocking  so  edge^ 
on  inside  will  foce  direction  of  shoft 
rototion.  This  is  o  must;  otherwise,  thin 
edges  flake  off,  reduce  pocking  life 


,  Neck  bushing 


9 Neck  bushing  slides  into  stuffing 
box.  Quick  woy  to  moke  it  is  to  pour 
soft  Leonng  metol  into  tin  con,  turn 
ond    bore   for   sliding   fit   into  ploc* 


in  scabbing  new  metollic  pockfaigs  with 
iubricont  supplied  by  pocking  maker 
is  OK.  These  include  foil  types,  !ead^ 
core,  etc.  If  the  rod  is  oily,  don't  swob  It 


10  Stogger  joints  180  degrees  if  only 
■  V  two  rings  ore  in  stuffing  box.  Spoce 
ot  120  degrees  for  three  rings,  or  90 
degrees  if  four  rings  or  mOre  ore  in  set 


Lonrern  rtng^ 


■KIBCB 


1  i  Instoll  pocking  so  Jontern  ring  lines  up  with  cooling-liquid  opening.  Also,  remem* 
■  ■  ber  that  this  ring  moves  bock  into  box  os  pocking  is  compressed.  Leave  space 
for  glond  to  enter  os  shown.  Tighten  glond  with  wrench — bock  off  finger^tight. 
Allow  the  pockmg  to  leak  until  it  seots  itself,  then  ollow  o  slight  operortng  leokoge 


Hydroulic-packing  pointers 

First,  clean  stuffing  box,  examine  ram  or  rod.  Next,  measure  stuffing-box 
depth  and  packing  set— find  difference.  Place  %-in.  washers  over  gland 
studs  as  shown.  Lubricate  ram  and  packing  set  fif  for  water).  If  you 
can  use  them,  endless  rings  give  about  17%  more  wear  than  cut  rings. 
Place  male  adapter  in  bottom,  then  carefully  slide  each  packing  turn 
home— don't  harm  lips.  Stagger  joints  for  cut  rings.  Measure  from  lop 
of  packing  to  top  of  washers,  then  compare  with  gland.  Never  tighten 
down  new  packing  set  until  all  air  has  chance  to  work  out.  As  packing 
wears,  remove  one  set  of  washers,  after  more  wear,  remove  othe*-  washer. 


ERLC 


Fig.  16,25  How  to  pack  a  pump  (continued) 

2dl 


Maintenance  271 


Frequency 
of 
Service 


If  a  bronze  shaft  sleeve  is  not  too  badly 
scored,  the  shaft  sleeve  can  be  restored  to 
service.  The  repair  procedure  consists  of 
turning  the  sleeve  down  to  a  uniform  diame- 
ter with  a  rough  cut.  Then  spray  the  sleeve 
with  stainless  steel  to  a  slightly  oversized 
outside  diameter  followed  by  machining  and 
polishing  to  bring  the  sleeve  back  to  its 
original  diameter.  You  will  probably  find  that 
these  reworked  sleeves  will  outlast  the 
originals. 

W  7.  CHECK  MECHANICAL  SEALS.  Mechanical 
seals  usually  consist  of  two  sub-assem- 
blies:  (1)  a  rotating  ring  assembly,  and  (2)  a 
stationary  assembly. 

Inspect  seal  for  leakage  and  excessive  heat. 
If  any  part  of  the  seal  needs  replacing, 
replace  the  entire  seal  (both  sub-assem- 
blies) with  a  new  seal  that  has  been  pro- 
vided by  the  manufacturer.  Before  installing 
a  new  seal,  be  sure  that  there  are  no  chips 
or  cracks  on  the  carbide  sealing  surface. 
Keep  a  new  mechanical  seal  clean  at  all 
times 

Always  be  sure  that  a  mechanical  seal  is 
surrounded  with  water  before  starting  and 
running  the  pump. 

Q        8.  INSPECT  AND  LUBRICATE  BEARINGS. 

Unless  otherwise  specifically  directed  for  a 
particular  pump  model,  lubricate  according 
to  the  procedures  covered  in  Section 
18.224,  page  263.  Check  sleeve  bearings  to 
see  that  oil  rings  turn  freely  with  the  shaft. 
Repair  or  replace  if  deJective. 

Measure  sleeve  bearings  and  replace  those 
worn  excessively.  Generally,  allovy  clear- 
ance of  0.002  inch  plus  0.001  Inch  for  each 
inch  or  fraction  of  inch  of  shaft-journal  diam- 
eter. 

Q  9.  CHECK  OPERATING  TEMPERATURE  OF 
BEARINGS.  Check  bearing  temperature 
with  thermometer,  not  by  hand.  If  antifriction 
bearings  are  running  hot,  check  for  over- 
lubrication  and  relieve  if  necessary  If  sleeve 
bearings  run  too  hot,  check  for  lack  of 
lubricant.  If  proper  lubrication  does  not  cor- 
rect condition,  disassemble  and  inspect 
bearing.  Check  alignment  of  pump  and  mo- 
tor if  high  temperatures  continue. 

S  10.  CHECK  ALIGNMENT  OF  PUMP  AND  MO- 
TOR. For  method  of  aligning  panp  and 
motor,  see  Paragraph  10:  Couplings.  If  mis- 
alignment recurs  frequently,  inspect  entire 
piping  system.  Unbolt  piping  at  suction  and 
discharge  nozzles  to  see  if  it  springs  away, 
indicating  strain  on  casing.  Check  all  piping 
supports  for  soundness  and  effective  sup- 
port of  load. 

Vertical  pumps  usually  have  flexible  shafting 
which  permits  slight  angular  misalignment; 


however,  if  solid  sJiafting  is  used,  align 
exactly.  If  beams  carrying  intermediate 
bearings  are  too  light  or  are  subject  to 
contraction  or  expansion,  replace  beams 
and  realign  intermediate  bearings  carefully. 

1 1    INSPECT  AND  SERVICE  PUMPS. 

a  Remove  rotating  element  of  pump  and 
inspect  thoroughly  for  wear.  Order  re- 
placement parts  where  necessary- 
Check  impeller  clearance  between  vo- 
lute 

b.  Remove  any  deposit  or  scaling.  Clean 
out  v/ater-seal  piping. 

c.  Determine  pump  capacity  by  pumping 
into  empty  tank  of  known  size  or  by 
timing  the  draining  of  pit  or  sump. 


Pump  Capacity,  GPM 


Volume,  gallons 
Time,  minutes 


or 


Pump  Capacity, 


liters    Volume,  liters 


sec    Time,  seconds 


ERIC 


See  EXAMPLE  1  for  procedures  on  how 
to  calculate  pump  capacity. 

d.  Test  pump  efficiency.  Refer  to  pump 
manufacturer's  instructions  on  how  to 
collect  data  and  perform  calculations. 
Also  see  pages  147  and  148  in  SMALL 
WMER  SYSTEM  OPERATION  AND 
MAINTENANCE  of  this  series  of  man- 
uals. 

e.  Measur<?  total  dynamic  suction  head  or 
lift  and  discharge  head  to  test  pump  and 
pipe  condition.  Record  figures  for  com- 
parison with  later  tests. 

f.  Inspect  foot  and  check  valves,  paying 
particular  attention  to  check  valves, 
which  can  cause  water  hammer  when 
pump  stops.  (See  Paragraph  13:  Check 
Valves  also.)  Foot  valves  are  a  type  of 
check  valve  which  are  used  when  pump- 
ing raw  water. 

g.  Examine  wearing  rings.  Replace  serious- 
ly worn  wearing  rings  to  improve  efficien- 
cy. Check  wearing  ring  clearances  which 
generally  should  be  no  more  than  0.003 
inch  per  inch  of  wearing  diameter. 

CAUTION:  To  protect  rings  and  castings, 
never  allow  pump  to  run  dry  through  lack 
of  proper  priming  when  starting  or  loss  of 
suction  when  operating. 

12.  DRAIN  PUMP  FOR  LONG-TERM  SHUT- 
DOWN. When  shutting  down  pump  for  a 
long  pcnod,  open  motor  disconnect  switch; 
and  if  so  equipped,  turn  on  the  electnc 
motor  winding  heaters.  Shut  all  valves  on 
suction,  discharge,  water-seal,  and  priming 
lines;  dram  pump  completely  by  removing 
vent  and  drain  plugs.  This  procedure  pro- 
tects pump  against  corrosion,  sedimenta- 
tion, and  freezing.  Inspect  pump  and  bear- 
ings thoroughly  and  perform  all  necessary 

2ii:i 


272  Water  Treatment 


Frequency 
of 
Service 


servicing.  Drain  bearing  housings  and  re- 
plenish with  fresh  oil.  purge  old  grease  and 
replace.  When  a  pump  is  out  of  service,  run 
it  monthly  to  warm  It  up  and  to  distribute 
lubncalion  so  the  packing  will  not  "freeze"  lo 
the  shaft.  Resume  periodic  checks  after 
pump  is  put  back  in  service. 


FORMULAS 

To  find  the  volumes  of  a  rectangle  In  cubic  feet,  multiple 
the  length  times  width  times  depth. 

Volume,  cu  ft  =  (Length,  ft)  (Width,  ft)  (Depth,  ft) 

To  find  the  volume  of  a  cylinder  in  cubic  feet,  multiply 
0.785  times  the  diameter  squaied  times  the  depth. 

Volume,  cu  ft  =  (0.785)  (Diameter,  ft}^  (Depth,  ft) 

To  convert  a  volume  from  cubic  feet  to  gallons,  multiply 
the  volume  in  cubic  feet  times  7.48  gallons  per  cubic  foot. 

Volume,  gal  =  (Volume,  cu  ft)  (7.48  gal/cu  ft) 

To  calculate  the  output  or  capacity  of  a  pump  in  gallons 
per  minute,  divide  the  volume  pumped  in  gallons  by  the 
pumping  time  in  minutes. 

no*   r^r^^M    Volume  Pumped,  gallons 

Pump  Capacity,  GPM  =  — —  

Pumping  Time,  minutes 


EXAMPLE  1 

A  pump's  capacity  is  measured  by  recording  the  time  in 
minutes  for  water  to  rise  3  feet  in  an  8-foot  diameter  tank. 
What  is  the  pumping  rate  or  capacity  in  gallons  per  minute 
when  the  pumping  time  is  9  minutes? 

Known  Unknown 

Diameter,  ft  =  8  ft  Pump  Capacity.  GPM 

Depth,  ft     =  3  ft 
Time,  min    =  9  min 
Calculate  the  tank  volume  in  cubic  feet. 

Volume,  cu  ft  =  (0.785)  (Diameter,  ft)^  (Depth,  ft) 

=  (0.785)  (8  ft)2  (3  ft) 

=  151  cu  ft 

Convert  the  tank  volume  from  cubic  feet  to  gallons. 
Volume,  gal  =  (Volume,  cu  ft)  (7.48  gal/ru  ft) 

=  (151  cu  ft)  (7  48  gal/cu  ft) 

=  1129  gallons 

Calculate  the  pump  capacity  in  gallons  per  minute. 

^      .    _        Volume  Pumped,  qal 

Pump  Capacity,  GPM  =   ^    '  ^ 

Pumping  Time,  min 

_  1129  gallons 

9  min 

=  125  GPM 

ERLC 


QUESTIONS 

Wnte  your  answers  m  a  notebook  and  then  compare  your 
answers  with  those  on  page  325. 

18  23A  What  is  a  cross-connection'? 

18.23B  Is  a  slight  water-seal  leakage  desirable  when  a 
pump  is  running?  If  so,  why? 

18.23C  How  would  you  measure  the  capacity  of  a  pump? 

18.23D  Estimate  the  capacity  of  a  pump  (In  GPM)  if  it 
lowers  the  water  in  a  10-foot  wide  by  15-foot  long 
wet  well  1.7  feet  in  five  minutes. 

1 8.23E  What  should  be  done  to  a  pump  before  !t  Is  shut 
down  for  a  long  time,  and  why? 

Paragraph  2:  Reciprocating  Pumps,  General 

The  general  procedures  in  this  paragraph  apply  lo  all 
reciprocating  pumps  described  in  this  section. 

Frequency 
of 

Service 


W  1.  CHECK  SHEAR  PIN  ADJUSTMENT.  Set  ec- 
centric by  placing  shear  pin  through  proper 
hole  In  eccentric  f'anges  to  give  required 
stroke.  Tighten  the  two  Vs-  or  %-inch  hexag- 
onal nuts  on  connecting  rods  just  enough  to 
take  spring  out  of  lock  washers.  (See  Para- 
graph 11:  Shear  Pins).  When  a  shear  pin 
fails,  eccentric  moves  toward  neutral  posi- 
tion, preventing  damage  to  the  pump.  Re- 
move cause  of  obstruction  and  Insert  new 
shear  pin.  Shear  pins  fall  because  of  one  of 
three  common  causes: 

(1)  Solid  object  lodged  under  piston, 

(2)  Clogged  discharge  line,  and 

(3)  Stuck  or  wedged  valve. 

D  2.  CHECK  PACKING  ADJUSTMENT.  Give 
special  attention  to  packing  adjustment.  If 
packing  is  too  tight.  It  reduces  efficiency  and 
scores  piston  walls.  Keep  packing  just  tight 
enough  to  keep  s'udge  from  leaking  through 
gland.  Before  pump  is  installed  or  after  it 
has  been  idle  for  a  time,  loosen  all  nuts  on 
packing  gland.  Run  pump  with  sludge  suc- 
tion line  closed  and  valve  covers  open  for  a 
few  minutes  to  break  In  the  packing.  Turn 
down  gland  nuts  no  more  than  necessary  to 
prevf-ni  sludge  from  getting  past  packing. 
Tighten  all  packing  nuts  uniformly. 

When  packing  gland  bolts  cannot  be  taken 
up  farther,  remove  packing.  Remove  old 
packing  and  thoroughly  clean  cylinder  and 
piston  walls.  Place  new  packing  Into  cylin- 
der, staggering  packing-ring  joints,  and 
tamp  each  ring  into  place.  Break  In  and 
adjust  packing  as  explained  above.  When 
chevron  type  P'-^.king  is  used,  tighten  gland 
nuts  only  finger  tight  becauss  excessive 
pressure  ruins  packing  and  scores  plunger. 

Q  3.  CHECK  BALL  VALVES.  When  vaVe  balls 
are  so  worn  that  diameter  Is  Ve  inch  (1 .5  cm) 
smaller  than  original  size,  they  may  jam  Into 


Maintenance  273 


Frequency 
of 
Service 


guides  in  valve  chamber.  Check  size  of 
valve  balls  and  replace  if  badly  worn. 

Q        4.  CHECK  VALVE-CHAMBER  GASKETS. 

Valve-chamber  gaskets  on  most  pumps 
serve  as  a  safety  device  and  blow  out  under 
excessive  pressure.  Check  gaskets  and  re- 
place if  necessary.  Keep  additional  gaskets 
on  hand  for  replacement. 

A  5.  CHECK  ECCENTRIC  ADJUSTMENT.  To 
take  up  babbitt  bearing,  remove  brass 
shims  provided  on  connecting  rod.  After 
removing  shims,  operate  pump  for  at  least 
one  hour  and  check  to  see  that  eccentric 
does  not  run  hot. 

D  6.  NO^E  UNUSUAL  NOISES.  Check  for  no- 
ticoable  water  hammer  when  pump  is  oper- 
ating. This  noise  is  most  pronounced  when 
pumping  water  or  very  thin  sludge;  it  de- 
creases or  disappears  when  pumping  heavy 
sludge.  Eliminate  noise  by  opening  the  V4- 
inch  (0.6  cm)  petcock  on  pump  body  slightly: 
this  draws  in  a  small  amount  of  air,  keeping 
discharge  air  chamber  full  at  all  times. 

D  7.  CHECK  CONTROL  VALVE  POSITIONS.  Be- 
cause any  plunger  pump  may  be  damaged  if 
operated  against  closed  valves  in  the  pipe- 
line, especially  the  discharge  line,  make  all 
valve  setting  changes  with  pump  shut  down; 
otherwise  pumps  which  are  installed  to 
pump  from  two  sources  or  to  deliver  to 
separate  tanks  at  different  times  may  be 
broken  if  all  discharge  line  valves  are  closed 
simultaneously  for  a  few  seconds  or  dis- 
charge valve  directly  above  pump  is  closed. 

W  8.  GEAR  REDUCER.  Check  oil  level  by  remov- 
ing plug  on  the  side  of  the  gear  case  Unit 
should  not  be  in  operation. 

Q  9.  CHANGE  OIL  AND  CLEAN  MAGNETIC 
DRAIN  PLUG. 

W  1 0.  CONNECTING  RODS.  Set  oilers  to  disperse 
two  drops  per  minute. 

W  11.  PLUNGER  CROSSHEAD.  Fill  plunger  as  re- 
quired to  half  cover  the  wrist  pin  with  oil. 

D  12.  PLUNGER  TROUGH.  Keep  small  quantity  of 
oil  in  trounh  to  lubricate  the  plunger. 

M  13  MAIN  SHAFT  BEARING.  Grease  bearings 
monthly.  Pump  should  be  in  operation  when 
lubricating  to  avoid  excessive  pressure  on 
seals. 

14.  CHECK  ELECTRIC  MOTOR.  See  Para- 
graph 5:  Electric  Motors. 


Paragraph  3:  Propeller  Pumps,  General 

D        1.  CHECK  MOTOR  CONDITION.  See  Para- 
graphs 6.1  and  6.2. 

D        2.  CHECK  PACKING  GLAND  ASSEMBLY.  See 
Paragraph  1.6. 


W  3.  INSPECT  PUMP  ASSEMBLY.  See  Para- 
graph 1.4. 

W  4.  LUBE  LINE  SHAFT  AND  DISCHARGE 
BOWL  BEARING.  Maintain  oil  in  oiler  at  all 
times.  Adjust  feed  rate  to  approximately 
four  drops  per  minute. 

W  5.  LUBE  SUCTION  BOWL  BEARING.  Lube 
through  pressure  fitting.  Usually  three  or 
four  strokes  of  gun  are  enough. 

W  6.  OPERATE  PUMPS  ALTERNATELY.  See 
Paragraph  1.3. 

A  7.  LUBE  MOTOR  BEARINGS.  See  Paragraph 
6.3. 


Paragraph  4:  Progressive  Cavity  Pumps,  General 

(Fig.  18.20,  page  260). 

D  1  CHECK  MOTOR  CONDITION.  See  Para- 
graphs 6.1  and  6.2. 

D  2.  CHECK  PACKING  GLAND  ASSEMBLY.  See 
Paragraph  1.6. 

D  3.  CHECK  DISCHARGE  PRESSURE.  A  higher 
than  normal  discharge  pressure  may  indi- 
cate a  line  blockage  or  a  closed  valve  down- 
stream. An  abnormally  low  discharge  pres- 
sure can  mean  reduced  rate  of  discharge. 

S  4.  INSPECT  AND  LUBRICATE  BEARINGS  — 
GREASE.  If  possible,  remove  bearing  cover 
and  visually  inspect  grease.  When  greasing, 
remove  relief  plug  and  cautiously  add  5  or  6 
strokes  of  the  grease  gun.  Afterwards, 
check  bearing  temperature  with  thermom- 
eter. If  over  220''F  (104*^0),  remove  some 
grease. 

5.  LUBEFLUSH  MOTOR  BEARINGS.  See 
Paragraph  6.3. 

6.  CHECK  PUMP  OUTPUT  Check  how  long  it 
takes  to  fill  a  vessel  of  known  volume  or 
quantity;  or  check  performance  against  a 
meter,  if  available.  See  Paragraph  1.1  I.e. 


S 
S 

A 

A 


7.  SCOPE  MOTOR  BEARINGS.  See  Para- 
graph 6.4. 

8.  SCOPE  PUMP  BEARINGS.  See  Paragraph 
6.4. 


Paragraph  5:  Pump  Controls 

To  ensure  the  best  operation  of  the  pump,  a  systematic 
inspection  of  the  controls  should  be  made  at  least  once  a 
week. 

W  1.  CHECK  CONTROLS.  Controls  respond  to 
the  control  variable. 

W  2.  STARTUP.  The  unit  starts  when  the  control 
^.yotem  makes  contact,  and  the  pump  stops 
at  the  prescribed  control  setting. 

W  3.  MOTOR  SPEED.  The  motor  comes  up  to 
speed  quickly  and  is  maintained. 

W  4.  SPARKING.  A  brush-type  motor  does  not 
spark  profusely  in  starting  or  running. 


2<J4 


274  Water  Treatment 


Frequency 
of 

Service 
W 


W 


INTERFERENCE  WITH  CONTROLS. 
Gr  se  and  d»rt  are  not  interfering  with 
conn  uls. 

ADJUSTMENTS.  Any  necessary  adjust- 
ments are  properly  completed. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  325. 

1 8.23F  What  are  some  of  the  common  causes  of  shear  pin 
failure  in  reciprocating  pumps? 

18.23G  What  may  happen  when  water  or  a  thin  sludge  is 
being  pumped  by  a  reciprocating  pump? 

18.23H  What  could  be  the  causes  of  a  higher  than  normal 
discharge  pressure  in  a  progressive  cavity  pump? 


Paragraph  6:  Electric  Motors  (Fig.  18.26) 

In  order  to  ensure  the  proper  and  continuous  function  of 
electric  motors,  the  items  listed  in  this  paragraph  must  be 
performed  at  the  designated  imervals.  If  operational  checks 
indicate  a  motor  is  not  functioning  properly,  these  items  will 
have  to  be  checked  to  locate  the  Drobiem. 

D        1.  CHECK  MOTOR  CONDITIONS. 

a.  Keep  motors  free  from  dirt,  duot  and 
moisture. 

b.  Keep  operating  space  free  from  articles 
which  may  obstruct  air  circulation. 

c.  Check  for  excessive  grease  leakage 
from  bearings. 

D        2.  NOTE  ALL  UNUSUAL  CONDITIONS. 

a.  Unusual  noises  in  operation. 

b.  Motor  failing  to  start  or  come  to  speed 
normally,  sluggish  operation. 

c.  Motor  or  bearings  which  feel  or  smell 
hot. 

d.  Continuous  or  excessive  sparking  com- 
mutator or  brushes.  Blackened  commu- 
tator. 

e.  Intermittent  sparking  at  brushes. 

f.  Fine  dust  under  coupling  having  rubber 
buffers  or  pins. 

g.  Smoke,  charred  insulation,  or  solder 
whiskers  extending  from  armatu''e. 

h.  Excessive  humming. 

i.  Regular  clicking, 
j.  Rapid  knocking. 


Frequency 
of 
Service 

k.  Brush  chatter. 

I.  Vibration. 

m.  Hot  commutator. 

A  3  LUBRICATE  BEARINGS  (Fig.  18.27).  Check 
grease  in  ball  bearing  and  relubricate  when 
necessary. 

Follow  instructions  in  Section  18.224,  Pump 
Lubrication,  when  lubricating  greased  bear- 
ings. 

A  4.  USING  A  STETHOSCOPE.^^  CHECK  BOTH 
BEARINGS.  Listen  for  whines,  gratings,  or 
uneven  noises.  Listen  all  around  the  bearing 
and  as  near  as  possible  to  the  bearing. 
Listen  while  the  motor  is  being  started  and 
shut  off.  If  unusual  noises  are  heard,  pin- 
point the  location. 

5.  IF  YOU  THINK  THE  MOTOR  is  running 
unusually  hot,  check  with  a  thermometer. 
Place  the  thermometer  on  the  casing  near 
the  bearing,  holding  it  there  with  putty  or 
clay.  Check  the  current  on  each  leg  to 
determine  if  the  currents  are  balanced  and 
within  the  motor  name  plate  limits. 

A  6.  DATEOMETER}^  If  there  is  a  dateome  er 
on  the  motor,  after  changing  the  oil  in  the 
motor,  loosen  the  dateometer  screw  and  set 
to  the  corresponding  year. 

QUESTiONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  325. 

18.231    What  are  the  major  items  you  would  include  when 
checking  an  electric  motor? 

18.23J  What  is  the  purpose  of  a  stethoscope? 

Paragraph  7:  Belt  Drives 

Frequency 
of 
Service 

1.  GENERAL.  Mamtaii-ing  a  proper  tension 
and  alignment  of  belt  drives  ensures  long 
life  of  belts  and  sheaves.  Incorrect  align- 
ment causes  poor  operation  and  excessive 
belt  wear.  Inadequate  tension  reduces  the 
belt  gnp,  causes  high  belt  loads,  snapping, 
and  unusual  wear. 

a.  Cleaning  belts.  Keep  belts  and  sheaves 
clean  and  free  of  oil,  which  causes  belts 
to  deteriorate.  To  remove  oil,  take  belts 
off  sheaves  and  wipe  belts  and  sheaves 
with  a  rag  moistened  in  a  non-oil  base 
solvent.  Carbon  tetrachloride  is  NOTrec- 


I*  Stethoscope.   An  instrument  used  to  magnify  sounds  and  convey  them  to  the  ear 


ERIC 


Maintenance  275 


DRIP  PROOF 


ITEM 

PART  NAME 

NO. 

1 

Wound  Stator  w/  Frame 

2 

Rotor  Assembly 

3 

Rotor  Core 

4 

Shaft 

5 

Bracket 

6 

Bearing  Cap 

7 

Bearings 

8 

Seal,  Labyrinth 
Thru  Bolts /Caps 

9 

10 

Seal,  Lead  Wire 

11 

Terminal  Box 

12 

Terminal  Box  Cover 

13 

Fan 

14 

Deflector 

15 

Lifting  Lug 

11*5 


TOTALLY  ENCLOSED  PAN  COOLED 


ITEM 

NO. 

PART  NAME 

1 

Wound  Stator  w/  Frame 

2 

Rotor  Assembly 

3 

Rotor  Gore 

4 

Shaft 

5 

Brackets 

6 

Bearings 

7 

Seal,  Labyrinth 

8 

Thru  Bolts /Caps 

9 

Seal,  Lead  Wire 

10 

Terminal  Box 

11 

Terminal  Box  Cover 

12 

Fan J  Inside 

13 

''an.  Outside 

14 

Fan  Grill 

15 

Fan  Cover 

16 

Fan  Cover  Bolts 

17 

Lifting  Lug 

Fig.  18.26   Typical  motors 

{C'^Mosi  of  Sterling  Power  Systems.  Inc ) 


276  Water  Treatment 


ELECTRIC  MOTOR 


MOTOR  LUBRICATION 


FRONT  BEARING  BRACKET 
FRONT  AIR  DEFLECTOR 
FAN 
ROTOR 

FRONT  BEARING 
END  COVER 
STATOR 


8  SCREENS 

9  CONDUirBOX 

10  BACK  AIR  DEFLECTOR 

11  BACK  BEARING 

12  BACK  BEARING  BRACKET 

13  OIL  LUBRICATION  CAP 


Fig.  18.27  Electric  motor  lubrication 


ERIC 


Maintenance  277 


Frequency 
of 

Service 


ommended  because  exposure  to  its 
fumes  has  many  toxic  effects  on  hu- 
mans. Carbon  tetrachloride  also  is  ab- 
sorbed into  the  skin  on  contact  and  its 
effects  become  stronger  with  each  con- 
tact. 

b.  Installing  belts.  Before  installing  belts, 
replace  //orn  or  damaged  sheaves,  len 
slack  off  on  adjustments.  Do  not  try  to 
force  belts  into  position.  Never  use  a 
screwdriver  or  similar  lever  to  get  belts 
onto  sheaves.  After  belts  are  installed, 
adjust  tension;  recheck  tension  after 
eight  hours  of  operation.  (See  Table 
18.3). 

c.  Replacing  belts.  Replace  belts  as  soon 
as  they  become  frayed,  worn,  or 
cracked.  NEVER  REPLACE  ONLY  ONE 
V-BELT  ON  A  MULTIPLE  DRIVE.  Re- 
place the  complete  set  with  a  set  of 
matched  belts,  whi'.  h  can  be  obtained 
from  any  supplier.  All  belts  in  a  matched 
set  are  machine-checked  to  insure  equal 
size  and  tension. 

d.  Storing  spare  belts.  Store  spare  belts  in  a 
cool,  dark  place.  Tag  all  belts  in  storage 
to  identify  them  with  the  equipment  on 
which  they  can  be  used, 

2.  V-3ELTS.  A  properly  adjusted  V-belt  has  a 
slight  bow  in  the  slack  side  when  running; 
when  idle  it  has  an  alive  springiness  \NUen 
thumped  with  the  hand.  An  improperly  tight- 
ened helt  feels  dead  when  thumped. 

If  the  slack  side  of  the  drive  is  less  than  45° 
from  the  horizontal,  vertical  sag  at  the  cen- 
ter of  the  span  may  be  adjusted  in  accor- 
dance With  table  18.3  below: 


TABLE  18.3   HORIZONTAL  BELT  TENSION 


span 
(inches) 

10 

20 

50 

100 

150 

200 

Vertical 
Sag 

From 

01 

03 

20 

80 

1  80 

3  30 

(inches) 

To 

03 

09 

58 

2  30 

4  90 

8  60 

Span 
(miiiimoters) 

250 

500 

1250 

2500 

3750 

5000 

Vertical 
Sag 

From 

0  25 

0  75 

5  00 

POO 

45  0 

82  5 

(rniUimeters) 

To 

0  75 

2  25 

14  50 

57  5 

122  5 

2150 

M  a.  Check  tension.  If  tightening  belt  to  proper 

tension  does  not  cc  ect  slipping,  check 
for  overload,  oil  on  belts,  or  other  possi- 
ble causes.  Never  use  belt  dressing  to 
stop  belt  slippage.  Rubber  wearings  near 
the  drive  are  a  sign  of  improper  tension. 
Incorrect  alignment,  or  damaged 
sheaves. 

M  b.  Check  sheave  (pulley)  alignment.  Lay  a 

long  straight  edge  or  string  across  out- 
side faces  of  pulley,  and  allow  for  differ- 
ences in  dimensions  from  center  lines  of 
grooves  to  outside  faces  of  the  pulleys 

O 

ERLC 


being  aligned.  Be  especially  careful  in 
aligning  drives  with  more  than  one  V-be't 
on  a  sheave,  as  misalignment  can  cai<se 
unequal  tension 

Parrigraph  8:  Chain  Drives 

1.  GENERAL.  Cham  drives  may  bo  designated 
for  slow,  medium,  or  high  speeds. 

a.  Slow-speed  drives.  Because  slow-speed 
drives  are  usually  enclosed,  adequate 
lubrication  5s  difficult.  Heavy  oil  applied  to 
the  outside  of  the  chain  seldom  reaches 
the  working  parts;  in  addition,  the  oil 
catches  dirt  and  grit  and  becomes  abra- 
sive. For  lubricating  and  cleaning  meth- 
ods, see  5  and  6  below. 

b.  Medium-  and  high-speed  drives.  Medi- 
um-speed drives  should  be  continuously 
lubricated  with  a  device  similar  to  a  sight- 
feed  oiler.  Highspeed  drives  should  be 
completely  enclosed  in  an  oil-tight  case 
and  the  oil  maintained  at  proper  level. 

D  2.  CHECK  OPERATION.  Check  general  oper- 
ating condition  during  regular  tours  of  duty. 

Q  3.  CHECK  CHAIN  SLACK.  The  correct  amount 
of  slack  IS  essential  to  proper  oneration  of 
chain  drives.  Unlike  other  belts,  chain  belts 
should  not  be  tight  around  the  sprocket; 
when  chains  are  tight,  working  parts  carry  a 
much  heavier  load  than  necessary.  Too 
much  slack  is  also  harmful;  on  long  centers 
particularly,  too  much  slack  causes  vibra- 
tions and  chain  whip,  reducing  life  of  both 
chain  and  sprocket.  A  properly  installed 
Cham  has  a  slight  sag  or  looseness  on  the 
return  run. 

S  4.  CHECK  ALIGNMENT.  If  sprockets  are  not  in 
line  or  if  shafts  are  not  parallel,  excessive 
sprocket  and  chain  wear  and  early  chain 
failure  result.  Wear  on  inside  of  chain,  side 
walls,  and  sides  of  sprocket  teeth  are  signs 
of  misalignment.  To  check  alignment,  re- 
move chain  and  place  a  straight  edge 
against  sides  of  sprocket  teeth. 

S  5.  CLEAN.  On  enclosed  types,  flush  chain  and 
enclosure  with  a  petroleum  solvent  (kero- 
sene). On  exposed  types,  remove  chain  and 
soak  and  wash  it  in  solvent.  Clean  sprock- 
ets, install  chain,  and  adjust  tension. 

S  6.  CHECK  LUBRICATION.  Soak  exposed-type 
chains  in  oil  to  restc.e  lubricating  film.  Re- 
move excess  lubricant  by  hanging  chains  up 
to  drain. 

Do  not  lubricate  underwater  chains  which 
operate  in  contact  with  considerable  grit.  If 
water  is  clean,  lubricate  by  applying  water- 
proof grease  with  brush  while  chain  is  run- 
ning. 

Do  not  lubricate  chains  on  elevators  or  on 
conveyors  of  feeders  A^hich  handle  dirty  or 
gritty  materials.  Dust  and  grit  combine  with 
'ubricants  to  form  a  cutting  compound  which 
reduces  chain  life. 


278  Water  Treatment 


Frequency 
of 

Service 


S  7.  CHANGE  OIL.  On  enclosed  types  only,  dra.n 
Oil  and  refill  case  to  proper  level. 

S  8.  INSPECT.  Note  and  correct  abnormal  condi- 
tions before  scnous  damage  results.  Do  not 
put  a  new  chain  on  worn  sprockets.  Always 
replace  worn  sprockets  when  replacing  a 
chain  because  out-of-pitch  sprockets  cause 
as  much  chain  wear  in  a  few  hours  as  years 
of  normal  operation. 

9.  TROUBLESHOOTING.  Some  common 
symptoms  of  improper  chain-drive  oper- 
ation and  their  remedies  follow: 

a.  Excessive  noise.  Correct  alignment,  if 
misaligned.  Adjust  centers  for  proper 
Cham  slack.  Lubricate  In  accordance  with 
aforementioned  methods.  Be  sure  all 
bolts  are  tight.  If  chain  or  sprockets  are 
worn,  reverse  or  renew  if  necessary. 

b.  Wear  on  chain,  side  walls,  and  sides  of 
teeth.  Remove  chain  and  correct  align- 
ment. 

c.  Chain  climbs  sprockets.  Check  for  poorly 
fitting  sprockets  and  replace  if  neces- 
sary. Make  sure  tightener  is  installed  on 
dnve  Cham. 

d.  Broken  pins  and  rollers.  Check  fo-^  chain 
speed  which  may  be  too  high  ,or  the 

pitoii.  UMU  buuotuuic  oiidiii  dfiO  bpfUCKetS 

with  shorter  pitch  if  necessary.  Breakage 
abo  may  be  caused  by  shock  loads. 

e.  Cham  clings  to  sprockets  Check  for  in- 
correct or  worn  sprockets  or  heavy, 
tacky  lubricants.  Replace  sprockets  or 
lubricants  i'  necessary. 

f.  Cham  whip.  Check  for  too-long  centers 
or  high,  pulsating  loads  and  correct 
cause. 

g.  Chains  get  stiff.  Check  for  misalignment, 
improper  lubncation,  or  excessive  over- 
loads. Make  necessary  corrections  or 
adjustments. 

Paragraph  9;  Variable  Speed  Belt  Drives  (See  Fig  18.28) 

D  1-  C'-EAN  DISCS.  Remove  grease,  acid,  and 
water  from  disc  faces. 

D        2.  CHECK  SPEED-CHANGE  MECHANISM. 

Shift  drive  through  entire  speed  range  to 
make  sure  shafts  and  bearings  are  lubricat- 
ed and  discs  move  freely  in  lateral  direction 
on  shafts. 

W  3.  CHECK  V-BELT.  Make  sure  it  runs  level  and 
true.  If  one  side  rides  high,  a  disc  is  sticking 
on  shaft  because  of  insufficient  lubncation 
or  wrong  lubricant.  In  this  case,  stop  the 
drive  at  once,  remove  V-belt,  and  clean  disc 
hub  and  shaft  thoroughly  with  petroleum 
solvent  until  disc  moves  freely.  Relubricate 
with  soft  ball-beanng  grease  and  replace  V- 

ERIC 


Frequency 
of 

Service 


belt  in  opposite  direction  from  that  in  which 
It  formerly  ran. 

M  If  drive  is  not  operated  for  30  days  or  more, 

shift  unit  to  minimum  speed  position,  plac- 
ing spnng  on  vanable-speed  shaft  at  mini- 
mum tension  and  relieving  belt  of  excessive 
pressure. 

4  LUBRICATE  DRIVE.  Make  sure  to  apply 
lubricant  at  all  the  six  force-feed  lubrication 
fittings  (Fig.  1 8.28:  A,  B,  D,  E,  G  and  H)  and 
the  one  cup  type  fitting  (C). 

NOTE:  If  the  drive  is  used  with  a  reducer, 
fitting  E  IS  not  provided. 

W  a.  Once  every  ten  days  to  two  weeks,  use 

two  or  three  strokes  of  a  grease  gun 
through  fittings  A  and  B  at  ends  of  shift- 
ing screw  and  variable-speed  shaft,  re- 
spectively, to  lubricate  bearings  of  mov- 
able discs.  Then,  with  unit  running,  shift 
drive  from  one  extreme  speed  position  to 
the  other  to  ensure  thorough  distribution 
of  lubricant  over  disc-hub  bearings. 

0  b.  Add  two  or  three  shots  of  grease  through 

fittings  D  and  E  to  lubricate  frame  bearing 
on  variable-speed  shaft. 

Q  c  Every  90  days,  add  two  or  three  cupfulls 

of  grease  to  Cud  C  which  lubricates 
thrust  bearing  on  constant-speed  shaft. 

Q  d.  Every  90  days,  use  two  or  three  strokes 

of  grease  gun  through  fittings  G  and  H  to 
lubncate  motorframe  beanngs. 

CAUTION:  Be  sure  to  follow  manufactur- 
er's recommendation  on  type  of  grease. 
After  lubricating,  wipe  excessive  grease 
from  sheaves  and  belt. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
ansv^ers  with  those  on  page  325. 

18  23K  How  can  you  tell  if  a  belt  on  belt-drive  equipment 
has  proper  tension  and  alignment 

18  23L  Why  should  sprockets  be  replaced  when  replacmg 
a  Cham  in  a  chain-drive  unif 

Paragraph  10:  Couplmgs 

1  GENERAL.  Unless  couplings  between  the 
driving  and  driven  elements  of  a  pump  or 
any  other  piece  of  equipment  are  kept  in 
proper  alignment,  breaking  and  excessive 
weai  results  m  either  or  both  the  driven 
machinery  and  the  driver.  Burned-out  bear- 
ings, sprung  or  broken  shaft,  and  exces- 
sively worn  or  ruined  gears  are  some  of  the 
damages  caused  by  misalignment.  To  pre- 
vent oui^ages  and  the  expense  of  installing 
replacement  parts,  check  [he  alignment  of 
all  equipment  before  damage  occurs. 

29j 


Maintenance  279 


NOTE  A,  B,  D,  E,  G  and  H  are  force-feed  lubrication  fittings. 
C  ts  a  cup  type  lubncation  fitting 

Fig  18.28  Reeves  '  aridnve 

(Source  war  Departmenl  Technical  Manual  TMS-666) 


Frequency 
of 
Service 


a.  Improper  original  installation  of  the 
equipment  may  not  necessarily  be  the 
cause  of  the  trouble.  Settling  of  founda- 
tions, heavy  floor  loadings,  warping  of 
bases,  excessive  bearing  wear,  and 
many  other  factors  cause  misalignment. 
A  ngid  base  is  not  always  security 
against  misalignment.  The  base  may 
have  been  mounted  off  level,  which  could 
cause  it  to  warp. 

b.  Flexible  couplings  permit  easy  assembly 
of  equipment,  but  they  must  be  aligned 
as  exactly  as  flanged  couplings  if  maintp- 
nance  and  r«»pair  are  to  be  kept  a 
minimum.  Rubber-bushed  *ypes  cannot 
function  properly  if  the  bolts  cannot 
move  in  their  bushings. 

S  2.  CHECK  COUPLING  ALIGNMENT  (straight 
edge  method).  Excessive  bearing  and  motor 
temperatures  caused  by  overload,  notice- 
able vibration,  or  unusual  noises  may  all  be 
warnings  of  misalignment.  Realign  when 


necessary  (Fig  18  29)  using  a  straight  edge 
and  thickness  gage  or  wedge.  To  ensure 
satisfactory  operation,  level  up  to  within 
0.005  inch  (0.13  mm)  as  follows: 

a.  Remove  coupling  pins. 

b.  Rigidly  tighten  driven  equipment;  slightly 
tighten  bolts  holding  drive. 

c  To  correct  horizontal  and  vertical  misa- 
lignment, shift  cr  shim  drive  to  bring 
coupling  halves  into  position  so  no  I'ght 
can  be  seen  under  a  straight  edge  laid 
across  them.  Place  straight  edge  in  four 
positions,  holding  a  light  in  back  of 
straight  edge  to  help  ensure  accuracy. 

d.  Check  for  angular  misalignment  with  a 
thickness  or  feeler  gage  inserted  at  four 
placfts  to  make  certain  space  between 
coupling  halves  is  equal. 

e.  If  proper  alignment  has  been  secured, 
coupling  pins  can  be  put  in  place  easily 
using  only  finger  pressure.  Never  ham- 
mer pins  into  place. 

f.  If  equipment  is  still  out  of  alignment, 
repeat  the  procedure. 

30'.j 


280  Water  Treatment 


—  STRAIGHT  EDGE 


FEELER  GAGE  - 

ANGULAR  MISALIGNMENT 


FEELER  GAGE 
PERFECT  ALIGNMENT 


Fig.  18.29  Testing  alignment  straight  edge 

(Source  Unknown) 


Frequency 
of 
Service 

S  3  CHECK  COUPLING  ALIGNMENT  (dial  indi- 
cator method).  Dial  indicators  also  are  used 
to  measure  coupling  alignment.  This  meth- 
od produces  better  results  than  the  straight 
edge  method.  The  dial  indicates  very  small 
movements  or  distances  which  are  meas- 
ured in  mils  (one  mil  equals  1/1000  of  an 
inch).  The  indicator  consists  of  a  dial  with  a 
graduated  face  (with  "plus"  and  "minus" 
readings,  a  pedestal,  and  a  rigid  indicator 
bar  (or  "fixture")  as  shown  in  Figure  18.30). 

The  dial  indicator  Is  attached  to  one  cou- 
pling via  the  fixture  and  adjusted  to  the  zero 
position  or  reading.  When  the  shaft  of  the 
machine  Is  rotated,  misalignment  will  cause 
the  pedestal  to  compress  (a  "plus"  reading), 
or  extend  (a  "minus"  reading).  Literature 
;  ovided  by  the  manufacturer  of  machinery 
usually  will  indicate  maximum  allowable  tol- 
erances or  movement. 

Carefully  study  the  manufacturer's  literature 
provided  with  your  dial  Indicator  before  at- 
te.npting  to  use  the  device. 

A  4.  CHANGE  OIL  IN  FAST  COUPLINGS.  Drain 
out  old  oil  and  add  oil  to  proper  level. 
Correct  quantity  is  given  on  instruction  card 
supplied  with  each  coupling. 

Paragraph  11:  Shear  Pins 

Some  water  treatment  units  use  shear  pins  as  protective 
devices  to  prevent  damage  In  case  of  sudden  overloads.  To 
serve  this  purpose,  these  devices  must  be  In  operational 
condition  at  all  times.  Under  some  operating  conditions, 
shearing  surfaces  of  a  shear  pin  device  may  freeze  together 


so  solidly  that  an  overload  fails  to  break  them. 

Me  lufacturers*  drawings  for  particular  installations  usual- 
ly specify  shear  pin  material  and  size.  If  this  information  is 
not  available,  obtain  the  information  from  the  manufacturer, 
giving  the  model,  serial  number,  and  load  conditions  of  unit. 
When  necessary  to  determine  shear  pin  size,  select  the 
lowest  strength  which  does  not  break  under  the  unit's  usual 
loads.  When  proper  size  is  determined,  never  use  a  pin  of 
greater  strength,  such  as  a  bolt  or  a  nail. 

If  necked  pins  are  used,  be  sure  the  necked-down  portion 
IS  properly  positioned  with  respect  to  shearing  surfaces. 
When  a  shear  pin  breaks,  determine  and  remedy  the  cause 
of  failure  before  inserting  new  pin  and  starting  drive  in 
operation. 


Frequency 
of 
Service 

M         1   GREASE  SHEARING  SURFACES 

Q  2.  REMOVE  SHEAR  PIN.  Operate  motor  for  a 
short  time  to  smooth  out  any  corroded 
spots. 

A  3.  CHECK  SPARE  INVENTORY.  Make  sure  an 
adequate  supply  is  on  hand,  properly  Identi- 
fied and  with  record  of  proper  pin  size, 
necked  diameter,  and  longitudinal  dimen- 
sions. 

QUESTIONS 

Write  your  answors  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  325. 

18.23M  What  factors  could  cause  couplings  to  become  out 
of  alignment? 


ERIC 


18.23N  What  is  the  purpose  of  shear  pins'? 

30} 


Maintenance 


INDICATOR  BAR 
(FIXTURE) 


REVERSE 
DIALING 
PARALLEL 
MISALIGNMENT 


ILLUSTRATION  INDICATES 
A  TOTAL  OFFSET  OF 
40  MILS  (20  MILS  +  20  FlILS) 


Fig.  18.30  Use  of  a  dial  indicator 

(Permission  of  DYMAC.  a  Divieion  of  Spectral  Dynamics  Corporation) 

302 


282   Water  Treatment 


18.24  Pump  Operation 

18.240  Starting  a  New  Pump 

The  initial  startup  work  described  in  this  paragraph  should 
be  done  by  a  competent  and  trained  person,  such  as  a 
manufacturer's  representative,  consulting  engineer,  or  an 
experienced  operator.  The  operator  can  learn  a  lot  about 
pumps  and  motors  by  accompanying  and  helping  a  compe- 
tent person  put  new  equipment  into  operation. 

Before  starting  a  pump,  lubncate  it  according  to  the 
lubncation  instructions.  Turn  the  shaft  by  hand  to  see  that  it 
rotates  freely.  Then  cl-eck  to  see  that  the  shafts  of  the  pump 
and  motor  are  ahg.ied  and  the  flexible  coupling  adjusted. 
(Refer  to  Paragraph  10:  Couplings,  page  278;  also  see 
Section  18.23.  "Pump  Maintenance,"  page  265.)  If  the  unit  is 
belt  dijven,  sheave  (pulley)  alignment  and  belt  adjustment 
should  be  checked.  (Refer  to  Paragraph  7:  Belt  Drives.) 
Check  the  electric  voltage  with  tre  motor  characteristics  and 
inspect 


the  wiring  See  that  thermal  overload  units  in  the  starter  are 
set  properly  Turn  on  the  motor  just  long  enough  to  see  that 
it  turns  the  pump  in  the  direction  indicated  by  the  rotational 
arrows  marked  on  the  pump.  If  separate  water  seal  units  or 
vacuum  pr.mer  systems  are  used,  these  should  be  started. 
Finally,  make  sure  lines  are  open  Sometimes  there  is  an 
exception  (see  following  paragraph)  in  the  case  of  the 
discharge  valve. 

A  pump  should  not  be  run  without  first  having  been 
primed  To  pnme  a  pump,  the  pump  must  be  completely 
filled  with  water  In  some  cases,  automatic  primers  are 
provided.  If  they  are  not,  it  is  necessary  to  vent  the  casing. 
Most  pumps  are  provided  with  a  valve  to  accomplish  this. 
Allow  the  trapped  air  to  escape  until  v/ater  flows  from  the 
vent;  then  replace  the  vent  cap.  In  the  case  of  suction-lift 
applications,  the  pump  must  be  filled  with  water  unless  a 
self-primer  is  provided.  !n  nearly  every  case,  you  may  start  a 
pump  with  the  discharge  valve  open.  Exceptions  to  this, 
however,  are  where  water  hammer  or  pressure  surges 
might  result,  or  where  the  motor  does  not  have  sufficient 
margin  of  safety  or  power.  Sometimes  there  are  no  check 
valves  in  the  discharge  iine.  In  this  case  (with  the  exception 
of  positive  displacement  pumps)  it  is  necessary  to  start  the 
pump  and  then  open  the  discharge  lines.  Where  there  are 
common  discharge  headers,  it  is  essential  to  start  the  pump 
and  then  open  the  discharge  valve  A  positive  displacement 
pump  (reciprocating  or  piston  types)  should  never  be  operat- 
ed against  a  closed  discharge  line. 


After  starting  the  pump,  again  check  to  see  that  the 
direction  of  rotation  is  correct.  Packing-gla.id  boxes  (stuffing 
boxes)  should  be  observed  for  slight  leakage  (approximately 
60  drops  per  minute)  as  described  in  Paragraph  1:  Pumps, 
General  Check  to  see  that  the  bearings  do  not  overheat 
from  over-  or  under-lubncation.  The  flexible  coupling  should 
not  be  noisy,  if  it  is,  the  noise  may  be  caused  by  misalign- 
ment or  improper  clearance  or  adjustment.  Check  to  be  sure 
pump  anchorage  is  tight  Compare  delivered  pump  flows 
and  pressures  with  pump  performance  curves.  If  pump 
delivery  falls  below  performance  curves,  look  for  obstruc- 
tions in  the  pipelines  and  inspect  piping  for  leaks 


18.241   Pump  Shutdown 

When  shutting  down  a  pump  for  a  long  period,  the  motor 
disconnect  switch  should  be  opened,  locked  out,  and  tagged 
with  reason  for  tag  noted.  If  the  electric  motor  is  equipped 
with  winding  heaters,  check  to  be  sure  they  are  turned  on. 
This  helps  to  prevent  condensation  from  forming  which  can 
weaken  the  insulation  on  the  windings.  All  valves  on  the 
suction,^  discharge,  and  water-seal  lines  should  be  shut 
tightly.  Completely  dram  the  pump  by  removing  the  vent  and 
dram  plugs. 

Inspect  the  pump  and  beanngs  thoroughly  so  that  all 
necessary  servicing  may  be  done  during  the  inactive  period. 
Dram  the  beanng  housing  and  then  add  fresh  lubricant. 
Follow  any  additional  manufacturer's  recommendations. 


18.242  Pump-Driving  Equipment 

Driving  equipment  used  to  operate  pumps  includes  elec- 
tric motors  and  internal  combustion  engines.  In  rare  in- 
s'tances,  pumps  are  driven  with  steam  turbines,  steam 
engines,  air  and  hydraulic  motors. 

In  all  except  the  large  installations,  electnc  motors  are 
used  almost  exclusively,  with  synchronous  and  induction 
types  being  the  most  commonly  used.  Synchronous  motors 
operate  at  constant  speeds  and  are  used  chiefly  In  large 
sizes.  Three-phase,  squirrel-cage  induction  motors  are  most 
often  used  in  treatment  plants.  These  motors  require  little 
attention  and,  under  average  operating  conditions,  the  fac- 
tory lubncation  of  the  bearing  will  last  approximately  one 
year.  (Check  with  the  manufacturer  for  average  number  of 
operating  hours  for  beanngs.)  When  lubricating  motors, 
remember  that  too  much  grease  may  cause  beanng  trouble 
or  damage  the  winding. 

Clean  and  dry  all  electncal  contacts.  Inspect  for  loose 
electncal  contacts.  Make  sure  that  hold-down  bolts  on 
motors  are  secure.  Check  voltage  while  the  motor  is  starting 
and  running.  Examine  beanngs  and  couplings 

18.243  Electrical  Controls 

A  variety  of  electncal  equipment  is  used  to  control  the 
operation  of  pumps  or  to  protect  .electric  motors.  If  starters, 
disconnect  switches,  and  cutouts  are  used,  they  should  be 
installed  in  accordance  with  the  local  regulations  (city  and/or 
county  '^odes)  regardmg  this  equipment.  In  the  case  of  larger 
motors,  the  power  company  often  requires  starters  which  do 
not  overload  the  power  lines. 

The  electrode-type,  bubbler-type,  and  diaphragm-type 
water  level  control  systems  are  all  similar  in  effect  to  the 
float-switch  system.  Scum  is  a  problem  with  most  water- 
level  controls  that  operate  pumps  and  must  be  removed  on  a 
regular  basis. 


Maintenance  283 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  325. 

1 8.24A  Where  would  you  find  out  how  to  lubricate  a  pump'' 

18  24B  What  problems  can  develop  if  too  much  grease  is 
used  in  lubricating  a  motor'? 

18.244  Operating  Troubles 

The  following  list  of  operating  troubles  includes  most  of 
the  causes  of  failure  or  reduced  operating  efficiency.  The 
remedy  or  cure  is  either  obvious  or  may  be  identified  from 
the  description  of  the  cause. 

SYMPTOM  A  —  PUMP  WILL  NOT  START 
CAUSES: 

'i   Blown  fuses  or  tripped  circuit  breakers  due  to: 

A.  Rating  of  fuses  or  circuit  breakers  not  correct, 

B.  Switch  (breakers)  contacts  corroded  or  shorted, 

C.  Terminal  connections  loose  or  broken  somewhere  in 
the  circuit, 

D.  Automatic  control  mechanism  not  functioning  prop- 
erly, 

E.  Motor  shorted  or  burned  out, 

F.  Wiring  hookup  or  service  not  correct, 

G.  Switches  not  set  for  operation, 

H.  Contacts  of  the  control  relays  dirty  and  arcing, 

I.  Fuses  or  thermal  units  too  warm, 
J.  Wiring  short-circuited,  and 

K.  Shaft  binding  or  sticking  due  to  rubbing  impeller,  tight 
packing  glands,  or  clogging  of  pump. 

2.  Loose  connections,  fuse,  or  thermal  unit 

SYMPTOM  B  —  REDUCED  RATE  OF  DISCHARGE 
CAUSES: 
1   Pump  not  primed 

2.  Air  in  the  water 

3.  Speed  of  motor  too  low 

4.  Improper  wiring 

5.  Defective  motor 

6.  Discharge  head  too  high 

7.  Suction  lift  greater  than  anticipated 

8.  Impeller  clogged 

9.  Discharge  line  clogged 

10.  Pump  rotating  in  wrong  direction 

11.  Air  leaks  in  suction  line  or  packing  box 

12.  Inlet  to  suction  line  too  high,  permitting  air  to  enter 

13.  Valves  partially  or  entirely  closed 


14  Check  valves  stuck  or  clogged 

15  Incorrect  impeller  adjustment 

16  Impeller  damaged  or  worn 
17.  Packing  worn  or  defective 

18  impeller  turning  on  shaft  because  of  broken  key 

19  Flexible  coupling  broken 

20  Loss  of  suction  dunng  pumping  may  be  caused  by  leaky 
suction  line,  ineffective  water  or  grease  seal 

21  Belts  slipping 

22  Worn  wearing  ring 

SYMPTOM  C  —  HIGH  POWER  REQUIREMENTS 
CAUSES' 
1   Speed  of  rotation  too  high 

2.  Operating  heads  lower  than  rating  for  which  pump  was 
designed,  resulting  in  excess  pumping  rates 

3.  Sheaves  on  belt  drive  misaligned  or  maladjusted 

4.  Pump  shaft  bent 

5  Rotating  elements  binding 

6.  Packing  too  tight 

7.  Wearing  rings  worn  or  binding 

8.  Impeller  rubbing 

SYMPTOM  D  —  NOISY  PUMP 
CAUSES 

1  Pump  not  completely  primed 

2  Inlet  clogged 

3.  Inlet  not  submerged 

4  Pump  not  lubricated  properly 

5.  Worn  impellers 

6.  Strain  on  pumps  caused  by  unsupported  piping  fast- 
ened to  the  pump 

7  Foundation  insecure 

8.  Mechanical  defects  in  pump 

9  Misalignment  of  motor  and  pump  where  connected  by 
flexible  shaft 

10  Rocks  in  the  impeller 

1 1  Cavitation 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  325. 

18  24C  What  Items  would  you  check  if  a  pump  will  not 
start'' 

18.24D  How  would  you  attempt  to  increase  the  discharge 
from  a  pump  if  the  flow  rate  is  lower  than  expected? 

304 


284  Water  Treatment 


18.245  Starting  and  Stepping  Pumps 

The  operator  must  determine  what  treatment  processes 
will  be  effected  by  either  starting  or  stopping  a  pump.  The 
pump  discharge  point  must  be  known  and  vaVes  either 
opened  or  closed  to  direct  flows  as  desired  by  the  operator 
when  a  pump  is  started  or  stopped 

1 8  2450  Centrifugal  Pumps.  Basic  rules  for  the  operation 
of  centrifugal  pumps  Include  the  following  items 

1.  Do  not  operate  the  pump  when  safety  guards  are  not 
installed  over  or  around  moving  parts. 

2.  Do  not  start  a  pump  that  has  been  locked  or  tagged  out 
for  maintenance  or  repairs 

3.  Never  run  a  centnfugal  pump  when  the  impeller  is  dry. 
Always  be  sure  the  pump  is  primed. 

4.  Never  attempt  to  start  a  centnfugal  pump  whose  impeller 
or  shaft  is  spinning  backwards. 

5.  Do  not  operate  a  centnfugal  pump  that  is  vibrating 
excessively  after  startup.  Shut  unit  down  and  isolate 
pump  from  system  by  closing  the  pump  suction  and 
discharge  valves  Look  for  a  blockage  in  the  suction  line 
and  the  pump  impeller 

There  are  several  situations  in  whiuh  It  may  be  necc-ssary 
to  start  a  CENTRIFUGAL  pump  against  a  CLOSED  dis- 
charge valve.  Once  the  pump  Is  primed,  running  and  indicat- 
ing a  discharge  pressure,  slowly  open  the  pump  discharge 
valve  until  the  pump  is  fully  on  line.  This  procedure  is  used 
With  treatment  processes  or  piping  systems  with  vacuums 
or  pressures  that  cannot  be  dropped  or  allowed  to  fluctuate 
greatly  while  an  alternate  pump  is  put  on  the  line. 

Most  centrifugal  pumps  used  in  water  treatment  piei-its  are 
designed  so  that  they  can  be  easily  started  even  if  they 
haven't  been  primed.  This  is  accomplished  with  a  positive 
static  suction  head  or  a  low  suction  lift.  On  most  of  t.iese 
arrangements,  the  pump  will  not  require  priming  as  long  as 
the  pump  and  the  piping  system  do  not  leak.  Leaks  would 
allow  the  water  to  drain  out  of  the  pump  volute.  When  pumps 
in  water  systems  lose  their  prime,  the  cause  is  often  a  faulty 
check  valve  on  the  pump  discharge  line.  When  the  pump 
stops,  the  discharge  check  valve  will  not  seal  (close)  proper- 
ly. Water  previously  pumped  then  flows  back  through  the 
check  valve  and  through  the  pump.  1  he  pump  is  drained  and 
has  lost  its  prime. 

About  ninety-five  perciint  of  the  time,  the  centnfugal 
pumps  In  v.dter  treatment  plants  are  ready  to  operate  with 
suction  and  discharge  valves  open  and  seal  water  turned  on. 
When  the  automatic  start  or  stop  comma  ;d  is  received  by 
the  pump  from  the  controller,  the  pump  is  ready  to  respond 
properly. 

When  the  pumping  equipment  must  be  serviced,  take  it  off 
the  line  by  locking  and  tagging  out  the  pump  controls  until  all 
service  work  Is  completed. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  325. 

1 8.24E  Why  should  a  pump  that  has  been  locked  or  tagged 
out  for  nriaintenance  or  repairs  not  be  started? 

1 8  24F  Under  what  conditions  might  a  centrifugal  pump  be 
started  against  a  closed  discharge  valve? 

STOPPING  PROCEDURES 

This  >ection  contains  a  typical  sequence  of  procedures  to 
follow  to  stop  a  centrifugal  pump.  Exact  stopping  proce- 
dures for  any  pumping  system  depend  upon  the  condition  of 
the  discharge  system.  The  sudden  stoppage  of  a  pump 
could  cause  severe  WATER  HAMMER^^  problems  in  the 
piping  system. 

1  Inspect  process  system  affected  by  pump,  start  alternate 
pump  if  required,  and  notify  supervisor  or  log  action. 

2  Before  stopping  and  operating  pump,  check  its  oper- 
ation. This  will  give  an  indication  of  any  developing 
problems,  required  adjustments,  or  problem  conditions  of 
the  unit.  This  procedure  only  requires  a  few  minutes 
Items  to  be  inspected  include: 

a  Pump  packing  gland. 

1)  Seal  water  pressure 

2)  Seal  leakage  (too  much,  sufficient  or  too  little 
leakage) 

3)  Seal  leakage  dram  flowing  clear 

4)  Mechanical  seal  leakage  (if  equipped) 
b-  Pump  operating  pressures. 

1)  Pump  suction  (Pressure  Vacuum) 

A  higher  vacuum  than  normal  may  indicate  a  partial- 
ly plugged  or  restncted  suction  line.  A  lower  vacu- 
um may  indicate  a  higher  suction  water  level  or  a 
worn  pump  impeller  or  wearing  rings. 


Water  Hammer  The  ^nund  ,tke  someone  hammering  on  a  pipe  that  occurs  when  a  valve  is  opened  or  closed  very  rapidly.  When  a 
valve  position  is  changed  quickly,  the  wati..  pressure  in  a  pipe  will  increase  and  decrease  back  and  forth  very  quickly.  This  rise  and  fall 
in  pressures  can  do  serious  damage  to  the  system. 


Maintenance  285 


2)  Pump  discharge  pressure 

System  pressure  Is  indicated  by  the  pump  dis- 
charge pressure.  Lower  than  normal  discharge 
pressures  can  be  caused  by: 

a)  Worn  impeller  or  wearing  rings  in  the  pump; 

b)  A  different  point  of  discharge  can  change  dis- 
charge pressure  conditions; 

c)  A  broken  discharge  pipe  can  change  the  dis- 
charge head. 

NOTE.  To  determine  the  maximum  head  a  centrifugal  pump 
can  c^'^velop,  slowly  close  the  discharge  valve  at  the 
pump.  Read  the  pressure  gage  between  the  pump 
ana  the  discharge  valve  when  the  valve  is  fully 
closed.  This  is  the  maximum  pressure  the  pump  is 
capable  of  developing.  Do  not  operate  the  pump 
longer  than  a  few  minutes  with  the  discharge  valve 
closed  completely  because  the  energy  from  the 
pump  is  converted  ;o  heat  and  water  in  the  pump  can 
become  hot  enough  to  damage  the  pump. 


c.  Motor  temperature  and  pump  bearing  temperature. 

If  motor  or  bearings  are  too  hot  to  touch,  further 
checking  is  necessary  to  determine  if  a  problem  has 
developed  or  if  the  temperature  is  normal.  High  tem- 
peratures may  be  measured  with  a  thermometer. 

d  Unusual  noises,  viDrations,  or  conditions  about  the 
equipment. 

If  any  of  the  above  items  indicate  a  change  from  the 
pump*s  previous  operating  condition,  additional  ser- 
vice or  maintenance  may  be  required  during  shut- 
down. 

3.  Actuate  stop  switch  for  pump  motor  and  lock  out  switch. 
If  possible  use  switch  next  to  equipment  so  that  you  may 
observe  the  equipment  stop.  Observe  the  following  items: 

a.  Check  valve  closes  and  seats. 

Valve  should  not  slam  shut,  or  discharge  piping  will 
jump  or  move  in  their  supports.  There  should  not  be 
any  leakage  around  the  check  valve  shaft.  If  check 
valve  is  operated  automatically,  it  should  close 
smoothly  and  firmly  to  the  fully  closed  position. 

ERIC 


NOTE  If  the  pump  is  not  equipped  with  a  check  valve, 
close  discharge  valve  before  stopping  pump. 

b  Motor  and  pump  should  wind  down  slowly  and  not 
make  sudden  stops  or  noises  during  shutdown. 

c  After  equipment  has  completely  stopped,  pump  shaft 
and  motor  should  not  start  back-spinning.  If  back- 
spinning  IS  observed  in  a  pump  with  a  check  valve  or 
foot  valve,  close  the  pump  discharge  valve  SLOWLY' 
Be  extra  careful  if  the.^  is  a  plug  valve  on  a  line  with  a 
high  head  because  when  the  discharge  valve  is  part 
way  closed,  the  plug  valve  could  slam  closed  and 
damage  the  pump  or  piping. 

4.  Go  to  power  control  panel  containing  the  pump  motor 
starters  just  shut  down  and  OPEN  motor  breaker  switch, 
lock  O'jt,  and  tag. 

5.  Retum  to  pump  and  close: 
a.  Discharge  valve, 

b  Suction  valve, 

c.  Seal  water  supply  valve,  and 

d  Pump  volute  bleed  line  (if  so  equipped). 

6.  If  required,  close  and  open  appropnate  valves  along 
piping  system  through  which  pump  was  discharging. 

Starting  Procedures 

This  section  contains  a  typical  sequence  of  procedures  to 
follow  to  start  a  centrifugal  pump. 

1  Check  motor  control  panel  for  lock  and  tags.  Examine 
tags  to  be  sure  that  NO  item  is  preventing  startup  of 
equipment. 

2.  Inspect  equipment 

a.  Be  sure  stop  switch  is  locked  out  at  equipment  loca- 
tion. 

b.  Guards  over  moving  parts  must  be  in  place. 

c.  Clean-out  on  pump  volute  and  dram  plugs  shoulc*  '^e 
installed  and  secure. 

d.  Valves  should  be  in  closed  position. 

e.  Pump  shaft  must  rotate  freely. 

f  Pump  motor  should  be  clean  and  air  vents  clear. 

g  Pump,  motor,  and  auxiliary  equipment  lubncant  level 
must  be  at  proper  elevations. 

h.  Determine  if  any  special  considerations  or  precautions 
are  to  be  taken  dunng  startup. 

3.  Follow  pump  discharge  piping  route.  Be  sure  all  valves 
are  in  the  proper  position  and  that  the  pump  flow  will 
discharge  where  intended. 

4.  Retum  to  motor  control  panel. 

a.  Remove  tag. 

b.  Remove  padlock. 

c.  Close  motor  main  breaker. 

d.  Place  selector  switch  to  manual  (if  you  have  automatic 
equipment). 

3'Ju 


286  Water  Treatment 


5.  Return  to  pump  equipment 

a.  Open  seal  water  supply  line  to  packing  gland.  Be  sure 
seal  water  supply  pressure  is  adequate 

b.  Open  pump  suction  valve  slowly. 

c  Bleed  air  out  of  top  of  pump  volute  in  order  to  pnme 
pump  Some  pumps  are  equipped  with  air  relief  valves 
or  bleed  lines  back  to  the  we!  well  for  this  purpose. 

d.  When  pump  is  primed,  slowly  open  pump  discharge 
valve  and  recheck  prime  of  pum.p  Be  su^'e  no  air  is 
escaping  from  volute. 

e.  Unlock  stop  switch  and  actuate  start  switch.  Pump 
should  start 

6.  Inspect  equipment. 

a.  Motor  should  come  up  to  speed  promptly.  If  ammeter 
IS  available,  test  for  excessive  draw  of  power  (amps) 
dunng  startup  and  normal  operation.  Most  Ihree- 
phase  induction  motors  used  in  water  treatment  plants 
will  draw  5  to  7  times  their  normal  running  current 
during  the  brief  penod  when  they  are  coming  up  to 
soeed. 

b  No  unusal  noise  or  vibrations  should  be  observed 
dunng  startup 

c.  Check  valve  should  be  open  and  no  chatter  or  pulsa- 
tion should  be  observed. 

d.  Pump  suction  and  discharge  pressure  readings  should 
be  within  normal  operating  range  for  this  pump. 

e  Packing  gland  leakage  should  be  normal. 

f.  If  a  fiow  meter  is  on  the  pump  discharge,  record  pump 
output 

7  If  the  unit  IS  operating  properly,  return  to  the  motor 
control  panel  and  place  the  motor  mode  of  operation 
selector  tn  the  prope'  operating  position  (manual-auto- 
off). 

8.  The  pump  and  auxiliary  equipment  should  be  inspected 
routinely  after  the  pump  has  been  placed  back  into 
service. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  325. 

18,24G  What  should  be  done  before  stopping  an  operating 
pump? 

18.24H  What  could  cause  a  pump  shaft  or  motor  to  spin 
backwards? 

18.241    Why  should  the  position  (open  or  closed)  of  all 
valves  be  checked  before  starting  a  pump*? 

18.2451  Positive  Displacement  Pumps.  Steps  for  starting 
and  stopping  positive  displacement  pumps  are  outlined  m 
this  section.  There  are  two  basic  differences  in  the  operation 
of  positive  displacement  pumps  as  compared  with  centrifu- 
gal pumps.  Centrifugal  pumps  (due  to  their  design)  will 
permit  an  operator  error,  jut  a  positive  displacement  pump 
will  not  and  someone  will  have  to  pay  for  correcting  the 
damages. 

ERIC 


Important  rules  for  operating  ucsitive  displacement 
pumps  include 


VAUVg,g4PeglAtLVAC7l4CUAg6gyAl\/e. 


'i  Excessive  pressure  could  rupture  the  equipment  and 
possibly  seriously  injure  or  kill  someone  ne?r*by. 

2  Positive  displacement  pumps  are  used  to  pump  solids 
(sludge)  and  meter  chemicals.  Certain  precautions  must 
be  taken  to  prevent  .njury  or  damage.  If  the  valves  on 
both  ends  of  a  sludge  line  are  closed  tightly,  the  I'ne 
becomes  a  closed  vessel  Gas  from  decomposition  of  the 
sludge  can  build  up  and  rupture  pipes  or  valves. 

3.  Positive  displacement  pumps  also  are  used  to  meter  and 
pump  chemicals,  oare  must  be  exercised  to  avoid  venting 
chemicals  to  the  atmosphere. 

4.  Never  operate  a  positive  displacempnt  pump  when  it  is 
dry  or  empty,  especially  the  progressive-cavity  types  that 
use  rubber  stators.  A  small  amount  of  liquid  is  needed  for 
lubncation  in  the  pump  cavity  between  the  rotor  and  the 
stator. 


In  addition  to  NEVER  closin/  a  discharge  valve  on  an 
operating  positive  displacement^pump,  the  only  other  differ- 
ence (when  compared  with  a  centrifugal  pump)  may  be  that 
the  positive  dibplacement  pump  system  may  or  may  not 
have  a  check  valve  m  the  discharge  piping  after  the  pump 
Installation  of  a  check  valve  depends  upon  the  designer  and 
the  material  being  pumped. 

Other  than  the  specific  differences  mentioned  in  this 
section,  the  starting  and  stopping  procedures  for  positive 
displacement  pumps  are  similar  to  the  procedures  for  centn- 
fugat  pumps. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  326. 

18  24J  What  IS  the  most  important  rule  regarding  the 
operation  of  positive  displacement  pumps? 

18  24K  What  could  happen  if  a  positive  displacement  pump 
IS  started  against  a  closed  discharge  valve? 

18  24L  Why  should  both  ends  of  a  sludge  line  never  be 
closed  tighf? 


Please  answer  the  discussion  and  review  questions  be- 
fore continuing  with  Lesson  4. 


311/ 


Maintenance  287 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  18.  MAINTENANCE 

(Lesson  3  of  5  Lessons) 


Write  your  answers  to  these  questions  in  your  notebook 
before  continuing.  The  question  numbering  continues  from 
Lesson  2 

1 8  When  two  or  more  pumps  of  the  same  size  are  installed, 
why  should  they  be  ojierated  alternately'? 

19  vv^.!?t  should  be  checked  if  pump  bearings  are  running 
hof? 

20.  What  happens  when  the  packing  is  too  tight  on  a 
reciprocating  pump'? 

21   Why  should  adjustments  in  control  valves  for  recipro- 
cating pumps  be  made  when  the  pump  is  shut  down'? 

22.  Why  would  you  use  a  stethoscope  to  check  an  electric 
motor'? 

23.  How  would  you  determine  if  a  motor  is  running  unusual- 
ly hof? 

24  How  would  you  clean  belts  on  a  belt  drive? 

25.  Why  should  you  never  replace  only  one  bt  '  on  a 
multiple-dnve  unif? 

26.  What  do  rubber  wearings  near  a  belt  drive  indicate'? 

27.  How  can  you  dete^'mme  if  a  chain  in  a  chain-drive  unit 
has  the  proper  slack'? 

28.  What  happens  when  couplings  are  not  in  proper  align- 
ment? 


29  How  can  you  determine  if  a  new  pump  will  turn  in  the 
direction  intended'? 

30.  When  shutting  down  a  pump  for  a  long  pe..od,  what 
precautions  should  be  taken  with  the  motor  disconnect 
switch'? 

31  How  can  you  determine  if  a  new  pump  is  delivering 
design  flows  and  pressures'? 


CHAPTER  18.  MAINTENANCE 

(Lesson  4  of  5  Lessons) 


18.25  Compressors 

Compressors  (Fig  18.31)  are  commonly  used  in  the 
operation  and  maintenance  of  water  treatment  plants  They 
are  used  to  activate  and  control  pump  control  systems 
(bubblers),  valve  operators,  and  water  pressure  systems 
They  are  also  used  to  operate  portable  pneumatic  tools, 
such  as  jack  hammers,  compactors,  air  drills,  sand  blasters, 
tapping  machines,  and  air  pumps. 

A  compressor  is  a  device  used  to  increase  the  pressure  cf 
air  or  gas.  They  can  be  of  a  very  simple  diaphragm  or 
bellows  type  such  as  are  found  in  aquanum  pumps,  or 
extremely  complex  rotary,  piston,  or  sliding  vane  type  com- 
pressors. A  compressor  usually  has  a  suction  pipe  with  a 
filter  and  a  discharge  pipe  which  goes  tq  an  air  receiver  or 
storage  tank.  The  compressed  air  or  gas  \  then  used  from 
the  air  receiver. 


ERIC 


Due  to  the  complexity  of  compressors,  the  water  treat- 
ment plant  operator  usually  will  not  be  repairing  them.  You 
will,  however,  be  required  to  maintain  these  compressors. 
With  proper  maintenance  a  compressor  should  give  years  of 
trouble-free  service. 

The  first  step  for  compressor  maintenance,  and  this 
pertains  to  any  mechanical  equipment,  is  to  get  the  manu- 
facturer's istruction  book  and  read  it  completely.  Each 
compressor  is  different  and  the  particular  manufacturer  will 
provide  its  recommended  maintenance  schedules  and  pro- 
cedures. Some  of  the  maintenance  procedures  are  dis- 
cussed in  the  following  paragraphs. 

1.  Inspect  the  suction  filter  of  the  compressor  regularly. 
The  frequency  of  cleaning  depends  upon  the  use  of  the 
compressor  and  the  atmosphere  around  it.  Under  nor- 
mal operations  the  filter  should  be  inspected  at  least 


30 


'JC3 


288  Water  Treatment 


Fig.  18.31   Two-stage  piston  compressor 

(Courtesy  Worthington  Corporation) 


monthly  and  cleaned  or  replaced  every  three  to  six 
months  Inspect  and  replace  the  filter  more  frequently  in 
areas  with  excavation  and  dust.  When  breaking  up 
concrete,  inspect  the  filters  daily. 


There  are  several  types  of  filters,  such  as  paper,  cloth, 
vyire  screen,  oil  bath,  and  others.  The  impregnated 
paper  filters  must  be  replaced  when  dirty.  The  cloth- 
type  filters  can  be  washed  with  soap  and  water,  dried 
and  reinstalled.  If  a  cloth-type  filter  Is  used,  it  is  recom- 
mended that  a  spare  be  kept  so  one  can  be  cleaned 
while  the  other  is  being  used.  The  wire  mesh  and  oil- 
bath  type  filters  can  be  cleaned  with  a  standard  solvent, 
reoiled  or  oil  bath  filled  and  used  again.  Never  operate  a 
compressor  without  the  suction  filter  because  dirt  and 
foreign  materials  will  collect  on  the  rotors,  pistons,  or 
blades  and  cause  excessive  wear. 

2.  Lubrication.  Improper  or  lack  of  lubrication  is  probably 
the  biggest  cause  of  compressor  failures.  Most  com- 
pressors require  oiling  of  the  bearings.  They  can  have 
crank  case  reservoirs,  oil  cups,  grease  fittings,  a  pres- 
sure systeni  or  separate  pump  Whatever  type.  It  must 
be  Inspected  daily.  Examine  the  reservoir  dip  stick  or 
sight  glass.  Make  sure  that  dnp-feed  oilers  are  dripping 
at  the  proper  rate,  force  fred  oilers  have  the  proper 

O 

ERLC 


pressure,  and  grease  fittings  are  greased  at  the  proper 
interval.  Compressors  use  a  certain  amount  of  oil  in 
their  operation  and  special  attention  is  needed  to  keep 
the  reservoirs  full.  Care  also  must  be  used  to  not  overfill 
the  crankcase.  On  some  compressors  it  is  possible  for 
the  oil  to  get  into  the  compression  side  and  lock  up  the 
compressor,  or  damage  It.  Remember! 

A  UiaUlP  CANNOT  SB  COIAPQt^^SV. 

When  air  or  gas  are  compressed,  they  give  off  heat  and 
the  compressor  becomes  very  hot.  This  tends  to  break 
down  oil  faster,  so  most  compressor  manufacturers 
have  special  oils  recommended  for  their  particular  com- 
pressor. Also,  due  to  the  heat  and  contamination,  it  is 
necessary  to  change  oil  quite  frequently.  Compressor 
oil  should  be  changed  at  least  every  three  months, 
unless  manufacturer  states  differently.  If  there  are  filters 
m  the  oil  system,  these  also  should  be  changed. 

3.  Cylinder  or  casing  fins  should  be  cleaned  weekly  with 
compressed  air  or  vacuumed  off.  The  fins  must  be  clean 
to  insure  proper  cooling  of  the  compressor. 

4.  Unloader.  Many  compressors  have  unloaders  that  allow 
the  compressor  to  start  under  a  no-load  condition. 
These  can  be  inspected  by  observing  the  compressor. 
When  the  compressor  starts,  it  should  come  up  to 
speed  and  the  unloader  will  change,  starting  the  com- 
pression cycle.  This  can  usually  be  heard  by  a  change  in 
sound.  When  it  stops,  you  can  hear  a  small  pop  and 
hear  the  air  bleed  off  the  cylinders.  If  the  unloader  is  not 
working  properly,  the  compressor  will  stall  when  start- 
ing, not  start,  or  if  belt-driven,  burn  off  the  belts. 


Maintenance  289 


5  Test  the  safety  valves  weekly  The  pop  off  or  safety 
valves  are  located  on  the  air  receiver  or  storage  tank. 
They  prevent  the  pressu^'e  from  building  up  above  a 
specified  pressure  by  opening  and  venting  to  thp  atmos- 
phere, in  gas  compressors,  they  vent  to  the  suction  side 
of  the  compressor.  Some  compressors  have  high  pres- 
sure cut-off  switches,  low  oil  pressure  switches,  and 
high  temperature  cut-off  switches.  These  switches  have 
pre-set  cut-off  settings  and  must  not  be  changed  with- 
out proper  authorization  If  for  any  reason  any  of  the 
safety  switches  are  not  functioning  properly,  the  prob- 
lem must  be  corrected  before  starting  the  compressor 
again  The  safety  switch  settings  should  be  recorded 
and  the  results  kept  ir  the  equipment  file 

6.  Dram  the  condensate  (condensed  water)  from  the  air 
receiver  daily.  Due  to  temperature  changes,  the  air 
receiver  will  fill  with  condensate.  Each  day  the  conden- 
sate should  be  drained  from  the  bottom  of  the  tank 
There  is  usually  a  small  valve  at  the  bottom  of  the  air 
receiver  for  this  purpose.  Some  air  receivers  are 
equipped  with  automatic  dram  valves  These  must  be 
inspected  periodically  to  insure  they  are  operating  satis- 
factorily 

7  Inspect  belt  tension  on  compressors  Usually  you 
should  be  able  to  press  the  belt  down  with  hand 
pressure  approximately  three-fourths  of  an  inch.  This  is 
done  at  the  center  between  the  two  pulleys  MAKE 
SURE  COMPRESSOR  IS  LUCKED  OFF  BEFORE  MAK- 
ING THIS  TEST.  Do  not  over-tighten  belts  because  it  will 
cause  overheating  and  excessive  wear  on  bearings  and 
motor  Overloading 

8  Examine  operating  controls  Make  sure  the  compressor 
IS  starting  and  stopping  at  the  proper  settings  If  it  is  a 
dual  installation,  make  sure  they  are  alternating  if  so 
designed,  inspect  gage  for  accuracy  Compare  readings 
with  recorded  startup  values  or  other  known,  accurate 
readings 

9.  Many  portable  compressors  are  equipped  with  tool 
oilers  on  the  receivers.  These  are  used  for  mixing  a 
small  quantity  of  oil  with  the  compressed  air  for  lubrica- 
tion of  the  tools  being  used  These  are  located  on  the 
discharge  side  of  the  air  receiver.  They  have  a  reservoir 
which  must  be  filled  with  rock  drill  oil. 

10  All  compressors  should  be  thoroughly  cleaned  at  least 
monthly  Dirt,  oil,  grease,  and  other  material  must  be 
thoroughly  cleaned  off  the  compressor  and  surrounding 
area  Compressors  have  a  tendency  to  lose  oil  around 
piping,  fittings  and  shafts;  thus  constant  cleaning  is 
required  by  the  maintenance  operator  to  insure  proper 
and  safe  operation. 

QUESTIONS 

Write  your  answers  m  a  notebook  and  then  compare  your 
answers  with  those  on  page  326. 

18  25A  List  some  of  the  uses  of  a  compressor  in  connec- 
tion with  operation  and  maintenance  of  a  water 
treatment  plant. 

1 8.25B  How  often  should  the  suction  filter  of  a  compressor 
be  cleaned'' 

18.26C  How  often  should  compressor  oil  be  changed*? 


18  25D  How  often  should  the  condensate  from  the  air 
receiver  be  drained*? 

18  25E  What  must  be  done  before  testmg  belt  tension  on 
compressors  with  your  hands'? 

18.26  Valves^^ 

18.260  use  of  Valves 

Valves  are  the  controlling  devices  placed  m  piping  sys- 
tems to  stop,  regu'ate,  ^.^teck,  divert,  or  otherv^ise  modify  the 
flow  of  liquids  or  gases  There  are  specific  valves  that  are 
more  suitable  for  certain  ;obs  than  others.  The  five  most 
common  valves  that  you  will  find  m  a  water  treatment  facility 
are  discussed  in  this  section 

18.261  Gate  Valves  (Figures  18.32  and  18  33) 

The  basic  parts  of  a  gate  valve  are-  the  operator  (handle), 
the  shaft  packing  assembly,  the  bonnet,  the  valve  body  with 
seats,  the  stem,  and  the  disc  Gate  valves  cor.^e  a  large 
number  of  sizes,  but  the  principle  of  operation  is  quite 
similar  for  all  sizes.  One  could  associate  the  action  of  a  gate 
valve  to  that  of  a  guillotine  having  a  screw  shaft  instead  of 
the  rope  The  valve  disc  is  raised  or  lowered  by  a  threaded 
shaft  and  is  guided  on  each  side  to  ensure  that  it  will  not 
hang  up  m  the  operation.  The  disc  is  screwed  down  until  it 
wedges  itself  between  two  machined  valve  seats  This 
makes  a  leak-proof  seat  on  both  sides  of  the  disc  The  discs 
are  replaceable  Some  gate  valves  have  discs  with  wedges 
inside  As  more  force  is  applied  to  the  screwed  stem,  the 
wedges  force  the  discs  into  tighter  contact  with  the  valve 
seats 

Gate  valves  are  either  of  the  rising  (Figure  18  32)  or  non- 
rismg  stem  (Figure  1 8.33)  type  The  rising  stem  has  compan- 
ion threads  m  the  valve  bonnet.  As  the  valve  is  opened,  the 
stem  IS  threaded  out,  lifting  the  wedged  disc  In  the  non- 
rising  type,  the  stem  is  held  in  place  in  the  bonnet  by  a  collar. 
The  stem  is  threaded  with  companion  threads  in  the  wedged 
disc  As  the  valve  opens,  the  disc  rises  on  the  stem 
Consequently,  the  hand  wheel  stays  on  the  same  plane. 

Gate  valves  are  not  commonly  used  to  control  flows  With 
the  valve  partially  open,  the  water  velocity  is  increased 
through  the  valve  and  minute  particles  transported  in  the 
water  can  cause  undue  seat  wear.  However,  the  vee-ported 
gate  valve  can  be  used  m  controlling  flows.  As  the  valve  is 
opened,  the  vee  is  widened  to  allow  more  flow  Because  of 
the  valve  design,  little  damage  is  done  to  the  valve  seats  m 
the  vee-ported  type  of  gate  valve. 

Suggested  operation  and  maintenance  procedures  are 
listed  below 

1  Open  valve  fully.  When  at  stop,  reverse  and  close  valve 
one-half  turn. 

2  Operate  all  large  valves  at  least  yearly  to  insure  proper 
operation 

3.  Inspect  valve  stem  packing  for  leaks  Tighten  as  needed 

4.  If  the  valve  has  a  rising  stem,  keep  stem  threads  clean 
and  lubricated 

5.  Close  valves  slowly  in  pressure  lines  to  prevent  water 
hammer 


17  For  additional  information  on  valves,  see  WATER  DISTRIBUTION  SYSTEM  OPERATION  AND  MAINTENANCE,  Chapter  3,  Distribution 
System  Facilities,  Section  3.670,  "Valves,''  in  this  series  of  manuals. 


310 


290   Water  Treatment 


Ftg.  18.32  Rising  stem  gate  valve 

(Permission  of  Stockham  Valves  &  Frttings.  Copyright.  1976) 


Fig.  18.33  Non-nsing  stem  gate  valve 

(Permission  of  Stockham  Valves  &  Fittmgs.  Copyright.  1976) 

ERIC  311 


Maintenance  291 


6.  If  a  valve  wiH  not  close  by  using  the  normal  operator, 
check  for  the  cause.  Using  a  "cheater"  (bar-pipe  wrench) 
Will  only  aggravate  your  problem. 

18.262  Maintenance  of  Gate  Valves 

Paragraph  12:  Gate  Valves 

The  most  common  maintenance  required  by  gate  valves  is 
Oiling,  tightening,  or  replacing  the  stem  stuffing  box  packing. 

Frequency 
of 
Service 


A  1.  REPLACE  PACKING.  Modern  gate  valves 
can  be  repacked  without  removing  tnem 
from  service.  Before  repacking,  open  valve 
wide.  This  prevents  excessive  leakage 
when  the  packing  or  the  entire  stuffing  box 
IS  removed.  It  draws  the  stem  collar  tightly 
against  the  bonnet  on  a  non-rising  stem 
valve,  and  tightly  against  the  bonnet  bush- 
ing on  a  rising  stem  valve. 

a.  Stuffing  box.  Remove  all  oij  packing 
from  stuffing  box  with  a  packing  hook  or 
a  rattail  fih  with  bent  end.  Clean  valve 
stem  of  all  adhering  particles  and  polish  it 
with  fine  emery  cloth.  After  polishing  re- 
move the  fine  gnt  with  a  clean  cloth  to 
which  a  few  drops  of  oil  have  been 
added. 

b.  Insert  packing  Insert  new  split-ring  pack- 
ing in  stuffing  box  and  tamo  it  into  place 
with  packing  gland.  Stagger  ring  splits. 
After  stuffing  box  is  filled,  place  a  few 
drops  of  oil  on  stem,  assemble  gland, 
and  tighten  it  down  on  packing 

S  2  OPERATE  VALVE.  Operate  inactive  gate 
valves  to  prevent  sticking. 

A  3  LUBRICATE  GEARING.  Lubricate  gate 
valves  as  recommended  by  manufacturer. 
Lubricate  thoroughly  any  gearing  in  large 
gate  valves.  Wash  open  gears  with  solvent 
and  lubricate  with  grease. 

S         4  LUBRICATE  RISING-STEM  THREADS. 

Clean  threads  on  rising-slem  gate  valves 
and  lubncate  with  grease 

A  5  LUBRICATE  BURIED  VALVES.  If  a  buried 
valve  works  hard,  lubricate  it  by  pouring  oil 
down  through  a  pipe  which  is  bent  at  the 
end  to  permit  oiling  the  packing  follower 
below  the  N/alve  nut 

A  6  REFACE  LEAKY  GATE  VALVE  SEATS  If 
gate  valve  seats  leak,  reface  them  immedi- 
ately, using  the  method  discussed  below.  A 
solid  wedge  disc  valve  is  used  for  illustra- 
tion, but  the  general  method  also  applies  to 
other  types  of  reparable  gate  valves.  Pro- 
ceed as  follows: 

a  Remove  bonnet  and  clean  and  examine 
disc  and  body  thoroughly.  Carefully  de- 
termine extent  of  damage  to  body  rings 

18  Prussian  Blue.  A  blue  paste  or  hqwd  (often  on  a  paper  like  carbon 
seats  fit  properly. 


and  disc  If  corrosion  has  caused  exces- 
sive pitting  or  eating  away  of  metal,  as  in 
guide  ribs  in  body,  repairs  may  be  im- 
practical. 

b  Check  and  service  all  parts  of  valve  com- 
pletely. Remove  stem  from  bonnet  and 
examine  it  for  sconng  and  pitting  where 
packing  makes  contact.  Polish  lightly 
with  fine  emery  cloth  to  put  stem  in  good 
condition.  Use  soft  jaws  if  stem  is  put  in 
vise 

c.  Remove  all  old  packing  and  clean  out 
stuffing  box  Clean  ail  dirt,  scale,  and 
corrosion  from  inside  of  valve  bonnet 
and  other  parts. 

d  Do  not  salvage  an  old  gasket.  Remove  it 
completely  and  replace  with  one  of  prop- 
er quality  and  size. 

e.  After  cleaning  and  examining  all  parts, 
determine  .nether  valve  can  be  repaired 
by  ren^oving  cuts  from  disc  and  body 
seat  faces  or  by  replacement  of  body 
S'iats.  If  repair  can  be  made,  set  disc  in 
vise  with  face  leveled,  wrap  fine  emery 
cloth  around  a  flat  tool,  and  rub  or  lap  off 
entire  bearing  suriace  on  both  sides  to  a 
smooth,  even  finish.  Remove  as  little 
metal  as  possible. 

f  Repair  cuts  and  scratches  on  body  rings, 
lapping  with  an  emery  block  small 
enough  to  permit  convenient  rubbing  all 
around  rings.  Work  carefully  to  avoid 
removing  so  much  metal  that  disc  will 
seat  too  low.  When  seating  surfaces  of 
disc  and  seat  rings  are  properly  lapped 
in,  coat  faces  of  disc  with  PRUSSIAN 
BLUE^^  and  drop  disc  in  body  to  check 
contact.  Wlien  good,  continuous  contact 
IS  obtained,  the  valve  is  tight  and  ready 
for  assembly.  Insert  stem  in  bonnet,  in- 
stall new  packing,  assemble  other  parts, 
attach  disc  to  stem,  and  place  assembly 
in  body  Raise  stem  to  prevent  contact 
with  seats  so  bonnet  can  be  properly 
seated  on  body  before  tightening  the 
joint. 

g.  Test  repaired  valve  before  putting  it  back 
in  line  to  ensure  that  repairs  have  been 
properly  made. 

h.  If  leaky  gate  valve  seats  cannot  be  re- 
faced,  remove  and  replace  seat  rings 
with  a  power  lathe  Chuck  up  body  with 
rings  vertical  to  lathe  and  use  a  strong 
steel  bar  across  ring  lugs  to  unscrew 
them.  They  can  be  removed  by  hand  with 
a  diamond  point  chisel  if  care  is  taken  to 
avoid  damaging  threads.  Dnve  new  rings 
home  tightly.  Use  a  wrench  on  a  steel  oar 
ac.oss  lugs  when  putting  in  rings  by 
hand.  ^Jways  coat  threads  with  a  good 
lubncant  before  putting  threads  into  the 
valve  body.  This  helps  to  make  the 

used  to  show  contact  area  Used  to  determine  if  gate  valve 


292  Water  Treatment 


Frequency 
of 
Service 


threads  easier  to  remove  the  next  time 
the  seats  have  to  be  replaced  Lap  in 
rings  to  fit  disc  perfectly. 

18.262   Globe  Valves  (Fig.  18.34) 

The  globe  valve  seating  configuration  is  quite  different 
from  the  gate  vatve  Globe  valves  use  a  circular  disc  to  maKe 
a  flat  surface  contact  with  a  ground-fitted  valve  seat.  This  is 
Similar  to  placing  your  thumb  over  the  end  of  a  tube.  The 
parts  of  the  valve  are  similar  m  name  and  function  to  the  gate 
valve.  They  can  be  of  the  rising  or  non-nsing  stem  type 

What  IS  unique  about  the  globe  valve  is  its  internal  design 
(Figure  18.34).  This  design  enables  the  valve  to  be  used  in  a 
controlling  mode  The  valve  seats  are  not  subject  to  exces- 
sive wear  when  partially  opened  like  the  gate  valve.  After 
extended  use.  the  valve  may  not  have  a  positive  shutoff  but 
It  will  still  be  effective  in  throttling  flows.  Procedures  for 
operating  and  maintaining  globe  valves  are  similar  to  the 
procedures  outlined  for  gate  valves  in  Section  18  262 

18.264  Eccentric  Valves  (Figs  18.35  and  18.36) 

The  eccentric  valve  has  many  desirable  features  These 
features  include  allowance  for  high  flow  capacity,  quarter 
turn  operation,  no  lubrication,  excellent  resistance  to  wear, 
and  good  throttling  characteristics.  The  eccentric  vaive  uses 
a  cam  shaped  plug  to  match  an  eccentric  valve  seat.  As  the 
valve  IS  closed,  the  plug  throttles  the  flow  yet  maintains  a 
smooth  flow  rate  The  plug  does  not  come  into  contact  with 
the  valve  seat  until  it  is  in  the  closed  position. 


Because  the  plug  has  a  resilient  coating,  it  insures  a  leak- 
tight  seal  at  the  valve  seats  The  Buna-N,  neoprene.  or  viton 
plug  coating  is  a  very  wear  resistant  compound  and  can 
function  well  under  a  wide  temperature  range.  This  valve  is 
excellent  for  controlling  the  flows  of  sfurnes  and  sludges 
found  in  water  treatment  facilities 

18.265  Butterfly  Valves  (Fig.  18.37) 

The  butterfly  valve  is  used  primarily  as  a  control  valve.  The 
flow  Characteristics  allow  the  water  to  move  in  straight  lines 
w'th  little  turbulence  in  the  area  of  the  valve  disc  (butterfly;. 
Complete  flow  shutoff  can  be  accomplished  but  the  PSI 
rating  is  relatively  low  in  comparison  to  eccentric  or  gate 
valves 

The  butterfly  valve  uses  a  machined  disc  that  can  be 
opened  to  90  degrees  to  allow  full  flow  through  the  valve. 
Quarter  turn  operation  moves  the  valve  from  the  closed'  to 
open'  position  The  disc  is  mounted  on  a  shaft  eccentric  that 
allows  the  disc  to  come  into  its  seat  with  minimum  seating 
torque  and  scuffing  of  the  rubber  seat  There  is  no  contact 
between  the  disc  and  the  seat  until  the  last  few  degrees  of 
valve  closure 

A  resilient  rubber  is  used  as  the  seat  and  is  of  a  continu- 
ous form  that  ic  not  interrupted  Dy  a  shaft  connection.  Wear 
resistance  characteristics  are  good  when  used  m  slurry  and 
sludge  applications. 

When  the  valve  is  closed,  the  disc  is  forced  against  the 
.jbber  seat  Wedges  with  jacking  screws  compress  the 
rubber  seat  via  a  jack  nng.  The  rubber  seat  then  w^nforms  to 
the  entire  disc  circumference.  The  rubber  can  be  readily 
replaced  when  necessary  without  complete  valve  disman- 
tling Large  valves  do  not  need  to  be  removed  from  the  line 
for  seat  repacement. 


IDENTIFICATION  PUTE 


DISC  lOCK  NUT 


Fig.  18.34  Globe  valve 

(Permission  of  Stockham  Valves  and  "ittings) 

ER?C  3IJ 


Maintenance  293 


ECCENTRIC  ACTION 

The  DeZurik  design  matches  a  single-faced 
eccentric  or  cam-shaped  plug  with  an  ec- 
centric raised  body  seat.  With  rotary 
motion  only,  the  plug  advances  against 
the  seat  as  It  closes.  Here's  how  It  works: 


OPEN— The  plug  Is  out  of  the  flow  path. 
There  Is  no  bonnet  or  other  cavity  to  fill 
with  slurry  material.  Flow  is  straight- 
through  with  minimum  pressure  drop. 


CLOSING— At  any  position  between  open 
and  closed,  the  eccentric  plug  still  has  not 
touched  the  seat.  There  Is  no  friction  to 
cause  wear  or  binding.  Flow  Is  still  smooth 
and  straight.  Throttling  action  Is  excellent 
on  all  types  of  services  from  slurries  to  gas. 


CLOSED— The  eccentric  plug  makes  con- 
tact with  the  eccentric  seat  only  in  the 
fully  closed  position.  Action  Is  easy,  with- 
out binding  or  scraping.  There  is  no  con- 
tinual seat  wear.  The  plug  Is  moved  firmly 
into  the  seat  to  provide  a  positive,  drip- 
tight,  long-lasting  seal. 


Fig,  18.35  How  eccentric  valves  work 

(Permission  of  DeZurik  Corporation.  Sartell.  Minnesota) 


ERIC 


31 'I 


294  Water  Treatment 


Maintenance  295 


Fig.  18  37  Butterfly  valve 

(Permi5S»on  ol  Amencan-Dfefling  Valvo.  Birmtngham.  Alabama) 


316 


296  Water  Treatment 


18.266  Check  Valves  (Fig.  18.38) 

The  term  check  valve'  describes  its  function.  A  check 
valve  allows  water  to  flow  in  one  direction  only.  If  the  water 
attempts  to  flow  in  the  opposite  direction,  an  internal  mecha- 
nism closes  the  valve  and  "checks"  the  flov^.  Three  types  of 
check  mechanisms  may  be  used  —  the  swing  check,  the 
water  check,  or  the  lift  check.  In  the  swing  check,  a  move? 
ble  disc  rests  at  a  right  angle  to  the  flow  and  seats  against  a 
ground  seat.  The  moveable  disc  is  called  the  clapper.  The 
clapper  can  be  one  of  three  types:  gravity  operated,  lever 
and  weight  operated,  or  lever  and  spnng  operated.  In  many 
installations  the  water  being  pumped  must  be  delivered  at  a 
desired  flow  rate  and  pressure.  A  clapper  with  an  external 
means  of  adjusting  the  opening  in  the  check  valve  may  be 
necessary  to  produce  desired  flows  and  pressures.  By 
positioning  the  weight  on  the  lever  or  adiusting  the  spring 
tension,  a  check  valve  can  be  made  to  operate  either 
partially  or  fully  open  at  vanous  pressures  and  flows.  The 
spring  or  counter  weight  also  ensures  that  the  check  valve 
closes  at  "no  flow."  This  is  very  helpful  if  the  valve  is  not  in  a 
position  that  will  enable  gravity  alone  to  operate  the  clapper 
The  gravity-operated  clapper  does  not  have  an  externa! 
adjustment  and  relies  on  the  weight  of  the  clapper  to  close 
the  valve  at '  no  flow"  conditions. 


Most  swing  check  valves  provide  for  full  opening,  that  is, 
the  clapper  can  move  up  into  the  bonnet  and  thus  be 
c  "oletely  out  of  the  flow.  Head  loss  in  swing  check  valves 
ma;,  je  relatively  high  and  this  factor  must  be  considered  in 
selecting  the  device  for  a  particular  application.  This  type  of 
check  valve  is  quite  common  in  pump  installations  and  often 


has  a  dampening  feature  to  cushion  the  clos-ng  of  the 
clapper. 

The  wafer  check  has  a  circular  disc  that  hinges  in  the 
center  (diameter)  of  the  disc  Water  passing  through  col- 
lapses the  disc  and  the  stoppage  of  flow  allows  the  disc  to 
return  to  its  circular  form  Because  the  valve  has  a  tendency 
to  be  fouled  up  by  stringy  material,  it  is  not  commonly  used 
in  handling  raw  water.  Wafer  check  valves  a''e  very  effective 
when  used  with  clean  water. 

The  lift  check  uses  a  vertical  lift  disc  or  ball.  When  there  is 
flow,  the  disc  or  ball  is  lifted  from  its  ground  seat  and  fluid 
passes  through  the  valve  As  flow  stops,  the  check  realigns 
itself  with  Its  seat  and  checks  or  prevents  water  backflow. 
The  moveable  portion  can  be  a  spring  or  gravity  return. 

The  foot  valves  used  in  pump  suctions  are  nearly  always 
of  the  vertical  lift  disc  design.  A  check  valve  of  this  type  is 
usually  applied  to  handle  clean  water. 

Backflow  prevention  by  check  valves  is  essential  in  many 
applications  to: 

1  Prevent  pumps  from  reversing  when  power  is  removed, 

2.  Protect  water  systems  from  being  cross-connected, 

3  Aid  in  pump  operation  as  a  dampener,  and 

4.  Ensure  "full  pipe"  operation  (pipe  is  full  of  water). 

Table  18.4  provides  a  comparison  of  vanous  types  of 
check  valves  with  features  of  these  valves.  Figures  18.39 
through  18.45  prov  drawings  and  photographs  of  the 
different  types  of  ch  ^k  valves  listed  in  Table  18.4. 


ERLC 


Tight  closing  assured 
since  clapper  arm  shaft 
is  set  slightly  back  of 
vertical  seat  face. 


Bronze  clapper  arm  shaft 
can  be  extended  through 
bod*/  when  lever  with 
weight  or  spring  i 
quired. 


Fully  revolving  disc^ 
seats  in  different  posi- 
tion on  seat  ring  face 
and  distributes  wear  uni- 
formly over  the  entire 
seating  fare. 


Bronze  seat  ring  is 
screwed  In  body  and 
made  with  lugs  and  can  ' 
be  replaced  with  body 
in  line.  It  can  be  furn- 
ished with  a  resilient  in- 
sert for  bottle«tight  ser- 
vice on  gas  or  air. 


Bronze  bushed  ductile 
iron  clapper  arm  for 
added  strength  and  im- 
pact resistance. 


Body  design  permits  re* 
moval  of  clapper  arm 
assembly  through  bon- 
net opening. 


Bronze  or  alloy  disc  ring 
is  securely  peened  into 
machined  dove-tai led 
groove. 


Fig.  18.38  Check  valve 

(Permssion  of  Amencan-Dariing  Valve.  Birmingham,  Alabama) 


Vertical  seating  surfaces 
provide  sensitive  seating 
action. 


31V 


Maintenance  297 


TABLE  1 8.4   COMPARISON  OF  FEATURES  OF 
DIFFERENT  TYPES  OF  CHECK  VALVES^ 


Lowest  initital  cost 
Shiortest  laying  lengrhi 
Highest  hiead  loss  (see  hiead  loss  curves) 
Resilient  seat  (optional) 
For  waste  and  raw  sewage 
Clean  water  only 
Cushiion  closing 
Silent  closing  (positively  silent) 
Free  open  -  Free  close 
Control  open  or  close  or  bothi  (optional) 
Vertical  installation  flow  up  or  down 
Can  be  rubber  lined 
Disc  position  indicator 
Buried  service 
Outside  lever 
Surge  pressure  control 
Reverse  flow 
Up  to  600#  class 
Uptol500#class 

Lowest  hiead  loss  (see  hiead  loss  curves) 
Up  to  2500#  class 
Control  open  and  close  standard 
Shut  off  valve 
Throttling  valve 

Vertical  installation  flow  up  only 
Electric  motor  operated 
Remote  control 

Control  closure  upon  power  failure 
Resilient  seat  standard 
Velocities  in  excess  of  1 5  FPS 
Velocities  up  to  5  FPS 
Velocities  up  tolOFPS 


a  Permission  of  APCO/Valve  and  Primer  Corporation. 


er|c 


318 


298  Water  Treatment 


Maintenance  299 


300  Water  Treatment 


Maintenance  301 


Fig,  18,42  Slanting  disc  check  valves  (pivot  off  center) 

(pormission  of  APCO/Valve  and  Prtmer  CorporaJion) 

ERJC  3H2 


302  Water  Treatment 


Maintenance  303 


304   Water  Treatment 


Maintenance  305 


18.267  Maintenance  of  Check  Valves 
Paragraph  13:  Check  Valves 

Frequency 
of 

Service 


A  1  INSPECT  DISC  FACING  Open  valves  to 
observe  condition  of  facing  on  swing  check 
valves  equipped  with  leather  or  rubber 
seats  on  disc.  If  metal  seat  ring  is  scarred, 
dress  it  with  a  fine  file  and  lap  with  fine 
emery  paper  wrapped  around  a  flat  tool. 

A  2.  CHECK  PIN  WEAR.  Check  pin  wear  on 
balanced  disc  check  valve,  sincG  disc  must 
be  accurately  positioned  in  seat  to  prevent 
leakage 

18,268  Automatic  Valves 

Water  treatment  plants  usually  have  a  number  of  auto- 
matically operated  valves.  The  simplest  type  Is  either  open 
or  closed  and  is  not  required  to  operate  in  an  intermediate 
position.  Frequently  these  valves  are  similar  to  gate  valves 
that  have  had  their  threaded  stems  and  handwheels  re- 
placed by  a  smooth  shaft  and  hydraulic  piston.  Maintenance 
on  these  v^*'  '-;s  Is  essentially  the  same  as  for  gate  valves. 

Other  automatically  operated  valves  are  used  to  control 
flow  in  water  treatment  plants  and  are  usually  located  at 
some  point  between  tight  shut  and  wide  open.  These  are 
commonly  called  modulating  valves.  A  buttp  fly  valve  with  a 
hydraulic  cylinder  operator  can  be  use^  for  this  type  of 
service. 


The  diaphragm-operated  globe  valve  (Figure  18.46)  is  also 
used  for  modulating  service  These  valves  can  be  equipped 
with  pilot  control  devices  to  control  pressure,  flow,  or  level 
either  singly  or  in  combination.  Maintenance  on  these  valves 
consists  of  the  following: 

1.  Periodically  clean  any  strainers  in  the  pilot  control  sys- 
tem Scheduling  should  be  adjusted  to  accommodate  the 
rate  at  which  the  strainer  collects  foreign  material. 

2.  Check  the  operation  of  the  valve  to  see  ihat  the  controls 
are.  in  fact,  correctly  positioning  the  valve  to  accomplish 
the  job. 

3.  If  the  valve  is  used  in  an  application  where  it  seldom  or 
never  is  wide  open,  it  should  periodically  be  exercised 
manually  to  cycle  from  tight  shut  to  wide  open.  This  is  to 
insure  that  there  is  no  buildup  on  the  stem  that  could  jam 
the  valve.  These  valves  can  be  opened  wide  by  drawing 
all  the  pressure  from  the  cover  chamber.  If  water  does 
not  stop  flowing  out  of  the  cover  chamber,  when  the  valve 
IS  wide  open,  it  is  an  indication  that  the  diaphragm  Is 
leaking  and  should  be  replaced. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  326. 

18.26A  What  IS  the  purpose  of  valves'? 

18  26B  List  six  common  types  of  vah'^s  found  in  water 
treatment  facilities 

18  26C  What  is  the  purpose  of  a  check  valve? 

18.26D  Why  is  backflow  prevention  by  check  valves  essen- 
tial in  many  applications? 

18  26E  What  maintenance  is  required  by  gate  valves'? 

Please  answer  the  discussion  and  review  questions  be- 
fore continuing  with  Lesson  5. 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  18.  MAINTENANCE 

(Lesson  4  of  5  Lessons) 


Write  your  answers  to  these  questions  in  your  notebook 
before  continuing.  The  question  numbering  continues  from 
Lesson  3. 

32.  What  are  the  uses  of  a  compressor? 

33.  What  Items  should  be  maintained  on  a  compressor*? 


34  Why  should  inactive  gate  valves  be  operated  periodic- 
ally? 

35.  What  factors  can  cause  wear  on  gate  valve  seats? 


ER?C 


32S 


306  Water  Treatment 


ERIC 


Fig.  18.46  Diaphragm  operated  globe  valve 

(Permission  of  CLA-VAL  Co  ) 


Maintenance  307 


CHAPTER  18.  MAINTENANCE 

(Lesson  5  of  5  Lessons) 


18.3    INTERNAL  COMBUSTION  ENGINES 
18.30  Gasoline  Englnes^^ 

18.300  Need  to  Maintain  Gasoline  Engines 

In  the  water  treatment  departments  of  all  cities  there  is 
occasion  to  use  gasoline-powered  engines  that  drive 
pumps,  generators,  tractors,  and  vehicles.  Although  we  all 
drive  automobiles  that  are  powered  by  internal  combustion 
engines,  are  you  aware  of  the  fundamentals'? 

Very  'ew  operators  actually  do  the  repair  of  gasoline- 
powered  engines.  Although  you  may  not  be  able  to  perform 
the  duties  of  an  engine  mechanic,  there  are  a  number  of 
steps  you  can  take  to  ensure  that  your  particular  engine  is 
well  maintained. 

At  the  end  of  this  section  you  will  have  an  adequate 
knowledge  of  how  a  gasoline  engine  operates  in  order  to 
maintain  it  so  as  to  provide  many  hours  at  optimum  per- 
formance. 

18.301  Maintenance 

In  order  to  have  an  engine  that  will  provide  you  with  many 
hours  of  trouble-free  operation,  it  must  be  well  cared  for 
PLEASE  REFER  TO  THE  OWNER/OPERATOR  MANUAL 
FOR  YOUR  PARTICULAR  ENGINE.  Typical  maintenance 
procedures  are  as  follows: 

1  Change  engine  oil  regularly  every  25  hours, 

2  Clean  carburetor  air  filter  every  25  hours; 

3  Blow  dust  and  chaff  from  louvered  engine  vanes  regu- 
larly; 

4  Clean  carbureto''  fuel  filter/screen  eveiy  100  hours; 

5  Lubncate  generator  and/or  starter  motor  as  recommend- 
ed, every  100  hours; 

6.  Lubricate  throttle  linkage  every  100  hours. 

7.  Clean,  gap,  or  rer/!3C0  spark  plug  every  100  hours;  and 

8.  Remove  carbon  deposits  from  top  of  piston  and  valves 
every    )0  to  3C0  hours. 


18.302  Starting  Problems 

Listed  below  are  some  items  to  check  if  you  have  prob- 
lems starting  a  gasoline  engine 

1 .  No  fuel  in  tank,  valve  closed 

2  Carburetor  not  choked 

3  Water  or  dirt  in  fuel  lines  of  carburetor 


4  Carburetor  flooded 

5  Low  compression 

6  Loose  spark  plug,  and 
7.  No  spark  at  plug 

a  Dirty  and  improper/gapped  plug 

b  Broken  or  wet  ignition  cables 

c.  Greaker  points  not  opening  or  closing,  and 

d  Magneto  grounded 

18.303   Running  Problems 

Check  the  following  items  a  gasoline,  engine  does  not 
run  properly 

1  Engine  misses 

a  Faulty  spark  plug/gappmg 

b  Weak  ignition  spark 

c  Loose  ignition  cable 

d  Worn  breaker  points 

e  Water  in  fuel 

f  Poor  compression 

2  Engine  surges 

a  Carburetor  flooding 

b  Governor  spring  connected  improperly 


For  additional  information  on  y^soline  engines,  see  INDUSTRIAL  WASTE  TREATMENT,  Chapter  7,  Support  Systems,  Section  74, 
"Gasoline  Engines,"  in  this  series  of  manuals. 


308  Water  Treatment 


3  Engine  stops 
a  Fuel  tank  empty 

b.  Vapor  lock 
c  Tank  air  vent  plugged 

4  Engjne  overheats 
a  Low  crankcase  oil 
b  igmtjon  fming  wrong 
c  Engine  overloaded 

d  Restricted  air  circulation/high  ambient  temperature 
e.  Poor  grade  of  gasoline 

5.  Engine  knocks 
a  Poor  grade  of  gasoline 
b  Engine  under  heavy  load  at  low  speed 

c.  Carbon  deposits  m  cylinder  head 

d.  Spark  advanced  too  far 

e.  Loose  connecting  rod  bearing 
f  Worn  or  loose  piston  pin 

6.  Engine  backfires  through  carburetor 
a  Water  or  dirt  n  fuel 
b  Cold  engine 
c  Poor  grade  of  gasoline 
d.  Sticking  mlet  valves 
e  Spark  plug  heat  range  too  hot 

QUESTIONS 

Wnte  your  answers  m  a  notebook  and  then  compare  your 
a.iswers  with  those  on  page  326 

18.30A  List  some  possible  uses  of  gasoline  engines  m 
water  treatment  plants. 

18.30B  What  items  would  you  check  if  you  had  problems 
starting  a  gasoline  engine? 

18.30C  What  Items  could  cc  jse  a  gasoline  engine  to  not 
run  properly? 

18,304  How  to  Start  a  Gasoline  Engine 

Because  of  the  wide  variety  of  uses  for  gasoline-powered 
engines,  no  one  starting  sequence  will  apply  to  all  engines. 
In  general,  gasoline  engines  can  be  divided  into  two  groups. 
In  the  first  group  are  small  engines  with  magneto  Ignition 
and  recoil  start.  Larger  engines  with  battery-powered  igni- 
tion and  elertnc  start  are  in  the  second  group. 

18.3040  imaii  Engines.  The  procedure  for  starting  small 
engines  is  as  follows: 

1.  Check  fuel  tank  for  adequate  fuel; 

2.  Ensure  fuel  shut  off  valve  fron.  the  tank  to  the  carburetor 
is  open; 

3.  Disengage  ignition  ground  f  kill"  switch  or  mechanism 
that  grounds  the  spark  plug); 

4.  Check  crankcase  lubricating  oil; 

ERLC 


5  Set  throttle  to  start  position  or  %  full  throttle; 

6  Set  choke  lever  or  pull  out  choke  on  carburetor. 

7  Pull  recoil  starter  twice. 

8  If  engine  has  started,  push  choke  to  "off",  and 

9  If  engine  does  not  start  after  two  pulls,  disengage  the 
choke  and  try  three  or  four  more  times. 

If  repeated  efforts  at  starting  have  been  unsuccessful, 
remove  the  high  tension  voltage  wire  from  the  spark.  Hold 
the  end  of  the  wire  (grasp  the  insulated  portion,  NOT  the 
connector)  Ve  inch  (3  mm)  from  the  spark  plug  Pull  the  recoil 
starter.  You  should  see  a  small  blue  spark  This  will  indicate 
that  the  points  are  opening  and  closing  and  providing 
ignition  voltage. 

The  next  step  is  to  remove  the  spark  plug  from  the 
cylinder  head  (use  a  ^^le  inch  (20.6  mm)  deep  socket).  Check 
for  a  carbon  buildup  on  the  electrode.  A  piece  of  carbon  may 
have  lodgea  between  the  center  electrode  and  the  side 
electrode.  Also  check  to  see  if  the  plug  is  wet  with  fuel  or  oil. 
This  could  indicate  that  you  have  flooded  the  cylinder  with 
fuel  by  having  the  choke  on  too  long.  If  there  is  oil  residue,  it 
could  mdlcaie  worn  piston  rings. 

Replace  the  spark  plug  with  a  new  one  if  in  doubt.  If  you 
must  use  the  one  you  have,  clean  it  by  buffing  with  a  wire 
brush.  Check  the  "gap"  between  the  center  electrode  and 
side  electrode;  it  should  be  approximately  .030  inch  (30 
thousands  of  an  inch  or  0.76  mm). 

Try  staring  the  engine  as  previously  described.  If  the 
engine  does  not  sputter  or  pop,  close  the  fuel  shut-off  valve, 
remove  fuel  sedimentation  bowl  and  clean.  Open  fuel  va've.' 
Catch  a  small  amount  of  fuel  in  the  palm  of  your  hand  and 
examine  the  fuel  for  grit  or  water.  If  everything  looks  okay, 
replace  sediment  bowl  and  open  fuel  valve. 

Try  to  start  the  engine.  If  you  still  cannot  achieve  ignition, 
you  may  have  other  problems  that  will  require  further 
checking  by  a  small-engine  mechanic  Do  not  feel  disgrun- 
tled, you  have  checked  for  the  most  common  problems. 

1 8.3041  Large  Engines.  The  procedure  for  starting  large 
engines  is  as  follows: 


1 .  Check  fuel  tank  for  fuel; 

2.  Check  crankcase  for  oil; 

3.  Check  radiator  for  coolant  (if  water  cooled); 
4  Set  throttle  to  V2  full  position; 


Maintenance  309 


5  Pull  out  choke. 

6  Turn  on  ignition  switch  and  press  start  button. 

7  After  four  or  five  engine  revolutions,  push  m  the  choke, 
and 

8  Engine  should  start 

After  repeated  tries,  further  invebtgation  by  a  mechanic 
may  be  needed 

NOTE  Do  not  crank  engine  with  the  starter  lotor  foi  more 
than  one  minute  initially  Wait  two  minutes  and  try 
again  for  45  seconds  After  three  tiys.  let  starter 
motor  cool  for  5  minutes  before  trying  again  This  will 
avo.d  starter  motor  damage. 

Preliminary  checks  for  a  large  engine  that  won  t  start  are 
Similar  to  procedures  for  small  engines 

Remove  spark  plug  wires  Test  each  one  by  holding  it  Vs 
inch  (3  mm)  from  the  spark  plug  or  ground,  and  turn  engine 
over  with  the  starter.  You  should  see  a  small  blue  spark.  If 
you  have  no  spark,  the  points  are  not  openir  or  high 
tension  voltage  is  not  present  from  the  ignition  coil.  Check 
further  as  needed 

If  spark  IS  present,  inspect  spark  plugs.  Clean  or  replace  if 
needed 

After  checking  the  ignition  system,  make  sure  fuel  is 
present  at  the  carburetor  Remove  the  fuel  line  at  the 
carburetor  and  direct  it  away  from  you  and  the  engine 
Engage  starter  motor  for  two  revo  jtions.  Fuel  should  spurt 
from  the  line  if  the  fuel  pump  is  working  satisfactorily 
Replace  fuel  line  and  wipe  away  any  fuel  that  may  be  present 
on  the  engine. 

With  fuel  and  ignition  voltage  present,  it  should  start. 
Repeat  start  procedure  If  you  still  cannot  start  the  engine, 
call  on  your  mechanic  to  look  for  the  problem. 

NOTE' Some  engines  have  a  low  oil  pressure  switch  that 
must  be  manually  held  in  until  sufficient  oil  pressure 
IS  present. 

Do  not  use  a  starting  fluid  on  gasoline  engines  unless  it  is 
a  LAST  RESORT  eiion  to  get  a  critical  piece  of  equipment 
running.  Hard-starting  engines  should  be  inspected  and 
repaired  by  a  reliable  mechanic 

After  an  engine  has  been  starred,  give  it  an  opportunity  to 
warm  up  before  applying  the  load.  Follow  manufacturer  s 
recommendations  for  the  starting  procedure  since  there  is 
some  variation  between  different  makes  of  engines 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  326. 

18  30D  If  a  gasoline  eng.ne  will  not  start  and  the  spark  plug 
IS  wet  with  fuel  or  oil,  what  has  happened'^ 

18  30E  If  a  gasoline  engine  will  not  start  and  there  is  an  oil 
residue  on  the  spark  plug,  what  has  happened*^ 

18.30F  After  an  engine  has  started,  what  should  be  done 
before  applying  the  load? 


18.3 1    Diesel  Engmes^° 

18.310  How  Diesel  Engines  Work  (f\g  18  47) 

Diesel  engines  are  similar  to  gasoline  engines  and  are 
either  two  or  four  cycle  They  can  be  air  or  water  cooled  In 
general  the  diesel  engine  is  of  heavier  construction  to 
Withstand  the  higher  pressures  resulting  from  higher  com- 
pression ratios 

The  diesel  does  not  use  spark  plugs,  but  instead  relies  on 
heat  generated  by  air  compressed  in  the  cylinder  (1.000 
degrees  F  or  540''C)  to  ignite  the  fuel  mixture.  The  fuel  is  a 
petroleum  product  that  is  heavier  than  gasoline  and  with  a 
higher  flash  point  Gasoline  cannot  be  used  in  a  diesel 
because  it  would  start  to  burn  frcm  the  heat  generated  by 
compression  before  the  piston  reached  the  top  of  the  stroke 

A  diesel  has  no  carburetor  The  fuel  is  sprayed  (injected) 
into  the  cylinder  while  the  cylinder  is  compressing  air  The 
heat  of  compression  ignites  the  fuel-air  mixture  and  burns, 
producing  power  similar  to  a  gasoline  engine  The  introduc- 
tion of  fuel  into  the  cylinder  must  be  "timed'"  in  the  same 
manner  as  spark  to  the  plug  m  a  gasoline  engine  Fuel  is 
pumped  by  a  pumping  device  that  is  geared  tc  ine  crank- 
shaft 

Diesel  fuel,  unlike  gasoline,  does  not  vapo  'ze  readily  The 
fuel  must  be  broken  up  in  fine  particles  and  sprayed  into  the 
cylinder  The  atomization  of  fuel  is  accomplished  by  forcing 
the  fuel  through  a  nozzle  at  the  top  of  the  combustion 
chamber  As  the  fuel  combines  with  the  air  in  the  cylinder,  it 
becomes  a  combustible  mixture  Since  the  diesel  engine 
depends  upon  the  heat  of  compressed  air  to  ignite  the  fuel- 
air  mixture,  compression  pressure  must  be  maintained 
Leaking  valves  or  piston  rings  (causing  "blow  by  )  cannot  be 
tolerated 

The  fuel  IS  also  important.  The  automotive-type  diesel  is 
designed  to  run  on  a  specific  type  or  grade  of  fuel  Trouble 
can  be  expected  if  an  attempt  is  made  to  use  other  than  the 
proper  type 

18.311  Operation 

In  the  two-cycle  engine,  intake  and  exhaust  takes  place 
during  part  of  the  compression  and  power  strokes;  whereas, 
the  four-cycle  engine  requires  four  strokes  to  complete  the 
operating  cycle  During  one-half  of  the  cycle,  the  four-stroke 
acts  as  an  air  pump.  The  two-stroke  must  have  a  blower  (air 
pump)  to  provide  the  necessary  air  to  expei  the  exhaust 
gases  and  rcjharge  the  cylinder  with  fresh  air 

In  the  two-cycle,  a  series  of  ports  surround  the  cylinder  at 
a  point  higher  than  the  lowest  position  of  the  piston.  These 
are  the  intake  ports  that  allow  air  into  the  cylinder  The  four- 
cycle engine  uses  intake  valves  The  incoming  air  forces  the 
expended  gases  out  the  exhaust  valve,  leaving  the  cylinder 
full  of  clean  air 

As  the  piston  starts  '*s  upward  stroke,  the  exhaust  valve 
closes,  the  intake  ports  are  sealed  off  by  the  piston,  and  the 
air  in  the  cylinder  is  compressed  Shortly  before  the  piston 
reaches  the  top  of  the  stroke,  the  required  amount  of  fuel  is 
sprayed  into  the  combustion  chamber  by  the  fuel  injector. 
The  intense  heat  of  compression  ignites  the  fuel-air  mixture 
with  the  resulting  combustion  driving  the  p'Ston  down  on  its 
power  stroke. 


20  For  additional  information  on  diesel  engines,  see  INDUSTRIAL  WASTE  TREA  TMENT.  Chapter  7,  Support  Systems.  Section  7.5,  "Diesel 
Engines,"  in  this  series  of  manuals. 


ERLC 


'3:1 


310  Water  Treatment 


CHARGE  OF  FUEL  BEING  INJECTED 
INTO  COMBUSTION  CHAMBER 


EXHAUST  TAKING  WACE  AND  CYLINDER  ABOUT 
TO  BE  SWEPT  WITH  QEAN  SCAVENGING  AIR 

T.50I4 


Power  and  Exhaust 


ERLC 


Fig.  16  47  How  diessi  engines  work 

{Source  GMC  Truck  Overhaul  Manual  Series  53.  permission  cf  General  Motors  Corp  ) 


33  i 


Maintenance  311 


As  the  piston  nears  the  bottom  of  the  stroke,  the  exhaust 
valve  opens  and  the  spent  gases  are  released,  assisted  by 
the  incoming  fresh  air.  The  cycle  is  complete. 

18.312  Fuel  System  (Fig.  1 8.48) 

The  basic  parts  of  the  fuel  system  are: 
1 .  Primary  fuel  filter. 
2  Secondarv  fuel  filter. 

3.  Fuel  injection  pump,  and 

4.  Fuel  injector. 

The  primary  filter  removes  all  coarse  particles  from  the 
fuel  and  the  secondary  filter  removes  any  minute  particles 
that  remain.  This  ensures  a  clean  fuel  that  will  not  clog  the 
injector  pump  or  fuel  injectors.  The  heart  of  the  fuel  system 
IS  the  injection  pump  (Fig.  18.49)  This  pump  is  a  gear-type 
positive-displacement  pump  that  can  deliver  fuel  to  the 
injector  at  a  very  high  pressure.  Incorporated  into  the  pump 
IS  a  timing  advance  mechanism  to  advance  or  retard  the 
instant  when  fuel  is  injected  into  the  cylinder.  At  high  engine 
speed,  injection  would  take  place  sooner  in  the  cycle.  The 
reverse  happens  for  lower  speeds. 

A  governor  which  uses  centrifugal  weights  and  is  driven 
by  the  pump  shaft,  activates  a  fuel  control  unit.  When  engine 
speed  increases,  the  weights  are  thrown  toward  th-  ir  outer 
limit  Geared  to  the  assembly,  the  fuel  control  valve  is 
opened  wider  allowing  more  fuel  to  flow  to  the  injector. 

We  now  have  higher  engine  speed,  advanced  "timing'  of 
injection,  and  the  necessary  fuel  to  sustain  the  faster  oper- 
ation. When  the  engine  is  slowed,  the  reverse  takes  place. 

Fuel  under  pressure  is  fed  from  ths  injection  pump  to  the 
appropriate  fuel  nozzles.  When  the  pressure  reaches  ap- 
proximately 3,00C  psi  (20,700  kPa  or  207  kg/sq  cm),  the 
valve  in  the  injector  opens  allowing  fuel  to  be  Injected  into 
the  combustion  chambers  As  line  pressure  drops,  the 
return  spring  closes  the  nozzle  valve.  Fuel  left  in  the  line  is 
Jed  back  to  the  pump  through  "leak  off"  lines. 

18.^  13  Water-cooled  Diesel  Engines 

Usually  the  larger  diesel  engines  are  of  the  water-cooled 
type,  similar  to  gasoline  engines.  In  order  to  deliver  a 
sustained  amount  of  high  horsepower,  an  effective  cooling 
system  is  necessary  to  dissipate  the  extreme  heat  of  com- 
bustion. Because  of  this  fact,  a  water-cooled  engine  of 
comparative  horsepower  to  the  air-cooled  will  cost  more  to 
manufacture,  and  subsequently  to  maintain. 

18.314  Air-cooled  Diesel  Engines 

When  a  lighter  weight,  lower  horsepower,  and  more 
ccrpoact  engine  is  desired,  the  air-cooled  engine  will  serve 
your  needs.  You  get  the  benefits  of  a  diesel  engine  in  a 
smaller  package. 

There  are  some  definite  advantages  to  the  diesel  engine 
over  the  gasoline  engine.  The  initial  cost  is  greater  for  the 
diesel;  however,  the  diesel: 

1.  Requires  less  maintenance  because  there  are: 

a.  No  plugs, 

b.  No  contact  points  to  pit, 

c.  No  ignition  coils  or  high  tension  wires,  and 

d.  Fewer  tune-ups. 


2  Is  cheaper  to  operate  because: 
a.  Diesel  fuel  may  be  cheaper,  and 
b  Better  fuel  efficiency 

Perhaps  the  biggest  drawbacks  against  Oiesel  engines 
are 

1.  Initial  investment  costs,  and 

2.  Repair  costs 

The  pros  and  cons  must  be  weighed  to  provide  you  with 
an  engine  that  will  fill  your  particular  needs  Whichever 
engine  you  select,  remember  that  a  well-cared-for  engine 
will  De  there  to  serve  you  when  it  is  needed  and  will  provide 
trouble-free  operation  that  is  essential  to  most  users 

18.315  How  to  Start  Diesel  Engines 

Diesel  engines  vary  in  size  and  use  and  have  varied 
starting  procedures.  Follow  manufacturer's  suggested  pro- 
cedures for  your  particular  engine.  As  with  the  gasoline 
engine,  check  fuel,  oil.  and  coolant. 

To  start  a  diesel  engine,  the  procedures  are  as  follows 

1.  Push  in  "stop"  control, 

2.  Set  throttle  to  V3  full, 

3.  Turn  on  switch  and  engage  starter,  and 

4.  Engine  should  start 

Some  engines  have  glow  plugs  that  are  energized  when 
the  switch  is  placed  in  the  start  position.  They  preheat  the 
air-fuel  mixture  in  tud  cylinder  to  aid  in  starting.  After  the 
engine  is  started,  maintain  the  lower  RPM's  on  the  engine 
tachometer  and  allow  the  engine  to  warm  up.  The  warm-up 
period  IS  vital  to  the  diesel  engine  for  eff^ient  engine 
performance.  When  operating  the  engine,  maintain  ade- 
quate engine  RPM's  as  recommended  by  the  manufacturer. 

When  a  diesel  engine  will  not  start  after  repeated  tries,  a 
small  amount  of  starting  fluid  sprayed  into  the  air  intake  may 
be  needed  to  start  the  engine.  If  you  use  starting  fluid,  do  not 
get  carried  away  with  its  use;  a  little  goes  a  long  way.  Use  it 
only  as  a  last  resort  or  as  specified  by  the  manufacturer.  If 
your  efforts  have  failed  to  start  the  engine,  have  a  mechanic 
that  IS  familiar  with  diesel  engines  detern.ine  the  cause  of 
the  problem. 

18.316  Maintenance  and  Troubleshooting 

For  detailed  maintenance  procedu  .  z  for  your  diesel  en- 
gine, see  your  diesel  manufacturer's  service  manual. 


312   Water  Treatmert 


1  Nozzle  Valve  and  Body 

2  No7j2le  Valve  Spring 

3  Leak-off  Lines 

4  Hydraulic  Head  Assembly 

5  Fuel  Metering  Sleeve 

6  Pump  Plunger 


7  Face  Gear 

8  Tappet  and  Roller 

9  Can\ 

10  Governor  Gears 
i  1  Governor  Weights 


12  Governor  Stop  Plate 

13  Fulcrum  Lever 

14  Stop  Lever 

15  Shut-off  (when  used) 

16  Fuel  Return  Line 


Fig.  18,48  Diesel  engine  fuel  system 

(Source  Maintenance  Manual,  permisston  of  General  Motors  Corp  ) 

Er|c  33  j 


Maintenance  313 


Fig.  16.49  Cut-away  view  of  fuel  injection  pump  for  G-cylinder  engine 

(Source  Maintenance  Manual,  permission  of  General  Motors  Corp  ) 


TROUBLESHOOTING 

Certain  abnormal  conditions  which  sometimes  interfere 
with  satisfactory  engine  operation  are  listed  in  this  section. 

Satisfactory  engine  operation  depends  pnmanly  on: 

1.  An  adequate  supply  of  air  compressed  to  a  sufficiently 
high  compression  pressure. 

2.  The  injection  of  the  proper  amount  of  fuel  at  the  right 
time. 

Lack  of  power,  uneven  running,  excessive  vibration,  stall- 
ing at  idle  speed  and  hard  starting  may  be  caused  by  either 
low  compression,  faulty  injection  in  one  or  more  cylinders,  or 
lack  of  sufficient  air. 

Since  proper  compression,  fuel  injection  and  the  proper 
amount  of  air  are  important  to  good  engine  performance, 
possible  problems  are  listed  below: 

1.  Misfiring  cylinders, 

2.  Improper  compression  pressure, 

3.  Engine  out  of  fuel, 

4.  Proper  fuel  flow, 

5.  Excessive  crankcase  pressure, 


6.  Excessive  back  pressure. 

7.  Improper  air  box  pressure, 
8-  Restricted  air  inlet, 

9.  Low  oil  pressure,  and 

10  Improper  engine  coolant  operating  temperature. 

Solut.ons  to  these  problems  can  be  found  in  the  operation 
and  maintenance  instructions  for  the  engines. 


18.32  Cooling  Systems  (Fig.  18.50) 

In  an  air-cooled  engine,  the  heat  generated  by  combustion 
IS  dissipated  by  the  air  circulating  past  the  louvered  cylinder 
block.  With  a  water-cooled  system,  the  same  effect  is 
achieved  by  using  water.  Each  cylinder  is  surrounded  with  a 
water  jacket  through  which  coolant  circulates.  This  is  ac- 
complished by  a  water  pump  that  is  belt-driven  from  the 
cankshaft.  The  heat  transfers  from  the  cylinder  wall  to  the 
water  which,  in  turn,  is  pumped  back  to  the  radiator  where 
the  heat  is  dissipated.  A  fan  mounted  on  the  same  shaft  as 
the  water  pump  ensures  that  a  large  volume  of  air  is  blown 
across  the  radiator  coils  to  facilitate  rapid  disbursbment  of 
heat.  The  cooled  Wcter  is  then  pumped  back  into  the  engine. 


ERLC 


334 


314  Water  Treatment 


Engine  temp^atures  are  regulated  by  transferrtng  excess 
heat  to  surrounding  air. 


With  woftr  focktts  eniircly  around  toch  cylindtr  and  valve,  thtrt  ts  o  great  amount  o/  oreo  exposed  to 

th^  circulating  coolant. 

Fig,  18.50  Water  cooling  system 

(Source  Automotive  Encyclopedia,  permission  of  the  Goodheart-Wiicox  Co  inc ) 


ERIC 


Maintenance  315 


Internal  combustion  engines  operate  more  efficiently 
when  their  temperature  is  maintained  within  narrow  limits 
This  objective  is  achieved  with  the  insertion  of  a  thermostat 
in  the  cooling  system  which  is  called  a  "temperature  actu- 
ated valve."  When  the  engine  is  cold,  the  thermostat  remains 
closed  not  allowing  the  water  to  circulate  back  to  the 
radiator  As  the  engine  temperature  increases  to  normal 
operating  temperature,  the  thermostat  opens. 

The  radiator  cap  provides  a  function  other  than  preventing 
coolant  from  splashing  out  the  filter  opening  The  cap  is 
designed  to  seal  the  cooling  system  so  that  it  operates 
under  pressure  This  imprc/es  cooling  efficiency  and  pre- 
vents evaporation  of  coolant.  The  boiling  point  of  water  is 
212  degrees  F  (100°C)  However,  for  every  pound  of  pres- 
sure applied  to  the  system,  the  boiling  point  rises  3.25 
degrees  F  (1.8°C).  If  your  cooling  system  had  a  15  psi  (100 
kPa  or  1  kg/sq  cm)  radiator  cap  and  used  water  for  coolant. 
It  would  have  a  boiling  point  near  260  degrees  F  (127''C) 

The  use  of  coolant/anti-freeze  provides  protection  against 
the  radiator  coolant  freezing  and  ruptunng  the  system  and 
also  provides  better  heat  transfer  and  heat  dissipation 
characteristics  than  water.  Most  of  the  name-orand  coolants 
contain  rust  inhibitors.  Rust  buildup  in  the  cooling  system 
interferes  with  good  heat  transfer  and  the  sloughing  of  rusi 
scale  can  block  narrow  passages. 

Stationary  internal  combustion  enginej  such  as  those 
that  are  used  to  drive  pumps  and  generators  at  the  water 
treatment  plants,  are  often  installed  in  a  building  where  free 
circulation  of  air  for  radiator  cooling  may  not  be  possible. 
For  these  installations,  a  liquid-to-liquid  heat  exchanger 
often  replaces  the  radiator  (which  is  a  liquid-to-air  heat 
exchanger).  In  this  case,  instead  of  the  heat  in  the  cooling 
jacket  water  being  transferred  to  the  surrounding  air,  it  is 
transferred  to  anotner  liquid,  usually  tap  water.  This  water 
may  be  wasted,  if  the  engine  is  a  standby  unit  and  not 
operated  very  much,  or  the  cooling  water  may  be  recovered 
in  a  cooling  tower  if  the  engine  is  in  regular  use. 

In  liquid-to-liquid  heat  exchanger  systems  a  thermostati- 
cally controlled  valve  is  usually  installed  to  regulate  ♦he  flow 
of  cooling  water  through  the  exchanger.  This  valve  should 
be  checked  periodically  to  see  that  it:  (1)  provides  sufficient 
water  flow  when  the  engine  is  running  and  (2)  closes  off  tight 
when  ihe  engine  is  shut  down  to  prevent  waste. 

Cooling  water  from  a  heat  exchanger  should  not  be  put 
back  mtc  a  potable  wa^er  system  Any  leakage  in  the  heat 
exchanger  could  result  in  engine  jacket  coolant  contaminat- 
ing the  potable  water  supply. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  326. 

18  31 A  Why  is  gasoline  not  used  as  a  fuel  in  diesel  en- 
gines? 

18  31 B  List  the  four  basic  parts  of  a  diesel  fuel  system 

18.31C  What  IS  the  purpose  of  the  fuel  injection  pump? 

18.32A  How  IS  heat  removed  from  the  cylinders  m  a  water- 
cooled  engine*? 

1G.33  Fuel  Stor..9e 

18,330  Code  Requirements 

Storage  and  use  of  fuels  for  internal  combustion  engines 
must  always  be  in  accordance  with  local  building  and  firo 


marshal  codes  In  addition,  the  water  treatment  plant  opera- 
tor should  be  familiar  with  the  particular  problems  associat- 
ed with  each  of  the  commonly  used  fuels 

18.331  Diesel 

DIESEL  This  fuel  comes  in  two  grades  known  as  #1  and 
#2  Be  sure  to  use  the  grade  recommended  by  the  engine 
manufacturer.  Be  aware  that  the  fuel  grade  recommendation 
may  vary  with  the  season.  Diesel  fuel  is  often  stored  in 
above  ground  tanks.  The  fuel  may  be  kept  in  storage  for 
years  without  deteriorating  To  protect  stored  diesel  from 
water  contamination,  keep  the  storage  tanks  full  and  use 
special  additives. 

18.332  Gasoline 

GASOLINE  Except  for  very  small  quantities,  gasoline  is 
stored  in  underground  tanks  This  can  result  in  problems  for 
the  operator  If  the  storage  tank  develops  a  leak,  either  fuel 
can  leak  out  or  water  can  leak  m.  Either  condition  is 


undesirable  Fuel  loss  ca  i  not  only  be  an  unwanted  operat- 
ing expense,  but  can  be  a  danger  to  underground  plant 
piping.  Gasoline  detenorates  rubber  and  if  the  piping  is  put 
together  with  rubber  gaskets  or  rings,  the  detenoration  can 
result  in  major  leaks  and  broken  couplings.  Fuel  loss  can 
best  be  monitored  by  careful  accounting. 

Water  leakage  into  underground  fuel  tanks  can  result  in 
engine  stoppages  and  possible  damage  to  the  engine. 
Special  devices  are  available  for  detecting  water  in  gasoline 
tanks  and  such  a  test  should  be  run  routinely.  These  devices 
can  be  obtained  by  contacting  your  local  wholesale  fuel 
distributor 

Gasoline,  unlike  diesel,  deteriorates  in  storage.  For  en- 
gines that  are  in  normal  everyday  use,  this  is  not  a  problem. 
However,  fuel  storage  for  standby,  engine-driven  equipment 
requires  further  consideration.  Engine  operation  and  fuel 
tank  rej^!enishment  should  be  scheduled  so  that  at  least  one 
half  of  the  gasoline  in  storage  is  used  each  year.  Failure  to 
do  this  can  result  in  engines  that  are  hard  to  start  and  in  the 
formation  of  varnish  and  gummy  deposits  that  can  cause 
malfunctions  in  the  parts  of  the  fuel  syste.n. 


316  Water  Treatment 


18.333  Liquified  Petroleum  Gas  (LPG) 

LIQUIFIED  PETROLEUM  GAS  (LPG).  LPG  is  usually  a 
mixture  of  propane  and  butane.  The  proportions  of  each  is 
varied  according  to  the  weather  temperature.  The  cooler  the 
weather,  the  greater  the  proportion  of  propane. 

This  fuel  IS  always  stored  under  pressure  in  above-ground 
tanks  that  are  located  out  in  the  open.  LPG  does  not 
deteriorate  in  storage  and  therefore  can  be  kept  for  many 
years. 

LPG  IS  heavier  than  air  and  will  collect  in  low  areas  if  there 
IS  any  leakage.  This  poses  an  extremely  dangerous  explo- 
sive threat  that  treatment  plant  operators  must  constantly 
guard  against. 

18.334  Natural  Gas 

NATURAL  GAS.  This  fuel  is  usually  obtained  from  the 
local  gas  company  through  a  metered  connection  from  their 
distribution  system.  There  is  no  on-site  storage. 

Natural  gas,  being  lighter  than  air,  tends  to  rise  and 
dissipate  from  leaks  and  therefore  is  less  dangerous  to 
handle  than  LPG.  Explosions  can  occur,  however,  if  the 
leakage  is  confined  inside  a  building. 

18.34  Standby  Engines 

Internal  combustion  engines  must  be  run  periodically  to 
ensure  that,  when  needed,  they  will  function  properly.  An 
engine  that  is  not  in  regular  service  should  be  started  up  and 
test  run  at  least  once  a  week.  The  test  run  should  be  long 
enough  for  the  engine  to  come  up  to  its  normal  operating 
temperature  before  the  engine  is  shut  down.  If  at  all  possi- 
ble, run  the  engine  under  its  normal  load.  Just  idling  an 
engine  for  20  minutes  doesn't  give  you  much  of  an  indication 
as  to  whether  it  can  handle  a  load.  Check  and  make  note  of 
the  engine  instruments.  Look  for  changes  that  may  indicate 
a  need  for  repairs.  Lube  oil  pressure  and  intake  manifc'^i 
pressure  (on  spark  ignition  engines  without  supercharging 
or  fuel  injection)  are  two  key  indicators  of  engine  condition. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  326. 

18.33A  The  storage  and  use  of  fuels  for  internal  combus- 
tion engines  must  be  in  accordance  with  what 
codes? 

18  33B  List  four  types  of  fuels  commonly  used  by  inlernal 
combus^lion  engines. 

18.34A  Hov  often  should  standby  internal  combustion  en- 
gines be  test  run  when  not  in  regular  service*^ 

18.34B  Under  what  conditions  should  standby  engines  be 
test  run*? 


18.4  CHEMICAL  STORAGE  AND  FEEDERS^' 

18.40  Chemical  Storage 

Certain  dry  chemicals  such  as  alum,  ferric  chloride,  and 
soda  ash  are  HYGROSCOPIC.^^  These  chemicals  require 
special  considerations  to  protect  them  from  moisture  during 
storage.  Dry  quicklime  should  be  kept  dry  because  of  the 


tremendous  heat  which  is  generated  when  it  comes  in 
contact  with  water.  This  heat  is  sufficient  to  cause  a  fire 

Some  liquid  chemicals  such  as  sodium  hydroxide  (caustic 
soda)  should  not  be  exposed  to  air  because  of  the  formation 
of  calDum  carbonate  (a  solid)  due  to  the  carbon  dioxide  in 
the  air  Also  some  liquid  chemicals  may  "freeze."  A  50 
percent  sodium  hydroxide  solution  becomes  crystalized 
(forms  a  solid)  at  temperatures  below  55°F  (13°C).  Therefore 
a  heater  may  be  required  to  keep  the  storage  area  warm  or 
the  solution  may  have  to  be  diluted  down  to  a  25  percent 
solution. 

Potassium  permanganate  can  be  kept  indefinitely  if  stored 
in  a  cool  dry  a''ea  in  closed  containers.  The  drums  should  be 
protected  from  damage  that  could  cause  leakage.  Potas- 
sium permanganate  should  be  stored  in  fire-resistant  build- 
ings, having  concrete  floors  as  opposed  to  wooden  floors.  It 
should  not  be  exposed  to  intense  heat,  or  stored  next  to 
heated  pipes  Any  organic  solvent,  such  as  greases  and  oils 
in  general,  should  be  kept  away  from  stored  KMnO^. 

Potassium  permanganate  spills  should  be  swept  up  and 
removed  Immediately.  Flushing  with  water  is  an  effective 
way  to  eliminate  spillage  on  floors.  Potassium  permangan- 
ate fires  should  be  extinguished  with  water. 

Carbon  should  be  stored  in  a  clean,  dry  place,  in  single  or 
double  rows,  and  with  access  aisles  around  every  stack  for 
frequent  fire  inspections.  The  removal  of  burning  carbon  will 
thus  be  facilitated.  Carbon  should  never  be  stored  in  large 
stacks. 

The  storage  area  should  be  of  fireproof  construction,  with 
self-closmg  fire  doors  separating  the  carbon  room  from 
other  sections.  Storage  bins  for  dry  bulk  carbon  should  be  of 
fireproof  construction  equipped  for  fire  control  by  the  instal- 
lation of  carbon  dioxide  equipment,  or  should  be  so  ar- 
ranged that  they  can  be  flooded  with  a  fine  spray  of  water. 

Ca;bon  storage  areas  should  be  protected  from  contact 
with  flammable  materials.  (Carbon  dust  mixed  with  oily  rags 
or  chlorine  compounds  can  ignite  in  spontaneous  combus- 
tion.) SMOKING  SHOULD  BE  PROHIBITED  AT  ALL  TIMES 
DURING  THE  HANDLING  AND  UNLOADING  OF  CARBON 
AND  IN  THE  STORAGE  AREA.  Carbon  should  not  be  stored 
where  a  spark  from  overhead  electric  equipment  could  start 
a  fire.  If  a  fire  occurs,  the  carbon  monoxide  hazard  should  be 
taken  into  account. 

Electnc  equipment  should  be  protected  from  carbon  dust 
and  cleaned  frequently  or,  better,  explosion-proof  electric 
wiring  and  eauipment  should  be  used.  (The  heat  from  a 
motor  may  ignite  the  accumulated  carbon  dust,  this  material, 
especially  when  damp,  is  a  g  ^od  conductor  of  electncity  and 
could  short-circuit  the  mechanism.) 

Polymer  sc'utions  will  be  degraded  (lose  their  strength)  by 
bioloq»cal  contamination.  A  good  cleaning  of  polymer  stor- 
age tanks  IS  recommended  before  a  new  shipment  is  deliv- 
ered to  the  plant. 

Liquid  chemical  storage  tanks  should  have  a  berm  or 
earth  bank  around  the  tanks  to  contain  any  chemicals 
released  if  the  tank  fails  due  to  an  earthquake,  corrosion  or 
any  other  reason. 

Some  chemicals  such  as  chlonne  and  fluoride  compounds 
are  harmful  to  the  human  body  when  they  are  released  as 
the  result  of  a  leak.  Continual  surveillance  and  maintenance 
of  the  storage  and  feeding  systems  are  required. 


2»  For  additional  information  on  chemical  feeders,  see  Chapter  13,  Fluoridation,  Section  13  30,  "Chemical  Feeders 
22  Hygroscopic  (HI-grow-SKOP-ick).   Absorbing  or  attracting  moisture  from  the  air. 


ERIC 


33/ 


Maintenance  317 


18.41  Drainage  from  Chemical  Storage  and  Feeders 

Safety  regulations  prohibit  a  single  drainage  pit  which  can 
accept  and  contain  both  acid  and  alkali  chemicals  because 
of  the  possibility  of  an  explosion  whenever  these  two  types 
of  chemicals  come  in  coiitact.  Also,  any  organic  chemical 
waste  such  as  a  polymer  solution  should  not  be  allowed  to 
be  discharged  into  a  pit  or  sump  which  could  also  receive  a 
waste  from  oxidizing  chemicals  such  as  potassium  perman- 
ganate (KMnO^)  because  of  the  possibility  of  a  fire.  There- 
fore, separate  drainage  systems  or  a  high  dilution  of  certain 
chemicals  are  necessary  for  a  safe  drainage  system. 

18.42  Use  of  Feeder  Manufacturer's  Manual 

Water  treatment  plants  will  have  a  number  of  chemical 
feeders  to  accurately  control  the  i  ate  at  which  chemicals  are 
fed  into  the  water  as  a  part  of  the  treatment  processes 
There  are  many  types  of  feeders  and  they  work  on  many 
different  principles.  Study  the  feeder  manufacturer's  manual 
that  you  should  find  in  the  treatment  plant  library  for  details 
on  maintaining  the  equipment.  Additional  information  on 
chemical  feeders  is  contained  in  specific  chapters  on  treat- 
ment processes  that  require  the  use  of  chemical  feeders. 

18.43  Solid  Feeders 

Solid  feeders  usually  handle  powdered  material  and  usu- 
ally have  many  moving  mechanical  parts  that  need  adjust- 
ment, lubrication,  and  replacement  when  worn.  The  chemi- 
cal supply  IS  usually  stored  in  a  hopper.  Keep  the  hopper 
and  feeder  clean  and  dry  in  order  to  prevent  "bndging"  (a 
hardened  layer  which  can  form  an  arch  and  prevent  flow)  of 
the  chemical  in  the  hopper  and  clogging  in  the  feeder. 

18.44  Liquid  Feeders 

Liquid  feeders  handle  many  types  of  chemicals,  some  of 
which  may  be  corrosive  and/or  have  a  tendency  to  plug  up 
the  mechanism.  The  key  to  reliable  operations  is  constant 
vigilance  and  cleaning  as  needed 

18.45  Gas  Feeders 

The  principal  chemical  found  in  gaseous  form  at  water 
treatment  plants  is  chlorine  Chlonne  is  quite  poisonous  to 
humans  and  must  be  handled  with  great  caution 

18.46  Calibration  of  Chemical  Feeders^^ 

To  ensure  chemical  feed  rates,  liquid-chemical  metering 
pumps  and  dry-chemical  feed  systems  should  be  tested  and 
calibrated  when  first  installed  and  at  regular  intervals  there- 
after. This  section  presents  general  proceaures  for  calibrat- 
ing several  types  of  liquid-  and  dry-chemical  feeders. 

18.460  Large-Volume  Metering  Pumps 

Pumps  metering  chemicals  such  as  liquid  alum  deliver  a 
relatively  large  volume  of  chemical  in  a  short  time  period. 
These  pumps  can  be  accurately  calibrated  with  a  clear 
plastic  sight  tube  and  a  stopwatch  (Figure  18.51). 

To  calibrate  'ine  pump,  fill  the  sight  tube  from  the  chemical 
solution  tank,  then  set  the  valve  so  the  tube  Is  the  only 
source  of  liquid  chemicai  entering  the  pump.  Run  the  pump 
for  exactly  one  minute  (use  the  stopwatch)  at  each  of  five  or 


SIX  representative  settings  of  the  pump-control  scale.  Re- 
cord the  amount  pumped  at  each  setting  as  observed  in  the 
Sight  tube  Use  this  information  to  develop  curves  of  pump 
setting  vs  chemical  dose  in  mg//_  or  chemical  feed  in  gallons 
per  day  for  your  plant  (Figure  18.52). 

The  graph  developed  by  this  process  is  called  a  calibration 
curve  it  can  be  used  to  determine  the  pump  setting  needed 
to  deliver  a  required  chemical  feed  rate,  or  the  commonly 
used  range  of  feed  rates  can  be  marked  in  gallons  per  day 
directly  on  the  pump  control  panel. 

18.461  Small-Volume  Metering  Pumps 

Pumps  metering  a  chemical  such  as  sodium  hexameta- 
phosphate,  a  lime  feed  solubility  enhancer,  feed  a  very  small 
volume  per  day.  The  procedure  for  calibration  of  these 
pumps  IS  similar  to  the  procedure  for  large-volume  units.  For 
very  low  feed  rates,  pumping  times  of  longer  than  one 
minute  may  be  required  to  give  accurately  measurable 
results. 

Once  the  test  data  have  been  recorded,  convert  the  test 
results  to  appropriate  units  and  draw  a  calibration  curve  to 
be  used  as  for  the  larger  pumps. 

18.462  Dry-Chemical  Systems 

Dry-chemical  feed  systems  are  used  for  chemicals  such 
as  activated  cartx)n,  fluoride,  and  lime.  Two  types  of  sys- 
tems are  common,  the  rocker-dump  type  and  the  helix-feed 
type  The  rocker-dump  chemical  feed  uses  a  scraper  moving 
back  and  forth  on  a  platform  located  at  the  bottom  of  a 
hopper  filled  with  dry  chemical  The  platform  may  be  adjust- 
ed up  and  down  to  regulate  the  thickness  of  the  nbbon  of 
chemical,  and  the  length  of  stroke  for  the  scraper  can  be 
adjusted,  usually  by  means  of  an  indicator  on  an  exterior 
arm. 

The  helix-type  feeder  feeds  the  dry  chemical  with  a 
rotating  screw  (helix).  The  feed  rate  is  adjusted  by  varyng 
the  drive-motor  speed.  The  speed  can  usually  be  vaned  from 
0  to  100  percent. 

To  calibrate  either  type  of  feed  system,  choose  five  or  six 
representative  settings  of  the  arm  (rocker-dump)  or  of  the 
motor  speed  control  (helix  type),  and  a,  each  of  the  settings 
catch  the  amount  of  chemical  fed  dunng  a  precisely  meas- 
ured time  interval.  Next,  weight  each  volume  of  chemical  as 
accurately  as  possible  and  convert  the  information  into 
pounds  per  day.  Use  the  data  to  construct  a  calibration 
curve  with  one  axis  representing  feeder  settings  and  the 
other  representing  pounds  per  day.  The  curve  is  used  in  the 
same  manner  as  the  curves  for  licuid-feed  pumps. 

FORMULAS 

To  determine  the  chemical  feed  rate  or  flow  from  a 
chemical  feeder,  we  need  to  know  the  amount  or  volume  fed 
during  a  known  time  period.  The  flow  from  a  chemical  feeder 
can  be  calculated  by  knowing  the  volume  pumped  from  a 
chemical  storage  tank  and  the  time  period. 


Flow,  GPM  = 


or  Flow,  GPM  = 


Volume  Pumped,  gal 
Pumping  Time,  minutes 
(Volume  Pimped,  gal)  (24  hr/day) 
(Pumping  Time,  hour) 


For  additional  information  on  i.^i!.trct.Kjn  of  chemical  feeders,  see  Volume  L  Appendix  Section  A  13h  Chemical  Doses,  pages 
^  567-570. 

ERIC 


333 


•A 
00 


CHEMICAL 
SOLUTION 
TANK 

(CHLORINE,  ALUM,  ETC.) 


CLEAR  PLASTIC 
GRADUATED 
CYLINDER 
MARKED  IN 
MILLILITERS 


5? 


9 
3 

ID 
3 


->-T0  POINT  OF 

CHEMICAL  INJECTION 


 ' 


CHEMICAL 
SOLUTION 
FEED  PUMP 


THE  FEED  RATE  OF  A  CHEMICAL  SOLUTION  FEED  PUMP  CAN  BE  DETERMINED  BY  MEASURING  THE  AMOUNT  OF 
SOLUTION  WITHDRAWN  FROM  A  GRADUATED  CYLINDER  IN  A  GIVEN  TIME  PERIOD.  ALLOW  THE  CYLINDER  TO  FILL  WITH 
SOLUTION.  THEN  CLOSE  THE  VALVE  ON  THE  LINE  FROM  THE  TANK  SO  THE  FEED  PUMP  TAKES  SUCTION  FROM  THE 
CYLINDER  ONLY.  OBSERVE  THE  MILLILITERS  OF  SOLUTION  USED  IN  ONE  MINUTE.  COMPARE  THIS  RESULT  WITH  THE 
DESIRED  FEED  RATE  AND  ADJUST  THE  FEED  PUMP  ACCORDINGLY. 


Fig.  18,51   Calibration  of  a  chemical  feed  pump 


ERIC 


Maintenance  31S 


CHEMICAL  DOSE,  mg/L 

Fig.  18.52  Chemical  feed  pump  settings  for  various  chemical  doses 


Liquid  polymer  feed  rates  are  often  measured  in  pounds 
per  day.  To  calculate  this  feed  rate  we  need  to  know  the 
strength  of  the  polymer  solution  as  a  percent  or  as  milli- 
grams per  liter,  the  specific  gravity  of  the  solution,  the 
volume  pumped  and  the  time  period. 

Polymer  ^  (ppiy  Conc.  mg/L)  (Vol  Pumped,  mi)  (60  min/hr)  (24  hr/day) 
Ibs^day  '  ^^^"^^  Pumped,  mm)  (1000  mL/L)  (lOOO  mg/gm)  (454  gm/lb) 

To  determine  the  actual  feed  from  a  dry  chemical  feeder,  we 
need  to  know  the  pounds  of  chemical  fed  and  the  time 
period. 


Chemical 
Feed, 
lbs/day 


(Chemical  Fed,  lbs)  (60  min/hr)  (24  hr/day) 
Time,  minutes 


EXAMPLE  2 

A  chemical  feed  pump  lowered  the  chemical  solution  in  a 
four-foot  diameter  chemical  storage  tank  two  feet  during  a 
seven-hour  period.  Estimate  the  flow  delivered  by  the  pump 
in  gallons  per  minute  ana  gallons  per  day. 


Known 
Tank  Diameter,  ft  =  4  ft 
Chemical  Drop,  ft  =  2  ft 
Time,  hr  =  7  hr 


Unknown 

Flow,  GPM 
Flow,  GPD 


1.  Determine  the  volume  of  water  pumped  in  gallons, 
volume,  gal  -  (0  785)  (Diameter,  ft)2  (Dron.  ft)  (7  48  gai/cu  ft) 
=  (0  785)  (4  ft)2  (2  ft)  (7  48  gal/cu  ft; 
-  188  gal 


2  Calculate  the  flow  from  the  chemical  feed  pump  in  gallons 
per  minute. 


Flow,  GPM 


Volume  Pumped,  gal 
(Pi-Tiping  Time,  hr)  (60  min/hr) 

188  gal 
(7  hr)  (60  min/hr) 

0  45  GPM 


3  Calculate  the  flow  from  the  chemical  feed  pump  in  gallons 
per  day. 


Flow,  GPD  = 


(Volume  Pumped,  gal)  (24  hr/day) 

Pumping  Time,  hr 
(188  gal)  (24  hr/day) 


7  hr 


-  645  GPD 


320  Water  Treatment 


EXAMPLES 

Determine  the  chemical  feed  in  pounds  of  polymer  per  day 
from  a  chemical  feed  pump.  The  polymer  solution  is  2  C 
percent  or  20,000  mg  polymer  per  liter  Assume  a  specific 
gravity  of  the  polymer  solution  c'  1.0.  During  a  test  run  the 
chemical  feed  pump  delivered  '50  m/_  of  polymer  solution 
during  six  minutes. 

Unknov^n 


Polymer  Feed, 
lbs/day 


Known 

Polymer  Solutio'^.  %  =  2  0% 
Polymer  Cone,  mg/L  -  20,000  mg//. 
Polymer  SpGr         =  1.0 
Volumed  Pumped,  m/_-  750  mL 
Time  Pumped,  mm    =  6  mm 

Calculate  the  polymer  feed  by  the  chemical  feed  pump  in 
pounds  of  polymer  per  day. 

Polymer    (Poiy  Conc.  mg/L)  (Vol  Pumped,  ml)  (60  mm/hr)  (24  hr/clay) 

Feed.  ^   

lbs/day    ^ '  ""^  Pumped,  mm)  (1000  mL/L)  (1 000  mg/gm)  (454  gm/lb) 

_  (20.000  mg/L)  (750  mL)  (60  min/hr)  (24  hr/day) 
(6  mm)  (1000  mL/L)  (1000  mg/gm)  (454  gm/lb) 
-  7  9  lbs  polymer/day 

EXAMPLE  4 

Determine  the  actual  chemical  fed  in  pounos  per  day  from 
a  dry  chemical  feeder  A  pie  tin  placed  under  a  chemical 
feeder  collected  1000  grams  of  chemical  in  five  minutes. 

Known  Unknown 

Dry  Chemical,  gm  =  1000  gm  Chemical  Feed,  lbs/day 
Time,  mm  =  5  mm 

Determine  the  chemical  feed  in  pounds  of  chemical  applied 
per  day. 

*"Feed'^^'  =  (Chemical  Applieo,  gm)  (60  mm/hr)  (24  hr/day) 
lbs/day  (454  gm/lb)  (Time,  mm) 

(1000  gm)  (60  miri/hr)  (24  hr/day) 
(454  gm/lb)  (5  min) 
-  635  lbs/day 

18.47  Chlorinators 

Chlonne  gas  leaks  around  chlorinators  oi  containers  of 
chlorine  will  cause  corrosion  of  equipment  Check  every  day 
for  leaks.  Large  leaks  will  be  detected  by  odor:  small  leaks 
may  go  unnoticed  until  damage  results.  A  green  or  reddish 
deposit  on  metal  indicates  a  chlorine  leak.  Any  chlonne  gas 
leakage  m  the  presence  of  moisture  will  cause  corrosion. 
Always  plug  the  ends  of  any  open  connection  to  prevent 
moisture  from  entering  the  lines.  Never  pour  water  on  a 
chlorine  leak  because  this  will  only  create  a  bigger  problem 
by  enlarging  the  leak.  Chlonne  gas  reacts  with  water  to  form 
hydrochloric  acid. 


WARNING 


> 


Toxic      mi  man^. 


Ammonia  water  will  detect  any  chlorine  leak.  A  small  piece 
of  cloth,  soaked  with  ammonia  water^"*  and  wrapped  around 
the  end  of  a  short  stick,  makes  a  good  leak  detector  Wave 
this  stick  m  the  general  area  of  the  suspected  leak  (do  not 
touch  the  equipment  ^vith  it)  if  chlorine  gas  leakage  is 
occunng.  a  white  cloud  of  ammonium  chloride  will  form  You 
should  make  this  test  at  all  gas  pipe  joints,  both  inside  and 
ou\side  the  chlorinators,  at  regular  intervals.  Bottles  of 
ammonia  water  should  be  kept  tightly  capped  to  avoid  loss 
of  strength.  All  pipe  fittings  must  be  kept  tight  to  avoid  leaks. 
NEW  GASKETS  SHOULD  BE  USED  FOR  EACH  NEW  CON- 
NECTION 


CAUTION 


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PRESENCE:  OP  A^AMV  LeAk:^.40Me 
OPECATO^a^  ^BPBHTO  WAVE  A  -STiCfel  WITH 
A  CLOTK  OM  THeENP  iM  PCOMTOP  TUEM 
WWEMTf^EV  At?E  iO0\^\N6x  C[\LOU.\  ME 


Do  not  use  a  spray  bottle  in  a  room  where  large  amounts 
of  chlcnne  gas  have  already  leaked  into  the  air.  After  one 
squeeze,  the  entire  area  may  be  full  of  white  smoke  and  you 
will  have  troi  jle  locating  the  leak.  Under  these  conditions, 
use  a  cloth  t^oaked  in  ammonia  water  to  look  for  leaks. 

The  exterior  casing  of  chlorinators  should  be  painted  as 
required,  however,  most  chlonnators  manufactured  recently 
have  plastic  cases  ♦hat  do  not  require  protective  coatings.  A 
clean  machine  is  a  better  op^^  itmg  machine.  Parts  of  a 
chlonnator  handling  chlorine  gas  must  be  kept  dry  to  prevent 
the  chlorine  ard  moisture  from  forming  hydrochloric  acid. 
Some  parts  may  be  cleaned,  when  required,  first  with  water 
to  remove  water  soluble  material,  then  with  wood  alcohol, 
followed  by  drying  The  above  chemicals  leave  no  moisture 
residue.  Another  method  would  oe  to  wash  them  with  water 
and  dry  them  over  a  pan  or  heater  to  remove  all  traces  of 
moisture. 

Water  strainers  on  chlorinators  frequently  clog  and  re- 
quire attention  They  may  be  cleaned  by  flushing  with  water 
or.  if  badly  fouled,  they  may  be  cleaned  with  r'llute  hydro- 
chloric acid,  followed  with  a  water  .  mse. 

The  atmosphere  vent  lines  from  nhlormators  must  be 
opeii  and  free.  These  vent  lines  evacuate  the  chlorne  to  the 
outside  atmosphere  when  the  chlonnator  is  being  shut 
down.  Place  a  screen  over  the  end  of  the  pipe  to  keep 
insects  from  building  a  nest  in  the  pipe  and  clogging  it  up. 

When  chlonnators  are  removed  from  service,  as  much 
chlonne  gas  as  possible  should  be  removed  from  the  supply 
lines  and  machines.  The  chlonne  valves  at  the  containers 
are  shut  off  and  the  chlonnator  injector  is  operated  for  a 
penod  to  remove  the  chlonne  gas.  In  "V"  notch  chlonnators, 
the  rotameter  goes  to  the  bottom  of  the  manometer  tube 
when  the  chlorine  gas  has  been  expelled. 

All  chlonnators  will  give  c^  tinuous  t-  )uble-free  operation 
if  properly  maintained  and  operated  ^ach  chlonnator  manu- 
facturer provides  with  each  machine  a  mamtena'^ce  and 
operations  instruction  booklet  with  line  diagrams  showing 
the  operation  of  the  component  parts  of  the  machine. 
Manufacturer's  instructions  should  be  followed  for  mainte- 


24  Use  a  concentrated  ammcma  solution  containing  28  to  30  percent  ammonia  as  NH3  (this  is  the  same  as  58  percent  ammonium  hydrox- 
ide, NH4OH,  or  commercial  26""  Baume). 


Maintenance  321 


nance  and  lubrication  of  your  particular  chlonnator.  If  you  do 
not  have  an  instruction  booklet,  you  may  obtain  one  by 
contacting  the  manufacturer  s  representative  in  your  area 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  327 

18  4A  How  can  an  operator  locate  information  on  how  to 
operate,  control  and  maintain  chemical  feeders'' 

18  4B  List  three  common  types  of  chemical  feeders 

1 8  4C  Why  should  chlorine  leaks  be  detected  and  repaired'' 

18  4D  How  would  you  search  for  chio  .we  leaks'' 

18.5   TANKS  AND  RESERVOIRS^^ 

18.50  Scheduling  Inspections 

Plant  tanks  should  be  drained  and  inspected  at  regular 
intervals  If  the  interior  is  well  protected,  five-year  intervals 
between  inspections  may  be  sufficient  If  the  tank  is  below 
the  surface  of  the  ground,  be  sure  the  groundwater  level  is 
down  far  enough  (below  the  bottom  of  the  tank)  so  the  tanks 
will  not  float  on  the  groundwater  when  empty  or  develop 
cracks  from  groundwater  pressure. 

Schedule  inspections  o<  tanks  and  channels  during  per- 
iods of  low  plant  demand  so  that  plant  operation  won  t  be 
disrupted 

18.51  Steel  Tanks 

All  steel  tanks  must  be  protected  from  rusting  Once  metal 
IS  lost  because  of  rusting,  it  can  t  be  recovered.  The  ex- 
teriors of  the  tanks  are  easily  inspected  —  don  t  forget  the 
roof  —  and  should  be  repainted,  as  needed,  not  only  to 
protect  the  steel  surface  but  to  provide  a  pleasing  appear- 
ar.ce.  The  interiors  of  steel  tanks  are  exposed  to  a  much 
harsher  environment  due  either  to  being  constantly  sub- 
merged or  to  constant  high  humidity. 

Protective  coatings  for  steel  tank  interiors  must  be  care- 
fully selected  to  provide  superior  protection  and  at  the  same 
time  impart  neither  taste  nor  odors  to  the  water  Proper 
surface  preparation  and  application  is  as  important  as  the 
coating  materials  in  getting  interior  protection  that  will  last  a 
reasonable  period  of  time 

When  interior  tank  recoating  is  required,  schedule  the 
work  when  plant  demand  is  low  but  not  dunng  rainy  weather 
when  it  may  be  impossible  to  maintain  a  dry  steel  surface 
warm  enough  to  ensure  proper  curing  of  the  coating.  This 
type  of  work  is  usually  done  by  outside  contrac'.ors.  Con- 
stant inspection  is  a  must  if  the  work  is  go.ng  to  be 
completed  according  to  the  specifications. 

18.52  Cathoaic  Protections^ 

An  alternative  to  repainting  the  submerged  interior  sur- 
faces of  a  steel  water  tank  is  installation  of  a  cathodic 
protection  system.  The  rusting  of  steel  is  accompanied  by 
the  flow  of  small  electrical  currents.  Cathodic  protection 
systems  prevent  rusting  of  bare  steel  surfaces  by  causing 
an  electrical  current  to  flow  from  anodes  hung  in  the  water  to 


the  tank  surface  The  polarity  of  this  current  is  opposite  to 
what  It  would  be  if  rust  were  forming  The  current  can  be 
obtained  from  sacrificial  anodes  that  make  the  tank  into  a 
giant  low  voltage  battery,  or  from  electronic  rectifiers  that 
are  powered  from  the  commercial  power  lines. 

Cathodic  protection  systems  provide  protection  only  so 
long  as  they  are  operat  ng  and  properly  idjusted  Systems 
with  rectifiers  should  be  checked  weekly.  The  inspection 
consists  of  reading  and  record  .  the  DC  volt  and  ammeter 
readings  Compare  the  readings  with  previous  readings  and 
with  the  readings  recommended  by  the  corrosion  engineer 
or  technician  Deviations  from  normal  should  be  investigated 
without  delay 

Once  a  year,  a  corrosion  specialist  should  be  called  in  to 
take  potential  profile  readings  on  the  inside  of  the  tank  and 
to  set  the  rectifier  and  recommend  new  normal  current 
settings.  Over  the  years,  as  more  and  more  of  the  interior 
tank  coating  fails,  the  bare  surface  area  to  be  protected  by 
the  cathodic  protection  system  will  increase.  For  this  reason. 
It  IS  to  be  expected  that  the  current  required  to  provide 
protection  will  increase  m  small  amounts  or  increments  each 
year 

18.53  Concrete  Tanks 

Concrete  tanks  are  not  usually  coated  on  the  inside  and 
are  painted  on  the  exterior  for  appearance  purposes  only. 
This  would  seem  to  indicate  that  maintenance  on  concrete 
tanks  IS  minimal,  but  this  may  not  be  true  Concrete  tanks 
are  all  reinforced  with  steel  Steel  can  rust.  If  too  much  steel 
IS  lost  to  rust,  the  structural  strength  of  the  tank  can  be 
threatened  Periodically  inspect  the  tank  for  signs  of  rusting. 
This  IS  particularly  important  for  pre-stressed  concrete  tanks 
that  have  a  tensioned  wire  wrap  on  the  exterior.  The  wires 
are  small  in  diameter  and  even  a  small  amount  of  rust  could 
reduce  the  size  of  the  wire  to  the  point  where  it  might  faJ. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  w  ^h  those  on  page  327. 

18  5A  How  often  should  tanks  and  reservoirs  be  drained 
and  inspected'' 

1 8  SB  Why  must  the  groundwater  level  be  below  the  bottom 
of  a  tank  before  it  is  drained? 

18  50  What  IS  an  alternative  to  applying  a  protective  coat- 
ing to  prevent  corrosion  of  a  steel  tank'' 

18.6    BUILDING  MAINTENANCE 

Building  maintenance  is  another  program  that  should 
receive  attention  on  a  regular  schedule  Buildings  in  a 
treatment  plant  are  usually  built  of  sturdy  materials  to  last  for 
many  years,  if  they  are  kept  in  good  repair.  In  selecting  paint 
for  a  treatment  plant,  it  is  always  a  good  idea  to  have  a 
painting  expert  help  the  operator  select  the  types  of  paint 
needed  to  protect  the  buildings  from  deterioration.  The 
expert  also  will  have  some  good  ideas  as  to  color  schemes 
to  help  blend  the  plant  in  with  the  surrounding  area.  Consid- 
eration should  also  be  given  to  the  quality  of  paint  A  good 
quality,  more  expensive  material  will  usually  gr'^  better 
service  over  a  longer  period  of  time  than  the  economy-type 
products. 


25>%/so  r.ee  WATER  DISTRIBUTION  SYSTEM  OPERATION  AND  MAINTENANCE,  Chapter  2.  Storage  Facilities,  Section  2.4,  "Mamte- 
nance,"  in  this  series  of  manuals. 

^^Also  see  Chapter  8,  Corrosion  Control,  Section  8.36.  Xatholic  Protectionism  WATER  TREATMENT  PLANT  OPERATION,  Volume  1. 


ERLC 


322   Water  Treatment 


Building  maintenance  programs  depend  on  the  age,  t/oe 
and  use  of  a  building  New  buildings  require  a  thorough 
check  to  be  certain  essential  items  are  available  and  working 
properly  Older  buildings  require  careful  watching  and 
prompt  attention  to  keep  ahead  of  leaks,  breakdowns, 
replacements  when  needed,  and  changing  uses  of  the 
building  Attention  must  be  given  to  the  maintenance  re- 
quirements of  many  items  in  all  plant  buiMings,  such  as 
etectncal  systems,  plumbing,  heating,  coo!'  ^g,  ventilating, 
floors,  windows,  roofs,  and  drainage  around  the  buildings. 
Regularly  scheduled  examinations  and  necessary  mainte- 
nance of  these  Items  can  prevent  many  costly  and  time- 
consuming  problems  in  the  future 

In  each  plant  building,  periodically  check  all  stairways, 
(adders,  catwalks,  and  platforms  for  adequate  lighting,  head 
clearance,  and  sturdy  and  convenient  guardrails  Protective 
devices  should  surround  all  moving  equipment.  Whenever 
any  repairs,  alterations,  or  additions  are  built,  avoid  building 
accident  traps  such  as  pipes  laid  on  top  of  floors  or  hung 
from  the  ceiling  at  head  height,  which  could  create  serious 
safety  hazards. 

Organized  storage  areas  should  be  provided  and  main- 
tained in  an  accessible  and  neat  manner. 

KEEP  ALL  BUILDINGS  CLEAN  AND  ORDERLY.  Janitorial 
work  should  be  done  on  a  regular  schedule.  All  tools  and 
plant  equipment  should  be  kept  clean  and  in  tneir  proper 
place.  Floors,  walls,  and  windows  should  be  cleaned  at 
regular  intervals  in  order  to  maintain  a  neat  appearance.  A 
treatment  plant  kept  in  a  clean,  orderly  condition  makes  a 
safe  place  to  work  and  aids  in  building  good  public  and 
employer  relations. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  327. 

18  6A  What  items  should  be  included  in  a  build-ng  mainte- 
nance program*? 


18  6B  What  factors  influence  the  type  of  building  mainte- 
nance program  that  might  be  needed  for  your  water 
treatment  planf? 

18.7  ARITHMETIC  ASSIGNMENT 

Turn  to  the  appendix  at  the  back  of  this  manual  and  read 
Section  A  35,  'Maintenance  "  Also  work  the  example  prob- 
lems and  check  the  arithmetic  using  your  calculator  You 
should  be  able  to  get  the  same  answers 

18.8  ADDITIONAL  READING 

1.  NEW  YORK  MANUAL,  Chapter  19,  "Treatment  Plant 
Maintenance  and  Accident  Prevention 

2.  TEXAS  MANUAL,  Chapter  13.  "Pumps  and  Measurement 
of  Pumps " 

18.9  ACKNOWLEDGMENTS 

Major  portions  of  this  chapter  were  taken  from  the  follow- 
ing California  State  University,  Sacramento,  Operator  Man- 
uals 

1.  OPERATION  OF  WASTEWATER  TREATMENT  PLANTS 

Volume  11,  Chapter  15,  "Maintenance,"  by  Norman 
Farnum,  Stan  Walton,  John  Brady,  Roger  Peterson 
and  Malcolm  Carpenter. 

2  OPERATION  AND  MAINTENANCE  OF  WASTEWATER 
COLLECTION  SYSTEMS 

Chapter  9,  "Equipment  Maintenance,  "  by  Lee  Doty. 

3.  INDUSTRIAL  WASTE  TREATMENT 
Chapter  7,  "Maintenance,"  by  Roger  Ham. 

OVl 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  18.  MAINTENANCE 

(Lesson  5  of  5  Lessons) 


Write  your  answers  to  these  questions  in  your  notebook 
before  continuing  to  the  objective  test  on  page  327.  The 
question  numbering  continues  from  Lesson  4 

36  What  factors  could  cause  gasoline  engine  starting  prob- 
lems'? 

37.  Why  IS  rust  a  problem  in  water-cooled  systems? 

38  What  IS  the  purpose  of  the  fillers  in  the  diesel  fuel 
system? 


39  What  are  the  advantages  of  air-cooled  diesel  engines  as 
compared  with  water-cooled  types'? 

40  How  should  large  quantities  of  gasoline  be  stored'? 

41  Why  IS  "idling"  not  a  satisfactory  method  of  testi.ig 
standby  engines? 

42  Why  should  ory  chemical  fee^prs  and  hoppers  be  kept 
clean  and  dry? 

43  V\/hat  problems  can  be  caused  by  chlorine  gas  leaks 
around  chlorinators  or  containers  of  chlorine'? 


ERIC 


•6U 


Maintenance  323 


SUGGESTED  ANSWERS 

Chapter  18.  MAINTENANCE 


ANSWERS  TO  QUESTIONS  IN  LESSON  1 

Answers  to  questions  on  page  220 

1 8  OA  A  good  maintenance  program  is  es-  ?ntial  for  a  water 
treatment  plant  to  operate  at  peak  efficiency. 

18  OB  The  most  important  item  is  maintenance  of  the 
mechanical  equipment  —  pumps,  valves,  scrapers, 
and  other  moving  equipment.  Other  items  include 
plant  buildings  and  grounds. 

1 8  OC  A  good  record  system  tells  when  maintenance  is  cue 
and  also  provides  a  record  of  equipment  perform- 
ance. Poor  performance  is  a  good  justification  for 
replacement  o"  new  equipment.  Good  records  help 
keep  your  warranty  in  force. 

18.0D  Both  cards  are  vital  in  a  good  recordkeeping  system. 
The  equipment  service  record  card  is  a  permanent  or 
master  card  that  indicates  when  or  how  often  certain 
maintenance  work  should  be  done.  The  service  rec- 
ord card  IS  a  record  of  who  did  that  work  on  what 
date  and  is  hel?  ul  in  determining  when  the  future 
maintenance  w^ik  is  due. 

18  OE  Emergency  phone  numbers  for  a  treatment  plant 
should  include  the  phone  numbers  for  police,  fire, 
hospital  and/or  physician,  responsible  plant  officials, 
local  emergency  disaster  office,  emergency  team 
and  CHEMTREC.  (800)  424-9300. 

18.0F  A  training  program  for  an  emergency  team  should 
include: 

1.  Use  of  proper  equipment  (self-contained  breath- 
ing apparatus,  repair  kits  and  repair  tools), 

2.  Properties  and  detection  of  hazardous  chemicals, 
3  Safe  procedures  for  handling  and  storage  of 

chemicals, 

4.  Types  of  containers,  safe  procedures  for  shipping 
contain  ..-rs,  and  container  safety  devices, 

5.  Installation  of  repair  devices,  and 

6.  Simulated  field  emergencies 

Answers  to  questions  on  page  221. 

18.1  OA  Unqualified  or  inexperienced  people  must  be  ex- 
tremely careful  when  attempting  to  troubleshoot  or 
repair  electrical  equipment  because  they  can  be 
seriously  injured  and  damage  costly  equipment  if  a 
mistake  is  made. 

18.10B  When  machine  is  not  shut  off.  locked  out,  and 
tagged  properly,  the  follo'vng  accidents  could  oc- 
cur: 

1.  Maintenance  operator  could  be  cleaning  pump 
and  have  it  start,  thus  losing  an  arm,  hand  or 
finger; 

2.  Electrical  motors  or  controls  not  properly 
grounded  could  lead  to  possible  severe  shock, 
paralysis,  or  death;  and 

3.  Improper  circuits  such  as  a  wrong  connection, 
safety  devices  jumped,  wrong  fuses,  or  improp- 
er wiring  can  cause  fires  or  Injunes  due  to 
incorrect  operation  of  machinery. 


Answers  to  questions  on  page  225. 

18  11A  The  two  types  of  current  are  Direct  Current  (D.C.) 
and  Alternating  Current  (A  C  ). 

1 8  1 1 B  Amperage  is  a  measurement  of  work  being  done  or 
"how  hard  the  electricity  is  working." 

18  lie  The  proper  voltage  and  allowable  current  in  amps 
for  a  piece  of  equipment  can  be  determined  by 
reading  the  name  plate  information  or  the  instruc- 
tion manual  for  the  equipment. 


Answers  to  questions  on  page  230. 

18  12A  You  test  for  voltage  by  using  a  voltage  tester 

18  12B  A  voltage  tester  can  be  used  to  test  for  voltage, 
ooen  circuits,  blown  fuses,  single  phasing  of  mo- 
tors and  grounds. 

18.12C  Before  attempting  to  change  fuses,  turn  off  power 
and  check  both  power  lines  for  voltage  Use  a  fuse 
puller. 

18.12D  If  the  voltage  is  unknown  and  the  voltmeter  has 
different  scales  that  are  manually  set,  always  start 
with  the  highest  voltage  range  and  work  down. 
Otherwise  the  voltmeter  could  be  damaged. 

18.12E  Amp  readings  different  from  the  name  plate  rating 
could  be  caused  by  low  voltage,  bad  bearings,  poor 
connections,  plugging  or  excessive  load. 

1 8  1 2F  Motors  and  winngs  should  be  megged  at  least  once 
a  year,  and  twice  a  year  if  possible. 

18  12G  An  ohm  meter  is  used  to  test  the  control  circuit 
components  such  as  coils,  fuses,  relays,  resistors 
and  switches. 


Answers  to  questions  on  page  231. 

18.13A  The  two  types  of  safety  devices  in  main  electncal 
panels  or  control  units  are  fuses  or  circuit  breakers. 

18.13B  Fuses  are  used  to  protect  operators,  wi'  ^,  cir- 
cuits, heaters,  motors,  and  various  other  electrical 
equipment, 

l8.i3C  A  fuse  must  never  be  by-passed  or  jumped  be- 
cause the  fu£.e  may  be  the  only  protection  the 
Circuit  has;  without  it,  serious  damage  to  equipment 
and  possible  injury  to  operators  can  occur. 

18  13D  A  Circuit  breaker  is  a  switch  that  is  opened  auto- 
matically when  the  current  or  the  voltage  exceeds 
or  falls  below  a  certain  limit.  Unlike  a  fuse  that  has 
to  be  replaced  each  time  it  "blows,"  a  circuit  breaker 
can  be  reset  after  a  short  delay  to  allow  time  for 
cooling. 

18.13E  Motor  starters  can  be  either  manually  or  automati- 
cally controlled. 

18.13F  Magnetic  starters  are  generally  used  to  start 
pumps,  compressors,  blowers  and  anything  where 
automatic  or  remote  control  is  desired, 


ERIC 


324   Water  Treatment 


Answers  to  questions  on  page  234. 

18  14A  Electrical  energy  is  commonly  converted  into  me- 
chanical energy  by  electric  motors. 

18.14B  An  electric  motor  usually  consists  of  a  stator,  rotor, 
end  bells,  and  windings. 

1 8  1 4C  Motors  can  be  kept  trouble  free  with  proper  lubrica- 
tion and  maintenance. 

18  14D  Motor  name  plate  data  should  be  recorded,  com- 
pared with  manufacturer's  data  sheets  and  instruc- 
tions, and  placed  in  a  file  for  future  reference.  Many 
times  the  name  plate  Is  painted,  corrodes  or  is 
missing  from  ♦he  unit  when  the  information  is  need- 
ed to  repair  the  motor  or  replace  parts 


18.16D  Symptoms  that  a  power  distribution  transformer 
may  be  in  need  of  maintenance  or  repair  include 
unusual  noises,  high  -  'ow  oil  levels,  oil  leaks  or 
high  operating  temperatures. 


Answers  to  questions  on  page  247. 

1 8  1 7A  Rusted  conduits  are  of  concern  because  they  could 
become  the  source  of  a  spark  which  could  cause  an 
explosion. 

18  17B  Electrical  safety  check  lists  are  used  to  make 
operators  awcre  of  potential  electrical  hazards  in 
their  water  treatment  plant. 


Answers  to  questions  on  page  236. 

18.14E  The  key  to  effective  troubleshooting  is  practical, 
step-by-step  procedures  combined  with  a  common 
sense  approach. 

18  14F  When  troubleshooting: 

A.  Gather  preliminary  information. 

B.  Inspect: 

1.  Contacts, 

2.  Mechanical  parts,  and 

3.  Magnetic  parts. 

18.14G  Types  of  information  that  should  be  recorded  re- 
garding electrical  equipment  mcluc*  even/  change, 
repair  and  test. 

Answers  to  questions  on  page  246. 

18.15A  A  qualified  electrician  should  perform  most  of  the 
necessary  maintenance  and  repair  of  electrical 
equipment  to  avoid  endangering  lives  and  to  avoid 
damage  to  equipment. 

18.15B  The  purpose  of  a  "kirk-key"  system  (one  key  is  used 
for  two  locks)  Is  to  Insure  proper  connection  of 
standby  power  into  your  power  distribution  system. 
The  commercial  power  system  must  be  locked  out 
by  the  use  of  switch  gear  before  the  standby  power 
IS  connected  to  your  power  distnbution  system. 

18.15C  Battery-powered  lighting  units  are  considered  bet- 
ter than  engine-driven  power  sources  because  they 
are  more  economical.  If  you  have  a  momentary 
power  outage,  the  system  responds  without  an 
engine-generator  startup. 

18.150  If  water  lost  from  a  lead-acid  battery  is  replaced 
With  tap  water,  the  impurities  in  the  water  will 
become  attached  to  the  lead  plates  and  shorten  the 
life  of  the  battery. 

Answers  to  questions  on  page  247. 

18.16A  Electricity  Is  transmitted  at  high  voltage  to  reduce 
the  size  of  transmission  lines. 

18  16B  If  outdoor  transforme'-'^  have  exposed  high  voltage 
wires,  the  following  precautions  must  be  taken: 

1.  An  eight  foot  (2.4  m)  high  '-^^nce  is  required  to 
prevent  accessibility  by  un-  ilified  or  unauthor- 
ized persons;  and 

2.  Signs  attached  to  the  fence  must  indicate  "High 
Voltage." 

18.16C  The  treulTient  plant  operator  must  keep  the  exteri- 
or and  surroundings  of  the  switch  gear  clean. 

ERIC 


ANSWERS  TO  QUESTIONS  IN  LESSON  2 

Answers  to  questions  on  page  258 

18.20A  Pieces  of  equipment  and  special  tools  commonly 
found  in  a  pump  repair  shop  include  welding  equip- 
ment, lathes,  drill  press  and  drills,  power  hack  saw, 
flame-cutting  equipment,  micrometers,  calipers, 
gages,  portable  electric  tools,  grinders,  a  forcing 
press,  metal-spray  equipment,  and  sand-blasting 
equipment. 

1 8  21 A  The  purpose  of  a  pump  impeller  is  to  suck  water  in 
the  suction  piping  and  to  throw  water  out  between 
the  impeller  blades. 

1 3  21B  A  suitable  screen  should  be  installed  on  the  intake 
end  of  suction  piping  to  prevent  foreign  matter 
(sticks,  refuse)  from  being  sucked  into  the  pump 
and  clogging  or  wearing  the  Impeller. 

18  21C  Suction  piping  must  be  up-sloping  to  prevent  air 
pockets  from  forming  in  the  top  of  a  pipe  where  air 
could  be  drawn  into  the  pump  and  cause  the  loss  of 
suction. 

18.21D  Cavitation  is  the  formation  and  collapse  of  a  gas 
pocket  or  bubble  on  the  blade  of  an  impeller.  The 
collapse  of  this  gas  pocket  or  bubble  drives  water 
into  the  impeller  with  a  terrific  force  that  can  cause 
pitting  on  the  Impeller  surface. 

18  21 E  An  advantage  of  a  double-suction  pump  Is  that  the 
longitudinal  thrust  from  the  water  entering  the  im- 
peller is  balanced. 

Answers  to  questions  on  page  263, 

18  22A  The  purpose  of  lubrication  is  to  reduce  friction 
between  two  surfaces  and  to  remove  heat  caused 
by  friction. 

18  22B  Oils  in  service  tend  to  become  acid  (contaminated) 
and  may  cause  corrosion,  deposits,  sludging  and 
other  problems. 

18  22C  To  ensure  proper  lubrication  of  equipment,  deter- 
mine the  proper  lubrication  schedule,  lubricant,  and 
amount  of  lubricant  and  prepare  a  lubrication  chart. 

Answers  to  questions  on  page  264 

18  22D  A  soft  grease  has  a  low  viscosity  index  as  com- 
pared with  a  hard  grease. 

18  22E  Oil  IS  used  with  higher  speeds. 

18  22F  Overfilling  with  oil  or  grease  can  result  in  high 

pressures  and  temperatures,  and  ruined  seals  or 

other  components. 


346 


Maintenance  325 


ANSWERS  TO  QUESTIONS  IN  LESSON  3 

Answers  to  questions  ^n  page  272 

18  23A  A  cross-connection  is  a  connection  between  two 
piping  systems  where  an  undesirable  water  (water 
from  water  seal)  could  enter  a  domestic  water 
supply. 

18  23B  Yes.  A  slight  leakage  is  desirable  when  the  pumps 
are  running  to  keep  the  packing  cool  and  in  good 
condition. 

18  23C  To  measure  the  capacity  of  a  pump,  measure  the 
volume  pumped  during  a  specific  time  period 

Volume,  gallons 

v:apacity.  GPM 


or 


Capacity. 


Time,  minutes 


liters     Volume,  liters 


18  23D 


Capacity.  GPM 


sec       Time,  sec 
Volume,  gallons 


Time,  minutes 

(10  ft)  (15  ft)  (1  7  ft)  (7  5  gal/cu  ft) 


5  minutes 


or 


Capacity 


382  5  GPM 


liters    Volume,  liters 


sec       Time,  sec 

(3  m)  (5  m)  (0  5  m)  (1000  L/cu  m) 

(5  minutes)  (60  sec/mm) 
25  liters/sec 

1 8  23E  Before  a  prolongeo  shutdown,  the  pump  should  be 
drained  to  prevent  damage  from  corrosion,  sedi- 
mentation, and  freezing  Also,  the  motor  disconnect 
switch  should  be  opened  to  disconnect  motor 

Answers  to  questions  on  page  274 

18  23F  Shear  pins  commonly  fail  in  leciprocating  pumps 
because  of  (1)  a  solid  object  lodged  under  piston, 
(2)  a  clogged  disc'  Jrge  line,  or  (3)  a  stuck  or 
wedged  valve 

18  23G  A  noise  may  develop  when  pumping  thin  sludge 
due  to  water  hammer,  but  will  disappear  when 
heavy  sludge  is  pumped. 

18  23H  Higher  than  normal  discharge  pressures  in  a  pro- 
gressive cavity  pump  may  indicate  a  line  blockage 
or  a  closed  valve  downstream 

Answers  to  questions  on  page  274 

18.231  When  checking  an  electric  motor,  the  following 
Items  should  be  checked  periodically,  as  well  as 
when  trouble  develops: 

1 .  Motor  condition, 

2.  Note  all  unusual  conditions, 

3.  Lubricate  bearings, 

4.  Listen  to  motor,  and 

5.  Check  temperature. 

1 8.23J  The  purpose  of  a  stethoscope  is  to  magnify  sounds 
and  carry  them  to  the  ear.  This  instrument  is  used 
to  detect  unusual  sounds  in  electric  motors  such  as 
whines,  gratings,  or  uneven  noises. 


Answers  to  questions  on  page  278. 

1 8  23K  A  properly  adjusted  horizontal  belt  has  a  slight  bow 
in  the  slack  side  when  running.  When  idle,  it  has  an 
alive  spnnginess  when  thumoed  with  the  hand, 
vertical  belts  should  have  a  springmeso  when 
thumped.  To  check  for  proper  alignment,  place  a 
straight  edge  against  the  puller  face  or  faces.  If  a 
ruler  won't  work,  use  a  transit  for  long  runs,  or  the 
belt  may  be  examined  for  wear. 

18  23L  Always  replace  sprock(its  v/hen  replacing  a  chain 
because  old.  out-of-pitch  sprockets  cause  as  much 
Cham  wear  in  a  few  hours  as  years  of  normal 
operation 

Answers  to  questions  on  page  280 

18  23M  Improper  original  installation  of  equipment,  settling 
of  foundations,  heavy  floor  loadings,  warping  of 
bases,  and  excessive  bearing  wear  could  cause 
couplings  to  become  out  of  alignment. 

1 8  23N  Shear  pins  are  designed  to  fail  if  a  sudden  overload 
occurs  that  could  damage  expensive  equipment. 

Answers  to  questions  on  page  283. 

1 8  24A  Pumps  must  be  lubricated  in  accordance  with  man- 
ufacturer's recommendations  Quality  lubricants 
should  be  used. 

18  24B  In  lubricating  motors,  too  much  grease  may  cause 
bearing  trouble  or  damage  the  winding 

Answers  to  questions  on  page  283. 

18.24C  If  a  prmp  will  not  start,  check  for  blown  fuses  or 
tnpped  Circuit  breakers  and  the  cause.  Also  check 
for  a  loose  connection,  fuse,  or  thermal  unit. 

1 8  24D  To  increase  the  rate  of  discharge  from  a  pump,  you 
should  lock  for  something  causing  the  reduced  rate 
of  discharge,  such  as  pumping  air,  motor  malfunc- 
tion, plugged  lines  or  valves,  impeller  problems,  or 
other  factors. 


Answers  to  questions  on  page  284. 

18  24E  If  a  pump  that  has  been  locked  or  tagged  out  for 
maintenance  or  repairs  is  started,  an  operator 
working  on  the  pump  could  be  seriously  injured  and 
also  equipment  could  be  damaged. 

1 8  24F  Normally  a  centrifugal  pumo  should  be  tarted  after 
the  discharge  valve  is  o,.ened.  Exceptions  are 
treatment  processes  or  piping  systems  with  vacu- 
ums or  pressures  that  cannot  be  dropped  or  al- 
lowed to  fluctuate  greatly  while  an  alternate  pump 
IS  put  on  the  line.  If  the  pump  is  not  equipped  with  a 
check  valve  and  the  discharge  pressure  is  higher 
than  the  suction  pressure  under  static  conditions, 
the  pump  could  run  backwards  and  cause  damage 
to  the  equipment. 

Answers  to  questions  on  page  286. 

18  24G  Before  stopping  an  ope  ating  pump: 

1  Start  another  pump  (if  appropriate);  and 

2  Inspect  the  operating  pump  by  looking  for  devel- 
oping problems,  required  adjustments,  and 
problem  conditions  of  the  unit. 


347 


326   Water  Treatment 


18  24H  A  pump  shaft  or  motor  will  spin  backwards  if  water 
being  pumped  flows  back  through  the  pump  when 
the  pump  IS  shut  off.  This  will  occur  if  there  is  a 
faulty  check  valve  or  foot  valve  m  the  system. 

18.241  The  position  of  aii  valves  should  be  checked  before 
starting  a  pump  to  ensure  that  the  water  being 
pumped  will  go  where  intended. 

Answers  to  questions  on  page  286. 

18  24 J  The  most  important  rule  regarding  the  operation  of 
positive  displacement  pumps  is  to  NEVER  start  the 
pump  against  a  closed  discharge  valve. 

18.24K  If  a  positive  displacement  pump  is  started  against  a 
closed  discharge  valve,  the  pipe,  valve  or  pump 
could  rupture  from  excessive  pressure.  The  rupture 
will  damage  equipment  and  possibly  seriously  in- 
jure or  kill  someone  standing  nearby. 

18  24L  Both  ends  of  a  sludge  line  should  never  be  closed 
tight  because  gas  from  decomposition  can  build  up 
and  rupture  pipes  or  valves. 


ANSWE"  "  TO  QUESTIONS  IN  LESSON  4 

Answers  to  questions  on  page  289. 

18  25A  Compressors  are  used  with  water  ejectors,  pump 
control  systems  (bubblers),  valve  operators,  and 
water  pressure  systems.  Also  they  are  used  to 
operate  portable  pneumatic  tools  such  as  jack 
hammers,  compactors,  air  drills,  sand  blasters, 
tapping  machines,  and  air  pumps. 

18  25B  The  frequency  of  cleaning  a  suctic  i  filter  on  a 
compress  depends  on  the  use  of  a  compressor 
and  the  atmosphere  around  it.  The  filter  should  be 
inspected  at  least  monthly  and  cleaned  or  replaced 
every  three  to  six  months.  More  frequent  inspec- 
tion, cleaning  and  replacement  are  required  under 
dusty  conditions  such  as  operating  a  jack  hammer 
on  a  street. 

18  25C  Compressor  oil  should  be  changed  at  least  every 
three  months,  unless  manufacturer  states  different- 
ly. If  there  are  filters  .n  the  oil  system,  these  also 
should  be  changed. 

18.25D  Dram  the  condensate  from  the  air  receiver  daily. 

18  25E  Before  testing  belt  tension  on  a  compressor  v;ith 

your  hands,  MAKE  SURE  COMPRESSOR  !S 

LOCKED  OFF. 

Answers  to  questions  on  page  305. 

18.26A  Valves  are  the  controlling  devices  placed  in  piping 
systems  to  stop,  regulate,  check,  divert,  or  other- 
wise modify  the  flow  of  liquids  or  gases. 

18.26E  Six  common  types  of  valves  found  in  water  treat- 
.ent  facilities  include  gate  valves,  globe  valves, 
eccentnc  valves,  butterfly  valves,  check  valves  and 
plug  valves. 

18.260  The  purpose  of  the  check  valve  is  to  allow  water  to 
flow  In  one  direction  only. 

18.26D  Backflow  prevention  by  check  valves  is  essential  in 
many  applications  to: 

1.  Prevent  pumps  from  reversing  when  power  Is 
removed, 

2.  Protect  water  systems  from  being  cross-con- 
.lected, 

O 

ERLC 


3  Aid  in  pump  operation  as  a  dampener,  and 

4  Ensure  "full  pipe"  operation. 

18  26E  The  most  common  maintenance  required  by  gate 
valves  IS  oiling,  tightening,  or  replacing  the  stem 
stuffing  box  packing. 

ANSWERS  TO  QUESTIONS  IN  LESSON  5 

Answers  to  questions  on  page  308. 

18.30A  Gasoline  engines  may  be  used  in  water  treatment 
plants  to  drive  pumps,  generators,  tractors,  and 
vehicles 

18. JOB  If  a  gasoline  engine  will  not  start,  check  the  follow- 
ing Items: 

1  No  fuel  in  tank,  valve  closed. 

2  "arburetor  not  choked, 

3  V/ater  or  dirt  in  fuel  lines  of  carburetor, 

4.  Carburetor  flooded, 

5.  Low  compression, 

6  Loose  spark  plug,  and 
7.  No  spark  at  plug. 

18  30C  A  gasoline  engine  may  not  run  properly  du3  to: 

1  Engine  missmy, 

2.  Engine  surging, 

3.  Engine  stopping. 

4.  Engine  overheating, 

5.  Engine  knocking,  and 

6.  Engine  backfinng  through  carburetor. 

Answers  to  questions  on  page  309. 

1 8.30D  If  a  gasoline  engine  will  not  start  and  the  spark  olug 
IS  wet  with  oil  or  fuel,  this  could  indicate  that  the 
cylinder  is  flooded  with  fuel  by  having  the  choke  on 
too  long. 

1 8  30E  If  a  gasoline  engine  will  not  start  and  there  is  an  oil 
residue  on  the  spark  plug,  this  could  indicate  worn 
piston  rings. 

1 8  30F  After  an  engine  has  started,  give  it  an  opportunity  to 
warm  up  before  applying  the  load. 

Answers  to  questions  on  page  315. 

18  31A  Gasoline  is  not  used  as  a  fuel  in  diesel  engines 
because  It  would  start  to  burn  from  the  heat  gener- 
ated by  compression  before  the  piston  reaches  the 
top  of  the  stroke. 

18.31B  The  four  basic  parts  of  a  diesel  fuel  system  are: 

1.  Primary  fuel  filter, 

2.  Secondary  fuel  filte* 

3.  Fuel  Injection  pump,  and 

4.  Fuel  injector. 

18  31C  The  purpose  of  the  fuel  injection  pun  ^  is  to  deliver 
fuel  to  ♦he  injector  at  a  very  high  pressure. 

18.32A  Heat  Is  removed  from  *Ue  cylinders  by  a  water 
cooling  system.  Each  cylinder  Is  surrounded  with  a 
water  jacket  through  which  the  coolant  (water) 
Circulates  and  pulls  heat  from  the  cylinder.  This  is 
accomplished  by  a  water  pump  that  is  belt-driven 
from  the  crankshaft. 

Answers  to  questions  on  page  316. 

18.33A  The  storage  and  use  of  fuels  for  internal  combus- 
tion engines  nust  be  in  accordance  with  building 
and  fire  marshal  codes. 


Maintenance  327 


18.33B  Four  types  of  fuels  commonly  used  by  internal 
combustion  engines  include  (1)  diesel,  (2)  gasoline, 
(3)  liquified  petroleum  gas  (LPG),  and  (4)  natural 
gas. 

18.34A  Standby  internal  combustion  engines  not  in  regular 
service  should  be  started  up  and  test  run  at  least 
once  a  week. 

1 8.34B  Standby  engines  should  be  test  run  long  enough  fcr 
the  engine  to  come  up  to  its  normal  operating 
temperature.  If  at  all  possible,  the  engine  should  be 
run  under  its  normal  load 

Answers  to  questions  on  page  321. 

18.4A  Information  on  how  to  operate,  control  and  maintain 
chemical  feeders  may  be  found  in  the  feeder  manu- 
facturer's literature. 

18.4B  The  three  common  types  of  chemical  feeders  are  (1) 
solid  feeders,  (2)  liquid  feeders,  and  (3)  gas  feeders. 

18.4C  Chlorine  is  toxic  to  humans  and  will  cause  corrosion 
damage  to  equipment 

18.4D  Large  chlonne  leaks  can  be  detected  by  smell.  Small 
leaks  are  detected  by  soaking  a  cloth  with  ammonia 
water  and  holding  the  cloih  near  areas  where  leaks 
might  develop.  A  white  cloud  will  indicate  the  pres- 
ence of  a  leak. 


Answers  to  questions  on  page  321 

18.5A  Tanks  and  reservoirs  should  be  drained  and  inspect- 
ed at  least  once  every  fjve  years  if  the  interior  is  well 
protected:  more  often  if  it  is  not  well  protected. 

1 8.5B  The  groundwater  level  should  be  below  the  bottom  of 
a  tank  before  tt  is  drained  so  the  tank  will  not  float  on 
the  groundwater  when  empty  or  develop  cracks  from 
groundwater  pressure. 

18.5C  Cathodic  protection  is  an  alternative  to  applying  a 
protective  coating  to  prevent  corrosion  of  a  steel 
tank. 


Answers  to  questions  on  page  322. 

18.6A  A  building  maintenance  program  will  keep  the  build- 
ing in  good  shape  and  includes  painting  when  neces- 
sary. Attention  also  must  be  given  to  electncal  sys- 
tems, plumbing,  heating,  cooling,  ventilating,  floors, 
windows,  and  roofs.  The  building  should  he  kept 
clean,  tools  should  be  stored  in  their  proper  place, 
and  essential  storage  should  be  available. 

18.6B  Factors  that  influence  the  type  of  building  mainte- 
nance program  needed  by  a  water  treatment  plant 
include  the  age,  type  and  use  of  each  building. 


OBJECTIVE  TEST 

Chapter  18.  MAINTENANCE 


Please  mark  correct  answers  on  the  answer  sheet  as 
directed  at  the  end  of  Chapter  1.  There  may  be  more  than 
one  correct  answer  to  the  multiple  choice  questions. 

TRUE-FALSE 

1.  An  Equipment  Service  Card  is  another  name  for  a 
Service  Record  Card. 

1.  True 

2.  False 

2.  Building  maintenace  is  NOT  part  of  a  treatment  plant 
operator's  duties. 

1.  True 

2.  False 

3.  A  treatment  plant  library  should  contain  copies  of  the 
plant's  drawings  and  specifications. 

1.  True 

2.  False 

4.  Pumps  in  water  treatment  plants  are  driven  only  by 
electric  motors. 

1.  True 

2.  False 


5.  If  a  pump  IS  going  to  be  shut  down  for  a  long  period  of 
time,  the  pump  should  be  drained. 

1.  True 

2.  False 

6.  An  empty  clear  well  drained  for  inspection  purposes 
could  f  oat  up  out  of  the  ground  when  the  groundwater 
level  IS  high. 

1.  True 

2.  False 

7  All  gate  valves  have  non-nsing  valve  stems. 

1.  True 

2.  False 

8  The  most  practical  form  of  emergency  lighting  is  that 
provided  by  standby  power  generators. 

1.  True 

2.  False 

9  Standby  power  generators  should  be  operated  once  a 
week  at  full  load. 

1.  True 

2.  False 


ERLC 


34J 


328  Water  Treatment 


10  Diesel  engines  can  use  gasoline  for  fuel. 

1.  True 

2.  False 

11  Diesel  engines  se  spark  plugs 

1.  True 
2  False 

12.  A  qualified  electncian  should  perform  most  of  the  nec- 
essary maintenance  and  repair  of  electncal  equipment 

1.  True 

2.  False 

13.  When  a  pump  is  not  snut  off,  locked  out,  and  tagged 
properly,  a  plant  operator  could  be  maintaining  a  pump, 
the  pump  could  start,  and  the  operator  cuuld  lose  a 
finger. 

1.  True 
2  False 

14  Most  electrical  equipment  does  not  indicate  the  proper 
voltage  on  the  name  plate 

1  True 

2.  False 

15.  Closing  an  electncal  circuit  is  like  closing  a  valve  on  a 
water  pipe. 

1.  True 

2.  False 


MULTIPLE  CHOICE 

16  Which  of  the  following  items  are  parts  of  an  electnc 
motor? 

1.  Impeller 

2.  Rotor 

3.  Stator 
4  Volute 

5.  Windings 

17  Centnfugai  pump  parts  mchide 

1.  Diaphragm. 

2.  Impeller 

3.  Piston 

4.  Rotor 

5.  Volute. 

18.  Wearing  rings  are  installed  in  a  pump  to 

1.  Hold  the  shaft  in  position. 

2.  Keep  the  impeller  in  place. 

3.  Plug  internal  water  leakage. 

4.  Wear  instead  of  Impeller. 

5.  Wear  out  the  sleeves. 

19.  What  could  be  the  cause  of  a  pump's  electnc  motor  not 
starting? 

1.  Fuse  or  circuit  breaker  out 

2.  Incorrect  power  supply 

3.  No  power  supply 

4.  Pump  not  hooked  to  motor 

5.  Rotating  parts  of  motor  may  be  jammed  mechanically 

ERIC 


20.  Equipment  name  plate  data  must  be  recorded  and  filed 
because  the 

1  Filing  caoinet  is  supposed  to  have  this  information. 

2  Information  is  needed  to  order  replacement  parts. 

3  Manufacturer  doesn't  keep  the  information  on  older 
models. 

4  Name  plate  could  become  corroded. 
5.  Name  plate  could  get  lost 

21  Compressor  maintenance  includes 

1.  Cleaning  cylinder  or  casing  fins  weekly. 
2  Examining  the  oil  reservoir  dipstick  or  sight  glass. 
3.  Inspecting  the  suction  filter  of  the  compressor  regu- 
larly 

4  Keeping  the  belts  as  tight  as  possible 

5  Washing  off  the  compressor  weekly. 

22  What  IS  the  purpose  of  an  equipment  preventive  mainte- 
nance program'? 

1  To  extend  equipment  life. 

2  To  insure  proper  and  efficient  operation  of  the  equip- 
ment. 

3.  To  keep  operators  looking  at  equipment. 

4.  To  protect  the  public's  investment  spent  buying  the 
equipment. 

5.  To  provide  jobs  for  operators  when  they  visit  a 
facility. 

23  When  belts  are  used  to  dnve  equipment,  important 
considerations  include 

1 .  Belt  dressing  should  be  used  monthly  for  pliability  of 
belts 

2  Belts  must  be  matched  sets 

3.  Guaros  are  required  on  all  belt  drives  that  are  ex- 
posed. 

4.  Noise  or  squeal  on  startup  can  be  corrected  by 
proper  tension 

5.  Proper  number  of  belts. 

24  Some  of  the  advantages  of  mechanical  seals  over 
packing  include 

1.  Continual  adjusting,  cleaning,  o»  repacking  is  not 
required. 

2.  Lower  initial  cost. 

3  Pump  does  not  have  to  be  dismantled  for  repair. 

4  They  last  longer,  thus  resulting  in  labor  savings. 

5.  Usually  there  isn't  any  damage  to  shaft  sleeve  when 
they  need  replacing. 

25  Wnat  information  must  be  on  a  warning  tag  attached  to 
a  locked  out  switch? 

1.  Directions  for  removing  tag 

2.  Name  of  company  that  printed  tag 
3  Name  of  equipment 

4.  Signature  of  person  who  locked  out  switch  and  who 
IS  only  person  authonzed  to  remove  tag 

5.  Time  to  unlock  switch 

26  Operators  should  not  do  actual  electncal  repairs  or 
troubleshooting  because 

1 .  Costly  damage  can  be  done  to  equipment  by  unauth- 
onzed  persons. 

2.  It  IS  too  dangerous. 

3.  Many  are  not  adequately  trained 

4.  They  realize  their  own  limitations  regarding  electrical 
work. 

5.  This  IS  a  highly  specialized  field. 


350 


Maintenance  323 


27.  If  a  pump  wiH  not  start,  check  for 

1 .  Loose  terminal  connections 

2.  Nuts,  bolts,  scrap  iron,  wood,  or  plastic  in  the  wrong 
places 

3.  Shaft  binding  or  sticking 

4.  Tripped  circuit  breake  s. 

5.  Water  in  the  wet  weh. 

28.  How  can  a  chlonne  leak  be  detected*^ 

1 .  By  an  explosiometer 

2.  By  checking  the  rotameter 

3.  By  waving  an  ammonia-soaked  rag 

4.  deen  or  reddish  deposits  on  metal 

5.  Smell 

29  What  can  heppen  if  you  DO  NOT  penodical'y  dram  and 
inspect  plant  tanks  and  channels? 

1 .  An  emergency  situation  may  develop  dunng  a  period 
of  high  demand. 

2.  Costly  repairs  could  result. 

3.  Senous  maintenance  problems  could  develop. 

4.  The  operator  will  not  know  if  cracks  are  developing  in 
underground  tanks  and  channels. 

5.  The  operator  will  stay  out  of  trouble. 

30  Pump  maintenance  includes 

1 .  Checking  operating  temperature  of  bearings. 

2.  Checking  packing  gland. 

3.  Lubricating  the  impeller. 

4.  Operating  two  or  more  pumps  of  the  same  si/e 
alternately  to  equalize  wear. 

5.  Preventing  all  water  seal  leaks  around  packing 
glands 

31  Preventive  ma.ntenance  of  electric  motors  includes 

1.  Checking  temperature  of  motor. 

2.  Frequently  starting  and  stopping  the  motor  to  give  it 
a  rest. 

3.  Keeping  motor  free  from  dust,  dirt  and  moisture. 

4.  Keeping  motor  outdoors  where  it  can  stay  cool. 

5.  Lubricate  bearings. 

32.  Maintenance  of  gate  valve  includes 

1 .  Lubricating  bearing. 

2.  Lubricating  with  Prussian  Blue. 

3.  Operating  inactive  valves  to  prevent  sticking. 

4.  Refacing  leaky  valve  seats. 

5.  Tightening  or  replacing  the  stem  stuffing  box  pack- 
ing. 


33 


34. 


Proper  selection  of  an  emergency  lighting  unjt  for  a 
particular  location  requires  careful  consideration  of 
which  of  the  following  items'^ 

1.  Costs 

2.  Lighting  requirements 

3.  Nearness  of  vendor  to  repair  failures 

4.  Necessary  switch  gear 

5.  Type?  of  batteries 

Possible  causes  of  a  gasoline  engine  not  starting  in- 
clude 

1. 
2. 
3. 
4. 
5. 


Carburetor  choked. 
Carburetor  floodea. 
Loose  spark  plugs. 
SparK  at  plug. 

Water  in  fuel  lines  of  carburetor. 


ERIC 


35.  The  ignition  system  for  a  gasoline  engine  consists  of  the 

1  Battery 

2.  Coil. 

3.  Distnbutor 

4.  Filter 

5.  Thermostat. 

36.  If  a  compressor  fails  to  operate  or  provide  rated  capac- 
ity, what  could  be  the  cause  of  the  problem*? 

1  Air  cleaner,  cap  and/or  screen  clogged 

2  Air  used  by  compressor  is  polluted 

3.  Engine  fails  to  develop  proper  RPMs 

4.  Faulty  oil  seal 

5.  Pressure  regulator  improperly  adjusted 

37.  Maintenance  of  automatic  valves  includes 

1  Adjusting  the  check  valve. 

2  Cleaning  any  strainers  in  the  pilot  control  system. 
3.  Determining  if  controls  are  properly  positioning 

valve. 

If  valve  IS  inactive,  manually  exercise  valve  from  tight 
shut  to  wide  open  position. 
5  Reversing  the  flow  through  the  valve. 

38  Problems  that  may  be  encountered  when  storing  gaso- 
line include 

1.  Deterioration  of  gasoline  stored  for  a  iong  time. 

2  Easy  starting  of  engines. 

3  Gasoline  leaking  into  an  underground  water  supply. 

4  Lack  of  gummy  deposits  on  parts  of  the  fuel  system. 

5  Water  leaking  into  the  gasoline  storage  tank. 

39.  Steel  tanks  may  be  protected  from  rusting  by 

1.  Alternately  wetting  and  drying  walls. 

2.  Cathodic  protection. 

3  Maintaining  humidity  in  tank 

4  Protective  coatings. 

5  Washing  tank  walls. 

40  Equipment  service  cards  and  service  record  cards 
should 

1.  Identify  the  piece  of  equipment  that  the  record  card 
represents. 

2.  Indicate  the  work  done. 

3  Indicate  the  work  to  be  done. 

4  Maintain  selective  service  records. 

5  Record  sick  leave. 

41  Estimate  the  pumping  capacity  of  a  pump  in  gallons  per 
minute  if  1 1  minutes  are  required  for  the  water  level  in  a 
tank  to  drop  3  feet.  The  tank  is  6  feet  in  diameter. 

1  8GPM 

2.  10GPM 

3.  36  GPM 
4  58  GPM 
5.  74  GPM 

42  Calculate  the  feed  rate  of  a  dry  chemical  feeder  in 
pounds  per  day  if  two  pounds  of  chemical  are  caught  in 
a  weighing  tin  dunng  nine  minutes. 

1 .  320  lbs/day 

2.  2394  lbs/day 

3.  2670  lbs/day 

4.  2660  lbs/day 

5.  3200  lbs/day 


35.1 


CHAPTER  19 

INSTRUMENTATION 

by 

Leonard  Ainsworth 


332  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  19  Instrumentation 


Page 

OBJECTIVES  334 

GLOSSARY   335 

SYMBOLS    339 

LESSON  1 

19.0  Importance  and  Nature  of  Measurement  and  Control  Systems  342 

19.00  Need  for  Understanding  Measurement  and  Control  Systems  342 

19.01  Importance  to  Waterworks  Operator  342 

19.02  Purpose  and  Naiu.c  '^f  the  Measurement  Process  342 

19  03    Explanation  of  Control  Systems   343 

19.1  Safety  Hazards  of  Instrumentation  Work   345 

19.10    Be  Careful  345 

19  11     Electrical  Hazards   345 

19  12    f\/1echanical  Hazards . .     347 

19  13    Vaults  and  Other  Confined  Spaces   348 

19  14     Falls  348 

19.2  Measured  Variables  and  Types  of  Sensors/Transmitters   348 

19.20    How  Variables  are  Measured     348 

19  21     Pressure  349 

19  22     Level  349 

19.23  Flow  (Rate  of  Flow  and  Total  Flow)  356 

19.24  Chemical  Feed  Rate  360 

19.25  Process  Instrumentation    360 

19.26  Signal  Transmitters/Transducars  360 


Instrumentation  333 


LESSON  2 

19.3  Categories  of  Instrumentation   ....   363 

19.30  Measuring  Elements        363 

19.31  Panel  Instruments  363 

19  310  Indicators  . .   363 

19  311   Indicators/Recorders    363 

19  312  Recorders  364 

19  313  Totalizers   367 

19  314  Alarms    367 

19.32  Automatic  Controller  368 

19.33  Pump  Controllers   368 

19.34  Telemetemg  Links  (Phone  Lines)  369 

19  35     Air  Supply  Systems  371 

19  36     Laboratory  Instruments   374 

19.37    Test  and  Calibration  Equipment      374 

19.4  Operation  and  Preventive  Maintenance    375 

19.40     Proper  Care  of  Instruments  375 

19  41     Indications  of  Proper  Function   375 

19.42    Startup/Shutdown  Considerations   378 

19  43     Maintenance  Procedures  and  Records  379 

19.44  Operational  Checks  379 

19.45  Preventive  Maintenance     379 

19.5  Additional  Reading   380 

Suggested  Answers  .       ...  .   381 

Objective  Test    383 


334  Water  Treatment 


OBJECTIVES 

Chapter  19.  INSTRUMENTATION 

Following  completion  of  Cnapter  19,  you  should  be  able 
to: 

1  Explain  the  purpose  and  nature  of  measurement  and 
control  systems, 

2.  Identify,  avoid  and  correct  safety  hazards  associated  with 
instrumentation  work, 

3.  Recognize  various  types  of  sensors  and  transducers, 

4.  Operate  and  maintain  measurement  and  control  instru- 
ments, 

5.  Read  instruments  and  make  proper  adjustments  in  oper- 
ation of  waterworks  facilities,  and 

6.  Determine  location  and  cause  of  measurement  and  con- 
trol system  failures  and  take  corrective  action. 


Instrumentatioh  335 


GLOSSARY 

Chapter  19.  INSTRUMENTATION 


ACCURACY  ACCURACY 
How  closely  an  instrument  measures  the  true  or  actual  value  of  the  process  variable  being  measure  or  sensed. 

ALARM  CONTACT  ALARM  CONTACT 

A  switch  that  operates  when  some  pre-set  low,  high  or  abnormal  condition  exists. 

ANALOG  ANALOG 
The  readout  of  an  "istrunent  by  a  pointer  (or  other  indicating  means^  against  a  djal  or  scale. 

ANALYZER  ANALYZER 

A  device  wh'ch  conducts  periodic  or  continuous  measurements  of  some  factor  such  as  chlorine,  fluoride  or  turbid'ty.  Analyzers 
operate  by  any  of  several  methods  including  photocells,  conductivity  or  complex  instrumentation. 

CALIBRATION  CALIBRATION 
A  procedure  which  checks  or  adjusts  an  instrument's  accuracy  by  comparison  with  a  standard  of  reference 

CONTACTOR  CONTACTOR 
An  electrical  switch,  usually  magnetically  operated. 

CONTROL  LOOP  CONTROL  LOOP 

The  path  through  the  control  system  between  the  sensor,  which  measures  a  process  variable,  and  the  controller,  which  con- 
trols or  adjusts  the  process  variable. 

CONTROL  SYSTEM  CONTROL  SYSTEM 

A  system  which  senses  and  controls  its  own  operation  on  a  close,  continuous  basis  in  what  is  called  proportional  (or 
modulatjng)  control. 

CONTROLLER  CONTROLLER 
A  device  which  controls  the  starting,  stopping,  or  operation  of  a  device  or  piece  of  equipment. 

DtSICCANT  'OESS-uh-kant)  DESlCCANT 
A  drying  agent  which  is  capable  of  removing  or  absorbing  moisture  from  the  atmosphere  in  a  small  enclosure 

DESiCCATIO:.  (DESS-uh-KAY-shun)  DESICCATION 
A  process  used  to  thoroughly  dry  air;  to  remove  virtually  all  moisture  from  air. 

DETECTION  lAG  DETECTION  LAG 

The  time  period  between  the  moment  a  change  is  made  and  the  moment  when  such  a  change  is  finally  sensed  by  the  associat- 
ed measuring  instrument. 

DIGITAL  READOUT  DIGITAL  READOUT 

The  ust  of  numL>ers  lu  indicate  the  value  or  measurement  o^  a  variable.  The  readi/Ut  of  an  instrument  by  a  direct,  numerical 
reading  of  the  measured  value. 

EFFECTIVE  RANGE  EFFECTIVE  RANGE 

That  portion  of  the  design  range  (usually  upper  90  percent)  in  which  an  instrument  has  acceptable  accuracy.  Also  see  RANGE 
^  ^ndSPAN. 


ERIC  -  3  Do' 


336  Water  Treatment 


FEEDBACK  FEEDBACK 

The  circulating  action  between  a  sensor  mesuring  a  process  variable  and  the  controller  which  controls  or  adjusts  the  process 
variable 

HERTZ  (HURTS)  HERTZ 

The  number  of  complete  electromagnetic  cycles  or  waves  in  one  second  of  an  electrical  or  electronic  circuit  Also  called  the  fre- 
quency of  the  current  Abbreviated  Hz. 

INTEGRATCn  INTEGRATOR 

A  device  or  meter  that  continuously  measures  ana  calculates  (adds)  total  flows  in  gallons,  million  gallons,  cubic  feet,  or  some 
other  unit  of  volume  measurement.  Also  called  a  TOTALIZER. 

INTERLOCK  INTERLOCK 

An  electrical  switch,  usually  magnetically  operated  Used  to  interrupt  all  (local)  power  to  a  panel  or  device  when  the  door  is 
opened  or  the  circuit  is  exposed  tc  service. 

LEVEL  CONTROL  LEVEL  CONTROL 

A  float  device  (or  pressure  switch)  which  sensec  changes  in  a  measured  variable  and  opens  or  closes  a  switch  in  response  to 
that  change  In  its  simplest  form,  this  control  might  be  a  floating  ball  connected  mechanically  to  a  switch  or  valve  such  as  is 
used  to  stop  water  flow  into  a  toilet  when  the  tank  is  full. 

LINEARITY  (LYNN-ee-AIR-it-ee)  LINEARITY 

How  closely  an  instrument  measu  ^--^  actual  values  of  a  variable  through  its  effective  range,  a  measure  used  to  determine  the 
arc-jracy  of  an  instrument. 

MEASURED  VARIABLE  MEASURED  VARIABLE 

A  characteristic  or  component  part  that  is  sensed  and  quantified  (reduced  to  a  reading  of  some  ktnd)  by  a  primary  element  or 
sensor. 

OFFSET  (or  DROOP)  OFFSET 

The  difference  between  the  actual  value  and  the  desired  value  (or  set  point),  characteristic  of  proportional  controllers  that  do 
not  incorporate  reset  action. 

PRECISION  PRECISION 

Tne  ability  of  an  instn-ment  to  measure  a  process  variable  and  to  repeatedly  obtain  the  same  result.  The  ability  of  an  instrument 
to  reproduce  the  same  results 

PRESSURE  \        JL  PRESSURE  CONTROL 

A  switch  which  operates  on  changes  in  pressure  Usually  this  .s  a  diaphragm  pressing  against  a  spring.  When  the  force  on  the 
diaphragm  overcomes  the  spring  pressure,  the  switch  is  actuated  (activated). 

PRIMARY  ELEMENT  PRIMARY  ELEMENT 

The  hydraulic  structure  used  to  measure  flows.  In  open  channels  weirs  and  flumes  are  primary  elements  or  devices.  Venturi 
meters  and  orifice  plates  are  the  primary  elements  in  pipes  or  pressure  conduits. 

PROCESS  VARIABLE  PROCESS  VARIABLE 

A  physical  or  chemical  quantity  which  is  usually  measured  and  controlled  in  the  operation  of  a  water  treatment  plant  or  industri- 
al plant. 

RANGE  RANGE 

The  spread  from  minimum  to  maximum  values  tha*  an  instrument  is  designed  to  measure.  Also  see  EFFECTIVE  RANGE  and 
SPAN. 

RECEIVER  RECEIVER 
A  device  which  indicates  the  value  of  a  measurement  Most  receivers  in  the  water  utility  field  use  either  a  fixed  scale  and  mov- 
able indicator  (pointer)  such  as  a  pressure  gage  or  a  moving  chart  with  movable  pen  such  as  on  a  circular-flow  recording  chart. 
Also  called  an  INDICATOR. 

RECORDER  RECORDER 
A  device  that  creates  a  permanent  record,  on  a  paper  chart  or  magnetic  tape,  of  the  changes  of  some  measured  variable. 

ERIC  35/ 


Instrumentation  337 


REFERENCE  REFERENCE 
A  physical  or  chemical  quantity  whose  value  is  known  exactly,  and  thus  is  used  to  calibrate  or  standardize  instruments 

ROTAMETER  (RODE-uh-ME-ter)  ROTAMETER 

A  device  used  to  measure  the  flow  rate  of  gases  and  liquids.  The  gas  or  liquid  being  measured  flows  vertically  up  a  tapered 
calibrated  tube.  Ii  .side  the  tube  is  a  small  ball  or  a  bullet-shaped  float  (it  may  rotate)  that  rises  or  falls  depending  on  the  flow  rate 
The  flow  rate  may  be  read  on  a  scale  behind  or  on  the  tube  by  looking  at  the  middle  of  the  ball  or  at  the  widest  part  or  top  of  the 
float. 

SENSOR  SENSOR 
An  instrument  that  measures  (senses)  a  physical  condition  or  vanable  of  interest  Floats  and  thermocouples  are  examples  of 
sensors. 

SET  POINT  SET  POINT 

The  position  at  which  the  control  or  controller  is  set  This  is  the  same  as  the  desired  value  of  the  process  variable 

SOFTWARE  PROGRAMS  SOFTWARE  PROGRAMS 

Computer  programs,  the  list  of  instructions  that  tell  a  computer  how  to  perform  a  given  task  Some  software  programs  are  de- 
signed and  written  u  Tionitor  and  control  distribution  systems  and  water  treatment  processes 

30LEN0ID  (SO-lu-noid)  SOLENOID 
A  magnetically  (electrical  coil)  operated  mechanical  device.  Solenoids  oan  operate  pilot  valves  or  electrical  switches 

SPAN  SPAN 
The  scale  or  range  of  values  an  instrument  is  designed  to  measure.  Also  see  RANGE. 

STANDARD  STANDARD 

A  physical  or  chemical  quantity  whose  value  is  known  exactly,  and  is  used  to  calibrate  or  standardize  instruments  Also  see 
REFERENCE 

STANDARDIZE  STANDARDIZE 

To  compare  with  a  standard.  (1)  In  wot  chemistry,  to  find  out  the  exact  strength  of  a  solution  by  comparing  with  a  standard  of 
known  strength.  This  information  is  used  to  adjust  the  strength  by  adding  more  water  or  more  ct  the  substance  dissolved  (2)  To 
set  up  an  instrument  or  device  to  read  a  standard.  This  allows  you  to  adjust  the  instrument  so  that  it  reads  accurately,  or  en- 
ables you  to  apply  a  correction  factor  to  the  readings. 

STARTERS  STARTERS 

Devices  used  to  start  up  motors.  Special  motor  starters  gradually  start  large  mo^'^rs  to  avoid  severe  mechanical  shock  to  a  driv- 
en machine  and  to  prevent  disturbance  to  the  electrical  lines  (causing  dimming  and  flickering  of  lights) 

TELEMETRY  (tel-LEM-uh-tree)  TELEMETRY 
The  electrical  link  between  the  transmitter  and  the  receiver  Telephone  lines  are  commonly  used  to  serve  as  the  electrical  link 

THERMOCOUPLE  THERMOCOUPLE 

A  heat-sensing  device  made  o.'  two  conductors  of  different  metcils  jOined  at  their  ends  A  thermoelectncal  current  is  produced 
when  there  is  a  difference  in  temperature  between  the  ends. 

TIME  LAG  TIME  LAG 

The  time  required  foi  processes  and  control  systems  to  respond  to  a  signal  or  to  reach  a  desired  level 

TIMER  TIMER 
A  device  for  automatically  starting  or  stopping  a  machine  or  other  device  at  a  given  time 

TOTALIZER  TOTALIZER 

A  device  or  meter  that  continuously  measures  and  calculates  (adds)  total  flows  m  gallons,  million  gallons,  cuDic  feet  or  some 
other  unit  of  volume  measurement.  Also  called  an  INTEGRATOR. 

TRANSDUCER  (trans-DUE-sir)  TRANSDUCER 

A  device  which  senses  some  varying  condition  and  converts  it  to  an  electrical  or  other  signal  for  transmission  to  some  other  de- 
vice (a  receiver)  for  progressing  or  decision  making. 


ERIC  ^^-i 


338  Water  Treatment 


TURN-DOWN  RATIO  TURN-DOWN  RATIO 

The  ratio  of  the  design  range  to  the  range  of  acceptable  accuracy  or  precision  of  an  instrument.  Also  see  EFFECTIVE  RANGE. 
VARIABLE.  MEASURED  V^^^I^BLE.  MEASURED 

A  factor  (flow,  temperature)  that  is  sensed  and  quantified  (reduced  .o  a  reading  of  some  kind)  by  a  primary  element  or  sensor. 
VARIABLE.  PROCESS  ^^^,^3^,  p^O^^SS 

du?Sarplant  ^^^"^'^^^  ^"^"^'^^  ""^"^^  '®  ^^^^''^  -measured  and  ccntrolled  in  the  operation  of  a  water  treatment  plant  or  an  in- 


ERIC 


S'oj 


Instrumentation  339 


SYMBOLS 

Chapter  19.  INSTRUMENTATION 


Special  symbols  are  used  for  simplicity  and  clarity  on 
circuit  drawings  for  instruments.  Usually  instrument  manu- 
facturers and  design  engineers  provide  lists  of  symbols  they 
use  with  an  explanation  of  the  meaning  of  each  symbol.  This 
section  contains  a  list  of  typical  instrumentation  abbrevia- 
tions and  symbols  used  in  this  chapter  and  also  used  by  the 
waterworks  profession. 

ABBREVIATIONS 

A  —  Analyzer,  such  as  used  to  measure  a  water  quality 

indicator  (pH,  lemperature). 
C  —  Controller,  such  as  a  device  used  to  start,  operate  or 

stop  a  pump. 

D  —  Differential,  such  as  a  "differential  pressure"  or  D.  P. 

cell  used  with  a  flow  meter. 
E  —  Electrical  or  Voltage. 

Element,  such  as  a  primary  element. 
F  —  Flow  rate  (A/OTtof^l  flow). 
H  —  Hand  (manual  operation). 

High  as  in  hi-level. 
I    —  Indicator,  such  as  the  indicator  on  a  flow  recording 

chart. 

I  =  E/R  where  I  is  the  electrical  current  in  anr.ps. 
L  —  Level,  such  as  the  level  of  water  in  a  tank. 
Low,  as  in  a  lo-level  switch. 
Light,  as  in  indicator  light. 


M  —  Motor. 

Middle,  as  in  a  mid-level  switch. 
P  —  Pressure  (or  vacuum). 

Pump. 

Program,  as  in  a  software  program. 
Q  —  Quantity,  such  as  a  totalized  volume    for  summation 
is  also  used). 

R  —  Recorder  (or  printer),  such  as  a  chart  recorder. 

Receiver. 

Relay. 
S  —Switch. 

Speed,  such  as  an  increase  in  the  RPM  (revolutions 

per  minute)  of  a  motor. 
Starter,  such  as  a  motor  starter. 
Solenoid. 
T  —  Transmitter 
Temperature. 
Tone. 
Valve. 
Voltage. 
Weir;;it. 
Watt. 

X  —  Special  or  unclassifft^d  variable. 
Y  —  Computing  function,  such  as  a  square-root  {\:'  ) 
extraction. 

Z  —  Position,  such  as  a  percent  valve  opening. 


V  — 


w 


TYPICAL  SYMBOLS 


Pressure  transmitter  #1 


Level  indicator-recorder  #2 


3. 


ERLC 


Flow  indicator-controller  #3  with 
hi-low  control  switches 


3Gj 


340  Water  Treatment 


4. 


Flow  rate  computer 
and  indicator-transmitter 
4-  20  ma  D.C 


Flow  recorder 
and  totalizer 
(loop  r/4) 


FE-6 

CX3 


He  d  valve  #5  10. 


Flow  element  (tube)  #6 


Relay  #1 


N.O. 


R1-1        Contacts  Normally  Open 
N.C. 


R1-2      Contacts  Normally  Closed 


CV  -  7 


7 


Electric  control  valve  #7 


11. 


^  ^^Y^  Pneumatic  control  valve  #8 


12. 


Hi 


Hi-level 

Indicator  light  (red) 


VW\A 

100 


Resistor 
100  ohms 


9. 


pH 


Analyzer  (pH)  transmitter 
(either  at  location  9  or  the  pH 
level  IS  at  9) 


13. 


If    480  V'  AC  Y, 

UjuuuuuJ 


Transformer 
Jstep-down) 


110  V  AC 


ERIC 


36i 


instrumentation  341 


14. 


15. 


S-1 


OFF       Switch  #1  (SPST)* 


ON 


S-2 


Switch  #2  (DPST)* 


19. 


10A 


1A 


O.L. 


20A 


FUSES 

10  amp  cartridge 


1  amp  line  fuse 


overload  contacts 


20  amp  circuit  breaker 


16. 


S-3 


Switch  #3  (SPOT)* 


17 


PB-1 


L.O.S. 


PB-2 


Push  button  switches 
#1  push  tc  rrake 

#2  push  to  ureak 

Lock-out  stop  safety 
fc  iture 


20. 


L2  (OR  N) 
o 


Line  1  and  Line  2 

(neutral) 
with  duplex  outlet 


110  V  AC 


18. 


H 


O 


A 


Hand  switch 


Hand  —  Off  —  Automatic 


21. 


M  \  Electric  motor,  3  phase 
25  HP )    power  25  horsepower 


*  SPST  means  Single  Pole,  SingleThrow 
DPST  means  Double  Pole,  Single  Throw 
SPOT  means  Single  Pole,  Double  Throw 


ERLC 


342  Water  Treatment 


CHAPTER  19.  INSTRUMENTATION 

(Lesson  1  of  2  Lessons) 


19.0   IMPORTANCE  AND  NATURE  OF  MEASUREMENT 
AND  CONTROL  SYSTEMS 

19.00   Need  for  Understanding  Measurement  and  Control 
Systems 

In  this  chapter,  you  will  learn  some  basic  concepts  about 
waterworks  measurement  instruments  and  their  associated 
control  systems.  Since  the  water  treatment  plant  operator 
frequently  must  monitor,  and  sometimes  control,  the  distri- 
bution system  suppliea  from  the  plant,  both  in-plant  and 
field-type  instrumentation  will  be  discussed.  You  will  be- 
come generally  acquainted  with  the  WHAT,  HOW,  and  WHY 
Instrument  systems  measure,  and  how  some  measured 
quantities  are  controlled  automatically.  However,  this  chap- 
ter IS  not  intended  to  teach  you  how  to  "fix"  a  malfunctioning 
instrument,  though  some  general  preventive  maintenance 
steps  are  incluaed  in  the  discussion. 

Your  understanding  of  the  measurement  and  control  bas- 
ics presented  here  enhance  the  efficient  and  effective  oper- 
ation of  your  plant  and/or  system.  Specifically,  if  you  can 
recognize  a  meter  as  faulty  (by  the  way  the  pointer  acts,  for 
example),  your  treatment/distribution  decisions  will  then  be 
based  upon  that  knowledge  rather  than  a  blind-faith-in-the- 
b?ack-box  attitude  you  might  otherwise  have  to  assume. 


Also,  the  operator  who  recognizes  the  general  operating 
principles  of  typical  instrumentation  systems  is  prepared  to 
perform  not  only  routine  preventive  maintenance,  but  also  to 
take  the  minor  corrective  action  sometimes  really  necessary 
to  keep  the  system  operating.  The  operator  who  knows 
enough  to  free  a  stuck  pen,  safely  replace  a  fuse,  or  dram  an 
air  line  can  avoid  a  lot  of  personal  worry  and  the  expense  of 
an  electrician's  service  call  while  still  protecting  the  oper- 
ational integrity  of  the  plant  or  system. 

19.01   Importance  to  Waterworks  Operator 

In  a  real  sense,  measurement  instruments  can  be  consid- 
ered extensions  of  your  human  senses,  comparable  in  many 
ways  to  your  own  wide-ranging  and  exact  eyes  and  ears. 
The  associated  automatic  control  systems,  in  turn,  are  like 
having  extra  sets  of  far-reaching  and  strong  hands,  to 

ERIC 


constantly  and  precisely  manipulate  valves,  motors  and 
switches.  In  effect  then,  instrumentation  provides  you  with  a 
staff  of  hard-working  assistants,  always  on  the  job  to  help 
you  operate  your  plant  and  system  easily.  If  you  have  failed 
to  adequately  appreciate  the  advantages  of  automation, 
consider  the  alternative  methods  of  operating  your  plant.  For 
example,  in  the  recent  past,  or  for  some  older  operations  in 
existence  today,  the  situation  described  in  the  following 
paragraph  could  have  occurred. 

You  have  a  complete  and  unrestorable  power  failure  in  the 
circuit  which  supplies  all  of  the  instruments  and  control 
systems  in  your  conventional  water  filtration  plant.  As  the 
operator  you  must  try  to  keep  the  plant  on-line  manually  by 
controlling  influent  and  effluent  flows,  basin  levels,  pump 
operation,  chemical  feeders,  and  filter  valves.  You  must  do 
all  of  this  by  watching  and  listening,  and  running  to  manipu- 
late valves,  start  and  stop  pumps,  and  reset  chemical 
feeders.  Even  if  you  could  do  it  (and  some  Nights  on  shift  It 
seems  like  that  IS  what  you  have  to  do)  for  a  small  plant,  you 
certainly  couldn't  exercise  close  control  and  do  it  for  a  long 
time.  If  you  are  trying  to  operate  a  larger  plant,  continued 
operation  would  be  impossible  without  the  instrumentation 
systems  functioning.  Accordingly,  you  would  do  well  to 
familiarize  yourself  now  with  these  "eyes.  ears,  and  hands" 
that  are  so  essential  to  your  effective  performance  as  a 
professional  waterworks  operator. 

19.02  Purpose  and  Nature  of  the  Measurement  Process 

Instrument  capabilities  can  greatly  extend  our  range  of 
personal  observations.  They  also  have  an  additional  and 
quite  important  advantage  over  our  senses  in  that  instru- 
ments provide  quantitative  or  measurable  information, 
whereao  only  qualitative  information  is  available  from  our 
senses.  That  is  to  say,  instruments  provide  us  with  numbers; 


the  direct  senses  can  only  tell  us  that  an  observation  is 
"more  than"  or  less  than"  what  the  observation  was  the  last 
time  it  was  recently  observed.  Some  very  simple  water 
supply  operations  can  and  do  get  by  with  such  imprecise 

3t)j 


Instrumentation  343 


visual  observations  of  a  chemical  process,  rate  of  flow,  or 
basin  level.  However,  modern  water  facilities  must  operate 
"by  the  numbers"  so  to  speak,  and  only  instrumentation  can 
provide  these  numbers  (Figure  19.1). 

A  measurement  is.  by  definition,  the  companson  of  the 
quantity  or  PROCESS  VARIABLE,'^  in  question  to  an  accept- 
ed standard  nnit  of  measure.  Certain  basic  units  of  length, 
volume,  weigut,  and  time  have  been  agreed  upon  by  interna- 
tional convention  to  serve  3s  "primary  standards."  All  meas- 
urements of  length  (levels  area,  volume,  capacity,  weight, 
pressure,  and  rate  of  flow  encountered  in  waterworks  prac- 
tice ultimately  refer  to  these  standards.  Thus,  the  weight  of  a 
100-pound  sack  oi'  chemicals,  for  instance,  amounts  to  100 
times  that  of  the  standard  pound;  or,  the  capacity  of  a  tank 
could  be  1000  times  larger  than  the  standard  gallon.  Some 
important  terms  often  encountered  in  measurement  practice 
v/ill  be  discussed  in  '.he  following  paragraphs. 

ACCURACY  refers  to  hovj  closely  an  instrument  deter- 
mines the  true  or  actual  value  of  the  process  variable  being 
measured.  Accuracy  depends  upon  the  PRFCISION,  or 
general  quality  and  condition  of  the  instrument,  as  well  as 
upon  its  CALIBRATION.  An  instrument  is  calibrated  in  order 
to  standardize  its  measurements.  That  is,  the  instrument 
Itself  IS  nade  to  measure  the  value  of  a  standard  unit  or 
reference  and  its  indicator  is  adjusted  aoCordlngiy.  STAN- 
DARDIZATION \s  a  simple  calibration  procedure  done  regu- 
larly (by  the  operator).  Most  instruments  are  accurate  to 
about  one  or  two  parts  in  one  hundred;  this  is  expressed  as 
±  1  to  2  percent  error  (or  at  times  98  to  99  percent  accuracy). 
The  RANGE  of  an  instn  ment  is  the  spread  between  the 
minimum  and  the  maximum  value  of  the  variable  it  is 
designed  to  measure  accurately.  The  EFFECTIVE  RANGE  is 
that  portion  of  its  complete  range  within  which  acceptable 


accuracy  can  be  expected,  usually  from  10  to  90+  percent  of 
its  nominal  (des'3n)  r^nge,  though  it  is  technically  not  the 
same  LINEARITY  r  ''^rs  to  how  closely  the  instrument 
measures  actual  valuer  of  the  vanable  through  its  effective 
range,  and  thus  bears  upon  its  stated  accuracy.  An  ANALOG 
readout  of  an  instrument  has  a  pointer  (or  other  indicating 
means)  reading  against  a  dial  or  scale,  a  DIGITAL  display 
provides  a  direct,  numerical  reading. 

QUESTIONS 

Write  your  answers  m  a  notebook  ana  then  compare  your 
answers  with  those  on  page  381. 

19.0A  How  can  measurement  instruments  be  considered 
an  extension  of  your  human  senses? 

19.0B  What  water  treatment  processes  and  equipment 
could  be  monitored  or  controlled  by  measurement 
and  control  systems? 

1 9.0C  What  is  an  advantage  of  instruments  over  our  human 
senses? 

19.0D  What  IS  an  analog  readout? 

19.03  Explanation  of  Control  Systems 

The  terms  "controller"  and  "control  s^  tems^'are  used  in 
the  waterworks  field  in  two  different  senses.  The  electrical 
panel  which  controls  only  the  starting/stopping  of  an  electric 
motor  IS  referred  to  as  "controller.**  This  controller  may 
control  a  pump's  operation  or  a  chemical  feeder  motor.  The 
control  exercised  may  be  manual,  through  push-buttons  or 
switches,  or  a^  tomatic  with  a  switch  responding  to  c  alue  of 
level,  p''essure,  or  other  variable  —  such  as  is  usually  the 
case  with  a  "Hanc'-Off-Automatic'  (H.O.A.)  function  switch. 


^  Process  Vanable.   A  physical  or  chemical  quantity  which  /s  usually  measured  <ind  controlled  m  the  operation  of  a  water  treatment  plant 
or  industrial  plant 

ERIC  .  ■■ 


344  Water  Treatment 


This  type  of  so-called  controller  is  more  correctly  termed  a 
motor  control  station  or  panel,  and  will  be  discussed  later. 
The  other,  technically  proper,  usage  o?  the  terms  controller 
and  control  system  identify  a  system  which  senses  and 
controls  its  own  operation  on  a  close,  continuous  basis,  m 
what  Is  called  proportional  (or  modulating)  control  This  type 
of  true  controller  will  be  discussed  first  (Figure  19.2). 

in  order  for  a  process  vanable,  whether  pressure,  level, 
w  ^ight,  o  fiDw.  to  he  closely  controlled,  it  must  be  measured 
precisely  and  continuously.  The  measuring  device  sends  a 
signal  (electrical  or  pneumatic,  as  discussed  in  a  following 
section)  proportional  to  the  value  o.'  the  vanable.  to  the 
actual  controller.  Within  the  controller,  the  signal  is  com- 
pared to  the  ^<5ired  or  set-point  value  (Figure  19.3).  A 
difference  between  the  actual  and  desired  values  results  in 
the  Controller  sending  out  a  command  signal  to  the  "con- 
trolled element,"  usually  a  valve,  pump,  or  feeder.  Such  an 
*"error  signar  produces  an  adjustment  in  the  system  that 
causes  a  corresponding  change  in  the  original  measured 


variable  making  it  more  closely  match  the  set-point.  This 
continuous  "cut  and  try"  process  can  result  in  very  fine  on- 
going control  of  variables  requinng  constant  values,  such  as 
some  flow  rates,  pressures,  levels,  or  chemical  feeds  The 
term  applied  to  this  circulating  action  of  the  variable  in  such 
a  controller  is  FEEDBACK,  The  path  .  .rough  the  control 
system  is  the  CONTROL  LOOP,  The  internal  settings  o^  ^he 
♦nje  controller  can  be  quite  critical  since  close  ccuiol 
c  'nds  upon  sensitive  adjustments.  Thus,  you  should  not 
'  ,  (O  adjust  any  such  control  system  unless  you  know 
exactly  what  you  are  doing.  Many  plant  and  system  oper- 
ations have  been  drastically  upset  due  to  such  efforts, 
however  well  intentioned,  of  unqualified  personnel. 

Examples  of  the  above  proportional  control  of  waterworks 
operations  which  may  be  encountered  are:  (1)  chlorine 
residual  analyzer/controller;  (2)  chemical  feed;  flow-paced 
(open  loop);  (3)  pressure-  or  flow-regulating  valves;  (4) 
continuous  level  control  of  filter  basins;  and  (5)  variable- 
speed  pumping  systems  for  flow/level  control. 


FLOW 

RECORDER/CONTROLLER 


FLOW 
TOTALIZER 


□QQDSGQ 


_i_  SET 
1  POINT 

FLOW 
SIGNAL 


4  PROCESS  N 
I  CONTROL  ) 
^FEEDBACK) j 


1 CONTROL 
SIGNAL 


VALVE 
ACTUATOR 


CONTROLLED 
FLOW 


PIPELINE 


*  D.P.  TYPE 


V/ATER 
—  FLOW 
(VARIABLE) 


CONTROL 
VALVE 
(F!NAL 
ELEMENT) 

NOTE   ELECTRIC  SYSTEM  SHOWN  MAY  BE  PNEUMATIC  ALSO 
*  D.P.  MEANS  "DIFFERENTIAL  PRESSURE" 


FLOW 
METER 
(PRIMARY  ELEMENT) 


Fig.  19.2  Automatic  control  system  diagram,  flow 
(closed  loop  proportional) 


Instrumentation  345 


The  MOTOR  CONTROL  STATU  .  v^igures  19.4  and  19.5), 
as  mentioned,  essentially  provides  only  for  on-off  operation 
of  an  electric  motor,  which  in  turn  powers  a  pump,  valve,  or 
chemical  feeder.  Primarily  it  is  a  standard  electric  motor 
panel,  with  manual  operation  push-buttons,  overload  relays, 
and  function  switch  (H.O.A.  or  Hand-Off-Automatic).  Addi- 
tionally It  may  include,  in  good  electrical  design  practice, 
provisions  for  power  failure  or  loss-of-phase  ("fail-safe" 
circuitry),  and  such  protective  devices  as  high  or  low  pres- 
sure/temperature/level cut-off  switches.  For  this  type  of 
panel  even  to  be  considered  a  controller  (within  our  second- 
ary meaning  of  the  term),  its  operation  must  be  controlled  by 
the  value  or  values  of  some  variable,  not  merely  by  a  device 


NOTE:  Controller  in  photo  is  the  lower  instrument  with  s  t 
point  at  10  MOD. 

Fig,  19.3  Photo  of  flow  recorder/controller  m  Fig,  19.2 


such  as  a  timer  In  other  words,  it  must  be  turned  on  and  off 
as  a  result  of  a  measurement  of  a  level,  pressure,  flow, 
chemical  concentration,  or  other  variable  which  reaches  a 
predetermined  setting.  In  the  automatic  mode  (A  on  the 
H.O.A.  switch)  then,  its  operation  is  In  fact  automatic  in  the 
sense  that  the  variable  is  controlled,  even  though  the  limits 
of  Its  value  are  quite  wide  compared  to  those  attainable  with 
a  true  controller  as  previously  described.  Whereas  a  filter 
basin  level  controller  may  allow  only  an  inch  or  so  of  water 
level  change,  an  on-cff  system  might  operate  within  a  few 
feet  of  level  difference.  In  many  applications,  however,  such 
wide  control  is  of  no  particular  disadvantage,  and  some- 
times is  even  oesirable  (such  as  with  a  distribution  system 
reservoir  level).  However,  one  problem  with  level  controllers 
in  some  water  treatment  plants  is  that  small  changes  in  the 
water  level  over  the  filters  will  cause  the  effluent  controller  to 
modulate  suddenly.  In  cases  of  rising  levels  the  effluent 
valve  will  open  suddenly  and  turbid  water  from  within  the 
filter  may  be  discharged  as  treated  water. 

Terms  used  in  control  practice  can  be  now  defined  oper- 
ationally in  this  paragraph.  FEEDBACK  and  CONTROL 
LOOP  have  been  mentioned  previously,  however,  the  term 
CONTROL  LOOP  needs  qualification.  An  OPEN-LOOP  con- 
trol system  controls  one  variable  on  the  basis  of  another.  A 
good  example  of  this  is  a  chlonnator  "paced"  by  iiov  signals 
(rather  than  by  the  chlorine  residual  analyzer).  CLOSED- 
LOOP  control  remains  as  discussed  previously,  the  true 
controller.  PROPORTIONAL-BAND.  RESET  and  DERIVA- 
TIVE act'ons  are  adjustments  of  the  controller  that  bear 
upon  effectiveness  and  speed  of  control  action.  OFFSET  \s 
the  difference  between  the  desired  value  of  the  variable  (the 
SET-POINT)  and  the  controlled  (actual)  value.  DETECTION 
LAG,  common  to  chlonnator  control  systems,  refers  to  the 
prolonged  period  between  the  moment  when  a  change  in 
control  IS  effected  and  the  moment  when  such  change  is 
finally  sensed  by  the  associated  measunng  instrument 


QUESTIONS 

Write  you.  answers  m  a  notebook  and  then  compare  your 
answers  with  those  on  page  381. 

19.0E  What  does  an  on-off  type  "controller"  control? 

19.0F  List  three  examples  of  "proportional  control"  m 
waterworks  operations. 

19.0G  What  IS  the  purpose  of  a  motor  control  station*? 


19.1    SAFETY  HAZARDS  OF  INSTRUMENTATION  WORK 

19.10  Be  Careful 

The  general  pnnciples  for  safe  performance  on  the  job, 
summed  up  as  always  avoiding  unsafe  acts  and  correcting 
unsafe  conditions,  apply  as  much  to  instrumentation  work 
as  to  otiier  plant  operations.  However,  there  are  some 
special  dangers  associated  with  instrument  systems,  mainly 
electrical  shock  hazards,  that  merit  special  mention  in  this 
section.  Repetition  is  well  justified  for  the  sake  of  safe 
practice! 

19.1 1  Electrical  Hazards 

A  hidden  aspect  of  energized  electrical  equipment  is  that  it 
"coKS  normal,"  that  is,  there  are  no  obvious  signs  that  tend 
to  discourage  one  from  touching.  In  fact,  there  seems  to  be  a 
peculiar  fascination  to  "see  if  it's  really  live"  by  touching 
circuit  components  with  a  tool,  often  a  screwdriver  (usually 


346  Water  Treatment 


A 

OS 
HOA 
HP/LP 
LOS 
PB 
R 

SW 

L1/L2 


—  ELECTRICAL  W!RE 

—  MECHANICAL  LINK  ("GANGED") 
AMPERE:  100A  (RATING) 

DISCONNECT  SWITCH  /"H,  SS_ 

HAND-OFF-AUTO:  J  oo 
HiGH/LOW  r  "ESSURE  I  *  •  5S_ 


RELAy 
CONTACTS 


LOCK-OUT  STOP 
PUSH-BUTTON: 

relay;  l^iA^f^^^^^ 

CO 

SWI  I  UM;  open CLOSED 

LINE  1  (HOT)   2  (NEUTRAL) 
VAC  POWER    60  HZ  3jrf  VOLTS  AC  (60  CYCLES,  3  PHASE  ) 
CB  CIRCUIT  BREAKER  (MAGNETIC) 

MS  MOTOR  STARTER  (CONTACTOR) 

AUX  AUXILIARY  CONTACTS 


L1        120  VAC  60  HZ  1  jOr 

(FROM  CONTROL  TRANS.) 


CONTROL 
CIRCUIT 


POWER 
CIRCUIT 


DOOR  INTER- 
LOCK 


FUSE 


ON 


SPACE  HEATER 

H^!!^JlJl^LJb-- 


CB 


OFF 


TO 
^L2 


480  VAC 
60  HZ 

100A 
SERVICE 


TEST 


I!- 

R1-b 


LO.S 


START 

_li 


Rl-a  * 


100  A 

<5> 


MAIN 
DISCONNECT 


OS 


CONTROL 
CIRCUIT 
TRANS. 


♦holding  CONTACTS 
STOP  RELAY 


MS-AUX. 

HI  


-OPERATING 
HOURS  METER 


MOTOR  ON 

LITE 


CONTACTS 
OVERLOAD  PROTECTION 


x^HEATERf 


MSI -A 


H3 


MS2-B 


MS3-C 


MOTOR' 
25  HP 


Fig.  19.4  Motor  control  panel 
(simplified  double-line  schematic) 


Instrumentation  347 


Fig.  19.5  Photo  of  motor  control  panel 


having  an  insulated  handle,  fortunately)  but  f'ven  with  the 
finger  Only  training,  coupled  with  bad  expenbiice  at  times, 
IS  effective  m  squelching  this  morbid  curiosity  Even  so,  most 
practicing  electricians'  tools  have  an  "arc-mark  trademark' 
or  two.  evidence  of  the  need  for  continuing  self-discipline  in 
this  area  Though  such  mention  may  conjure  up  humorous 
images  of  the  maintenance  person's  surpnse  and  "shock" 
upon  such  an  incident,  one  only  need  consider  that  electrical 
shock  can  and  does  regularly  cause  disfigurement  and  even 
death  (by  asphyxiation  due  to  paralysis  of  the  muscles  used 
in  breathing  and/or  burning)  to  bring  the  problem  into  sober 
perspective.  Also,  the  expense  and  effort  caused  by  a 
needless  shorting-outof  anelectrical  device  could  be  signifi- 
cant. The  point  is,  RESIST  THE  URGEto  "test"  any  electrical 
device  with  a  tool  or  part  of  your  body' 

If  there  is  ANY  doubt  in  your  mind  that  ALL  sources  of 
voltage  (not  merely  ths  local  switch)  have  been  switched  off. 
then  DON  T  TOUCH,  except  possibly  with  the  ,  .obes  of  a 
test  meter  Remember,  you  can't  "see"  even  the  highest 
voltage,  and  an  unverified  presumption  of  a  dead  circuit  is 
worthless  and  may  be  deadly 

Do  not  simulate  a  known  electrical  action,  for  example 
pressing  down  a  relay  armature,  within  an  electncal  panel 
without  a  POSITIVE  understanoing  of  the  circuitry.  Your 
innocent  action  may  cause  an  electrical  "explosion'  to  show- 
id 

ERIC 


er  you  with  molten  metal  or  startle  you  into  a  bumped  head 
or  elbow,  or  a  bad  fall.  Again  the  adage,  WHEN  IN  DOUBT 
—  DON'T. 

Usually  the  operator  does  not  have  the  test  equipment  nor 
the  technical  knowledge  to  correct  an  electncal  malfunction, 
other  than  possibly  resetting  a  circuit  breaker,  regardless  of 
how  critical  the  device  s  function  is  to  plant  operations. 
Though  the  foregoing  applies  mainly  to  motor  control  cen- 
ters, there  also  may  be  a  shock  hazard  within  measurement 
instiument  cases  —  and  the  sure  destruction  of  expensive 
components  —  when  the  foolhardy  lool-touch-test"  is  used. 

Most  oanels  have  an  INTERLOCK  on  the  door  that  inter- 
rupts (local)  power  to  a  panel  or  device  when  the  door  is 
opened  or  the  circuit  is  exposed  for  service  Do  not  discon- 
nect or  disable  interlocks  that  interrupt  all  (local)  power. 
Warning  labels,  insulating  covers  (over  "hot"  terminals), 
safety  switches,  lock-outs,  and  other  safety  provisions  on 
electncal  equipment  must  be  used  at  all  times.  Your  atten- 
tion to  this  crucial  aspect  of  your  work  place  may  save  a  life, 
and  as  the  slogan  goes,  it  could  be  your  own! 

CUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  381 

19.1  A  What  are  the  general  pnnciples  for  safe  performance 
on  the  job'? 

19  IB  How  can  electncal  shock  cause  death'? 

1 9  1 C  What  could  happen  to  you  as  a  result  of  an  electncal 
'explosion'?' 


19.12  Mechanical  Hazards 

There  exists  a  special  danger  when  working  around 
powered  mechanical  equipment,  such  as  electric  motors, 

3S3 


348  Water  Treatment 


valve  operators,  and  chemical  feeders  which  are  operated 
remotely  or  by  an  automatic  control  system  Directly  stateo. 
the  machinery  may  START  or  MOVE  when  you  are  not 
expecting  it'  Most  devices  are  powered  by  motors  with 
enougn  torque  or  RPM  to  severely  injure  anyone  in  contact 
with  a  moving  part  Even  when  the  exposed  rotating  or 
meshing  elements  are  fitted  with  "guards"  in  compliance  with 
safety  regulations,  a  danger  may  exist  A  motor  started 
remotely  may  catch  a  shirt  tail,  finger,  or  tool  hanging  near  a 
loose  or  poorly-f:tted  shaft  guard 

The  sudden  automatic  operation  of  equipment,  even  if 
half-expected,  may  startle  one  nearby  into  a  fall  or  slip. 
Signs  indicating  that  "This  equipment  may  start  at  anytime" 
tend  to  be  ignored  after  a  while  Accordingly,  you  must  stay 
alert  to  the  fact  tha»  any  automatic  device  may  begin  to 
operate  at  any  time,  even  if  by  "off-chance  "  You  must  stay 
well  clear  of  automatic  equipment,  especially  when  it  is  not 
operating. 

Lock-out  devices  on  electncal  switches  must  be  respect- 
ed at  all  times.  The  electrician  who  inserts  one  to  physically 
preveiii  ihe  operation  of  an  electncal  circuit  is,  in  effect, 
trusting  his  life  and  health  to  the  d-*^vice.  Once  the  lock-out 
device  is  attached  to  the  switch  (whether  the  switch  is 
tagged-off  or  actually  locked  with  lock  and  key),  the  electri- 
cian will  consider  the  circuit  de-energized  and  safe  and  will 
feel  free  to  work  on  it.  Consider  the  potential  consequences 
then  of  an  unauthonzed  operator  who  removes  a  lock-out  to 
place  needed  equipment  back  Into  service,  presuming  the 
electrician  is  finished  (as  might  occur  after  several  hours' 
work).  The  point  cannot  be  overstressed: 

A^  IF  A  LIFg-  l^Bl^rtZUf^BOroWO. 

IT  MAY  WELL  BE, 

Operators  often  use  power  tools  on  instrumentation  and 
associated  equipment.  All  power  tools  present  not  o,nly  a 
shock  hazard,  waterworks  being  damp  places  at  times,  but  a 
mechanical  hazard  as  well.  The  use  of  power  tools  in  the 
performance  of  instrumentation  work,  with  its  special  na- 
ture, should  wait  until  the  operator  can  have  an  observer  on 
hand  in  case  of  an  accident. 

19.13  Vaults  and  Other  Confined  Spaces 

Included  as  part  and  parcel  of  measurement  and  control 
systems  are  those  remotely  installed  sensors  and  control 
valves.  Quite  often  these  are  founo  in  meter  or  valve  vaults, 
or  other  closed  concrete  structures.  There  are  some  special 
precautions  beyond  those  stated  in  Chapter  20,  "Safety  '  Be 
sure  the  ventilation  equipment  is  working  properly  before 
entering  The  use  of  power  tools,  including  a  soldering  iron, 
can  be  even  more  dangerous  in  wet  environments.  NEVER 
stand  in  water  with  a  power  tool,  even  when  off.  Brace 
yourself,  if  necessary,  in  such  a  way  that  electrical  current 
cannot  flow  from  arm  to  arm  in  case  of  an  ungrounded  tool. 
Shocks  through  the  upper  body  involve  your  heart  and/or 
your  head,  whose  importance  to  you  is  self-evident! 

19.14  Falls 

All  the  general  safety  measures  to  guard  the  operator 
against  falls,  a  leading  cause  of  lost-time  accidents,  are 
covered  in  Chapter  20,  "Safety,"  and  need  not  be  repeated  m 
this  instrumentation  chapter  However,  if  one  considers  that 


an  electrical  shock  of  even  minor  intensity  can  result  in  a 
serious  fall,  a  special  mention  herein  is  justified.  When 
working  above  ground  on  a  ladder,  even  though  you  position 
It  safely,  use  the  proper  non-conductive  type  (such  as 
fiberglass),  are  duly  cautious  on  the  way  up,  and  comply  with 
all  other  considerations  of  safety,  a  slight  shock  can  still  rum 
all  your  precautions!  When  required  t^  do  preventive  mainte- 
nance from  a  ladder,  turn  off  tha  power  to  the  equipment  if  at 
all  possible  If  not  feasible,  take  special  care  to  stay  out  of 
contact  with  any  component  inside  the  enclosure  of  a 
measuring  or  operating  mechanism,  and  well  away  from 
terminal  stnps,  unconduited  wiring  ,and  "black-boxes " 
Though  not  commonly  considered  essential,  the  wearing  of 
thin  rubber  or  plastic  gloves  can  reduce  your  chances  of 
electric  shock  markedly  (whether  on  a  ladder  or  off), 

Make  provisions  for  carrying  tools  or  other  required 
objects  on  an  electrician's  belt  rather  than  in  your  hands 
when  climbing  up  or  down  ladders  Finally,  never  leave  tools 
or  any  object  on  a  step  or  platform  of  the  ladder  when  you 
climb  down,  even  temporarily.  YOU  might  be  the  one  upon 
whom  they  fall  if  the  ladc'er  is  moved  or  even  steadied  from 
below  In  this  regard,  it  is  always  a  good  idea  (even  if  not 
required)  for  preventive  maintenance  personnel  to  wear  a 
hard  hat  whenever  working  on  or  near  equipment,  especially 
when  a  ladder  must  be  used 


QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
ansvvers  with  those  on  page  381. 

19.1  D  Why  should  operators  be  especially  careful  when 
working  around  powered  automatic  mechanical 
equipment? 

19  IE  What  IS  the  purpose  of  an  electrical  lock  out  device"? 

19  1 F  Why  should  you  brace  yourself  when  operating  pow- 
er equipment  so  that  electrical  current  cannot  flow 
from  arm  to  arm  in  case  of  an  ungrounded  tooP 

19  1G  What  kind  of  specific  protective  clothing  items  couli 
be  wom  to  protect  you  fiom  electrical  shock? 


19.2    MEASURED  VARIABLES  AND  TYPES  OF 
SENSORS/TRANSMITTERS 

19.20   How  Variables  are  Measured 

A  measured  vanable  is  any  quantity  which  is  sensed  and 
oujntitied  (reduced  to  a  reading  of  some  kind)  by  a  prima-y 
element  ur  sensor.  In  waterworks  practice  pressure,  levei, 


Instrumentation  349 


and  flow  are  the  most  common  .neasured  variables,  some- 
fmes  chemica)  feed  rates  and  some  •'•hyslcai  or  "emical 
water  quality  c  ^2r2cterlst»cs  are  also  ^sed 

The  sensor  Is  often  a  transc'ucer  ome  type,  in  that  it 
converts  energy  of  one  kind  into  some  v^ther  fomi  to  produce 
a  readout  or  signal,  For  example,  one  type  of  flow  meter 
converts  the  hydraulic  action  of  the  wai  r  Into  the  mechani- 
cal motions  necescary  to  dnve  a  meter  ifidicator,  and  also 
into  an  electrical  signal  for  a  remote  readout  device.  If  such  a 
signal  is  produced,  be  ,  electric  or  (..leumatic,  the  sensor  is 
then  considered  a  transmitter. 

The  signal  produced  is  frequently  not  a  continuous  one 
proportional  to  the  variable  (such  as  an  analog  signal),  but 
merely  a  switch  which  is  set  to  detect  when  the  variable  goes 
above  or  below  pre-set  limits.  In  this  type  of  on-off  contrc', 
the  pre-determined  setfngs  are  called  control  points.  This 
distinction  between  continuous  and  set-point  operation 
bears  upon  the  two  types  of  controllers  discussed  previous- 
ly. The  remainder  of  this  section  discusses  each  of  the 
common  variables  sensed  in  waterworks  practice. 

19.21  Pressure 

Since  pressure  is  defined  as  a  force  per  unit  of  area 
(pound  per  squa«'e  Inch  or  klloPaScal),  you  might  expect  that 
sensing  pressure  would  entail  the  movement  of  some  flexi- 
ble element  subjected  to  a  force.  In  fact,  that  is  how  pressure 
is  always  measured.  Such  pressure  elements  (a  class  of 
primary  elements)  consists  of  strain  gages  and  mechanically 
deformable  devices  such  as  the  Bourdon  tube  (Figures  19.6 
and  19  7),  bellows,  and  diaphragm  arrangements.  The  slight 
motion  each  exhibits,  prooortional  to  the  applied  force,  is 
then  amplified  mechanically  by  levers  or  gears  to  position  a 
pointer  on  a  scale  or  to  provide  an  input  for  an  associated 
transmitter.  (NOTE:  A  "blind"  transmitter,  of  any  variable,  has 
no  local  indicator.)  Again,  the  sensing  of  pressure  can  take 
place  only  at  important  points,  such  a-i  with  pump  control 
systems. 

There  being  many  classes  and  brands  of  pressure  sen- 
sors, It  serves  no  purpose  to  elaborate  further  on  specific 
types.  Some  sensors  are  fitted  with  surging  and  overrange 
protection  (dampeners)  to  limit  the  effect  pressure  spikes  or 
water  hammer  have  on  the  sensor.  Most  protection  devices 
function  by  restrictinQ  flow  into  the  sensing  element.  Surge 
protection  equipment  prevents  sudden  pressure  'urges 
from  overranging  instrumentation  which  can  easily  .amage 
many  pressur*^  sensors.  One  type  of  overrange  protection 
uses  a  mechanical  device  to  prevent  the  pressure  element 
from  exceeding  its  upper  limit.  The  actual  degree  of  protec- 
tion necessary  depends  on  the  type  and  range  of  the  sensor. 

A  second  surge  piui?ctlon  device  is  a  snubber  (Figuie 
19.8)  which  consists  of  a  restrictor  through  which  the 
pressure  producing  fluid  must  flow.  A  simple  restrictor  is 
made  of  a  short  section  of  capillary  (very  small)  tubing  fitted 
into  a  plug  in  the  pressure  pipe  to  lorm  an  orifice.  A  more 
elaborate  mechanical  snubber  responds  to  surges  by  mov- 
i'^g  a  pbton  or  plunger  that  effectively  controls  the  <?ize  of 
the  orif  oe.  Some  snubbers  are  subject  to  cloggii  q  or  being 
sdjusted  so  tight  as  to  prevent  any  response  at  an  to 
pressure  changes.  If  a  pressure  sensor  is  not  performing 
properly,  look  first  'jt  clogging  or  adiustment  tha.t  is  too 
tight. 

A  third  device  Is  an  air  cushion  chamber  (Figure  19.9) 
which  is  simply  constructed  yet  very  effective.  The  top  half  c 
the  chamber  contains  air. '  Vater  flows  Into  ♦he  bottom  half.  A 
suUde  "Change  :.i  water  p»'essure  compresses  the  air  within 
the  chamber  The  rale  of  response  can  easily  be  regulated 

erJc 


by  placing  a  small  oiifice  in  the  pipe  on  the  water  side  of  the 
air  cushion  chamoer 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  381. 

19.2A  What  IS  a  sensor'? 

19.2B  How  IS  pressure  measured"? 

19  2C  Why  are  some  pressure  sensors  fitted  with  surging 
and  overrange  protection"? 

19.22  Level 

Systems  for  sensing  the  level  of  water  or  any  other  liquid 
level,  either  continuously  or  single-point,  are  probably  the 
most  common  sensors  found  in  waterworks.  P'jmps  are 
controlled,  filters  operated,  clear  wells  monitored  basins 
and  tanks  filled,  chemicals  fed  and  ordered,  sumps  emptied, 
and  distribution  system  reservoirs  controlled  on  the  basis  of 
hquid  level.  Fortunately,  level  sensors  usually  are  simple 
devices.  A  float,  for  example.  Is  a  reliable  liquid  levv  I  sensor. 
Other  types  of  level  sensing  devices  include  direct  pressure, 
pneumatic  bubblers,  sonar  and  capacitance  probes.  Single- 
point  detection  of  el  is  very  common  to  levels  controlled 
by  pumps  and  valve  peratlon. 

A  float  on  the  end  of  a  cable  (see  Figure  19.10)  is 
frequently  us^^d  to  continuously  measure  and/or  to  key 
pump/valve  operation  at  control  points.  For  distribution 
reservoir  or  local  tank  measurement  only,  the  cable  rides 
over  a  pulley  on  the  lip  of  the  tank,  the  other  end  terminating 
at  a  "target"  which  moves  and  reads  against  a  vertical  scale 
on  the  tank's  side.  These  simple  systems  read  out  ba:k- 
wards  (for  example,  high  levels  result  in  lower  scale  read- 
ings as  shown  in  Figure  19.10),  but  are  entirely  satisfactory 
for  many  purposes.  Though  the  action  of  the  float  can  key 
switches  to  signal  high  or  low  itvels,  no  continuous  trans- 
mission of  level  to  a  remote  instrument  is  commonly  used 
with  the  simple  float-cable  system.  Targets  are  often  read 
through  binoculars  when  this  system  used  on  a  remote 
distribution  system  reservoir. 


Variations  on  this  scheme  to  measure  liquid  levels  use 
either  a  perforated  steel  tape  riding  on  a  toothed  pulley  or 
fine  cable  riding  over  a  grooved  dn^m  The  cable  transmits 
the  level  sensed  as  a  signal  (electrical)  proportional  to  pulley 
or  drum  rotation  (Figur3s  19.11a  and  19  11b).  Most  of  these 
deviceb  use  a  counter-weight  on  the  end  ot  the  tape/cable 
opposite  the  float  to  insure  tautness.  Also,  all  types  of  float- 
operated  sensors  work  best  with  the  float  traveling  within  a 
long  tube  called  a  stilling  we",  which  d.  npens  out  unwanted 
liquid  turbulence  or  waves. 

3/0 


350  Water  Treatment 


An  industrial  pressure  gage  with  a  Bourdon  pressure  element 


ERIC 


(T)DlAPh«AGM 


(2)b£LL0WS 


(T)CAPSUL€ 


©BOURDON  TUBE 


(?)  SPltAL 


0HELIX 


Elastic  deformation  elements.  Pressure  tends  to  expand  or 
unroll  elements  as  shown  by  arrows. 


Fig.  19.6  Bourdon  tuba  and  other  pressure  sensing  elements 

(Permission  of  Huse  Gai/ge,  Grosser  Industries) 


37i 


Instrumentation  351 


Fig,  19.6  Snubber  arrangement  for  surge  protection  Fig.  ^9.9  Air  cushion  chamber  for  surge  protection 


373 


352  Water  1  reatment 


NOTE.  As  liqLiO  level  drops,  float  falls  and  pointer  (target) 
rises  and  vice  versa.  Therefore,  pointer  indicates 
deptn  of  water  in  tank  "backwards." 

Fig.  19.10  Reservoir  level  gage,  float/target  type 


Another  common  system  of  level  sensing  is  the  displacer 
type  (Figure  19.11c).  By  its  nature  only  single-point  determi- 
nations of  level  can  be  obtained,  hut  this  type  of  sensino  for 
on-off  control  is  adequate  for  many  purposes.  The  displacer 
is  a  weight,  usually  of  a  non-corroding  heavy  material  such 
as  porcelain,  which  hangs  down  on  a  cable  into  the  liquid 
within  a  stilling  well.  The  cable  is  supported  by  a  spnng 
which  is  sized  so  as  to  keep  an  electrical  switch  (a  mercury 
vial,  usually)  in  one  position  with  the  displacer  immersed,  but 
allowing  it  to  switch  to  another  position  when  the  displacer  is 
out  of  the  liquid.  The  basic  principle  is  that  the  weight  is 
buoyed  up  by  the  liquid  when  immersed,  thus  weighing  less. 
Accordingly,  the  motion  of  the  displacer  is  very  slight, 
typicaiiy  less  than  one  inch  (25  mm)  so  this  design  is  more 
reliable  than  a  float  device  which  may  be  subject  to  sticking 
in  its  stilling  well. 

An  alternative  to  a  float  or  displacer,  both  of  which  are 
mechanical  systems,  is  the  use  of  electrical  probes  to  sense 
liquid  level  (Figure  19.1  Id).  Agali..  only  single-point  determi- 
nations can  be  made  this  way,  though  several  probes  can  be 
set  up  to  detect  several  different  levels.  Level  probes  are 


used  where  a  mechanical  system  is  inoractical,  such  as 
within  sealed  or  pressurized  tanks,  or  with  chemically  active 
liquids. 

The  probes  are  small-diarreter  stainless  sieel  rods  that 
are  inserted  into  a  tank  through  a  special  fitting,  usually 
through  the  top  but  at  times  in  the  side  of  the  vessel.  Each 
rod  IS  cut  to  length  corresponding  to  ^  specific  liquid  level  in 
the  case  of  t\  e  top-entering  probes;  in  the  side-entering 
setup,  a  sr.ort  rod  merely  enters  the  vessel  at  the  appropri- 
ate height  or  depth.  One  problem  encountered  with  probes 
IS  the  accumulation  of  scum  or  caking  (by  CaCOj)  on  the 
surface  of  the  rods. 

A  sniall  voltage  is  applied  to  the  probe(s)  by  the  system's 
power  supply,  with  current  flowing  only  when  the  probe 
"sees  liquid,"  that  is,  becomes  immersed.  When  current  flow 
IS  sensed,  a  switch  activates  a  pump/valve  control  or 
alarm(s)  at  as  many  control  points  as  necessary.  Though  at 
times  only  a  single  probe  is  used,  with  the  metal  tank 
completing  the  circuit  as  a  ground,  usually  at  least  two 
probes  are  found  —  the  ground  probe  extending  all  the  way 
to  the  bottom  of  the  tank  so  as  to  be  in  constant  contact  with 
the  electrically-conducting  hquid  (a  liquid  ground  as  it  were). 

Levels  can  be  sensed  continuously  by  measurement  of 
liquid  pressure  near  the  bottom  of  a  vessel  or  basin.  The 
pressure  elements  used  for  level  sensing  must  be  quite 
sensitive  to  the  low  pressures  created  by  liquid  level  (23  feet 
of  water  column  equals  only  10  psi.  or  7  meters  of  water 
column  equals  7  kPa  or  0.7  kg/sq  cm).  Therefore,  simple 
pressure  gages  such  as  are  found  on  pumps  are  not  used  to 
measure  water  levels.  ^Vater  level  sensors  are  used  to 
measure  levels  of  water  in  systems  on  filter  basins,  or  in 
chemical  storage  tanks  where  control  or  monitoring  must  be 
close,  continuous,  and  positive.  Rather  than  being  calibrated 
in  units  of  pressure  (psi),  these  gages  read  directly  in  units  of 
liquid  level  (feet).  Single-point  control/alarm  contacts  can  be 
made  a  part  of  this,  or  any  continuous  type  of  level  sensor. 

A  very  precise  method  of  measuring  liquid  level  is  the 
bubbler  tube,  w  th  its  associated  pneumatic  instrumentation 
(Figure  19.12).  The  pressure  created  by  the  liquid  level  is 
sensed,  but  not  directly  as  with  a  mechanical  pressure 
element.  Air  pressure  is  created  in  a  bubbler  tube  to  just 
match  the  pressure  applied  by  the  liquid  above  the  open  end 
immersed  to  some  pre-determined  depth  in  the  tank  or 
basin.  This  AIR  pressure  is  then  measured  (sensed)  as 
proportional  to  liquid  level  ABOVE  THE  END  OF  THE  TUBE. 
This  indirect  determination  of  level  using  air  permits  the 
placement  of  the  instrumentation  anywhere  above  or  below 
the  liquid's  surface,  whereas  direct  pressure-to-level  gages 
must  be  installed  at  the  very  point  where  liquid  pressure 
must  be  sensed. 

These  nneumatic  devices  are  adjusted  so  air  JUST  BE- 
GINS to    'bble  out  of  the  submerged  end  of  the  sensing 


ERIC 


373 


Instrumentation  353 


TELEMETRY 

LEVEL 

TO  PLANT 

TRANS- 

MITTER 

7^ 


NOTE:   AS  ARROWS 
DEPICT,  COUNTER- 
WEIGHT MOVES  ONLY 
A  FRACTION  OF  FLOAT 
TRAVEL,  DUE  TO  DIFF- 
ERENCE IN  DRUM 
DIA.  WHERE  RESPEC- 
TIVE CABLES  ATTACHED. 


HOLES- 


FLOAT 


DRUM 


TOOTHED 
PULLEY- 


LEVEL 

LEVEL  SIGNAL 

TRANS- 

MITTER 

 ^ 

CABLE 


Oo  0 


XOwNTER- 
WEIGHT 


I 


.TANK  OR  RESERVOIR"^ 


C.W. 


NOTE:   SIGNAL  PRO- 
PORTIONAL TO  TURNS 
OF  PULLEY/DRUM 
FROM  LOWEST 
(EMPTY)  POSITION. 


PERFORATED 
S.S.  TAPE 

STILLING  WELL 


Fig.  19. 1 1a  Float  and  cable  (continuous) 


Fig.  19. 7  lb  Float  and  tape  (continuous) 


LEVEL  TRANSDUCER 
(MECHANICAL  TO  ELECTRIC) 


SIGNAL  Wir 


NOTE:   WHEN  DISPLACER 
COMPLETELY  IMMERSED, 
SPRING  RELAXES  TO 
CLOSE  ELECTRICAL 
CONTACTS  FOR  SIGNAL. 


DISPLACER 


(SEVERAL  MAY  BE 
USED  FOR  MULTI- 
POINT SENSING). 


+SiNGLE 
POINT 
LEVEL 
SENSING 


u 

EL^" 


LEVEL 
PROBES 
MAY  BE 
SIDE- 
ENTERING 

TO  SENSOR 


  /ie;^<P  i  GROUNDING  (COMMON)  PROBE 


LEVEL 
=1>  SENSOR 


SI 


CONTROL  OR 
ALARM  SIGNALS 


HI-LEVEL  PROBE 


S.S. 
RODS 


NOTE:  ELECTRIC 
CURRENT  FLOWS 
BETWEEN  COMMON 
AND  LEVEL  PROBES 
TO  SENSE  LIQUID 
LEVEL. 

LO-LEVEL  PROBE 


Fig.  19.11c  Displacer  (smgle-point) 


Fig.  19.1  Id  Electrical  probes  (multi-point) 


Fig.  19.11   Lipuid'level  sensing  systems 
(Le\el  measurement  and  single-point  sensing) 


ERLC 


374 


354  Water  Treatment 


LEVEL 
READOUT 
UNIT(S) 


ROTAMETER 


INST. 
AIR-i 
SUPPLY 


PRES. 
REG. 
AND 
FILTER 


SET-^ 

 rrm 


CONSTANT 

FLOW 
REGULAIOR 


PURGE  VALVE' 


FUNCTIONAL  DIAGRAM 


0 

0 

0 

Ql  IRni  CD 

^^^.^TUBE 

0 

0 

0 

-** —  LOWEST  

LEVEL 

SENSED 

TANK  OR  BASIN 

FOR  APPLICATIONS  WITH  CLOGGING  TENDENCY. 
EG;  CHEMICALS,  SLURRIES,  WASTEWATER 


(ABOVE,  BELOW  OR  LEVFL 
WITH  INSTRUMENTATION) 


ERIC 


Fig,  19, 12  Bubbler  tube  system  for  measuring  liquid  level 

375 


instrumentation  355 


tube.  They  automatically  compensate  for  changes  in  liquid 
level  by  providing  a  small,  constant  flow/  of  air.  There  is  no 
advantage  to  "turning-up-the-amount-of-air"  to  create  more 
intense  bubbling  (the  pressure  will  still  depend  on  the  vjater 
level).  In  fact,  such  action  may  create  a  sizeable  measuring 
error  in  the  system  and  any  air  flow  changes  should  be  left  to 
qualified  instrument  service  personnel. 

Bubbler  tube  systems  are  common  in  filter-level  control- 
lers which  must  naintain  water  levels  within  a  range  of  a  few 
inches  (or  centimeters).  Usually  tne  level  transmitter  for  this 
use  is  "blind"  since  it  only  controls  liquid  level  and  doe  not 
provide  an  indication  or  re'    ut  of  the  level. 


QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  381. 

19.2D  List  the  mapr  types  of  liquid  level  sensors. 

19.2E  How  can  a  signal  be  generated  by  a  float  element? 

1 9.2F  Under  what  circumstances  are  probes  used  to  meas- 
ure liquid  level  instead  of  mechanical  systems 
(floats)? 

19.2G  How  does  a  bubbler  measure  the  level  of  a  liquid'' 


Rotameters  [RATE-oi-ilovj) 
Fig,  19, 13  Flow  se  ^sing  devices 

E±  376 


356  Water  Treatment 


19.23  Flow  (Rate  of  Flow  and  Total  Flow) 

The  term  'flow'  can  be  used  to  refer  to  either  RATE  OF 
FLOW,  such  as  MGD,  CPS,  and  GPM  (volume  per  unit  of 
time),  or  to  TOTAL  FLOW\n  simfJe  units  of  volume  such  as 
gallons  or  cubic  feet.  Such  volumes  are  usually  obtained  as 
a  running  total,  with  a  comparatively  long  time  period  for  the 
flow  delivery  (such  as  a  month).  This  distinction  Is  Important 
sn  the  understanding  ol  flow  instrumentation,  most  of  which 
provides  SOTHvalues  (for  rate  of  flow  and  total  flow).  Some 
flow  meters,  however,  provide  only  total  flow  readings. 

While  It  IS  possible  in  pnnciple  to  measure  flow  directly, 
such  as  IS  done  with  pressure  and  most  level  sensing 
devices,  it  is  quite  impractical.  Direct  measurement  woulJ 
involve  the  » onstant  filling  ana  emptying  of.  say,  a  gallon 
container  with  water  flowing  from  a  pipe  on  a  timed  basis 
This  method  is  simply  not  practical.  Therefore,  sensing  of 
flows  in  waterworks  practice  is  done  INFERENl  \LLY.  that 
IS.  by  inferring  what  the  flow  is  from  the  observation  of  some 
associated  hydraulic  action  of  the  water  The  inferential 
techniques  that  are  used  in  waterworks  flow  measurement 

3  (1)  velocity  sensing,  (2)  differential-pressure  sensing.  (3) 
L.agnetic,  and  (4)  ultrasonic  First,  let's  look  at  a  few  other 
methods  used  in  flow  sensing  for  specialized  applications 
before  studying  velocity  sensing  devices. 

ROTAMETERS  (Figure  19.13)  are  transparent  tubes  with 
a  tapered  bore  containing  a  ball  (or  float).  The  ball  rises  up 
within  the  tube  to  a  point  corresponding  to  a  particular  rate 
of  flow.  The  rotameter  tube  is  set  against,  or  has  etched 
upon  the  tube,  marks  calibrated  in  whatever  flow  rate  unit  is 
appropnate.  Rotameters  are  used  to  indicate  approximate 


liquid  flow  or  gas  flow,  such  as  those  installed  at  the  readout 
device  of  a  gas  chlonnator  Sometimes  a  simple  rotameter  is 
installed  merely  to  indicate  a  flow  or  no-flow  condition  in  a 
pipe  such  as  found  on  chbrinator-injector  supply  lines. 

Service  meters  are  the  type  of  flow  meters  used  to  record 
total  water  usage  through  individual  service  connections  in  a 
distribution  system  (Figure  19.14).  The  smaller  service  me- 
ters are  usually  one  of  the  positive-displacement  types.  The 
larger  service  meters  use  the  velocity-sensing  principle. 

VELOCITY-SENSING  DEVICES  measure  water  speed 
within  a  pipeline.  Vhis  can  be  done  by  sensing  the  rate  of 
rotation  of  a  special  impeller  (Figure  19.15)  placed  within  the 
flowing  stream:  the  rate  of  flow  is  directly  proportional  to 
impeller  RPM  (within  certain  limits).  Since  normal  water 
velocities  in  pipes  c  nd  channels  are  well  under  100  feet  per 
second  (about  8  mph  or  3  m/sec),  the  impeller  turns  rather 
slowly.  This  rotary  motion  drives  a  train  of  gears  which 
finally  indicates  PATE  of  flow  as  a  speedometer-type  read- 
out. TOTAL  flow  appears  as  the  cumulative  number,  similar 
to  the  odometer  (total  mileage)  on  your  car. 

Rotation  of  the  velocity-sensing  element  is  not  always 
transferred  by  gears,  but  may  be  picked  up  as  a  magnetic  or 
electric  signal  (pulses)  by  the  instrument  system.  Nor  is 
velocity  always  sensed  mechanically;  it  may  also  be  detect- 
ed or  measured  purely  electncally  (the  thermister  type)  or 
hydrauhcally  (the  pitot  tube),  but  the  principle  of  equating 
water  velocity  with  rate  of  flow  within  a  constant  flow-area  is 
the  same.  Of  course,  all  such  flovy  meters  are  calibrated  to 
read  out  m  an  appropnate  unit  of  flow  rate,  rather  than 
velocity  units. 


Instrumentation  357 


FLOW 
TRANSDUCER/ 
TnANSMITTER 


FLOW 


PIPE 


^    FLOW  METER  ^ 


RATE-OF-FLOW 
RECORDER 
OR 

INDICATOR 

 "I  


FLOW  TOTALIZER 


*  NOTE:   MOTION  OF  PROPELLER 
CAN  BE  SENSED/TRANSMITTED 
MECHANICALLY,  MAGNETICALLY 
OR  ELECTRICALLY,  OR  ANY 
OF  THESE  IN  COMBiNATIOtl. 


SCHEMATIC  DIAGRAM 


F/g.  J9. 75  Propel'er  (v  ilcoity)  meter 

ErIc  37S 


358  Water  Treatment 


Typically,  this  type  of  flow  element  transmits  its  reading  to 
a  remote  site  as  electrical  pulses,  although  other  devices 
can  be  used  in  order  to  convert  to  any  standard  electrical  or 
pneumatic  signal. 

Preventive  maintenance  of  impeller-iype  flow  meters  cen- 
ters around  regular  lubrication  of  rotating  parts.  Propeller 


meters,  as  they  are  called,  have  a  long  history  of  reliability 
and  acceptable  accuracy  in  v\/aterworks  practice.  When 
propeller  meters  become  old,  they  become  susceptible  to 
under-registration  (read  lov\/)  due  to  bearing  wear  and  gear- 
train  friction.  Accordingly,  annual  tear-down  tor  inspection  is 
.ndicated.  An  over-registration  is  a  physical  impossibility  as 
far  as  the  operating  principle  goes,  but  a  partially  full 
pipeline,  wrong  gears  installed,  or  a  malfunctioning  transmit- 
ter can  cause  high  readings. 

DIFFERENTIAL-PRESSURE  SENSING  DEVICES  (Figures 
19.16  and  19.17),  also  called  venturi  or  just  differential 
meters,  depend  for  their  operation  upon  a  basic  principle  of 
hydraulics.  When  a  liquid  is  forced  to  go  faster  in  a  pipe  or 
tuf^e,  its  internal  pressure  drops.  If  a  carefully  sized  restric- 
tion IS  placed  within  the  pipe  or  flow  channel,  the  ^lowing 
water  must  speed  up  to  get  thiough  it.  In  doing  so,  ^ts 
pressure  drops  a  little;  and,  it  always  drops  ths  same 
amount  for  the  same  flow.  This  small  pressure  drop,  the 
differential,  is  the  difference  between  the  water  pressure 
before  the  restriction  and  within  the  restriction.  This  differ- 
ence is  proportional  to  the  rate  of  flow.  The  difference  in 
pressure  is  measured  very  precisely  by  the  instrumentation 
associated  with  the  certain  flow-tube  or  venturi  installed. 
Typically,  only  a  difference  of  a  few  psi  is  required.  This 
small  value  of  pressure  difference  is  often  described  m 
inches  of  water  (head). 


ERIC 


Measuring  flow  by  this  method  removes  a  little  hydraulic 
energy  from  the  water.  However,  the  classical  ventun  tube, 
with  its  carefully  tapered  form,  allows  recovery  of  well  over 
95  percent  of  the  original  pressure  throughout  its  range  of 
flows  Other  ways  of  constricting  the  flow  do  not  ?llow  such 
high  recoveries  of  pressure,  nor  the  accuracy  possible  with 
modern  venturi  flow  tubes.  The  Dall  tube  is  a  shortened  form 
of  the  venturi.  with  acceptable  accuracies  for  many  in-plant 
purposes  (filter  wash-water  flows). 


FLOW 
RECORDER 
OR 

INDICATOR 


UPSTREAM 


SECTIONS 


PREdS. 
GRAPH 


Ventun  system  (flow  rate) 


f instrumentationN 

V  SAME  AS  ABOVE  J 


LOW  TAP 
MAY  BE 

HERE 


FLANGES 


ORIFICE 
PLATE 


Orifice  plate  installation  (flow  rate) 

Fig.  19.16  Schematic  diagrams  of 
differential  pressure  flow  metering 

The  orifice  plate  (Figures  i9.l6  and  19.17)  is  inserted 
between  flanges  in  a  pipe  and  is  a  stainless  steel  plate  with  a 
calculated  size  hol^  (orifice)  in  it.  The  pressure  drop  is 
sensed  right  at  the  orifice,  or  immediately  downstream  to 


379 


Instrumentation  35r 


360  Water  Treatment 


yield  a  comparatively  rough  flow  indication  This  drop  in 
pressure  is  permanent;  that  is,  a  permanent  pressure  loss 
occurs  with  orifice  plate  installations. 

Difierential  devices  require  little  if  any  preventive  mainte- 
nance by  the  operator  since  there  are  no  real  moving  parts 
Occasionally,  flushing  of  the  hydraulic  sensing  lines  is  good 
practice.  This  flushing  should  only  be  done  by  a  qualified 
person.  When  dealing  with  an  instrument  sensitive  to  small 
fractions  of  a  psi,  opening  the  wrong  valve  can  damage  the 
internal  parts  Also,  if  an  instrument  containing  mer  jry  is 
used,  this  toxic  (and  expensive)  metal  can  easily  be  blown 
out  of  the  device  and  INTO  THE  WATER  PIPELINE'  Thus, 
all  valve  manipulations  must  be  understood  and  done  delib- 
erately after  careful  planning. 

In  nearly  all  cases,  the  instrumentation  associated  with  the 
larger  flow  tubes  is  transmitted  to  a  remote  readout  station. 
Local  readout  is  also  provided  (sometimes  .nside  the  case 
only),  for  purposes  of  calibration.  Differential  meter  flow 
transmitters  may  be  electncal  or  pneumatic  types  (with 
signal  transmitted  proportional  to  the  square  root  of  the 
differential  pressure). 

Venluri  meters  have  been  in  use  for  many  decades  and 
can  produce  very  close  accuracies  year  after  year.  Older 
flow  tubes  are  quite  long  physically  (to  yield  maximum 
accuracy  and  pressure  recovery).  Newer  units  are  much 
shorter  but  have  even  better  accuracy.  With  no  moving 
parts,  the  venturi-type  meter  is  not  subject  to  mechanical 
failure  as  is  the  propeller  meter.  Flow  tubes,  however,  must 
be  kept  clean  and  without  obstructions  upstream  and  down- 
stream to  provide  designed  accuracy. 

These  flow  meter  types  all  provide  rate  of  flow  md  .ation. 
The  rate  of  flow  is  continuously  totalized,  usually  at  the  read- 
out instrument,  as  the  total  flow  up  to  that  point  in  time 
(recorded  in  gallons  or  cubic  feet). 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  381. 

19.2H  What  are  two  types  of  flow  readings'? 

19.21   Ltst  the  two  mam  types  of  (larger)  flow  measurement 
devices. 

19.2 J  Smaller  service  meters  are  what  type  of  flow  meter"? 
19  2K  riow  do  velocity-sensing  devices  measure  flows'? 
19.2L  How  are  flows  measured  with  venturi  meters'? 


19.24  Chemical  h^ed  Rate 

Chemical  feed  'ate  indicators  are  usually  a  necessary  part 
of  the  particular  chemical  feed  system  and  thus  are  usually 
not  considered  instrumentation  as  such.  For  example,  a  dry 
feeder  for  lime  or  dry  polymer  may  be  provided  with  an 
indicator  for  feed  rate  in  units  of  weight  per  time,  such  as 
Ibs/hr  or  grams/minute.  In  a  fluid  (liquid  or  gas)  feeder,  the 
indication  of  quantity/time,  such  as  gallons/hour  or  pounds/ 
day  may  be  provided  by  use  of  a  rotameter  (Figure  19.13). 

19.25  Process  instrumentation 

Process  instrumentation  provides  for  continuous  check- 
ing of  physical  or  chemical  indicators  or  water  quality  in  a 
treatment  plant.  The'^q  .instruments  do  not  include  laboratory 
Instruments  (unless  set  up  tc  measure  sample  water  con- 
tinuously), although  the  operating  principles  are  usually 


qi"te  similar.  The  process  vanabias  of  turbidity  and  pH  are 
alwcvs  monitored  closely  in  a  modern  water  treatment  plant 
(Figu,e  19  18).  Very  frv^quently  chlorine  residuals  are  also 
contnuously  measured  and  controlled.  Usually  these  three 
variables  are  measured  at  several  locati  ;ns.  For  example, 
turbidity  of  >avv,  settled,  and  filtered  water  is  frequently 
measured  Additionally,  otherindicators  of  water  quality  may 
be  sensed  on  a  continuous  basis  such  as  fluoride,  electrical 
conductivity  (for  TDS),  water  hardness  and  alkalinity,  and 
temperature.  In  every  case,  the  instrumentation  is  specific 
as  to  operating  principle,  standardization  procedures,  pre- 
ventive maintenance,  and  operational  checks.  The  manufac- 
turer's technical  manual  sets  forth  routine  procedures  to 
check  and  operate  the  equipment. 

Operators  must  realize  that  most  process  instrumentation 
IS  quite  sensitive  and  thus  requires  careful  handling  and 
special  training  to  service.  No  adjustments  should  be  made 
without  a  true  understanding  of  the  device.  Generally  speak- 
ing, this  category  of  instrumentation  must  be  maintained  by 
the  water  agency's  instrument  specialist  or  the  factory 
representative  rather  than  by  an  operator  (unless  specially 
instructed) 

19-26  Signal  Transmitters/Transducers 

Common  practice  measures  a  variable  at  one  location  and 
provides  a  readout  of  the  value  at  a  remote  location,  such  as 
a  mam  panel  board  Except  in  the  case  of  a  blind  transmitter, 
a  local  indication  is  provided  at  the  field  site  as  well  as  being 
available  at  the  remote  site.  Associated  with  the  remote 
(panel)  readout  system  quite  often  are  alarm  set-points,  an 
integrator,  or  a  controller  (though  any  of  these  may  exist  at 
the  measuring  site  also).  Usu'JIy  a  recorder  is  found  only  on 
a  panel  board  along  with  all  other  recorders  remote  from  the 
sensor  in  the  field.  These  system  components  will  be 
discussed  further  in  Section  19.3,  "Categories  of  Instrumen- 
tation." 

In  order  to  transmit  a  measured  value  to  a  remote  location 
for  readout,  it  is  necessary  to  generate  a  signal  proportional 
to  the  value  measured.  This  signal  is  then  transmitted  to  a 
receiver  which  provides  a  reading  based  upon  the  signal. 
Also,  a  controller  may  use  the  signal  to  control  the  measured 
variable. 

Presently,  two  general  systems  for  transmission  of  sig- 
nals, electncal  and  pneumatic,  are  used  in  waterworks,  as 
well  as  in  most  other  industrial  situations.  Electricity,  of 
course,  requires  winng  (though  radio  transmission  or  micro- 
wave are  possible).  Pneumatic  systems  require  small-diam- 
eter tubing  (usually  V4  inch  or  6  ^rx])  between  transmitter  and 
receiver.  When  the  transmitter  is  quite  far  removed  from  the 
receiving  station,  a  special  terminology  is  used  tor  the 
electrical  link  between  the  two;  this  is  called  telemetry.  The 
wiring  used  is  telephone  lines,  leased  from  the  local  tele- 
phone company,  or  owned  by  the  water  agency.  Telemetry 
will  be  discussed  separately  in  Section  19.33,  "Telemetry," 
since  the  signals  are  usually  a  special  type. 


381 


Instrumentation 


Turbidimeter 


Ig,  19. 18   Water  treatment  plant  instrumentation 
(Continued  on  the  next  page; 


Er|c  382 


362  Water  Treatment 


Chlorine  residual  analyzer 

Fig.  19,18  Water  treatment  plant  instrumentation 
(Cotit'nued  from  previous  page) 


Electric  signals  used  within  a  water  treatment  plant  are 
either  voltage  (1  to  6  volts  D.C.),  current  (4  to  20  milliamps 
D  C ),  or  pulse  types.  Milliamp  signals  (4  to  20  ma)  are  the 
most  common  electncal  signals  for  most  instrumentation 
and  control  systems  in  recent  years.  In  any  of  these,  a  low 
voltage  is  applied  so  no  severe  shock  hazard  exists  (though 
shorting  signal  wires  may  still  destroy  electrical  compo- 
nents). Signal  transmission  is  limited  to  several  hundred 
feet,  with  signal  strength  usually  set  up  for  the  specific 
connecting  lines. 

A  power  supply  to  generate  the  required  electrical  energy 
may  be  at  the  transmitter,  the  receiver,  or  at  another 
location.  The  transmitter  may  be  an  integral  part  of  the 
measurement  sensor/transducer,  or  separately  housed.  In 
any  case,  the  transmitter  adjusts  the  signal  to  a  correspond- 
ing value  of  the  measured  vanable,  and  the  receiver  in  turn 
converts  this  signal  to  a  visible  indication  whjch  is  the 
readout. 

Pneumatic  signal  systems  are  restricted  to  comparatively 
short  distances.  Components  include  a  compressor  to  pro- 
vide air  under  pressure,  as  well  as  the  necessary  air  filters 
and  an  air  dryer.  The  precision  of  signal  transmission  by 
pneumatics  is  comparable  to  electrical  signals  so  both 
systems  are  found  about  equally  in  waterworks. 

Compressed  air  presents  no  shock  hazard  and  most 
plants  must  have  compressors  available  for  other  purposes. 


Also,  pneumatic  systems  seem  to  be  more  understandable 
to  operatin*^  personnel  and  thus  easier  to  K'^ep  functioning 
as  desired.  As  with  electrical  signal  circuits,  the  transmitter 
and  receivers  perform  as  their  names  imply.  Pneumatic 
controllers,  and  all  other  types  of  equipment,  are  as  avail- 
able as  their  electncal  counterparts.  Pneumatic  signals  are 
generated  by  causing  pressures  from  3  to  16  psi  (20  to  100 
kPa  or  0  2  to  1.1  kg/sq  cm),  proportional  to  the  vanable,  in 
almost  every  installation,  with  9  psi  (52  kPa  or  0,66  kg/sq 
cm)  then  representing  a  60  percent  signal. 

Preventive  maintenance  of  pneumatic  components  cen- 
ters around  ensuring  a  c'san.  dry  air  supply  at  all  times 
which  requires  alert  operators. 

QUESTIONS 

Write  your  answers  in  a  noteboCN  and  then  compare  your 
answers  with  those  on  page  38^! . 

^9/J*  How  are  chemical  feed  rate^  measured*? 

19  2N  What  process  vanables  are  commonly  monitored 
and/or  controlled  by  instruments? 

19.20  By  what  means  can  values  measured  at  one  site  be 
read  out  at  a  remote  location? 

19.2P  What  are  the  two  general  systems  used  to  transmit 
measurement  signals'? 


'383 


instrumentation  363 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  19.  INSTRUMENTATION 

(Lesson  1  of  2  Lessons) 


Write  the  answers  to  these  questions  in  your  notebook 
before  continuing. 

1.  Why  should  operators  understand  measurement  and 
control  systems? 

2.  How  can  measurement  and  control  systems  make  an 
operator's  job  easier'? 

3.  What  IS  the  difference  between  precision  and  accuracy? 

4.  Why  should  a  screwdriver  not  be  used  to  test  an  electrical 
circuit? 


5  What  precautions  should  an  operator  take  before  entor- 
ing  a  vault'? 

6.  How  can  water  levels  be  measured'? 

7  What  problems  can  develop  with  propeller  meters  when 


CHAPTER  19.  INSTRUMENTATION 

(Lesson  2  of  2  Lessons) 


19.3   CATEGORIES  OF  INSTRUMENTATION 

19.30  Measuring  Elements 

Measuring  (or  primary)  elements  are  those  devices  which 
make  the  actual  measurement  of  the  variable.  Transducers 
are  usually  associated  with  sensors  to  convert  the  sensor's 
signal  to  another  magnified  action  producing  a  more  useable 
indication.  If  remote  transmission  of  tne  value  is  required,  a 
transmitter  may  become  part  of  th'^  transducer.  An  illustra- 
tive example  of  these  three  components  is  the  typical  venturi 
meter:  (1)  the  flow  tube  is  the  primary  element,  (2)  the 
differential-pressure  device  ("D.P.  cell")  the  transducer,  and 
(3)  the  signal  producing  components  are  the  transmitter.  An 
understanding  of  the  separate  lunctions  of  each  section  of 
the  "flow  meter"  is  important  to  the  proper  understanding  of 
equipment  problems. 

19.31  Panel  Instruments  (See  Figure  19.1,  page  343) 

i9.310  Indicators 

The  components  of  measurement  and  control  systems 
found  on  the  water  plant's  mam  panel  board  are  generally 
thought  of  as  the  plant  instrumentation.  These  components 
are  important  to  the  operator,  and  hence  to  plant  operation 
Itself,  because  they  display  the  variable  directly.  These  panel 
devices  can  produce  alarm  signals  to  indicate  if  a  variable  is 
outside  Its  range  of  expected  values.  In  addition,  the  control- 
lers are  often  installed  on  (or  behind)  the  mam  panel  along 
with  the  operating  buttons  and  switches  for  the  plant's 
equipment 

However,  m  this  age  of  cybernetics  (a  fancy  term  for 
instrumentation),  you  can  easily  be  lulled  into  an  overde- 
pendence  on  automation  to  operate  the  plant  processes 


more  or  less  blindly.  You  must  realize  that  the^'e  is  no 
substitute  for  critical  evaluation  and  informed  judgment  in 
the  "trusting"  of  instrument  systems  as  they  relate  to  impor- 
tant plant  functions.  You  must  not  rely  solely  upon  the 
readings  of  any  single  instrument  to  ensure  proper  plant 
operation,  but  must  consult  other  instruments  and  closely 
watch  the  other  indicators  of  plant  operation.  Even  the  most 
sophisticated  and  expensive  instrument  systems  require 
constant  maintenance  work  by  specialists  and  do  malfunc- 
tion at  times 

19.311  Indicators/Recorders 

The  major  components  found  on  the  plant's  mam  panel 
are  indicators  and  recorders.  Indicators  give  a  visual  presen- 
tation of  a  vanable's  value,  either  as  an  analog  or  as  a  digital 
display  (Figures  19.19  and  19.20).  The  analog  display  uses 
some  manner  of  pointer  (or  other  indicator)  against  a  scale. 
A  digital  display  is  a  direct  numerical  readout.  Recorders, 
which  can  also  serve  as  indicators,  give  a  permanent  record 
of  how  the  variable  changes  with  time  by  way  of  a  moving 


3S4 


364  Water  Treatment 


chart  Whereas  there  are  usually  several  indicators  out  in  the 
plant  or  field,  recorders  are  usually  housed  at  a  central 
location  in  the  plant.  We  wi"  discuss  both  indicators  and 
recorders  in  the  following  paragraphs. 

Since  there  are  two  types  of  signal  transmission  available, 
panel  indicators  may  be  of  the  electric  or  the  pneumatic  type. 
The  digital  readout  is  a  relatively  recent  development,  with 
both  advantages  and  disadvantages.  Digitals  may  be  "ead 
more  quickly  and  precisely  from  a  longer  distance,  and  can 
respond  virtually  instantly  to  variable  changes.  But  analog 
indicators  are  cheaper,  more  rugged,  and  may  not  even 
require  electrical  power  (the  pneumatic  type),  an  advantage 
during  a  power  failure. 

Another  advantage  of  the  electric  or  pneumatic  analogs  or 
gages  is  that  a  wrong  indication  (value)  is  more  recognizable 
than  with  a  digital  system,  and  also  is  more  easily  repaired 
by  the  operator. 

For  example,  the  pointer  on  a  flow  meter  gage  may  merely 
be  stuck,  as  evidenced  by  a  perfectly  constant  reading.  With 
a  digital  reading  there  is  no  practical  way  for  the  operator  to 
see  whether  a  problem  actually  does  exist,  nor  is  there  any 
way  for  the  operator  to  attempt  a  repair,  such  as  freeing  a 
pointer.  Erratic  or  unreliable  operation,  while  always  a 
problem,  seems  to  be  worse  when  digitals  are  involved  since 
there  is  "no  way  out"  for  the  operotor.  You  often  can't  tell  if 
the  problem  is  real,  and  you  can't  do  anything  to  "get-by-'til  8 
A.M."  as  is  often  required  on  a  night  shift. 

With  all-electronic  Instrumentation,  as  advantageous  as  :t 
may  seem  from  a  technical  and  economic  standpoint,  the 
operator  has  little  recourse  in  case  of  malfunction  of  critical 
instrumentation.  Temporary  power  failures,  tripped  panel 
circuit  breakers,  voltage  surges  (lightning)  resulting  in  blown 
fuses,  and  problems  of  excessive  heat  can  all  result  in 
electronic  instrument  problems.  However,  electromechani- 
cal or  pneumatic  instruments  may  keep  operating,  or  recov- 


er operation,  readily  after  such  power  or  heat  problems. 
Electronic  systems  may  require  the  services  of  an  instru- 
ment technician,  or  even  the  factory  technician,  to  become 
fully  operable  again.  Accordingly,  i  le  operator  should  insist 
upon  some  input  into  the  design  phase  of  instrument  sys- 
tems to  ensure  that  the  plant  is  still  operable  during  power 
outages,  Jiot  weather,  and  other  contingencies.  Standby 
power  ^jenerators  and/or  batteries  are  used  to  keep  plants 
operating  during  power  outages. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  382. 

19.3A  What  IS  the  purpose  of  indicators? 

19.3B  Describe  an  analog  display. 

19.3C  Where  are  recorders  usually  found  at  a  water  treat- 
ment plant? 

19  3D  What  factors  can  cause  electronic  Instrument  prob- 
lems? 


19.312  Recorders 

Recorders  are  indicators  designed  to  show  how  the  value 
of  the  variable  has  changed  with  time  (Figure  19.20).  Usually 
this  is  done  by  attaching  a  pen  (or  stylus)  to  the  indicating 
arm,  which  then  marks  or  scribes  the  value  of  the  variable 
onto  a  continuously  moving  chart.  The  chart  is  marked  on  a 
horizontal  or  circular  scale  in  time  units.  Sorro  models  of 
recorders  reverse  the  scales  by  indicating  time  on  the 
vertical  and  variable  on  the  horizontal  scales. 

The  chart  is  driven  along  at  a  pi  3cise  speed  under  the  pen, 
to  correspond  with  the  time  markings  on  the  chart.  Chart 
speeds  range  from  several  inches  to  a  fraction  of  an  inch  per 


ERIC 


Fig,  19.19  Analog  chlorine  residual  indicator 

385 


366  Water  Treatment 


minute,  with  the  pen  and  drying  time  of  the  ink  specific  to  a 
given  range  of  speeds. 

There  are  two  mam  types  of  recorder  charts  and  record- 
ers: the  horizontal  stnp-chart  type  and  the  circular  type.  The 
horizontal  strip-chart  r^irries  its  chart  on  a  roll  or  as  folded 
stock,  with  typically  several  months'  supply  of  chart  avail- 
able. Several  hours  of  charted  data  are  usually  visible  or 


euSily  available  for  the  operator  to  read.  On  a  circular 
recorder,  the  chart  makes  one  revolijtion  every  day,  week, 
or  month,  and  the  record  of  the  entire  elapsed  time  period  is 
visible  at  any  time. 

changing  of  charts  is  usually  the  operator's  duty,  and  is 
easier  with  circular  recorders,  though  not  that  difficult  with 
most  strip-chart  units. 


Strip-chart  recorders 


Seven-day  circular-chart  recorder 


Fig.  19.21   Recorders,  strip  chart  and  circular  chart 


ERLC 


3S7 


Instrumentation  367 


Recorders  may  be  electric  or  pneumatic.  Pneumatic  mod- 
els frequently  Nave  electnc  chart  drives.  Purely  mechanical 
units,  useful  at  a  remoie,  unpowered  pressure  gaging  sta- 
tion, have  hand-wound  chart  drives  and  are  of  the  circular- 
chart  type.  Other  models  are  battery  powered.  Recorders 
are  most  commonly  described  by  the  nominal  size  of  the 
strip-chart  width  or  circular-chart  diameter  (for  example,  a  4- 
inch  (100  mm)  stnp-chart,  or  a  lO-inch  (250  mm)  circular- 
chart  recorder).  Figures  19.20  and  19.21  present  various 
popular  models  of  indicators  and  recorders. 

19.313  Totalizers 

The  rate  of  flow  as  a  variable  is  a  time-rate:  that  is,  it 
involves  time  directly,  such  as  in  gallons  per  minute,  or 
million  gallons  per  day,  or  cubic  feet  per  second.  Flow  rate 
units  become  units  of  volume  with  the  passage  of  time.  For 
example,  flow  in  gallons  per  minute  accumulates  as  total 
gallons  during  an  hour  or  day.  The  process  of  calculating 
and  presenting  an  on-going,  lunning  total  of  flow  volumes 
passing  through  a  meter  is  termed  Integration"  or  totalizing. 

An  integrator,  also  called  a  totalizer,  continually  adds  up 
gallons  or  cubic  feet  as  a  cumulative  total  up  to  that  point  in 
time.  Virtually  all  flow  indicators  and  recorders  are  equipped 
with  totalizers,  though  sometimes  as  separate  units  (Figures 
19.20  and  19.21).  Many  flow  meters  OA/Ly  measure  the  total 
quantity  of  fluid  passing  through  it;  the  domestic  service 
meter  (common  water  meter)  is  an  example  of  this  type  of 
flow  meter. 

Large  quantities  of  water  (or  liquid  chemical)  are  common- 
ly measured  in  units  of  hundreds  or  thousands  of  gallons  or 
cubic  feet.  This  is  simply  a  shorthand  means  of  expressing 
the  measurement.  On  the  face  of  a  totalizei  you  will  find  a 
multiplier  such  as  x  100  or  x  1000.  This  indicates  that  the 
reading  is  to  be  multiplied  by  this  (or  another)  'actor  to  yield 
the  full  amount  of  gallons  or  cubic  feet.  If  the  readout  uses  a 
large  unit,  such  as  "mil  gal,"  a  decimal  will  appear  between 


appropriate  numbers  on  the  display,  or  a  fractional  multiplier 
( •  0.001 ,  for  example)  will  appear  on  the  face  of  the  totalizer. 

Every  operator  should  personally  be  able  to  CALCULATE 
total  flow  for  a  time  penod  in  order  lo  verify  that  the 
integrator  is  actually  producing  the  correct  value.  Accuracy 
to  one  or  two  parts  in  a  hundred  ( ±  1  or  2  percent)  is  usually 
acceptable  in  a  totalizer.  There  are  methods  to  integrate 
(add  up)  the  area  under  the  flow-rate  curve  on  a  recorder 
chart,  to  check  total  flow  for  long-term  accuracy  calcula- 
tions. 

19.314  Alarms 

Alarms  are  visual  and/or  audible  signals  that  a  variable  is 
out  of  bounds  or  that  a  condition  exists  in  the  plant  requiring 
the  operator's  attention.  For  noncritical  conditions,  the  glow 
of  a  small  lamp  or  light  on  (or  outside  of)  an  indicating 
instrument  is  sufficient  notice.  For  more  important  vanables 


or  conditions,  an  attention-getting  an.unciator  panel  (Figure 
19.22)  with  flashing  lights  and  an  unmistakable  and  penetrat- 
ing alarm  horn  is  commonly  used. 


Fig.  19.22  Annunciator  (alarm)  panel 
(each  rectangle  represents  a  monitored  location) 

383 


368  Water  Treatnent 


Annunciator  panels  all  have  "acknowledge"  and  "reset*" 
features  to  allow  the  operator  to  squelch  the  alarm  sound 
(leaving  the  visible  indication  alone)  and  to  reset  the  system 
after  the  alarm  condition  is  corrected.  The  alarm  contacts 
(switches)  activating  the  system  commonly  use  the  same 
instrument  as  the  variables  presented  on  the  main  panel,  or 
are  wired  in  from  remote  alarm  sensors  In  the  plant  or  field. 
The  operator  is  usually  responsible  for  st^tting  these  alarm 
contacts  and  the  operator  must  use  juc^gment  as  to  the 
actual  limits  of  the  particular  variables  that  will  ensure 
meeting  proper  operational  goals.  Each  system  is  different 
so  no  attempt  will  be  made  here  to  instruct  operating 
personnel  in  alarm  re-setting  procedures. 

Sometimes,  operators  fail  to  reset  alarm  limits  as  condi- 
tions and  judgments  change  in  the  plant.  It  is  not  uncommon 
to  see  the  annunciator  panel  lit  up,"  with  the  operator 
ignoring  all  the  alarm  conditions  as  the  normal  status  quo' 
SUCH  PRACTICE  IS  NOT  ADVISED  BECAUSE  A  TRUE 
ALARM  CONDITION  REQUIRING  IMMEDIATE  OPERATOR 
ATTENTION  MAY  BE  LOST  IN  THE  RESULTING  GENERAL 
INDIFFERENCE  TO  THE  ALARM  SYSTEM.  For  some  oper- 
ators, acknowledging  an  alarm  sound  to  get  nd  of  the  noise 
is  second  nature,  without  due  attention  to  each  and  every 
activating  condition.  Alarm  contact  limits  should  always  be 
reset  (or  deactivated)  as  necessary  to  assure  that  the 
operator  is  as  attentive  to  the  alarm  system  as  possible  to 
prevent  real  emergencies. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  382. 

19.3E  What  is  the  purpose  of  recorders? 

19.3F  What  are  the  two  types  of  charts  used  on  recorders? 

19.3G  How  are  charts  driven  in  remote  locations  whers 
there  is  no  electricity  available? 

19.3H  List  two  types  of  warnings  that  are  produced  by 
alarms. 


19.32  Automatic  Controller 

Section  19.0  explains  the  nature  of  control  systems, 
especially  as  they  are  used  in  waterworks  operations,  indi- 
cations of  proper  and  Improper  control  need  to  be  recog- 
nized even  though  actual  adjustment  of  the  controller  should 
be  left  to  a  qualified  instrument  technician.  By  shifting  to  the 
manual  mode,  you  can  bypass  the  operation  of  any  control- 
ler, whether  electric,  pneumatic,  or  even  hydraulic.  Learn 
how  to  shift  all  controllers  to  manual  operation.  This  will 
allow  you  to  take  over  control  of  a  critical  system  when 
necessary  in  an  emergency,  as  well  as  at  any  other  time  it 
suits  your  purposes.  For  example,  you  could  quickly  correct 
a  "cycling"  or  "sluggish"  recorder  indication  rather  than 
waiting  for  the  controller  to  correct  the  condition  in  time,  if  it 
does  3t  all. 

A  controller,  while  adniiitedly  "superhuman"  in  some  of  its 
abilities,  is  still  limited.  It  can  only  do  what  has  been 
programmed  to  do.  You  as  the  operator  can  exercise 
JUDGMENTbase6  on  your  experience  and  observations,  so 
do  not  hesitate  to  intervene  if  a  controller  is  not  exercising 
control  within  sensible  limits.  Of  course,  you  must  be  SURE 
of  your  conclusions,  and  competent  to  take  over  control  if 
you  decide  to  operate  manually. 

To  repeat  a  few  of  the  more  important  operational  control 
considerations,  remember  that  ^'on-off"  control  is  quite  dif- 

ERIC 


ferer.t  in  operation  than  proportional  control.  Both  methods 
may  exercise  close  control  of  a  variable;  however,  propor- 
tional control  may  be  better  suitsd  to  the  purpose.  Attempt- 
ing to  set  up  an  "on-off"  control  system  to  maintain  a  vanable 
within  too  close  a  tolerance  may  result  in  rapid  on-off 
operation  of  equipment.  Such  operation  can  damage  both 
the  equipment  and  the  switching  devices.  Therefore,  do  not 
attempt  to  set  a  level  controller,  for  instance,  to  cycle  the 
pump  or  valve  more  often  than  actually  necessary  for  plant 
operation. 

In  the  case  of  a  proportional  controller,  It  too  may  begin  to 
cycle  its  final  control  element  (pump  or  valve)  thrjugh  a  wide 
range  if  any  of  the  internal  settings,  namely  proportional 
band  or  reset,  are  adjusted  so  as  to  gain  closer  control  of  the 
variable  than  is  reasonable.  Accordingly,  it  may  be  better  to 
accommodate  to  a  small  offset  (difference  between  set- 
point  and  control  point),  than  risk  an  upset  in  control  by 
attemf:*ing  too  much  control. 

19.33  Pump  Controllers 

Control  of  pumping  systems  can  be  achieved  by  an 
automatic  controller  which  determines  the  output  of  a  vari- 
able-speed pump,  or  by  an  on-off  type  of  controller  starting/ 
stopping  the  pump(s)  according  to  a  level,  pressure,  or  flow 
measurement.  The  control  of  a  variable-speed  system  was 
discussed  earlier  in  the  description  of  the  automatic  (propor- 
tional) control  method,  so  this  section  v.  ill  restrict  comments 
tc  on-off  pump  confol. 

Usually  an  on-off  pump  control  system  responds  to  level 
changes  in  a  tank  or  a  reservoir  of  some  type.  Water  level 
can  be  sensed  directly  or  by  pressure  change  at  the  pump 
site.  The  pump  is  turned  off  or  on  as  tank  level  rises  above  or 
falls  below  pre-determined  level  or  pressure  limits.  Ccrtrol  is 
rather  simple  in  this  case. 

However,  sucr;  systems  may  include  several  extra  fea- 
tures to  ensure  fail-safe  operation.  To  prevent  the  pump 
from  running  after  a  loss  of  signal,  electrical  circuitry  should 
be  designed  so  the  pump  will  turn  OFF  on  an  OPEN  signal 
circuit,  and  ON  only  with  a  CLOSED  circuit.  Ideally,  the 
sensor  can  distinguish  between  an  open  or  closed  remote 
level/pressure  contact  and  an  open  or  shorted  telemetry 
line.  Larger  pump  systems  will  usually  have  a  low-pressure 
cut-off  switch  on  the  suction  side  to  prevent  the  pump  from 
running  when  no  water  is  available,  such  as  with  a  dry  wet 
well  or  a  closed  suction  valve. 

Pumps  may  also  be  protected  againsv  overheating, 
caused  by  continuing  to  pump  into  a  closed  discharge 
situation,  by  a  high-pressure  cut-off  switch  on  the  discharge 


339 


InstruiT.ontation  369 


piping.  Both  the  high-  and  low-pressure  switches  may  shut 
off  the  pump  through  a  time  delay  circuit,  so  that  short-term 
pressure  surges  can  be  tolerated  within  the  pump  piping. 
Usually  the  low-  or  high-pressure  switches  also  key  an  alarm 
to  notify  the  operator  of  the  condition.  For  remote  stations, 
the  plant's  mam  panel  may  include  indicator  lights  to  show 
the  pump  s  operating  condition.  Figure  19.23  shows  a 
typical  pump  control  circuitry. 

Pump  control  panels  (Figure  19.24)  may  also  include 
automatic  or  manual  sequencers.  This  provision  allows  the 
total  pump  operating  time  required  for  the  particular  system 
to  be  distributed  equally  among  all  the  pumps  at  a  pump 
station.  A  manual  switch  for  a  two-pump  station,  for  exam- 
ple, wiP  read  "1-2"  in  one  position  and  "2-1"  in  the  other 
position.  In  the  first  position,  pump  #1  is  the  *'lead"  pump 
(which  runs  most  of  the  time)  and  #2  the  "lag"  pump  (which 
runs  less).  When  the  operator  changes  the  switch  to  *'2-1," 
the  lead-lag  order  of  pump  operation  is  reversed,  as  it 
should  be  periodically,  to  keep  the  running  time  (as  read  on 
the  elapsed  time  (E.T.)  meters,  or  as  estimated)  of  both 
pumps  to  about  the  same  number  of  total  hours.  In  a  station 
with  multiple  pumping  units,  an  automatic  sequencer  regu- 
larly changes  the  order  of  the  pumps'  startup  to  maintain 
similar  operating  times  for  all  pumps. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  382. 

19.31  Under  what  conditions  might  an  operator  decide  to 
bypass  a  proportional-type  controller?  How  could 
this  be  done? 

19.3J  What  basic  principle  should  guide  you  in  program- 
ming the  frequency  of  operation  of  an  "on-off"  con- 
trol? 

1^..3K  How  can  pumps  be  prevented  from  running  upon 
loss  of  signal? 

19.3L  Mow  can  you  ensure  that  all  pumps  in  a  pump  station 
operate  for  roughly  equal  lengths  of  time? 


19.34  ^etemetering  Links  (Phone  Lines) 

Remote  monitonng  or  controlling  of  water  distribution 
system  operational  variables,  such  as  level,  pressure,  and 
flow,  may  require  the  use  of  long  signal  transmission  lines. 
These  lines  may  be  wires  (two  being  required  for  each 
circuit)  owned  by  the  water  agency  or  telephone  lines  leased 
from  the  local  telephone  company  (Figure  19.25).  This  lease 
line  arrangement  is  being  usea  by  many  utility  agencies.  In 
most  cases,  a  transmitter  generates  an  audio  frequency  or 
tone  on  Me  line.  For  example,  a  frequency  of  1000  Hz^ 
produces  a  medium  high-pitched  hum  on  the  tone  channel 
(line).  Each  variable  to  be  transmitted  and  received  has  its 
own  tone.  This  helps  limit  the  number  of  phone  lines  needed 
to  and  fronr.  the  remote  sites.  A  very  limited  numbe*"  of 
different  tones  can  be  sent  over  the  same  phone  lines  and 
then  be  unscrambled  by  their  individual  receivers.  A  remote 
sensing  and  control  station  can  send  tone  signals  to  the 
wa'.er  plant  and  simultaneously  receive  tone  signals  to  effect 
control  at  the  same  site.  An  example  would  be  a  flow/ 
pressure/level  sensing  station  across  town,  with  a  control 
valve  or  pump  there  under  remote  manual  control.  The  term 
"telemetry"  is  used  to  denote  such  use  of  remote  signaling  to 
monitor  and/or  control  remote  station  operation.  The  term 
"supervisory  control"  applies  to  the  remote  control  feature 
exercised  through  telemetry  systems. 

With  or  without  use  cf  tone  equipment  (which  mainly 
serves  to  allow  multiple  signals  on  single  phone  lines),  the 
actual  signal  is  of  the  pulse-duration  or  the  pulse-frequency 
type  in  virtually  every  application  in  waterworks.^  Pulse- 
duration,  also  called  pulse-width  or  time-duration  depending 
on  the  brand  of  equipment,  functions  by  creating  a  15 
second  (sometimes  less)  regular  signal  cycle  within  the 
transmitter.  The  value  of  the  variable  transmitted  occupies 
more  or  less  of  this  basic  time  cycle;  a  50-percent  signal 
would  produce  a  7V2-second  tone  (during  the  remaining  7V2 
seconds  the  circuit  would  be  silent).  Each  manufacturer  has 
selected  some  standard,  usable  portion  of  the  15  second 
cycle.  For  example,  one  company  uses  only  9  seconds  (from 
3  seconds  to  12  seconds)  of  the  time  to  proportion  0  to  ''90 
percent  of  th3  variable's  value.  If  the  panel  indicator  shows 
that  the  depth  of  water  in  a  remote  tank  can  range  from  0  to 
9  feet,  a  tone  lasung  6  seconds  (67  percent  signal)  out  of  the 
possible  9  seconds,  would  cause  the  indicator  to  show  a 
depth  of  water  of  6  feet.  In  any  case,  the  correspo^.ding 
receiver  is  set  up  to  accept  and  relay  the  proper  signal  to  the 
indicating/controlling  instrumentation.  This  form  of  signal 
telemetry  is  very  popular,  being  easy  to  understand,  requir- 
ing no  sophisticated  instrumentation  to  check  or  calibrate, 
and  being  virtually  insensitive  to  improper  signals  origii  .ating 
in  the  telephone  lines  or  at  the  phone  company.  A  limitation 
of  this  form  of  signal  (time-duration)  is  when  it  is  used  for  the 
'pacing'*  of  chemloal  feeders,  especially  coagulants.  During 
a  low  flow  period,  alurr  feeders  will  be  feeding  alum  intermit- 
tently which  will  produce  very  poor  coagulation/flocculation 
results.  A  loss  of  signal  or  interference  causes  the  indicator 
to  go  to  zero  or  to  maximum  scale.  If  you  have  the  opportuni- 
ty, ask  the  instrumentation  service  person  to  allow  you  to 
listen  to  a  tone  channel,  or  better,  to  a  phone  line  carrying 
several  channels. 

From  an  operational  standpoint,  there  isn't  much  you  can 
do  if  yju  lose  a  channel,"  no  matter  how  important  it  is  to 
plant  operations.  Fuse  replacement  can  be  tried,  then  a  call 


2  Hz  or  Hertz  (HURTS).    The  number  of  complete  electromagnetic  cycles  or  waves  m  one  second  of  an  electrical  or  electronic  circuit  Also 
called  the  frequency  of  the  current.  Abbreviated  Hz. 

3  Some  short-distance  signals  operate  only  by  sensing  opening  or  closing  of  an  electrical  contact,  completely  analogous  to  a  local  (in- 
plant)  level  or  pressure  switch. 


ERLC 


300 


370  Water  Treatment 


LI 


PUMP 
CONTROL 
PANEL 


MOTOR 
POWER 
CIRCUIT 


(120  VAC  60  HZ) 


L2(N) 


✓  \ 
POWER 

ON 


y^H.CA.  \     (P  B.  STATION) 

^switch; 

START  STOP 
HAND         I ^ 


FUSE 


c:;p*-M5)-i 


HP 


LP 


m 

AUTO 

— ( 

O.L.*S 

JT  Ji(  ir 


*  LEVEr.  SWITCH 
CLOSES  ON 
LOW  LEVEL, 
OPENS  ON 
HIGH  LEVEL 


r-TO 
TANK 


REFER  TO  FIG.  19.4,  page  346,  FOR  LEGEND  OF  TERMS  AND  SYMBOLS 


Fig.  19.23  Fump  control  station  diagram  (on-olf  control) 
(simplified  double-line  schematic) 


Instrumentation  371 


Fig.  19.24  Photo  of  pump  control  station 


The  plant's  instrument  air  supply  system  consists  of  a 
compressor  with  its  controls,  master  air  pressure  regulator, 
air  filter  and  air  dryer,  as  well  as  the  individual  pressure 
regulator/filters  in  the  line  at  each  pneumatic  instrument 
(Figure  19.26).  Only  the  instrument  air  is  filtered  and  dried; 
the  plant  air  usually  does  not  require  such  measures  since  it 
is  being  used  only  for  pneumatic  tools. 

As  air  passes  through  a  compressor,  it  not  only  picks  up 
oil  but  the  air's  moisture  content  is  concentrated  by  the 
compression  process.  Special  measures  must  be  taken  to 
remove  both  of  these  liquids.  You  can  remove  oil  by  filtering 
the  air  through  special  oil-absorbent  elements.  A  process 
called  DESICCATION^  can  be  used  to  remove  the  water. 
This  IS  simply  a  matter  of  either  passing  the  moisture-laden 
air  through  desiccant  columns,  which  regenerate  their  ab- 
sorption capacity  periodically  through  heating,  or  of  refriger- 
ating the  instrument  air.  The  refrigeration  method  is  based 
upon  the  principle  that  cold  air  can  hold  comparatively  little 
moisture  within  it.  You  must  recognize  that  the  capacity  of 
any  of  these  systems  of  oil  or  water  removal  is  limited  to 
amounts  of  liquid  encountered  under  normal  conditions. 

If  the  compressor  is  so  worn  as  to  pass  more  oil  than 
usual,  the  oil  separation  process  may  permit  large  amounts 
of  oil  to  pass  into  the  air  supply.  If  the  air  storage  tank 
contains  excessive  liquid  water  (due  to  irregular  or  improper 
drainage),  the  air  drying  system  may  not  handle  the  excess 
moisture.  Learn  enough  about  the  instrument  air  system  to 
be  able  to  open  the  draip  vaUes,  cycle  the  desiccator,  or 
bypass  the  tank.  In  order  to  prevent  instrumentation  prob- 
lems due  to  an  jily,  moisture-saturated  air  supply. 

Operators  should  regularly  crack  the  regulator/fil'ier  drain 
valves  at  the  site  of  the  plant  instruments.  An  unusual 
quantity  of  liquid  drainage  may  indicate  an  overloading  or 


^  Desiccation  (DESS-uh-KAY-shun),   A  prOi:ess  used  to  thoroughly  dry  air,  to  remove  virtually  all  moisture  from  air 

ER?C  3U0 


to  the  telephone  company  to  check  on  its  otatus  (phone  lines 
may  be  down  in  an  accident  or  incident),  after  which  the 
instrument  service  person  must  be  called  in.  At  times,  tone 
channels  may  be  lost  for  several  minutes  (pens  go  to  top  or 
bottom),  only  to  return  t  .ormal  service  later;  therefore,  you 
may  wish  to  try  to  wait  out  the  interruption.  An  indicator 
pointer/pen  cannot  move  from  its  last  position  during  a 
power  outage  if  the  readout  instrument  (electronic)  has  no 
internal  power.  If  you  push  a  pointer/pen  up  or  down  and  it 
remains  in  the  new  position,  you  have  an  internal  power 
problem.  Thus  a  different  action  would  then  be  required  of 
the  operator,  not  related  to  a  telemetry  problem. 

19*35  Air  Supply  Systems 

Pneumatic  instrumentation  depends  upon  a  constant 
source  of  clean,  dry,  pressurized  air  for  reliable  operation- 
Given  a  quality  air  supply,  pneumatics  can  operate  seeming- 
ly forever  without  significant  problems.  Without  a  quality  air 
supply,  operational  problems  can  be  frequent.  The  operator 
of  a  plant  is  usually  assigned  the  task  of  ensuring  that  the 
"instrument  air"  is  available  and  dry,  though  rarely  are 
operators  told  how  to  accomplish  this  (it  being  assumed 
evidently  that  clean  air  will  ''be  there'  automatically). 


372  Water  Treatment 


FLOW- 


eELD  (REMOTE)  STATION 


1 


PRES. 

FLOW 

VALVE 
CONTROL 

SYSTEM 
RESERVOIR 


-0=110  V  AC 

LEASED 
PHONE 
LINE 
(ONE  PAIR  ONLY) 


LOCAL  TELEPHONE 
COMPANY  OFFICE 
(OR  RELAY  STATION) 


NOTES: 

1.  SINGLE  PAIR  OF  PHONE 
LINES  TRANSMIT 
SEVERAL  TONE  SIGNALS 
TO/FROM  SITES 
SIMULTANEOUSLY. 

2.  TONE  UNITS  ARE 
TRANSMITTERS  (TRANS) 
OR  RECEIVERS  (RCVRS). 
POWER  SUPPLY  ALSO 
NECESSARY. 

3.  AS  SHOWN,  FIELD  STATION 
PRESSURE,  FLOW  AND  TANK 
LEVEL  MONITORED,  DIRECT 
CONTROL  EXERCISED  OVER 
FLOW  (WITH  PRESSURE  AND 
LRVEL  CHANGING  ACCORDINGLY). 


TONE 
CABINET 


PRES. 

IND. 

SET 

FLOW 

CONTROL 
STATION 


CENTRAL  CONTROL 
(WATER  PLANT  OR  STATION) 


Fig.  19.25  Diagram  of  telemetry  system 
(monitoring  and  supervisory  control) 


Instrumentation  373 


Pt  ANT 
PNEUMATIC 
SYSTEMS 


PRESSURE/ 
CONTAMINANT 
CONThOL 


FILTER 

VALVE 

— >- — 

CON- 

ACTU- 

TROLLER 

ATOR 

LEVEL 
TRANS- 
MITTER 
(BLIND) 


FILTER 
EFFLUENT 
VALVE 


PLANT 
FILTER 
/  CONTROL 


REGU- 
LATOR 


ROTAMETER 


BUBBLER  1 
->TUBE  1 


0 

GAGE(S) 


20  PSt 


FILTER/ 
REGULATORS 


(TYPICAL) 


LOCAL 

TRANS- 

3-15 PSI      TO  REMOTF 

INDICA- 

MITTER 

^  READ-OUT 

TOR  ^ 

® 

TRANS- 
DUCER 

^  PRIMARY 
ELEMENT 

PROCESS  VARIABLE  MONITORING 

PNicUMATIC 
INSTRUMENTATION 


INSTRUMENT 
AIR 


DRYER 
(REFRIG. 
OR 

ELEMENTS) 


SEPA- 
RATOR/ 
FILTER 


50  PSI 


(TYPICAL) 


MASTER 
REGULATOR 

GAGE(S)  ^ 


PLANT 

Am 


-SET 


DRAIN 


MOISTURE 
REMOVAL 


OIL  AND  PARTICULATE 
REMOVAL 


PRESSURE 
REGULATION 


50-100  PSt 


AIR 
SUPPLY 


BYPASS 

 ¥r- 

GAGE 


SAFETY 
VALVE 


RECEIVER 


COMPRESSORS 


STORAGE  TANK(S) 


DRAIN 


NOTES: 

1.  COMPRESSOR  ANO  i  ANK  OFTEN  AN  INTEGRAL  UNIT. 

J.  MOST  CRITICAL  COMPONENTS  HAVE  ALTERNATe/STANOBY  UNITS. 

3.  SOME  DRAINS  MAY  BE  AUTOMATIC  TYPE. 


Fig.  19.26  Instrument  air  system  functional  diagram 
(simplified,  not  all  valves  and  piping  shown) 

ERJC  3^4 


374  Water  Trertment 


failure  in  he  instrurrent  air  filter/drying  parts.  Also,  pneu- 
matic indicatcrs/recorders  should  be  watched  for  erratic 
pointer/pen  movements  which  may  well  be  indicative  of  air 
quality  or  supply  problems. 

The  seriousness  of  temporary  plant  or  compressor  station 
power  failures  can  be  lessened  if  you  temporarily  turn  off  all 
non-essential  usages  of  compressed  air  in  the  plant.  The  air 
storage  tank  is  usually  sized  so  that  theie  is  enough  clean, 
dry  air  on  hand  to  last  for  several  hours,  if  conserved. 
Knowing  this,  you  may  be  able  to  wait  out  a  power  failure 
without  undue  drastic  action  by  observing  remaining  avail- 
able pressure  at  the  air  supply. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  382, 

19.3M  How  are  signals  transmitted  over  lo'.g  distances, 
such  as  frt  m  a  water  storage  reservoir  to  pumps  at  a 
water  treatment  plant? 

19  3N  What  happens  to  a  remote  indicator  when  a  siqnal  is 
losf? 

19.30  What  are  the  essential  qualities  of  the  air  supply 
needed  *or  reliable  operation  of  pneumatic  instru- 
mentation pressure  systems'? 

19  3P  How  are  moisture  ana  oil  removed  from  instrument 
air'? 


19.36  Laboratory  Instruments 

This  category  of  instrumentation  includes  those  analytical 
units  usually  found  in  larger  water  treatment  pk  it  laborato- 
nes  Turbidimeters,  colorimeters  and  comparators,  pH,  con- 
ductivity (TDS),  dissolved  oxygen  (D.O.),  and  temperature 
indicators  fit  in  this  classification  of  instruments  (Figure 
19.27).  We  have  already  sf^en  that  process  models  of  each 
of  these  units  monitor  these  eame  variables  out  in  the  plant. 
Operators  rarely  are  required  to  do  anything  more  tnan 
make  periodic  readings  from  lab  instruments,  though  stand- 
ardizing the  particular  instrument  Is  often  required  before 
the  determination  of  a  sample's  turbidity  or  color  is  made. 
Preventive,  and  certainly  corrective,  maintenance  (if  any)  is 
handled  by  the  chemist,  factory  rep.  or  instrument  technician 


since  each  unit  is  quite  specialized  and  complex.  Some  of 
these  countertop  instruments  or  devices  are  quite  delicate 
and  replacement  parts,  such  as  turbidimeter  tubes  or  pH 
electrodes,  are  quite  expensive.  Moreover,  the  use  of  many 
of  these  instruments  requires  the  regular  handling  of  labora-* 
tory  glassware  and  other  breakable  items.  The  operator 
who.  through  carelessness,  lack  of  knowledge,  or  simple 
hurrying,  consistently  breaks  glassware  or  "finds  the  7* 

ERIC 


meter  broken"  does  not  become  popular  with  the  chemist, 
supervisor,  nor  the  other  operators.  The  byword  in  the  lab  is 
WORK  WITH  CAUTION.  Protect  valuable  and  essential 
equipment  and  instrumentation. 

19.37  Test  and  Calibration  Equipment 

In  most  larger  water  plant  operations,  the  plant  operating 
staff  have  little  occasion  to  use  testing  and  calibration 
meters  and  devices  on  the  plant  instrumentation  systems.  A 
trained  technician  will  usually  be  responsible  for  maintaining 
such  systems.  There  are,  however,  some  general  consider- 
ations the  operator  should  understand  concerning  the  test- 
ing and  calibration  of  plant  measuring  and  control  systemc 
With  this  basic  knowledge,  you  may  be  able  to  discuss 
needed  repairs  or  adjustments  with  an  instrument  technician 
and  perhaps  actually  assist  with  that  work.  A  greater  under- 
standing of  your  plant's  instrument  systems  may  also  enable 
you  to  analyze  instrument  problems  as  they  bear  upon 
continued  plant  operation,  to  handle  emergency  situations 
created  by  instrument  failure,  and  finally  your  skills  in 
instruTjent  testing  and  calibration  equipment  may  result  in  a 
job  promotion  and/or  pay  raise. 

The  most  useful  piece  of  test  equipment  is  the  V-O-M,  that 
is  the  Volt-Ohm-Milllammeter,  commonly  called  the  "multi- 
meter" (Figure  19.28).  To  use  this  instrument  you  will  need  a 
workable  understanding  of  electricity,  but  once  you  learn  to 
use  It.  the  V-O-M  has  potential  for  universal  usage  in 
instrument  and  general  electrical  work.  Local  colleges  and 
other  educational  institutions  may  offer  courses  in  basic 
electricity  which  undoubtedly  include  practice  with  a  V-O-M. 
You.  as  a  professional  plant/systom  operator,  are  unlikely  to 
find  technical  training  of  greater  practical  value  than  this  type 
of  course  or  program.  Your  future  use  of  test  and  calibration 
equipment  in  general  certainly  should  be  preceded  by  in- 
struction in  the  I  'ndamentals  of  electricity. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  (hose  on  page  382. 

19  3Q  Why  should  an  operator  be  especially  careful  when 
working  in  a  laboratory'? 

19. 3R  Why  should  an  operator  become  familiar  with  the 
testing  and  calibration  of  plant  measuring  and  control 
systems'? 

19.3S  What  IS  a  V-O-M'? 


Instrumentation  375 


6  "-f^'ll*  'f        OslU-~|riU-  p, 

t 


A  •  79.27   Water  laboratory  instruments 


19.4   OPERA  1 ICN  AND  PREVENTIVE  MAINTENANCE 

19.40  Proper  Care  of  Instruments 

Usually  instrumentation  systems  are  remarkably  reliable 
year  after  year,  assuming  proper  application,  setup,  oper- 
ation and  maintenance.  Measurement  systems  may  be 
found  still  in  service  at  some  utilities  up  to  50  years  after 
installation  To  a  certain  extent,  good  design  and  application 
account  for  such  long  service  life,  but  most  important  is  the 
careful  operation  and  regular  maintenance  of  the  instru- 
ment's parts  or  components.  The  key  to  such  proper  "0  & 
IS  the  operator's  practical  understanding  of  the  system. 
Operators  must  know  how  to  (1;  recognize  properly  func- 
tioning instruments,  so  as  to  prevent  prolonged  and  damag- 
ing malfunction,  (2)  shut  down  and  prepare  devices  for 
seasonal  or  prolonged  nonoperation.  and  (3)  perform  pre- 
ventive (and  rninor  corrective)  maintenance  tasks  to  ensure 
proper  operation  in  the  long  term.  By  contrast,  a  sensitive 
instrumentation  system  can  be  quite  easily  ruined  in  short 
order  with  neglect  of  ANY  ONE  of  the  three  principles  listed 

Or.arators  should  be  famiiiar  with  the  "Technical  Manual" 
(also  called  the  "Instruction  Book"  or  "Operating  Manual")  of 
each  piece  of  equipment  and  instrument  encountered  in  a 
plant.  Each  manual  will  Wave  a  section  devoted  to  the 
operation  of  some  component  of  a  measuring  or  control 
system  (though  frequently  not  for  the  entire  system).  De- 
tailed descriptions  of  maintenance  tasks  and  operating 
checks  will  usually  be  found  in  the  same  section  of  the 
manual.  Depending  upon  tho  general  type  of  ins*a  .nt 
(electro-mechanical,  pneumatic,  or  electronic),  the  suggest- 
ed frequency  of  the  operation  and  maintenance/checking 
tasks  can  range  from  none  to  monthly.  Accordingly,  this 
section  of  the  course  only  addresses  itself  to  those  general 
tasks  an  operator  might  be  expected  to  perform  to  operate 
and  maintain  instrumentation  systems.  These  general  tasks 
can  be  summed  up  from  the  OPERATIONS  STANDPOINT 
AS  LEARNING  AND  CONSTANT  ATTENTION  TO  WHAT 


CONSTITUTES  NORMAL  FUNCTION,  AND  FROM  A  MAIN- 
TENANCE STANDPOINT,  ENSURING  PROPER  AND  CON- 
TINUING PROTECTION  AND  CARE  uh  EACH  COMPO- 
NENT 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  382 

19  4A  List  the  three  principles  which  are  the  keys  to  proper 
instrument  0  &  M. 

19.4B  What  generally  .s  expected  of  an  operator  of  instru- 
mentation systems  from  (1)  an  operations  standpoint 
and  (2)  a  maintenance  standpoint? 


19.41   Indications  of  Proper  Function 

The  usual  pattern  of  day-to-day  operation  of  every  meas- 
uring and  control  system  in  a  plant  should  become  so 
familiar  to  all  operators  that  they  almost  unconsciously 
sense  any  significant  change.  This  will  be  especially  evident 
and  true  for  systems  with  recorders  where  the  pen  trac3  is 
visible.  An  operator  should  watch  indicators  and  controllers 
for  their  characteristic  actions.  With  analog  instruments, 
each  pen  or  pointer  may  display  its  own  unique  characteris- 
tics (though  some  may  be  virtually  the  same).  Thus,  the  pen 
for  "Flow  Recorder  A"  may  normally  scribe  out  a  one-eight- 
inch  (3  mm)  wide  track  due  to  inherent  sensitivity  or  flow 
variations,  whereas  "Level  Recorder  B"  may  normally  pro- 
duce a  trace  as  steady  as  a  rock  (Figure  19.29).  However,  if 
the  flo^v  pen  is  noticed  as  steady  one  day,  or  the  level 
indicciion  widens  due  to  a  quiver,  then  the  operator  should 
suspect  a  problem.  In  this  regard,  signs  of  possible  improper 
function  (though  not  NECESSARILY  so)  include  (Figure 
19.29): 


39« 


Controls,  lacks  and  Indicator 


Has  12-positions.  May  be  turned  in  either 
direction.  There  are  5-voltage  positions. 
4-direct  current  positions,  and  three  re- 
sistance positions  used  to  select  desired 
ranges. 

Has  3-positions' -D.C  +  D.C.  and  A.C.  To 
measure  DC  voltage,  current  or  resistance, 
the  function  switch  is  set  to  -D  C.  or  -t-D.C. 
according  to  the  polarity  of  the  applied 
current  or  voltage.  Turning  this  switch  n 
verses  tlie  test  lead  connections  without 
removing  the  leads  from  the  circuit  under 
test. 

This  control  is  used  to  compensate  for  vari- 
ation in  the  voltage  of  the  interna!  batteries 

There  aie  8-jacks.  vo  in  each  corner  ol  the 
sub-panel  Thev  pru\ide  an  electrical  con- 
nection to  the  tost  leads. 

4-1  2"  indicating  instrument.  Ha^  a  scale 
for  each  function  and  range. 


397 


ERIC 


1.  Range  Switch: 

2.  Function  Switch: 


3.  ZERO  OHMS: 

4.  Circuit  Jacks: 

5.  Meter: 


Instrumentation  377 


MEASURlNG/MONiTORING  SYSTEMS 


1  Normal  function:  Ink  trace  dark  and  steady,  variable  withm  expected  range. 

2.  Pen  skips.  Pen  dirty,  dry,  or  not  on  chart;  ciean  pen/tubing,  re-ink,  check  contact. 

3.  Wide  trace:  "No:3y"  system,  too  sensitive;  causes  inking  problems,  can  be  adjusted  out. 

4.  Flat  trace  (upscale):  OK  if  usual  for  system,  otherwise  check  sensor  or  process. 

5.  Trace  to  max.  scale:  Instrumentation  problem  (sudden  or  constant  100%  unlikely). 

6.  Trace  to  min.  scale:  Process  or  sensor  off,  aiso  may  be  signal  loss. 


CONTROL  SYSTEMS 

r-SET-POINT 


©©©00© 


1  Normal  control:  Pen  trace  steady,  process  or  set-point  changes  controlled  well. 

2.  Normal  control:  Small  oscillations  normal  with  process  or  set-point  change. 

3.  Abnormal  control:  Excessive  departure  from  set-point,  "sloppy"  controller. 
4  Cycling  or  hunting:  Unstable  control,  controller  settings  need  adjustment. 
5.  Damped  oscillations:  Process  upset,  control  OK  If  acceptable  for  process. 

S.  Worsening  oscillations*  Rystem  out  of  control  due  to  process  or  set-pomt  change,  service 
required.  Do  not  use  "auto,"  switch  to  "manual"  <^''  itrol. 


Fig.  19,29  Indications  of  proper  and  abnormal  function 
(systems  with  strip-chart  recorders;  circular  chart  indications  are  similar) 


378  Water  Treatment 


1  Very  flat  or  steady  pen  trace  is  the  system  working  at  all, 
or  is  the  variable  really  that  constant?); 

2.  Excessive  pen/pointer  quiver  (causes  undue  wear  on 
parts,  can  usually  be  adjusted  out);  and 

3  Constant  or  periodic  hunting,  or  spikes,  In  a  pen/pointer 
(improper  adjustment,  control  or  other  problem). 

Additionally,  U  is  not  uncommon  for  a  pointer  or  pen  to 
become  stuck  at  some  position  on  its  scale,  usually  at  the 
extreme  limits  of  movement.  Pens  are  particularly  prone  to 
sticking,  getting  hung-up  on  the  chart  edge  or  in  a  tear  or 
hole.  Therefore,  operators  should  become  observant  not 
only  of  unusual  pointer/pen  movement,  but  unusual  LACKoi 
movement  by  indicators  and  recorders.  In  the  case  of 
recorders,  you  may  LIGHTLY  TAP  an  instrument  to  check  on 
the  pointer/pen  motion.  If  a  gentle  tap  does  not  cause  slight 
movement,  a  problem  may  well  exist.  Anyone  hitting  or 
shaking  a  delicate  instrument  hard,  however,  m  an  attempt 
to  check  it  cut,  only  reveals  a  lack  of  training  in  this  area. 

At  times,  firmly  pushing  an  instrument  into  its  case,  or 
closing  the  door  completely,  may  close  the  interlock  switch 
and  switch  the  system  on,  as  designed.  However,  jamming 
the  device  into  its  case,  or  slamming  a  door  is  NEVER 
considered  proper  action.  If  a  device  still  doesn't  begin  to 
work,  check  the  power  connection  and  instrument  fuse(s),  if 
any. 

For  pneumatic  systems,  an  unnoticed  failure  of  the  instru- 
ment air  supply  is  the  most  common  reason  for  an  inopera- 
ble instrument.  Such  a  failure  of  the  air  supply  extends  the 
inoperable  situation  to  all  pneumatic  systems  in  the  plant. 
Complete  functional  loss  of  a  singie  pneumatic  instrument  is 
rather  rare,  but  erratic  operation  is  not  uncommon,  due  to 
previously  mentioned  water  or  oil  in  the  air  supply. 

One  of  the  surest  indications  of  a  serious  electrical 
problem  in  instrument  or  power  circuits  is,  of  course,  smoke 


and/or  a  burning  odor.  Such  signs  of  a  problem  should  never 
be  ignored.  Smoke/odor  means  heat,  and  no  device  can 
operate  long  at  unduly  high  temperatures.  Any  electrical 
equipment  which  begins  to  show  signs  of  excessive  heating 
must  be  shut  down  inimedlately,  regardless  of  how  critical  it 
is  to  plant  operation.  Overheated  equipment  will  very  likely 
fail  soon  anyway,  with  the  damage  being  aggravated  by 
continued  usage.  Fuses  and  circuit  breakers  are  not  always 
designed  to  de-energize  circuits  before  damage  occurs,  and 
cannot  be  relied  upon  to  do  so. 

Finally,  operators  frequently  forget  to  reset  an  individual 
alarm,  either  after  an  actual  occurrence  or  after  a  system 
test.  This  is  especially  prevalent  when  an  annunciator  panel 
is  allowed  to  operate  day  after  day  with  lit-up  alarm  indica- 
tors (contrary  to  good  practice)  and  one  more  light  is  not 
easily  noticeable  Also,  when  a  plant  operator  must  be  away 
from  the  mam  duty  station,  the  system  may  be  set  so  the 


5  Desiccant  (DESS-uh-kant)    A  drying  agent  which  is  capable  of 
enclosure. 

ERIC 


audible  part  of  the  alarm  system  is  temporally  squelched. 
When  the  operator  returns,  the  audible  alarm  system  may 
inadvertently  not  be  reset.  In  both  instances  (individual  or 
collective  loss  of  audible  alarm)  the  consequences  of  such 
inattention  can  be  serious.  Therefore,  get  in  the  habit  of 
checking  and  re-setting  your  annunciator  system  often. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  382. 

19  4C  List  three  possible  signs  of  an  improperly  functioning 
flow  recorder. 

19  4D  Where  or  how  are  recording  pens  most  likely  to 
become  stuck  or  "hung-up?" 

19  4E  What  is  a  common  reason  for  nonoperation  of  pneu- 
matic systems? 

19.4F  What  IS  an  indication  of  a  serious  problem  in  an 
electrical  instrument  or  power  circuit'^ 


19,42   Startup/Shutdown  Considerations 

The  startup  and  periodic  (seasonal)  or  prolonged  shut- 
down of  instrumentation  equipment  requires  very  little  extra 
work  by  the  operator.  Startup  is  limited  mainly  to  undoing  or 
reversing  the  shutdown  measures  taken. 

When  shutting  down  any  pressure,  flow  or  level  measur- 
ing system,  valve  off  the  access  of  water  to  the  measuring 
element  Exercise  particular  care,  as  explained  previously, 
regarding  the  ORDER  in  which  the  valves  are  manipulated 
for  any  flow-tube  installation.  Also,  the  power  source  of 
some  instruments  may  be  shut  off,  unless  the  judgment  is 
made  that  keeping  an  instrument  case  warm  (and  thus  dry) 
IS  in  order.  In  such  cases,  constantly  moving  parts,  such  as 
chart  drives,  should  be  turned  off  With  an  electrical  panel 
room  containing  instrumentation,  it  is  good  practice  to  leave 
some  power  components  on  (such  as  a  power  transformer) 
to  provide  space  heat  for  moisture  control.  In  a  known  moist 
environment,  sealed  instrument  cases  may  be  protected  for 
a  while  w:th  a  container  of  DESICCANT^  ("indicating  silica 
gel"  which  is  blue  if  O.K.  and  pink  when  the  moisture- 
absorbent  capacity  is  exhausted). 

Though  preventing  the  access  of  insects  and  rodents  into 
any  area  appears  difficult,  general  cleanliness  seems  to  help 
considerably  Rodenticides  are  available  to  control  mict,  this 
IS  good  preventive  maintenance  practice  in  any  electrical 
space  Mice  will  chew  off  wire  and  transformer  insulation, 
and  may  urinate  on  other  insulator  material,  leading  to 
serious  damage. 

Nest-building  activities  of  some  birds  can  also  be  a 
problem  Screening  buildings  and  equipment  against  entry 
by  birds  has  become  a  design  practice  of  necessity.  Insects 
and  spiders  are  not  known  to  caise  specific  functional 
problems,  but  startup  and  operation  of  systems  invaded  by 
ants,  bees,  or  spiders  should  await  cleanup  of  each  such 
component  of  the  system.  All  of  these  pests  can  bite  or 
sting,  so  take  care! 

With  pneumatic  instrumentation,  it  is  desirable  to  purge 
each  device  with  dry  air  before  shutdown.  This  measure 
helps  rid  the  individual  parts  of  residual  oil  and  moisture  to 
minimize  internal  corrosion  while  standing  idle.  As  before. 

removing  or  absorbing  moisture  from  the  atmosphere  in  a  small 


'iO'J 


Instrumentstion  379 


periodic  blow-off  of  air  receivers  and  filters  keeps  these 
liquids  out  of  the  instruments  to  a  large  degree.  Before 
shutdown,  however,  extra  attention  should  be  paid  to  instru- 
ment air  quality  for  purging.  Before  startup  each  filter/ 
receiver  should  again  be  purged. 

Finally,  pay  attention  to  the  pens  and  chart  drives  of 
recorders  upon  shutdown.  Ink  containers  (capsules)  may  be 
removed  if  deemed  necessary,  and  chart  drives  turned  off.  A 
dry  pen  bearing  against  one  track  (such  as  zero)  of  a  chart 
for  weeks  on  end  is  an  invitation  to  startup  problems.  Re- 
inking  and  chart  replacement  at  startup  is  an  easy  matter  if 
the  proper  shutdown  procedures  were  followed. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  382. 

19.4G  How  can  moisture  be  controlled  in  an  instrument*? 

19.4H  Why  should  pneumatic  instrumentation  be  purged 
before  shutdown? 


19.43  Maintenance  Procedures  and  Records 

Preventive  maintenance  means  that  attention  is  given 
periodically  to  equipment  in  order  to  PREVENT  future  mal- 
functions. Ccjrective  maintenance  involves  actual,  signifi- 
cant repairs  which  are  beyond  the  scope  of  this  work  and 
responsibility  of  the  operator  (in  most  cases).  Routine  oper- 
ational checks  are  part  of  all  P.M.  (preventive  maintenance) 
programs  in  that  a  potential  problem  may  be  discovered  and 
thereby  corrected  before  it  becomes  serious. 

P.M.  duties  for  instrumentation  should  be  included  in  the 
plant's  general  P.M.  program.  If  your  plant  has  no  formal, 
routine  P.M.  program,  it  should  have!  Such  a  program  must 
be  set  up  "on  paper.**  That  is,  the  regular  duties  required  are 
pnnted  on  forms  or  cards  which  the  operator  (or  technician) 
uses  as  a  reminder,  guide,  and  record  of  P.M.  tasks  per- 
formed. Without  such  explicit  measures,  experience  shows 
that  preventive  maintenance  will  almost  surely  be  put  off 
indefinitely.  Eventually,  the  pre:;s  of  critical  corrective  main- 
tenance (often  due  to  lack  of  preventive  maintenance!)  and 
even  equipment  replacement  projects  may  well  eliminate 
forever  any  hope  of  a  regular  P.M.  program.  The  fact  that 
instrumentation  is  usually  very  reliable  (being  of  quality 
design)  may  keep  it  running  long  after  r  on-maintained 
pumps  and  other  equipment  have  failed.  Nevertheless, 
instrumentation  does  require  proper  attention  periodically  to 
maxim,ze  its  effective  life.  P.M.  tasks  and  checks  on  modern 
instrument  systems  are  quite  minimal  (even  virtually  non- 
existent on  some),  so  there  are  no  valid  reasons  for  failing  to 
ever  perform  these  tasks. 

19.4>!  Operational  Checks 

Operational  checks  are  most  efficiently  performed  by 
always  observing  each  system  f  .r  its  continuing  signs  of 
normal  operation.  However,  some  measuring  systems  may 
be  cycled  within  their  range  of  action  as  a  check  on  the 
responsiveness  of  components.  For  instance,  if  a  pressure- 
sensing  system  indicates  only  one  pressure  for  months  on 
end,  and  some  doubt  arises  as  to  whethP''  it's  working  or 
not,  the  operator  may  bleei  off  a  little  pressure  at  the 
pnmary  element  to  produce  a  small  fluctuation.  Or,  if  a  flow 
has  appear'id  constant  for  an  overly  long  period,  the  bypass 
valve  in  the  D.P.  (Differential  Pressure)  cell  piping^  may  be 


cracked  open  briefly  to  cause  a  drop  in  reading.  Be  sure  you 
crack  the  bypass  valve.  If  you  open  the  wrong  valve  the 
pressure  may  be  excessive  and  be  beyond  the  rang3  of  the 
D.P.  cell  which  could  cause  some  problems.  A  float  suspect- 
ed of  being  stuck  (very  constant  level  indication)  may  be 
freed  by  jiggling  its  cable,  or  other  measures  taken  to  cause 
a  slight  fluctuation  in  the  reading. 

Whenever  an  operator  or  a  technician  disturbs  normal 
operation  during  checking  or  for  any  reason,  operating 
personnel  must  be  informed  —  ideally  PRIOR  TO  the 
disturbance.  If  a  recorder  trace  is  altered  from  its  usual 
pattern  in  the  process,  the  person  causing  the  upset  should 
initial  the  chart  appropnately,  with  time  noted.  Some  plants 
require  operators  to  mark  or  date  each  chart  at  midnight  (or 
noon)  of  each  day  for  easy  filing  and  retrieval. 

In  the  case  where  a  pen/pcinter  is  thought  to  be  stuck 
mechanically,,  that  is,  it  does  not  respond  at  all  to  simulated 
or  actual  change  in  the  measured  variable,  it  is  normally 
permissible  to  open  an  instrument's  case  and  try  to  move 
the  pointer/pen,  BUT  ONLY  TO  THE  MINIMUM  extent 
possible  to  establish  its  freedom.  Funher  deflection  may  well 
bend  or  break  the  device's  linkage.  A  "dead  pen"  often  is  due 
only  to  loss  of  power  or  air  to  the  readout  mechanism.  Any 


hard  or  repeated  striking  of  an  instrument  to  make  it  work 
identifies  the  striker  as  ignorant  of  good  operational  practice 
and  can  rum  the  equipment.  Insertion  of  tools  into  an 
instrument  case  in  a  random  "fix-if  attempt  could  damage 
the  instrument.  Generally  speaking,  any  extensive  operating 
check  of  instrumentation  should  be  performed  by  the  instru- 
ment technician  during  routine  P.M.  prog-am  activities. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  382. 

19.41  Why  should  regular  preventive  maintenance  duties 
be  printed  on  forms  or  cards? 

19  4J  How  are  operational  checks  performed  on  instru- 
ment equipment'' 

19  4K  What  should  be  done  if  a  recorder  trace  is  altered 
from  Its  usual  pattern  during  the  process  of  checking 
an  instrument? 

19.45  Preventive  Maintenance 

The  technical  manual  for  each  item  of  instrumentation  in 
your  plant  should  be  available  so  you  can  refer  to  it  for  0  &  M 
purposes.  When  a  manual  cannot  be  located,  contact  the 


6  There  is  no  similar  easy  'vay  to  check  a  propeller  meter's  response. 


ERIC 


4Ui 


380  Water  Treatment 


manufacturer  of  the  unit.  Be  sure  to  give  all  relevant  serial/ 
model  numbers  in  your  request  for  the  manual.  Request  tv\/o 
manuals,  one  to  use  and  one  to  put  in  reserve.  All  equipment 
manuals  should  be  kept  in  one  protected  location,  and 
Signed  out  as  needed.  Become  familiar  vjiXh  the  sections  of 
these  manuals  related  tc  0  &  M,  and  follow/  their  procedures 
and  recommendations  closely. 

A  good  practice  is  to  have  on  hand  any  supplies  and  spare 
parts  which  are  or  may  be  necessary  for  instrument  oper- 
ation (such  as  charts)  or  service  (such  as  pens  and  pen 
cleaner)  Some  technical  manuals  contain  a  list  of  recom- 
mended spare  parts  which  you  could  use  as  a  guide.  Try  to 
obtain  these  supplies/parts  for  your  equipment.  A  new  pen 
on  hand  for  a  critical  recorder  can  be  a  lifesaver  at  times. 

Since  P  ^/l.  measures  can  be  so  diverse  for  different  types, 
brands,  and  ages  of  instrumentation,  only  the  few  general 
considerations  applicable  to  all  will  be  covered  in  this 
section. 

1.  Protect  all  instrumentation  from  moisture  (except  as 
needed  by  design),  vibration,  mechanical  shock,  vanoal- 
ism  (a  very  real  problem  m  the  field)  and  unauthorized 
access. 

2  Keep  instrument  component?  clean  on  the  outside,  and 
closed/sealed  against  inside  contamination.  This  specifi- 
cally includes  spider  webs  and  rodent  wastes. 

3.  DON'T  presume  to  lubricate,  adjust,  fix,  calibrate,  free- 
up,  or  modify  any  component  of  a  system  arbitrarily.  If 
you  are  not  qualified  to  take  any  of  these  measures,  then 
don't  do  It. 

4  DO  keep  record  pens  and  charts  functioning  as  designed 
by  frequent  checking  and  service,  bleed  pneumatic  sys- 
tems regularly  as  instructed,  ensure  continuity  of  power 
for  electncal  devices,  and  don't  neglect  routine  analytical 


instrument  cleanings  (such  as  turbidimeters)  and  stand- 
ardizing duties  as  required  by  your  own  plant's  estab- 
lished procedures. 

As  a  final  note,  it  is  a  good  idea  to  get  to  know  and 
cooperate  fully  with  your  plant's  instrument  service  person. 
Good  communication  between  this  person  and  the  operating 
staff  can  only  result  in  a  better  all-around  operation.  If  your 
agency  is  too  small  to  staff  such  a  specialist  (most  are),  it 
may  be  a  good  idea  to  enter  into  an  instrumentation  service 
contract  with  an  established  company  or  possibly  even  with 
the  manufacturers  of  the  majority  of  the  components.  With 
rare  exceptions,  general  maintenance  persons  (even  jour- 
neyman electricians)  are  not  qualified  to  perform  extensive 
maintenance  on  modern  instrumentation.  Be  sure  that 
someone  takes  good  care  of  your  instruments  and  they  will 
take  good  care  of  you 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  383. 

19  4L  How  can  the  technical  manual  for  an  instrument  be 
obtained  if  the  only  copy  in  a  plant  is  lost'' 

19  4M  What  instrument  supplies  and  spare  parts  should 
always  be  available  at  your  plant? 

19.5   ADDITIONAL  READING 

1   TEXAS  MANUAL  Chapter  1 4,  "'Instrumentation.' 

2.  AUTOMATION  AND  INSTRUMENTATION  (M2).  Obtain 
from  Computer  Services,  American  Water  Works  Associ- 
ation, 6666  West  Quincy  Avenue,  Denver,  Colorado 
80235.  Order  No.  30002.  Price  to  members,  $18.00; 
nonmembers.  $23.00 


Bud  of  U^^mti^2  Ic^^owv 

OK 

IN^TCUMeMrAriOM 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  1 9,  INSTRUMENTATION 

(Lesson  2  of  2  Lessons) 


Wnte  the  answers  to  these  questions  in  your  notebook 
before  continuing  with  the  Objective  Test  on  page  383.  The 
question  numbering  continues  from  Lesson  1 . 

8  What  are  the  advantages  and  limitations  of  analog 
versus  digital  indicators? 

9  Why  is  it  poor  practice  to  ignore  many  of  the  lamps  that 
are  "lit  up"  (alarm  conditions)  on  an  annunciator  paneP 

10  How  should  the  constantly  "lit  up"  lamps  (alarm  condi- 
tions) on  an  annunciator  panel  be  handled? 

11  What  controls  are  available  to  protect  pumps  from 
damage? 


12  What  problems  are  created  by  oil  and  moisture  in 
instrument  air,  and  how  can  these  contaminants  be 
removed'^ 

13.  Why  should  plant  measuring  and  control  systems  be 
reQjlarly  tested  and  periodically  calibrated'? 

1 4  V'hat  could  cause  erratic  operation  of  pneumatic  instru- 
ments'? 

15.  Why  should  insects  and  rodents  be  kept  out  of  instru- 
ments'? 

16  How  could  you  tell  if  a  float  might  be  stuck  and  how 
would  you  determine  if  it  was  actually  stuck? 


Instrumentation  381 


SUGGESTED  ANSWERS 

Chapter  19  INSTRUMENTATION 


ANSWERS  TO  QUESTIONS  IN  LESSON  1 

Answers  to  questions  on  page  343. 

19.0A  Measurement  instruments  can  be  considered  an 
extension  of  your  human  sens.^s  because  they  Cc.n 
perform  the  same  duties  as  your  eyes  and  ears  can 
directly. 

19.0B  Water  treatment  processes  and  equipment  that 
could  be  monitored  or  controlled  by  measurement 
and  control  systems  include  influent  and  effluent 
flows,  basin  levels,  pump  operation,  chemical  feed- 
ers and  filter  valves. 

1 9.0C  An  advantage  of  instruments  over  our  senses  is  that 
instruments  provide  quantities  or  measurable  infor- 
matio.i,  whereas  only  qualitative  information  is  avail- 
able from  our  senses. 

1 9.0D  The  anabg  readout  of  an  instrument  has  a  pointer  (or 
other  indicating  means)  that  reads  against  a  dial  or 
scale. 

Answers  to  questions  on  page  345. 

19.0E  An  on-off  type  "controller"  controls  the  automatic 
starting-stopping  of  a  pump  or  a  chemical  feeder 
motor. 

19.0F  Examples  of  "proportional  control"  in  waterworks 
operations  include:  (1)  chlorine  residual  analyzer/ 
controller;  (2)  chemical  feed,  flow  paced  (open  loop); 
(3)  pressure-  or  flow-regulating  valves;  (4)  continu- 
ous level  control  of  filter  basins;  (5)  variable-speed 
pumping  system  for  flow  control. 

19.0G  The  motor  control  station  provides  for  on-off  oper- 
ation of  electric  motors. 

Answers  to  questions  on  page  347. 

19.1  A  The  general  principles  for  safe  performance  on  the 
job  are  to  ALWAYS  avoid  unsafe  acts  ana  correct 
unsafe  conditions. 

19  IB  Electrical  shock  can  cause  death  by  asphyxiation 
and/or  burning. 

19.1C  An  electrical  "explosion"  could  shower  you  with  mol- 
ten metal,  startle  you  into  a  bumped  head  or  elbow, 
or  cause  a  bad  fall. 

Answers  to  questions  on  page  348. 

19.1D  Operators  should  be  especially  careful  when  working 
around  powered  automatic  mechanical  equipment 
because  the  equipment  could  start  unexpectedly  and 
cause  senous  injury. 

19,1E  The  purpose  of  an  electrical  lock-out  device  is  to 
positively  prevent  the  operation  of  an  electrical  cir- 
cuit, or  to  de-energize  the  circuit  temporarily. 

19  IF  If  electrical  current  flows  through  your  upper  body, 
electrical  shock  could  harm  your  heart  and/or  your 
head. 

19.1G  Thin  rubber  or  plastic  gloves  can  be  worn  to  reduce 
markedly  your  chances  of  electrical  shock. 


Answers  to  questions  on  page  349. 

19  2A  A  sensor  is  the  primary  element  that  measures  a 
vanable.  The  sensor  is  often  a  transducer  of  some 
type  that  converts  energy  of  one  kind  into  some  other 
form  to  produce  a  readout  or  signal. 

19.2B  Pressure  is  measured  by  the  novemen:  of  a  f'axible 
element  or  a  mechanically  deformable  device  sub- 
jected to  the  force  of  the  pressure  being  measured. 

19.2C  Some  sensors  are  fitted  with  surging  and  overrange 
protection  to  limit  the  effect  of  press^'re  spikes  or 
water  hammer  on  the  sensor. 

Answers  to  questions  on  page  355. 

19  2D  Liquid  level  sensors  include  floats,  displacers. 
probes,  pressure  sensors,  and  bubbler  tubes. 

19.2E  A  signal  can  be  generated  by  a  float  element  by 
attaching  the  float  to  a  steel  tape  or  cable  that  is 
wrapped  around  a  drum  or  pulley.  The  level  sensed 
is  transmitted  as  a  signal  (electrical)  proportional  to 
the  rotation  (position)  of  the  pulley  or  drum. 

19-2F  Probes  are  used  instead  of  mechanical  systems  to 
measure  liquid  levels  in  sealed  or  pressurized  tanks, 
or  with  chemicc.3ly-active  liquids. 

19.2G  A  bubbler  measures  the  level  of  a  liquid  by  sensing 
(measuring)  air  pressure  necessary  to  cause  bubbles 
to  just  flow  out  the  end  of  the  tube. 

Answers  to  questions  on  page  360. 

19.2H  The  two  types  of  flow  readings  are  (1)  rate  of  flow 
and  (2)  total  flow  (volume). 

19  21  The  two  main  types  of  larger  flow  measurement 
devices  are  (1)  velocity  sensing  and  (2)  differential- 
pressu»'e  sensing.  Magnetic  and  ultrasonic  devices 
are  also  used. 

19.2J  Smaller  service  meters  are  one  of  the  positive- 
displacement  types  of  total  flow  meters. 

19.2K  Velocity-sensing  devices  measure  flows  by  sensing 
the  rate  of  rotation  of  a  special  impeller  placed  within 
the  flowing  system. 

19.2L  Flows  are  measured  with  ventun  meters  by  sensing 
the  pressure  differential  between  the  water  pressure 
l^efore  the  restnction  in  the  meter  or  tube,  and  the 
pressure  within  the  restriction. 

Answers  to  questions  on  page  362. 

19.2M  Chemical  feed  rates  are  measured  on  a  weight  or 
volumetric  basis  if  the  chemical  is  in  a  dry  solid  form. 
If  chemical  is  in  liquid  form,  ^  volumetric  flow  device 
such  as  a  rotameter  may  be  used. 

19.2N  Process  variables  commonly  measured  and/or  con- 
trolled by  instruments  include  turbidity,  pH,  chlorine 
residual,  fluoride,  electrical  conductivity,  hardness, 
alkalinity  and  temperature. 

19.20  Values  measured  at  one  site  are  transmitted  by  a 
signal  to  a  receiver  at  a  remote  location. 


403 


382  Water  Treatment 


19. 2P  The  two  general  systems  used  to  transmit  measure- 
ment signals  are  electrical  and  pneumatic  systems. 


ANSWERS  TO  QUESTIONS  IN  LESSON  2 

Answers  to  questions  on  page  364. 

19.3 A  The  purpose  of  indicators  is  to  give  a  visual  presen- 
tation of  a  variable's  value,  either  as  an  analog  cr  as 
a  digital  display. 

19.3B  An  analog  display  uses  some  type  of  pointer  (or 
other  indicator)  against  a  scale. 

19.3C  Recorders  are  usually  found  in  a  central  location  at  a 
water  treatment  plant. 

19.3D  Factors  that  can  cause  electronic  instrument  prob- 
lems include  temporary  power  failures,  tripped  panel 
circuit  breakers,  voltage  surges  (or  lightning)  result- 
ing in  blown  fuses,  and  excessive  heat. 

Answers  to  questions  on  page  368. 

19.3E  Recorders  are  indicators  designed  to  show  how  the 
value  of  the  variable  has  changed  with  time, 

19.3F  Recorder  charts  may  be  circular  or  strip  types. 

19.3G  In  remote  locations  where  no  electricity  is  available, 
charts  are  driven  by  hand-v/ound  drives  or  batteries. 

19.3H  Alarms  may  produce  either  visual  and/or  audible 
signals. 

Answers  to  questions  on  page  369. 

19.31  An  operator  might  bypass  a  proportional-type  con- 
troller in  an  emergency  or  when,  in  the  judgment  of 
the  operator,  the  controller  is  not  exercising  control 
within  sensible  limits.  To  bypass  a  controller,  switch 
to  the  manual  mode  of  operation. 

19.3J  "On-off"  controls  should  be  programmed  to  operate 
or  cycle  associated  equipment  on  and  off  no  more 
often  than  actually  necessary  for  plant  or  system 
operation. 

19.3K  Pumps  can  be  prevented  from  running  -jpon  loss  of 
signal  by  electrical  circuitry  designed  so  the  pump 
will  turn  OFF  on  an  OPEA/ signal  circuit  and  OA/ only 
with  a  CLOSED  circuit. 

19.3L  Pumps  in  a  pump  station  can  be  operated  for  si.milar 
lengths  of  time  by  the  use  of  manual  or  automatic 
"sequencers"  which  switch  different  pumps  to  the 
"lead"  pump  position  and  the  other(s)  to  the  "lag" 
position  periodically. 

Answers  to  questions  on  page  374. 

19.3M  Signals  are  transmitted  over  long  distances  by  the 
use  of  signal  tra'^smission  lines.  These  lines  may  be 
wires  owned  by  the  water  agency,  or  telephone  lines 
leased  from  the  local  telephone  agency.  Radio  or 
microwave  transmission  is  sometimes  used. 

19.3N  A  loss  of  signal  causes  the  indicator  to  go  to  zero  or 
to  maximum  scale,  depending  on  type  of  signal. 

19.30  Pneumatic  instrumentation  pressure  systems  must 
have  a  constant  source  of  clean,  dry,  pressurized  air 
for  reliable  operation. 

19.3P  Oil  is  removed  by  filtration  through  special  oil-absor- 
bent elements,  and  a  dryer  desiccator  or  refrigera- 
tion is  used  to  remove  moisture  from  instrument  air. 

O 

ERLC 


Answers  to  cjestions  on  page  374. 

19.30  Care  must  be  exercised  when  working  in  the  labora- 
tory so  as  not  to  break  t.he  sensitive  instruments, 
delicate  equipment,  or  fragile  glassware, 

19.3R  Operators  should  become  familiar  with  the  testing 
and  calibration  of  plant  measuring  and  control  sys- 
tems in  order  to  assist  instrument  technicians,  and  to 
better  understand  the  plant's  instrumentation  sys- 
tem. Also,  development  of  skills  in  instrument  testing 
and  calibration  equipment  may  result  in  a  job  promo- 
tion and/or  pay  raise. 

19.3S  V-O-M  stands  for  Volt-Ohm-Milliammeter,  conrnonly 
referred  to  as  a  multi-meter. 

Answers  to  questions  on  page  375. 

19.4A  The  three  principles  which  are  the  keys  to  proper 
instrument  0  &  M  are: 

1.  Recognizing  properly  functioning  instruments,  so 
as  to  prevent  prolonged  and  damaging  malfunc- 
tions, 

2.  Shutting  down  and  preparing  devices  for  seasons 
or  prolonged  nonoperation,  and 

3.  Performing  preventive  (and  minor  corrective) 
maintenance  tasks  to  ensure  proper  operation  in 
the  long  term. 

19.4 B  General  tasks  expected  of  operators  of  instrumenta- 
tion systems  can  be  summed  up  (1)  from  an  oper- 
ations standpoint  as  learning  and  constant  attention 
to  what  constitutes  normal  function,  and  (2)  from  a 
maintenance  standpoint,  as  ensuring  proper  and 
continuing  protection  and  care  of  each  component. 

Answers  to  questions  on  page  378. 

19.40  Three  signs  tiiat  a  flow  recorder  may  not  be  function- 
ing properly  are: 

1.  Very  flat  or  steady  pen  trace  (is  the  system 
working  at  all.  or  is  the  variable  really  that  con- 
stant?); 

2.  Excessive  pen/pointer  quiver  (causes  undue  wear 
on  parts,  can  usually  be  adjusted  out);  and 

3.  Constant  or  periodic  hunting,  or  spikes,  in  a  pen/ 
pointer  (improper  adjustment,  control  or  other 
problem). 

19.40  Recording  pens  are  most  hkely  to  become  stuck  or 
"hung-up"  on  the  chart  edge  or  in  a  tear  or  hole. 

19.4E  A  common  reason  for  nonoperation  of  a  pneumatic 
system  is  the  failure  of  the  instrument  air  supply 
caused  by  water  and  oil. 

19.4F  An  indication  of  a  serious  problem  in  an  electrical 
instrument  or  power  cicuit  is  the  presence  of  smoke 
and/or  a  burning  odor. 

Answers  to  questions  on  page  379. 

19.4G  Moisture  can  be  controlled  in  instruments  by  a 
space-heat  source  (such  as  a  power  transformer)  or 
by  inserting  a  container  of  desiccant  into  its  case. 

19.4H  Pneumatic  instrumentation  should  be  purged  with 
dry  air  before  shutdown  to  rid  the  individual  parts  of 
residual  oil  and  moisture  and  to  minimize  internal 
corrosion. 

Answers  to  questions  on  page  379. 

19.41  Regular  preventive  maintenance  duties  should  be 
printed  on  forms  or  cards  for  use  by  operators  as  a 


404 


Instrumentation  383 


reminder,  guide  and  record  of  preventive  mainte« 
nance. 

1 9.4J  Operational  checks  are  performed  by  always  observ- 
ing each  system  for  its  continuing  signs  of  norma! 
operation,  and  cycling  some  indicators  by  certain 
testing  methods. 

19.4K  If  a  recorder  trace  is  altered  from  its  usual  pattern 
dunng  the  process  of  checking  an  instrument,  the 
operator  causing  the  upset  should  initial  the  chart 
appropriately,  with  the  time  noted. 


Answers  to  questions  on  page  380. 

19.4L  To  obtain  a  technical  manual  for  an  inst^'ument,  write 
to  the  manufacturer.  Be  sure  to  provide  all  relevant 
serial/model  numbers  in  your  request  to  the  manu- 
facturer for  a  manual. 

19.4M  Instrument  supplies  and  spare  parts  that  should 
always  be  available  include  charts,  pens,  pen  clean- 
ers and  ink,  and  any  other  parts  necessary  for 
Instrument  operation  or  service. 


OBJECTIVE  TEST 

Chapter  19.  INSTRUMENTATION 


Please  wnte  your  name  and  mark  the  correct  answers  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1 .  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
questions. 

TRUE-FALSE 

1 .  Accuracy  cf  an  instrument  relates  to  the  closeness  of  a 
measurement  to  the  actual  value. 

1.  True 

2.  False 

2.  A  digital  readout  display  provides  a  direct,  numerical 
reading. 

1.  True 

2.  False 

3.  A  motor  control  station  provides  for  the  on-of f  operation 
of  an  electric  motor. 

1.  True 

2.  False 

4.  The  pressing  down  of  a  relay  armature  within  an  electri- 
cal panel  may  cause  an  electncal  "explosion"  to  shower 
you  with  molten  metal. 

1.  True 

2.  False 

5.  A  danger  may  exist  around  powered  mechanical  equip- 
ment even  when  the  exposed  rotating  or  meshing 
elements  have  "guards"  fitted  in  compliance  with  safety 
regulations. 

1.  True 

2.  False 

6.  Power  tools  are  often  used  to  calibrate  instruments. 

1.  True 

2.  False 

7.  Falls  are  a  leading  c'luse  of  lost-tirrie  accidents. 

1.  True 

2.  False 


8.  A  measured  variable  is  that  quantity  which  is  sensed 
and  quantified  by  a  primary  element  or  sensor. 

1.  True 

2.  False 

9.  Pressure  is  sensed  by  mechanically  immovable  ele- 
ments. 

1.  True 

2.  False 

10.  Use  of  a  bubbler  tube  is  a  very  precise  method  of 
measuring  water  levels. 

1.  True 

2.  False 

11.  When  propeller  meters  become  old,  they  become  sus- 
ceptible to  over  registration  (read  hiyh). 

1.  True 

2.  False 

12.  The  permanent  pressure  loss  through  a  venturi  meter  is 
greater  than  *.TOugh  an  orifice  plate. 

1.  True 

2.  False 

1 3.  Pneumatic  signal  systems  are  commonly  used  over  very 
long  distances. 

1.  True 

2.  False 

14.  Operators  may  safely  rely  solely  upon  the  readings  of 
instruments  to  ensure  proper  plant  operation. 

1.  True 

2.  False 

15.  Alarms  are  visual  and/or  audible  signals  that  a  variable 
is  out  of  bounds. 

1.  True 

2.  False 


ERLC 


4o:; 


384  Water  Treatment 


1 6.  Several  different  tone  signals  can  be  sent  over  the  same 
pair  of  phone  lines. 

1.  True 

2.  False 

17.  A  remote  sensing  and  control  station  can  send  tone 
signals  to  the  water  plant  and  simultaneously  receive 
tone  signals  to  effect  control  at  the  site  ove.  the  same 
!ines. 

1.  True 

2.  False 

18.  "Pneumatics"  may  operate  for  many  years  without  sig- 
nificant problems  if  they  have  a  quality  air  supply. 

1.  True 

2.  False 

19.  "Plant  air"  must  be  filtered  and  dried,  as  with  "instrument 
air." 

1.  True 

2.  False 

20.  If  a  gentle  tap  on  an  instrument  causes  a  slight  pen 
movement,  the  instrument  is  functioning  properly. 

1.  True 

2.  False 


which  controls  or  adjusts  the  process  variable. 

1.  Control  loop 

2.  Control  system 

3.  Feedback 

4.  Linearity 

5.  Telemetry 

26  Which  of  the  following  items  are  safety  provisions  that 
may  be  used  on  electrical  equipment? 

1.  Insulating  covers 

2.  Lockouts 

3.  Safety  switches 
<4.  Torque  ratings 
5.  Warning  labels 

27.  When  working  on  instruments  while  standing  on  a 
ladder,  you  should 

1.  Carry  tools  on  an  electrician's  belt. 

2.  Leave  tools  on  the  ladder  steps  when  not  working. 

3.  Use  a  non-conductive  type  of  ladder. 

4.  Wear  a  hard  hat. 

5.  Wear  thin  rubber  or  plastic  gloves. 

28.  Pressure  is  measured  or  sensed  by 

1.  Bourdon  tubes. 

2.  Bellows. 

3.  Diaphragms. 

4.  Pistons. 

5.  Propellers. 


MULTIPLE  CHOICE 

21.  Objectives  of  this  chapter  include  how  to 

1.  Determine  location  and  cause  of  measurement  and 
control  system  failures. 

2.  Dismantle  an  automatic  controller  and  repair  it. 

3.  Safely  enter  a  vault  without  any  ventilation  system. 

4.  Test  an  electrical  circuit  with  a  screwdriver. 

5.  Use  power  tools  in  wet  environments. 

22.  Operators  should  be  able  to 

1.  Dram  an  air  line. 

2.  Free  a  stuck  pen. 

3.  Repair  a  turbidimeter. 

4.  Replace  a  fuse. 

5.  Restore  proper  control  of  a  controller. 

23.   refeis  to  how  closely  an  instrument  measures 

the  actual  value  of  the  process  variable  being  meas- 
ured. 

1.  Accuracy 

2.  Calibration 

3.  Precision 

4.  Repeatability 

5.  Standardization 

24.  Examples  of  proportional  control  encountered  by  water- 
works operators  include 

1.  Chemical  feed,  flow  paced. 

2.  Chlorine  residual  analyzer/controller. 

3.  Continuous  level  control  of  filter  basins. 

4.  Flow  regulating  valves 

5.  Pressure  regulating  valves. 

25.    is  the  circulating  action  between  the  sensor 

which  measures  a  process  variable  and  the  controller 

ERIC 


29.   are  used  to  measure  the  level  of  water. 

1.  Bubblers 

2.  Displacers 

3.  Electrical  probes 

4.  Floats 

5.  Stilling  wells 

30.  Velocity  may  be  sensed  

1.  Chemically 

2.  Electrically 

3.  Hydraulically 

4.  Mechanically 

5.  Naturally 

31.  Flow  measuring  devices  include 

1.  Impellers. 

2.  Orifice  niates. 

3.  Propellers. 

4.  Rotameters. 

5.  Venturis. 

32.  Which  of  the  following  process  variables  are  usually 
monitored  continuously  by  instrumentation  in  a  modern 
water  treatment  plant? 

1.  Chlorine  residual 

2.  Cohforms 

3.  Iron  and  manganese 

4.  pH 

5.  Turbidity 

33.  Advantages  of  digital  panel  indicators  include 

1.  Cheaper  than  analog. 

2.  Erroneous  values  easily  recognized. 

3.  Quickly  read. 

4.  Respond  virtually  instantly  to  variable  change. 

5.  Rugged. 

406 


Instrumentation  385 


34.  Causes  of  electronic  instrument  problems  include 

1 .  Dirty  instrument  air. 

2.  Excessive  heat. 

3.  Temporary  power  failure. 

4.  Tripped  panel  circuit  breakers. 

5.  Voltage  surges. 

35.  Controls  available  to  protect  pumps  from  damage  in- 
clude 

1.  High-pressure  cut-off  switches. 

2.  Lock-out  switches. 

3.  Low-pressure  cut-off  switches. 

4.  Sensors  that  detect  open  or  closed  signal  circuits. 

5.  Warning  tags. 

36.  Reliable  operation  of  pneumatic  instrumentation  pres- 
sure system  requires 

1.  Clean  air. 

2.  Dry  air. 

3.  Pressurized  air. 

4.  Properly  lubricated  air. 

5.  Uninterrupted  power. 

Essential  parts  of  a  plant's  instrument  air  supply  system 
include 

1.  Air  filters. 


2  Air  dryers. 

3.  Compressors. 

4.  Compressor  controls. 

5.  Master  air  pressure  regulators. 

38.  Erratic  performance  by  pneumatic  instruments  may  be 
caused  by 

1.  Carbon  dioxide  in  the  air  supply. 

2.  Excessive  temperature  of  air  supply. 

3.  Oil  in  air  supply. 

4.  Over-pressurized  air  supply. 

5.  Water  in  air  supply. 

39.  An  operator  should  be  alert  for  which  of  the  pen 
movements  that  could  indicate  a  ootential  problem*? 

1.  Constant  hunting 

2.  Periodic  spikes 

3.  Quivering  pen  movement 

4.  Similar  cycles 

5  Very  flat  pen  trace 

40.  Recording  pens  may  get  stuck  on  or  in 

1.  Chart  edges. 

2.  Chart  ends. 

3.  Holes. 
4  Ink. 

5.  Tears. 


ERIC 


407 


CHAPTER  20 

SAFETY 

by 

Joe  Monscvitz 


ERIC 


388  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  20.  Safety 


Page 

OBJECTIVES  

 391 

GLOSSARY  

 392 

LESSON  1 

20.0  Responsibilities  

 o9w 

20.00  Everyone  Is  Responsible  for  Safety   3g3 

20.01  Regulatory  Agencies  

20.02  Utilities  

 393 

20.03  Supervisors  

 394 

20.04  Operators  

 394 

20.05  First  Aid  

 395 

20.06  Reporting  

20.07  Training  

20.08  Measuring  

 o99 

20.09  Human  Factors  

 400 

LESSON  2 

20.1  Chemical  Handling  

20.10  Safe  Handling  of  Chemicals   

20.11  Acids  

 402 

20.110  Acetic  Acid  (Glacial)  

20.1 1 1  Hydrofluosilicic  Acid  

20.112  Hydrofluoric  Acid  

20.113  Hydrochloric  Acid   ^^3 

20.114  Nitric  Acid  

 405 

20.115  Sulfuric  Acid  

 405 

20.12  Bases  

 405 

20.120  Ammonia  

 406 

20.121  Calcium  Hydroxide  

20.122  Sodium  Hydroxide  (Caustic  Soda)   4Q7 


Safety  389 


20.123  Sodium  Silicate  "^07 

20.124  Hypochlorite  

20.126  Sodium  Carbonate  

20.13  Gases   

20.130  Chlorine  (Cy  

20.131  Carbon  Dioxide  (CO2)  

20.132  Sulfur  Dioxide  (SO2)   

20.14  Salts  

20.140  Aluminum  Sulfate  (alum)  

20.141  Ferric  Chloride  

20.142  Ferric  Sulfate  

20.143  Ferrous  Sulfate  

20.144  Sodium  Aluminate  ^'•^ 

20.145  Fluoride  Compounds  ^"'^ 

2015  Powders  

20.150  Potassium  Permanganate  (KMnOJ  

20.151  Powdered  Activated  Carbon  

20.152  Other  Powders  

20.16    Chemical  Storage  Drains  ^"^^ 

LESSON  3 

20.2  Fire  Protection  

20.20  Fire  Prevention  

20.21  Classification   

20.22  Extinguishers  

20.23  Fire  Hoses   

20.24  Flammable  Storage  

20.25  Exits  

20.3  Plant  Maintenance  

20.30  Maintenance  Hazards   ^20 

20.31  Cleaning  "^20 

20.32  Painting  ^20 

20.33  Cranes   

20.34  Manholes  ^21 

20.35  Power  Tools  ^21 

20.36  Welding  "^22 

20.37  Safety  Valves  ^22 

20.4  Vehicle  Maintenance  and  Operation  ^23 

20.40    Types  of  Vehicles  ^23 

ERIC  410 


390  Water  Treatment 

20.41  Maintenance  

20.42  Seat  Belts  

20.43  Accident  Prevention 

20.44  Forklifts 

LESSON  4 

20.5  Electrical  "Equipment .  . . 

20.50  Electrical  Safety 

20.51  Current  —  Voltage 

20.52  Transformers 

20.53  Electrical  Starters 

20.54  Electrical  Motors  . . 

20.55  Instrumentation 

20.56  Control  Panels 

20.6  Laboratory  Safety 

20.60  Laboratory  Hazards 

20.61  Glassware 

20.62  Chemicals 

20.63  Biological  Considerations 

20.64  Radioactivity 

20.65  Laboratory  Equipment 

20.650  Hot  Plates 

20.651  Water  Stills 

20.652  Sterilizers 

20.653  PIpet  Washers 
20J    Operator  Protection 

20.70  Operator  Safety 

20.71  Respiratory  Protection 

20.72  Safety  Equipment . . 

20.73  Eye  Protection 

20.74  Foot  Protection 

20.75  Hand  Protection 

20.76  Head  Prelection 

20.77  Water  Safety 

20.8  Preparation  For  Emergencies 

20.9  Arithmetic  Assignment 

20.10  Additional  Reading 
Suggested  Answers 
Objective  Test 


OBJECTIVES 


Chapter  20.  Safety 


Following  completion  of  Chapter  20,  you  should  be  able 
to: 

1.  List  the  responsibilities  of  all  persons  and  agencies 
involved  in  waterworks  safety, 

2.  Identify  ana  safely  handle  hazardous  chemicals, 

3.  Recognize  fire  hazards  and  properly  extinguish  various 
types  of  fires, 

4.  Safely  maintain  waterworks  equipment  and  facilities, 

5.  Properly  operate  and  maintain  vehicles, 

6.  Recognize  electrical  hazards, 

7.  Safely  perform  duties  in  a  laboratory,  and 

8.  Protect  other  operators  and  yourself  while  working  in  and 
around  waterworks  facilities. 


392  Water  Treatment 


GLOSSARY 

Chapter  20.  SAFETY 


DECIBEL  (DES-uh-bull)  DECIBEL 

A  unit  for  expressing  the  relative  intensity  of  sounds  on  a  scale  from  zero  for  the  average  least  perceptible  sound  to  about  130 
for  the  average  level  at  which  sound  causes  pain  to  humans. 


OLrACTORY  FATIGUE  (ol-FAK-tore-ee)  OLFACTORY  FATIGUE 

A  condition  in  which  a  person's  nose,  after  exposure  to  certain  odors,  is  no  longet  able  to  detect  the  odor. 

OSHA  Q^^^ 

The  Williams-Stelger  Occupational  Safety  and  Health  Act  of  1970  (OSHA)  is  a  law  designed  to  protect  the  health  and  safety  of 
industrial  workers  and  also  the  operators  of  water  supply  systems  and  treatment  plants. 

TAILGATE  SAFETY  MEETING  TAILGATE  SAFETY  MEETING 

The  term  TAILGATE  comes  from  the  safety  meetings  regularly  held  by  the  construction  industry  around  the  tailgate  of  a  truck. 


413 


Safety  393 


CHAPTER 

(Lesson  1 


20.0  RESPONSiBILITIES 

20.00  Everyone  Is  Responsible  for  Safety 

Waterworks  utilities,  regardless  of  size,  must  have  a 
safety  program  if  they  are  to  realize  a  low  frequency  of 
'"ccideht  occurrence.  A  safety  program  also  provides  a 
means  of  comparing  frequency,  disability  and  severity  with 
other  utilities.  The  utility  should  identify  causes,  provide 
training,  have  means  of  reporting,  and  hold  supervisors 
responsible  for  the  program  implementation.  Each  utility 
should  have  a  safety  officer  or  supervisor  evaluate  every 
accident,  offer  recommendations,  and  keep  and  apply  statis- 
tics. The  c*fectiveness  of  any  safety  program  will  depend 
upon  how  the  utility  holds  its  supervisors  responsible.  If  the 
utility  hclds  only  the  safety  officer  or  the  employees  respon- 
sible, the  program  will  fail.  The  supervisors  are  key  in  any 
organization.  If  they  disregard  safety  measures,  essential 
parts  of  the  program  Wh  lot  work.  The  results  will  be  an 
overall  poor  safety  record.  After  all,  the  first  line  supervisor 
IS  where  the  work  is  being  performed,  and  some  may  take 
advantage  of  an  unsafe  situation  in  order  to  get  the  job 
completed.  The  organization  must  discipline  such  supervi- 
sors and  make  them  aware  of  their  responsibility  for  their 
own  and  their  operators'  safety. 


Safety  is  good  business  both  for  the  operator  and  the 
agency.  For  a  good  safety  record  to  be  accomplished,  all 
individuals  must  be  educated  and  must  believe  in  the  pro- 
gram. All  individuals  involved  must  have  the  conviction  that 
accidents  can  be  prevented.  The  operations  should  be 
studied  to  determine  the  safe  way  of  performing  each  job. 
Safety  pays,  both  in  monetary  sav  ings  and  in  happiness  of 
the  operating  staff. 

20.01   Regulatory  Agencies 

There  are  many  state  and  federal  agencies  involv<>'J  in 
ensuring  safe  working  conditions.  The  one  law  that  has  had 
the  greatest  impact  has  been  the  Occupational  Safety  and 
Health  Act  ot  1970  (OSHA),  Public  Law  91-596,  which  ♦^ok 
^'^zX  on  December  29, 1970.  This  legislation  affect:  more 

ERIC 


20.  SAFETY 

of  4  Lessons) 


than  75,000,000  employees  and  has  been  the  basis  for  most 
of  the  current  state  laws  covering  employees.  Also,  many 
state  regulatory  agencies  enforce  the  OSHA  requirements. 

The  OSHA  regulations  provide  for  safety  inspections, 
penalties,  recordkeeping  and  variances.  Supervisors  must 
understand  the  OSHA  Act  and  must  furnish  each  operator 
With  the  rules  of  conduct  in  order  to  comply  with  occupation- 
al safety  and  health  standards.  The  intent  of  the  regulations 
IS  to  create  a  place  of  employment  which  is  free  from 
recognized  hazards  that  could  cause  serious  physical  harm 
or  death  to  an  operator. 

Civil  and  criminal  penalties  are  allowed  under  the  OSHA 
Law,  depending  upon  the  size  of  the  lousiness  and  the 
seriousness  of  ^^e  violation.  A  routine  violatio"  could  cost  an 
employer  or  supervisor  up  to  $1,000  for  each  violation.  A 
serious,  willful  or  repeated  violation  could  cause  the  c  mploy- 
er  or  supervisor  to  be  assessed  a  penalty  of  not  more  than 
$10,000  for  each  violation.  Penalties  are  assessed  against 
the  supervisor  responsible  for  the  injured  operator.  Opera- 
tors should  become  familiar  with  the  OSHA  regulations  as 
they  apply  to  their  organizations.  They  mu^^t  correct  viola- 
tions and  prevent  others  from  occurring. 


20.02  Utilities 

Water  utilities  must  make  safety  a  part  of  management's 
responsibility.  Each  utility  should  start  and  maintain  a  safety 
program  by  holding  its  supervisors  responsible  for  the 
elfectiveness  of  the  program.  The  utilities  must  have  a 
reporting  system  to  keep  records;  they  may  be  required  to 
submit  reports  to  state  and  federal  agencies.  Even  if  the 
utility  does  not  submit  reports  to  other  agencies,  it  should 
keep  and  review  such  reports  on  its  own,  as  a  means  of 
reducing  hazards  to  the  operators. 

Each  utility  should  develop  policy  statements  on  safety, 
giving  its  objective  concerning  the  operator's  welfare  (Table 
20.1).  The  statement  should  be  brief,  but  express  the  utility's 
recognition  of  the  need  for  safety  to  stimulate  efficiency, 
improve  service,  imp^'Ove  morale  and  to  .naintain  oood 

414 


394  Vi^ei^  Treatment 


public  relPtions.  ^he  poiicy  should  recognize  the  human 
factor  (the  unsafe  act)  as  the  most  slgnificent  cause  of 
accidents,  and  thereby  emphasize  the  operator's  responsi- 
bility to  perform  the  job  safely.  The  policy  should  be  one  of 
providing  the  operators  with  proper  equipment  and  safe 
working  conditions.  Finally,  it  is  essential  that  the  policy 
reinforce  the  supervisory  responsibility  to  maintain  safe 
work  practices 

This  policy  statement  should  be  made  by  every  utility 
regardless  of  size.  The  statement  should  be  written  and 
given  to  each  operator  and  all  other  employees  and  rein- 
forced by  the  supervisory  staff.  Without  such  an  objective, 
the  utility  cannot  hope  to  gain  the  loyalty  and  respect  of  its 
operators,  nor  can  it  achieve  efficient  plant  operation.  The 
utility  must  hold  everyone  responsible  for  safety  and  desig- 
nate a  specific  indi\/idual  to  be  responsible  for  an  active,  on- 
going safety  program. 


TABLE  20.1    SAFETY  POLICY  STATEMENT 

LAS  VEGAS  VALLEY  WATER  DISTRICT 
SAFETY  STATEMENT  WORK  RULE  #920 

The  Distnct  recognizes  its  responsibility  for  providing  the 
safest  working  conditions  for  its  employees  and  customers. 
This  responsibility  is  met  by  means  of  a  safety  program 
which  will  be  applied  through  the  development  of  safety 
awareness  among  the  t  nployees.  the  use  of  up-to-date 
safety  equipment,  and  the  continual  inspection  of  conditions 
and  practices  by  all  levels  of  supervision. 

It  IS  the  responsibility  of  everv  emplo/ee  to  develop  safe 
working  hibits.  The  development  of  proper  attitudes  toward 
safety  is  the  only  method  to  improve  safe  working  habits. 
Therefore,  training  sessions  play  a  large  part  in  the  safety 
program.  The  District  wants  to  protect  all  employees  and  the 
public  from  injury  and  accidents.  To  accomplish  this  goal, 
the  safety  program  will  involve  everyone,  and  it  will  require 
the  active  participation  and  cooperation  of  all  to  make  it 
operate  effectively. 

Safety  training  sessions  are  conducted  for  all  Dl<itrict  em- 
ployees and  employees  are  expected  to  perform  in  a  safe 
manner  Negligent  or  unsafe  conduct  by  an  employee  will 
subject  the  employee  to  disciplinary  action. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  438. 

20.0A  Wha*  ihould  be  the  duties  of  a  safety  office-'? 

20.0B  Who  should  be  responsible  for  the  iinpiemenL  tion  of 
a  safety  program? 

20.0C  Who  enforces  the  OSHA  requirements'? 

20  OD  What  should  be  included  in  a  utility's  policy  statement 
on  safety? 


thereby  effectively  ensure  compliance  with  all  aspects  of  the 
utility's  safety  program. 

The  problem,  however,  is  one  of  tne  supervisor  accepting 
this  responsibility.  The  supervisor  vho  wishes  to  complete 
the  job  and  go  on  to  the  next  one  without  taking  time  to  be 
concerned  about  working  conditions,  the  welfare  of  opera- 
tors, or  considenng  any  aspects  of  safety  is  a  poor  supervi- 
sor. Only  after  an  accident  occurs  will  a  careless  supervisor 
question  the  need  t,ir  a  work  program  based  on  safety.  At 
this  point,  however,  it  is  too  late,  and  the  supervisor  may  be 
tempted  to  simply  cover  up  past  mistakes.  As  sometimes 
happens,  the  supervisor  may  even  be  partially  or  fully 
responsible  for  the  accident  by  causing  unsafe  acts  to  take 
place,  by  requiring  work  to  be  performed  in  haste,  by 
disregarding  an  unsafe  work  environment  or  by  overlooking 
or  failing  to  consider  any  number  of  safety  hazards.  This 
negligent  supervisor  could  be  fined,  sentenced  to  a  jail  term, 
or  even  De  barred  from  working  In  the  profession. 

All  utilities  should  make  their  supervisors  bear  the  great- 
est responoibllity  for  safety  and  hold  them  accountable  for 
planning,  implementing  and  controlling  the  safety  program. 
If  most  accidents  are  caused  and  do  not  just  happen,  then  It 
IS  the  supervisor  who  can  help  prevent  most  accidents. 

Equally  important  are  the  officials  above  the  supervisor. 
These  officials  Include  commissioners,  managers,  public 
works  directors,  chief  engineers,  superintendents  and  chief 
operators.  The  person  In  responsible  charge  for  the  entire 
agency  or  operation  must  believe  In  the  safety  program.  This 
peroon  must  budget,  promote,  support  and  enforce  the 
safety  program  by  vocal  and  visible  examples  and  actions. 
The  top  person's  support  is  absolutely  essential  for  an 
effective  safety  program. 

20.04  Operators 

Each  operator  also  shares  in  the  responsibility  for  an 
effective  safety  program.  After  all.  operators  have  the  most 
to  gam  since  they  are  the  most  likely  victims  of  accidents.  A 
review  of  accident  causes  shows  that  the  accident  victim 
often  has  not  acted  responsibly.  In  toiDe  way  the  victim  has 
not  complied  with  the  safety  regulations,  has  not  been  fully 
aware  of  the  working  conditions,  has  not  been  concerned 
about  fellow  employees,  or  just  has  not  accepted  any 
responsibility  for  the  utility's  safety  program. 

Each  operator  must  accept,  at  least  in  part,  responsibility 
for  fellow  operators,  for  the  utility's  equipment,  for  the 
operator's  own  welfare,  and  even  for  seeing  that  the  super- 
visor complies  with  established  safety  regulations.  As  point- 
ed out  above,  the  operator  has  the  most  to  gain.  If  the 
operator  accepts  and  uses  unsafe  equipment,  it  is  the 
operator  who  is  in  danger  if  something  goes  wrong.  If  the 
operator  fails  to  protect  the  other  operators,  it  is  the  opera- 
tor who  must  make  up  the  work  lost  because  of  injury.  If 
operators  fail  to  consider  their  own  welfare,  it  is  they  who 
suffer  the  pain  of  any  injury,  the  loss  of  income,  and  maybe 
even  the  loss  of  life. 


20.03  Crupervisors 

The  success  of  any  safety  program  will  depend  upon  how 
the  supervisors  of  the  utility  t/jew  their  responsibility.  The 
supervisor  who  has  the  responsibility  for  directing  work 
activities  must  be  safety  conscious.  This  supervisor  controls 
the  operators'  general  environment  and  work  habits  and 
influences  whethe;  or  not  the  operators  comply  with  safety 
regulations.  The  supervisor  Is  In  the  best  position  to  counsel. 
Instruct  and  review  the  operators'  working  methods  and 


ERIC 


41:3 


Safety  395 


The  operator  must  accept  responsibility  for  an  active  role 
in  the  safety  program  by  becoming  aware  of  the  utility's 
safety  policy  and  conforming  to  established  regulations 
THE  OPERATOR  SHOULD  ALWA  YS  CALL  TO  THE  SUPER- 
VISOR'S ATTENTION  UNSAFE  CONDITIONS,  environment, 
equipment  or  other  concerns  operators  may  have  about  the 
work  they  are  performing.  Safety  should  be  an  essential  part 
of  the  operator's  responsibility. 

20.05  First  Aid 

By  definition,  first  aid  means  emergency  treatment  for 
injury  or  sudden  illness,  before  regular  medical  treatment  is 
available.  Everyone  in  an  organization  should  be  able  to  give 
some  degree  of  piompt  treatment  and  attention  to  an  injury. 

First  aid  training  m  the  basic  principles  and  practices  of 
life-saving  steps  that  can  be  taken  in  the  early  stages  of  an 
injury  are  available  through  the  local  Red  Cross,  Heart 
Association,  local  fire  departments  and  other  organizations. 
Such  training  should  periodically  be  reinforced,  so  that  the 
operator  has  a  complete  understanding  of  water  safety, 
cardio-pulmonary  resuscitation  (CPR)  and  other  life-saving 
techniques.  All  operators  need  training  'n  first  aid,  but  it  is 
especially  important  for  those  who  regularly  work  with 
electrical  equipment  or  must  handfa  chlorine  and  other 
dangerous  chemicals. 

First  aid  has  little  to  do  with  preventing  accidents,  but  it 
has  an  important  bearing  upon  the  survival  of  the  injured 
patient.  A  well-equipped  first  aid  chest  or  kit  is  essential  for 
proper  treatment.  The  kit  should  be  inspected  regularly  by 
the  safety  officer  to  a&sure  that  supplies  are  available  when 
needed.  First  aid  kits  should  be  prominently  displayed 
throughout  the  treatment  plant  and  in  company  vehicles. 
Special  consideration  must  be  given  to  the  most  hazardous 
areas  of  the  plant  such  as  shops,  laboratories,  and  chemical 
handling  facilities. 

Regardless  of  size,  each  utility  should  establish  standard 
operating  procedures  (SOP)  for  first  aid  treatment  of  injured 
personnel.  All  new  operators  should  be  instructed  in  the 
utility's  first  aid  program. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  438. 

20.0E  How  could  a  supervisor  be  responsible  for  an  acc- 
dent? 

20.0F  What  types  of  safety-re'ated  responsibilities  must 
each  operator  accept? 

20.0G  What  is  first  a«d? 

20.0H  First  aid  training  is  most  important  for  operators 
Involved  In  what  types  of  activities'? 

20.06  Reporting 

The  mainstay  of  a  safety  program  is  the  method  of 
reporting  and  keeping  of  statistics,  These  records  are  need- 
ed regardless  of  size  of  the  utility,  as  they  provide  a  means 
of  identifying  accident  frequencies  and  causes  as  well  as  the 
personnel  involved.  The  records  can  be  looked  upon  as  the 
operator's  safety  report  card.  Therefore,  it  becomes  the 
responsibility  of  each  injured  operator  to  fill  out  the  utility's 
accident  report. 

All  injuries  snould  be  reported,  even  if  they  are  minor  in 
nature,  so  as  to  establish  a  record  in  case  the  injury 


develops  into  a  senous  injury,  it  may  be  difficult  at  a  later 
date  to  prove  the  accident  did  occur  on  the  job  and  have  the 
utility  accept  the  responsibility  for  costs.  The  responsibility 
for  reporting  accidents  affects  several  levels  of  personnel. 
First,  of  course,  is  the  injured  person.  Next,  it  is  the  respon- 
sibility of  the  supervisor,  and  finally,  the 

Accident  report  forms  may  be  very  simple.  However,  they 
must  record  all  details  required  by  law  and  all  data  needed 
for  statistical  purposes.  The  forniS  shown  here  in  Figures 
20.1  and  20.2  are  examples  for  you  to  consider  for  use  in 
your  plant.  The  report  must  show  the  name  of  the  injured, 
employee  number,  divisior:,  t,me  of  accident,  nature  of 
in;  jry,  cause  of  accident,  first  aid  administered,  and  remarks 
for  Items  not  covered  elsewhere.  There  should  be  a  review 
process  by  foreman,  supervisor,  safety  officer,  and  manage- 
ment. RECOMMENDATIONS  ARE  NEEDED  AS  WELL  ASA 
FOLLOW-UP  REVIEW  TO  BE  SURE  THAT  PROPER  AC- 
TION HAS  BEEN  TAKEN  TO  PREVENT  RECURRENCE.  In 
addition  to  reports  needed  by  the  utility,  there  are  other 
reports  that  may  be  required  by  state  or  federal  agencies. 
For  example,  vehicle  accident  reports  must  be  submitted  to 
local  police  departments.  If  a  member  of  the  Public  is  injured, 
additional  forms  are  needed  because  of  possible  subse- 
quent claims  for  damages.  If  the  accident  is  one  of  occupa- 
tional injury,  causing  lost  time,  other  reports  may  be  re- 
quired. Follow-up  investigations  to  identify  causes  and 
responsibility  may  require  the  development  of  other  specific 
types  of  record  forms. 

In  the  preparation  of  accident  reports,  it  is  the  operator's 
responsibility  to  correctly  fill  out  each  form,  giving  complete 
details.  The  supervisor  must  be  sure  no  information  is 
overlooked  which  may  be  helpful  in  preventing  recurrence. 

4afeiM  Officer  rc\\cw 
coy^^ti\c  agii^nt^  ^di  make 

In  day-to-day  actions,  operators,  supervisors  and  man- 
agement often  overlook  opportunities  to  counsel  individual 
operators  in  safety  matters.  Then,  when  an  accident  occurs, 
they  are  not  inclined  to  look  too  closely  at  accident  reports. 
First,  the  accident  is  a  series  of  embarrassments,  to  the 
injured  person,  to  the  supervisor  and  to  management. 
Therefore,  there  is  a  reluctance  to  give  detailed  consider- 
ation to  accident  reports.  However,  if  a  safety  program  is  to 
function  well,  it  will  require  a  thorough  effort  on  the  part  of 
the  operator,  supervisor  and  management  in  accepting  their 
responsibility  for  the  accident  and  making  a  greater  effort 
through  good  reporting  to  prevent  future  similar  accidents. 
Accident  reports  must  be  analyzed,  discussed,  and  the  real 
cause  of  the  accident  identifiec  and  corrected. 

Emphasis  on  the  prevention  of  future  accidents  cannot  be 
overstressed.  We  must  identify  the  caust-  of  accidents  and 
implement  whatever  measures  are  necessary  to  protect 
operators  from  becoming  injured. 


41'6 


396  Water  Treatment 


Date . 


Name  of  injured  employee  . 
Date  of  accident  


Location  of  accident . 
Name  of  doctor  


Name  of  hospital . 


Witnesses  (name  &  address) . 


.  Time . 


Employee  # 


Employee's  Occupation . 
 Nature  of  injury  


.  Address . 
.  Address. 


.  Area . 


PHYSICAL  CAUSES 
Indicate  below  by  an  'X  whether  in  your  opinion,  the  accident  was  caused  by: 

 Improper  guarding 

 Defective  substances  or  equipment 

 Hazardous  arrangement 

 Improper  Illumination 

 Improper  dress  or  apparel 

 No  mechanical  cause 

 Not  listed  (describe  briefly)  


Working  methods 
Lack  of  knowledge  or  skill 
Wrong  attitude 
Physical  defect 


UNSAFE  ACTS 

Sometimeb  the  »njured  person  is  not  directly  associated  with  the  causes  of  an  accident.  Using  an  "X"  to  represent  the  injured 
worker  and  an  "O"  to  represent  any  other  person  involved,  indicate  whether,  in  your  opinion,  the  accident  was  caused  by: 


 Operating  without  authority 

 Failure  to  secure  or  warn 

 Working  at  unsafe  speed 

 Make  safety  device  inoperative 

 Unsafe  equipment  or  hands  instead  of  equip. 

 No  unsafe  act 

 Not  listed  (describe  briefly)  


Unsafe  loading,  placement  &  etc. 

Took  unsafe  position 

Worked  on  moving  equipment 

Teased,  abused,  distracted  &  etc. 

Did  not  use  safe  clothing  or  personal 
protective  equipment. 


What  job  was  the  employee  doing?  

What  specific  action  caused  the  accident'^  

What  steps  will  be  taken  to  prevent  recurrence'? 


Date  of  Report . 


.  Immediate  Supervi^^or. 


Comments: 


REVIEWING  AUTHORITY 
Comments: 


ERIC 


Safety  Officer  Department  Director 
Fig.  20.1   Supervisor's  accident  report 

41 V 


Date 


Safety  397 


INJURED:  COMPLETE  THIS  SECTION 


Name . 


Address . 
Title  


Place  of  Accident 


Street  or  Intersection 
Date  


Type  of  Job  You  Were  Doing  When  Injured 


Dept  Assigned. 


Hour. 


Age. 


.Sex . 


.  Marital  Status . 


A.M. 


.  P.M. 


Object  Which  Directly  Injured  You 


Part  of  Body  Injured 


How  Did  Accident  Happen'?  (Be  specific  and  give  details;  use  back  of  sheet  if  necessary). 


DiJ  You  Report  Accident  or  Exposure  at  Once?  (Exp'ain  "No")  Yes  □   No  □ 


Did  You  Report  Accident  or  Exposure  to  Supervisor? 
Give  Name 

YesD 

NoD 

Were  There  Witnesses  to  Accident  or  Exposure'? 
Give  Names 

Y3sn 

NoD 

Did  You  See  a  Doctor?  Nf  Yes.  fiive  Name) 

YesD 

NoD 

Are  You  Goina  to  See  a  Doctor'?  (Give  NJamp) 

YesD 

NoD 

Date  Signature 

SUPERVISOR:  COMPLETE  THIS  SECTION  —  (Beto'n  to  Personnel  as  soon  as  Possible) 

,^as  an  Investigation  of  Unsafe  Conditions  and/or 
Unsafe  Acts  Made'?  If  Yes,  Please  Submit  Copy. 

YesD 

NoD 

Was  Injured  Intoxicated  or  Misconducting 
Himself  at  Time  of  Accident?  (Explain  "Yes") 

YesD 

NoD 

Date  Disability  Last  Day  Date  Back 
Commenced  Wages  Earned  on  Job  

Date  Report  Completed  ^  19          Signed  By  


Title 


Oistfibutton  •  Canary  •  Department  Head.  Pmk  •  Supervisor.  White  •  Personnel 

Fig,  20,2  Accident  report 

ERIC  -  418 


398  Water  Treatment 


20.07  Training 

If  a  safety  program  ts  to  ever  work  well,  management  will 
have  to  accept  responsibility  for  the  following  three  compo- 
nents of  training: 

1 .  Safety  education  of  all  employees, 

2  Reinforced  education  in  safety,  and 

3.  Safety  education  in  the  use  of  tools  and  equipment. 

Or  to  put  It  another  way,  the  three  most  important  controlling 
factors  in  safety  are  education,  education  and  education. 

Responsibility  for  overall  training  must  be  that  of  upper 
management.  A  program  that  will  educate  operators  and 
then  reinforce  this  education  in  sa'ety  must  be  planned 
systematically  and  promoted  on  a  continuous  basis.  There 
are  many  avenues  to  achieving  this  goal. 

The  safety  education  program  should  start  with  the  new 
operator.  Even  before  employment,  verify  the  operator's 
past  record  and  qualifications  and  review  the  pre-employ- 
ment physical  examination.  In  the  new  operator's  orienta- 
tion, include  instruction  in  the  importance  of  safety  at  /our 
utility  or  plant.  AJso  discuss  the  matter  of  proper  reporting  of 
accidents  as  well  as  the  organization's  policies  and  prac- 
tices. Give  new  operators  copies  of  all  safety  SOP's  and 
direct  their  attention  to  parts  that  directly  involve  them.  Ask 
the  safety  officer  to  give  a  talk  about  utility  policy,  safety 
reports  and  past  accidents,  and  to  orient  the  new  operator 
toward  the  importance  of  safety  to  operators  and  to  the 
organization. 

The  next  consideration  must  be  one  of  training  the  new 
operator  in  how  to  perform  assigned  work.  Most  supervi- 
sors think  in  terms  of  On-the-Job  Training  (OJT).  However, 
OJT  is  not  a  good  way  of  preventing  accidents  with  ah 
inexperienced  operator.  The  idea  is  all  right  if  the  operator 
comes  to  the  organization  trained  in  how  to  perform  the 
work,  such  as  a  treatment  operator  from  another  plant.  Then 
you  only  need  to  explain  your  safety  program  and  how  your 
policies  affect  the  new  operator.  For  a  new  operator  who  is 
inexperienced  in  water  treatment  or  in  utility  operation,  the 
supervisor  must  gi^e  detailed  consideration  to  the  opera- 
tor's welfare.  In  this  instance,  the  training  should  include  not 
only  a  safety  talk,  but  the  foreman  (supervisor)  must  train  the 
inexperienced  operator  in  all  aspects  of  treatment  plant 
safety.  This  training  includes  instruction  in  the  handling  of 
chemicals,  the  dangers  of  electrical  apparatus,  fire  hazards, 
and  proper  maintenance  of  equipment  to  p''event  accidents. 
Special  instructions  will  also  be  needed  for  specific  work 
environments  such  as  manholes,  gases  (chlorine  and  hydro- 
gen sulfide  (HgS)),  water  safety,  and  any  specific  hazards 
thai  are  unique  to  your  facility.  The  new  operator  must  be 
checked  out  on  any  equipment  personnel  may  operate  such 
as  vehicles,  forklifts,  valve  operators,  and  radios.  All  new 
operators  should  be  subjected  to  a  safety  orientation  pro- 
gram during  the  first  few  days  of  their  employment,  and  an 
overall  training  program  in  the  first  few  months. 

The  next  step  in  safety  education  is  reinforcement.  Even  if 
the  operator  is  well  trained,  mistakes  can  occur;  therefore, 
the  education  must  be  continual.  Many  organizations  use 
the  "tailgate"  method  as  a  means  of  maintaining  the  opera- 
tor's interest  in  safety.  The  program  should  be  conducted  by 
the  first  line  supervisor.  Schedule  the  informal  tailgate 
meeting  for  a  suitable  location,  keep  it  short,  avoid  distrac- 
tions and  be  sure  that  everyone  can  hear.  Hand  out  litera- 


ture, if  available.  Tailgate  talks  should  communicate  to  the 
operator  specific  considerations,  new  problems,  and  acci- 
dent information.  These  topics  should  be  published.  One 
resource  for  such  meetings  can  be  those  operators  who 
have  been  involved  in  an  accident.  Although  it  is  sometimes 
embarrassing  to  the  injured,  the  victim  is  now  the  expert  on 
how  the  accident  occurred,  what  could  have  been  done  to 
prevent  it,  and  how  it  felt  to  have  the  injury.  Encourage  all 
operators,  new  and  old,  to  participate  in  tailgate  safety 
sessions. 


Use  safety  posters  to  reinforce  safety  training  and  to 
make  operators  aware  of  the  location  of  dangerous  areas  or 
show  the  importance  of  good  work  habits.  Such  posters  are 
available  through  the  National  Safety  Council's  catalog.^ 
Awards  for  good  safety  records  are  another  means  of 
keeping  operators  aware  of  the  importance  of  safety.  The 
awards  could  be  given  to  individuals  in  recognition  of  a  good 
safety  record.  Publicity  about  the  awards  may  provide  an 
incentive  to  the  operators  and  demonstrates  the  organiza- 
tion's determination  to  maintain  a  good  safety  record.  The 
awards  may  include:  AWWA's  water  drop  pins,  certificates, 
and/or  plaques  shewing  number  of  years  without  an  acci- 
dent. Consider  publishing  a  utility  newsletter  on  safety  tips 
or  giving  deta.is  concerning  accidents  that  may  be  helpful  to 
other  operators  in  the  organization.  Awards  may  be  given  to 
the  organization  in  recognition  of  its  effort  in  preventing 
accidents  or  for  its  overall  safety  program.  A  suggestion 
program  concerning  safety  will  promote  and  reinforce  the 
program  and  give  recognition  to  the  best  suggestions.  The 
goal  of  all  these  efforts  is  to  reinforce  concerns  for  the  safety 
of  all  operators.  If  safety,  as  an  idea,  is  present,  then 
accidents  can  be  prevented. 

Education  of  the  operator  in  the  use  of  tools  and  equip- 
ment IS  necessary.  As  pointed  out  abo^'o,  OJT  is  not  the 
answer  to  a  good  safety  record.  A  good  safety  record  will  be 
achieved  only  with  good  work  habits  and  safe  equipment.  If 
the  operator  is  trained  in  the  proper  use  of  equipment  (hand 
tools  or  vehicles),  the  operator  is  less  likely  to  misuse  them. 
However,  if  the  supervisor  finds  an  operator  misusing  tools 
or  equipment,  then  it  is  the  supervisor's  responsibility  to 
reprimand  the  operator  as  a  means  of  reinforcing  utility 
policies.  The  careless  operator  who  misuses  equipment  is  a 
hazard  to  other  operators.  Careless  operators  will  also  be 
the  cause  of  a  poor  safety  record  in  the  operator's  division 
or  department. 

An  important  part  of  every  job  should  be  the  consideration 
of  Its  safety  aspects  by  the  supervisor.  The  superyisor 
should  instruct  the  foreman  or  operators  about  any  dangers 
involved  in  job  assignmen.s.  If  a  job  is  particularly  danger- 
ous, then  the  supervisor  must  bring  that  fact  to  everyone's 
attention  and  clarify  utility  policy  in  regard  to  unsafe  acts  and 
conditions. 


1  Write  or  call  your  local  safety  council  or  National  Safety  Council,  444  N.  Michigan  Avenue,  Chicago,  Illinois  60611,  phone  toll  free  "hot 
line"  (800)  621-8051  (not  applicable  within  Illinois). 

ER?C  413 


Safety  399 


If  the  operator  is  unsure  of  how  to  perform  a  job,  then  it  is 
the  operator's  responsibility  to  ask  for  the  training  needeo. 
Each  operator  must  think,  act.  and  promote  safety  if  the 
organization  is  to  achieve  a  good  safety  record  Training  is 
the  key  to  achieving  this  objective  and  training  is  everyone  s 
responsibility  —  management,  the  supe  visors,  foremen 
and  operators 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  438. 

20.01   What  IS  the  mainstay  of  a  safety  program'? 

20. OJ  Why  should  you  report  even  a  minor  injury? 

20. OK  Why  should  a  safety  officer  review  an  accident  report 
form'? 

20  OL  A  new  inexperienced  operator  must  receive  instruc- 
tion on  what  aspects  of  treatment  plant  safety'? 

20.0M  What  should  an  operator  do  if  unsure  of  how  to 
perform  a  job? 

20.08  Measuring 

To  be  complete,  a  safety  program  must  also  include  some 
means  of  identifying,  measuring  and  analyzing  the  effects  of 
the  program.  The  systematic  classification  of  accidents, 
injuries,  and  lost  time  is  the  responsibility  of  the  safety 
officer  This  person  should  use  an  analytical  method  which 
would  refer  to  types  and  classes  of  accidents.  Reports 
should  be  prepared  using  statistics  showing  lost  time,  costs, 
type  of  injuries  and  other  data  based  on  a  specific  time 
interval.  Such  data  calls  attention  to  the  effectiverass  of  the 
program  and  promotes  awareness  of  the  types  o\  accidents 
that  are  happening.  Management  can  use  this  information  to 
decide  where  the  emphasis  should  be  placed  to  avoid 
accidents.  However,  statistical  data  are  of  little  value  if  a 
report  is  prepared  and  then  set  on  the  bookshelf  or  placed  in 
a  supervisor  s  desk  drawer.  The  data  must  be  distributed 
and  read  by  all  operating  and  maintenance  personnel 


As  an  example.  Injuries  can  be  classified  as  fractures, 
burns,  bites,  eye  injuries,  cuts  and  bruises.  Causes  can  be 
referred  to  as  heat,  machinery,  falling,  handling,  chemicals, 
unsafe  acts,  and  miscellaneous.  Cost  can  be  considered  as 
lost  time,  lost  dollars,  lost  production,  contaminated  water  or 
any  other  means  of  showing  the  effects  of  the  accidents. 

Good  analytical  reporting  will  provide  a  great  deal  of  detail 
without  a  lot  of  paper  to  read  and  comprehend.  Keep  the 
method  of  reporting  simple  and  easy  to  understand  by  all 
operators,  so  they  can  identify  with  the  causes  and  be  aware 
of  how  to  prevent  the  accident  happening  to  themselves 
and/or  other  operators.  Table  20.2  gives  one  method  of 
showing  injury  and  cause  in  terms  of  operator-days  lost. 

ERIC 


TABLE  20.2    SUMMARY  OF  TYPES  AND  CAUSES  OF 
INJURIES 


Type  of  Injury 

CAUSE  OF  INJURY 

Unsafe  Act 

Chemical 

Fails 

Handling  Objects 

Heat 

Machinery 

Falling  Objects 

Stepping 

Striking 

Miscellanecus 

TOTAL 

Lacerations 

Sprains 

Eye  Injuries 

Bites 

Cuts 

Bruises 

ContuMons 

Miscellaneous 

There  are  many  other  methods  of  analyzing  data.  Table 
20  2  could  be  rearranged  by  using  cost  in  dollars  rather  than 
operator-days  lost.  Not  all  accidents  mean  time  lost,  but 
there  can  be  other  cost  factors.  The  data  analysis  should 
also  indicate  if  the  accidents  involve  vehicles,  company 
personnel,  the  public,  company  equipment,  loss  of  chemical, 
or  other  factors.  Results  also  should  show  direct  cost  and 
indirect  cost  to  the  agency,  operator  and  the  public. 

Once  the  statistical  data  have  been  compiled,  someone 
must  be  responsible  for  reviewing  it  in  order  to  take  preven- 
tive actions.  Frequently  such  responsibility  rests  with  the 
safety  committee.  In  fact,  safety  committees  may  operate  at 
several  levels,  for  example  management  committee,  work- 
ing committee,  or  an  accident  review  board.  In  any  event,  the 
committee  must  be  active,  be  serious  and  be  reinforced  by 
management. 

Another  means  of  measuring  safety  is  by  calculating  the 
injury  frequency  rate  for  an  indication  of  the  effectiveness  of 
your  safety  program.  Multiply  the  number  of  disabling  injur- 
ies by  one  million  and  divide  by  th3  total  number  of  employ- 
ee-hours worked.  The  number  of  injuries  per  year  is  multi- 
plied by  one  million  in  order  to  obtain  injury  frequency  rate 
values  or  numbers  which  are  easy  to  use.  In  our  example 
problems  we  obtained  numbers  between  one  and  one 
thousand. 

Injury  Frequency    (Numbe.  of  Disabling  injuries/year)  (1 ,000,000) 
Rate  Number  of  Hours  worked/year 

These  calculations  indicate  a  frequency  rate  per  year, 
which  IS  the  usual  means  of  showing  such  data.  Not  that  this 
calculation  accounts  only  for  disabling  injuries.  You  may 
wish  to  show  all  injunes,  but  the  calculations  are  much  the 
same. 


EXAMPLE  1 

A  rural  water  company  employs  36  operators  who  work  in 
many  small  towns  throughout  a  three-state  area.  The  opera- 
tors suffered  four  injunes  in  one  year  while  working  74,880 
hours.  Calculate  the  injury  frequency  rate. 

420 


400  Water  Treatment 


Unknown 

Injury  Frequency  Rate 


Known 

Number  of  Operators       =  36 
Number  of  Injuries  =  4/yr 

Number  of  Hours  Worked  =  74,880  yr 
Calculate  the  injury  frequency  rate. 

Injury  Frequency  _  (Number  of  Dtsablmg  Injurres/year)  (1 ,000.000) 


Rate 


Number  of  Hours  Worked/year 
(4/yr)  (1.000.000) 


74.880/yr 


^  53  4 


EXAMPLE  2 

Of  the  four  injuries  suffered  by  the  operators  in  Example  1 , 
one  was  a  disabling  injury.  Calculate  the  injury  frequency 
rate  for  the  disabling  injuries. 

Known  Unknown 

Injury  Frequency 
Rate 


Number  of  Disabling  Injuries  =  1  yr 
Number  of  Hours  Worked     =  74,880  yr 
Calculate  the  injury  frequency  rate. 
Injury  Frequency  Rate  _        ber  of  Disabling  Injurres/yr)  (1 .000,000) 


(Disabling  injuries) 


Number  of  Hours  Worked/yr 
(1/yr)  (1.000.000) 
"  74.b30/yr 


=  13  4 

Yet  another  consideration  may  be  lost-time  accidents.  The 
safety  officer's  analysis  may  take  into  account  many  other 
considerations,  but  in  any  event,  the  method  given  here  will 
provide  a  means  of  recording  and  measuring  injuries  In  the 
treatment  plant.  In  measuring  lost-time  Injuries,  a  severity 
rate  can  be  considered. 

A  seventy  rate  is  based  on  one  lost  ho'jr  for  every  million 
operator-hours  worked.  The  rate  is  found  by  multiplying  the 
number  of  hours  lost  by  one  million  and  dividing  by  the  total 
number  of  operator-hours  worked. 


Injury  Seventy  Rate 


EXAMPLE  3 


(Number  of  Hours  Lost/yr)  ("i  ,000.000) 
Number  of  Hours  Worked/yr 


The  water  company  described  in  Examples  1  and  2 
experienced  40  operator-hours  lost  due  to  injuries  while  the 


ERIC 


operators  worked  74,880  hours.  Calculate  the  injury  severity 
rate 


Known 

Number  of  Hours  Lost 
Number  of  Hours  Worked 


40  hrs/yr 
74,880  hrs/yr 


Unknown 

Injury  Severity 
Rate 


Calculate  the  injury  sev  .ity  rate. 

(Number  of  Hours  Lost/yr)  (1,000,000) 


Injury  Severity  Rate  = 


Number  of  Hours  Worked/yr 
(40  hrs/yr)  (1,000,000) 
74,880  hrs/yr 


=  534 

Notice  that  all  these  data  points  are  based  on  a  one  year 
time  interval  which  makes  them  suitable  for  use  by  the  safety 
officer  in  preparing  an  annual  report 

20.09  Human  Factors 

First,  you  may  ask,  what  is  a  human  factor?  Well,  it  is  not 
too  often  that  a  safety  text  considers  human  factors  as  part 
of  the  safety  program.  However,  if  these  factors  are  under- 
stood and  emphasis  is  given  to  their  practical  application, 
then  many  accidents  can  be  prevented.  Human  Factors 
Engineering  is  the  specialized  study  of  technology  relating  to 
the  design  of  operator-machine  interface.  That  is  to  say,  it 
examines  ways  in  which  machinery  might  be  designed  or 
altered  to  make  it  easier  to  u-.  ,  safer,  and  more  efficient  for 
the  operator.  We  hear  a  lot  about  making  computers  more 
user  friendly,  but  human  factor  engineering  is  just  as  impor- 
tant to  everyday  operation  of  other  machinery  in  the  every- 
day plant 

Many  accidents  occur  because  the  operator  forgets  the 
human  factors.  The  ultimate  responsibility  for  accidents  due 
to  human  factors  belongs  to  the  management  group.  How- 
ever, this  does  not  relieve  the  operator  of  the  responsibility 
to  point  out  the  human  factors  as  they  relate  to  safety.  After 
all,  It  IS  the  operator  using  the  equipment  who  can  best  tell  if 
It  meets  all  the  needs  for  an  inter-relationship  between 
operator  and  machine. 

The  first  step  in  the  preve.ition  of  accidents  takes  place  in 
the  plant  design.  Even  with  excellent  designs,  accidents  can 
and  do  happen.  However,  every  step  possible  must  be  taken 
during  design  to  assure  a  maximum  effort  of  providing  a 
safe  plant  environment.  Most  often  the  operator  has  little  to 
do  with  design,  and  therefore  needs  to  understand  human 
factors  engineering  so  as  to  be  able  to  evaluate  these 
factors  as  the  plant  is  being  operated.  As  newer  plants 
become  automated,  this  type  of  understanding  may  even  be 
more  important. 


Safety  401 


Other  contributing  human  factors  are  the  operator's  men- 
tal and  physical  characteristics.  The  operator's  decision- 
making abilities  and  general  behavior  (response  time,  sense 
of  alarm,  and  perception  of  problems  and  danger)  are  all 
important  factors.  Ideally,  tools  and  machines  should  func- 
tion as  intuitive  extensions  of  the  operator's  natural  senses 
and  actions.  Any  factors  disrupting  this  flow  of  action  can 
cause  an  accident.  Therefore,  be  on  the  lookout  for  such 
factors.  When  you  find  a  system  that  cannot  be  acted  upon 
by  inspection,  change  it.  You  may  prevent  an  accident.  If  the 
everyday  behavior  of  an  operator  is  inappropriate  mth 
regard  to  a  specific  job,  reconsider  the  assignment  to 
prevent  an  accident. 

The  human  factor  in  safety  is  the  responsibility  of  design 
engineers,  supervisors  and  operators.  However,  the  opera- 
tor who  IS  doing  the  work  will  have  a  greater  understanding 
of  the  operator-machine  interface.  For  this  reason,  the 
operUor  is  the  appropriate  person  to  evaluate  the  means  of 
reducing  the  human  factor's  contnbution  to  the  cause  of 
accidents,  thereby  improving  the  plant's  safety  record. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  wi^li  those  on  page  438. 

20. ON  Statistical  accident  reports  should  contain  what 
types  of  accident  data? 

20.00  How  can  injuries  be  classified*^ 

20. OP  How  can  causes  of  injuries  be  classified*^ 

20. OQ  How  can  costs  of  accidents  be  classified? 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  20.  SAFETY 

(Lesson  1  of  4  Lessons) 


At  the  end  of  each  lesson  in  this  chapter  you  will  find  some 
discussion  and  review  questions  that  you  should  work 
before  continuing.  The  purpose  of  these  questions  is  to 
indicate  to  you  how  well  you  understand  the  matenal  in  the 
lesson.  Write  the  answers  to  these  questions  in  your  note- 
book before  continuing. 

1.  Why  must  waterworks  utilities  have  a  safety  program*^ 

2.  How  can  a  good  safety  record  be  accomplished*? 

3.  What  IS  the  intent  of  the  OSHA  regulations'? 


4.  Why  should  water  utilities  establish  a  reporting  system 
that  supplies  data  for  a  permanent  record*? 

5  Why  do  operators  have  the  most  to  gam  from  an 
effective  safety  program? 

6.  Who  should  review  accident  report  forms'? 

7.  What  topics  should  be  included  in  a  safety  officer's  talk 
to  new  operators'? 

8.  What  are  the  purposes  of  "tailgate"  talks? 


402  Water  Treatment 


Chapter  20.  SAFETY 

(Lesson  2  of  4  Lessons) 

20.1    CHEMICAL  HANDLING 

20.10  Safe  Handling  of  Chemicals 

The  water  treatment  plant  operator  handles  a  wide  vanety 
of  chemicals  depending  on  the  type  of  plant.  In  a  simple  well 
system,  chlonne  may  be  the  only  chemical  used.  In  more 
complicated  plants,  there  may  be  chlorine,  other  gases, 
sulfuric  acid,  lime,  alum,  powdered  activated  ca'^bon  and 
anhydrous  ammonia.  All  of  these  chemicals  fall  into  groups: 
acids,  hydroxides,  gases,  salts,  organics  and  solvents.  Each 
group  requires  you,  the  operator,  to  have  a  good  under- 
standing of  all  types  of  chemicals.  You  must  know  how  to 
handle  the  many  problems  associated  with  each  of  these 
elements  or  compounds.  For  example,  you  must  know  how 
to  store  chemicals,  understand  the  fire  problem,  the  tenden- 
cy to  "arch"2  jn  a  storage  bin,  how  to  feed  dry,  how  to  feed 
liquid,  and  how  to  make  up  solutions.  All  of  these  factors  and 
many  more  problems  may  cause  an  unsafe  condition.  Over- 
heating gas  containers,  dust  problems  with  powdered  car- 
bon, burns  caused  by  a'^id,  reactivity  of  each  chemical  under 
a  variety  of  conditions  that  may  cause  fire  and  explosion  are 
other  safety  hazards.  You  will  need  to  know  the  usable  limits 
because  of  toxicity,  the  protective  equipmerit  required  for 
each  chemical,  each  chemical's  antidote,  and  how  to  control 
fires  caused  by  each  chemical.  Although  you  may  not 
regularly  handle  all  of  the  chemicals  listed  here,  you  may 
come  into  contact  with  them  from  tiine  to  time.  Try  at  least  to 
learn  all  of  the  charactenstics  or  the  chemicals  you  will  use 
regularly.  For  example,  learn  the  boiling  point,  explosive 
limits,  reactivity,  flammability,,  first  aid  used  for  each  chemi- 
cal, and  other  characteristics  that  may  prove  helpful  in 
preventing  a  safety  hazard.  Study  the  chemistry  of  each 
chemical  used  in  the  plant  in  order  to  have  a  safe  plant  in 
which  to  work.  In  the  following  discussions  we  shall  concen- 
trate on  the  characteristics  of  each  compound  and  point  out 
its  hazards,  reactivity  and  the  information  needed  to  avoid 
conditions  that  may  cause  a  safety  problem. 

20.11  Acids 

Acids  are  used  extensively  in  water  treatment.  For  exam- 
ple, hydrofluoric  acid  in  fluoride  addition  or  hydrochloric  acid 
in  cleaning  Table  20  3  lists  many  of  the  acids  used  in  water 


TABLE  20.3   ACIDS  USED  IN  WATER  TREATMENT 


Name,  Formula 

Common  Name 

Available  Specific 
Forms  Gravity 

Flam- 
mability 

Color 

Odor 

Containers 

Acetic  Acid,  CH3COOH 

Ethanoic  Acid 

Solution 

1.05 

N/A 

Clear 

Sharp,  pungent 

Carboys,  drums 

Hydrofluosilicic.  H2SiFg 

Fluosilicic  Acid 

Solution 

1.4634 

N/A 

Clear 

Pungent  fumes 

Drums,  trucks 
R.R.  tank  cars 

Hydrogen  Fluoride,  HF 

Hydrofluonc  Acid  Liquid 

0.987 

N/A 

Clear 

Funies,  toxic 

Drums,  tank  cars 

Hydrochloric  Acid,  HOI 

Monatic  Acid 

Solution 

1.16 

N/A 

Clear  to 
Yellow 

Pu  igent, 
sj.focating 

Drums,  carboys 

Nitnc  Acid,  HNO3 

Liquid 

1.5027 

N/A 

Colorless,  Toxic  fumes  in 
yellowish  presence  of  light 

Drums,  carboys, 
bottles 

Sulfuric  Acid,  HgSO^ 

Oil  of  Vitriol; 
Vitnol 

Solution 

(60-66^  G6)  N/A 
1.841 

Clear 

Odorless 

Bottles,  carboys, 
drums,  truck. 

tank  cars 

2  Arch,   To  form  a  bridge  or  arch  of  hardened  or  caked  chemical  which  will  prevent  the  flow  of  the  chemical 


treatment  and  gives  their  charactenstics.  This  quick  refer- 
ence gives  you  a  guide  for  learning  some  of  each  acid's 
limitations  and  its  reactivity  with  other  compounds. 

The  antidote  to  all  acids  is  neutralization.  However,  one 
must  be  careful  in  how  this  is  peformed.  Most  often  large 
amounts  of  water  will  serve  the  purpose,  but  if  the  acid  is 
ingesteo  (swallowed),  then  lime  water  or  milk  of  magnesia 
may  be  needed.  If  vapors  are  inhaled,  first  aid  usually 
consists  of  providing  fresh  air,  artificially  restoring  breathing 
(CPR),  or  supplying  oxygen.  In  general,  acids  are  neutralized 
by  a  base  or  alkaline  substance.  Baking  soda  is  often  used 
to  neutralize  acids  on  skin  because  it  is  not  harmful  on 
contact  with  your  skin.  To  understand  these  reactions,  you 
\N\\\  need  to  know  some  acid-base  chemistry.  The  knowledge 
of  acid-base  chemistry  and  fast  reactions  on  your  part  may 
reduce  the  safety  hazards  involved  in  handling  acids  in  water 
treatment. 

20. 1 10  Acetic  Acid  (Glacial) 

This  chemical  is  stable  when  stored  and  handled  properly. 
However,  it  may  react  volently  with  certain  compounds  such 
as  ammonium  nitrate,  potassium  hydroxide  and  other  alka- 
line materials.  Strong  oxidizing  glacial  acetic  acid  is  a 
combustible  matenal.  Fires  involving  the  acid  may  be  extin- 
guished wi.h  water,  dry  chemical  or  carbon  dioxide.  Under 
such  conditions  as  adding  water,  the  diluted  acid  may 
produce  hydrogen  gas  when  it  comes  in  contact  with  metals. 
When  the  chemical  is  involved  in  a  fire  situation,  self- 
contained  breathing  apparatus  must  be  used  to  protect  the 


Safety  403 


operator  against  suffocation  and  problems  caused  by  corro- 
sive vapors 

Most  people  ,'ind  inhalation  of  acetic  acid  vapors  in 
concentrations  over  50  ppm  intolerable,  resulting  in  nose 
and  throat  irritations.  Repeated  exposure  to  high  concentra- 
tions may  produce  congestion  of  the  larynx.  Skin  contact 
with  concentrated  acetic  acid  can  produce  deep  burns,  with 
skin  destruction.  High  vapor  concentration  may  blacken  the 
skin  and  produce  allergenic  reactions  and  eye  irritation. 
Possible  permanent  damage  or  immediate  burns  are  caused 
to  the  eye  if  the  acid  comes  Into  contact  with  the  eye.  If  the 
acid  is  ingested,  severe  intestinal  Irntation  will  result  as  well 
as  burns  to  the  mouth  and  upper  respiratory  tract. 

Operators  should  be  protected  by  adequate  exhaust  facili- 
ties to  ensure  ventilation  when  working  with  acetic  acid.  At  a 
minimum,  exhaust  hoods  should  have  air  velocity  of  100  fpm 
(30  m/min).  Wear  rubber  gloves  and  an  apron  to  prevent  skin 
contact.  Wear  splash-proof  goggles  or  a  face  shield  to 
prevent  any  eye  contact.  Gas-tight  goggles  may  also  be 
needed  to  prevent  vapors  from  irritating  your  eyes.  An  eye 
wash  station  must  be  readily  available  where  this  chemical  is 
being  handled.  Also,  respiratory  equipment  should  be  avail- 
able for  emergency  use  Acetic  acid  can  be  handled  safely 
by  using  adequate  ventilation  and  safety  equipment  to 
prevent  skin  and  eye  contact.  Remember  also  that  acetic 
acid  vapors  can  cause  OLFACTORY  FATIGUE  (o\-fAK-\ore- 
ee).  This  is  a  condition  in  which  a  person's  nose,  after 
exposure  to  certain  odors,  is  no  longer  able  to  detect  the 
odor.  Acetic  acid  is  detectable  by  your  nose  at  1  ppm,  but 
documentation  has  shown  operators  tolerating  up  to  200 
ppm. 

If  a  leak  or  spill  should  occur,  notify  safety  personnel  and 
provide  adequate  ventilation.  When  cleaning  up  large  spills, 
wear  self-contained  breathing  apparatus  and  equipment  to 
prevent  contact  with  eyes  and  skin.  To  clean  up  spill  areas 
and  remove  chemical  residue,  cover  the  area  with  sodium 
bicarbonate  and  flush  away  with  an  excess  of  water. 

First  aid  for  a  etic  acid  exposure  calls  for  removal  of  the 
victim  to  fresh  air,  rinsing  the  mouth  and  nasal  passages 
with  water  and  checking  for  Inhalation  problems.  If  the  acid 
made  contact  with  the  eyes,  immediately  irrigate  with  water 
for  at  least  15  minutes.  Obtain  medical  attention.  For  skin 
contact  problems,  wash  with  water  immediately,  if  the  acid 
was  swallovv'ed,  9»ve  three  gla^.ses  of  milk  or  water  and 
obtain  medical  altention  quickly  Acetic  acid  exposure,  like 
all  other  acids,  must  be  treate  immediately  to  prevent 
damaoe  to  the  victim. 

20,111   Hydrotiuosilicic  Acid 

This  chemical  is  hazardous  to  handle  under  any  condi- 
tions. Be  extren-ely  careful  using  this  acid.  The  acid  is 
colorless,  transparent,  fuming,  corrosive  and  is  a  li  ,uid.  A 
pungent  odor  is  created  by  the  acid  and  contact  causes  skin 
irritation.  When  the  acid  vaporizes,  it  decomposes  into 
hydrofluoric  acid  and  silicon  tetrafluonde.  Hydrofluoric  acid 
can  attack  jlass.  When  handling  the  acid,  always  use 
complete  protective  equipment,  rubber  gloves,  goggles  or 
face  shield,  rubber  apron,  rubber  boots  and  have  lime  slurry 
barrels,  epsom  salt  solution  and  safety  showers  (Figure 
20.3)  available.  Always  provide  adequate  ventilation  be- 
cause Its  vapor  can  cause  irntation  to  the  respiratory  sys- 
tem. Careful  maintenance  of  protective  equipment  is  essen- 
tial because  the  fumes  of  t  acid  corrode  or  etch  glass  on 
the  protective  equipment. 


First  aid  for  eye  contact  is  to  thoroughly  flush  with  water 
for  15  minutes  and  get  medical  aid  as  soon  as  possible.  For 
skin  contact,  wash  the  affected  areas  witn  water  For  gross 
(large)  contact,  remove  contaminated  clothing  under  a  safety 
shower  and  thoroughly  wash  entire  body  for  15  minutes  or 
longer.  In  case  of  inhalation,  remove  operator  to  fresh  air, 
restore  breathing,  if  required,  and  get  medical  aid. 

20.112  Hydrofluoric  Acid 

This  acid  :S  extremely  poisonous,  and  produces  terrible 
sores  when  allowed  to  come  into  contact  with  the  skin.  The 
t  "id  IS  a  clear,  corrosive  liquid  that  has  a  pungent  odor.  All  of 
the  precautions  discussed  for  hydrofluosilicic  acid  apply  to 
this  acid  also. 

20. 1 13  Hydrochloric  Acid 

This  ac'd  IS  used  most  often  for  cleaning  in  and  around  the 
treatment  plant  and  is  known  as  munatic  acid.  The  acid  is 
also  used  very  frequently  in  the  laboratory.  Hydrochloric 
acid  is  stable  vA^en  properly  contained  and  handled.  This 
acid  IS  one  of  tne  strong  mineral  acids  and  therefore,  is 
highly  reactive  ^*i;h  metals  and  these  oxides:  hydrocarbon, 
amine,  and  carbonate  compounds.  The  acid  liberates  signifi- 
cant iGveis  of  hydrogen  chloride  gas  (HCI)  beuduse  of  Its 
vapor  pressure  at  room  temperature  a"d  gives  off  large 
amounts  of  gas  when  heated.  In  reactions  with  most  metals, 
hydrochloric  acid  will  produce  hydrogen  gas. 

Inhalation  of  HCI  vapors  or  mists  for  long  periods  can 
cause  damage  to  teeth  an*^  irritation  to  ine  nasal  passages. 
Concentrations  750  ppm  or  more  will  cause  coughing, 
choking  and  produce  severe  damage  of  the  mucous  mem- 
branes of  the  respiratory  tract.  In  concentrations  of  1300 
ppm,  HCI  IS  dangerous  to  life.  Ingoction  can  cause  burns  of 
the  mouth  and  digpstive  fact. 

When  handling  HCI.  provide  adequate  exhaust  facilities  to 
ensure  ventilation  arj  wear  protective  clothing  and  equip- 
ment to  prevent  body  contact  with  the  acid.  Use  rubber 
gloves,  rubber  apron,  rubber  boots  and  wear  a  long-sleeved 
shirt  when  handling  nydrochloric  acid  To  protect  your  eyes 
against  splashing  of  :^e  acid,  you  must  .vear  safety  goggles 
and/or  a  face  shield,  ^here  should  ai.'  iys  be  an  eye  wash 
station  and  safety  sho.ver  located  near  -^reas  where  th-f^  acid 
IS  to  be  used. 

First  aid  consists  of  thoroughly  fiLsr-.  ng  the  *»yes  with 
running  water  for  15  min  jtes  and  se^Jr  g  medical  aid.  If 
hydrochloric  acid  comes  m  contact  •'ith  skin,  wash  the 
affected  areas  with  water  ^or  gross  co  i*act  remove  cloth- 
ing under  the  safety  show-;'  and  contint'  showering  for  15 
minutes  or  longer.  Shoula  'he  acid  be  ingested,  give  ime 


404  Water  Treatment 


Model  01-0354-07— Face  Wash.  Yello-Bowr^ 
and  Stainless  Steel  pipe  and  valve. 

Specially  Coated  Corrosion-Proof  Models 

In  addition  to  corrosion-resistant  Stainless  Steel, 
various  coatings  are  available  for  protection 
against  corrosive  atmospheres  at  additional  cost. 
The  sprayed  and  baked  epoxies  as  well  as  the 
new  fluorocarbon  coatings  can  be  applied  on  all 
galvanized  and  stainless  pipe  and  fittings.  Specify 
type  of  coating  required. 

Plastic  Models  Available 

All  PVC  plastic  models  for  Face/Eye  Washes 
as  well  as  combination  Shower-Face/Eye  Wash 
assemblies.  Ask  your  distributor  for  details. 


Part  *  01-1128-06— 

Shower  and  wash  sign. 
Rugged  plastic  base, 
yellow  and  black  con- 
trast, 8"  x  18". 


Model  01-0502-19— Shower/Face  Wash.  Yello- 
Bowr".  Stainless  Steel  piping,  fittings,  and  valves. 


Fig.  20.3  Safety  shower  with  face-eye  wash 

(Permission  of  Nevada  Safety  A  Supply) 


water,  or  water  and  milk  of  magnesia.  Do  not  induce 
vomiting;  get  medical  aid.  In  case  of  inhalation,  remove  the 
victim  to  fresh  air,  restore  breathing  if  required,  and  get 
medical  aid. 

Store  acid  containers  closed  in  a  clean,  cool,  open  and 
well-ventilated  area.  Keep  out  of  the  sun.  Keep  the  acid 
away  from  oxidizing  agents  or  alkaline  materials.  Provide 
emergency  neutralization  materials  in  use  areas. 

20.114  Nitric  Acid 

Like  hydrochloric  acid,  nitric  acid  is  one  of  the  most 
commonly  used  acids  in  the  water  treatment  laboratory  and 
plant.  The  acid  is  a  powerful  oxidizing  agent  and  attacks 
most  metals.  Nitric  acid  is  stable  when  properly  handled  and 
placed  into  a  proper  container.  The  acid  is  one  of  the  strong 
mineral  acids,  and  is  highly  reactive  with  materials  such  as 
metals.  When  handling  nitnc  acid,  use  protective  clothing 
and  equipment  to  prevent  body  contact  with  the  liquid.  Such 
equipment  includes  rubber  gloves,  rubber  apron,  and  safety 
goggles  or  a  face  shield  for  eye  protection  against  splashing 
of  the  acid.  Nitric  aad  is  a  strong,  poisonous  and  highly 
corrosive  liquid  and  must  be  handled  care  illy.  The  acid 
forms  toxic  fumes  in  the  presence  of  Lght;  therefore,  it 
should  be  kept  out  of  the  sun. 

Like  other  acids,  nitric  acid  should  be  stored  in  clean,  cool, 
well-ventilated  areas.  The  areas  should  have  an  acid-resist- 
ant floor  and  adequate  drainage.  Keep  it  away  from  oxidiz- 
ing agents  and  alkaline  materials.  Protect  containers  from 
damage  or  breakage.  Avoid  contact  with  skin  and  provide 
emergency  neutralization  materials  ,.nd  safety  equipment  in 
use  areas. 

First  aid  for  skin  contact  is  to  flush  thoroughly  with  water 
for  15  minutes.  Get  medical  aid  if  needed.  This  acid  will 
cause  burns,  but  these  can  be  greatly  reduced  if  the  contact 
area  is  immediately  flushed.  For  gross  (large)  contact,  re- 
move contaminated  clothing  under  a  safety  shower.  For  eye 
contact,  flush  with  water  for  15  minutes  and  get  medical  aid. 
If  acid  IS  ingested,  give  lime  water  or  water  with  milk  of 
magnesia;  get  medical  aid.  For  inhalation,  remove  to  fresh 
air,  restore  breathing  if  required,  and  get  medical  aid. 

20.115  Sulfuric  Acid 

Thts  mineral  acid  is  highly  corrosive  and  will  attack  most 
metals.  Sulfuric  acid  is  also  very  reactive  to  the  skin  and 
must  be  handled  with  extreme  care  or  you  will  suffer  severe 
burns.  Even  when  the  acid  is  diluted,  it  is  highly  corrosive 
and  must  be  contained  in  rubber,,  glass  or  plastic-lined 
equipment.  The  acid  will  decompose  clothing  and  shoes. 
Sulfuric  acid  should  not  come  in  contact  with  potassium 
permanganate  or  similar  compounds.  Sulfuric  acid  reacts 
violently  with  water.  ALWAYS  POUR  ACID  INTO  WATER 
while  stirnng  to  prevent  the  generation  of  steam  and  hot 
water  which  could  boil  over  the  container  and  cause  serious 
acid  burns. 

As  with  other  mineral  acids,  this  material  is  stable  when 
properly  contained  and  handled.  When  you  are  handling 
sulfuric  acid,  you  must  use  protective  clothing  and  equip- 
ment to  prevent  body  contact  with  the  acid.  Wear  rubber 
gloves,  safety  goggles  and/or  a  face  shield  for  eye  protec- 
tion against  splashing.  Also  wear  a  rubber  apron,  rubber 
boots,  and  long-sleeved  shirt.  The  eye  wash  station  and 
safety  shower  must  be  located  nearby  where  the  acid  is 
being  handled.  The  area  should  be  well-ventilated,  the  acid 
should  be  stored  in  closed  containers  in  a  clean,  cool,  open 
area.  The  area  should  have  an  acid-resistant  floor  which  is 
well  drained.  Keep  away  from  oxidizing  agents  and  alkaline 

ERIC 


Safety  405 

materials  and  protect  the  containers  from  damagt  or  break- 
age 


Because  the  acid  is  highly  corrosive  and  causes  severe 
burns,  first  aid  for  sulfuric  acid  must  be  immediate  to  avoid 
substantial  damage  to  human  tissue.  For  eye  contact,  flush 
thoroughly  with  running  water  for  15  minutes,  get  medical 
aid  —  the  first  seconds  are  important.  For  skin  contact, 
wash  affected  areas  thoroughly  with  water.  For  gross  (large) 
contact,  remove  contaminateo  clothing  under  the  safety 
shower  with  prolonged  washing  for  at  least  15  minutes.  In 
cases  of  ingestion,  give  lime  water  or  water  and  milk  of 
magnesia  to  drink;  get  medical  aid.  When  working  with 
sulfuric  acid,  avoid  skin  contact  and  ai  vays  provide  emer- 
gency neutralization  materials  and  a  safety  shower  near  the 
work  areas. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  438. 

20.10A  What  does  an  operator  need  to  know  about  chemi- 
cals used  in  a  water  treatment  plant? 

20.11  A  What  should  be  done  if  an  operator  inhales  acid 

vapors'? 

20.1  IB  Acetic  acid  will  react  violently  with  which  com- 
pounds'? 

20  1 1C  Under  what  conditions  can  acetic  acid  be  handled 
safely'? 

20  11D  What  protective  equipment  is  necessary  for  han- 
dling hydrofluosihcic  acid'? 

20.1 1 E  How  can  the  inhalation  of  hydrochloric  (HCI)  vapors 
or  mists  cause  damage  to  opei<:*ors? 

20  11F  How  should  nitric  acid  be  stored? 

20.12  Bases 

The  bases  that  are  used  in  water  treatment  are  known  as 
hydroxides  From  a  functional  standpoint  they  are  used  to 
raise  pH.  Most  common  bases  are  compounds  of  sodium, 
calcium  and  ammonium  which  are  strong  bases.  However, 
there  are  other  weak  bases,  such  as  silicate,  carbonate  and 
hypochlorite.  But  fiom  the  p'jint  of  safety,  both  weak  and 
strong  bases  must  be  given  the  same  consideration  when 
being  handled  Some  are  very  toxic,  and  will  attack  human 
tissue  very  rapidly  and  cause  burns.  Explosive  reactions  will 
occur  when  bases  come  in  contact  with  an  acid  and  hazard- 
ous decomposition  products  are  created  under  certain  con- 
ditions. Bases  must  be  neutralized  with  dilute  acids.  Howev- 
er, the  operator  must  work  carefully  because  under  some 
conditions  there  may  be  other  reactions,  suuh  as  with 
hypochlorite  compounds.  Therefore,  you  should  understand 
acid-base  chemistry  before  handling  any  of  the  basic  com- 


406  Wat**r  Treatment 


pounds  used  in  water  treatment  Table  20.4  give?  some  of 
the  common  basic  compounds  used  in  water  treatment.  The 
following  sections  will  discuss  some  of  their  characteristics 
and  the  precautions  the  operator  must  use  to  safely  handle 
such  compounds. 

12.120  Ammonia 

The  operator  may  use  one  of  two  forms  of  ammonia, 
anhydrous  or  hydroxide.  The  first  (anhydrous)  is  in  a  gas 
form  and  requires  one  type  of  consideration.  The  hydroxide 
IS  a  liquid  and  requires  another  type  of  consideration. 
Anhydrous  ammonia  in  the  gaseous  state  is  colorless,  about 
0.6  times  as  heavy  as  air.  In  a  liquid  state,  ammcnia  is  also 
colorless,  0.68  times  as  hsavy  as  water  and  u  vaporizes 
rapidly.  The  ammonia  gas  is  capable  of  forming  explosive 
mixtures  with  air.  For  your  own  safety,  be  aware  of  the 
possibility  of  suffocation  since  the  gas  can  displace  air 
which  contains  oxygen.  Although  the  vapors  are  not  poison- 
ous, they  can  and  will  irritate  the  mucous  membranes  of  the 
eyes,  nose,  throat  and  lungs.  Irritation  will  be  detected  in 
concentrations  of  5.0  ppm  and  when  human  tissue  comes  in 
contact  with  the  liquid,  it  will  cause  severe  burns. 

When  handling  ammonia  or  working  in  an  ammonia  p  ivi- 
ronment,  respiratory  protection  is  a  requirement.  For  entry 
into  emergency  areas,  use  only  a  self-contained  breathing 
apparatus.  Install  a  good  ventilation  system  to  control  va- 
pors In  the  application  room.  Use  protective  clothing,  rubber 
gloves,  apron,  boots  and  face  and  eye  protection  if  you  are 
going  to  work  with  ammonia  for  long  penods. 

Care  must  be  used  when  storing  or  transporting  contain- 
ers Always  keep  cylinders  with  caps  in  place  when  not  in 
use.  Store  cylinders  in  a  cool,  dry  location  away  from  heat 
and  protect  from  direct  sunlight.  Storage  near  radiators, 
steam  pipes  or  other  sources  of  neat  may  raise  the  pressure 
to  a  dangerous  point,  whereas  dampness  nay  cause  exces- 
sive corrosion.  Do  not  store  in  the  same  ''oom  with  chlorine. 
Always  use  lifting  clamps  or  cradles.  Avoid  hoisting  the 
cylinde  z  using  ropes,  cables  or  slings  and  never  drop  the 
containers  Control  ammonia  Isaks.  They  can  be  detected  by 
cdor  or  by  using  a  cloth  swab  soaked  with  hydrochloric  acid. 
This  will  form  a  white  cloud  of  r-mmonium  chloride. 

Ammonia  gas  will  burn  if  it  is  blended  with  z\r  in  a  mixture 
containing  15  to  28  percent  ammonia  by  volume.  Check 
cylinder  valve  stems  for  leaks*  tighten  the  packing  gland  nut 
only  with  a  special  wrench  pi  /ided  for  such  purposes.  If  a 
serious  leak  m  a  cylinder  cannot  be  controlled,  place  the 
container  in  a  vat  of  water.  Fifty-three  pounds  of  ammonia 
will  dissolve  in  100  pounds  of  water  at  68''F  (20''C).  NEVER 


neutralize  liquid  ammonia  with  an  acid.  The  reaction  gener- 
ates a  lot  of  heat  which  may  speed  up  the  release  of 
ammonia  gas. 

First  aid  for  skin  contact  with  ammonia  is  to  flush  with 
large  amounts  of  water  for  5  to  10  mmutes  and  get  medical 
aid  Remove  contaminated  clothing  under  a  safety  shower. 
For  eye  contact,  flush  thoroughly  with  water  *or  15  minutes 
immediately,  and  get  medical  aid.  In  the  case  of  inhalation, 
remove  to  fresh  air  and  restore  breathing.  If  required,  get 
medical  aid.  Nose  and  throat  burns  should  be  washed  with 
water  and  nnsed  with  two  percent  bone  acid  solution.  Urge 
the  patient  to  drink  large  amounts  of  milk. 


Ammonium  hydroxide  is  an  aqueous  (watery)  solution  of 
anhydrous  ammonia  and  is  quite  volatile  (will  evaporate)  at 
atmospheric  temperatures  and  pressures.  This  solution  can 
cause  local  skin  irritations  A  strong  solution  will  cause 
human  tissue  destruction  on  contact  with  eyes,  skin  and 
mucous  membranes  of  the  respiratory  system,  so  avoid 
contact  with  the  compound.  The  solution  will  cause  severe 
burns  depending  upon  solution  icentrations  and  length  of 
contact  time.  The  solution's  vapor  causes  the  same  effects 
as  the  gas  First  aid  should  be  the  same  as  for  anhydrous 
ammonia. 

20. 121   Calcium  Hydroxide 

Hydrated  lime  (calcium  hydroxide)  is  one  form  nf  hme  and 
quicklime  (calcium  oxide)  is  another  form.  The  hydrated  lime 
IS  the  least  troublesome  of  thp  two  forms.  The  hydrated  lime 
IS  less  caustic  and  is  therefore  less  irritating  to  the  skin,  but 
can  cause  injury  to  eyes.  However,  as  a  dust,  it  is  just  as 
hazardous  as  quicklime.  Quicklime  is  a  strong  caustic  and 
irritating  to  personnel  exposed  to  the  compound.  When 
quicklime  is  mix^d  with  water,  a  great  deal  of  heat  is 
generated  which  can  cause  explosions. 


Name,  Formula 


TABLE  20.4   BASES  USED  IN  WATER  TREATMENT 


Common 
Name 


Available 
Fomis 


Calcium  Hydroxide  and 
Oxide,  Ca(0H)2  or  CaO 


Hydrated  Lime  Dry  Powder, 
or  Quick  Lime  Lump 


Sodium  Hydroxide,  NaOH    Caustic,  Lye 


Codium  Silicate,  NagSiOg 


Water 
Glass 

Hypochlorite  Compounds,  HTH 
NaOCI,  Ca(0CI)2 

Sodium  Carbonate,  NagCOg  Soda  Ash 


Lump,  Liquid, 
Flake 


Liquid 

Powder 

Powder 


Spec.  Grav. 


50-70  lbs 
per  cu  ft 

1.524 


1.35-1.42 


23.  35,  and 
65  Ibs/cu  ft 


Flammabliity 

Color 

Odor 

Containers 

N/A 

White 

Dust 

Bags.  Bulk, 
Trucks 

May  Cause 
Flammable 
Condition 

Opaque 
White 

Toxic, 
Pungent 

Drums,  Bulk, 
Trucks 

N/A 

Opaque 

N/A 

Drums,  Bulk, 
Trucks 

Explosive  with 
Antifreeze 

White 

Toxic  CIg, 
Pungent 

Cans,  Drums 

N/A 

White 

Dust 

Bags,  Bulk, 
Trucks 

Safety  407 


Both  qucklime  and  hydrated  lime  should  be  stored  in  cool, 
dry  areas.  Care  must  be  taken  to  avoid  mixtures  of  alum  and 
quicklime,  since  quicklime  tends  to  absorb  the  water  that 
forms  as  alum  crystallizes  (water  of  crystallization)  away 
from  the  alum.  In  a  closed  container  this  could  lead  to  a 
violent  explosion.  Equal  care  should  be  taken  to  avoid 
mixtures  of  fernc  sulfate  and  lime. 

When  handling  bc*h  forms  of  lime,  the  operator  should 
use  chemical  goggles  and  a  suitable  dust  mask  to  protect 
the  eyes  and  mucous  membranes.  Also  wear  proper  cloth- 
ing to  protect  the  skin,  because  with  long  contact  the  lime 
can  cause  dermatitis  or  burns,  particularly  at  perspiration 
points.  Always  shower  after  handling  quicklime.  All  opera- 
tors should  wear  a  face  shield  when  inspecting  lime  slakers. 
Hot  lime  suspension  that  splatters  on  the  operator  may 
cause  severe  burns  of  the  eyes  or  skin.  The  hot  mist  coming 
from  the  slakers  is  also  dangerous.  The  loss  of  water  supply 
to  a  lime  slaker  can  create  explosive  temperatures. 

First  aid  for  lime  burns,  which  are  like  burns  -rom  other 
caustics,  consists  of  alternatively  washing  with  water  and  a 
mild  acetic  acid  solution.  One  may  also  use  large  amounts  of 
soap  and  water.  For  eye  contact,  wash  immediately  with 
large  amounts  of  warm  water  and  nnse  with  a  boric  acid 
solution.  Get  medical  aid.  For  irritation  of  nose  and  throat 
because  of  exposure,  see  a  physician. 

20,122  Sodium  Hydroxide  (Caustic  Soda) 

Sodium  hydroxide  is  available  in  pellet  and  flake  forms. 
Caustic  soda  usually  comes  as  a  50  percent  solution  of 
sodium  hydroxide.  This  base  is  a  strong  caustic  alkali  and 
very  hazardous  to  the  operator.  This  compound  is  extremely 
reactive.  Sodium  hydroxide  absorbs  carbon  dioxide  from  the 
air,  reacting  violently  or  explosively  with  acid  and  a  number 
of  organic  compounds.  Caustic  soda  1)  dissolves  human 
skin,  2)  when  mixed  with  water  cajses  heat,  and  3)  reacts 
with  amphotenc  metals  (such  as  aluminum)  generating  hy- 
drogen gas  which  is  flammable  and  may  explode  if  ignited. 
Sodium  hydroxide  can  be  dissolved  in  water  and  the  solution 
used  for  the  adjustment  of  pH  because  it  is  a  liquid  and  easy 
to  feed.  This  base  is  extensively  used  in  water  treatment. 
Because  of  its  everyday  use,  you  may  forget  just  how 
he  zardous  this  compound  if  and  throug.  ♦  neglect  may  injure 
yourself  or  another  operator.  Only  trairjed  and  protected 
operators  should  undertake  spill  cleanup.  The  operator 
must  act  cautiously,  dilute  the  spill  with  water  and  neutralize 
with  a  dilute  acid,  preferably  acetic. 

When  handling  caustic  soda,  control  the  mists  with  good 
ventilation.  Protect  your  nose  and  throat  with  an  approved 
respiratory  system.  For  eye  protection,  you  must  wear 
chemical  worker's  goggles  and/or  a  full  face  shield  to 
protect  your  eyes.  There  must  be  an  eye  wash  and  safety 
shower  at  or  near  the  work  station  for  this  chemical.  Protect 
your  body  by  being  fully  clothed,  and  by  using  impervious 
gloves,  boots,  apron  and  face  shield. 

Special  precautions  to  be  taken  when  handling  or  storing 
caustic  soda  include  (1)  prevent  eye  and  skin  contact,  (2)  do 
not  breath  dusts  or  mists,  and  (3)  avoid  storing  this  chemical 
next  to  strong  acids.  Dissolving  sodium  hydroxide  in  water 
or  other  substances  generates  excessive  heat,  causes 
splattering  and  mists.  Solutions  of  sodium  hydroxide  are 
viccous  and  slippery. 

First  aid  for  the  eyes  consists  of  irrigating  the  eyes 
immediately  and  continuously  with  flowing  water  for  at  least 
30  minutes.  Prompt  medical  attention  Is  essential.  For  skin 
burns,  immediate  and  continuous,  thorough  washing  in 
flowing  water  for  30  minutes  Is  important  to  prevent  damage 

ERIC 


to  the  skin  Consult  a  physician  if  required.  In  case  of 
inhalation,  remove  victim  to  fresh  air,  call  physician,  or 
transport  injured  person  to  a  medical  facility  For  ingestion, 
give  large  amounts  of  water  or  milk  and  immediately  trans- 
port injured  person  to  a  medical  facility,  DO  NOT  INDUCE 
VOMITING. 

You  may  also  have  occasion  to  use  sodium  hydroxide  as 
flakes  or  pellets  AH  of  the  precautions  stated  for  liquid 
caustic  also  apply  for  the  flake  form 

20,123  Sodium  Silicate 

This  chemical  is  a  liquid  as  used  in  water  treatment. 
However,  it  is  non-toxic,  non-flammable,  and  non-explosive, 
but  presents  the  same  hazards  to  the  eyes  and  skin  as  any 
other  base  compounds.  Sodium  silicate  is  a  strong  alkali  and 
should  be  handled  with  care  by  using  goggles  or  face  shield, 
wearing  gloves  and  protective  clothing.  The  chemical  will 
cause  damage  to  the  eyes  and  skin,  but  it  is  less  dangerous 
than  other  alkaline  compounds  used  in  water  treatment. 

First  aid  for  the  eyes  is  to  flush  immediately  and  thorough- 
ly with  flowing  water  for  at  least  15  minutes.  Get  medical 
attention.  If  sodium  silicate  makes  contact  wit'  zk\n,  wash 
thoroughly  with  water,  particularly  if  the  solution  is  hot.  Then 
wash  the  skin  with  a  10  percent  solution  of  ammonium 
chloride  or  10  percent  acetic  acid.  For  ingest'on.  give  plenty 
of  water  and  dilute  vinegar,  lemon  or  orange  juice.  Follow 
this  with  milk,  white  of  eggs  beaten  with  water  or  olive  oil. 
Call  a  physician. 

2ii124  Hypochlorite 

A  number  of  hypochlorite  compounds  are  commercially 
available  for  use  i'  A'ater  treatment.  If  you  understand  the 
precautions  for  one  such  compound,  you  will  know  what 
steps  must  be  taken  with  other  hypochlorite  compounds, 
su^h  as  calcium,  sodium,  or  lithium.  These  '"hemicals  may 
be  used  in  either  a  liquid  or  dry  form.  There  are  several 
grades  of  hypochlorite  compounds,  but  all  are  good  oxi- 
dizers and  are  used  for  disinfection.  When  these  com- 
pounds come  into  contact  with  organic  materials,  their 
decomposition  releases  heat  very  rapidly  and  produces 
oxygen  and  chlorine.  Although  hypochlorite  compounds  are 
non-flammable,  they  may  cause  fires  when  they  come  in 
contact  with  heat,  acids,  organic  or  other  oxidizable  sub- 
stances. 

All  solutions  of  hypochlontG  coinpounds  attack  the  skin, 
eyes  or  other  body  tissues  with  which  they  come  into 
contact.  When  handling  hypochlorite,  liquid  or  dry,  use 
suitable  protective  clothing  such  as  rubber  gloves,  aprons, 
goggles  and/or  a  face  shield.  Be  u.yare  that  many  times 
these  compounds  are  stored  in  containers  and  give  off 
chlorine  gas  when  opened.  Store  these  compounds  in  a 
cool,  dry,  dark  area. 


408  Water  Treatment 


First  aid  for  eyes  is  to  flush  with  plenty  of  water  lOr  at  least 
15  minutes  and  see  a  ohysiclan.  If  hypochlorite  compounds 
come  in  contact  with  tfie  skin,  flush  thoroughly  with  water  for 
at  least  15  minutes,  and  get  medical  attention  as  needed.  In 
case  of  ingestion,  wash  out  mouth  thoroughly  with  water 
and  give  plenty  of  water  to  drink,  and  get  medical  attention. 
For  inhalation,  move  the  victim  into  Uesh  air  and  get  meJical 
attention. 

Over-exposure  to  any  of  the  hypochlorite  compounds  may 
produce  severe  burns,  so  avoid  contact  with  these  com- 
pounds. They  are  hazardous  and  can  attack  skin,  eyes, 
mucous  membranes  and  clothing. 

20, 125  Sodium  Carbonate 

Soda  ash  is  a  mild  alkaline  compound,  but  requires  safety 
precautions  to  minimize  hazards  when  handling  the  chemi- 
cal. An  adequate  ventilation  system  is  needed  to  control  the 
dust  generated  by  the  compound.  Wear  protective  gear, 
such  as  chemical  safety  goggles  and/or  a  face  shield,  a  well- 
fitting  dust  respirator  and  protective  clothing  to  avoid  skin 
contact.  You  should  protect  yourself  by  using  a  suitable 
cream  or  petroleum  jelly  on  exposed  skin  surfaces,  such  as 
neck  and  hands.  This  compound's  dust  irritates  the  mucous 
membranes  and  prolonged  exposure  can  cause  sores  in 
your  nasal  pasi.age. 

First  aid  for  exposure  tc  eyes  (dust  or  solution)  requires 
irrigation  with  water  immediately  for  at  least  15  minutes. 
Consult  a  physician  if  the  exposure  hai;  been  severe.  For 
skin  exposure,  wash  with  large  amounts  of  water;  for 
contaminated  clothing,  wash  before  reusing.  For  inhalation 
or  irritation  of  the  respiratory  tract,  gargle  or  spray  with 
warm  water,  and  consult  a  physician  as  needed. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  439. 

20.1 2A  What  are  the  two  forms  of  ammonia  used  by 
operators 

20.1 2B  How  should  ammonia  be  stored? 

20.1 2C  What  are  the  two  forms  of  lime  used  in  water 
treatment  plants'? 

20.1 2D  What  would  you  do  if  someone  swallowed  sodium 
hydroxide? 

2012E  What  would  you  do  if  sodium  silicate  came  in 
contact  with  your  skin? 


20.13  Gases 

There  are  a  number  of  gases  used  in  water  treatment 
(Table  20  5)  Most  are  supplied  in  steel  drum  containers, 
others  must  be  generated  on  site.  Some  gases  can  be  seen, 
others  call  the  operator's  attention  by  odor,  and  still  others 
cannot  be  seen  or  detected  by  odor,  yet  are  deadly.  In  this 
section  we  shall  only  discuss  those  which  are  supplied  in 
containers  that  the  operator  must  connect,  disconnect, 
handle  or  store. 

Exposure  to  the  liquid  form  of  these  gases  usually  will 
cause  damage  to  human  tissue,  such  as  skin  burns,  but  the 
most  important  factor  to  remember  is  the  displacement  of 
oxygen.  Most  gases  are  heavier  than  aii  aiici  remove  air 
from  a  room  by  displacement.  Therefore,  it  is  very  important 
to  have  the  right  type  of  ventilation  and  respiratory  protec- 
tion. Use  only  the  self-contained  breathing  apparatus  when 
working  in  emergency  areas. 


20.130  Chlorine  (Cl^) 


Safety  is  of  the  utmost  importance  when  handling  chlo- 
rine. Do  not  treat  chlorine  cylinders  roughly;  never  drop  them 
or  permit  collision  of  two  or  more  cylinders.  Never  hoist 
chlorine  cylinders  by  the  neck.  Always  use  lifting  clamps  or 
cradles  —  do  not  use  ropes,  cables  or  chains.  Store  the 
cylinders  in  such  a  way  that  they  cannot  fail.  Do  not  store 
chlorine  cylinders  below  ground  level  and  always  keep  the 
protective  cap  on  the  cylinder  when  it  is  not  in  use.  Mark  the 
empty  containers  and  store  them  aside  from  full  cylinders. 
Always  store  containers  in  an  upright  position  in  a  clean,  dry 


TABLE  20.5    GASES  USED  IN  WATER  TREATMENT 


Name,  Formula 

Ammonia, 


Chlorine,  CL 


Carbon  Dioxide, 
CO2 

Sulfur  Dioxide, 

SO, 


er|c 


Common  Available  Spe'tific 
Name  Forms  Gravity 


Flammablllty  Color 


Ammonia        Liquid-Gas  0.04813  lbs/  None 

cu  ft  @  0°C 


Liquid 
Chlonne 


Dry  Ice 


Liquid-Gas  1.46b  (a>0°C  None 


Liquid-Gas  0.914 


None 


Sulfuric  Acid  Liquid-Gas  1.436  ^0°C  None 
Anhydride 


42j 


Colorless 

Greenish 
Yellow 

Colorless 

Colorless 


Odor 


Crntainers 


Irritating 
Irntating 

Odorless 


Cylinders, 
Tanks,  Trucks 

Cylinders, 
One  Ton  Units, 
Tank  Cars 

Bulk  Liquid 
Under  Pressure 


Suffocating,  Cylinders, 
Pungent      One  Ton  Units, 
Tank  Cars 


Safety  409 


location  free  of  flammable  materials.  The  storage  area  must 
be  equipped  with  forced-exhaust  ventilation  with  starting 
switches  located  c  n  the  outside  of  the  storage  room.  Ventila- 
tion must  provide  at  least  one  complete  air  change  per 
mmute.  The  temperature  of  the  storage  room  should  never 
be  permitted  to  approach  140^F  (60^C).  Protect  the  chlonne 
cylinder  from  heat  sources  and  never  use  an  open  flame  on 
cylinders  or  pipes  carrying  chlorine.  If  chlorine  is  heated,  the 
increase  in  temperature  will  cause  an  expansion  of  the  gas 
which  results  in  an  increase  in  pressure  inside  of  the 
cylinders  or  piping,  resulting  in  rupture  of  the  containers. 

When  working  with  chlorine,  be  equipped  to  control  chlo- 
nne leaks  which  are  most  often  found  in  the  control  valve. 
Repair  kits  are  available  for  the  lOO-  and  150-pound  (45  and 
68  kg)  cylinders,  as  is  emergency  equipment  for  the  one-ton 
(909  kg)  tanks  for  controll-ng  leaks.  Each  operator  must  be 
trained  in  the  use  of  theso  emergency  kits  and  must  practice 
with  the  equipment  at  least  cnce  a  year.  Always  check  out 
even  the  slightest  odor  of  chlorine;  it  may  indicate  a  leak. 
Chlorine  leaks  only  get  worse.  Small  leaks  can  grow  very 
rapidly  causing  serious  problems  that  could  have  been 
easily  solved  as  a  small  leak.  There  should  always  be  two 
operators  attending  a  chlorine  leak,  one  to  do  the  repairs 
and  the  other  to  act  as  safety  observer.  Some  repairs 
require  two  operators  to  do  the  job  (depends  on  leak  and 
repair  kit).  Once  again,  use  only  the  self-contained  breathing 
apparatus  when  repairing  a  chlorine  leak. 

When  connecting  chlorine  cylinders,  be  very  careful  with 
the  threaded  connections;  never  use  two  washers,  use  only 
one.  If  It  does  not  work  weli,  remove  the  washer  and  use 
another  one.  Do  not  reuse  an  old  or  used  washer;  always 
use  a  new  washer.  By  taking  this  precaution,  by  cleaning  the 
threads  and  washer,  and  by  being  careful  with  the  thread 
setting,  many  chlonne  leaks  will  be  prevented.  You  MUST  be 
aware  whethor  you  are  using  gas  or  liquid  when  connecting 
the  container.  On  the  one-ton  (909  kg)  tank,  the  top  valve  is 
for  gas,  the  bottom  valve  is  for  liquid.  If  liquid  chlorine  is 
allowed  into  a  gas  feed  system  it  will  cause  "freezing"^  and 
shut  down  (plug)  the  system.  Similarly,  if  liquid  gets  into  the 
gas  outlet,  it  will  cause  problems  by  "freezing."  You  must  not 
panic  in  this  situation.  Do  not  do  anything  as  foolish  as 
adding  heat  by  open  flame  or  electrical  heaters  to  clear  a 
"frozen"  (plugged)  gas  line.  Get  help  from  someone  expe- 
rienced with  chlonne  cylinders. 

Never  make  repairs  to  the  valve  or  chlonne  container.  Just 
stop  the  leak,  perhaps  by  tightening  the  packing  on  the  valve 
stem  or  placing  the  safety  device  onto  the  cylinder.  Let  the 
chlorine  supplier  repair  the  container.  Never  use  a  wranch 
longer  than  six  inches  (15  cm)  to  open  the  cylinder  valve, 
making  one  complete  turn  of  the  valve  stem  in  a  counter- 
clockwise direction.  The  one  turn  will  open  the  valve  suffi- 
ciently for  the  f.aximum  discharge.  As  a  safety  consider- 
ation, cylinders  are  equipped  with  fusible  metal  plugs  which 
are  designed  to  melt  at  1 58  to  1 68*'F  (70  to  76*^0).  This  will  al- 
low the  cylinder  contents  to  discharge  and  prevent  rupturing 
of  the  tank.  On  1 00-  to  1 50-pound  (45  to  68  kg)  cylinders,  the 
plug  IS  located  just  below  the  valve  seat.  The  one-ton  (909 
kg)  tanks  have  six  such  plugs;  three  on  each  end.  Should 
one  of  these  plugs  molt,  permitting  liquid  chlorine  to  dis- 
charge, place  the  cylinder  in  a  position  with  the  leak  at  the 
top  of  the  tank  so  that  it  permits  the  chlorine  gas  (rather  than 
the  liquid)  to  discharge.  This  action  will  reduce  the  amount  of 
chlorine  being  discharged  because  the  liquid  will  change  to  a 
gas  to  escape.  In  doing  so,  it  will  lower  the  temperature  of 
the  container,  reducing  the  discharge  rate. 

3  Liquid  chlorine  becomes  a  solid  around  -103  to 
line. 


All  employees,  Maintenance  personnel  and  operators  who 
handle  chlorine  must  have  access  to  an  approved  chlonne 
gas  mask  (Figure  20.4)  They  must  be  instructed  in  the  use 
and  maintenance  of  this  equipment.  A  monthly  program 
should  be  conducted  to  familiarize  and  train  each  user  of  the 
safety  equipment.  Those  employees  who  are  to  use  the 
chlorine  emergency  equipment  should  practice  with  this 
equipment  every  oix  months  while  wearing  a  self-contained 
breathing  apparatus.  The  emergency  kit  consists  of  clamps, 
gaskets,  drift  pins,  hammers,  wrenches,  and  other  tools 
needed  for  repairing  leaks.  The  operator  may  not  be  able  to 
practice  with  all  of  the  tools,  but  inspection  and  practice 
gives  the  operator  an  opportunity  to  do  maintenance  on  the 
emergency  equipment. 

All  operators  working  with  chlonne  should  be  familiar  with 
methods  of  detecting  chlorine  leaks.  When  testing  for  leaks, 
use  ammonia  water  on  a  small  cloth  or  swab  on  a  stick  or 
use  an  aspirator  containing  ammonia  water.  This  will  form  a 
white  cloud  of  ammonia  chlorine.  Leaks  should  be  repaired 
immediately.  Jo  not  apply  the  ammonia  swab  directly  to  the 
equipment  surface.  Also  do  not  spray  ammonia  into  a  room 
full  of  chlorine  because  a  white  cloud  will  form  and  you  won't 
be  able  to  see  anything. 

Many  plants  are  equipped  with  chlonne  gas  detectors. 
This  equipment  must  be  maintained  weekly.  If  not  properly 
maintained,  it  may  not  be  operable  when  you  need  it. 
Change  the  electrolyte  regularly,  test  the  alarm  and  keep  the 
detectors  clean  and  in  good  repair. 

Someone  must  be  assigned  the  responsibility  for  mainte- 
nance of  the  self-breathing  apparatus.  That  operator  must 
keep  records  of  the  maintenance  problems  and  of  monthly 
drills  using  the  gear.  The  a^oigned  operator  should  check 
the  masks  for  leaks,  loose  eyepieces,  faulty  tubing,  or  other 
worn  or  defective  spots.  If  inspection  indicates  any  defective 
parts,  they  should  be  discarded  or  repaired  by  a  properiy 
trained  employee.  Remember,  in  high  concentrations  of 
chlorine  within  a  confined  space  where  oxygen  can  be 
displaced,  DO  NOT  USE  THE  CANISTER  TYPE  OF  MASK. 
NO  CANISTER  CAN  PROVIDE  OXYGEN.  Therefore,  use 
only  self-contained  breathing  apparatus  or  a  hose-type 
mask  supplied  with  air  (Figure  20.5). 

If  you  are  caught  in  an  area  containing  chlorine,  do  not 
panic,  but  leave  immediately.  Do  not  breathe  or  cough,  and 
keep  your  ^  <?ad  high  until  you  are  out  of  the  affected  area. 

The  first  safety  measure  you  can  take  when  entenng  a 
chlonnation  room  is  to  make  sure  the  ventilating  system  is 
working.  The  ventilating  system  for  the  chlorination  room 
should  be  working  all  the  time.  Doors  of  chlorination  rooms 
should  have  panic  bars  as  door  openers  so  that  in  an 
emergency  you  will  not  have  to  search  for  the  door  opener. 
All  safety  equipment  should  be  located  outside  of  the 
chlonnation  room,  but  close  enough  so  you  can  find  the 
equi,3ment  when  needed. 

First  aid  for  eyes  exposed  to  liquid  chlorine  is  immediate 
irngation  with  flowing  water  for  at  least  30  minutes.  Medical 
attention  is  essential.  If  the  eyes  are  exposed  to  chlorine 
gas,  immediately  irrigate  with  flowing  water  for  a  period  of 
15  minutes.  Get  medical  aid.  If  skin  is  exposed  to  liquid 
chlorine,  it  will  most  likely  cause  burns.  The  skin  should  be 
washed  with  flowing  water  for  30  minutes.  If  the  skin  is 
burned,  get  medical  attention.  Chlorine  gas  can  becom' 
trapped  in  the  clothing  and  react  with  body  moisture  to  forn 


-  IOj'^C.  The  liquid  can  plug  a  chlorine  gas  line  which  operators  refer  to     a  "frozen" 

43J 


410  Water  Treatment 


scon  PRESUR-PAK  lla 


SPECiFICATiONS 
AIR  SUPPLY 

Rsud  Duration  at  modsraU  txtrtlon 
(MESA/NIOSH  t«ft 
procedure)  * 

Cylinder  C«P«city  at  2216  ptf 


US£  FACTORS 

Weight,  at  worn,  fully  chargad 

(appro  x») 
Donnino  Spaad  (tralnad  pmtonn^l) 

Facepiaca  (Scottoramlc  w/nota  cup) 
Cylinder  and  Valva  connection 
Cyllndar  Changa 

Harn««f  Wabbing  (raplacaabia  without 

tools  or  rivatf) 
Transport  arKi  Storaga 

SHIPPING  WEIGHT 

NOTES:  POStTlVt  PRESSURE 


BACK'PAK  STYLE 


30  min. 


45c»u  ft. 


32  Ibt. 
undar  30MCf. 

Widavlflon,  antl-fogging 
Straight  thraad,  gatkat  taal 
Haitd  ditconnact,  no  tools  raq'd 

Polypropylana 

Custom  Molded  High  Dantlty 
Polyathylena  Case 

48  lbs. 


Fig,  20.4   Chlorine  gas  ma$K 

(Permission  of  Nevada  Safety  &  Supply) 


hydrochloric  acid  which  coJd  burn  the  skin.  Remove  the 
clothing  of  the  victim  and  wash  the  body  down  with  water.  In 
case  of  inhalation,  remove  the  victim  to  fresh  air,  administer 
oxygen  if  available,  call  a  physician  or  transport  the  injured 
person  to  a  medica'  facility.  Ingestion  is  not  a  problem 
because  chlorine  is  a  gas  at  room  temperature. 

Each  operator  should  have  a  copy  of  the  Chlorine  Insti- 
tute's CHLORINE  MANUAL^  You  should  read  this  manual 
and  review  it  at  least  once  every  year.  The  manual  gives  data 
concerning  chlorine  as  an  element  and  gives  you  sugges- 
tions for  safely  handling  this  hazardous  liquid  or  ges. 

20,131  Carbon  Dioxide  (CO^) 

Water  plant  operators  are  not  often  exposed  to  carbon 
dioxide  because  of  its  limited  use,  but  it  is  hazardous  and 
can  cause  suffocation  due  to  the  lack  of  oxygen.  Therefore, 
when  using  COg  keep  in  mind  the  carbon  dioxidp  safety 
considerations  The  problem  with  carbon  dioxide  is  that  it  is 
odorless,  colorless,  and  will  accumulate  at  the  lowest  possi- 
ble level  because  it  is  heavier  than  air. 

Carbon  dioxide  is  obtained  in  bulk  lots,  as  a  liquid  under 
pressure.  This  gas  must  be  vaporized  before  using.  COg  is 
also  prepared  by  generation  on  site  In  either  case,  good 
ventilation  will  reduce  the  hazards  of  using  00^,  This  will 


co»"*'ol  the  accumulating  effects  of  the  gas.  If  you  must  go 
into  a  COg-filled  room,  use  a  self-contained  breathing  appa- 
ratus, not  a  canister  gas  mask.  Carbon  dioxide  displaces 
oxygen  and  you  may  suffocate  with  the  canister  type  of 
mask.  Exposure  to  carbon  dicxide  does  not  require  any 
protection  of  the  eyes,  skin  or  other  parts  of  the  body,  but 
take  precautions  when  entering  rooms,  low  spots,  or  man- 
holes that  may  be  filled  with  carbon  dioxide. 

First  aid  involves  moving  the  victim  to  fresh  air,  giving 
resuscitation  if  the  victim  has  stopped  breathing,  and  getting 
medical  attention. 


*  CHLORINE  MANUAL  (4th  Ec*  Jon),  The  Chlorine  Institute,  Inc.,  2001  L  Strec*t,  SW,  Washington,  DC  20036.  Price,  $10.00 


er|c 


431 


Safety  411 


Dual  m'tr  supply  cylinder  being  uMd  with  900007  Mrias 
hosclina  Atr-Pak  with  Egress. 


Typical  fixed  air  supply  installation  usiri^  **igh  pressure  air  cylinders. 
Fig.  20.5  Hose-type  mask  supplied  with  air 

(Permission  of  Nevada  Safety  &  Supply) 


412  Water  Treatment 


20.132  Sulfur  Dioxide  (SO2) 

This  gas  Is  about  2.3  times  as  heavy  as  air  and  therefore 
will  accumulate  in  low  areas.  Sulfur  dioxide  is  colorless  in 
the  gaseous  form.  As  a  liquid  it  is  also  colorless  and,  when 
unconfined.  will  vaporize  rapidly  into  a  gas.  The  gas  is 
extremely  irritating  and,  like  chlorine,  will  react  readily  with 
the  respiratory  system  if  inhaled.  Sulfur  dioxide  causes 
varying  degrees  of  Irritation  to  the  mucous  membranes  — 
eyes.  nose,  throat  and  lungs.  The  damage  is  caused  by  the 
formation  of  sulfurous  acid  in  reaction  with  moisture  in  these 
location^.  Sulfur  dioxide  can  be  readily  detected  in  concen- 
trations of  3  to  5  ppm.  In  higher  concentrations,  it  is  unlikely 
that  you  will  remain  in  the  area  unless  you  are  unconscious 
or  trapped.  If  the  liquid  comes  into  contact  with  the  skin,  it 
may  cause  local  freezing  as  the  liquid  evaporates. 

Always  use  self-contained  breathip'^  apparatus  around 
sulfur  dioxide  and  never  use  the  canister  type.  As  with  other 
gases,  good  ventilation  is  essential  in  a  roonri  where  sulfur 
dioxide  is  being  used.  The  fans  should  be  used  to  dissipate 
any  gas  vapors  that  may  occur.  There  should  always  be  an 
eye  wash  fountain  close  to  the  work  area  where  sulfur 
dioxide  is  used. 

First  aid  for  eyes  exposed  to  or  splashed  with  sulfur 
dioxide  Is  washing  immediately  with  water  for  at  least  15 
minutes,  then  getting  medical  attention.  In  case  of  inhalation, 
remove  victim  to  fresh  air,  give  resuscitation  if  needed, 
consult  a  physician  or  transport  the  injured  person  to  a 
medical  facility.  Sulfur  dioxide  leaks  and  injuries  should  be 
treated  similar  to  chlorine  problems. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  439. 

20.1 3A  Where  are  chlorine  leaks  most  often  found? 

20.1 3B  What  is  the  purpose  of  the  fusible  metal  plugs  on 
chlonne  cylinders? 

20.1 3C  How  can  chlorine  leaks  be  detected? 

20.13D  What  safety  considerations  must  be  observed 
when  using  carbon  dioxide? 

20.14  Salts 

There  are  many  salts  (chemicals)  used  in  water  treatment. 
Table  20.6  lists  the  salts  that  will  be  discussed  in  this 
section.  If  you  would  like  additional  information  about  com- 
pounds not  listed,  request  a  data  sheet  about  specific 
compounds  from  the  suppliers  of  the  chemicals.  Review  the 
chemistry  of  the  compounds  in  Table  20.6  and  become 
familiar  with  each  chemical's  characteristics.  You  should 
become  well  trained  in  how  to  handle  each  chemical  and 
know  and  observe  the  appropriate  safety  precautions.  For 
most  of  these  salts,  ventilation,  respiratory  protection  and 
eye  protection  will  prove  adequate.  Other  problems  may 
involved  chemical  solutions  and  dust.  The  solution  may 
attack  skin  and  clothing.  The  dust  may  attack  the  respiratory 
system  or  cause  an  explosion.  Even  though  these  chemicals 
do  not  normally  react  violently,  use  the  following  procedures 
when  handling  such  salts  to  reduce  the  hazards  and  to 
provide  a  safe  working  location. 


TABLE  20,6  SALTS  USED  IN  WATER  TREATMENT 


Available 


Density, 


Name,  Formula 

Common  Name 

Forms 

Lbs/Cu  Ft  Flammability 

Aluminum  Sulfate, 
AySO^ja'UHgO 

Alum.  Filter  Alum 

Liquids, 
Powder,  Lump 

1.69  (S.G.) 
38-67 

None 

Ferric  Chloride. 
FeCl3 

Ferrichlor, 
Chloride  of  Iron 

Syrup,  Liquid, 
Lump 

60-90 

None 

Fetnc  Sulfate. 
Fe2(SO,)3 

Ferrifloc.  Ferrisul 

Powder, 
Granule 

70-72 

None 

Ferrous  Sulfate. 

Coppras,  Green 
Vitriol 

Crystal, 
Granule,  Lump 

63-66 

None 

Sodium  Aluminate, 
NBgOAIgOj 

Soda  Alum 

Dry  Crystal, 
Liquid 

(27°  B6) 

None 

Fluoride  Compounds, 

NaF 

HjSIFe. 

Liquid  and 
Powder 

50-75 

None 

Sodium  Hexameta- 
phosphate,  (NaP03)g 

Calgon,  Glassy 
Phosphate 

Crystal, 
Flake 

47 

None 

Copper  Sulfate, 
CuSO^ 

Blue  Vitriol, 
Blue  Stone 

Crystal, 
Lump,  Powder 

60-90 

None 

Sodium  Chlorite, 
NaOCI 

Technical 
Sodium  Chlorite 

Powder,  Flake, 
Liquid 

70  dry 

Oxidizer 

Potassium 

Permanganate, 

KMnO^ 

Permanganate 

Crystal 

90-100 

Oxidizer 

Odor  Containers 


Ivory 


N/A 


Dark  Brown,  N/A 
Yellow-Brown 

Red-Brown  N/A 

Green  N/A 

White,  Green-  N/A 
Yellow 

Blue,  Dust 
White 

White  N/A 

Blue  None 

Light  Orange  None 

Purple  None 


Bags,  Tank 
Truck,  Bulk 

Carboys,  Tank 
Cars 

Bags,  Drums 


Bags,  Drum?. 
Bulk 

Bags,  Bulk 


Bags,  Carboys. 
Tank  Trucks 


Bags,  Drums 

Bags,  Drums 

Tank  Truck. 
100  lb.  Drums 

Drums,  Bulk 


ERIC 


433 


Safety  413 


When  handling,  stonng  or  preparing  solutions  of  chemi- 
cals, treat  them  all  as  being  hazardous.  All  chemicals  require 
careful  consideration.  They  may  be  sources  J  an  explosion, 
violent  reaction,  loss  of  eyesight,  burns  and  illness. 

Do  not  store  acid  or  oasic  compounds  with  salts.  Keep 
these  chemicals  in  e  clean,  dry  area.  When  handling  dry  bulk 
matenals,  store  in  a  fire-safe  area.  Keep  all  lids  on  contain- 
ers "^nd  follow  the  instructions  on  the  container  Make  sure 
that  the  operator  who  is  mixing  or  dispensing  these  chemi- 
cals is  well  trained  and  wears  proper  clothing  to  meet  all 
safety  requirements,  such  as  chemical  goggles,  face  shield, 
rubber  gloves,  rubber  boots,  rubber  apron  and  chemical 
respirator.  When  working  with  chemical  salts,  be  aware  that 
fumes,  gases,  vapors,  dusts  or  mists  may  be  given  off  and 
this  represents  a  hazard  to  the  safety  of  the  operator. 
PROTECT  YOURSELFf 

20.140  Aluminum  Sulfate  (alum) 

There  are  two  forms  of  alum;  dry  and  liquid.  Both  have  to 
be  handled  with  care.  Dry  alum  is  available  m  the  lump, 
ground  or  powdered  form  and  should  be  stored  in  a  dry 
location  because  moisture  can  cause  caking.  Liquid  alum  is 
acidic  and  very  corrosive.  Store  liquid  alum  in  corrosion 
resistant  storage  tanks  such  as: 

1.  Steel,  wood  (Douglas  Fir),  or  concrete-iined,  all  lined  with 
8-lb  lead. 

2.  Steel,  lined  with  3/16  mch  (5  mm)  soft  rubber, 

3.  Stainless  steel. 

4.  Steel,  lined  with  plartic  if  temperature  remains  below 
150°F  (65°C),  and 

5  Glass  reinforced  epoxy  or  polyester  plastic. 

When  working  with  dry  alum,  use  respiratory  protection 
and  ensure  adequate  ventilation  of  the  work  area.  There 
should  be  a  good  mechanical  dust-collection  system  to 
minimize  any  dust  collection. 

Exposure  to  alum  dust  greater  than  15  milligrams  per  cubic 
meter  of  air  for  more  than  an  8-hour  period  is  dangerous. 
Avoir'  skin  exposure  to  this  rhemical  by  using  long-sleeved, 
loose  fitting,  dust-proof  clothing. 

Liquid  alum  is  an  acidic  solution  and  should  be  handled  as 
you  would  handle  a  weak  acid.  Reduce  exposures  to  the 
skin  and  eyes  Avoid  ingestion.  Although  the  chemical  will 
not  cause  any  lasting  internal  damage,  it  will  be  uncomfort- 
able Use  good  ventilation  for  removing  any  mists.  Rubber 
gloves  and  protective  clothing  is  recommended. 

As  a  general  precaution,  avoid  prolonged  exposure  to  dry 
or  liquid  forms  of  alum.  If  used  dry,  a  dust  mask  and  goggles 
are  desirable  for  the  comfort  of  the  operator.  Alum  dust  can 
be  extremely  irritating  to  the  eyes.  When  handling  the  liquirJ, 
normal  precautions  should  be  used  to  prevent  splashing  of 
the  compound  onto  the  operator,  particularly  '  the  liquid  is 
hot  Wear  a  face  shield  to  protect  your  eyes  and  a  rubber 
apron  to  protect  clothing. 

ERIC  eti* 


First  aid  for  liquid  or  dry  alum  is  immediate  flushing  of  the 
eyes  for  15  minutes  with  large  amounts  of  water.  Alum 
should  also  be  washed  off  the  skin  with  water  because 
prolonged  contact  will  cause  irritation. 

20.141  Ferric  Chloride 

This  IS  a  very  corrosive  compound  and  should  be  treated 
you  would  treat  a.ny  acid.  The  salt  is  highly  soluble  *n 
water,  but  in  the  presence  of  moist  air  or  light,  -it  decom- 
poses to  give  off  hydrochloric  acid,  which  may  cause  other 
problems  regarding  safety.  Avoid  prolonged  exposure  to 
this  liquid  (there  is  a  dry  form  but  it  is  not  often  used).  When 
handling  liquid  ferric  chloride,  normal  precautions  should  be 
taken  to  prevent  splashing,  particularly  if  the  liquid  is  hot. 
Use  a  face  shield  to  protect  your  eyes  and  rubber  aprons  to 
protect  clothing.  This  compound  will  not  only  attack  the 
clothing,  but  also  stain  it.  First  aid  for  eyes  exposed  to  the 
liquid  IS  that  the  eyes  must  be  flushed  out  immediately  for  1 5 
minutes  with  large  amounts  of  water.  Ferric  chloride  should 
also  be  washed  off  the  skin  with  water  as  prolonged  contact 
will  cause  irritation  and  staining  of  the  skin. 

20.142  Ferric  Sulfate 

This  compound  produces  an  acidic  solution  when  mixed 
With  water.  Because  of  Its  acidic  nature,  operators  using  this 
compound  should  be  provided  with  protection  suitable  for 
dry  or  liquid  alum.  The  hazards  associated  with  the  use  of 
dry  ferric  sulfate  are  those  usually  connected  with  an  acid. 
Use  protective  clothing,  neck  cloths,  gloves,  goggles  or  face 
shield,  and  a  respirator.  Avoid  prolonged  exposure  to  the 
dry  form  because  of  its  acidic  reaction  with  moisture  on  the 
skin,  eyes  and  throat.  The  normal  precautions  should  be 
used  including  a  dust  mask  and  protective  clothing.  First  aid 
for  exposure  to  the  eyes  requires  the  eyes  to  be  flushed 
immediately  with  lot*^  '  water.  The  skin  should  also  be 
flushed  with  large  amounts  of  water.  Prolonged  contact  may 
cause  irritation. 

20. 143  Ferrous  Sulfate 

This  chemical  may  be  obtained  in  liquid  or  dry  form.  The 
safety  hazards  are  some  of  those  for  dry  or  liquid  forms  of 
alum  The  operator  should  be  provided  with  adequate  venti- 
lation and  respiratory  protection  The  material  should  be 
stored  in  a  clean,  dry  location.  Mechanical  dust  collecting 
equipment  must  be  used  to  minimize  the  dust.  Wear  chemi- 
cal goggles  or  a  face  shield,  loose  fitting,  long-sleeved 
clothing,  and  make  an  effort  to  minimize  all  skin  exposure. 

First  aid  for  ferrous  sulfate  in  the  eyes  is  to  flush  out 
immediately  with  large  amounts  of  water  for  1 5  minutes.  The 
chemical  should  be  washed  off  the  skin  to  reduce  irritations. 

20. 144  Sodium  Alumir)ate 

Sodium  aluminate  dissolved  in  water  produces  a  non- 
corrosive  solution.  In  the  dry  form,  its  powder  consistency 
raises  the  usual  dust  problems.  There  are  few  hazards  with 
this  compouno,  but  as  with  other  chemicals,  you  should  use 
precautions  when  handling  it.  Use  respiratory  protection 
when  handling  the  dry  compound  to  prevent  the  inhalation  of 
dust  First  aid  for  eyes  that  are  exposed  is  to  flush  with 
water;  keep  the  skin  clean  with  water. 

20.145  Fluoride  Compounds 

All  fluoride  compounds  should  De  treated  with  care  when 
you  are  handling  them  because  of  their  long  term  accumula- 
tive effects.  Provide  good  ventilation;  always  wear  respira- 
tory protection;  and  be  careful  not  to  expose  any  open  cuts. 

434 


41 4  Water  Treatment 


lesions  (wounds),  or  sores  to  fluoride  compounds  Clean  up 
any  spills  promptly  ano  wash  immediately  after  handling 
such  compounds. 

When  handling  acui  compounds  of  fluonde,  always  wear  a 
face  shield  and/or  chemical  goggles,  ruboer  gloves,  rubber 
apron  and  rubber  boots.  Your  weanng  apparel  should 
always  be  washed  after  working  around  fluoride,  and  the 
resDirator  should  be  kept  cle.in  and  sanitary  Keep  the  ac»d 
feeder  for  fluonde  in  good  repair.  Use  plastic  guards  to 
prevent  acid  spray  from  glands  or  other  parts  of  the  chemi- 
cal feeder  This  prevents  attack  upon  the  equipment  and 
protects  operators  All  fluoride  compounds  must  be  regard- 
ed as  hazardous  chemicals  that  are  toxic  to  operators.  Every 
means  possible  must  be  taken  to  prevent  exposure  to  these 
compounds  by  use  of  resp'rator  and  protective  clothing. 

First  aid  for  fluoride  compounds  is  limited,  but  the  follow- 
ing precautions  should  be  used.  For  the  eyes,  flush  immedi- 
ately with  warm  water  and  consult  a  physician.  For  external 
injuries,  wash  with  large  amounts  of  warm  water.  For 
poisoning,  the  victim  should  dnnk  a  glass  of  lime  water,  or  a 
one  percent  solution  of  calcium  chloride,  or  a  large  amount 
of  milk.  See  a  doctor 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  439. 

20  14A  What  kind  of  protection  does  an  operator  need 
when  handling  salts? 

20.14B  What  IS  the  recommended  first  aid  when  either 
liquid  or  dry  alum  comes  in  contact  with  your  skin  or 
your  eyes? 

20  14C  Whal  happens  when  ferric  chloride  is  exposed  to 
moist  air  or  light'' 

20.15  Powders 

20, 150  Potassium  Permanganate  (KMnO^) 

Under  normal  conditions  in  a  water  treatment  plant,  potas- 
sium permanganate  js  considered  to  be  a  safe  chemical. 
However,  potassium  permanganate  is  a  strong  oxidizing 
agent  and  will  react  with  certain  easily  oxidizable  sub- 
stances. Keep  potassium  permanganate  away  from  the 
possibility  of  reacting  with  sulfuric  acid,  hydrogen  peroxide, 
metallic  powders,  elemental  sulfur,  phosphorus,  carbon, 
hydrochlonc  acid,  hydrazine,  hydroxylamine,  and  metal  hy- 
drides. When  in  contact  with  potassium  permanganate,  the 
following  compounds  may  ignite:  ethylene  glycol  (anti- 
freeze), glycerine,  sawdust  compounds,  propylene  glycol, 
and  sulfuric  oxide. 

Potassium  permanganate  Is  available  either  as  pellets  or 
as  a  powder.  This  chemical  can  be  kept  indefinitely  if  stored 
in  a  cool,  dry  area  in  closed  containers.  The  drums  should  be 
protected  from  damage  that  could  cause  leakage  or  spillage 
Potassium  permanganate  should  be  stored  in  fire-resistant 
buildings,  having  concrete  floors  instead  of  wooden  floors. 
The  chemica'  must  not  be  exposed  to  intense  heat,  or  stored 
next  to  heated  pipes.  Organic  solvents,  such  as  greases  and 
oils,  should  be  kept  away  from  stored  potassium  perman- 
ganate. 

Potassium  permanganate  spills  should  be  swept  up  and 
removed  immediately.  Flushing  with  water  is  an  effective 
way  to  eliminate  spillage  on  floors.  Potassium  permangan- 
ate fires  should  be  extinguished  with  water. 

er|c 


To  avoid  inhalation  of  potassium  permanganate  dust,  use 
an  approved  mask  wh.ch  is  an  air-punfying  half-mask  respi- 
rator with  an  outblower  Safety  glasses  or  a  full  face  shield 
should  be  wom  to  protect  your  eyes.  Protective  clothing  that 
should  be  worn  includes  rubber  or  plastic  gloves  ^nd  apron, 
and  a  long-sleeved  shirt  for  handling  both  dry  and  dissolved 
potassium  permanganate. 

Mjirj  exposu*'*?  w!^!  cause  sneezing  and  mild  irritation  of  the 
mucous  membr<.nes  Prolonged  inhalation  of  potassium 
permanganate  should  be  avoided.  If  potassium  permangan- 
ate gets  on  your  skin,  flood  the  contacted  skin  with  water  If 
It  gets  in  your  eyes,  flush  with  plenty  of  water  and  call  a 
physician  immediately. 

20, 151   Powdered  Activated  Carbon 

Powdered  activated  carbon  is  the  most  dangerous  pow- 
der that  you  will  be  exposed  to  as  a  treatment  plant 
operator.  If  you  understand  how  to  handle  activated  carbon 
properly,  other  dust  problems  or  powdered  chemicals  will 
not  be  very  difficult  for  you  to  handle. 

There  are  two  problems  when  handling  activated  carbon. 
One  IS  dust  and  the  second  is  fire.  The  two  may  or  may  not 
be  related.  The  dust  causes  uncomfortable  working  condi- 
tions; fire  causes  damage  to  equipment  and  a  hazard  to 
personnel.  If  the  two  problems  are  treated  together,  it  will 
reduce  the  hazards  to  operators.  Left  unattended  they  may 
cause  loss  of  life  and  property.  If  you  will  use  the  following 
safety  precautions,  you  can  minimize  the  hazards  of  han- 
dling activated  carbon  and  aid  the  other  operators  in  han- 
dling other  powders. 

Store  activated  carbon  in  a  clean,  dry,  fireproof  location. 
Keep  free  of  dust,  protect  from  flammable  materials,  and  do 
not  permit  smoking  m  the  area  at  any  time  when  handling  or 
unloading  activated  carbon.  Install  carbon  dioxide  fire  extin- 
guishers. Store  bagged  carbon  in  single  rows.  Keep  access 
aisles  free  to  prevent  damage  to  the  bags  and  thus  reduce 
the  dust  and  fire  potential. 

Electrical  equipment  in  and  around  activated  carbon  stor- 
age should  be  explosion  proof  and  protected  from  the 
carbon  dust.  Keep  the  equipment  clean  and  dry.  Wet  or 
damp  carbon  is  a  good  conductor  of  electrical  current  and 
can  cause  short-circuit  fires  Heat  can  also  build  up  from  the 
motors  if  covered  with  carbon  dust,  causing  fires.  The  key  to 
controlling  fires  with  activated  carbon  is  keeping  the  storage 
area  clean  and  dust  free. 

Next  to  electrical  fires,  activated  carbon  gives  the  operator 
the  frost  difficult  fire  to  control.  The  carbon  gives  off  an 
intense  heat;  it  burns  without  smoke  or  visible  flame.  The 
fires  are  difficult  to  locate  and  are  very  hard  to  control.  They 
cannot  readily  be  detected  in  a  large  storage  bin  or  in  large 
stacks  of  bags. 

You  will  detect  the  indications  of  the  fire  before  seeing  any 
evidence  of  flames,  such  as  the  smell  of  charred  paper, 
burned  paint  or  other  odor. 

Do  not  douse  a  carbon  fire  with  a  stream  of  water.  The 
water  may  cause  burning  carbon  particles  to  fly,  resulting  In 
a  greater  fire  problem.  The  carbon  fire  should  be  controlled 
with  carbon  dioxide  (COg)  extinguishers  or  hoses  equipped 
with  fog  nozzles.  However,  when  using  COg,  be  aware  that 
there  is  a  potential  of  carbon  monoxide  formation  and 


435 


Safety  415 


take  the  precaution  of  using  a  self-contained  breathing 
apparatus 

Activated  carbon  supports  fire  without  atmospheric  oxy- 
gen because  it  may  have  absorbed  sufficient  oxygen  for 
combustion.  The  best  means  of  controlling  a  carbon  fire  is  to 
reduce  its  temperature  below  the  ignition  point.  This  can  be 
done  by  applying  cold  water  with  fog  or  spray  nozzles  and 
soaking  the  burning  carbon,  but  do  not  hit  the  carbon  with  a 
stream  of  water.  If  the  fire  is  small,  just  a  few  bags,  they 
should  be  ren  oved  to  a  safe  location  and  dealt  with  by  COg 
or  spray  nozzles  Blocks  of  dry  ice  can  be  used  to  control 
fires  in  storage  bins  or  other  confined  areas,  but  do  not 
expect  this  method  to  be  very  effective. 

A  final  word  about  fire  and  explosions  involving  activated 
carbon.  Tests  performed  by  carbon  manufacturers  have  not 
shown  that  dust  mixtures  of  carbon  have  explosive  tenden- 
cies. Activated  carbon  is  a  charcoal  and  performs  in  a  like 
manner,  the  carbon  burns  withOui  smoke  or  visible  flame, 
burns  very  hot,  and  will  spread  if  doused  wiih  a  large  stream 
of  water 

There  are  no  specfic  first  aid  methods  for  carbon  expo- 
sure because  the  carbon  will  not  attack  the  human  body. 
Carbon  does  sometimes  cause  problems  with  the  nasal 
passages,  however,  and  may  be  difficult  to  wash  off  your 
hands  and  body.  Therefore,  methods  h3re  are  those  of 
prevention  Provide  good  dust  collection  at  the  point  where 
carbon  is  being  unloaded,  in  storage  bins  for  liquid  prepara- 
tion, and  in  dry  storage  bin«^.  Wear  an  approved  dust  mask, 
loose  fitting  and  dust-proof  clothing.  If  there  is  an  excess  of 
dust,  you  should  use  chemical  goggles,  close  your  'ihirt 
collar  and  tape  your  trousers  to  cover  your  ankles.  Yo  i  wi!! 
need  adequate  shower  facilities  and  should  use  mild  liquid 
soap.  Most,  if  not  all,  hard  soap  bars  are  ineffective  in 
removing  activated  carbon  dust  from  pores  of  the  human 
body. 

20. 152  Other  Powders 

You  may  come  m  contact  with  other  powdered  com- 
pounds in  the  water  treatment  plant,  but  they  do  not  present 
the  problem  in  handling  that  activated  carbon  does.  Benton- 
ite  creates  no  significant  hazard  other  than  dust,  and  this 
can  be  controlled  by  using  dust  collection  systems. 

Similarly,  calcium  carbonate  presents  a  slight  dust  hazard 
that  can  be  controlled  by  a  dust  collection  system.  Also, 
whe'i  handling  calcium  carbonate  in  bags,  use  the  same 
methods  of  control  that  you  would  use  with  bags  of  caibon 

Of  thR  many  organic  coagulant  aids  used  in  water  treat- 
ment, only  a  few  are  applied  in  powder  form  Most  of  these 
compounds  are  used  in  the  liq'iid  form  which  reduces  the 
danger  in  their  use  to  operators.  The  dry  compounds  pre- 
sent a  slight  hazard  in  dust  irritation  to  the  nasal  passages, 
this  can  be  prevented  by  use  of  approved  dust  masks.  The 


liquid  coTipounds  can  and  will  attack  .f-.c  skin,  but  can  be 
treated  by  washing  with  ample  amounts  of  water  and/or 
soap  and  water  Organic  coagulant  aids  (polymers)  are 
extremely  slippery  when  wet.  Floors  and  walkways  should 
be  clean  and  dry  to  prevent  slips  and  falls. 

As  new  compounds  are  introduced  to  the  waterworks 
field,  ask  for  training  in  their  use  Such  a  training  program 
should  provide  information  about  detailed  safety  precau- 
tions, the  toxicity  of  the  compound,  and  the  appropriate  first 
aid  methods  Supervisors  have  the  responsibility  to  provide 
this  type  of  training,  either  in  conjunction  with  the  supplier  or 
sponsored  entirely  by  the  utility  The  training  must  be 
reinforced  periodically  for  those  compounds  that  are  not 
often  used  by  the  operator  A  review  and  updating  of 
information  will  go  a  long  way  in  preventing  accidents 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  439 

20  15A  How  can  potassium  permanganate  spills  be 
cleaned  up'? 

20  15B  What  is  the  most  dangerous  powder  the  water 
treatment  plant  operator  will  be  exposed  to'? 

20  150  How  should  activated  carbon  be  stored'? 

20  15D  How  can  fires  caused  by  activated  carbon  be  pre- 
vented'? 

20  15E  How  should  an  activated  carbon  fire  be  extin- 
guished'? 

20.16   Chemical  Storage  Drains 

Safety  regulations  prohibit  the  use  of  a  common  dram  and 
sump  for  acid  and  alkali  chemicals,  oxidizing  chemicals  and 
organic  chemicals  because  of  the  possibility  of  the  release 
of  toxic  gases,  explosions  and  fires  If  both  an  acid  and  an 
alkali  chemical  come  in  contact,  an  explosion  could  occur.  If 
an  organic  chemical  such  as  a  polymer  solution  comes  in 
contact  with  an  oxidizing  chemical  such  as  potassium  per- 
manganate, a  fire  could  develop  Be  sure  that  if  a  leak 
develops  from  any  chemical  container  or  storage  facility,  the 
chemical  will  not  be  able  to  reach,  mix  or  react  with  another 
chemical 

QUESTIONS 

Write  your  answers  in  a  notebook  \^d  then  compaie  your 
answers  with  those  on  page  439, 

20  1 6A  Why  should  drains  from  chemical  storage  areas  not 
use  comnon  drains  and  sumps? 

20.16B  What  co'Jid  happen  if  a  leak  from  a  polymer  storage 
container  comes  in  contact  with  potassium  perman- 
ganate'? 

end  ^  U44a%2  M  imm 

436 


416  Water  Treatment 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  JO.  SAFETY 

(Lessor  2  of  4  Lessons) 


Write  the  answers  to  these  questions  in  your  notebook 
before  continuing.  The  problem  numbenng  continues  from 
Lesson  1 

9  What  does  an  operator  need  to  know  about  chemicals 
used  In  a  water  trt  aiment  plant*? 

10.  How  can  hydrochloric  acid  be  hpndled  safely*? 

1 1   How  should  hydrochloric  acid  be  stored? 

12.  How  can  ammonia  leaks  be  detected? 

13.  What  IS  the  I'irst  aid  treatment  for  lime  burns'? 

14.  What  special  precautions  should  be  taken  when  han- 
dling and  storing  caustic  soda*? 


15.  How  should  hypochlorite  be  handled  and  stored*? 

16  What  first  aid  is  required  for  a  person  overcome  by 
carbon  dioxide? 

1 7  What  safety  hazards  may  be  causer^  by  salt  dust*? 

18  What  types  of  safety  hazards  might  an  operator  en- 
counter when  handling  alum? 

19  What  are  the  two  major  problems  encountered  when 
handling  activated  carbon*? 

20  How  can  an  operator  detect  an  activated  carbon  fire? 


ERIC 


Safety  417 


CHAPTER  20.  SAFET\ 

(Lesson  3  of  4  Lessons) 


20.2   FIRE  PROTECi  ION 

20.20  Fire  Prevention 

Fire  prever  tion  is  the  best  fire  protection  the  plant  opera- 
tor can  afford.  Fire  protection  is  just  good  housekeeping. 
The  word  "housekeeping"  best  descnbes  the  action  any 
water  plant  operator  can  take  to  protect  from  or  prevent 
fires.  This  means  a  well-kept,  neat  and  orderly  plant  repre- 
sents a  good  fire  bdfety  policy.  Fire  hazards  can  be  easily 
removed.  The  prompt  disposal  of  cartons,  crates  and  other 
packing  materials,  a  system  of  waste  paper  collection,  and 
the  removal  of  other  debris  can  greatly  reduce  fire  hazards. 
Provide  suitable  containers  for  used  wiping  cloths  and  have 
fire  extinguishers  conspicuously  located  in  hallways,  near 
work  areas  and  near  potential  fire  problem  areas.  All  of 
tnese  housekeeping  activities  are  low-cost  measures  that 
also  improve  the  appearance  of  the  plant  and  create  a  better 
work  environment. 


You  can  call  upon  the  service  of  the  local  fire  department 
for  advice  on  fire  prevention  in  and  around  the  treatment 
plant.  You  may  also  ask  the  utility  insurance  underwriter  for 
cooperation  In  your  fire  prevention  program.  All  operators 
should  be  trained  in  the  proper  use  and  maintenance  of  fire 
control  equipment.  These  simple  steps  can  reduce  fire 
losoes  to  a  minimum  and  prevent  most  fires  from  happening 
at  vary  lov  cost  to  the  utility. 

You  should  make  a  fire  analysis  of  your  plant  once  a  year 
to  determine  what  new  measures  should  be  taken  to  prevent 
fires.  As  activity  changes  occur,  there  may  be  a  need  to 
change  the  location  of  hoses  and  extinguishers  or  it  may  be 
necessary  to  add  fire  control  equipment.  Fire  and  police 
departments'  telephone  numbers  must  be  posted  in  ?  con- 
spicuous location  along  wlt^^  escape  routes.  Post  emeigen- 
cy  numbers  near  all  telephones  throughout  the  plant.  In 
hazardous  locations  the  means  of  oxit  should  be  lighted  and 
all  doors  equipped  with  "panic  bars."  As  indicated  above, 
your  best  fire  protection  or  prevention  is  good  housekeep- 
ing. 

20.21  Classification 

Fire  classifications  are  important  for  determining  the  type 
of  fire  ex*'nguisher  needed  to  control  the  fir. .  Classi.ications 
also  aid  .n  recordkeeping  and  for  comparison  with  other 
agencies.  Fires  are  claosified  as  ''A"  —  Ordinary  combusti- 
bles, '*B"  —  Flammable  liquids,  —  Electrical  equipment, 
and  "D"  —  Combustible  metals. 


A  Class  A  fires  involve  miscellaneous  combustible  materi- 
als These  include  fabrics,  paper,  wood,  dned  grass,  hay 
and  stubble. 

B.  Class  B  fires  involve  flammable  liquids  and  vapors.  This 
may  include  oils,  lacquers,  fats,  waxes,  paints,  petroleum 
products  and  gas  This  class  is  subdivided  into  two 

subclasses: 

B-2  -  are  those  fires  in  which  the  source  of  flammable 
vapors  is  substantially  in  a  single  place  such  as 
tank's,  vats,  spills  and  trenches. 

B-3  -  are  those  fires  that  are  complicated  by  a  falling 
stream.  LPG  and  other  vapor  fires  are  in  this  class. 

C  The  Class  C  fire  involves  electrical  equipment  such  as 
starters,  breakers  and  motors.  The  circuits  should  always 
be  killed  before  extinguishing  this  type  of  fire. 

D.  Class  D  fires  involve  metals  such  as  sodium,  zinc,  mag- 
nesium and  other  similar  metals.  Operators  rarely  en- 
counter this  type  of  fire. 

2';.22  Extinguishers 

There  are  many  types  of  hand-held  fire  extinguishers.  All 
are  classified  for  class  of  fires.  There  is  no  one  extinguisher 
that  IS  effective  for  all  fires,  so  it  is  important  that  you 
understand  the  clas.s  of  fire  you  are  trying  to  control.  You 
must  be  trained  in  ...a  use  of  the  different  types  of  extin- 
guishers, and  the  proper  types  should  be  located  near  the 
area  where  that  class  of  fire  may  ocour. 

A.  There  are  four  types  of  water  extinguishers:  stored 
pressure,  cartridge  operated,  water  pump  tank,  and 
soda-acid.  All  of  mese  perform  well  in  Class  A  fires,  but 
they  do  require  maintenance.  A  preventive  maintenance 
schedule  on  all  water  extinguishers  should  include  a 
monthly  check  by  the  operator  responsible  for  the  riain- 
tenance  and  completion  of  appropriate  maintenance  rec- 
ords. Some  agencies  make  the  safety  officer  responsi- 
ble for  ensuring  t*iat  an  ope.ator  checks  the  fire 
extinguishers. 

1.  The  method  of  operation  for  a  stored  p»'essure  extin- 
guisher IS  simply  to  squeeze  the  handle  or  turn  a  valve. 
The  maintenance  is  also  simpie:  check  air  pressure, 
record  and  recharge  the  extinguisher  as  needed. 

2.  For  the  cartridge  type,  the  maintenance  consists  of 
weighing  the  gas  cartndge  and  adding  water  as  re- 
quired. To  operate,  turn  upside  down  and  bump. 

3  To  use  the  water  pump  tank  type  of  extinguisher, 
simply  operate  the  pump  handle.  For  maintenance, 
one  has  only  to  discharge  the  contents  and  refill  with 
water  annually  or  as  needed. 

4.  The  soda-.'  td  type  r  jst  be  turned  upside  down  to 
operate;  it  also  requires  annual  recharging. 

B.  The  foam  type  of  extinguishers  will  control  Class  A  and 
Class  B  fires  well.  They,  like  soda-acid,  operate  by 
turning  upside  down  and  require  annual  recharging. 

The  foam  and  water  type  extinguishers  should  not  be 
used  for  fires  involving  electrical  equipment.  However, 

4S8 


418  Water  Treatment 


they  can  be  used  in  controlling  flammable  liquids  such  as 
gasoline,  oil.  paints,  grease  and  other  Class  B  fires. 

C  The  carbon  dioxide  (CO^)  extinguishers  are  common 
(Figures  20.6  and  20.7).  They  are  easy  to  operate,  just 
pull  the  pin  and  squeeze  the  lever  For  maintenance,  they 
must  be  weighed  at  least  semi-annually.  Many  of  these 
extinguishers  will  discharge  with  age.  They  can  be  used 
on  a  Class  C  (electrical)  fire.  All  electrical  circuits  should 
be  killed.  If  possible,  before  trying  to  control  this  type  of 
fire.  A  carbon  dioxide  extinguisher  is  also  satisfactory  for 
Class  B  fires,  such  as  gasoline,  oil  and  paint,  and  may  be 
used  on  surface  fires  of  the  Class  A  type. 

D.  There  are  two  types  of  dry  chemical  extinguishers.  These 
extinguishers  are  either  (1)  cartrMqe  operated  or  (2) 
stored  pressure.  These  are  recom.nended  for  Class  B 
and  C  fires  and  may  work  on  small  surface  Class  A  fires 

1 .  The  cartridge-operated  extinguishers  only  require  you 
to  rupture  the  cartridge,  usually  by  squeezing  the 
lever  The  maintenance  is  a  bit  more  difficult,  requiring 
weighing  of  the  gas  cartridge  and  checking  the  condi- 
tion of  the  dry  chemical. 

2  For  the  stored-pressure  extinguishers,  the  operation 
IS  the  same  as  the  CO^  extinguisher.  Just  pull  the  pin 
and  squeeze  the  lever.  The  inte nance  requires  a 
check  of  the  pressure  gages  arid  condition  of  the  dry 
chemical 

As  suggested  above,  a  preventive  maintenance  program 
for  fire  extinguishers  requires  a  considerable  amount  of  time 
from  the  operator  and  requires  a  system  of  recordkeeping 


You  might  consider  hiring  a  local  fire  prevention  agency  to 
perform  this  part  of  your  maintenance  piogram.  These 
service  agencies  will  check  and  maintain  the  plant's  fire 
fighting  equipment  on  a  regular  basis.  This  does  not  relieve 
the  operator  of  ultimate  responsibility  for  the  equipment,  but 
assures  that  the  equipment  is  in  proper  working  order  when 
needed 


20.23   Fire  Hoses 


Fire  hoses  are  usually  stationed  throughout  the  treatment 
and  pumping  plants.  These  are  the  type  of  fire  fighting 
equipment  that  an  operator  may  see  every  day,  but  never 
give  due  consideration  to  their  maintenance.  Without  proper 
maintenance,  the  hoses  may  develop  dry  rot  and  be  un- 
trustworthy at  the  time  they  are  needed.  Under  some  condi- 
tions, you  may  be  tempted  to  use  these  hoses  for  cleaning 
settling  basins  or  filters.  The  fire  hoses  should  only  be  used 
for  fighting  fires,  and  after  their  use,  they  must  be  cleaned 
and  stored  properly  The  hose  should  be  tested  periodically 
and  replaced  as  required,  or  at  regular  time  intervals.  Check 
with  the  local  fire  department  for  recommendations. 


[SPECIFICATIONS 


322 


CARBON  DIOXIDE 


Size/Type 

5 

Horn 

;  10 
!  Hose 

i 
1 

15 
Hose 

20 
Hose 

Model  Number 

'"'322 

331 

33"2 

U/L  Rating 

SBC 

10BC 

10BC 

10BC 

Capacity  (lbs ) 
Shipping  V\t  i^bs ) 

~5 

15  ' 

To' 

]     29' r 

15 

39T2 

i     51 V2 

Height 

V' 

30" 

^-     -   J 

30" 

'vVWfh' 

\2" 

12' 

Depth  (Diam)  ~ 

7" 

Range  {Ft ) 

"  ~  3-8 

3-8 

3-8  ~j 

Discharge  Time- 
Seconds 

10 

10 

12  5 

19 

Coast  Guard  App    ;  Yes 

[  Yes 

-I— 

i 

Yes 

"  Yes 

<S>  Approved 
Bracket 

Yes 

~j  Yes 
\  vvair  ' 

Yes 

Ves™" 
V^^ll  ' 

tg.  20.6  Carbon  dioxide  extinguishers 

(Permssion  of  Nevada  Safety  &  Supply) 


Er|c  439 


Safety  419 


442  425  41 7T  424  419  441  423 


SPECtFtCATlONS 

ABC 

Size/Type 

No22le 

5 

Noz2le 

Nozzle 

Hose 

10  Short 
Hose 

10  Tall 

Hose 

20  " 
Hose 

Model  Number 

417T 

425 

442 

424 

419 

441" 

^"423" 

U/L  Rating 

1A:10 
B:C 

2"a:To 
B.C 

3A.4d' 
B.C 

"2A:T6" 
B:C 

1a.60 
B:C 

^A:60' 
B:C 

20A.'l2b 
B.C 

Capacity  (ibs.) 

2V2 

5 

6 

5 

10 

10 

20 

Ship.  Wt.  (lbs.) 

5V2 

\\ 

10^/2 

19V2 

18 

46~_ 

Height 

14"%" 

14%" 

17" 

20  V2"" 

"24  " 

Width 

3%" 

8" 

9'/^j" 

9" 

10" 

Depth  (Dtam.) 

3" 

~4  y4 

5" 

4V4" 

6" 

5" 

7" 

----- 

Range  (Ft.) 

9-T5' 

"12T8^ 

""12-18 

12-78" 

15-21 

15-21 

D.scharge  Time- 
Seconds 

10 

10 

14 

10 

17 

17 

30 

Coast  Guard  Ap. 

~~Yes  ~  ^ 

~~Yes 

Yes 

Yes 

Yes 

^Ye~ 

<3>  Approved 

YeT 

Yes  ' 

Pend.ng 

Yes 

Yes 

Yes 

Yes 

Bracket 

Veh/Mar 

^Wafl ' 

Wall 

Wail 

Wail 

Wall 

Wall 

f\Q.  20.7  Typical  carbon  dioxide  extinguishers 

(Permission  of  tJevada  Safety  &  Supply) 


20.24  Flammable  Storage 

The  storage  of  flammable  material  should  be  isolated,  if 
possible,  from  other  plant  structures  Ideally,  these  storage 
areas  should  have  explosion-proof  lighting.  The  floor  should 
be  grounded  and  the  operator  should  only  use  sparkproof 
tools  when  working  near  or  handling  flammable  materials. 
The  room  should  have  an  alarm  system,  be  equipped  with 
automatic  extinguishers  and  have  supplementary  equipment 
located  outside  of  the  room.  In  and  around  the  storage  area, 
smoking  or  welding  must  be  prohibited.  The  flammable 
storage  areas  must  be  cleaily  marked  with  distinctive  signs 
and  all  entrances  should  be  lighted. 

More  often  than  not,  however,  you  will  be  compelled  to 
use  rooms  within  the  plant  for  storage  of  flammable  material 
Here  you  must  make  the  room  fireproof,  equip  the  room  with 
a  fire  door,  automatic  extinguishers  and  alarms.  Keep  pas- 
sageways free  from  obstructions.  Station  fire-fighting  equip- 
ment at  a  suitable  location,  readily  accessible  and  with 


plainly  labeled  operating  instructions  The  room  must  be 
equipped  with  explosion-proof  lights,  grounded  floor,  no 
smoking  permitted,  and  distinctive  signs  indicating  that  this 
room  IS  a  flammable  storage  area. 

20.25  Exits 

Access  and  "^xit  are  very  important  in  plant  safety  There- 
fore, all  exit  jns  should  be  distinctly  marked  and  well 
lighted  All  doors  should  open  outward  and,  in  hazardous 
areas,  there  should  be  "panic  bars"  on  the  doors  To  provide 
positive  protection  around  the  filter  and  sedimentation  ba- 
sins, install  hand  rails  or  other  enclosures  for  the  protection 
o'  operating  personnel  as  well  as  visitors. 

In  hioh-fire-hazard  occupied  areas,  there  should  be  at 
least  two  means  of  emfgency  exit  located,  if  possible,  at 
opposite  ends  of  the  room  or  building.  These  would  include 
areas  containing  woodworking  and  paint  spraying  residues 
that  burn  rapidly  or  give  off  poisonous  fumes. 

440 


420  Water  Treatment 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  439. 

20  2A  Class  A  fires  involve  what  types  of  materials'? 

20.2B  What  kinds  of  fires  can  be  controlled  by  a  foam  type 
of  extinguisher'? 

20.2C  How  can  an  electrical  fire  be  extinguished'? 

20.3   PLANT  MAINTENANCE 

20.30  Maintenance  Hazards 

Plant  maintenance,  housekeeping,  cleaning  up,  or  what- 
ever you  wish  to  call  it,  is  a  very  important  function  of  the 
treatment  plant  and  essential  for  plant  equipment.  This 
function  requires  the  use  of  cleaning  materials  and  hand 
tools  Maintenance  may  require  you  to  go  into  a  manhole, 
•-epair  electncal  motors,  lift  boxes  and  use  power  tools.  All  of 
these  functions  may  in  some  way  be  hazardous,  and  if  not 
given  proper  consideration,  may  cause  injury,  fire,  disease 
or  even  death. 


20.32  Painting 

There  are  a  number  of  considerations  when  painting  in  a 
treatment  plant.  First,  is  the  paint  exposed  to  the  drinking 
water  being  treated  and  are  there  toxic  compounds  in  the 
painf?  Next,  is  the  paint  being  applied  by  brush  or  spray?  In 
either  case,  is  there  sufficient  ventilation  if  the  operator  is 
painting  indoors  or  in  a  closed  area'? 

When  working  with  toxic  paints,  for  example,  those  con- 
taining lead,  zinc,  or  organics,  be  sure  to  clean  your  hands 
before  eating  or  handling  food.  Also,  avoid  exposing  your 
skin  to  solvents  and  thinners  and  try  not  to  use  compounds 
such  as  carbon  tetrachloride.  When  spiiy  painting,  always 
use  a  respirator  to  avoid  inhaling  fumes.  Do  not  allow 
smoking  or  open  flames  of  any  kind  around  areas  being 
painted.  Also,  when  painting  or  cleaning  the  spraying  equip- 
ment, avoid  closed  containers  where  heat  is  involved.  At  a 
certain  temperature  called  the  flash  point,  spray  or  vapors 
could  ignite  and  burn  the  operator  or  start  fires.  Always 
clean  the  spray  equipment  In  an  area  having  sufficient 
ventilation  If  the  painting  operation  Is  taking  place  in  a  paint 
booth,  use  only  explosion-proof  lighting  and  permit  no  open 
flame  and  no  electric  switch  that  may  cause  a  spark. 


20.31  Cleaning 

Any  effort  spent  keeping  the  entire  plant  clean  and  sani- 
tary will  provide  a  much  nicer  place  for  you  to  work  and  will 
also  make  visitors  feel  as  if  the  water  being  produced  is 
safe.  Even  if  you  car  just  keep  all  working  areas  free  of 
tnpping  hazards,  thr  .v^ill  add  greatly  to  the  safety  in  the 
plant 

Cleaning  duties  should  be  performed  at  such  times  of  day 
or  night  as  to  cause  a  minimum  of  exposure  to  other 
operators.  For  example,  floors  become  slippery  when  wet 
so  give  some  consideration  to  the  time  of  day  and  the  type  of 
wax  to  be  used.  When  cleaning  floors,  there  are  problems  of 
exposure  to  others  of  cleaning  equipment,  mops,  mop  and 
broom  handles,  other  tools,  cleaning  compounds,  and  most 
of  all,  wet  floors.  When  cleaning,  try  to  keep  others  out  of  the 
area  Warn  others  about  newly  waxed  floors.  Use  wax 
compounds  containing  nonslip  Ingredients.  Try  to  do  such 
cleaning  and  waxing  during  off-duty  hours,  weekends  or  at 
night. 

As  part  of  >jur  maintenance  program,  prOvjde  trash 
containers  for  collecting  waste  paper  and  for  separating 
used,  oily  rags.  Dispose  of  garbage  and  flammable  refuse 
on  a  routine,  frequent  basis.  Hazardous  waste,  acids  and 
caustics  should  be  cleaned  up  immediately.  These  steps  will 
add  to  the  safety  in  the  plant  and  to  the  safety  of  operators  in 
the  plant. 

Keeping  aisles,  doorways,  stairs  and  work  areas  free  of 
refuse  reduces  hazards  of  tripping  and  other  injuries,  as  well 
as  reducing  the  possibility  of  fires. 

Cleaning  windows  is  a  hazardous  occupation,  but  the 
operator  who  gives  due  consideration  to  the  task  can 
perform  it  safely.  If  windows  are  high,  time  of  day  is 
important.  Cleaning  tools  may  be  dropped  and  fall  on 
pedestrians  or  vehicles.  There  may  be  a  need  for  safety 
harnesses;  check  the  harness  each  time  it  Is  used.  Make 
sure  all  parts  of  the  harness  are  in  good  working  condition. 
Cleaning  compounds  that  are  acid  or  alkaline  may  attack  the 
harness  or  the  safety  rope.  Also,  such  compounds  may 
attack  human  skin:  therefore,  use  rubber  gloves  when 
appropriate. 


hiiiinniimrfTnaaia 


Some  of  the  other  hazards  when  painting  include  scaffold- 
ing, rags  and  threats  to  your  personal  health.  Be  very  careful 
when  using  scaffolding  and  ladders.  The  scaffolding  must  be 
in  good  repair  and  conform  to  current  safety  regulations. 
Ladders  must  also  be  in  good  repair.  If  they  are  broken  or 
badly  worn,  they  should  be  replaced  with  new  ones. 

Rags  are  always  a  problem  If  they  contain  oils,  paint  or 
other  cleaning  compounds;  there  is  always  the  possibility  of 
fire.  The  rags  should  be  placed  into  a  closed  netal  container 
to  reduce  the  fire  hazard. 

As  to  personal  protection,  consider  using  creams  to  help 
reduce  skin  exposure  to  paint  and  solvents.  Always  <'se  an 
approved  respirator  to  reduce  inhalation  of  fumes  and  paint 
♦s.  As  a  final  note,  avoid  any  unnecessary  exposure  to 
.  or  solvents  to  the  skin. 

20.33  Cranes 

Overhead  traveling  cranes  require  safety  considerations. 
First,  only  authorized  personnel  should  be  allowed  to  oper- 
ate them.  Inspections  should  be  made  to  check  out  the 
circuit  breaker,  limit  switches,  the  condition  of  the  hook,  the 
wire  rope  and  other  safety  devices.  The  load  limits  should  be 
posted  on  the  crane  and  you  should  never  overload  the  unit. 
Always  check  out  each  lift  for  proper  balance.  U«8  only  a 
standard  set  of  hand  signals,  and  make  sure  that  each 
operator  involved  with  the  crane  knows  all  of  the  signals. 
Personnel  In  and  around  an  overhead  crane  should  be 
required  to  wear  hard  hats.  When  making  repairs  to  the 
crane  lock  out  the  main  power  switch  and  allow  only 
authorized  personnel  to  make  repairs. 

441 


Safety  421 


Never  move  loads  over  areas  where  operators  or  other 
people  a'^e  working.  Do  not  let  the  load  remain  over  the 
heads  of  operators  or  other  workers  or  allow  them  to  work 
under  loaded  cranes.  If  loads  must  be  moved  over  populated 
areas,  give  a  warning  signal  and  make  sure  everyone  is  in  a 
safe  location.  Set  up  monthly  safety  inspection  forms  to  be 
filled  out  and  placed  into  the  maintenance  file.  The  plant 
supervisor  should  review  the  forms  and  authorize  any 
maintenance  necessary  on  the  crane  in  addition  to  following 
a  good  preventive  maintenance  program. 

20*34  Manholes 

There  are  mr'^y  hazards  involved  with  manholes  and  all  of 
them  can  cause  injury  to  the  operator.  Just  removing  the 
manhole  cover  can  cause  the  loss  of  hands  or  fingers.  You 
should  never  remove  the  manhole  cover  with  your  hands. 
Use  a  manhole  hook  or  special  tool  such  as  a  pick  with  a 
bent  point  to  remove  the  lid.  Be  very  careful  when  lifting  the 
lid.  Use  your  legs,  not  your  back  for  lifting.  This  will  help 
prevent  back  strains.  Locate  the  cov  tslde  the  working 
area  to  provide  adequate  working  area  jnd  the  manhole 
opening. 

Next  IS  the  problem  of  traffic  around  an  open  manhole. 
The  public,  other  operators  and  vehicles  must  be  protected. 
Therefore,  barncades,  warning  devices  and  lights  must 
conform  to  local  and  state  regulations.  There  also  should  be 
a  barricade  around  the  manhole  to  protect  the  operators.  All 
personnel  around  manholes  should  wear  hard  hats  for  their 
safety. 

Always  inspect  the  ladder  rungs  in  the  manhole  before 
using  them.  They  may  become  loose  or  corroded  and 
therefore  should  be  tested,  using  your  own  weight.  One 
should  never  enter  a  manhole  i-Ione;  there  should  be  at  least 
one  other  person  standing  by  at  the  top  and  at  least  one  or 
more  people  within  hearing  distance  in  case  of  injury. 

Perhaps  the  greatest  threats  to  operators  working  in 
manholes  are  air  contamination  or  depletion  of  oxygen. 
Many  operators  have  lost  their  lives  because  of  leaking  gas 
mams,  decaying  vegetation  or  other  gases.  Never  enter  a 
manhole  without  checking  the  atmosphere  for  (1)  sufficient 
oxygen,  (2)  presence  of  toxic  gases  (hydrogen  sulfide),  or  (3) 
explosive  conditions  (methane  or  natural  gas).  In  any  event, 
always  provide  adequate  ventilation.  This  will  remove  any 
hazardous  gases.  To  check  the  safety  of  the  atmosphere  In 
a  manhole,  use  a  gas-detection  Instrument  (Figure  20.8). 
These  devices  can  detect  explosive  gases,  oxygen  deficien- 
cy, and/or  toxic  conditions.  Remember,  just  because  there 
are  no  toxic  or  explosive  gases  present  does  not  mean  that 
you  may  not  lose  your  life  because  of  a  deficiency  of  oxygen. 
Normal  air  contains  about  21  percent  oxygen.  The  first 
effects  of  insufficient  oxygen  occur  when  the  oxygen  con- 
tent drops  to  about  15  percent.  Operators  who  work  around 


rr.dnholes  should  be  trained  in  applying  artificial  respiration 
(C.P.R ). 

Smoking  should  nc  be  permitted  in  or  around  man- 
holes. Always  use  a  mechanical  lifting  aid  (rope  and  bucket) 
for  raisi.ng  oi  lowenng  tools  and  equipment  in  and  out  of  a 
manholo  The  use  of  a  bucket  or  bJ»<- ket  will  keep  your  hands 
free  when  climbing  down  into  or  out  of  the  manhole 


To  review  the  hazards  of  underground  structures,  remem- 
ber to  give  consideration  to  proper  tools  for  opening  and 
closing  the  manhole.  Keep  in  mind  the  need  for  barricades 
and  lights  to  warn  traffic  and  to  prevent  endangering  other 
operators.  Be  sure  that  operators  are  trained  in  artificial 
respiration  methods  and  in  the  way  to  test  the  manhole  for 
oxygen,  explosive  and  toxic  gases. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  439. 

20.3A  What  safety  precautions  should  be  taken  when  wax- 
ing floors? 

20.3B  How  should  rags  containing  oils,  paint  or  other 
cleaning  compounds  be  stored? 

20. 3C  What  safety  precautions  should  be  exercised  when 
operating  an  overhead  crane? 

20  3D  How  can  traffic  be  warned  that  operators  are  work- 
ing in  a  manhole? 

20.3E  How  should  tools  and  equipment  be  lowered  into  and 
removed  from  manholes? 

20.35  Power  Tools 

The  two  general  classes  of  portable  power  tools  are  (1) 
pneumatic  md  (2)  electrical.  Safety  precautions  for  handling 
these  types  of  tools  are  much  the  same  for  both  types.  Wear 
eye  and  ear  protection  when  operating  gnndlng.  chipping, 
buffing,  or  pavement  breaking  equipment.  Sometimes  when 
using  grinding  or  buffing  tools  you  will  encounter  toxic 
materials  and,  therefore,  will  need  respiratory  protection.  At 


422  Water  Treatment 


other  trmes  there  is  a  need  for  full  face  protection  because  of 
fiying  particles:  you  should  use  a  face  shield  or  at  least 
goggles  In  the  use  of  electrical  loots,  always  replace  worn 
out  extension  core*  and  never  expose  cords  to  oils  or 
chemicals  Extension  cords  also  present  a  tripping  haz^ird  if 
left  in  the  way  Avoid  leaving  extension  cords  in  aisles  o»  in 
work  areas  Do  not  hang  extension  cords  over  sharp  edges 
which  could  cut  the  cord  and  always  store  the  cords  in  a 
clean,  dry  location  When  working  m  a  wet  or  damp  location, 
some  consideration  should  be  given  to  the  use  of  rubber 
mats  or  insulated  platforms.  As  indicated  above,  use  only 
grounded  tools.  When  using  pneumatic  tools,  never  use  the 
compressed  air  to  clean  off  your  clothing  or  parts  of  your 
body  Air  can  enter  your  tissues  or  other  openings  and 
cause  problems  Always  check  hose  clamps.  If  they  are 
loose  or  worn,  tighten  or  replace  as  needed.  Air  hoses,  like 
extension  cords,  are  a  tripping  hazard.  Therefore,  consider 
tneir  location  when  working  with  pneumatic  tools  For  the 
large  (3/4  inch  or  18  mm)  hoses,  always  use  an  approved 
safety-type  hose  connection  with  a  short  safety  chain  or 
-ither  safety  device  attached.  Air  hoses  that  come  apart  can 
cause  injuries  as  they  are  whipping  about.  Like  electrical 
cords,  krep  air  hoses  away  from  oils,  chemicals  or  sharp 
objects. 

Sandblasting,  using  a  pneumatic  tool,  requires  some 
special  consideration.  The  operator  should  protect  all  skin 
surfaces  with  protective  clothing,  wear  eye  and  face  protec- 
tion, use  a  respirator,  and  be  very  careful  of  toxic  fumes 
which  are  discharged  from  a  blasting  operation 

The  grinding  wheel,  pneumatic  or  electric,  requires  the 
same  safety  considerations.  Eye  and  face  protection  is 
required.  Do  not  use  this  tool  without  safety  guards  Be 
careful  of  gloves  being  caught  on  the  grinding  wheei.  Never 
operate  a  wheel  with  loose  nuts  on  its  spindle.  When  the 
grinding  wheel  is  badly  worn,  replace  it  and  use  the  proper 
wheel  and  speed  of  rotation. 

All  persons  using  power  tools  must  be  trained  in  their  use 
and  maintenance.  Use  the  manufacturers  operations  and 
maintenance  guide  for  details  of  proper  training.  Most 
injuries  by  power  tools  are  caused  by  incorrect  setup  and 
operation  due  to  poor  training. 

Finally,  a  high  level  of  noise  is  frequently  encountered 
When  operating  power  tools.  For  example,  air  drills  produce 
95  dB^  and  circular  saws  1^5  jb.  Ear  protection  must  be 
provided  when  exposed  t-^  long  periods  of  high  levels  of 
noise.  In  areas  of  noise  exposure,  all  operators  should  be 
provided  with  approved  ear  protective  devices. 

20.36  welding 

The  first  safety  rule  in  operation  of  gas  or  electric  welding 
equipment  is  that  the  operator  be  thoroughly  trained  in  the 
correct  operating  procedures.  The  second  rule  concerns  fire 
protection.  The  third  rule  is  personnel  protection.  None  of 
these  rules  is  first  or  last  —  they  should  ALL  be  followed. 

If  you  are  not  thoroughly  trained  in  the  use  of  the  welding 
equipment,  do  not  use  it.  If  you  absolutely  must  use  the 
equipment,  do  so  only  under  the  supervision  of  a  trained 
welder.  Whenever  such  work  must  be  performed  in  or 
around  a  water  treatment  plant,  take  time  to  consider  the  fire 
problem.  For  example,  welding  can  be  very  dangerous  in  an 
oxidizing  chemical  location,  near  powdered  activated  carbon 


storage,  and  in  storage  areas  for  other  bagged  chemicals. 
Avoid  welding  around  oil  and  grease  when  possible,  and 
when  that's  not  possible,  at  least  provide  for  ventilation  of 
fumes.  When  welding  or  cutting  is  done  in  the  vicinity  of  any 
combustible  material,  you  must  take  special  precautions  to 
prevent  sparks  or  slag  from  reaching  the  combustible  mate- 
rial and  causing  a  fire 

Regarding  the  safety  of  other  personnel  in  the  welding 
area,  eye  protection  comes  first  The  person  using  the 
welding  equipment  must  wear  protecti'3  clothing,  gloves, 
helmets  and  goggles  Others  in  and  around  the  welding 
operation  should  be  kept  at  a  safe  distance.  Always  be 
careful  of  overhead  welding  because  of  falling  sparks  and 
slag  If  other  operators  are  (or  itiust  be)  working  in  the 
vicinity  of  the  welding  operation,  they  too  must  be  pr  *ected 
from  the  rays  of  arc  welding,  never  look  at  the  welding 
operation  without  eye  protection. 

The  storage  of  welding  gas  cylinders  should  be  given  the 
same  consideration  as  those  of  other  gases  in  water  treat- 
ment. They  are  stored  upright,  kept  out  of  radiation  of  heat 
and  sunlight  and  stored  with  protective  covers  in  place  when 
not  in  use.  Store  cylinders  away  from  elevators  and  stairs, 
and  secure  them  with  a  chain  or  other  suitable  device. 

20,37  Safety  Valves 

There  are  quite  a  number  of  safety  valves  in  a  water 
treatment  plant,  operators  are  not  always  aware  of  their 
locations  or  functions  For  example,  most  operators  know  of 
the  safety  plugs  on  chlorine  cylinders,  but  the''e  are  also 
large  safety  valves  in  any  plant  that  stores  large  amounts  of 
chlorine  on  site.  These  containers  take  on  truck  load  lots  of 
17  tons  (15.540  kilograms).  The  safety  valves  on  such 
containers  should  be  certified  at  least  every  two  years  or  as 
often  as  the  state  requires.  Such  relief  valves  must  be 
maintained  on  a  regular  basis.  Inspect  the  inside  of  these 
tanks  at  regular  time  intervals  and  keep  a  record  of  the 
findings,  for  example,  evidence  of  deposits  and  corrosion. 

Water  heater  safety  valves  should  be  checked  on  an 
annual  basis  end  maintained  or  replaced  as  needed.  If  the 
plant  has  a  boiler  room,  the  steam  safety  valve  should  be 
maintained  and  checked  for  proper  operating  pressures. 
These  valves  should  not  discharge  in  such  a  manner  as  to 
be  a  hazard  to  operating  personnel. 

There  also  may  be  surge  relief  valves  on  discharge  piping 
(high  lift)  of  the  treatment  plant.  These  valves  also  act  as  a 
safety  valve  to  the  pumping  equipment  and  must  be  main- 
tained on  some  regular  time  Interval.  Tney  should  be 
checked  for  proper  pressure  setting,  with  a"  pilot  valves 
being  reconditioned  or  replaced  as  needed. 

There  may  be  other  safety  valve  located  in  ihe  pumping 
plant's  hydraulic  system  for  opening  and  closing  discharge 
valves  that  require  maintenance.  In  the  maintenance  of 
water  treatment  plants,  you  or  your  supervisor  must  set  up  a 
maintenance  system  for  all  equipment.  Hand  tools,  power 
tools  and  other  maintenance  equipment  must  also  be  kept  m 
safe  working  condition.  Operators  must  be  furnished  protec- 
tion for  the  eyes,  the  ears,  the  hands,  the  head,  feet  and  at 
other  times,  the  body.  Work  areas  should  be  well  ventilated 
and  noise  should  be  reduced  whenever  possible.  Each 
operator  should  always  be  on  the  lookout  for  additional 
ways  of  making  the  treatment  plant  a  safer  place  to  work. 


5  Decibel  (dB)  (DES-uh-buH)   A  unit  for  expressing  the  relative  intensity  of  sounds  on  a  scale  from  zaro  for  the  average  least  perceptible 
sound  to  about  130  for  the  average  level  at  v\/hich  sound  causes  pam  to  humans,  T 


Safety  423 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  440 

20  3F  What  type  of  protection  do  operacors  need  when 
operating  portable  power  tools'^ 

20.3G  How  can  operators  be  protected  from  high  noise 
levels  when  operating  air  dnils  and  circular  saws'? 

20  3H  What  personal  protection  should  be  used  when  oper- 
ating welding  equipment? 

20.4   VEHICLE  MAINTENANCE  AND  OPERATION 


20.40  Types  of  Vehicles 

Many  types  of  vehicles  are  used  in  the  waterworks 
industry.  However,  the  plant  operator  may  only  come  into 
contact  with  a  few.  Cars,  pickup  tiucks,  forklifts,  dump 
trucks  and  some  electrically  driven  cars  are  the  types  of 
vehicles  "  ^  operator  is  most  likely  to  be  involved  with  and 
need  to  n..  .<tain.  In  addition  to  motor  vehicle  safety,  this 
section  will  also  consider  the  storage  of  fuel  for  these  and 
other  engines  in  the  plant. 

20.41  Maintenance 

To  have  a  safe  motor  vehicle,  there  must  be  a  preventive 
maintenance  program.  Figure  20.9  gives  a  checklist  for 
finding  potential  safety  problems  and  a  means  of  recording 
the  preventive  maintenance. 

Tire  inflation  is  a  good  example  of  proper  safety  checks 
Not  only  is  it  unsafe  to  operate  on  under  inflated  tires,  but  it 
also  causes  undue  wear  on  the  tire.  Therefore,  tires  should 
be  checked  regularly  for  wear,  which  ,Tiay  be  caused  by 
misalignment  or  low  inflation.  If  tires  are  badly  worn,  they 
should  be  replaced.  '^Iways  maintain  the  recommended 
pressure  in  the  tirb^.  when  checking,  set  the  hand  brake  and 
turn  off  the  motor. 


Next,  when  changing  tires,  be  sure  the  jack  you  are  using 
has  sure  footing  Position  the  jack  at  nght  angles  to  the 
direction  of  the  lift  Jacko  are  a  problem  m  general,  and  you 
should  make  sure  that  proper  jacks  are  in  each  vehicle.  In 
other  words,  select  the  proper  jack  for  each  job  and  choose 
only  one  that  is  safe  and  strong  enough.  If  blocking  is 
required,  only  use  safe  supports,  avo:d  leaning  the  jack  and 
protect  hands  Always  stay  a  safe  distance  from  the  jack 
handle  as  many  injunes  are  caused  by  flying  jack  handles. 
Also,  injunes  are  caused  by  overloading  jacks.  In  addition, 
where  needed,  use  braces  or  other  supports  to  prevent 
tipping  the  vehicle  over,  another  cause  of  serious  injuries. 

Fueling  motor  vehicles  also  involves  some  hazards.  V- 
ways  stop  the  vehicle's  engine.  Remember  to  remove  the 
fuel  hose  immediately  after  using  it.  You  could  start  a  fire  if 
you  carelessly  drive  off  with  the  hose  still  attached.  Also, 
rake  sure  the  cap  is  replaced  tightly  on  the  tank.  Do  not 
permit  smoking  m  the  vicinity  of  gas  delivery  pumps  at 
anytime.  Avoid  any  sparks,  and  skin  contact.  Use  only  high- 
flash  point  solvent  for  cleaning  up  any  gasoline.  Some  other 
safety  tips  when  refueling  are:  do  not  let  the  tank  overflow, 
always  set  the  brake,  hang  nozzle  up  properly  onto  the 
pump  and  eliminate  any  leaks  on  the  hose  connections. 

Most  small  w'**'^"  *'C3tment  plants  do  rot  have  hoists  or 
pits  for  vehicle  luDrication.  However,  mosi  of  the  following 
suggestions  are  applicable.  First,  keep  all  walkways,  steps, 
tools  and  containers  free  from  grease,  oil  and  other  dirt.  This 
will  reduce  the  possibility  of  accidents  caused  by  these 
items.  As  when  maintaining  any  equipment,  use  the  right 
tools,  keep  shoes  free  of  all  oil  or  grease  and  use  only  non- 
slip  soles  on  the  shoes. 

If  the  plant  is  equipped  with  a  hoist,  do  not  permit  anyone 
to  remain  inside  the  vehicle  when 't  is  on  the  hoist.  When 
lifting  the  vehicle,  do  not  permit  tools  on  the  hoist  or  vehicle 
that  may  fall  onto  you  or  other  personnel  in  the  work  area. 
Keep  the  driveway  free  of  hoses,  tools,  and  cars  and  always 
keep  you  hand  on  the  operating  level  when  raising  or 
lowering  the  vehicle. 

Most  water  treatment  plants  have  assigned  specific  areas 
for  washing  or  steam  cleaning  vehicles.  If  your  plant  does 
not  have  such  an  area,  you  should  have  one  assigned.  This 
area  does  not  have  to  be  elaborate,  but  should  have  water 
hoses  and  steam  cleaning  equipment  and  be  adequately 
drained.  The  same  safety  rules  apply  to  makeshift  installa- 
tions as  apply  to  completely  equipped  cleaning  areas.  The 
most  important  consideration  is  the  steam  cleaner.  Keep  the 
nozzle  clean,  check  water  level  on  coils  before  turning  on 
the  flame,  and  always  wear  protection  for  your  eyes  and 
face  Make  sure  that  the  cleaner  is  adequately  ground  and 
be  careful  of  cleanin'^  compounds  (see  Caustic  Section  for 
burns).  Maintain  steam  hoses,  check  connections  and  never 
permit  horseplay  with  steam  cleaning  equipment.  As  in  other 
work  areas,  keep  the  wash  rack  free  ^''om  grease  and  oil  and 
oily  rags.  Hoses  should  be  stored  on  the  rack  when  not  in 
use.  always  use  scaffolding  or  platforms  when  cleaning  the 
tops  of  vehicles. 

20.42  Seat  Belts 

Many  water  treatment  plant  operators  have  some  reason 
for  not  wearing  seat  belts.  The  reasons  may  sound  good, 
but  they  won't  protect  you  in  the  event  of  an  accident.  Many 
lives  would  have  been  saved  if  seat  belts  were  used.  The 
water  utility  should  equip  all  vehicles  with  seat  belts  and 
require  evj?'/  operator  to  use  them. 


424  Water  Treatment 


GiECK 

1st 

2nd 

3rd 

4  th 

5th 

1 

Oil 

2 

Water 

3 

Tires 

4 

}tom 

5 

Headli^ts,  High  -  Low 

6 

Tail  Lights 

7 

Turn  Signals 

8 

Stop  Lights 

9 

Battery  v;ater 

10 

Fire  Extinguisher 

11 

First  Aid  Kits 

12 

Windshield  'vJipars  I 

13 

Visual  Inspection  -  Wire  Rope 

14 

-  Hook 

15 

tl  II 

-  Sheaves 

16 

~  Boom 

17 

-  Hydraulic  Ijovel 

18 

Operational  Test  Controls 

SERVICE  I^LEAGE  READINGS 

FUEL  CavJSUMPTION 

Week 

Present 

Last  Service 

Difference 

Start  Mileage 

1st 

End  Mileaqe 

2nd 

Total  Miles 

3rd 

Fuel  Used 

4th 

MPG  Averaqe 

5th 

Fijg.  20,9  Mobile  Equipment  Check  List 


Safety  425 


20.43  Accident  Prevention 

The  best  overall  means  of  preventing  vehicle  accidents  is 
defensive  dnving.  This  method  requires  training  and  a 
certain  mental  outlook  on  the  part  of  the  vehicle  operator. 
Most,  if  not  all,  drivers  think  they  are  good  at  what  they  do 
and  this  may  be  true  to  some  extent.  However,  if  each  driver 
would  operate  all  vehicles  as  if  all  other  drivers  were  the 
world's  worst  drivers,  accidents  would  be  greatly  reduced 

Good  drivers  check  out  their  vehicles  each  time  they  use 
them  and  have  any  maintenance  performed  when  needed. 
They  use  proper  signals  for  directional  change,  always 
observe  traffic  regulations  and  show  courtesy  to  others. 
Remember  that  drivers  in  an  agency  vehicle  represent  the 
agency.  Therefore,  good  driving  skills  are  good  for  public 
relations. 

Another  way  to  avoid  accidents  is. 

This  IS  a  very  unwise  practice  which  is  dangerous  to  the 
vehicle  and  hazardous  to  its  operator.  A  good  rule  to  use 
when  following  another  vehicle  is  the  old  one-car-length  for 
every  10  MPH,  and  if  there  is  limited  visibility,  increase  that 
distance.  Another  rule  is  the  "Ihree  Second  Rule"  which 
says  you  must  be  at  least  three  seconds  behind  the  car  in 
front  of  you.  Take  precautions  when  backing  up.  Always  set 
the  bi'ake  and/or  shift  to  "Park"  when  parking  the  vehicle.  Be 
cautious  at  intersections.  As  a  defensive  driver,  always  be 
ready  to  give  the  right  of  way.  No  right  of  way  Is  worth 
injuring  oneself. 

In  some  cases,  even  the  most  defensive  and  careful  driver 
Has  an  accident.  Because  of  this,  each  vehicle  should  carry 
tiashlights,  flares,  flags  and  a  fire  extinguisher,  along  with  a 
first  aid  kit.  In  the  event,  of  an  accident,  the  driver  should 
know  how  to  fill  out  all  the  forms,  a  supply  of  which  should 
be  provided  in  the  vehicle. 

Remember,  when  operating  a  vehicle,  an  accident  can  be 
prevented  by  defensive  driving.  The  plant  operator  should 
have  each  member  of  the  staff  take  a  defensive  driver 
training  course.  Each  driver  should  develop  a  defensive 
driver  frame  of  mind.  Developing  a  good  attitude  and  driving 
skills  are  the  key  to  accident  prevention  when  operating  a 
vehicle.  In  any  event,  new  employees  should  be  given  road 
tests  in  operating  the  types  of  vehicles  they  v/ill  be  using. 

Here  are  a  few  reminders  when  operating  a  vehicle. 
During  a  storm,  roadways  or  pavement  are  likely  to  be 


slippery.  Slow  down,  pump  the  brakes  when  stopping  and 
remember  the  minimum  distance  rules.  No  driver  should  be 
required  to  operate  an  unsafe  vehue.  Keep  copies  of  a 
suitable  form  for  reporting  mechanical  problems  in  each 
vehicle  and  encourage  operators  to  use  them. 

20,44  Forklifts 

Most  water  treatment  plants  and  pumping  stations  have  a 
forklift.  Most,  if  not  all,  p»ant  operators  use  this  vehicle  to 
move  chemicals,  repair  parts,  and  even  use  it  when  making 
repairs  to  lift  heavy  objects.  Therefore,  every  plant  operator 
should  be  trained  in  the  use  of  the  forklift. 

Following  are  a  few  points  regarding  safe  operation  of  the 
forklift  with  suggestions  for  operator  safety  as  well  as 
protection  of  others  who  may  be  in  the  operating  area  of  the 
forklift.  Keep  all  aisles  free  of  boxes  and  other  debris.  Do  not 
permit  anyone  to  nde  on  the  forklift  except  the  operator. 
Never  overload  the  forklift.  Always  be  sure  the  warning 
signals  are  operational  and  never  leave  the  power  on  when 
leaving  the  forklift.  Like  other  vehicles,  check  out  the  brakes 
before  operating.  Be  careful  at  intersections  of  aisles  and 
always  face  the  direction  of  travel.  If  a  loaded  forklift  is  to  be 
placed  on  an  elevator,  be  sure  that  the  load  on  the  forklift 
and  the  weight  of  the  vehicle  do  not  exceed  the  lifting  weight 
of  the  elevator.  Also,  make  sure  the  forklift  load  is  stacked 
properly  before  lifting  or  moving.  When  handling  drums, 
special  lifting  and  retaining  devices  are  needed. 

Figure  20.10  is  a  typical  forklift  inspection  form. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  440. 

20,4A  What  cause^  tire  wear  on  motor  vehicles? 

20  4B  Motor  vehicles  should  contain  what  safety  devices? 


id 

ERIC 


4iS 


426  Water  Treatment 


SOUTHERN  NEVADA  WATER  SYSTEM 
For  Truck  Operator  Inspection 

Operator 

Brake 

Boom 

Tilt 

Back 

UD 

Horn 

Horn 

Wheel 

Rprnarkc 

up 

un. 

r* 
r 

R 



FORM  ^/268  —  S.N.W.S. 

ERIC 


Fig,  20, 10  Forklift  inspection  form 

447 


Safety  427 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  20.  SAFETY 

Lesson  3  of  4  Lessons) 


Write  the  answers  to  these  questions  m  your  notebook 
before  continuing  The  problem  nuTl-yering  continues  from 
Lesson  2. 

21   How  can  an  operator  prevent  fires  in  a  water  treatment 
plant? 

22.  How  would  you  maintain  water-type  fire  extinguishers'? 

23.  How  would  you  maintain  fire  hoses  in  your  water 
treatment  plant? 

24  What  precautions  should  be  taken  in  areas  where 
flammable  material  is  stored? 


25  How  can  an  operator  make  visuors  feel  as  if  the  water 
being  produced  is  safe  to  drink? 

26  How  would  you  remove  a  manhole  cover? 

27.  What  precautions  should  be  taken  when  operating 
power  tools  in  a  wet  or  damp  location? 

28.  What  fire  hazards  should  be  considered  before  doing 
any  welding? 

29.  How  would  you  safely  refuel  a  motor  vehicle? 

30  What  safety  precautions  should  be  taken  when  driving 
during  a  storm? 


WO 


ERIC 


r 


428   Water  Treatment 


CHAPTER  20. 

(Lesson  4  of  4 


20.5   ELECTRICAL  EQUIPMENT 

20*50  Eiectrtcal  Safety 

As  a  water  plant  operator,  you  aie  not  expected  to  be  an 
expert  in  electrical  equipment,  but  you  nrijst  have  a  working 
understanding  of  electricity.  This  includes  an  understanding 
of  the  safety  precautions  needed  to  operate  the  electrical 
equipment.  After  all,  electrical  energy  is  required  to  power 
most  of  the  treatment  plant  operations.  The  objective  of  this 
section  is  to  show  you  how  to  operate  safely  and  to  become 
involved  to  a  limited  degree  in  the  maintenance  of  electrical 
equipment.  Elecfxity  is  unforgiving  to  the  careless  treat- 
ment plant  operator. 

20.51  Current  —  Voltage 

Many  types  of  electrical  current  are  used  in  water  treat- 
ment plants  and  the  associated  pumping  plant.  Each  day  the 
plant  operator  is  exposed  to  this  equipment,  giving  little 
thought  to  the  potential  hazards  ;f  the  equipment.  Current 
may  come  into  the  plant  at  a  high  voltage,  for  example,  69 
KVA,  reduced  to  4160  volts  or  2300  volts.  This  current  may 
power  pump  motors,  blowers  and  other  equipm.ent  at  lower 
voltages  of  440, 220,  or  120  volts  and  within  starters  may  be 
reduced  to  24  or  12  volts  or  changed  over  into  DC  voltages. 
Given  all  of  these  variou*"  voltages,  the  operator  mu't  be 
careful  not  to  become  careiess  working  with  equipment. 
Therefore,  become  familiar  with  the  types  of  current  and 
voltage  in  the  plant.  By  knowing  this,  you  will  avoid  the 
mistake  of  becoming  involved  with  unsafe  electrical  currents 
or  practices  for  which  you  are  not  trained.  This  will  also 
enable  you  to  know  when  to  ask  for  a  qualified  person  to 
perform  any  necessary  repairs. 

20.52  Transformers 

Electrical  power  entering  a  plant  is  routed  through  trans- 
fomfiers  to  reduce  the  voltage  in  most  cases.  There  are 
many  types  of  transformers  although  the  operator  may  only 
think  of  the  larger  ones  that  bring  the  power  into  the  plant. 
Sometimes  these  are  owned  by  the  waterworks  and  there- 
fore the  maintenance  is  the  responsibility  of  the  operator. 
There  are  few,  if  any,  plant  operators  who  are  qualified  to 
perform  such  maintenance.  Never  attempt  to  wcrk  on  a  high 
voltage  transformer  without  the  ass  itance  of  qualified  per- 
sonnel. Such  personnel  can  be  located  at  tlie  power  com- 
pany or  contact  an  electrical  contractor  who  specializes  in 
the  repair  and  maintenance  of  electrical  transformers.  You 
will,  however  need  to  keep  records  of  the  transformer's 
operation.  This  information  is  helpful  to  repair  personnel  and 
is  useful  to  operators  who  need  to  know  the  status  of  the 
transformer. 

There  are  many  small  transformei's  within  the  plant's 
operating  gear  and  it  is  these  you  may  have  to  maintain. 
Most  often  these  low-voitage  transformers  become  over- 
worked; they  overheat  and  burn  out.  Any  fire  in  the  electrical 
gear  can  be  hazardous.  Be  very  careful  when  opening  a 
starter,  breaker  box  or  indicating  instrumentation  if  a  fire  or 
overheated  transformer  is  suspected.  Operators  have  been 
badly  burned  by  not  thinking  before  opening  such  'devices 
when  they  smell  smoke  in  pumping  stations  or  treatment 
plants.  When  solving  problems  with  hot,  overheated,  or 
buming  transformers,  remember  what  you  learned  in  Sec- 


SAFETY 

Lessons) 


tion  20.2  about  electrical  fires.  For  the  safety  of  operating 
personnel  and  the  safety  of  the  plant,  regularly  inspect  or 
have  someone  inspect  both  large  and  small  transformers.  If 
you  detect  any  overheating,  have  a  qualified  electrician 
inspect  ano  replace  any  transformer  that  is  not  functioning 
properly. 

There  should  be  a  fence  around  the  transformer  station, 
with  a  locked  gate  and  only  a  limited  number  of  keys  issued 
to  plant  personnel.  The  operator  may  perform  routine  pre- 
ventive maintenance  such  as  removing  weeds,  brush  and 
general  cleanup.  Replacing  fuses  and  major  maintenance  or 
repairs  should  be  made  by  the  power  company  or  qualified 
electricians.  Maintenance  must  be  performed  by  qualified 
and  well  trained  personnel. 

20.53  Electrical  Starters 

As  a  treatment  plant  operator,  your  most  frequent  contact 
with  electrical  power  will  probably  be  with  electncal  starters 
on  the  motor  control  panels.  These  devices  are  used 
throughout  the  plant  and  provide  an  interface  between  the 
operator  and  the  flow  of  energy.  The  starter  may  be  located 
on  a  switch  panel  or  there  may  be  a  switch  that  is  remotely 
located  from  the  starter.  One  of  the  first  safety  procedures 
you  should  take  is  to  use  a  special  insulated  mat  on  the  floor 
at  all  switchboards.  The  starter  should  be  provided  with 
adequate  lighting  and  clearly  marked  Start-Stop  buttons. 
Replace  indicating,  lights  as  needed  without  delay.  There 
should  always  be  clear  and  adequate  working  space  around 
the  starter  or  sxyitch  panels.  To  reduce  the  hazards  of  fire  in 
electrical  starters,  they  should  be  cleaned  and  maintained  on 
a  regular  basis.  Such  maintenance  must  be  performed  by 
trained,  qualified  personnel.  In  electrical  starting  equipment, 
fires  can  easily  occur  because  of  accumulation  of  dust  and 
dirt  on  the  contactors,  or  when  they  become  so  badly  burned 
that  they  do  not  make  proper  contact;  thus,  they  become 
overheated  and  start  fires.  The  key  to  preventing  fires  in 
starting  equipment  is  a  good  preventive  maintenance  pro- 
gram. 


20.54  Electrical  Motors 


The  treatment  plant  operator  is  exposed  to  many  types 
and  sizes  of  electrical  motors.  In  some  plants,  the  motors 
are  old  and  require  more  attention  because  of  exposed 
parts.  The  newer  electncal  motors  are  enclosed  and  have  all 
parts  protected.  For  the  old  motors,  you  should  install 
guards  or  guard  rails  to  prevent  accidental  contact  with  live 
parts  of  the  motors. 

449 


Safety  429 


Some  of  the  electric  motors  may  have  exposed  couplings, 
pulleys,  gears  -^r  sprockets  that  also  require  consideration 
For  these  and  other  moving  devices,  a  wire  cloth  gear  guard 
may  be  installed  The  gear  guard  can  also  be  made  of  sheet 
metal  However,  no  matter  which  type  of  guard  is  used,  it 
must  be  securely  fastened  onto  the  floor  or  some  other  solid 
support  The  safeguards  must  be  constructed  and  fitted  to 
prevent  material  being  handled  by  operators  from  coming 
into  contact  with  the  moving  parts  driven  by  the  motors. 

Another  consideration  is  projections  on  couplinos,  pulley 
shafts  and  other  revolving  parts  on  the  motor  or  on  the 
device  being  driven  These  projections  can  be  bolts,  keys, 
set  screws  or  other  projections  The  projections  should  be 
removed,  reduced  or  protected  by  one  of  the  above  guards. 

Check  grounding  on  ait  electncai  n.otors  as  part  of  a 
routine  maintenance  program.  The  motor  frames  them- 
selves must  be  grounded  if  the  wires  to  the  motor  are  not 
enclosed  in  an  armored  conduit  or  other  metallic  raceway. 
Check  that  all  jointb  are  mechanically  secure  to  assure  good 
grounding.  In  the  case  of  portable  electric  motors,  the 
simplest  way  of  grounding  is  an  extra  conductor  m  the  cord 
serving  the  motor.  The  best  way  is  to  install  a  ground  fault 
interrupter  (G  F.I.)  receptacle.  This  device  will  automatically 
disconnect  the  tool  from  the  power  supply  if  the  ground  is 
not  connected  and  will  supply  the  greatest  protection  to  the 
operator  and  to  the  equipment. 

When  using  portable  electrical  motors  always  check  the 
service  cord.  If  the  cord  or  receptacles  are  in  poor  condition 
or  showing  signs  of  wear,  they  should  be  replaced.  A  badly 
worn  cord  must  never  be  used  in  a  wet  location. 

20*55  instrumentation 

In  this  area  of  water  treatment  the  operator  is  not  exposed 
to  a  great  deal  of  hazard,  but  must  give  some  consideration 
to  these  devices  since  they  are  operated  by  electncai 
current.  This  is  also  true  of  all  other  automatic  equipment. 
Although  most  instruments  protect  the  operator,  there  is  still 
a  degree  of  hazard  when  changing  charts,  calibrating  or 
performing  other  maintenance.  First,  when  calibrating  an 
instrument,  you  are  exposed  to  at  least  12  Volts  DC  to  120 
Volts  AC  If  you  become  grounded  with  the  120  Volts  AC, 
you  may  be  killed  or  severely  injured.  Also,  when  maintaining 
automatic  control  equipment,  adjustment  of  one  instrument 
may  start  another  device,  exposing  another  operator  to  a 
hazard  because  of  an  unexpected  start.  As  mentioned 
above,  electronic  devices  operate  on  low  current,  but  don't 
forget  that  there  is  still  high  voltage  located  somewhere  in 
the  instrument. 

20.56   Control  Panels 

Control  panels  and  switchboards  should  only  be  accessi- 
ble to  qualified  personnel.  The  plant  operator  should  have  a 
standard  operating  procedure  (SOP)  for  lockout  of  all  electri- 
cal equipment  (Figure  20.11).  Two  hazards  due  to  the  lack  of 
a  good  lockout  procedure  are  (1)  accidentally  starting  a 
piece  of  equipment  exposing  a  fellow  operator  to  a  hazard, 
and  (2)  turning  electrical  power  on  when  someone  is  still 
working  on  the  equipment,  exposing  that  person  to  danger. 

Always  provide  adequate  working  space  in  and  around 
control  panels.  As  with  electrical  motors,  the  panels  must  be 
well  grounded.  At  some  locations  there  may  be  a  need  for 
special  insulating  mats,  such  as  in  wet  locations.  Adequate 
lighting  must  be  available  inside  the  control  panel  as  well  as 


outside  for  those  who  do  the  maintenance  Moisture  or 
corrosive  gases  must  be  kept  away  f'-om  the  control  panels. 
To  reduce  fire  hazard,  never  store  any  hazardous  matena^ 
next  to  switchboards  or  control  panels.  Panels  carrying 
greater  than  600  volts  musr  be  permanently  marked  warning 
of  the  hazards  Areas  of  high  voltage  should  be  screened  off 
and  locked  with  a  limited  number  of  keys  given  to  authorized 
personnel  only 

In  a  safe  lockout  procedure,  the  switches  are  locked  open 
and  are  properly  tagged,  only  the  operator  who  is  doing  the 
maintenance  should  have  a  key.  In  fact,  all  people  who 
perform  electrical  m  .intenance  should  have  their  own  indi- 
vidual lock  and  key  so  as  to  maintain  control  over  the 
equipment  being  worked  on  by  each  individual 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  440. 

20  5A  Why  should  each  plant  operator  become  familiar  with 
the  type  of  current  and  voltage  in  the  water  treatnrient 
planf? 

20  5B  List  the  moving  parts  on  electrical  motors  that  re- 
quire safety  guards 

20  5C  What  are  two  hazards  created  by  the  lack  of  a  good 
lockout  procedure  for  control  panels  and  switch- 
boards'' 


20.6    LABORATORY  SAFETY^ 

20.60  Laboratory  Hazards 

In  general,  water  plant  operators  do  not  experience  a 
great  deal  of  exposure  to  hazardous  laboratory  conditions. 
However,  you  will  be  in  contaci  with  glassware,  toxic  chemi- 
cals, flammable  chemicals,  corrosive  acids  and  alkalies. 
There  may  be  times  when  you  will  be  exposed  to  hazardous 
bacteriological  agents.  The  seriousness  of  the  hazards 
depends  mainly  upon  the  size  of  the  plant  and  the  operating 
procedures  in  the  treatment  piant.  For  your  own  safety,  learn 
the  proper  procedures  for  handling  laboratory  equipment 
and  chemicals. 

20.61  Glassware 

An  important  item  in  laboratory  safety  is  handling  of 
glassware  Almost  all  tests  performed  by  an  operator  will 
require  the  use  of  some  glassware.  The  operator's  hands,  of 
course,  are  exposed  u  the  greatest  hazard.  To  reduce 
accidentc  when  handling  glassware,  never  used  chipped, 
cracked  or  .uoken  glassware  in  any  testing  procedures.  All 
such  glassware  should  be  disposed  of  in  a  container  marked 
"For  Broken  Glass  Only "  Never  put  broken  glass  m  waste- 
baskets  Although  it  may  not  be  a  hazard  to  the  operator,  it  is 
a  danger  to  those  who  clean  out  the  wastebaskets.  Clean  up 
any  broken  glass  and/or  spilled  chemicals  to  reduce  haz- 
ards to  others.  Never  let  broken  pieces  of  glass  remain  in  the 
sink  or  in  sink  drains.  This  may  cause  cuts  to  others  who 
unknowingly  try  to  clean  the  sink. 

Washing  glassware  is  always  potentially  hazardous.  The 
glassware  can  be  broken  while  being  washed,  causing  cuts, 
or  cuts  can  be  caused  by  chipped  or  cracked  glassware. 
Also,  the  cleaning  compounds  themselves  can  be  a  problem. 
Sometimes  strong  acid  cleaners  are  used  to  remove  stains 


6  See  FISHER  SAFETY  MANUAL  Fisher  Scientific  Company,  711  Forbes  Avenue,  Pittsburgh,  PA  15210. 

Er|c  Utl^  450 


430  Water  Treatment 


SOUTHERN  NEVADA  WATER  SYSTEM 
Standard  Operating  T/ocedure 


TITLE:  SAFETY,  EQUIPMENT  LOCKOUT 


Number:  122 


SECTION:  SAFETY 


Prepared  By: 
RLC-2/1/73 


OBJECTIVE 

The  purpose  of  this  procedure  is  to  provide  the  highest  degree  of  safety  to  SNWS  employees,  also  to  prevent 
mechanical  damage  or  undesirable  operation  of  equipment  when  it  is  being  serviced  or  repaired. 

PROCEDURE 

Locks  for  securing  equipment  shall  be  issued  to  maintenance  people  and  will  be  available  to  other  personnel 
at  the  superintendent's  office.  There  is  some  machinery  that  is  designed  and  equipped  with  facilities  for  minor 
rep?  "  adjustments  and  lubrication  while  in  opere.J;on.  However,  in  all  cases,  the  equipment  must  be  turned 
off  •    such  repairs  or  lubrication. 

In  order  to  prevent  accidental  starting  or  endangering  the  safety  of  operating  or  maintenance  personnel,  be- 
fore performing  any  woik  the  equipment  must  be  secured.  In  the  event  the  starter,  motor  or  electrical  service 
to  the  equipment  cannot  be  locked  out,  a  "Do  Not  Operate"  safety  tag  must  be  attached  to  the  starting  mecha- 
nism. 

During  inspection,  if  an  operator  finds  that  the  continual  operation  of  a  unit  may  cause  damage,  il  should  also 
be  shut  down  and  locked  out.  The  key  to  the  lockout  device  should  be  attached  to  the  Work  Crder.  Thereafter, 
no  one  other  than  the  Manager,  Maintenance  Superintendent  cr  Treatment  Superintendent  or  someone 
directly  ordered  by  the  above  is  to  remove  the  lockout  device. 


Fig.  20, 1 1   Standard  operating  procedure  for  locking 
out  of  electrical  equipment 

ER?C  451 


Safety  431 


from  the  glassware.  Without  protective  gloves,  you  hands 
could  be  seiicusly  burned  by  these  acids. 

20.62  Chemicals 

When  handling  liquid  chemicals  such  as  acids  and  bases, 
always  use  safety  glasses  or  face  shields.  If  working  with 
ether  or  hloroform,  avoid  inhalation  of  fumes  and  always  do 
this  type  of  work  under  the  ventilation  hooa.  Be  sure  to  turn 
the  ventilation  fan  on.  Of  course,  be  careful  of  open  flames 
when  using  flammables  such  as  ether.  As  d  general  rule,  do 
not  permit  smoking  in  the  laboratory.  All  chemicals  should 
be  stored  in  proper  locations;  do  not  set  chemicals  on  the 
laboratory  benches  where  they  may  cause  an  accident  if 
spilled  or  if  the  container  is  broken. 

When  handling  laboratory  gases,  give  consideration  to 
their  location  and  potential  accident  hazards.  Gas  cylinders 
must  be  prevented  from  falling  by  using  safety  retaining 
devices  such  as  chains.  The  valve  and  cylinder  regulator 
should  be  protected  from  being  struck  by  stools,  ladders 
and  other  objects. 

When  mixing  acid  with  water,  always  pour  tl^e  acid  into  the 
water  while  stirring. 

Nev^  add  wd^vto  add  \xcaM^a 

tkc^(y'i^^t\\i^  catMbiHq  splattering 
awd  esce^  heat  ^cnevs^iow. 

Always  use  safety  goggles,  yloves  and  protective  garments. 
When  cleaning  up  acid  or  alkali  spills,  dilute  with  lots  of 
water  even  if  you  flush  them  down  the  sink  drain.  Baking 
soda  can  ^e  used  to  neutralize  acids,  and  vinegar  is  used  to 
neutralize  bases.  Never  allow  mercury,  gasoline,  oil  or 
organic  compounds  into  the  laboratory  drains.  Use  only  a 
toxic  waste  disposal  dram  system  for  these  items.  Pouring 
such  compounds  down  sink  drains  can  cause  an  explosion, 
allow  toxic  gases  and  vapors  to  ente.  the  lab,  or  destroy  the 
piping. 

You  must  never  use  your  mouth  with  the  pipet  for  transfer- 
ring toxic  chemicals,  acids  or  alkalis.  Use  a  suction  bulb, 
aspirator,  pump  or  vacuum  line.  If  you  use  your  mouth,  there 
is  always  the  danger  of  getting  tho  toxic  solutions  into  your 
mouth. 

ERJC  .^1^ 


20.63  Biological  Considerations 

Do  not  take  chances  with  bacteria.  A  good  policy  is  to 
have  each  operator  immunized  vvith  anti-typhoid  vaccine  and 
to  keep  their  booster  shots  current.  Always  use  good 
sanitary  practices,  particularly  when  working  with  unknown 
bacteria  or  known  pathogens.  Never  pipet  bacteriological 
samples  by  mouth.  ALWAYS  USE  A  PIPET  BULB. 

When  exposed  to  any  bacteria,  you  should  make  it  a  habit 
to  always  wash  your  hands  before  eating  or  smoking.  If  you 
have  any  cuts  or  broken  skin  areas,  these  wounds  should 
not  come  in  contact  with  bacterial  agents.  You  should  wear 
protective  gloves  or  cover  the  wound  with  a  bandage  when 
working  with  any  kind  of  bacteria. 

All  work  areas  should  be  swabbed  down  with  a  good 
bacteriological  disinfectant  before  and  after  preparing  sam- 
ples. As  a  gene  il  policy,  the  preparation  or  serving  of  food 
should  never  be  permitted  in  the  laboratory.  Also,  give  some 
consideration  to  proper  ventilation,  because  some  bacteria 
may  be  transmitted  via  the  air  system. 

20.64  Radioactivity 

There  are  many  laboratory  and  treatment  plant  instru- 
ments that  use  radioactive  isotopes  in  laboratory  tests  and 
research.  A  plant  operator  may  be  exposed  to  radioactive 
compounds  when  calibrating  sludge  density  meters  or  using 
research  isotopes.  From  a  safety  standpoint,  only  qualified 
personnel  should  be  involved  in  the  use  of  radiorDtive 
compounds.  If  radioactive  compounds  are  present  in  the 
laboratory,  warning  signs  should  be  posted.  The  disposal  of 
all  radioactive  compounds  must  be  performed  strictly  by 
qualified  laboratory  personnel  in  accordance  with  govern- 
ment regulations. 

20.65  Laboratory  Equ'oment 


20.650  Hotplates 

You  will  probably  use  a  hot  plate  m  your  >""'^<^hold  odor 
number  (^ON)  tests.  YOo  should  turn  the  hot  plate  off  when 
not  in  use,  never  place  bare  hands  on  the  hot  plate  to  check 
if  It  IS  hot.  Wh"in  using  the  hot  plate  to  remove  gas  or  fumes, 
always  use  the  hood  and  turn  on  the  hood  ventilation  fan. 
Never  place  glassware  onto  a  hot  plate  if  the  outside  of  the 
glassware  has  water  or  moisture  on  the  surface  between  the 
glass  and  the  hot  plate.  Steam  will  form  at  this  interface  and 
cause  the  glass  to  break.  When  taking  hot  glassware  off  the 
hot  plate,  always  usj  asbestos  gloves. 

20.651  Water  Stills 

Most  water  btills  in  the  laboratory  today  are  the  electrical 
type.  To  observe  good  safety  practices,  check  the  items 
described  in  the  electrical  safety  section  of  this  chapter, 

452 


432  Water  Treatment 


such  as  good  grounding.  Set  up  a  SOP  (Standard  Operating 
Procedure)  for  proper  operation  of  the  still  and  follow  the 
manufacturer's  Instructions  for  proper  starting  and  stop- 
ping. The  sti..  will  require  cleaning  from  time  to  time.  Be  very 
careful  when  disassembling  the  still.  Parts  may  be  frozen 
together  because  of  hardness  in  the  water  and  may  require 
an  acid  wash  to  separate.  Be  sure  that  the  boiler  unit  is  full  of 
water  before  turning  the  still  on.  Never  allow  cold  water  into 
a  hot  boiler  unit  because  it  may  cause  the  unit  to  break. 

20.652  Steriliz  rs 

There  are  two  types  of  sterilizers:  (1)  dry  electrical  steriliz- 
ers a  Id  (2)  wet  sterilizers  (autoclaves).  In  the  dry  electrical 
sterilizers,  check  the  cords  frequently  because  the  high  heat 
may  damage  the  wiring.  Always  let  the  unit  cool  off  before 
removing  its  contents.  Wet  sterilizers  (autoclaves)  are  under 
pressure  by  steam  and  should  be  opened  very  slowly.  Use 
asbestos  gloves  and  protective  clothing  when  unloading  the 
autoclave.  Cover  the  steam  exhaust  with  asbestos  covering 
to  prevent  burns.  Any  leakage  around  the  donr  should  be 
repaired  by  replacing  door  gaskets,  or  even  the  door  if  It  is 
worn  or  bent  Always  load  the  autoclave  In  accordance  with 
the  manufacturer's  recommendations.  Never  allow  an  oper- 
ator to  work  with  this  equipment  without  proper  Instruction 
in  its  operation. 

20.653  Pipet  Washers 

Cleaning  p«pets  can  be  hazardous.  Many  laboratories 
have  P  oipet  cleaner  which  contains  an  acid  compound  or 
other  Cleaning  agents.  Always  use  protective  clothing  and  a 
face  shield  when  working  with  the  washer  jnit.  Try  to  avoid 
dripping  or  spilling  the  cleaninq  compound  when  transfer- 
ring the  pipets.  if  the  acid  cor  o  into  contact  with  your  skin, 
use  the  remedies  recommer.jed  in  Section  20.11,  "Acids." 

QUESTIONS 

Write  your  diibvvers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  440. 

20.6A  Why  -s  washing  glassware  always  a  potential  haz- 
ard? 

20  6B  Whr  p..     .dons  should  be  taken  when  handling 
liquid  chemicals  such  as  acids  and  bases? 

20.6C  Why  c'lould  mercury,  gasoline,  oil  or  organic  com- 
pounds never  be  allowed  into  laboratory  drains? 

20.6D  How  can  an  operator  be  exposed  to  raoioacttve 
compounds? 

20.6E  Why  should  cold  water  never  be  allowed  into  the  hot 
boiler  unit  of  a  water  still? 

20.7   OPERATOR  PROTECTION 

20.70  Operator  Safety 

So  far  In  this  chapter  we  have  discussed  many  means  by 
which  you  can  protect  yourself  and  your  equipme*  t.  In  this 
section  we  wish  to  discuss  your  own  personal  projection. 
Take  a  look  at  the  means  of  protecting  the  eye,  the  foot,  the 
head  and  most  of  all  —  look  at  wator  safety.  After  all,  a  plant 
operator  is  always  In  contact  with  water.  The  water  may  be 
found  in  raw  water  reservoirs,  settling  basins,  clear  wells  or 
filters.  Operators  have  lost  their  lives  by  falling  into  the 
backwash  gullet.  Operators  have  lost  their  lives  in  the 
finished  water  reservoirs.  As  unlikely  as  it  seems,  fatal 
accidents  have  happened  in  the  past  and  will  happen  again 
in  the  future.  Therefore,  it  is  the  responsibility  of  each 

ERIC  iH^^^ 


operator  to  watch  for  any  safety  problems  in  the  plant's 
reservoirs,  pumping  stations,  or  filters  You,  the  operator, 
are  responsible  for  yourself.  You  should  never  expose 
yourself  to  unsafe  conditions. 

A  major  problem  confronting  many  operators  is  where  ar 
how  can  reliable  safety  vendors  and  equipment  be  locate 
State,  regional  and  national  professional  meetings,  such  as 
those  spor.sored  by  the  American  Water  Works  Association, 
often  have  displays  or  exhibits  featuring  manufacturers  of 
safety  equipment.  This  is  an  excellent  opportunity  to  meet 
the  representative  of  these  companies  and  discuss  with 
them  what  equipment  they  would  recommend  for  your 
situation.  Also  other  operators  who  have  had  experience 
with  safety  equipment  of  interest  to  you  often  attend  these 
meetings  and  are  anxious  to  share  their  experiences  with 
you. 

If  you  are  unable  to  attend  these  meetings,  the  program 
announcements  will  often  have  a  short  description  of  the 
types  of  safety  equipment  that  will  be  featured  by  each 
vendor  exhibiting  at  the  conference  You  can  obtain  the 
vendor's  address  by  looking  in  professional  journals,  buy- 
ers' guides  or  by  writing  to  the  sponsor  of  the  conference. 

20.71  Respiratory  Protection 

There  are  many  respiratory  hazards  in  and  around  the 
treatment  plant  that  an  operator  is  exposed  to  daily  including 
chemical  dusts,  chemical  fumes,  and  chemical  gases  such 
as  chlorine,  ammonia,  sulfur  dioxide,  and  acid  fumes,  to 
name  on'y  a  few.  Whenever  working  around  or  handling 
these  and  other  compounds,  you  must  take  adequate  pre- 
cautions. 

Two  types  of  conditions  for  which  you  should  be  prepared 
are:  (1)  oxygen  deficient  atmosphere,  and  (2)  sufficient 
oxygen,  but  a  contaminated  atmosphere  containing  toxic 
gases  or  explosive  conditions.  In  either  circumstance  you 
wi!!  need  an  independent  oxygen  supply.  However,  an 
independent  oxygen  supply  will  not  protect  you  from  an 
explosion. 

Call  your  local  gas  company  and  ask  their  experts  to  enter 
the  explosive  area,  if  entry  is  essential.  Your  independent 
oxygen  supply  should  be  of  the  positive-pressure  type  to 
protect  you  if  there  are  any  leaks.  Good  ventilation  can 
reduce  explosive  conditions. 

20.72  Safety  Equipment 

All  waterworks  safety  equipment  such  as  life  lines,  life 
buoys,  fire  extinguishers,  fencing,  guards,  and  respiratory 
apparatus  must  be  kept  in  good  repair  This  and  other  safety 
equipment  is  necessary  to  protect  operators  or  visitors  from 
injury  or  death.  Safety  equipment  may  fall  into  disrepair 
because  it  Is  only  used  occasionally  and  may  detenorate  due 
to  heat,  time  and  other  environmental  factors.  First  aid 
equipment  should  also  be  provided  and  kept  resupplled  as  it 
IS  used.  The  operating  staff  should  be  given  regular  instruc- 
tions in  the  use  and  maintenance  of  the  safety  equipment. 

Provide  protective  clothing  for  all  operators  handling 
chenlcals  or  dangerous  matenals.  Keep  the  clothing  clean 
and  store  it  in  a  protective  environment  when  not  In  use. 

The  water  utility  is  responsible  for  providing  outward 
opening  doors,  remote-controlled  ventilation,  inspection 

453 


Safety  433 


windows  and  similar  safety  devices  where  appropriate.  This 
equipment  should  be  exercised,  kept  clean  and  well  main- 
tained so  that  it  will  operate  when  needed. 

Respiratory  (self-contained  breathing)  apparatus  must  be 
stored  in  unlocked  cabinets  outside  of  chlorination,  sulfur 
dioxide,  c?rbon  dioxide,  ozone  and  ammonia  rooms.  The 
storage  cabinets  must  have  a  controlled  environment  to 
prevent  deterioration  of  the  equipment. 

The  operator  has  the  responsibility  to  inspect  each  appa- 
ratus for  deterioration  and  need  for  repair.  Safety  equipment 
is  of  no  use  to  the  operator  if  it  fails  when  put  to  use,  and 
may  cost  you  your  life  if  it  is  in  poor  condition.  Some  self- 
contained  breathing  apparatus  (air  packs)  depend  on  com- 
pressed air  to  supply  the  oxygen.  Under  conditions  of 
deficient  oxygen  supply,  the  canister  type  of  respirator  is 
useless.  You  could  lose  your  life  by  entering  a  room  contain- 
iny  chlonne  gas  (which  is  heavier  than  air)  while  depending 
on  a  poorly  maintained  respirator.  Although  you  might  have 
protection  from  the  chlorine,  you  would  not  have  adequate 
oxygen.  Nevb  take  a  chance  with  a  toxic  gas.  In  water 
treatment  plants,  use  only  the  positive-pressure  type  of  self- 
breathing  apparatus. 

Many  newer  plants  are  bfting  constructed  with  indepen- 
dent air  supplies  consisting  of  a  helmet,  hose  and  com- 
pressed air.  The  helmet  is  connected  by  a  hose  to  an 
uncontaminated  air  source.  The  key  word  here  is  "unconta- 
minated."  Not  only  should  the  operator  follow  a  maintenance 
program  for  the  hose  and  mouth  pieces  of  the  apparatus, 
but  the  operator  must  maintain  the  air  supply.  The  air  is 
supplied  by  mechanical  equipment  which  requires  mainte- 
nance. The  air  pressure  is  controlled  by  a  reduce^  or 
regulator  which  must  be  kept  clean  anc  maintained  to  be 
available  when  needed.  Set  up  a  preventive  maintenance 
program  for  this  equipment.  It  should  be  checked  out  on  a 
weekly  basis,  and  records  should  be  kept  of  each  inspec- 
tion. The  record  should  show  conditions  of  the  hoses, 
regulators,  air  filters,  compressors,  helmet  and  any  other 
apparatus  furnished  with  the  system. 

The  old  standby,  of  course,  has  been  the  air  packs  or  seif- 
breathing  apparatus.  These  units  are  carried  by  the  user, 
giving  the  operator  an  independent  source  of  air  (oxygen). 
The  unit  can  be  used  in  any  concentration  of  contamination 
of  gases,  duot  or  anywhere  the  aimosphere  is  oxygen 
deficient.  There  are  two  types  of  units.  One  type  of  unit 
depends  on  compressed  air  or  oxygen,  and  the  second 
system  generates  oxygen  by  use  of  chemicals  in  a  canister. 
The  oxygen  is  generated  by  the  moisture  exhaled  by  the 
user.  Because  this  equipment  is  not  used  daily  in  the  water 
treatment  plant,  there  must  be  a  preventive  maintenance 
program,  with  records,  inspection  and  operator  check  out. 
As  with  any  system,  self-breathing  equipment  requires  main- 
tenance. This  is  vital  because  the  op  ator's  life  will  depend 
on  how  well  th's  apparatus  performs. 

Training  is  another  important  consideration.  Even  though 
you  may  have  used  the  breathing  apparatus  many  times  in 
the  past,  you  should  be  checked  out  each  month  on  the 
equipment.  There  should  be  a  maximum  allowable  time  for 
putting  on  the  apparatus.  The  apparatus  should  be  checked 
out  under  field  conditions,  such  as  using  amtnonia  or  some 
other  non-toxic  gas.  Remember,  it  is  too  late  to  learn  how 
fast  an  operator  can  put  on  a  self-breathing  apparatus  when 
a  room  is  filled  with  chlorine. 

Be  aware  that  there  have  been  cases  where  operators 
have  been  saved  t)ecauso  they  knew  how  to  use  the 
breathing  apparatus  properly.  Only  repeuted  practice  will 
enable  you  to  master  this  survival  skill. 

ERJC  ..[. 


20.73  Eye  Protection 


The  water  treatment  plant  operator  has  only  two  eyes. 
You  may  think  that  everyone  is  aware  of  this  fact.  However, 
some  operators  behave  as  though  they  have  many  eyes  and 
are  very  careless  about  protecting  them  from  hazards. 

Because  some  operators  fail  to  see  the  value  of  eye 
protection,  it  will  take  a  maximum  effort  on  behalf  of  the 
supervisory  staff  to  enforce  an  adequate  eye  protection 
program.  There  must  be  an  intense  program  of  education, 
persuasion,  and  appeal  to  guarantee  compliance  with  an 
eye  protection  program. 

Most  conditions  in  which  a  plant  operator  needs  eye 
protection  are  not  too  difficult  to  understand.  Eye  protection 
IS  needed  when  handling  msny  of  thf?  liquid  chemicals,  acids 
and  caustics.  Some  of  the  tests  per  ormed  in  the  laboratory 
require  eye  protection.  Only  a  few  moments  are  required  to 
put  on  a  ^.^^e  shield  or  safety  glasses,  and  remember  —  the 
loss  of  ai^  eye  will  last  a  lifetime. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  440. 

20.7A  When  entering  an  oxygen-deficient  atmosphere, 
what  type  of  oxygen  supply  is  recommended*^ 

20.7B  Where  should  respiratory  apparatus  be  stored? 

20.7C  How  frequently  should  independent  air  supply  equip- 
ment be  checked  out  and  what  should  be  inspected? 

20  7D  How  can  compliance  with  an  eye  protection  program 
be  encouraged? 

20.7E  Under  what  conditions  does  an  operator  need  eye 
proteotion*? 

20.74  Foot  Protection 

There  are  few  situations  under  which  a  water  treatment 
plant  operator  needs  foot  protection.  In  the  normal  routine  of 
daily  operation  of  the  plant,  there  are  not  many  hazards  to 
the  operator's  feet.  But  in  some  plants  the  operator  also 
performs  plant  maintenance.  Here  the  steel  toed  safety 
shoes  are  useful.  The  shoe  should  bo  able  to  resist  at  least  a 
3C0-pount^  (136  kg)  impact.  An  important  consideration  in 
any  plant  ^nder  operating  conditions  is  the  use  of  rubber 
boots.  Th  i  rubber  boots  are  needed  when  handling  acid  or 
caustic,  or  when  the  operator  is  working  in  wet  conditions 
such  as  reservoirs,  filters  or  chemical  tanks.  Under  these 
circumstances,  the  agency  should  have  an  adequate  supply 
of  boots  in  various  sizes.  If  these  conditions  are  something 
that  the  operator  is  exposed  to  daily  or  weekly,  the  agency 
should  give  the  operator  a  pair  of  boots  for  personal  use. 

454 


434  Safety 


20.75  Hand  Protection 

The  treatment  plant  operator's  hands  are  always  exposed 
to  hazards.  These  include  not  only  minor  scratches  or  cuts, 
but  also  exposure  to  chemicals  that  may  not  attack  immedi- 
ately. Some  compounds,  such  as  alum,  attack  the  skin 
slowly.  Because  there  is  no  immediate  pain,  you  may  think 
there  is  no  damage.  This  is  not  true;  the  attack  on  the  skin  is 
slow  and  may  cause  an  infection  at  a  later  date.  Therefore, 
when  handling  chemicals,  always  use  rubber  gloves.  As  part 
of  a  safety  package,  each  operator  should  be  issued  a  pair 
of  rubber  gloves  and  also  a  pair  of  leather  gloves.  These 
gloves  should  be  replaced  when  they  no  longer  provide  the 
necessary  protection. 

There  are  other  compounds  such  as  solvents  th&i  will 
absorb  through  the  skin  and  can  cause  long-term  effects. 
For  such  special  problems,  there  is  a  need  for  neoprene 
gloves.  Another  problem  is  that  of  handling  hot  materials, 
such  as  laboratory  flasks  and  beakers.  Here  you  may  need 
asbestos  fabnc  gloves.  When  wc  ng  around  machinery 
that  IS  revolving,  wea.ing  gloves  or  other  hand  protection 
can  be  dangerous.  If  a  glove  gets  caught  in  the  machinery, 
you  could  become  injured.  Don't  let  your  protective  equip- 
ment itself  become  a  hazard. 

Be  sure  that  t^^e  gloves  you  are  wearing  are  the  right  type 
for  the  job  you  are  doing.  The  gloves  should  allow  for  quick 
removal  and  be  in  good  condition.  Always  check  for  cracks 
and  holes,  flexibility  and  gnp.  Keep  them  clean  and  in  good 
condition.  Theie  are  many  types  of  gloves  and  the  proper 
type  should  be  wom  for  each  job. 

1.  CLOTH  GLOVES  protect  from  general  wear.,  dirt,  chaf- 
ing, abrasions,  wood  slivers  and  low  heat. 

2.  LEATHER  GLOVES  protect  from  sparks,  chips,  rough 
material  and  moderate  heat. 

3.  RUBBER  GLOVES  protect  against  acids  and  some 
chemical  burns. 

4.  NEOPRENE  AND  CORK-DIPPED  GLOVES  give  better 
grip  on  slippery  or  oii/  jobs. 

5.  ASBESTOS  OR  ALUMINIZED  GLOVES  are  heat-resist- 
ant to  protect  against  sparks,  flames  and  heat. 

6.  METAL  MESH  GLOVES  protect  from  cuts,  rough  mate- 
rials and  blows  from  edge  tools. 

7.  PLASTIC  GLOVES  protect  from  chemicals  and  corro- 
sive substances. 

8.  INVISIBLE  GLOVES  (barrier  creme)  protect  fronr.  exces- 
sive water  contact  and  from  substances  which  dissolve 
in  skin  oil. 

20.76  Head  Protection 


In  most  areas  of  a  water  treatment  plant,  there  is  really  no 
need  for  a  hard  hat.  However,  there  are  certain  hazardous 
conditions  under  which  the  operators  should  be  required  to 
wear  a  metal,  plastic-impregnated  fabric,  or  fiberglass  hat. 
The  hard  hat  should  have  a  suspended  crown  with  an 
adjustable  head  band;  provide  good  ventilation;  and  be 
water  resistant.  Operators  should  be  required  to  wear  the 
hard  hats  when  work  is  being  performed  overhead,  or  in  any 
location  where  .here  is  danger  of  tools  or  other  materials 
falling,  for  example,  working  in  filters,  settling  basins  or 
trenches.  There  has  been  a  long  history  showing  the  value 
of  hard  hats  in  reducing  injuries  and  death. 

20  J7  Water  Safety 

Every  operator  in  a  treatment  plant  is  exposed  to  situa- 
tions in  which  the  operator's  life  can  be  lost  due,  either 
directly  or  indirectly,  to  water.  Although  dunng  you.  daily 
activity  you  may  never  think  in  terms  of  drowning,  this 
hazard  is  always  present  in  the  treatment  plant.  If  you  are 
working  at  a  reservoir  or  a  lake  in  a  boat,  you  may  think  of 
water  safety,  but  still  never  pay  real  attention  to  the  danger. 

Starting  at  the  treatment  plant,  you  can  take  simple 
measures  that  will  reduce  hazards.  To  reduce  the  hazard  of 
slipping  when  working  around  clarifiers  or  settling  basins, 
use  non-skid  surfaces  on  ladders  and  walkways  going  into 
and  out  of  clanfiers  or  sedimentation  basins.  Be  very  cau- 
tious during  cold  or  wet  weather.  Water  freezes  into  ice 
which  is  slippery. 

Keep  all  handrails  or  other  guards  m  good  repair;  replace 
any  that  become  unsafe.  Many  older  plants  do  not  have 
protective  handrails;  install  rails  or  chain  off  the  unsafe  area 
to  a.i  employees  and  mark  off  with  warning  signs.  The 
unsafe  areas  can  be  guarded  with  %-inch  (9  mm)  manila 
rope,  chains  or  cables  thai  you  may  have  around  the  plant. 

Filters  are  an  important  area  of  safety  consideration 
because  there  is  always  activity  in  or  around  each  filter,  such 
as  washing  or  maintenance.  Here  you  should  make  repairs 
to  handrails  immediately  when  needed.  Station  emergency 
gear  around  the  filter  areas;  equipment  such  as  life  jackets 
are  good,  but  buoys,  Ve-inch  (9  mm)  manila  line  or  a  long 
wooden  pole  are  much  more  useful.  These  types  of  devices 
can  be  used  to  rescue  someone  who  has  fallen  into  the  filter. 
An  operator  should  never  work  m  the  filte  when  it  is  being 
backwashed.  There  is  always  the  danger  of  falling  into  the 
washwater  gullet  and  being  unable  to  get  out  before  drown- 
ing. 

Sedimentation  basins,  flocculation  basins  or  clarifiers 
present  many  of  the  same  problems  as  filters.  Maintain 
handrails,  place  warning  signs  or  put  up  guard  ropes  or 
chains.  Also  keep  life  nngs  and  manila  or  nylon  lines  in  good 
repair.  A  lift  ring,  life  pole  and  lines  should  be  stationed  at 
each  basin.  A  good  idea  Is  to  shelter  the  safety  gear  from  the 
weather,  but  do  not  cause  the  gear  to  become  Inaccessible. 

In  reservoir  operation  and  maintenance  you  will  encounter 
two  types  of  water:  (1)  raw  water  and  (2)  treated  water.  In  a 
raw  water  reservoir  or  lake,  you  have  to  worry  only  about 
personnel  safety.  In  a  treated  water  rebsr  /oir,  you  must  also 
be  concerned  about  the  safety  of  the  v.'ater  going  to  the 
customer.  If  you  are  working  out  oi  a  boat,  make  sure  that 
everyone  in  the  boat  is  wearing  a  life  jacket.  Also  take  on 
board  both  a  safety  line  and  buoys.  Cold  weather  conditions 
are  an  added  problem.  Even  though  you  may  be  a  good  or 
excellent  swimmer,  the  thermal  shock  of  cold  water  may 
quickly  paralyze  you,  making  you  unable  to  save  yourself. 
Under  such  conditions,  if  a  second  operator  goes  into  the 
water  to  save  you,  there  may  be  two  lives  lost. 


455 


Water  Treatment  435 


Of  course,  vjhen  taking  a  boat  out  on  the  water  it  should 
first  be  checked  out  for  safety.  Check  the  bilge  pump, 
ventilation  in  the  compartments,  the  safety  cushions,  fire 
extinguishers,  battery  and  the  engine.  Also  check  for  safety 
equipment,  life  jackets,  lights,  mooring  lines  and  fuel.  If )  m 
are  applying  copper  sulfate  powder  or  solution,  other  safeiy 
equipment  will  be  needed,  such  as  respiratory  and  eye 
protection  equipment.  Prepare  a  de*  iled  equipment  check- 
list to  use  each  time  the  boat  goe..  out  onto  the  lake  or 
reservoir.  The  boat  should  never  be  taken  out  on  choppy 
waters  or  when  the  wind  is  high. 

On  some  occasions,  there  is  a  need  for  underwater 
examination  of  valves,  intake  or  other  underwater  equip- 
ment or  apparatus.  Such  work  should  only  be  performed  by 
employees  who  are  trained  in  underwater  diving.  If  there  are 
no  qualified  divers  on  your  staff,  you  should  hire  such 
personnel  to  do  the  diving  and  underwater  inspections. 
There  are  organizations  with  people  who  do  this  type  of 
work  and  they  are  well  qualified  in  underwater  examinations. 
If  an  operator  on  staff  is  to  do  the  diving,  the  operator  should 
be  certified  by  a  local  diving  school  or  other  certifying 
agency.  The  operator's  certificate  should  always  be  kept 
current  and  the  operator  should  be  required  to  perform  the 
number  of  dives  necessary  to  keep  this  certification  current. 


In  closing,  all  plant  operators  should  know  how  to  swim.  If 
they  do  ne»,  they  should  take  a  Red  Cross  class  and  learn 
the  minimum  fundamentals  to  save  their  own  lives.  Any 
operator  working  over  open  water  should  be  required  to 
wear  a  buoyant  vest.  All  basins  should  have  approved  safety 
vests,  buoys  and  life  lines  stationed  at  outside  edges. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  .vitn  those  on  page  440. 

20.7F  Under  what  operating  conditions  should  an  operator 
wear  rubber  boots? 

2C.7G  Under  what  specific  conditions  should  an  operator 
be  very  careful  wearing  gloves? 

20.7H  Why  should  operators  never  work  in  a  filter  when  it  is 
being  backwashed? 

20,71   W^^'"*  Items  should  be  checked  before  an  operator 
takes  a  boat  out  in  the  water? 


20,8   PREPARATION  FOR  EMERGENCIES^ 

Emergencies  are  very  difficult  to  plan  and  prepare  for 
because  you  never  know  what  will  happen  and  when  it  will 
occur.  Catastrophic  events  could  include  floods,  tornados, 
hurricanes,  fjres  and  earthquakes.  Serious  injunes  to  any- 
one on  the  plant  grounds  is  an  emergency. 

Conduct  penodic  tours  of  your  facilities  with  the  local  fire, 
police  and  emergency  response  organizations  to  familianze 
them  with  the  site,  potentially  hazardous  locations,  and 
location  of  fire  hydrants  will  be  very  helpful  if  an  emergency 
ever  occurs.  Emphasize  to  these  people  that  if  a  disaster 
occurs,  how  important  it  is  for  your  plant  to  be  a  top  prionty 
for  assistance  because  the  entire  community  relies  on  you 
for  Its  dnnking  water. 

You  should  know  the  names  and  phone  numbers  of  your 
local  and  state  civil  preparedness  coordinators. 

If  a  chemical  emergency  occurs  such  as  a  chemical  spill, 
leak,  fire,  exposure,  or  accident,  phone  CHEMTREC,  800- 
424-9300.  CHEMTREC.  (Chemical  Transportation  Emergen- 
cy Center)  provides  immediate  advice  for  those  at  the  scene 
of  a  chemical  emergency,  and  then  quickly  and  promptly 
alerts  experts  from  the  manufacturers  whose  products  are 
involved  for  more  detailed  assistance  and  appropriate  follow 
up 

Prepare  a  procedure  for  quick  and  efficient  handling  of  all 
accidents  or  injuries  occurring  in  your  treatment  facilities 
and  your  outside  crews.  All  personnel  must  be  familiar  with 
these  procedures  and  must  be  prepared  to  carry  them  out 
with  a  minimum  amount  of  delay  or  confusion. 

A  copy  of  these  procedures  must  be  posted  in  all  working 
areas  accessible  to  a  phone  and  in  all  vehicles  containing 
work  crews.  Names,  addresses  and  phone  numbers  of 
operators  in  each  working  area  should  be  listed  in  that  area 
and  e.so  those  immediately  available  (day  or  night)  by 
telephone. 

Everyone  must  study  these  procedures  carefully  and  be 
able  to  respond  properly  and  quickly.  Your  health  and  life 
may  depend  on  these  proceduies. 

Table  20.7  is  an  example  of  a  typical  safety  procedure  and 
Table  20.8  is  a  checklist  of  what  must  be  done  if  someone  is 
seriously  injured. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  tho5e  on  page  441. 

20.8A  What  types  of  emergencies  should  operators  be 
prepared  to  handle? 

20  8B  Who  should  be  contacted  if  a  serious  chc.iical 
emergency  occurs  such  as  a  chemical  spill,  leak,  fire, 
exposure  or  accident? 

20.9   ARITHMETIC  ASSIGNMENT 

Turn  to  the  Appendix  at  the  back  of  this  manual  and  read 
Section  A.36,  "Safety."  Work  the  example  problems  on  your 
electronic  pocket  calculator.  You  should  be  able  to  get  the 
same  answers. 


7  Some  of  the  information  in  this  section  was  provided  by  M  Richard  9  Metcaif.  Training  Officer,  County  of  Onondaga,  New  York 

Er|c  456 


TABLE  20.7   EMERGENCY  SAFETY  PROCEDURE 


1 .  DO  NOT  MOVE  THE  INJURED  PERSON 

except  when  conditions  would  cause  additional  injury, 
such  as  a  gas  leak  or  a  fire. 

2.  ADMINISTER  ONLY  SUCH  AID  AS  NECESSARY  TO 
PRESERVE  LIFE  —  TREAT  FOR  SHOCK 

(a)  clear  throat  and  restore  breathing 

(b)  stop  bleeding 

(c)  closed  heart  massage 

3.  DO  NOT  ATTEMPT  MEDICAL  TREATMENT  such  as 

(a)  do  not  apply  splints  or  attempt  to  set  broken  bones 

(b)  do  not  remove  foreign  objects  from  the  body 

(c)  do  not  administer  liquids  or  oxygen 

4.  NOTIFY  YOUR  SUPERVISOR 

IF  AN  AMBULANCE  IS  REQUIRED: 

1.  CALL  AMBULANCE  —  phone  

2.  Give  this  information  carefu;*y  and  accurately: 

(a)  Location  of  the  injured  —  be  specific. 

1.  Street  location  and  number.  Town  or  City 
"Remember  some  streets  have  north  or  south 
or  east  or  west  designation  —  use  the  full  street 
name.  Also,  many  streets  in  different  towns 
have  the  same  name  —  specify  the  Town. 

2.  Location  within  the  Plant  area 

(b)  Phone  number  from  whicn  you  are  calling 

(c)  Number  of  persons  Injured  and  nature  of  the  injury 

(d)  Post  an  operator  to  direct  the  ambulance  to  the 
victim 

3.  Upon  arrival  of  the  ambulance: 

(a)  give  name,  address  and  phone  number  of  the 
irjured  person  to  the  ambulance  crew 

(b)  notify  relatives  of  injury  and  hospital  to  which 
person  is  being  taken 

(Medical  treatment  cannot  be  given  witnout  the 
permission  of  the  injured  or  a  relative,  if  a  minor) 

4.  Call  your  supervisor 

IF  AN  AMBULANCE  IS  NOT  REQUIRED: 

1.  Take  Injured:  (see  map)  (Phone  ,^ 

ask  for  Emergency  Room) 

Emergency  Room 
St.  Joseph's  Hospital 
301  Prospect  Avenu^ 

2.  If  possible,  call  ahead,  ^ive  the  nances  of  injured  and 
nature  of  injury. 

3.  Notify  relatives  of  injury  and  address  of  hospital 

4.  Call  your  supervisor 


ERIC 


TABLE  20.8   INJURED  PERSON  CHECKLIST 

1.  CALL  AMBULANCE  SERVICE,  Phone  

LOCATION  OF  INJURED  

STREET 

TOWN 

BUILDING  LOCATION 
PHONE  NUMBER 

NUMBER  OF  PERSONS  INJURED  

NATURE  OF  INJURY  

2.  POST  OPERATOR  TO  DIRECT  THE  AMBULANCE 
NAME,  ADDRESS,  PHONE  OF  INJURED  PERSON 

NAME^  

ADDRESS  


PHONE  ^  

3.  GIVE  ABOVE  INFORMATION  TO  AMBULANCE  CREW 
NAME  AND  LOCATIOi^j  OF  HOSPITAL 

HOSPITAL  NAME  

ADDRESS  


PHONE  

4.  NOTIFY  RELATIVES 

5.  NOTIFY  SUPERVISORS 

6.  MAKE  OUT  ACCIDENT  REPORT  AS  rjQON  AS 
POSSIBLE 


438  Water  Treatment 


SUGGESTED  ANSWERS 

Chapter  20.  SAFETY 


ANSWERS  TO  QUESTIONS  IN  LESSON  1 

Answers  to  questions  on  page  394. 

20.0A  A  safety  officer  should  evaluate  every  accident,  offer 
recommendations,  and  keep  and  apply  statistics 

20  OB  The  supervisors  should  be  responsible  for  the  imple- 
mentation of  a  safety  program. 

20.0C  Both  state  and  federal  regulatory  agencies  enforce 
the  OSHA  requirements. 

20.0D  Each  utility  should  develop  a  policy  statement  on 
safety,  giving  its  objective  concerning  the  operator's 
welfare.  The  statement  sho'jid  be  brief,  but  give  the 
utility's  recognition  of  the  need  for  safety  to  stimulate 
efficiency,  improve  service,  improve  morale  and  to 
maintain  good  public  relations.  The  policy  should 
recognize  the  human  factor  (the  unsafe  act),  and 
emphasize  the  operator's  responsibility.  The  opera- 
tors should  be  provided  with  proper  equipment  and 
safe  working  conditions.  Finally,  the  policy  must 
reinforce  the  supervisory  respop-^ibility  to  maintain 
safe  work  practices. 

Answers  to  questions  on  page  395. 

20.0E  A  supervisor  may  be  responsible,  in  part  or  corr:- 
pletely,  for  an  accident  by  causing  unsafe  acts  to 
take  place,  by  requiring  that  work  be  performed  in 
haste,  by  disregarding  an  unsafe  environment  of  the 
work  /'ace,  or  by  failing  to  consider  any  number  of 
safety  hazards. 

20.0F  Each  operator  must  accept,  at  least  in  part,  responsi- 
bility for  fellow  operators,  for  the  utility's  equipment, 
for  the  operator's  own  v/elfare,  and  even  for  seeing 
that  the  supervisor  complies  with  establishea  safety 
regulations. 

20.0G  First  aid  means  emergency  treatment  for  injury  or 
sudden  illness,  before  regular  medical  treatment  is 
available. 

20.0H  First  aid  training  is  most  important  for  operators  who 
regularly  work  with  electrical  equipment  and  those 
who  must  handle  chlorine. 

Answers  to  questions  on  page  399. 

20.01  The  mainstay  of  a  safety  program  is  the  method  of 
reporting  and  keeping  statistics. 

20  OJ  Even  a  minor  injury  should  be  reported  because  it 
may  be  difficult  at  a  later  date  to  prove  the  accident 
occurred  on  the  job  in  order  to  have  the  utility  accept 
the  responsibility  for  costs. 

20.0K  A  safety  officer  should  review  an  accident  report 
form  tod)  determine  corrective  actions  and  (2)  make 
recommendations. 

20.0L  A  new  Inexperienced  operator  must  receive  instruc- 
tion on  all  aspects  of  plant  safety.  This  training 
includes  Instruction  in  the  handling  of  cnemicals,  the 
dangers  of  electrical  apparatus,  fire  hazards,  and 
proper  maintenance  of  equipment  to  prevent  acci- 
dents. Special  instructions  are  required  for  specific 
work  environments  such  as  manholes,  gases  (chlo- 


rine and  hydrogen  sulfide  (HpS)),  wa^ir  safety,  and 
any  specific  »-dzards  that  are  unique  to  your  facility. 
All  new  operators  should  be  subjected  to  a  safety 
orientation  program  during  the  first  few  days  of 
employment,  and  an  overall  training  program  in  the 
first  few  months. 

20  OM  If  an  operator  Is  unsure  of  how  to  perform  a  job,  then 
it  is  the  operator's  responsibility  to  ask  for  the 
training  needed. 

Answers  to  questions  on  page  401. 

20.0N  Statistical  accident  reports  should  contain  accident 
statistics  showing  lost  time,  costs,  type  of  injuries 
and  other  data,  based  on  some  time  interval. 

20  OO  Injuries  can  be  classified  as  fractures,  burns,  bites, 
eye  injuries,  cuts  and  bruises. 

20.0P  Causes  of  injuries  can  be  classified  as  heat,  machin- 
ery, falling,  handling  chemicals,  unsafe  acts  and 
miscellaneous. 

20.0Q  Costs  of  accidents  can  be  classified  as  lost  time  lost 
doMars,  lost  production,  contaminated  water  or  any 
other  means  of  showing  the  effects  of  the  accidents 

ANSWERS  TO  QUESTIONS  IN  LESSON  2 

Answers  to  questions  on  page  405. 

201  OA  An  operator  needs  to  know  how  to  handle  the 
problems  associated  with  the  chemicals  used  in  a 
water  treatment  plant.  The  operator  needs  to  know 
how  to  store  chemicals,  the  fire  problem,  the  ten- 
dency to  "arch"  in  a  storage  bin,  how  to  feed  dry, 
1-  ow  to  feed  liquid,  and  how  to  make  up  solutions. 
Overheating  gas  containers,  dust  problems  with 
powdered  carbon,  burns  caused  by  acid,  reactivity 
of  each  chemical  under  a  variety  of  conditions  that 
may  cause  fire  and  explosions  are  other  safety 
hazard.*;  that  an  operator  needs  to  know  about  and 
know  how  to  control.  Also,  the  operator  .leeds  to 
know  the  usable  limits  because  of  toxicity,  the 
Protective  equipment  required  for  each  chemical, 
each  chemical's  antidote,  and  how  to  control  fires 
caused  by  each  chemical. 

20.11  A  To  give  first  aid  vhen  acid  vapors  are  inhaled, 
remove  the  victim  to  fresh  air,  restore  breathing,  or 
give  oxygen  when  necessary. 

2011B  Acetic  acid  will  react  violently  with  ammonium  ni- 
trate, potassium  hydroxide  and  other  alkaline  mate- 
rial. 

20  lie  Acetic  acid  can  be  handled  safely  the  operator 
uses  adequate  ventilation  and  prevents  skin  and 
eye  contact. 

20.1  ID  When  handling  hydrofluosilicic  acid,  always  use 
complete  protective  equipment  including  rubber 
gloves,  goggles  or  face  shield,  rubber  apron,  rub- 
ber boots  and  have  lime  slurry  barrels,  epsom  salt 
solution  and  safety  showers  available.  Always  pro- 
vide adequate  ventilation. 

20  1 1 E  Inhalation  of  hydrochloric  (HCI)  vapors  or  mists  can 
cause  damage  to  teeth  and  irritation  to  the  nasal 


ERIC 


453 


438  Water  Treatment 


SUGGESTED  ANSWERS 

Chapter  20.  SAFETY 


ANSWERS  TO  QUESTIONS  IN  LESSON  1 

Answers  to  questions  on  page  394. 

20.0A  A  safety  officer  should  evaluate  every  accident,  offer 
recommendations,  and  keep  and  apply  statistics 

20  OB  The  supervisors  should  be  responsible  for  the  imple- 
mentation of  a  safety  program. 

20.0C  Both  state  and  federal  regulatory  agencies  enforce 
the  OSHA  requirements. 

20.0D  Each  utility  should  develop  a  policy  statement  on 
safety,  giving  its  objective  concerning  the  operator's 
welfare.  The  statement  sho'jid  be  brief,  but  give  the 
utility's  recognition  of  the  need  for  safety  to  stimulate 
efficiency,  improve  service,  improve  morale  and  to 
maintain  good  public  relations.  The  policy  should 
recognize  the  human  factor  (the  unsafe  act),  and 
emphasize  the  operator's  responsibility.  The  opera- 
tors should  be  provided  with  proper  equipment  and 
safe  working  conditions.  Finally,  the  policy  must 
reinforce  the  supervisory  respop-^ibility  to  maintain 
safe  work  practices. 

Answers  to  questions  on  page  395. 

20.0E  A  supervisor  may  be  responsible,  in  part  or  corr:- 
pletely,  for  an  accident  by  causing  unsafe  acts  to 
take  place,  by  requiring  that  work  be  performed  in 
haste,  by  disregarding  an  unsafe  environment  of  the 
work  /'ace,  or  by  failing  to  consider  any  number  of 
safety  hazards. 

20.0F  Each  operator  must  accept,  at  least  in  part,  responsi- 
bility for  fellow  operators,  for  the  utility's  equipment, 
for  the  operator's  own  v/elfare,  and  even  for  seeing 
that  the  supervisor  complies  with  establishea  safety 
regulations. 

20.0G  First  aid  means  emergency  treatment  for  injury  or 
sudden  illness,  before  regular  medical  treatment  is 
available. 

20.0H  First  aid  training  is  most  important  for  operators  who 
regularly  work  with  electrical  equipment  and  those 
who  must  handle  chlorine. 

Answers  to  questions  on  page  399. 

20.01  The  mainstay  of  a  safety  program  is  the  method  of 
reporting  and  keeping  statistics. 

20  OJ  Even  a  minor  injury  should  be  reported  because  it 
may  be  difficult  at  a  later  date  to  prove  the  accident 
occurred  on  the  job  in  order  to  have  the  utility  accept 
the  responsibility  for  costs. 

20.0K  A  safety  officer  should  review  an  accident  report 
form  tod)  determine  corrective  actions  and  (2)  make 
recommendations. 

20.0L  A  new  Inexperienced  operator  must  receive  instruc- 
tion on  all  aspects  of  plant  safety.  This  training 
includes  Instruction  in  the  handling  of  cnemicals,  the 
dangers  of  electrical  apparatus,  fire  hazards,  and 
proper  maintenance  of  equipment  to  prevent  acci- 
dents. Special  instructions  are  required  for  specific 
work  environments  such  as  manholes,  gases  (chlo- 


rine and  hydrogen  sulfide  (HpS)),  wa^ir  safety,  and 
any  specific  »-dzards  that  are  unique  to  your  facility. 
All  new  operators  should  be  subjected  to  a  safety 
orientation  program  during  the  first  few  days  of 
employment,  and  an  overall  training  program  in  the 
first  few  months. 

20  OM  If  an  operator  Is  unsure  of  how  to  perform  a  job,  then 
it  is  the  operator's  responsibility  to  ask  for  the 
training  needed. 

Answers  to  questions  on  page  401. 

20.0N  Statistical  accident  reports  should  contain  accident 
statistics  showing  lost  time,  costs,  type  of  injuries 
and  other  data,  based  on  some  time  interval. 

20  OO  Injuries  can  be  classified  as  fractures,  burns,  bites, 
eye  injuries,  cuts  and  bruises. 

20.0P  Causes  of  injuries  can  be  classified  as  heat,  machin- 
ery, falling,  handling  chemicals,  unsafe  acts  and 
miscellaneous. 

20.0Q  Costs  of  accidents  can  be  classified  as  lost  time  lost 
doMars,  lost  production,  contaminated  water  or  any 
other  means  of  showing  the  effects  of  the  accidents 

ANSWERS  TO  QUESTIONS  IN  LESSON  2 

Answers  to  questions  on  page  405. 

201  OA  An  operator  needs  to  know  how  to  handle  the 
problems  associated  with  the  chemicals  used  in  a 
water  treatment  plant.  The  operator  needs  to  know 
how  to  store  chemicals,  the  fire  problem,  the  ten- 
dency to  "arch"  in  a  storage  bin,  how  to  feed  dry, 
1-  ow  to  feed  liquid,  and  how  to  make  up  solutions. 
Overheating  gas  containers,  dust  problems  with 
powdered  carbon,  burns  caused  by  acid,  reactivity 
of  each  chemical  under  a  variety  of  conditions  that 
may  cause  fire  and  explosions  are  other  safety 
hazard.*;  that  an  operator  needs  to  know  about  and 
know  how  to  control.  Also,  the  operator  .leeds  to 
know  the  usable  limits  because  of  toxicity,  the 
Protective  equipment  required  for  each  chemical, 
each  chemical's  antidote,  and  how  to  control  fires 
caused  by  each  chemical. 

20.11  A  To  give  first  aid  vhen  acid  vapors  are  inhaled, 
remove  the  victim  to  fresh  air,  restore  breathing,  or 
give  oxygen  when  necessary. 

2011B  Acetic  acid  will  react  violently  with  ammonium  ni- 
trate, potassium  hydroxide  and  other  alkaline  mate- 
rial. 

20  lie  Acetic  acid  can  be  handled  safely  the  operator 
uses  adequate  ventilation  and  prevents  skin  and 
eye  contact. 

20.1  ID  When  handling  hydrofluosilicic  acid,  always  use 
complete  protective  equipment  including  rubber 
gloves,  goggles  or  face  shield,  rubber  apron,  rub- 
ber boots  and  have  lime  slurry  barrels,  epsom  salt 
solution  and  safety  showers  available.  Always  pro- 
vide adequate  ventilation. 

20  1 1 E  Inhalation  of  hydrochloric  (HCI)  vapors  or  mists  can 
cause  damage  to  teeth  and  irritation  to  the  nasal 


ERIC 


453 


Safety  439 


passages.  Concentrations  of  750  ppm  or  more  will 
cause  coughing,  choking  and  produce  severe  dam- 
age to  the  mucous  membranes  of  the  respiratory 
tract.  In  concentrations  of  1300  ppm,  HCI  is  danger- 
ous to  life. 

2011F  Nitric  acid  should  be  stored  in  clean,  cool,  well- 
ventilated  areas.  The  area  should  have  sn  acid- 
»'esistant  floor  and  adequate  drainage.  Keep  away 
from  oxidizing  agents  and  alkaline  materials.  Pro- 
tect containers  from  damage  or  breakage.  Avoid 
contact  with  skin  and  provide  emergency  neutral- 
ization materials  and  safety  equipment  in  use 
areas. 

Answers  to  questions  on  page  408. 

20  12A  Operators  use  two  forms  of  ammonia.  The  gaseous 
form  (anhydrous)  and  the  liquid  form  (hydroxide) 
are  used  by  operators. 

20.1 2B  Care  must  be  used  when  storing  or  transporting 
ammonia  containers.  Always  keep  cyliiiders  with 
caps  in  place  when  not  in  use.  S*ore  cylinders  In  a 
cool,  dry  location  away  from  haat  and  protect  from 
direct  sunlight.  Do  not  store  in  the  same  room  with 
chlorine. 

2C  2C  The  two  forms  of  lime  f^ed  in  water  treatmei^t 
plants  are  (1)  hydrated  lime  (calcium  hydroxide)  and 
(2)  quicklime  (calcium  oxide). 

20.12D  If  someone  swallowed  sodium  hydroxide,  give 
large  amounts  of  water  or  milk  and  immediately 
transport  t  >  a  medical  facility;  do  not  induce  vomit- 
ing. 

20.12E  If  sodium  silicate  comes  in  contact  with  your  skin, 
wash  thoroughly  with  water,  followed  by  washing 
with  a  1 0  percent  solution  of  ammonium  chloride  or 
10  percent  acetic  acid. 

Answers  to  questions  on  page  412. 

20.1 3A  Chlorine  leaks  are  most  often  found  in  the  control 
valve. 

20.13B  The  purpose  of  the  fusible  metal  plugs  is  to  melt  at 
158  to  168°F.  If  a  cylinder  becomes  overheated,  the 
plugs  will  melt  and  let  the  gas  escape  rather  than 
the  cylinder  bursting. 

20.13C  Chlorine  leaks  can  be  detected  by  the  odor,  by  the 
use  of  ammonia  water  on  a  small  cloth  or  swab  on  a 
stick,  or  by  the  use  of  an  aspirator  containing 
ammonia  water.  (Remember  not  to  spray  ammonia 
into  a  room  full  of  chlonne  because  a  white  cloud 
vvill  form  and  you  won't  he  able  to  see  anything.) 
A?so.  a  chlorine  gas  detec  *or  may  be  used. 

20.13D  Carbon  dioxide  is  a  safety  hazard  because  it  is 
0'*'''!ess.  colorless,  and  will  accumulate  at  the 
Ic  Bt  possible  level.  Carbon  dioxide  will  displace 
oxygen  so  you  must  use  a  self-contained  breathing 
apparatus. 

Answers  to  questions  on  page  414. 

20.1 4A  For  handling  most  ^^alts.  ventilation,  respiratory 
protection  and  eye  protection  will  prove  adequate. 

20.1 4B  First  aid  when  liquid  or  dry  alum  gets  into  the  eyes 
consists  of  flushing  them  immediately  *or  15  min- 
utes with  large  amounts  of  water.  Alum  should  be 
washed  off  the  skin  with  water  because  prolonged 
contact  will  cause  skin  irritation. 


20  14C  When  exposed  to  moist  atr  or  light,  ferric  chloride 
oecomposes  ani  gives  off  hydrochloric  acid. 

Answers  to  qu'  I'ons  on  page  415. 

20.15A  Potassium  pernrianganate  spills  can  be  swept  up. 
Flushing  with  water  is  ari  effective  way  to  eliminate 
spillage  on  floors. 

20  158  Powdered  activated  carbon  is  the  most  dangerous 
powder  the  water  treatment  plant  operator  will  be 
exposed  to. 

20.1 5C  Activated  carbon  should  be  stored  in  a  clean,  dry, 
fire-proof  location.  Keep  free  of  dust,  protect  from 
flammable  materials,  and  do  not  permit  smoking  in 
the  area  at  any  time  when  handling  or  unloading 
activated  carbon. 

20.1 5D  The  key  to  preventing  activated  carbon  fires  is 
keeping  the  storage  area  clean  and  free  of  dust. 

20.15E  Carbon  fires  should  be  controlled  by  carbon  dioxide 
(COj)  extinguishers  or  hoses  equipped  with  fog 
nozzles.  An  activated  carbon  fire  should  not  be 
doused  with  a  stream  of  water.  The  water  may 
cause  burning  carbon  particles  to  fly,  resulting  in  a 
greater  fire  problem. 

Answers  to  questions  on  page  415. 

20.1 6A  Safety  regulations  prohibit  the  use  of  common 
drains  and  sumps  from  chemical  storage  areas  to 
avoid  the  ^possibility  of  chemicals  reacting  and 
producing  toxic  gases,  explosions  and  fires. 

20.168  If  a  polymer  solution  comes  in  contact  with  potas- 
>ium  permanganate,  a  fire  could  devciOp. 

ANSWERS  TO  QUESTIONS  IN  LESSON  3 

Answers  to  questions  on  page  420. 

20.2A  Class  A  fires  involve  miscellaneous  combustible  ma- 
terials. These  include  fabrics,  paper,  weed,  dried 
grass,  hay  and  stubble. 

20.28  Foam  extinguishers  can  control  Class  A  and  Chss  B 
fires.  They  can  control  ordinary  combustit:les  ("A^ 
such  as  fabrics,  paper,  wood  and  grass,  as  well  as 
flammable  liquids  and  vapors  ("8^  such  as  oils, 
lacquers,  fats,  waxes,  paints,  petroleum  products 
and  gas. 

20.2C  An  electrical  fire  can  be  extinguished  by  the  use  of 
carbon  dioxide  (COj)  extinguishers  or  with  a  dry 
chemical  extinguisher. 

Answers  to  questions  on  page  421. 

20.3A  When  waxing  floors  use  compounds  containing 
nonslip  ingredients.  Warn  others  about  newly  waxed 
floors.  Try  to  do  cleaning  and  waxing  during  off-duty 
n^L?»'S,  weekends  or  at  night. 

20.3B  Rags  are  always  a  problem  and  if  they  contain  oils, 
paint  or  other  cleaning  compounds  there  is  always 
the  possibility  of  fire.  The  rags  should  be  placed  into 
a  closed  metal  container  to  reduce  the  fire  hazard. 

20.3C  When  operating  an  overhead  crane,  the  following 
safety  precautions  must  be  exercised: 

1.  Allow  only  trained  and  authorized  personnel  to 
operate  the  overhead  crane, 

2.  Inspectthe  circuit  breaker,  limit  switches,  condi- 
tion of  hook,  wire  rope  and  other  safety  devices, 

460 


440  Water  Treatment 


3.  Post  load  limit  on  crane  and  never  overload 
crane, 

4.  Check  each  lift  for  proper  balance, 

5.  Use  a  standard  set  of  hand  signals, 

6.  Be  sure  everyone  in  vicinity  wears  a  hard  hat, 

7.  Allow  only  authorized  personnel  to  make  re- 
pairs, 

8.  Lock  out  the  mam  power  switch  before  repairs 
begin, 

9  Try  to  avoid  moving  loads  over  populated  areas, 
aiid 

10.  Set  up  monthly  safety  inspection  forms  to  be 
filled  out  and  placed  into  the  maintenance  file. 

20  3D  Traffic  can  be  warned  that  operators  are  working  in  a 
"^nhole  by  the  use  of  barricades,  signs,  flags,  lights 
and  other  warning  devices.  Warning  devices  and 
procedures  must  conform  to  local  and  state  regula- 
tions. 

20.3E  Operators  should  always  use  a  mechanical  lifting  aid 
(rope  and  bucket)  for  raising  or  lowering  tools  and 
equipment  into  and  out  of  a  manhole.  The  use  of  a 
bucket  or  basket  will  keep  your  hands  free  when 
climbing  down  Into  or  out  of  a  manhole. 


Answers  to  questions  on  page  423. 

20.3F  Operators  should  wear  eye  and  ear  protection  when 
operating  grinding,  chipoing,  buffing,  or  pavement- 
breaking  equipment.  Sometimes  when  using  grind- 
ing or  buffing  tools,  operators  encounter  toxic  dusts 
or  fumes  and  therefore  need  respiratory  protection. 
At  other  times  there  is  a  need  for  full  face  protection 
because  of  flying  particles. 

20.3G  Operators  can  be  protected  from  high  noise  levels  by 
wearing  approved  ear  protection  devices. 

20.3H  When  operating  welding  equipment*  the  operator 
should  wear  protective  clothing,  gloves,  helmets  and 
goggles. 


Answers  to  questions  on  page  425. 

20.4A  Tire  wear  Is  caused  by  misalignment  and  low  infla- 
tion 

20.4B  fVlotor  vehicles  should  have  flashlights,  flares,  flags 
and  a  first  aid  kit. 


ANSWERS  TO  QUESTIONS  IN  LESSON  4 

Answers  to  questions  on  page  429. 

20.5A  Each  operator  should  become  familiar  with  the  type 
of  current  and  voltage  in  the  plant  in  order  to  avoid 
any  mistake  of  becoming  involved  with  unsafe  elec- 
trical circuits  or  practices  for  which  they  are  not 
trained.  This  will  also  permit  operators  to  ask  for  a 
qualified  person  to  perform  any  necessary  repairs. 

20  58  Moving  parts  on  electrical  motors  that  require  safety 
guards  include  exposed  couplings,  pulleys,  gears 
and  sprockets,  as  well  as  projections  such  as  bolts, 
keys,  or  set  screws. 

20.50  Two  hazards  due  to  the  lack  of  a  good  lockout 
procedure  for  control  panels  and  switchboards  are 
(1)  accidentally  startinp  a  piece  of  equipment  expos- 
ing a  fellow  operator  to  a  hazard,  and  (2)  turning 
electrical  power  on  when  someone  is  still  working  on 
the  equipment,  exposing  that  person  to  danger. 

ErJc  Sc'> 


Answers  to  questions  on  page  432. 

20  6A  Washing  glassware  is  always  a  potential  hazard 
because  the  glassware  can  be  broken  while  being 
washed,  causing  cuts,  or  cuts  can  be  caused  by 
chipped  or  cracked  glassware.  If  your  hands  come  in 
contact  with  strong  acir*  cleaners,  the  acids  may 
cause  serious  burns. 

20  6B  When  handling  liquid  chemicals  such  acids  and 
bases,  always  use  safety  glasses  or  face  shields. 

20  60  Never  allow  mercury,  gasoline,  oil  or  organic  com- 
pounds into  the  laboratory  drains.  Use  only  a  toxic 
waste  disposal  dram  system  for  these  items.  Letting 
such  compounds  down  sink  drains  can  cause  an 
explosion,  allow  toxic  gases  and  vapors  to  enter  the 
lab  or  destroy  the  piping. 

20.6D  The  plant  operator  may  be  exposed  to  radioactive 
compounds  when  calibrating  sludge  density  meters 
or  using  research  isotopes. 

20  6E  Never  allow  cold  water  into  the  hot  boiler  unit  of  a 
water  still  because  it  may  cause  the  unit  to  break. 


Answers  to  questions  on  page  433. 

20.7A  When  entering  an  oxygen-deficient  atmosphere,  you 
should  have  an  independent  oxygen  supply  of  the 
positive-pressure  type  to  protect  you  If  there  are  any 
leaks  In  your  mask. 

20.7B  Respiratory  apparatus  must  be  stored  outside  of 
chlorinating,  sulfur  dioxide,  carbon  dioxide,  ozone 
and  ammonia  rooms  in  an  unlocked  cabinet.  The 
storage  cabinets  must  have  a  controlled  environment 
to  prevent  deterioration  of  the  equipment. 

20  70  Independent  air  supply  equipment  should  be 
checked  out  on  a  weekly  basis,  and  records  kept  of 
each  inspection.  The  record  should  show  conditions 
of  the  hoses,  regulators,  air  filters,  compressors, 
helmet  and  any  other  apparatus  furnished  with  the 
system. 

20.7D  To  obtain  compliance  with  an  eye  protection  pro- 
gram, supervisors  should  undertake  an  intense  pro- 
gram of  education,  persuasion,  and  appeal. 

20  7E  An  operator  needs  eye  protection  when  handling 
many  of  the  liquid  chemicals,  acids  and  caustics. 
Many  of  the  tests  performed  in  the  laboratory  also 
require  eye  protection. 


Answers  to  questions  on  page  435. 

20  7F  Rubber  boots  are  needed  when  handling  acid  or 
caustic,  or  when  tne  operator  is  working  in  wet 
conditions  such  as  leservoirs,  filters  or  chemical 
tanks. 

20.7G  An  operator  should  be  very  careful  weanng  gloves 
when  working  around  machinery  that  is  revolving. 

20.7H  Operators  should  never  work  in  a  filter  when  it  is 
being  backwashed  because  there  is  always  the  dan- 
ger of  falling  Into  the  washwater  gullet  and  being 
unable  to  get  out  before  drowning. 

20  71  Before  taking  a  boat  out  on  the  water,  it  should  be 
checked  out  for  safety.  The  operator  should  check 
the  bilge  pump,  ventilation  in  tha  compartments,  the 
safety  cushions,  fire  extinguishers,  battery  and  the 
engine.  For  safety  equipment,  check  oars,  life  jack- 
ets, lights,  mooring  lines  and  fuel. 

461 


Safety  441 


Answers  to  questions  on  page  435. 

20.8A  Operators  should  be  prepared  for  catastrophic 
events  such  as  floods,  tornados,  hurricanes,  fires 
and  earthquakes.  Serious  injuries  to  anyone  on  the 
plant  grounds  Is  an  emergency. 


20.8B  If  a  senous  CMemjcal  emergency  occurs  such  as  a 
chemical  spill,  leak,  fire,  exposure,  or  accident, 
phone  CHEMTREC,  800-424-9300 


OBJECTIVE  TEST 

Chapter  20.  SAFETY 


Please  write  your  name  and  mark  the  correct  answers  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1.  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
questions. 

TRUE-FALSE 

1.  The  OSHA  Law  provides  for  civil  penalties  only. 

1.  True 

2.  False 

2.  Supervisors  can  prevent  .nost  accidents. 

1.  True 

2.  False 

3.  First  aid  training  will  prevent  accidents. 

1.  True 

2.  False 

4.  On-the-job  training  is  a  good  way  of  preventing  acci- 
dents for  an  inexperienced  operator. 

1.  True 

2.  False 

5.  Acetic  acid  exposure  must  oe  treated  immediately  to 
prevent  damage. 

1.  True 

2.  False 

6.  Potassium  permanganate  fires  should  be  extinguished 
with  water. 

1.  True 

2.  False 

7  Some  weak  bases  will  attack  human  tissue  very  rapidly 
and  cause  burns. 

1.  True 

2.  False 

8.  Bases  mjst  be  neutralized  with  dilute  acids. 

1.  True 

2.  False 

9.  Ammonia  gas  is  capable  of  forming  explosive  ixtures 
v/ith  air. 

1.  True 

2.  False 


10  Never  neutralize  ammonia  with  an  acid. 

1.  True 
2  False 

11.  Quicklime  is  less  caustic  than  hydrated  lime. 

1.  "Trge 

2.  raise 

1 2.  When  quicklime  is  mixed  with  water,  a  great  deal  o^  heat 
IS  generated  and  explosions  can  occur. 

1.  True 

2.  False 

13.  The  loss  of  water  supply  to  a  lime  slaker  can  create 
explosive  temperatures. 

1.  True 

2.  False 

14.  The  storage  area  for  chlorine  cylinders  must  have  force- 
exhaust  ventilation. 

1.  True 

2.  False 

15.  Never  use  an  open  flame  on  cylinders  or  pipes  carrying 
chlorine. 

1.  True 

2.  False 

16.  All  safety  equipment  should  be  located  inside  the  chlo- 
rination  room. 

1.  True 

2.  False 

17.  First  aid  for  a  sulfur  dioxide  victim  is  similar  for  the 
victim  of  any  acid  injury. 

1.  True 

2.  False 

18.  Never  use  the  same  conveyor  for  quicklime  and  alum. 

1  True 
2.  False 


19.  Ferric  chlonde  is  an  acid. 

1.  True 

2.  False 


462 


442  Water  Treatment 


20  Ferric  chloride  should  be  treated  as  you  would  treat  any 
acid. 

1.  True 

2.  False 

21.  Activated  carbon  burns  without  smoke  or  visible  flame 

1.  True 

2.  False 

22.  Explosion-proof  lighting  must  be  used  in  paint  booths, 

1.  True 

2.  False 

23.  Never  use  compressed  air  to  clean  off  your  clothing  or 
Darts  of  your  body. 

1.  True 

2.  False 


24.  Never  look  at  a  welding  operation  without  eye  protec- 
tion. 

1.  True 

2.  False 


25.  Chlorine  may  be  the  only  chemical  used  in  a  simple  well 
system. 

1.  True 

2.  False 


26.  A  special  insulated  mat  should  be  used  on  the  floor  at  all 
switch  boards. 

1.  True 

2.  False 

27.  Badly  worn  electrical  cords  should  be  used  only  in  wet 
locations. 

1.  True 

2.  False 


28.  In  the  laboratory,  broken  glass  should  be  disposed  of  in 
wastebaskets. 

1.  True 

2.  False 

29.  Always  pour  acid  into  water,  nevf^--  the  reverse. 

1.  True 

2.  False 


30.  Never  enter  a  confined  space  with  an  explosive  atmos- 
phere. 

1.  True 

2.  False 


MULTIPLE  CHOICE 

31.  A  safety  officer  should  be  responsible  for 

1.  Applying  accident  statistics. 

2.  Evaluating  every  accident. 

3.  Implementing  safety  program. 

4.  Keeping  accident  statistics. 

5.  Offering  recommendations. 


32.  A  routine  OSHA  violation  could  cost  an  employer  up  to 
 for  each  violation. 

1.  $1000 

2.  $2500 

3.  $5000 

4.  $7500 

5.  $10,000 

33.  A  supervisor  could  be  responsible  for  an  accident,  in 
part  or  complete,  by 

1.  Causing  unsafe  acts  to  take  place. 

2.  Disregarding  an  unsafe  work  environment. 

3.  Overlooking  a  potential  hazard. 

4.  Requiring  operators  to  attend  safety  meetings. 

5.  Requiring  work  to  be  performed  in  haste. 

34.  A  review  of  accident  causes  shows  that  the  accident 
victim  often  has  not 

1.  Accepted  any  responsibility  for  the  safety  program. 

2.  Acted  responsibly. 

3.  Been  concerned  about  fellow  operators. 

4  Been  fully  aware  of  the  working  conditions. 
5.  Complied  with  the  safety  regulations. 

35.  Tailgate  safety  meetings  should  be 

1.  Held  where  distractions  can  be  avoided. 

2.  Held  where  everyone  can  hear. 

3.  Held  in  an  auditorium. 

4.  Kept  short. 

5  Scheduled  in  a  suitable  location. 

36.  Hydrofluosilicic  acid  is 

1.  Corrosive. 

2.  Fuming. 

3.  Pungent. 

4.  Transparent. 

5.  Yellow. 

37.  Hydrochloric  acid  is  highly  reactive  with 

1.  Amine. 

2.  Carbonate. 

3.  Glass. 

4.  Metals. 

5.  Porcelain. 

38.  Nitric  acid 

1.  Attacks  glass. 

2.  Attacks  most  metals. 

3.  Forms  fumes  in  the  presence  of  light. 

4.  Is  a  powerful  reducing  agent. 

5.  Is  unstable  even  when  properly  handled. 

39.  Sulfuric  acid  may  be  contained  in  -lined  contain- 
ers. 

1.  Glass 

2.  Metal 

3.  Plastic 

4.  Rubber 

5.  Wooden 

40.  The  most  common  strong  bases  are  compounds  of 

1.  Ammonia. 

2.  Calcium. 

3.  Carbonate. 

4.  Hypochlorite. 

5.  Sodium. 


ERLC 


463 


Safety  443 


41 .  Sodium  hydroxide 

1.  Absorbs  carbon  dioxide  from  the  air. 

2.  Causes  heat  when  mixed  with  water. 

3.  Dissolves  human  skin. 

4.  Is  used  to  neutralize  lime. 

5.  Is  very  hazardous  to  the  operator. 

42.  Dissolving  sodium  hydroxide  in  water 

1  Causes  splintering. 

2.  Develops  sludges. 

3.  Generates  excessive  heat. 

4.  Lowers  pH. 

5.  Proajces  mists. 

43.  Types  of  hypochlorite  compounds  used  in  water  treat- 
ment plants  include 

1  Calcium. 

2.  Iron. 

3.  Lithium 

4.  Magnesium. 

5.  Sodium. 

44.  Chlorine  cylinders  may  be  lifted  using 

1.  Cableo. 

2.  Chains. 

3.  Clamps. 

4.  Cradles. 

5.  Ropes. 

45.  Chlorine  cylinders  should  be  stored 

1,  Below  ground  level. 

2  In  a  clean,  dry  location. 
3.  On  their  sides. 

4  So  they  cannot  fall. 

5.  With  the  protective  cap  off. 

46.  Improper  handling,  storing  or  preparing  solutions  of 
chemicals  can  cause 

1.  Burns. 

2.  Cost  savings. 

3.  Explosions. 

4.  Illness 

5.  Loss  of  eyesight. 

47.  The  most  dangerous  powder  the  water  treatment  plant 
operator  could  be  exposed  to  is 

1.  Alum. 

2.  Calcium  carbonate. 

3.  Potassium  permanganate. 

4.  Powdered  activated  carbon. 

5  Quicklime. 

48.  The  operator's  BEST  fire  protection  or  prevention  is 

1.  Anr-'^lly  making  a  fire  analysis  of  plant. 
2  Good  housekeeping. 

3.  Properly  locating  fire  extinguishers 

4.  Providing  suitable  containers  for  used  wiping  cloths 

5.  Removal  of  fire  hazards. 

49.  Class  A  fires  involve 

1.  Electrical  equipment. 

2.  Fabrics. 

3.  Oils. 

4.  Paints. 

5.  Sodium. 


50.  Hazardous  atmospheric  conditions  that  may  be  encoun- 
tered in  manholes  include 

1  Hyd'-ogen  sulfide. 
2.  Insufficient  oxygen. 
3  Methane. 

4.  Natural  gas 

5.  Nitrogen. 

51.  Which  of  the  following  rules  apply  to  the  operation  of 
gas  or  electric  welding  equipment'^ 

1.  Adequate  fire  protection  must  be  provided. 

2.  Have  a  buddy  observe  your  performance. 

3.  Operators  must  be  thoroughly  trained. 

4.  Protection  of  other  personnel  must  be  provided  and 
used. 

5  Work  during  regular  hours  only. 

52.  Types  of  safety  valves  in  a  water  treatment  Diant  that 
should  be  inspected  and  maintained  on  a  regular  basis 
include: 

1  Butterfly  valves. 

2.  Chlorine  relief  valves 

3.  Gate  valves. 

^.  Surge  relief  valves. 

5.  Water  heater  valves. 

53  What  safety  precautions  must  be  exercised  around 
vehicle  wash  and  steam  cleaning  areas? 

1.  Always  use  scaffolding  or  platforms  when  cleaning 
the  tops  of  vehicles. 

2  Check  level  of  water  on  coils  before  turning  on 
steam. 

3.  Eye  and  face  protection  is  not  necessary. 

4.  Keep  the  steam  nozzle  clean. 

5.  Keep  the  wash  rack  free  from  oil  and  yrease. 

54.  Good  drivers 

1.  Always  observe  traffic  regulations 

2  Check  out  their  vehicles  each  time  they  use  thern. 

3  Drive  defensively. 

4.  Operate  vehicles  as  if  all  other  drivers  are  the  world's 

worst  drivers. 
5  Use  proper  signals  for  directional  change. 

55  When  safely  operating  a  forklift,  be  sure  to 

1.  Always  face  the  direction  of  travel. 

2  Check  warning  lights  for  proper  operation. 

3  Leave  the  power  on  when  leaving  the  forklift  to  keep 
the  battery  charged. 

4.  Never  overload  the  forklift. 

5.  Use  special  lifting  and  retaining  devices  when  han- 
dling drums. 

56,  The  purpose  of  most  transformers  where  power  enters 
a  water  treatment  plant  is  to 

1.  Decrease  electrical  resistance, 

2.  Detect  overheating. 

3.  Increase  the  electrical  voltage 

4.  Reduce  the  electrical  voltage. 

5.  Transform  low  voltage  to  high  voltage. 

57.  Hazardous  conditions  an  operator  may  encounter  in  the 
laboratory  include 

1.  Alkalies. 

2.  Distilled  water 

3.  Flammaole  chemicals. 

4.  Glassware. 

5.  Toxic  chemicals. 

464 


444  Water  Treatment 


58.  Toxic  chemicals,  acids  or  alkalis  can  be  transferred  with 
a  pipet  by  using 

1.  Aspirators. 

2.  Pumps. 

3.  Suction  bulbs. 

4.  Vacuum  lines. 

5.  Your  mouth. 

59.  Respiratory  hazards  in  and  around  the  treatment  plant 
that  operators  are  exposed  to  on  a  daily  basis  include 

1.  Acids. 

2.  Bases. 
3  Dusts. 


4.  Fumes. 

5.  Gases. 

60.  Types  of  gloves  that  an  operator  may  need  include 

1.  Asbestos  fabric. 

2  Cloth. 

3.  Leather. 

4.  Neoprene. 

5.  Rubber. 


ERIC 


405 


CHAPTER  21 

ADVANCED  LABORATORY  PROCEDURES 

by 

Jim  Sequeira 


446  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  21 .  Advanced  Laboratory  Procedures 

Page 

OBJECTIVES  447 

LESSON 

21.0  IJ'^e  of  a  Spectrophotometer  448 

21.1  Test  Procedures*    449 

1 .  Algae  Counts  449 

2.  Calcium   ,  45O 

3.  Chloride  45 -l 

4.  Color  453 

5.  Dissolved  Oxygen  454 

6.  Fluoride  457 


LESSON  2 

7.  Iron  (Total)  ^5^ 

8.  Manganese    453 

9.  Marble  Test  (Calcium  Carbonate  Stability  Te  >t)    466 

10.  Metals     467 

11.  Nitrate   ,  468 

12.  PH  471 

13.  Specific  Conductance  47-I 

14.  Sulfate  472 

15.  Taste  and  Odor  474 

16.  Trihalomethanes  479 

17.  Total  Dissolved  Solids  479 

Suggested  Answers  482 

Objective  Test   _  434 


''Test  Procedures  in  C^-nter  11  include  all(alinlty.  chlorine  residual,  chlorine  demand,  coliform  bacteria,  hardness,  is,  test,  pH, 
temperature  and  turbic 


467 


Lab  Procedures  447 


OBJECTIVES 

Chapter  21.   ADVANCED  LABORATORY  PROCEDURES 


Following  completion  of  Chapter  21 ,  you  should  be  able 
to: 

1.  Explain  how  a  spectrophotometer  analyzes  samples  of 
water,  and 


2.  Perform  the  following  field  or  laboratory  tests  algae 
counts,  calcium,  chloride,  color,  dissolved  oxygen,  flu- 
oride, iron,  manganese,  marble  test,  metals,  nitrate.  pH, 
specific  conductance,  sulfate,  taste  and  odor,  trihalo- 
methanes  and  total  dissolved  solids. 


448  Water  Treatment 


CHAPTER  21.   ADVANCED  LABORATORY  PROCEDURFS 

(Lesson  1  of  2  Lessons) 


21.0   USE  OF  A  SPECTROPHOTOMETER 

In  the  field  of  water  analysis,  many  determinations  such  as 
iron,  manganese,  and  phosphorus  are  based  on  the  color 
intern  .y  formed  when  a  specific  color  developing  reagent  is 
added  to  the  sample  being  tested.  Measuring  the  intensity  of 
the  color  enables  the  concentration  of  the  substance  to  be 
determined.  The  simplest  means  of  accomplishing  this  is 
through  either  nessler  tubes  or  a  pocket  comparator.  The 
color  developed  In  a  sample  is  compared  by  the  operator  to 
a  series  of  known  standards,  to  each  of  which  has  been 
added  the  bame  color  developing  reagents.  For  the  analysis 
of  phosphorus  present  in  a  water  sample,  for  example, 
ammonium  molybdate  reagent  is  added  as  the  color  devel- 
oping reagent.  If  phosphorus  is  present,  a  blue  color  devel- 
ops. The  more  phosphorus  there  is,  the  deeper  and  darker 
the  blue  color. 

The  human  eye  can  detect  some  differences  in  color 
intensity':  however,  for  very  precise  measurements  an  instru- 
ment called  a  spectrophotometer  (SPEK-tro-fo-TQI^-uh-tsr) 
is  used. 

THE  SPECTROPHOTOMETER.  A  spectrophotometer  is 
an  instrument  generally  used  to  measure  the  color  intensity 
of  a  chemical  solution.  A  spectrophotometer  m  its  simplest 
form  consists  of  a  light  source  which  Is  focused  on  a  prism 
or  other  suitable  light  dispersion  device  to  separate  the  light 
into  its  sepa'-aie  bands  of  energy.  Each  different  wave  length 
or  color  rnay  be  selectively  focused  through  a  narrow  slit. 
This  beam  of  light  then  passes  through  the  sample  to  be 
measured.  The  sample  is  usually  contained  in  a  glass  tube 
called  a  cuvette  (QUE-vet).  Most  cuvettes  are  standardized 
to  have  a  1.0  cm  light  path  length,  however  many  r*her  sizes 
are  available. 

After  the  selected  beam  of  light  has  passed  through  the 
sample,  it  emerges  and  strikes  a  photoelectric  cell.  If  the 
solution  in  the  sample  cell  has  absorbed  any  of  the  linht,  the 
total  energy  content  will  be  reduced.  If  the  solution  in  the 
sample  cell  does  not  absorb  the  light,  then  there  will  be  no 
change  in  energy.  When  the  transmitted  light  beam  strikes 
the  photoelectric  tube,  it  generates  an  electric  ci:rrent  that  is 
proportional  to  the  intensity  of  light  energy  striking  it.  By 
connecting  the  photoelectric  tube  to  a  galvanometer  (a 
device  for  measuring  electric  current)  with  a  graduated 
scale,  a  meins  of  measuring  the  intensity  of  the  transmitted 
beam  is  achieved. 

The  diagram  at  the  top  of  the  next  column  illustrates  the 
working  parts  of  a  spectrophotometer. 

The  operator  should  always  follow  the  working  instruc- 
tions provided  with  the  instrument. 

UNITS  OF  SPECTROSCOPIC  MEASUREMENT.  The 
scale  on  spectrophotometers  is  generally  graduated  in  two 
ways: 


Refracting 

Whxte 
light  source 


Sanple 

cuvette  Photo  _ 
electric 
Exit  tube 
slit 


Galvanometer 


(1)  in  units  of  percent  transmittance  (%T),  an  arithmetic 
scale  with  units  graded  from  0  to  100%;  and 

(2)  in  units  of  absorbance  (A),  a  logarithmic  scale  of 
nonequal  divisions  graduated  from  0.0  to  2,0. 

Both  the  units  percent  transmittance  and  absorbance  are 
associated  with  co*or  Intensity.  That  is,  a  sample  which  has  a 
low  color  intensity  win  nave  a  high  percent  transmittance  but 
a  low  absorbance. 


4p      so  60 


r     -3  -25  .2 


PERCENT  TRANSMITTANCE 

Absorbance 

As  illustrated  above,  the  absorbance  scale  is  ordinarily 
calibrated  on  the  same  scale  as  percent  transmittance  on 
spectrophotometers.  The  chief  usefulness  of  absorbance 
lies  in  the  fact  that  it  is  a  logarithmic  function  rather  than 
linear  (arithmetic)  and  a  law  known  as  Beer's  Law  states  that 
the  concentration  of  a  light-absorbing  colored  solution  is 
directly  proportional  to  absorbance  over  a  given  range  of 
concentrations.  If  one  were  to  plot  a  graph  showing  (%T) 
percent  transmittance  versus  concentration  on  straight 
graph  or  line  paper  and  another  showing  absorbance  versuo 
conce  -ation  on  the  same  paper,  the  following  curves 
(graphs)  would  result: 


€ 
o 
tn 
O 
< 


Concentration 


Concentration 


CALIBRATION  CURVES:  The  c  .bration  curve  is  used  to 
determine  the  concei.*ration  of  the  water  quality  indicator 


Lab  Procedures  449 


(iron  or  manganese)  cont?iined  sn  a  sample.  Three  s*eps 
must  be  completed  in  order  to  prepare  a  calibration  graph. 

First,  a  series  of  standards  must  be  prepared.  A  standard 
is  a  solution  which  contains  a  known  amount  of  the  same 
chemical  constituent  which  is  being  determined  in  the  sam- 
ple. 

Secondly,  these  standard  solutions  and  a  sample  contain- 
ing none  of  the  constituent  being  tested  for  (usually  distilled 
water  and  generally  referred  to  as  a  blank)  must  be  treated 
with  the  developing  reagent  in  the  same  manner  as  the 
sample  would  be  treated. 

Thirdly,  using  a  spectrophotometer  the  absorbance  or 
transmittance  at  the  specified  vvave  length  of  the  standards 
and  blank  must  be  determined  From  the  values  obtained,  a 
calibration  curve  of  ab<=orbance  (or  %T)  versus  concentra- 
tion can  be  plotted.  Once  these  several  points  have  been 
plotted,  you  can  then  extend  the  plotted  points  by  connect- 
ing the  known  points  with  a  straight  line.  For  example,  with 
the  data  given  below  one  could  construct  the  following 
calibration  curve. 


Absorbance 


Concentration,  mg/L 


0.0 
0.30 
0.55 
0.80 


0.0 
0.25 
0.50 
0.75 


Concentration,  mg/L 

Once  you  have  established  a  calibration  curve  for  the 
water  quality  indicator  in  question,  you  can  easily  determine 
the  amount  of  that  substance  contained  in  a  solution  of 
unknown  concentration.  You  merely  take  an  absorbance 
reading  on  the  color  developed  by  the  unknown  and  locate  it 
on  the  vertical  axis.  Then  a  straight  line  is  drawn  to  the  right 
on  the  graph  until  it  intersects  with  the  experimental  stan- 
dard curve.  A  line  is  then  dropped  to  the  horizontal  axis  and 
this  value  identifies  the  concentration  of  your  unknown 
water  quality  indicator. 


0.2$ 


0.«)  0.75 
Concentratton.  mgIL 


ERLC 


In  this  example,  an  absorbance  reading  of  0  32  was  read 
on  the  unknown  solution  or  sample,  which  indicates  a 
concentration  of  about  0.37  mg/L. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  482. 

21  .OA  When  measunng  the  color  intensity  of  phosphorus, 
what  color  Is  measured? 

21  .OB  What  are  the  units  of  measurements  for  spectropho- 
tometers? 

21 .00  Using  the  above  cibsorbance  vs.  concentration  call- 

ation  graph,  if  the  absorbance  reading  of  0.60  was 
read  on  an  unknown  solution  or  sample,  what  was 
the  concentration  of  the  unknown? 

21.1  TEST  PROCEDURES 

1.   Algae  Counts 

A.  Discussion 

The  quality  of  water  in  any  lake,  reservoir  or  stream  has  a 
very  direct  effect  on  the  abundance  and  types  of  aquatic 
organisms  found.  By  knowing  the  nature  and  numl)ers  of 
these  aquatic  organisms  one  can  obtain  a  good  idea  of  the 
water  quality.  A  biological  method  used  for  measuring  water 
quality  is  the  collection,  cou'iting,  and  identification  of  algae 


contained  in  a  particular  body  of  water.  Information  from 
algae  counts  can  serve  one  or  more  of  the  following  pur- 
poses: 

1.  Help  explain  the  cause  of  color  and  turbidity  and  the 
presence  of  tastes  and  odors  in  the  water, 

2.  Help  explain  the  clogging  of  screens  or  filters,  and 

3.  Help  document  variability  in  the  water  quality. 

Algae  counting  and  identification  may  be  done  very  simply 
or  It  may  be  developed  into  d  highly  technical  operation.  The 
beginner  should  use  great  caution  applying  the  results  of 
algae  identifications  until  considerable  experience  has  been 
gained. 

Somo  operators  perform  algae  counts  on  both  the  raw 
water  and  treated  water.  Taking  algae  counts  on  treated 
water  is  a  means  of  studying  the  e^*^ctiveness  of  coagula- 
tion and  the  performance  of  filters,  i.  ^^9  filters  are  perform- 
ing properly,  there  should  not  be  any  countable  algae  i'^  the 
treated  water. 


47n 


450  Water  Treatment 


(Calcium) 

B.   Materials  and  Procedures 
See  page  1043.  STANDARD  METHODS,  l6th  Edition.^ 

2.  Calcium 

A  Discussion 

In  most  natural  waters,  calcium  is  the  principal  cation.  The 
element  is  widely  distributed  in  the  common  minerals  of 
rocks  and  of  soil.  Calcium  in  the  form  of  lime  or  calcium 
hydroxide  may  be  used  to  soften  water  or  to  control  corro- 
sion through  pH  acJjustment. 


B.   What  IS  Tested'? 

Sample 


Common  Range.  mg/L 


Raw  and  Treated  Surface  Water  5  tc  50 

Well  Water  10  to  100 

C.  Apparatus  Required 

Buret.  25  mL 
Buret  support 

Graduated  cylinder.  lOO  mZ. 
Beaker.  100  m/. 
Magnetic  stirrer 
Magnetic  stir-bar 

D.  RCdgents 

{NOTE:  Standardized  solutions  are  commercially 
available  for  most  reagents.  Refer  to  STANDARD 
METHODS  'ii  you  wish  to  prepare  your  own  reagents.)^ 

1.    Sodium  hydroxide,  NaOH.  1  N. 


2 
3 


Enochrome  Blue  Black  R  indicator. 

Standard  EDTA  titrant,  O.Ol  M.  Standardize  against 
Standard  Calcium  Solution  and  store  in  plastic  polyeth- 
ylene bottle. 

Standard  Calcium  Solution.  Store  in  polyethylene  plastic 
bottle.  1  mL  of  this  solution*  =  i  mg  calcium  hardness  as 
CaCOg  or  400.8  micrograms  (^g)  Ca 

1  -  1  HCI.  Carefully  add  50  mL  concentrated  HCl  to  50 
mL  distilled  waier. 

Ammonium  hydroxide,  3  N. 

Methyl  Orange  indicator  solution. 

Procedure 

Taxe  a  clean  beaker  and  add  50  mL  of  sample. 

Add  2.0  mL  NaOH  solution. 

Add  0.1  to  0.2  g  indicator  mixture. 

Titrate  immediately  with  EDTA  titrant  until  last  redduh- 
purple  tinge  disappears.  Mix  with  magnetic  stirrer  dur- 
ing titration. 

Calculate  calcium  concentration 


F.  Example 

Results  from  calcium  testing  of  a  treated  water  sam- 
ple were  as  follows: 

sample  size  =  50  mL 

mL  EDTA  titrant  used,  A  =  7.3  mL 


6 
7. 

E. 
1. 
2 

3. 
4. 


OUTLINE  OF  PROCEDURE  FOR  CALCIUM 


m 


L  OF  EDTA  ^ 


f 


1.  Add  50  mL  to  a  clean 
beaker. 


2.  Add  2  mL  NaOH 
and  0.2  g 
indicator 
mixture. 


3.  Titrate  with 
EDTA.  Mix 
with  magnetic 
stirrer 


^  STANDARD  METHODS  FOR  THE  EXAMINATION  OF  WAJ:FR  AND  WASTEWATER.  I6th  Edition.  1985.  Order  No.  1003$  Available  from 
Computer  Services.  American  Water  Works  A<;sociit;on,  66u6  W.  Quincy  Avenue.  Denver  Colorado  80235.  Price  to  members.  $72  00- 
nonmembers.  $90.00. 

2  See  'Prepared  vs.  Do-lt-Yourself  Reagents."  oy  Josephine  W.  Boyd,  OPFLOW.  Vol.  9.  No.  10,  October  1983. 


ERIC 


47J 


Lab  Procedures  451 


Q  Calculation 

mgCa/L=-  A  x  400.8- 
mL  of  sample 
^(7.3mL)  X  400  8 

50  mL 
=  58  mg/L 

•  400.8  IS  a  constant  fo'  his  calculation. 

H.  Precautions 

I.  Titrate  immediately  after  adding  NaOH  soHion. 

2.  Use  50  mL  or  a  smaller  oortion  of  sample  diluted  to  50 
mL  with  distilled  water  so  tha;  the  calcium  content  is 
about  5  to  10  mg. 

3.  For  hard  waters  with  alkalinity  greater  than  300  mg 
CaCOg/L.  use  a  smaller  portion  or  neutralize  alkalinity 
with  acid,  boiling  for  one  minute,  and  cooling  before 
beginning  the  titration. 

1.  Reference 
See  page  199.  STANDARD  METHODS,  16th  Edition. 


(Chlonde) 


E.  Procedure 

1.  Place  100  mL  or  a  suitable  portion  of  sample  diluted  to 
100  mL  in  a  250  nr.L  Erienmeyer  flask. 

2.  Add  1.0  mL  KgCrO^  indicator  solution. 

3.  Titrate  with  standard  silver  nitrate  to  a  pinkish  yellow 
end  point.  Be  consistent  in  end  point  recognition.  Com- 
pare with  known  standards  of  various  chloride  concen- 
trations. 


3.  Chloride 

A.  Discussion 

Chlonde  occurs  in  all  natural  waters,  usually  as  a  metallic 
salt.  In  most  cases,  the  chloride  content  increases  as 
mineral  content  increases.  Mountain  water  supplies  usually 
are  quite  low  in  chloride  while  groundwaters  and  valley 
rivers  often  contain  a  considerable  amount.  The  maximum 
ailov;able  chloride  concentration  of  250  mg/L  in  drinking 
water  has  been  established  for  reasons  of  taste  rather  than 
as  a  safeguard  against  a  physical  or  a  health  hazard.  At 
concentrations  above  250  mg/L,  chloride  may  give  a  salty 
taste  to  the  water  which  is  objectionable  to  many  people. 


I     What  IS  Tested? 

Sample 


Common  Range,  mg/L 


Surface  or  Grounc*water  2  to  100 


C.  Apparatus  Required 

Graduated  cylinder.  100  mL 
Buret,  GO  mL 
Erienmeyer  flask,  250  mL 
Pipet,  10  mL 

Magnetic  stirring  apparatus 

D.  Reagents 

(NOTE:  Standard  solutions  may  be  purchased  from 
chemical  suppliers.) 


1. 
2. 
3. 
4. 


Chloride-free  water  —  distilled  or  deionized  water. 
Potassium  chromate  (KgCrOJ  indicator  solution. 
Standard  Silver  Nitrate  Titrant,  0.0141  /V. 
Standard  Sodium  Chloride.  0.0141  /V. 


erJc 


F.  Calculation 

Chlo„de  (as  CI).  mg/L  .(A-B)  x  iV  .  35,450 

mL  of  sample 

A  =  mL  AgNOj  used  for  titration  of  sample 

B  =  mL  AgNOj  used  for  blank 

N=  normality  of  AgN03 


Example 
Sample  size  =  100  mL 

A  =  mL  AgNOa  used  for  sample  =  10.0  mL 
B  =  mL  AgNOa  used  for  blank  =  0.4  mL 
:  normality  of  AgNOa  =  0  0141  N 

.(10.0  -  0  4)  X  (0.0141)  X  35>450 
100 

-  48  mg/L 


N 


Chlonde.  mg/L 


H.   Special  Notes 

1  Sulfide,  thiosulfate,  and  sulfite  ions  interfere,  but  can  be 
removed  by  treatment  with  1  mL  of  30  percent  hydrogen 
peroxide  (HgOg). 

2.  Highly  colored  samples  must  be  treated  with  an  alumi- 
num hyd''oxide  suspension  and  then  filtered. 

3.  Orthophosphate  in  excess  of  25  mg/L  and  iron  in 
excftss  of  10  mg/L  also  Interfere. 

4.  If  tne  pH  of  the  sample  is  not  betv/een  7  to  10.  e'^just 
with  1  N  sulfuric  acid  or  1  /V  sodium  hydroxide. 


472 


452  Water  Treatment 


(Chloride) 


OUTLINE  0^  PROCEDURE  FOR  CHLORIDE 


1.  Place  100  mL  or  other 
measured  sample  In  flask. 


2.  Add  1  mL  chromate  indicator. 


s  -:o:-  / 


3.  Place  flask  on  magnetic  stirrer  and 
titrate  with  standard  silver  '*rate. 


5.    Procedure  for  standardization  of  AgN03: 

a.  Add  10  m/.  (1  mg  CI)  standard  sodium  chloride 
solution  to  a  clean  250  mL  Erienmeyer  flask. 

b.  Add  90  mL  distilled  water. 

c.  Titrate  as  in  Section  E  above. 
Normality,  A/,  standard  x  0.0141 


AgNO, 


mL  AgNOj  used  in  titration 


ERLC 


EXAMPLE 

10.0  mL  NaCI  standard  used 
10.0  mL  AgNO,  u^ed  in  titration 


0.0-^  :i  N  =  norm,  ity  of  NaCI  standard 
Normality,  N,  ^10.0  mL  x  0.0141 
10  mL 
=  0.0141 


AgN03 


473 


Lab  Procedures  453 


(Color) 


1.  Reference 
See  page  286.  STANDARD  METHODS.  16th  Edition 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  cn  page  482. 

21.1  A  Does  the  quality  of  water  in  any  lake,  reservoir  or 
stream  effect  the  abundance  and  types  of  aquatic 
organisms  found  in  the  water''  Yes  or  No? 

21. IB  How  are  calcium  compounds  used  to  treat  water? 

21. 1C  How  soon  should  a  sample  be  titrated  for  calcium 
after  the  sodium  hydroxide  (NaOH)  solution  has  been 
added? 

21.1  D  Why  are  concentrations  of  chlonde  above  250  mg/L 
objectionable  to  many  people? 

4.  Color 

A.  Discussion 

ColOi  in  water  supplies  may  result  from  the  presence  of 
metallic  ions  (iron,  manganese,  and  copper),  organic  matter 
of  vegetable  or  soil  origin,  and  industrial  wastes.  The  most 
cc^mon  colors  which  occur  in  raw  water  are  yellow  and 
br^wn.  There  are  two  general  types  of  color  found  in  water. 
True  color  results  from  the  presence  of  dissolved  organic 
substances  or  from  certain  minerals  such  as  copper  sulfate 
dissolved  in  the  water.  Suspended  materials  (including  col- 


loidal substances)  ca^  add  what  is  called  apparent  color. 
True  color  is  normally  removed  or  at  least  reduced  by 
coagulation  and  chlorination  or  ozonation.  The  method 
given  below  is  suitable  only  for  the  measurement  of  color  in 
clear  treated  water  supplies  having  a  turbidity  of  less  than 
one  unit  of  turbidity.  When  greater  amounts  of  turbidity  are 
present  in  the  sample,  some  fcm  of  pretreatment  for 
turbidity  removal  must  be  used  before  measuring  the  color. 

B.   What  is  Tested? 


Sample 


Common  Range.  mg/L 


Treated  Surface  Water  1  to  1 0 

Groundwater  0  to  5 

C.   Apparatus  Required 

Nessler  tubes,  matched,  50  mL  taP  form 
Pipet,  1.0  mL 


D. 
1 


Reagents 

Color  Standard.  Use  a  stock  standard  with  a  color  of 
500  units. 

Prepare  color  standards  by  adding  the  following  incre- 
ments of  stock  color  standard  to  a  nessler  tube  and 
diluting  to  50  mL. 

Color  Unit  Standard    mL  of  Stock  Color  Standard 


1 
2 

3 
4 
5 


0.1 
0.2 
0.3 
0.4 
0.5 


Protect  these  standards  against  eva^  oration  and  con- 
tamination when  not  in  use. 

E.  procedure 

1 .  Fill  a  clean  matched  nessler  tube  to  the  50  mL  mark  Vi^ith 
sample. 

2.  Compare  the  sample  with  the  various  color  standards 
by  looking  downward  vertically  through  the  tubes  to- 
ward a  white  surface. 


Match  as  closely  as  possible  sample  color  with  a  color 
standard. 


F.    Other  Procedures 

Color  may  aiso  be  measurec  by  the  use  of 
1.    Color  comparator  kiis.  and 
Spectrophotomete  i  c . 


2. 

G. 
1. 


Notej 

If  the  color  exceeds  70  units,  dilute  sample  with  distilled 
water  in  known  proportions  until  the  color  is  within 
range  of  the  standards.  Calculate  color  units  by  the 
following  equation: 


Color  units 


^A  X  50 
B 


where: 

A  =  estimated  color  of  diluted  sample 

B  =  mL  of  sample  taken  from  dilution 

2.    If  turbidity  is  greater  than  one  unit,  consult  STANDARD 
METHODS  for  pretreatment  for  turbidity  removal. 

H.  Refe.ence 
See  page  67,  STANDARD  METHODS.  16th  Edition. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  482. 

21  .IE  What  are  the  most  common  colors  w.iich  occur  in 
raw  Vt/ater? 

21. IF  How  can  true*  color  be  removed  from  water? 

21. 1C  When  not  in  use,  stock  color  standards  should  be 
protected  against  what? 


ERIC 


474 


454  Water  Treatment 

(Dissolved  Oxygen) 


OUTLINE  OF  PROCEDURE  FOR  COLOR 


5.   Dissolved  Oxygen 

A.  Discussion 

Dissolved  oxygen  (DO)  is  important  to  the  /vater  treatment 
plant  operator  for  a  number  of  reasons.  In  surface  waters, 
dissolved  oxygen  must  be  present  in  order  for  fish  and 
smaller  aquatic  organisms  to  survive.  The  taste  of  water  is 
improved  by  dissolved  oxygen.  However,  the  presence  of 
dissolved  oxygen  in  water  can  contribute  to  corrosion  of 
piping  systems.  Low  or  zero  dissolved  oxygen  levels  at  the 
bottom  of  lakes  or  reservoirs  often  causa  taste  and  odor 
problems  in  drinking  water. 

B.  What  is  Tested? 

Sample  Common  Range,  mg/L 

Surface  Water  5  to  IT 

Groundwaters  0  to  2 


•  Some  reservoirs  ard  lakes  may  have  zero  DO  near  he 
bottom. 

C.  Apparatus  Required 

Method  A  (Sodium  Azide  Modification  of  Winkler 
Method) 

Buret,  graduated  to  0.1  tr)L 
Buret  support 
BOD  bottle,  300  mL 

Er|c  ;;;cc 


Magnetic  stirrer 
Magnetic  stir*bar 
Pipets,  10  mL 

Method  B  (Membrane  Electrode  Method) 

Follow  manufacturer's  instructions.  To  be  assured 
that  the  DO  probe  reading  is  accurate,  the  probe  must 
be  calibrated  frequently.  Take  a  sample  that  does  not 
contain  substances  that  interfere  with  either  the  probe 
reading  or  the  Modified  Winkler  procedure.  Split  the 
sample.  Measure  the  DO  in  one  portion  of  the  sample 
using  the  Modified  Winkler  procedure  and  compare  this 
result  with  the  DO  probe  reading  on  the  other  portion  of 
the  sample.  Adjust  the  probe  reading  to  agree  with  the 
results  from  the  Modified  Winkler  procedure.  To  obtain 
good  results  when  using  a  probe,  you  should  be  avi^are 
of  the  following  PRECAUTIONS: 

a.  Periodically  check  the  calibration  of  the  probe, 

b.  Keep  the  membrane  in  the  tip  of  the  probe  fro'  )  drying 
out. 

c.  Dissolved  inorganic  salts,  such  as  found  in  sea  water,  can 
influence  the  readings  from  a  probe. 

d.  Reactive  compounds,  such  as  reactive  gases  and  sulfur 
compounds,  can  interfere  with  the  output  of  a  probe,  and 

e.  Don't  place  the  probe  directly  over  a  diffuser  because  you 
want  to  measure  the  dissolved  oxygen  in  the  water  being 
treated,  not  the  oxygen  in  the  air  supply  to  the  aerator. 

475 


Lab  Procedures  455 


(Dissolved  Oxygen) 


D.  Reagents 

(Standardized  solutions  may  be  purchased  from  chemi- 
cal suppliers.) 

1 .  Manganous  Sulfate  Solution. 

2.  Alkaline  Iodide-sodium  Azide  Solution. 

3.  Sulfuric  Acid:  Use  concentrated  reagent-grade  acid 
(HjSO^).  Handle  carefully,  since  this  material  will  burn 
hands  and  clothes.  Rinse  affected  parts  with  tap  water 
to  preveril  injury. 

CAUTION:  When  working  with  alkaline  azide  and  sul- 
furic acid,  keep  a  nearby  water  faucet 
running  for  frequent  hand  rinsing. 

4.  0.025  N  Phenylarsine  Oxide  (RAO)  solution. 

5.  0.025  N  Sodium  Thiosulfate  solution. 

For  preservation,  add  0.4  g  or  1  pellet  of  sodium 
hydroxide  (NaOH).  Solutions  of  "thio"  should  be  used 
within  two  weeks  to  avoid  loss  of  accuracy  due  to 
decomposition  of  solution. 

6.  Starch  solution. 

E.  Procedure 

SODIUM  AZIDE  MODIFICATION  OF  THE  WINKLER 
METHOD 

NOTE:  The  sodium  azide  destroys  nitrate  which  would 
otherwise  interfere  with  this  test. 


ERIC 


The  reagents  are  to  be  added  in  the  quantities,  order,  and 
methods  as  follows: 

1  Collect  a  sample  to  be  tested  in  300  mL  (BOD)  bottle 
taking  cpecial  care  to  avoid  aeration  of  the  liquid  being 
collected.  Fill  bottle  completely  and  add  cap. 

2.  Remove  cap  and  add  1  mL  of  manganous  sulfate 
solution  below  surface  of  the  liquid. 

3.  Add  1  mL  of  alkaline-iodide-sodium  azide  solution  be- 
low the  surface  of  the  liquid. 

4.  Replace  the  stopper,  avoid  trapping  air  bubbles,  and 
shake  well  by  inverting  the  bottle  several  times.  Repeat 
this  shaking  after  the  floe  has  settled  halfway.  Allow  the 
floe  to  settle  halfway  a  second  time. 

5.  Acidify  with  2  mL  of  concentrated  sulfuric  acid  by 
allowing  the  acid  to  run  down  the  neck  of  the  bottle 
above  the  surface  of  the  liquid. 

6.  Restopper  and  shake  well  until  ?  \e  precipitate  has 
dissolved.  The  solution  will  then  be  ready  to  titrate. 
Handle  the  bottle  carefully  to  avoid  acid  burns. 

7.  Pour  201  mL  from  bottle  into  an  Erienmeyer  flask. 

8.  If  f  solution  is  brown  in  color,  titrate  with  0.025  N  PAO 
until  the  solution  is  pale  yellow  color.  Add  a  small 
quantity  of  starch  indicator  and  proceed  with  Step  10. 
(Note:  Either  PAO  or  0.025  N  sodium  thiosulfate  can  b3 
used.) 

9.  If  the  solution  has  no  brown  color,  or  is  only  slightly 
colored,  add  a  small  quantity  of  starch  indicator.  If  no 
blue  color  dev(  ips,  there  is  zero  Dissolved  Oxygen.  If  a 
blue  color  does  develop,  proceed  to  Step  10. 

10.  Titrate  to  the  first  disappearance  trie  blue  color. 
Record  the  number  of  mL  of  PAO  useo. 

1 1 .  The  amount  of  oxygen  dissolved  in  the  original  solution 
will  be  equal  to  the  number  of  mL  of  PAO  used  in  the 
titration  provided  significant  interfering  «'jbstances  are 
not  present. 

mg  DO/L  =  mL  PAO 


F.  Example 

A  sample  is  collected  from  just  upstream  of  a  river  intake 
to  a  water  treatment  facility.  The  water  temperature  is  18^C. 
The  sample  is  tested  for  DO  and  the  operator  uses  9.1  mL  of 
0.025  N  PAO  titrant. 


G.  Calciiiation 

The  DC  titration  of  201  mL  sample  required  9.1  mL  of 
0.025  N  PAO.  Therefore,  the  dissolved  oxygen  (DO)  concen- 
tration In  the  sample  is  9.1  mg/L. 

The  percent  saturation  of  DO  in  the  river  can  be  calculated 
using  the  dissolved  oxygen  saturation  values  given  in  Table 
21.1.  Note  that  as  the  temperature  of  water  increases,  the 
DO  saturation  value  (100%  Saturation  Column)  decreases. 


476 


456  Water  Treatment 

(Dissolved  Oxygen) 


OUTLINE  OF  PROCEDURE  FOR  DO 


1.  Take 
300  mZ_ 
sample. 


2.  Add 
1  VOL 
MnSO^ 
below 
surface. 


Add 
1  VOL 
Kl  + 
NaOH 

below 
surface. 


Brown  floc; 
DO  present. 


Mix  by 
inverting. 


White  floc; 
no  DO. 


HjSO,. 


Reddish- 
brown 
iodine 
solution. 


Titration  of  Iodine  Solution: 


1.  Pour  201  VOL 
Into  flask. 


Reddish- 
Brown 


Pale 
Yellow 


I 


Blue 


2.  Titrate 
with  PAO  or 
Sodium 
Thiosulfate. 


Clear 


3.  Add  Starch 
Indicator. 


End  Point 


ERLC 


477 


Lab  Procedures  457 


Table  21.1  gives  100  percent  DO  saturation  values  for 
temperatures  in  °C  and  °F. 

DO  Saturation,  %  ^  DO  of  sample,  mg/L  x  100% 
DO  at  100%  Saturation,  mg/L 

For  example,  given 

DO  Saturation.  %  =9jjTig/L  >^  ^qqo/^ 
9.5  mg/L 

=  0.9C  X  100% 

=  96% 

where 

9.1  mg/L  =  DO  of  sample 

P  5  mg/L  =  DO  at  100%  Saturation  at  18°C 
(river  temperature) 


TABLE  21.1 

EFFECT  OF  TEMPERATURE  ON  OXYGEN  SATURATION 
FOR  A  CHLORIDE  CONCENTRATION  OF  ZERO  mg/L 


mg/L  DO  at 

°C  °f  Saturation 


0  0  14.6 

1  33.8  14.2 

2  35.6  13.8 

3  37.4  13.5 

4  39.2  13.1 

5  41.0  12.8 

6  42.8  12.5 

7  44.6  12.2 

8  46.4  1 1 .9 

9  4b.2  11.6 

10  50.0  11.3 

11  51.8  11.1 

12  53.6  10.8 

13  55.4  10.6 

14  57.2  10.4 

15  60.0  10.2 

16  61.8  10.0 

17  63.6  9.7 

18  65.4  9.5 

19  67.2  9.4 

20  68  0  _92 

21  69.8  9.0 

22  71.6  8.8 

23  73.4  8.7 

24  75.2  8.5 

25  77.0  8.4 


(Fluoride) 

H  Precautions 

1 .  Samples  for  dissolved  oxygen  measurements  should  be 
collected  very  carefully.  Do  not  let  sample  remain  in 
contact  with  air  or  be  agitated.  Collect  samples  in  a  300 
mL  BOD  bottle.  Avoid  entraining  or  dissolving  atmos- 
pheric oxygen. 

2.  When  sampling  from  a  water  line  under  pressure,  attach 
a  tube  to  the  tap  and  extend  tube  to  bottom  of  bottle.  Let 
bottle  overflow  two  or  three  times  its  volume  and 
replace  glass  stopper  so  no  air  bubbles  are  entrapped. 

3.  Use  suitable  sampler  for  streams,  reservoirs  or  tanks  of 
moderate  depth  such  as  that  shown  in  Figure  21.1.  Use 
a  Kemmerer-type  sampler  for  samples  collected  from 
depths  greater  than  6V2  feet  (2  m). 

4.  Always  record  temperature  of  water  at  time  of  sampling. 

5.  Use  the  proper  bottle  with  matched  stopper. 

6.  When  working  with  a  lake  or  reservoir,  examine  the 
temperature  and  DO  profile  (measure  temperature  and 
DO  at  surface  and  at  various  depths  all  the  way  down  to 
the  bottom). 

7.  Measure  the  DO  in  the  sample  as  soon  as  possible. 

I.  Reference 
See  page  418,  STANDARD  METHODS,  16th  Edition. 

6.  Fluoride 

A.  Discussion 

Fluoride  may  occur  naturally  or  it  may  be  added  in 
controlled  amounts.  The  concentration  of  fluoride  in  most 
natural  waters  is  less  than  one  mg/L.  There  are,  however, 
several  areas  in  the  United  States  which  have  natural 
fluoride  concentrations  of  as  high  as  30  mg/L.  The  impor- 
tance of  fluoride  in  forming  human  teeth  and  the  role  of 
fluoride  intake  from  drinking  water  in  controlling  the  charac- 
teristics of  tooth  structure  has  been  realized  only  within  the 
past  40  to  50  years.  Studies  have  shown  that  a  fluoride 
concentration  of  approximately  1.0  mg/L  reduces  dental 
caries  of  young  people  without  harmful  effects  on  health. 

B.  What  is  Tested? 

 Sample  Common  Range,  mg/L 

Fluoridated  Water  0.8  to  1 .2 

C.  Apparatus  Required 

Spectrophotometer  for  use  at  570  nanometers 

wavelength 
Pipe.s,  5  mL 

Flaso,  Erienmeyer,  125  mL 

D.  Reagents 

1.  Stock  fluoride  solution.  1.0  mL  =  0.100  mg  F. 

2.  Standard  fluoride  solution:  Dilute  100  mL  stock  fluoride 
solution  to  1000  mL  with  distilled  water;  1 .0  mL  =  O.OlO 
mg  F. 

3.  SPADNS  solution.  This  solution  is  stable  indefinitely  if 
protected  from  direct  sunlight. 

4.  Zirccnyl-acid  reagent. 


ERIC 


478 


458  Water  Treatment 


(Fluoride) 


Fig.  21,1   DO  sampler 

(Reprinted  from  STANDARD  MBTHODS.  I5th  Edition  by 
permission  Copyright  1980,  the  American  Public  Health  Association) 


5.  Acid  zirconyl-SPADNS  reagent:  Mix  equal  volumes  of 
SPADNS  solution  and  zirconyl-acid  reagent.  The  com- 
bined reagent  is  stable  for  at  least  2  years, 

6.  Reference  solution:  Add  1 0  mL  SPADNS  solution  to  1 00 
mL  distilled  water  Dilute  7  mL  concentrated  HCl  to  10 
mL  and  add  to  the  diluted  SPADNS  solution.  The 
resulting  solution,  used  for  setting  the  instrument  refer- 
ence point  (zero),  Is  stable  and  may  be  reused  indefi- 
nitely. Alternatively,  use  a  prepared  st'^ndard  as  a 
reference. 

7.  Sodium  aroenite  solution.  (CAUTION,  Toxic  —  avoid 
ingestion). 

E.  Procedure 

1.   Measure  50  mL  of  sample  and  add  to  a  clean  125  mL 

ERIC  v^.:v 


Erienmeyer  flask.  (If  sample  contains  residual  chlonne, 
add  one  drop  NaAsOg  solution  per  0.1  mg  chlorine 
residual  and  mix.) 

2.  Add  5.0  mL  each  of  SPADNS  solution  and  zirconyl-acid 
reagent,  or  10.0  mL  acid  zirconyl-SPADNS  reagent. 
Mix. 

3  Set  spectrophotometer  to  0.730  absorbance  with  refer- 
ence solution  containing  zero  mg/L  of  fluoride  (see  G. 
Example). 

4.  Read  absorbance  at  570  nm  with  spectrophotometer 
and  determine  the  amount  of  fluoride  from  ;-ccindard 
curve. 

NOTE:  A  colorimeter  may  also  be  used  to  measure  flu- 
oride. 


47.9 


Lab  Procedures  459 


(Fluoride) 


F. 
1. 


Construction  of  Standard  Calibration  Curve 

Using  the  standard  fluoride  solution,  prepare  the  follow- 
ing standards  in  100  mL  volumetric  flasks. 


mL  of  Standard  Fluoride  Solution  Fluoride 
Placed  in  100  mL  Volumetric  Flask   Concentration,  mg/L 


H.  Calculation 


5.0 
75 
10.0 
12.5 


0.50 
0.75 
100 
1.25 


Dilute  flasks  to  100  mL 

Transfer  50  mL  to  125  mL  Erienmeyer  flask. 

Determine  amount  of  fluoride  as  outlined  previously. 

Prepare  a  standard  curve  by  plotting  the  absorbance 
values  of  standards  versus  the  corresponding  fluoride 
concentrations. 


G.  Example 

Results  from  a  series  of  tests  for  fluoride  were  as  follows: 


Flask 

Volume, 

No. 

Sample 

mg/L 

Absorbance 

1 

Distilled  Water 

50 

0.730 

2 

C  Street  Well 

50 

0.470 

3 

Plant  Effluent 

50 

0.510 

4 

0.5  mg/L  F 

50 

0.625 

5 

0.75  mg/L  F 

50 

0.560 

6 

1.0  mg/L  F 

50 

0.500 

7 

1.25  mg/L  F 

50 

0.444 

1. 


Prepare  a  standard  curve  by  using  data  from  prepared 
standards.  From  above  example: 


Fliioride 
Concentration,  mg/L 


Absorbattce 


0.0 

0.5 

0.75 

1.0 

1.25 


0.730 
0.625 
0.560 
0.500 
0.444 


The  graph  below  is  a  result  of  plotting  concentration  of 
fluoride  standards  versus  their  corresponding  absorbance. 


LU 
O 

z 
< 

CD 

o 

CO 
ffl 
< 


FLUORIDE,  mg/L 


OUTLINE  OF  PROCEDURE  FOR  FLUORIDE 


460  Water  Treatment 


(Fluoride) 

2    Obtain  concentration  of  unknown  samples  from  curve. 


0^  0^  0  75  10  1  ' 

FLUORIDE,  mg/L 

PLANT  EFFLUENT  =  0.90  mg/L 
C  STREET  WELL  =  1.2  mg/L 

I.  Precautions 

1.   Whenever  any  of  the  following  substances  are  present 


in  the  listed  quantities^  the  sample  must  be  distilled  prior 
to  analyFss. 


Substance 


Concentration  mg/L 


Alkalinity 
Aluminum 
Chloride 
Iron 

Hexametaphosphate 

Phosphate 

Sulfate 


5,000 

0.1 
7,000 

10 

1.0 

16 
200 


2.    Samples  and  standards  should  be  at  the  same  tempera- 
ture throughout  color  development. 

J.  Reference 
See  page  359.  STANDARD  METHODS,  16th  Edition. 


QUESTIONS 

Write  your  answers  In  a  notebook  and  then  compare  your 
answers  with  those  on  page  482. 

21. 1H  Why  is  the  presence  of  dissolved  oxygen  (DO)  in 
water  in  piping  systems  of  concern  to  operators? 

21.11   What  IS  the  common  range  of  fluoride  in  fluoridated 
drinking  water? 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  21.   ADVANCED  LABORATORY  PROCEDURES 

(Lesson  1  of  2  Lessons) 


At  the  end  of  each  lesson  in  this  chapter  you  will  find  some 
discussion  and  review  questions  ♦hat  you  should  answer 
before  continuing.  The  purpose  of  these  questions  is  to 
indicate  to  you  how  well  you  understand  the  material  In  this 
lesson.  Write  the  answers  to  these  questions  In  your  note- 
book before  continuing. 

1.  What  is  the  purpose  of  spectrophotometer  calibration 
curves? 

2.  How  would  you  prepare  a  spectrophotometer  calibr^ition 
graph? 

3.  Why  are  algae  counts  in  raw  water  important  to  opfa- 
tcrs? 

ERIC 


4.  The  maximum  allowable  chloride  concentration  in  drink- 
ing water  has  been  established  on  what  basis? 

5.  What  are  the  two  general  types  of  color  found  m  water 
and  what  is  the  cause  of  each  type*? 

6  Why  IS  dissolved  oxygen  ^JO)  In  water  important  to  the 
treatment  plant  operator? 

7.  What  precautions  would  you  take  when  collecting  a  lake 
sample  for  a  dissolved  oxygen  measurement? 

8.  How  does  fluoride  get  into  drinking  waters'^ 


4S1 


Lab  Procedures  461 


Chapter  21.   ADVANCED  LABORATORY  PROCEDURES 

(Lesson  2  of  2  Lessons) 


7.    Iron  (Total) 

A.  Discussion 

Iron  IS  an  abundant  and  widespread  constituent  of  rocks 
and  soils.  The  most  common  form  of  iron  in  solution  in 
groundwater  and  in  water  under  anaerobic  conditions  (bot- 
tom of  a  lake  or  reservoir)  is  the  ferrous  ion,  Fe^^.  Ferric  iron 
can  occur  in  soils,  in  aerated  water,  and  in  acid  solutions  as 
Fe^*,  ferric  hydroxide  and  polymeric  forms  depending  upon 
pH.  Above  pH  of  4.8,  however,  the  solubility  of  the  ferric 
species  is  less  than  0.1  mg/L.  Colloidal  ferric  hydroxide  is 
commonly  present  in  surface  water  and  small  quantities  may 
persist  even  in  water  that  appears  clear. 

Iron  in  a  domestic  water  supply  can  be  the  cause  of 
staining  laundry,  concrete,  and  porcelain.  A  bitter  astringent 


taste  can  be  detected  by  some  people  at  levels  above  0.3 
mg/L.  When  iron  reacts  with  oxygen,  a  red  precipitate  (rust) 
is  formed. 


B. 


What  is  Tested? 

Source 


Common  Range,  mg/L 


Untreated  Surface  Water  0.10  to  1.0 

Treated  Surface  Water  <0.01  to  0.20 

Groundwater  <0.01  to  10 

C.  Apparatus  Required 

Spectrophotometer  for  use  at  510  nm 

Acid-washed  glassware.  Wash  all  glassware  with  con- 
centrated HCI  and  rinse  with  distilled  water  to  remove 
deposits  of  iron  oxide. 

Flasks,  Erienmeyer,  125  mL 

Pipets,  5  and  10  mL 

Flasks,  Volumetric,  100  mL 

Hot  plate 

D.  Reagents 

Use  reagents  low  in  iron.  Use  iron-free  distilled  water. 
Store  reagents  In  glass-stoppered  bottles.  The  hydrochloric 
acid  and  ammonium  acetate  volutions  are  stable  indefinitely 
if  tightly  stoppered.  The  hydroxylamlne,  phenanthroline,  and 


ERIC 


stock  iron  solutions  are  stable  for  several  months.  The 
standard  iron  solutions  are  not  stable;  prepare  daily  as 
needed  by  diluting  the  stock  solution.  Visual  standards  in 
nessler  tubes  are  stable  fo''  several  months  if  sealed  and 
protected  from  light. 

1.  Hydrochloric  acid,  HCI. 

2.  Hydroxylamine  solution. 

3.  Ammonium  acetate  buffer  solution.  Because  even  a 
good  grade  of  NH^CgHjOg  contains  a  significant  amount 
of  iron,  prepare  new  reference  standards  with  each 
buffer  preparation. 

4.  Sodium  acetate  solution. 

5.  Phenanthroline  solution.  (NOTE:  One  milliliter  of  this 
reagent  is  sufficient  for  no  more  than  100  /ig  Fe.) 

6.  Stock  iron  solution.  1.00  mL  =  0.200  mg  Fe. 

7.  Standard  iron  solutions.  Prepare  daily  for  use.  PIpet 
50.00  mL  stock  solution  into  a  one-liter  volumetric  flask 
and  dilute  to  mark  witii  iron-free  distilled  water;  1.00  mL 
=  0.010  mg  Fe. 

E  Procedure 
For  Total  Iron 

1.  Measure  50  mL  of  thoroughly  mixed  sample  into  a  125 
mL  Erienmeyer  flask. 

2.  Add  2  mL  concentrated  HCI  and  1  mL  hydroxylamine 
solution. 

3.  Heat  to  boiling.  Boil  sample  until  volume  is  reduced  to 
20  mL.  Cool  to  room  temperature. 

4.  Transfer  to  100  mL  volumetric  flask. 

5.  Add  10  mL  acetate  buffer  solution  and  2  mL  phenan- 
throline solution.  Dilute  to  100  mL  mark  with  Iron-free 
distilled  water.  Mix  thoroughly. 

6.  After  15  minutes,  measure  the  absorbance  at  510  nm 
and  determine  the  amount  of  iron  from  the  standard 
curve. 


F.    Construction  of  Standard  Calibration  Curve 

1.    Using  the  standard  solution,  prepare  the  following  stan- 
dards in  100  mL  volumetric  flasks. 

mL  of  Standard  iron  Solution    Iron  Concentration 
Placed  in  100  mL  Volumetric  Flask  mg/L 


0 

1.0 
2.5 
5.0 
7.5 
10.0 


0 

0.10 
0.25 
0.50 
075 
1.00 


2.  Dilute  flasks  to  100  mL. 

3.  Transfer  50  mL  to  100  mL  volumetric  flask. 

4.  Add  1.0  mL  hydroxylamine  solution  and  1  mL  acetate 
solution  to  each  flask. 


48? 


462  Water  Treatment 


Lab  Procedures  463 


(Iron) 


5.  Dilute  to  about  75  ruL  add  10  mL  phenanthroline 
solution,  dilute  to  100  mL  mark.  Mix  thoroughly. 

6.  Measure  absorbance  at  510  nm  against  the  reference 
blank. 

7.  Prepare  a  standard  curve  by  plotting  the  absorbance 
values  of  standards  versus  the  corresponding  iron 
concentrations. 


G.  Example 

Results  from  a  series  of  tests  for  total  iron  were  as 
follows: 


Flask  # 


Sample 


Absorbance 


1  Distilleo  Water 

2  Plant  Clear  Well 

3  River  Sample 

4  0.10  mg/L  Fe  Standard 

5  0.25  my/L  Fe  Standard 

6  0.50  mg/L  Fe  Standard 

7  0.75  mg/L  Fe  Standard 

8  1.00  mg/L  Fe  Standard 


0.000 
0.100 
0.420 
0.066 
0.161 
0.328 
0.495 
0.658 


2.    Obtain  concentration  of  unknown  clear  well  and  river 
samples  from  curve. 


0 10     0^     QJX     0  40     0^     OAO     0  70 


IRON,  mg/L 

PLAMT  CLEAR  WELL  =  0.16  mg/L  Fe 
RIVER  SAMPLE  =  0.66  mg/L  Fe 


H.  Calculation 


1. 


Prepare  a  standard  curve  by  using  data  from  prepared 
standards.  From  the  above  example: 


Concentration  Iron, 
mg/L 


Absorbance 


CO 

0.10 

0.25 

0.50 

0.75 

1.00 


0.000 
0.066 
0.161 
0.328 
0.495 
0.658 


The  graph  below  is  a  result  of  plotting  concentration  of 
standards  versus  their  corresponding  absorbance 


010     0.20    0^     040     0^     OJO     0  70     OJO     OM     100      1  tO 


IRON,  mg/L 


ERIC 


I.  Notes 

1 .  Iron  In  well  water  or  tap  samples  may  vary  in  concentra- 
tion and  form  with  duration  and  degree  of  flushing 
before  and  during  sampling. 

2.  For  precise  determination  of  total  iron,  use  a  separate 
container  for  sample  collection.  Treat  with  acid  at  time 
of  collection  to  place  iron  in  solution  and  prevent 
deposition  on  walls  of  sample  container. 

3.  Exercise  caution  when  handling  sulfuric  acid. 

J.  Reference 
See  page  215.  STANDARD  METHODS.  16th  Edition, 

8.  Manganese 

A  Discussion 

Although  manganese  is  much  less  abundant  than  iron  in 
the  earth's  crust,  it  is  one  of  the  most  common  elements  and 
widely  distributed  in  rocks  and  soils.  Some  groundwaters 


484 


464  Water  Treatment 


(Manganese) 

that  conta'H  objectionable  amounts  of  iron  also  contain 
considerable  amounts  of  manganese,  but  groundwaters  that 
contain  more  manganese  than  iron  are  rather  unusual. 
Manganese  in  surface  waters  occurs  both  in  suspension 
and  as  a  soluble  complex.  Although  rarely  present  in  excess 
of  1  mg/Z..  manganese  imparts  objectionable  stains  to 
laundry  and  plumbing  fixtures.  Manganese  will  aisc  cause 
stains  on  the  walls  of  tanks  and  driveways  in  treatment 
plants. 


B.  What  is  Tested? 

Source   Common  Range.  mg/L 

Treated  and  Untreated 

Surface  Water  <0.01  to  0.10 

Groundwater  <0.01  to  1.0 

C.  Apparatus  Required 

Spectrophotometer  for  use  at  525  nm 
Hot  plate 

Flask,  Erienmeyer,  250  mL 

Pipets,  5  and  10  mL 

Flask,  Volumetric,  100  and  500  mL 

D.  Reagents 

1 .  Special  reagent. 

2.  Ammonium  persulfate,  (NH^j^SPg,  solid. 

3.  Standard  manganese  solution.  1  mL  ^  0.01  mg  Mn. 
Prepare  dilute  solution  daily. 

4.  1%  HCI:  Add  10  mL  concentrated  HCI  carefully  to  990 
mL  distilled  water. 

5.  Hydrogen  peroxide,  H^O^,  30  percent. 

E.  Procedure 

1 .  Measure  1 00  mc  of  thoroughly  mixed  sample  into  a  250 
mL  Erienmeyer  flask  which  as  been  marked  with  a  line 
at  the  90  mL  level. 

2. 
3. 


4. 
5. 


F. 
1. 


2.  Dilute  flasks  to  100  mL. 

3.  Transfer  to  250  mL  Erienmeyer  flask. 

A.  Determine  amount  of  manganese  as  outlined  previ- 
ously. 

5-  Prepare  a  standard  curve  by  plotting  the  absorbance 
values  of  standards  versus  the  corresponding  manga- 
nese concentrations. 


G.  Example 

Results  from  a  series  of  tests  for  manganese  were  as 
follows: 


^lask 

Sample 

Absorbance 

1 

Distilled  Water 

0.000 

2 

Plant  Effluent 

0.000 

3 

Jones  St.  Well 

0.030 

4 

0.05  mg/L  Mn  Standard 

0.009 

5 

0.10  mg/L  Mn  Standard 

0.018 

6 

0.20  mg/L  Mn  Standard 

0.036 

7 

0.30  mg/L  Mn  Standard 

0.053 

8 

0.40  mg/L  Mn  Standard 

0.071 

Calculation 

Prepare  a  standard  curve  by  using  data  from  prepared 

standards.  From  the  above  example: 

Concentration  Manganese, 

mg/L 

Absor'oance 

0.0  (distilled  water) 

0.000 

0.05 

0.009 

0.10 

0.018 

0.20 

0.036 

0.30 

0.053 

0.40 

0.071 

The  graph  below  is  the  result  of  plotting  concentration  of 
standards  versus  their  corresponding  absorbance. 


Add  5  mL  special  reagent  and  1  dro^^  wp^- 

Concentrate  to  90  mL  by  boiling.  Add  1  gram  ammonium 
persulfate.  Cool  Immediately  under  water  tap. 

Dilute  to  100  mL. 

Measure  the  absorbance  at  525  nm  with  a  spectropho- 
tometer and  determine  the  amount  of  manganese  from 
the  standard  curve. 


Construction  of  Calibration  Curve 

Using  the  standard  manganese  solution,  prepc.3  the 
following  standards  in  100  mL  volumetric  flasks. 

mL  of  Standard  Manganese  Solution  Manganese 
Placed  In  100  mL  Vctumetric  Flask   Concentration,  mg/L 


0 

0 

1.0 

0.10 

2.0 

0.20 

3.0 

0.30 

4.0 

0.40 

MANGANESE,  mg/L 


Lab  Procedures  465 


(Manganese) 


OUTLINE  OF  PROCEDURE  FOR  MANGANESE 


1.  Measure  100  mL  into  flask. 


2.  Add  5  mL  special  reagent  and 
1  drop  HgOj. 


/Q 


a 


3.  Concentrate  to  90  m/.  then  add 
1  g  ammonium  persulfate. 
Dilute  to  100  mL  after 
cooling. 


4.  Measure  absorbance  at  525  nm  with 
spectrophotometer. 


2.    Obtain  concentration  of  unknown  plant  effluent  and  well 
sample  from  curve. 


MANGANESE,  mg/L 

PLANTEFFLUENi  =  <0*01  mg/L  Mn 
JONES  ST.  WELL  =  0.17  mg/L  Mn 


ERIC 


I.  Notes 

1 .  If  turbidity  or  Interfering  color  is  present,  use  the  follow- 
ing "bleaching"  method:  as  soon  as  the  spectrophotom- 
eter reading  has  been  made,  add  0.05  mL  hydrogen 
peroxide  solution  directly  to  the  optical  cell.  Mix  and 
read  again  as  soon  as  the  color  has  faded.  Deduct 
absorbance  of  bleached  solution  from  initial  absorb- 
ance to  obtain  absorbance  due  to  manganese. 

2.  Determine  manganese  as  soon  as  possible  after  sam- 
ple collection.  If  this  is  not  possible,  acidify  sample  with 
nitric  acid  to  pH  less  than  2. 

J.  Reference 
See  page  229,  STANDARD  METHODS,  16th  Edition. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  yt  Jr 
answers  with  those  on  page  483. 

21 .1J  Iron  in  a  domestic  water  supply  may  cause  what 
problems? 

21.1  K  Why  must  all  glassware  be  acid  washed  when  ana- 
lyzing samples  for  iron? 


r<\> 


486 


466  Water  Treatment 


(Marble  Test) 


21. 1L  In  what  forms  does  manganese  occur  in  surface 
waters? 

21.1  M  If  the  manganese  concentration  in  a  sample  cannot 
be  measured  immediate!   what  would  you  do? 

9.    Marble  Test  (Calcium  Carbonate  Stability  Test) 
A.  Discussion 

The  Marble  Test  is  intended  to  determine  the  degree  to 
which  a  sample  of  water  is  saturated  with  calcium  carbon- 
ate. Water  in  intimate  contact  with  powdered  calcium  car- 
bonate (calcite)  will  approach  saturation.  The  water  being 
tested  should  not  be  exposed  to  atmospheric  carbon  diox- 
ide. The  Marble  Test  must  be  conducted  at  the  specific 

A 


D.  Reagents 


temperature  because  the  solubility  of  calc'um  carbonate 
varies  with  temperature.  However,  equipment  that  will  main- 
tain a  constant  temperature  (either  lower  or  higher  than 
room  temperature)  while  mixing  the  solution  is  not  common- 
ly available  in  water  treatment  plants.  The  only  other  way  to 
keep  a  reasonable  uniform  temperature  is  to  run  the  test  as 
rapidly  as  possible. 


B.  What  is  Tested? 

Source 


Common  Range* 


Untreated  Surface  Water 
Treated  Surface  Water 
Well  Water 


-1    to  +1 
-0.2  to  +0.2 
-0.1  to  +1 


•  Initial  pH  -  Final  pH 

C.  Apparatus  Required 

Bottle,  BOD,  300  mL 

Magnetic  stirrer 

Stir-bar 

Thermometer 

Funnel,  glass,  125  mm 

Filter  paper,  Watman  #50  (18.5  inch) 

Equipment  for  determining  pH  and  hardness 


1. 
2. 


Calcium  carbonate,  reagent  grade. 
Reagents  for  determining  pH  and  hardness. 


E.  Procedure 


1. 
2. 

3. 


Measure  the  temperature  of  the  water  to  be  tested. 

Measure  the  pH,  hardness  and,  if  desired,  the  alkalinity 
of  the  sample  being  tested. 

Insert  the  stirring  bar  in  the  BOD  bottle  and  fill  with  the 
water  being  tested.  Adjust  the  water  temperature  io 
within  IX  of  the  initial  temperature.  Add  approximately 
one  (1)  gram  of  calcium  carbonate  and  stir  for  five 
minutes  at  a  rate  high  enough  to  keep  the  calcium 
carbonate  in  suspension  and  the  sample  vigorously 
agitated. 

4.  Recheck  the  temperature.  If  the  temperature  has 
changed  more  than  one  degree  Celcius,  repeat  the 
stirring  with  a  fresh  sample  whose  temperature  has 
been  adjusted  so  that  the  final  temperature  will  be  within 
one  degree  Celcius  of  the  initial  temperature. 

5.  Immediately  measure  the  final  pH. 

6.  Filter  the  remaining  sample.  Determine  the  hardness 
and,  if  desired,  the  final  alkalinity  on  the  filtrate  (v/ater 
that  passed  through  the  filter). 

F.  Example 

Results  from  a  series  of  tests  for  the  calcium  carbonate 
precipitation  potential  were  as  follows* 

  Filtered  Water  Sample 


Initial  Temperature 
Final  Temperature 

Initial  pH 
Final  pH 

Initial  Hardness 
Final  Hardness 

Initial  Alkalinity 
Fina»  Alkalinity 

G.  Calculation 

Calcium  Carbonate 
Precipitation 
Potential 


14*^0 
14^0 

8.7 
9.1 

34  mg/l 
38  mg/L 

24  mg/l 
27  mg/l 


=  Initial  Hardness  -  Final  Hardness 


The  Langelier  Index^  is  approximately  equal  to  the  initial 
pH  -  final  pH.  If  the  value  of  this  index  is  less  than  0.2.  this 
value  will  indicate  that  the  water  is  very  near  the  saturation 
level.  In  any  event,  the  sign  of  this  value  will  be  the  same  as 
the  sign  of  the  Langelier  index.  That  is  to  say,  both  the 
Langelier  Index  and  the  calcium  carbonate  precipitation 
potential  will  be  negative  if  the  water  is  undersaturated  and 
positive  if  the  water  is  supersaturated. 


^  !/zKp/«r'?r.(t;fm/  ho'J/i'''^^''^^^'^''^*"^     equMriumpHofa  water  with  respect  to  calcium  andalkahmty.  ms.ndexis  usedm  stabi^ 
itzmg  water  to  control  both  corrosion  and  deposition  of  scale. 

Langelier  Index  =  pH  -  pH€ 

Where  pH    actual  pH  of  the  water,  and 

pHs  -  pH  at  which  water  having  the  same  alkalinity  and  calcium  conterjt  is  just  saturated  with  calcium  carbonate. 


ERIC 


487 


Lab  Procedures  467 


OUTLINE  OF  PROCEDURE  FOR  MARBLE  TEST 


(Marble  Test) 


O  0 


1.  Measure  temperature,  pH 
hardness,  and  alkalinity 
of  sample  being  tested. 


2.  Transfer  to  BOD  bottle  and 
add  1  g  calcium  carbonate. 
Mix. 


3.  Measure  final  pH  and 
temperature 


T 

7 

0 


4.  Filter. 


5.  Determine  hardness 
and  alkalinity  of 
filtrate. 


From  the  example  above: 
Caictum  Carbonate 


Preapitatton 
Potential 


Langelier  index 


initial  Hardness,  mg/l  -  Final  Hardness.  mg/L 

~  34  mg/l  -  J8  mg/t 
=  -4 

^  Initial  pH  -  Final  pH 
=  8.7  -  9.1 
^  -0  4 


This  water  is  undersaturated  (and  therefore  corrosive)  with 
respect  to  calcium  carbonate. 

10.  Metals 

A.  Discussion 

The  presence  of  certain  metals  in  drinking  water  can  be  a 
matter  of  serious  concern  because  of  the  toxic  properties  of 


ERIC 


these  materials.  The  analyses  of  these  metals  is  generally 
done  by  using  atomic  absorption  spectroscopy  or  colorimet- 
nc  methods.  The  term  "metals"  would  include  the  following 
elements: 


Aluminum 

Antimony 

Arsenic 

Barium 

BerrylliUHi 

Cadmium 

Calcium 

Chromium 


Cobalt 
Copper 
Iron 
Lead 

Magnesium 

Manganese 

Mercury 

Molybdenum 

Nickel 


Potassium 

Selenium 

Silver 

Sodium 

Than:um 

Tin 

Titanium 

Vanadium 

Zinc 


B.  Reference 
For  materials  and  procedures  see: 
Page  143,  STANDARD  METHODS,  16th  Edition. 


4«« 


468  Water  Treatment 


(Nitrate) 


QUESTIONS 

Write  your  answers  In  a  notebook  and  then  compare  yo  tr 
answers  with  those  on  page  483. 

21. IN  Why  is  temperature  important  when  running  the 
Marble  Test? 

21.10  The  results  from  the  Marble  Test  produce  an  initial 
pH  of  8.9  and  a  fin=il  pH  of  8.6.  Would  this  water  be 
considered  corrosive? 

21  .IP  How  are  the  concentrations  of  most  metals  in  water 
measured? 


11.  Nitrate 

A.  Discussion 

Nitrate  represents  the  most  completely  oxidized  form  of 
nitrogen  found  in  water.  High  levels  of  nitrate  in  water 
indicate  biological  wastes  in  ihe  final  state  of  stabilization  or 
runoff  from  fertilized  areas.  High  nitrate  levels  degrade 
water  quality  by  stimulating  excessive  algal  growth.  Drinking 
water  that  contains  excessive  amounts  of  nitrate  can  cause 
infant  methemoglobinema  (blue  babies).  For  this  reason  a 
level  of  10  mg/L  (as  Nitrogen)  has  been  established  as  a 
maximum  level.  The  procedure  given  below  measures  the 
amount  of  both  nitrate  and  nitrite  nitrogen  present  in  a 
sample  by  reducing  all  nitrate  to  nitrite  through  the  use  of  a 
copper-cadmium  column.  The  total  nitrate  (any  nitrite  pre- 
sent originally  plus  the  reduced  nitrate)  is  then  measured 
colonmetrically. 


B. 


What  IS  Tested? 

Sample 


Common  Range.  mg/L 


Treated  Surface  Water  <0.1  to  5 

Groundwater  0.5  to  1 0 

C.  Apparatus 

Reduction  column.  The  column  in  Figure  21 .2  was  con- 
structed from  a  100  mL  volumetric  pipet  by  removing  the  top 
portion.  This  column  may  also  be  constructed  from  two 
pieces  of  tubing  joined  end  to  end.  A  10  cm  length  of  3  cm 
I.D.  tubing  is  joined  to  a  25  cm  length  of  3.5  mm  i.D.  tubing.  A 
column  may  be  purchased  from  HACH  Company.  Order  by 
Code  No.  14563-00.  $85.20,  Post  Office  Box  389.  Loveland. 
Colorado  80539. 

Spectrophotometer  for  U5>e  at  540  nm.  providing  a  light 
path  of  1  cin  cr  longer 

Beakers.  125  mL 
Glass  wool 

Glass  fiber  filter  or  0.45  micron  membrane  filter 


Filter  holder  assembly 
Filter  fiask 
pH  meter 

Separatory  funnel.  250  mL 
Pipets.  volumetric.  1,  2.  5.  and  10  mL 
D  Reagents 

1 .  Granulated  cadmium:  40  to  60  mesh  (available  from:  cM 
Laboratories.  Inc..  500  Executive  Boulevard.  Elmsford. 
New  York  10523.  Catalog  No.  2001  Cadmium.  Coarse 
Powder  and  HACK  Company.  Catalog  No.  74560-26). 

2.  Copper-Cadmium:  The  cadmium  granules  (new  or  used) 
are  cleaned  with  6  A/HCI  and  copperized  with  2  percent 
solution  of  copper  sulfate  in  the  following  mar.ner: 

a.  Wash  the  cadmium  with  6  N  HCI  and  rinse  wilh 
distilled  water.  The  color  of  the  cadmium  should  be 
Silver. 

b.  Swirl  25  gm  cadnrium  in  100  rng/L  portions  of  a  2 
percent  solution  of  copper  sulfate  for  5  minutes  or 
until  the  blue  color  partially  fades,  decant  and  repeat 
with  fresh  copper  until  a  brown  precipitate  foi  tis. 

c.  Wash  the  copper-cadmium  with  distilled  water  at 
least  10  times  to  remove  all  the  precipitated  copper. 
The  color  of  the  cadmium  should  now  be  black. 

3.  Preparation  of  reaction  column:  Insert  a  glass  wool  plug 
into  the  bottom  of  the  reduction  column  and  fill  with 
distilled  water.  Add  sufficient  copper-cadmium  granules 
to  produce  a  column  18.5  cm  In  length.  Maintain  a  level 
of  distilled  water  above  the  coppsr-cadmium  granules 
to  eliminate  entrapment  of  air.  Wash  the  column  with 
200  mL  of  dilute  ammonium  chloride  —  EDTA  solution 
(reagent  5).  The  column  is  then  activated  by  passing 
through  the  column  100  mL  of  solution  composed  of  25 
mL  of  a  1.0  mg/L  NOg-N  standard  and  75  mL  of 
concentrated  ammonium  chloride  —  EDTA  solution. 
Use  a  flow  rate  of  7  to  10  mL  per  minute.  Collect  the 
reduced  standard  until  the  level  of  solution  is  0.5  cm 
above  the  top  of  the  granules.  Close  the  screw  clamp  to 
stop  flow.  Discard  the  reduced  standard. 

4.  Measure  about  40  mL  of  concentrated  ammonium  chlo- 
ride —  EDTA  and  pass  through  column  at  7  to  10  mL 
per  minute  to  wash  nitrate  standard  off  column.  Always 
leave  at  leasi  0.5  cm  of  liquid  above  top  of  granules.  The 
column  is  now  reac*y  for  use. 

5.  Dilute  ammonium  chlcnde  ~  EDTA  solution.  Dilute  300 
mLof  concentrated  ammonium  chloride  — -  EDTA  solu- 
tion (reagent  4)  to  500  mL  with  distilled  water. 

6.  Color  reagent. 

7.  Zinc  sulfate  solution. 

8.  SoJi'j'^i  hydroxide.  6  A/. 

9.  Ammonium  hydroxide,  concentrated. 

1 0.  Hydrochlonc  acid,  6  A/.  Dilute  50  mL  concentrated  HCI  to 
100  mL  with  distilled  water. 

11.  Copper  sulfate  sclution.  2  percent. 

12.  Nitrate  stock  solution.  1.0  mL  =  1.00  mg  NO3-N.  Pre- 
serve with  2  mL  of  chloroform  per  liter.  This  solution  is 
stable  for  at  least  six  months. 


EMC 


483 


Lab  Procedures  469 


(Nitrate) 


10  CM 


80-85  tttL 


CM  I.D. 


3.5  MM  I.D. 


100  mL 
VOLUMETRIC 
PIPET 


-  Cut 


GLASS  WOOL  PLUG 
CLAMP 


TYGON  TUBING 


-  Cut 


\/ 


F\g.  21.2  Reduction  column 


490 


470  Water  Treatment 

(Nitrate) 

13.  Nitrate  standard  solution.  1.0  mL  =  0.01  NO3-N. 
Dilute  10.0  mL  of  nitrate  stock  solution  (reagent  12)  to 
1000  mL  with  distilled  water. 

14.  Chloroform. 

E.  Procedure 

Removal  of  Interferences  (if  necessary). 

"  Turbidity  removal.  Use  one  of  the  following  mathods  to 
remove  suspended  matter  that  can  clog  the  reduction 
column. 

a.  Filter  sample  through  a  glass  fiber  or  a  0.45  micron 
pore  size  filter  as  long  as  the  pH  is  less  than  8,  or 

b.  Add  1  mL  zinc  solution  (reagent  7)  to  1 00  mL  sample 
and  mix  thoroughly.  Add  enough  (usually  8  to  10 
drops)  sodium  hydroxide  stiution  (reagent  8)  to 
obtain  a  pH  of  10.5.  Let  treated  sample  stand  a  few 
minutes  to  allow  the  heavy  flocculent  precipitate  to 
settle.  Clarify  by  filtering  through  a  glass  fiber  filcer. 

Reduction  of  Nitrate  to  Nitrite. 

1 .  Using  a  pH  meter  adjust  the  pH  of  sample  (or  standard) 
to  between  5  and  9  either  with  concentrated  HCI  or 
concentrated  NH^OH. 

2.  To  25  mL  of  sample  (or  standard)  or  aliquot  diluted  to  25 
mL.  add  75  rr.L  of  concentrated  ammonium  chloride 
EDTA  solution  and  mix. 

3.  Pour  sample  Into  column  and  collect  reduced  sample  at 
a  rate  of  7  to  10  mL  per  minute. 

4.  Discard  the  first  25  mL.  Collect  the  rest  of  the  sample 
(approximately  70  mL)  In  the  original  sample  flask. 
Reduced  samples  should  not  be  allowed  to  stand  longer 
than  15  minutes  before  addition  of  color  reagent. 

5.  Add  2.0  mL  of  color  reagent  to  50  mL  of  sample.  Allow 
10  minutes  for  color  development.  Within  two  hours 
measure  the  absorbance  at  540  nm  against  a  reagent 
blank  (50  mL  distilled  water  to  which  2.0  .nL  color 
reagent  has  been  added). 

F.  Construction  of  Standard  Calibration  Graph 

1.  Prepare  working  standards  by  pipeting  the  following 
volumes  of  nitrate  standard  solution  into  each  of  five 
100  mL  volumetric  flasks. 

Add  this  volume  of  Nitrate       Concentration  of 
Standard  Solution  to  100  mL  flask    NO^-N  in  mg/L 

0.0  0.00 

1.0  0,10 

2.0  0.20 

5.0  0.50 

10.0  1.00 

Dilute  each  to  100  mL  with  distilled  water  and  mix. 

2.  Determine  the  amount  of  nitrate-nltnte  as  outlined 
above  in  the  procedure  for  reduction  of  nitrate  to  nitnte. 

3.  Plot  on  a  sheet  of  graph  paper  the  absorbance  versus 
concentration. 

G.  Example 

Results  from  the  analyjes  of  samples  and  working  stand- 
ards for  nitrate-fiitnte  were  as  follows: 

ER?C 


Rask  # 

Volume  Absorbance 

1 

Jones  St.  Well 

25  mL 

0.440 

2 

Blank  (distilled  water) 

25  mL 

0.00 

3 

0.10  mg/L  NO3-N 

25  mL 

0.075 

4 

0.20  mg/L  NO3-N 

25  mL 

0.142 

5 

0.50  mg/L  NO3-N 

25  mL 

0.355 

6 

1.00  mg/L  NO3-N 

25  mL 

0.700 

H.  Calculation 

I.  Using  graph  paper,  plot  the  absorbance  values  of 
working  standards  versus  their  known  concentrations. 
For  example,  from  the  above  data  the  following  graph 
can  be  constructed. 


10        }0        30       .40       50        60        70       10        90  10 


NITRATE  &  NITRITE-NITROGEN,  mg/L 


2.    Read  concentration  of  NO3  +  NOg  nitrogen  in  plant 
effluent  from  graph  shown  below. 

mg/L  nitrate  +  nitrite  niirogen  in  sample  =  0,62  mg/L 


NITRATE  &  NITRITE-NITROGEN,  ng/L 
(NO3  +  (NO2  -  N) 


3.  Determine  concentration  of  NItnte-Nitrogen  (NOg-N)  in 
sample  using  nitnte  procedure. 

4.  Subtract  nitrite  from  NOg  +  NO3  nitrogen  concentration. 
The  result  is  the  amount  of  nitrate  nitrogen  in  sample. 

491 


Lab  Procedures  471 


5.  For  examole.  if  the  sample  of  Jones  St.  Well  used  in  the 
above  example  contained  no  nitrite  nitrogen  then  the 
nitrate  nitrogen  (NO3-N)  would  be  0.62  mg/L. 

I  Notes 

1 .  If  concentration  of  titrate  in  the  sample  is  greater  than  1 
mg/L,  then  the  s^iimple  must  be  diluted. 

2.  Cadmium  malal  iS  v*"!y  to^  'c  thus  caution  must  be 
ex  .•'^'5d  ir»  Its  use.  ,ubbwi  gloves  should  be  used 
w» .     'c;  il  IS  hanc'ied. 


J.  Reference 


See  page  394,  STANDARD  METHODS,  16th  Edition. 

12.  pH  by  Jack  Rossum 

DISCUSSION 

This  discussion  is  presented  to  give  you  a  better  under- 
standing of  what  a  pH  value  actually  represents.  Procedures 
for  measuring  pH  are  given  in  Chapter  11,  "Laboratory 
Procedures." 

Pure  water  dissociates  according  to  the  following  reac- 
tion: 

y\p  -  H*  +  OH". 

At  25'^C  and  a  pH  of  7,  the  activity  of  the  hydrogen  ion  is 
equal  to  the  activity  of  the  hydroxyl  ion  at  .000  000  1  moles/li- 
ter. "Activity"  is  a  term  used  by  chemists  to  allow  real  atoms, 
molecules  and  ions  to  behave  as  If  they  were  perfect 
particles  (having  zero  size).  Activity  is  obtained  by  multiply- 
ing the  concentration  by  an  activity  coefficient.  The  value  of 
the  activity  coefficient  depends  on  the  electrical  charge  on 
ihe  particle,  the  temperature  and  the  other  substances 
dissolved  in  the  water.  For  hydrogen  ion  the  activity  coeffi- 
cient at  rS'^C  varies  from  0.996  in  pure  water  to  0.900  in 
water  containing  400  mg/L  of  dissolved  solids.  Activities  are 
expressed  in  moles  per  liter  which  Is  assumed  to  be  the 
number  of  grams  per  liter  since  the  molecular  weight  of 
hydrogen  Ion  Is  1.008  (almost  1.0). 

When  the  activities  of  the  hydrogen  and  hydroxyl  Ions  are 
equal,  the  solution  is  neutral.  If  hydrogen  ions  are  in  excess, 
the  solution  is  acid  and  if  hydroxyl  Ions  are  in  excess,  the 
solution  IS  alkaline.  An  Important  property  of  water  is  that  for 
any  temperature,  the  product  of  the  activities  of  these  ions  is 
a  constant.  At  25*'C,  this  constant  is  .000  000  000  000  01. 

In  a  strong  solution  of  hydrochloric  acid,  the  hydrogen  ion 
activity  may  be  as  high  as  1  mole  per  liter,  while  In  a  strong 
solution  of  lye,  the  hydroxyl  ion  concentration  may  be  as 
high  as  1  mole  per  liter.  To  avoid  the  Inconvenience  of 


(pH) 

writing  these  very  small  numbers,  hydrogen  ion  activities  are 
expressed  in  terms  of  pH,  with 

pH  =  log^o  _1_ 

The  relation  between  pH,  H'  and  OH  at  25X  is  shown  in 
Table  21.2. 

Most  natural  waters  have  pH  values  between  6  5  and  8.5. 
Human  blood  has  a  pH  of  7.4  and  the  gastric  juices  in  your 
stomach  have  a  pH  of  approximately  0.9  to  aid  in  the 
digestion  of  food. 

Alum  coagulates  most  effectively  at  pH  values  near  6.8. 

The  pH  of  natural  waters  is  controlled  by  the  relative 
amounts  of  carbon  dioxide,  bicarbonate,  and  carbonate 
ions.  Ram  water  usually  has  a  pH  of  slightly  less  than  7 
because  carbon  dioxide  from  the  air  dissolves  to  form 
carbonic  acid. 

QUESTIONS 

WriVe  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  483. 

21. 1Q  How  IS  n'trate  measured  in  the  nitrate  test? 

21.1  R  If  turbidity  is  interfering  with  a  nitrate  analysis,  how 
can  turbidity  be  removed? 

21.13  The  pH  of  natural  waters  Is  usually  controlled  by  the 
relative  amounts  of  what  ions? 


TABLE  21.2    RELATION  BETWEEN  pH, 
AND  OH-  AT  25°C 


Activity  of 

Activity  of  OH" 

moles/L 

moles/L 

pH 

1. 

0.000  000  000  000  01 

0 

0.1 

0  000  000  000  000  1 

1 

0  01 

0.000  000  000  001 

2 

0  001 

0.000  000  000  01 

3 

0  000  1 

0.000  000  000  1 

4 

0  000  01 

0.000  000  001 

5 

0.000  001 

0.000  000  01 

6 

0.000  000  1 

0.000  000  1 

7 

0.000  000  01 

0.000  001 

8 

0.000  000  001 

0.000  01 

9 

0.000  000  000  1 

0.000  1 

10 

0.000  000  000  01 

0.001 

11 

0.000  000  000  001 

0.01 

12 

0.000  000  000  000  1 

0.1 

13 

0.000  000  000  000  01 

1. 

14 

13.  Specific  Conductance 

A.  Discussion 

Spe'  J  conductance  or  conductivity  is  a  numerical  ex- 
pression (expressed  in  micromhos  per  centimeter)  of  the 
ability  of  a  water  to  conduct  an  electrical  current.  This 
number  depe'^ds  on  the  total  concentration  of  the  minerals 
dissolved  in  the  sample  (TDS)  and  the  temperature. 
Changes  in  conductivity  om  normal  may  indicate  changes 
in  mineral  composition  of  the  water,  seasonal  variations  in 
lakes  and  re^^^rvoirs,  or  intrusion  of  pollutants.  The  custom 
of  reporting  conductivity  values  in  microhmos/cm  at  25°C 


472  Water  Treatment 


(Sulfate) 


requires  the  accurate  determination  of  each  sample's  tem- 
perature at  the  time  of  conductivity  measurement 

Specific  conductance  is  measured  by  the  use  of  a  conduc- 
tivity meter. 


B.  What  IS  Tested'? 


Sample 


Common  Range, 
micromhos/cm 


Raw  and  Treated 
Surface  Waters 

Groundwater 


C.   Materials  and  Procedure 


30  to  500 


100  to  1000 


Follovi/  ins  ument  manufacturer's  instructions.  Also  see 
page  76,  STANDARD  METHODS,  16h  Edition. 


14.  Sulfate 

A.  Discussion 

The  sulfate  ion  is  one  of  ihe  major  anions  occurring  in 
natural  v\/aters.  Sulfate  ions  are  of  importance  in  water 
supplies  because  of  the  tendency  of  appreciable  amounts  to 
form  hard  scales  in  boilers  and  heat  exchangers.  The 
secondary  maximum  contaminant  level  for  sulfate  listed  in 
the  Safe  Drinking  Water  Act  is  250  mg/L. 


B.   What  IS  Tasted'? 

Sample 


Common  Range,  mg/L 


Raw  or  Treated  Water  Supply  5  -  1 00 

Apparatus  Required 

Turbidimeter  OR  spectrophotometer 
Stopwatch  or  timer 
Measuring  spoon,  0  3  m/. 
Magnetic  stirrer 
Magnetic  stir-bar 
Pipet,  10  vnL 

Flasks,  Erienmeyer,  250  mL 
Reagents 

(Note.   Standardized  solutions  are  commercially  avail- 


able.) 
1 
2 


Conditioning  reagent. 

Barium  chlonde,  BaClg,  crystals:  Sized  for  turbidimetnc 
work.'  To  ensure  uniformity  of  results,  construct  a 
standard  curve  for  each  batch  of  BaClg  crystals. 

Standard  sunate  solution:  Prepare  a  standard  sulfate 
solution  as  described  in  (a)  or  (b)  below;  1.00  mL  -  0.10 
mg  SO4. 

(a)  Dilute  10.41  vnL  standard  0.0200  N  H^SO^  titrant 
specified  in  Alkalinity  Test,  Chapter  11,  to  100  m/_ 
with  distilled  water. 


(b)  Dissolve  147.9  mg  anhydrous  Na^SO^  in  distilled 
water  and  dilute  to  1,000  mL. 


E  Procedure 

1  Place  100  mL  of  sample  or  a  suitable  portion  diluted  to 
100  mL  into  a  clean  250  mL  Erienmeyer  flask 

2.  Add  5  0  mL  of  conditioning  reagent  and  mix 

3.  While  stirnng,  add  a  spoonful  of  barium  chloride  crys- 
tals. Stir  for  exactly  1  minute. 

4.  Measure  turbidity  at  30-second  intervals  for  4  minutes. 
Consider  turbidity  to  be  the  maximum  reading  obtained 
in  the  4-minute  interval. 


F.    Construction  of  Standard  Calibration  Curve 

1.    Using  the  standard  solution  prepare  the  following 
standards  in  100  mL  volumetric  flasks. 

mL  of  Standard  Sulfate  Solution  Sulfate 
Placed  in  100  mL  Volumetric  Flask    Concentration,  mg/L 


2. 
3. 
4. 
5 


5.0 
100 
150 
20  0 
25  0 


50 
100 
150 
20.0 
25  0 


Dilute  flasks  to  100  mL. 
Transfer  to  250  mL  Erienmeyer  flask. 
Determine  amount  of  sulfate  as  outlined  previously. 

Prepare  a  standard  curve  by  plotting  turbidity  values  of 
standards  versus  the  corresponding  sulfate  concentra- 
tions. Set  nephelometer  (or  spectrophotometer)  at  zero 
sulfate  concentration  using  distilled  water  as  a  control. 

I.  Example 

Results  from  a  series  of  tests  for  sulfate  were  as  follows: 


Flask 

Sample 

Volume 

Tuibidity 

1 

Distilled  Water 

100  mL 

0 

2 

Plant  Effluent 

100  mL 

35 

3 

Jor.es  St.  Well 

50  mL 

45 

4 

5.0  mg/L  SO4  Standard 

100  mL 

11 

5 

10.0  mg/L  SO^  Standard 

100  mL 

29 

6 

15.0  mg/L  SO^  Standard 

100  mL 

40 

7 

20.0  mg/L  SO^  Standard 

100  mL 

53 

H.  Calculation 

I.  Prepare  1  standard  curve  by  using  data  from  prepared 
standards  From  t^e  above  example: 


Concentration  Sulfate,  mg/L 


Turbidity,  TU 


0.0 
5.0 
10.0 
15.0 
20.0 


0.0 

11 

29 
40 
53 


'  Baker  No.  0974  or  equivalent. 


Lab  Procedures  473 


(Sulfate) 

OUTLINE  OF  PROCEDURE  FOR  SULFATE 


The  graph  below  is  the  result  of  plotting  concentration  of  2.  Obtain  concentration  of  unknown  plant  and  well  sam- 
standards  versus  their  corresponding  turbidity,  pies  from  curve. 


474  Water  Treatment 


(Taste  and  Odor) 

3.    Correct  (if  necessary)  for  samples  of  less  than  100  mi. 
by  using  the  following  formula: 

Sulfate,       ^  (Graph  Sulfate.  ma/LU100  mD 


mg/L  SO4 

Samp! 

9  Size,  mi. 

Using  data  from  example. 

Tample 
Volume 

Turbidity 

Concentration 
from  Graph 

Plant  Effluent 

100  mL 

35  TU 

13  mg/L 

Sulfate,  mg/L 

-  13mg/t 

Sample 
Volume 

Turbidity 

Concentration 
from  Graph 

Jones  St  Well 
Sulfate,  mg/L 


50  mL       45  TU 
^  (Sulfate,  mg/L)(10U  mL) 

Sample  Size.  niL 
^(17  mg/L)(100  mL) 

(50  mL) 
^  34  mg/L  SO4 


17  mg/L 


Notes 


A  spectrophotometer  can  be  used  to  measure  ab- 
sorbance  of  barium  sulfate  suspension.  Use  at  420 
nanometer  (nm)  wavelength. 

Color  or  suspended  matter  will  interfere  when  present  in 
large  amounts.  Correct  for  these  items  by  testing  blanks 
from  which  banum  chloride  is  withheld. 

Analyze  samples  and  standards  with  their  temperatures 
in  the  range  of  20  to  25°C. 

Reference 

See  page  467,  STANDARD  METHODS,  l6th  Edition. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  483. 

21. 1T  What  IS  the  meaning  of  specific  conductance  or 
conductivity'^ 

21 .1 U  Sulfate  ions  are  of  concern  in  drinking  water  for  what 
reason'^ 

21  IV  A  50  mL  sample  from  a  well  produced  a  turbidity 
reading  of  40  TU  using  a  nephelometer  (turbidi- 
meter). What  was  the  sulfate  concentration  in  mg/L? 


15.  Taste  and  Odor 

A.  Discussion 

Taste  and  odor  are  sensory  clues  that  provide  the  first 
warning  of  potential  hazards  in  the  environment.  Water,  in  its 
pure  form,  cannot  produce  odor  or  taste  sensations.  Howev- 
er, algae,  actinomycetes,  bacteria,  decaying  vegetation, 
metals,  and  pollutants  can  cause  tastes  and  odors  in  drink- 
ing water.  Corrective  measures  designed  to  reduce  unpleas- 
ant tastes  and  odors  include  aeration  or  the  addition  of 
chlorine,  chlonne  dioxide,  potassium  permanganate  or  acti- 
vated carbon. 

Odor  IS  considered  a  quality  factor  affecting  acceptability 
of  drinking  water  (and  foods  prepared  with  it),  tainting  of  fish 
and  other  aquatic  organisms,  and  aesthetics  of  recreational 
waters.  Most  organic  and  some  inorganic  chemicals  contrib- 
ute to  taste  and  odor.  These  chemicals  may  originate  from 
municipal  and  industrial  waste  discharges,  from  natural 
sources  (such  as  decomposition  of  vegetable  matter),  or 
from  associated  microbial  activity. 


Some  substances,  such  as  certain  inorganic  salts,  pro- 
duce taste  without  odor.  Many  other  sensations  considered 
to  cause  taste  actually  cause  odors,  even  though  the  sensa- 
tion is  not  noticed  until  the  water  Is  in  the  mouth. 

Taste,  like  odor,  is  one  of  the  chemical  senses.  Taste  and 
odor  are  different  in  that  odors  are  sensed  high  up  in  our 
nose  and  tastes  are  sensed  on  our  tongue.  Taste  Is  simpler 
than  odor  because  there  may  be  only  four  true  taste  sensa- 
tions: sour,  sweet,  salty,  and  bitter.  Dissolved  inorganic  salts 
of  copper,  iron,  manganese,  potassium,  sodium,  and  zinc 
can  be  detected  by  taste. 

Operators  must  remember  that  a  tasteless  water  is  not  the 
most  desirable  water.  Distilled  water  is  considered  less 
pleasant  to  dnnk  than  a  high-quality  water.  The  taste  test 
must  determine  the  taste  intensity  by  the  threshold  test  and 
also  evaluate  the  quality  of  the  dnnking  water  on  the  basis  of 
desirability  for  consumers. 


ERIC 


49, 


Lab  Procedures  475 


B.  Apparatus  Required 

Sample  bottles,  glass-stoppered  or  with  TFE-lined  clo- 
sures 

Constant  temperature  bath 

Odor  flasks  (600  mL  glass  stoppered  Erienmeyer  flasks) 
Transfer  and  volumetric  pipets  or  graduated  cylinders 

(200,  100,  60.  and  25  mL) 
Measuring  pipets  (10  mL,  graduated  in  0  1  mLs) 
Thermometer  (0  to  110°C) 

C  Precautions 

Use  preliminary  tests  to  select  the  persons  to  make  taste 
or  odor  tests.  Use  only  persons  who  want  to  participate  in 
the  test.  Avoid  distracting  odors  such  as  those  caused  by 
smoking,  foods,  soaps,  perfumes,  and  shaving  lotions.  The 
testers  should  not  have  colds  or  allergies  that  affect  odor 
response.  Do  not  have  the  testers  perform  too  many  tests 
and  allow  frequent  rests  so  the  testers  won't  become  tired 
and  lose  their  sensitivity.  Keep  the  room  in  which  the  tests 
are  conducted  free  from  distractions,  drafts  and  odors. 

A  panel  of  five  or  more  testers  is  recommended  for 
precise  work.  Do  not  allow  the  testers  to  prepare  the 
samples  or  to  know  the  dilution  concentrations  being  evalu- 
ated. Familiarize  testers  with  the  procedure  before  they 
particip*  In  a  panel  test.  Present  most  dilute  sample  first  to 
avoid  tinng  the  senses  with  a  concentrated  sample.  Keep 
temperature  of  sample  during  test  within  1°C  of  the  specified 
temperature.  Use  opaque  or  darkly  color'^d  flasks  to  avoid 
biasing  the  results  due  to  turbid  or  colored  waters  being 
tested. 

D.  Procedure 
ODOR 

1.  Determine  the  approximate  range  of  the  threshold  odor 
number  by  adding  200  mL,  50  mL,  12  mL,  and  2.8  mL  of 
sample  to  500  mL  glass-stoppered  Erienmeyer  flasks 
containing  odor-free  water^  to  make  a  total  volume  of 
200  mL.  Use  a  separate  flask  containing  only  odor-free 
water  as  a  reference  for  comparison.  Heat  dilutions  and 
reference  to  desired  test  temperature  (usually  60°C  or 
140T). 

2.  Shake  flask  containing  odor-free  water,  remove  stop- 
per, and  sniff  vapors.  Test  sample  containing  least 
amount  of  odor-bearing  water  in  ihe  same  way.  If  an 
odor  can  be  detected  in  this  dilution,  prepare  more 
dilute  samples. 


(Taste  and  Odor) 

To  prepare  more  dilute  samples,  prepare  an  interme- 
diate dilution  consisting  of  20  mL  sample  diluted  to  200 
mL  with  odor-free  water.  Use  this  dilution  for  the  thresh- 
old determination.  Multiply  the  threshold  odor  number 
(T  O.N.)  obtained  by  10  to  correct  for  the  intermediate 
dilution. 

If  an  odor  cannot  be  detected  in  the  first  dilution, 
repeat  the  above  procedure  using  sample  containing 
the  next  higher  concentration  of  odor-beanng  water  and 
continue  this  process  until  odor  is  detected  clearly. 

3.  Based  on  the  results  obtained  in  the  preliminary  test, 
prepare  a  set  of  dilutions  using  Table  21.3  as  a  guide. 
Prepare  the  five  dilutions  shown  in  the  approprir.ee 
column  and  the  three  next  most  concentrated  in  the 
next  column  to  the  right  in  Table  21.3.  For  example,  if 
odor  was  first  noted  in  the  flask  containing  the  50  mL 
sample  in  the  preliminary  test,  prepare  flasks  containing 
50,  35,  25,  17,  12,  8.3,  5.7.  and  4.0  mL  sample,  each 
diluted  to  200  mL  with  odor-free  water.  This  procedure 
IS  necessary  to  challenge  the  range  of  sensitivities  of 
the  entire  panel  of  testers. 


TABLE  21.3   DILUTIONS  FOR  VARIOUS  ODOR 
INTENSITIES 

PRELIMINARY  TEST 
Sample  Volume  in  Which  Odor  First  Noted 


200  mL  50  mL  12  mL  3.8  mL 

FINAL  TEST 

Volume  in  mL  of  Sample  to  be  Diluted  to  200  mL 

200  50  12  (Intermediate 

140  35  8.3  dilution) 

100  26  5.7 

70               17  4.0 

50               12  2.8 


Insert  two  or  more  blanks  near  the  expected  thresh- 
old, but  avoid  any  repeated  patterns.  Do  not  let  the 
testers  know  which  dilutions  are  odorous  and  which  are 
blanks.  Instruct  each  tester  to  smell  each  flask  in 
sequence,  beginning  with  the  least  concentrated  sam- 
ple, until  odor  is  detected  with  certainty. 

4.  Record  observations  by  indicating  whether  odor  is 
noted  in  each  flask.  For  example 

mL  Sample  Diluted 

to200  mL  12    0    1/  25    0    35  50 

Response  _         -    4.    _    +  + 

5.  Calculate  the  threshold  odor  number  (T.O.N.)  as  shown 
in  E.  Calculations. 

TASTE  THRESHOLD  TEST 

1.  The  taste  threshold  test  is  used  when  the  purpose  is 
quantitative  measurement  of  detectable  taste.  When 
odor  IS  the  predominant  sensation,  as  in  the  case  of 
chlorophenols,  the  threshold  odor  test  takes  pnorii/. 

2.  Use  the  dilution  and  random  blank  system  described  for 
odor  tests  when  preparing  taste  sample^. 


^  See  STANDARD  METHODS,  16th  Edition,  page  85,  for  directions  on  how  to  prepare  odor-free  water 

ERIC  496 


476  Water  Treatment 


(T aste  and  Odor) 

3.  Present  each  dilution  and  blank  to  the  tester  in  a  clean 
50-mL  plastic  container  filled  to  the  30-mL  level.  Use 
high  quality  clear  plastic  containers.  Discard  the  plastic 
container  when  finished.  Do  not  use  glass  containers 
because  the  soap  used  to  clean  the  glass  could  leave  a 
residue  which  may  affect  the  results. 


4.  STANDAHD  METHODS  recommends  maintaining  the 
sample  presentation  at  40  ±  1°C(104  ±  2°F). 

NOTE:  Some  operators  use  normal  water  tempera- 
tures for  taste  tests  or  a  temperature  of  15°C 
(59°F). 

5.  Present  the  series  of  samples  to  each  tester.  Pair  each 
sample  with  a  known  blank. 

6.  Have  each  tester  taste  the  sample  by  taking  into  the 
mouth  whatever  voiume  is  comfortable,  holding  it  in  the 
mouth  for  several  seconds,  and  discharging  the  sample 
without  swallowing  the  water. 

7.  Have  the  tester  compare  the  sample  with  the  blank  and 
record  whether  a  taste  or  aftertaste  is  detectable  in  the 
s:  .pie. 

8.  Submit  samples  in  an  increasing  order  of  concentration 
until  the  tester's  taste  threshold  has  been  passed. 

9.  Calculate  individual  threshold  and  threshold  of  the  panel 
as  shown  in  E.  Calculations. 

TASTE  RATING  TEST 

1.  When  the  purpose  of  the  test  is  to  estimate  the  taste 
acceptability,  use  the  "taste  rating  test"  procedure  de- 
scribed below. 

2.  Samples  for  this  test  us>ually  represent  treated  water 
ready  for  human  consumption.  If  experimenta'ly  treated 
water  is  tested,  BE  CERTAIN  THAT  THE  WATER  IS 
SAFE  TO  DRINK  {no  pathogens  and  no  toxic  chemicals 
present). 

3.  Give  testers  thorough  instructions  and  trial  or  orienta- 
tion sessions  followed  by  questions  and  discussions  of 
procedures. 

4.  Select  panel  members  on  basis  of  performance  in  trial 
sessions. 

5.  When  testing  samples  testers  work  alone. 

6.  Present  samples  at  a  temperature  that  testers  find 
pleasant  for  drinking  water.  Maintain  this  temperature 
by  the  use  of  a  water  bath  apparatus.  A  temperature  of 
15X  (59®F)  is  recommended,  but  in  any  case,  do  not  let 
the  test  temperature  exceed  tap  water  temperatures 
that  are  customary  at  the  time  of  the  test.  Specify  the 
test  temperature  in  reporting  results. 

ERIC 


7  Present  each  dilution  and  blank  to  the  tester  in  a  clean 
50-mL  plastic  container  filled  to  the  30-mL  level.  Use 
high  quality  clear  plastic  containers.  Discard  the  plastic 
containers  when  finished.  Do  not  use  glass  containers 
because  the  soap  used  to  clean  the  glass  could  leave  a 
residue  which  may  affect  the  results. 

8.  Each  testffr  is  presented  with  a  list  of  nine  statements 
about  the  water  ranging  on  a  scale  from  very  favorable 
to  very  unfavorable  (Table  21.4).  The  testers  task  is  to 
select  the  statement  that  best  expresses  the  tester's 
opinion.  The  scored  rating  is  the  scaie  number  of  the 
statement  selected.  The  panel  rating  is  the  arithmetic 
mean  (average)  of  tne  scale  numbers  of  aH  testers. 

9.  Rating  involves  the  following  steps: 

a.  Initial  tasting  of  about  half  the  sample  by  taking  water 
into  the  mouth,  holding  it  for  several  seconds,  and 
discharging  it  without  swallowing; 

b.  Forming  an  initial  judgment  on  the  rating  scale: 

c.  A  second  tasting  is  made  in  the  same  manner  as  the 
first; 

d.  A  final  rating  is  made  for  tne  sample  and  t^.e  result  is 
recorded  on  the  appropriate  data  form; 

e.  Rinse  mouth  with  taste-  and  odor-free  water;  and 

f.  Rest  one  minute  before  repeating  steps  a  through  e 
on  the  next  sample. 

TABLE  21.4   ACTION  TENDENCY  RATING  SCALE  FOR 
TASTE  RATING  TEST 

1 .  I  would  be  very  happy  to  drink  this  water  as  my  everyday 
drinking  water. 

2.  I  would  be  happy  to  accept  this  water  as  my  everyday 
drinking  water. 

3.  I  am  sure  that  I  coula  accept  th's  water  as  my  everyday 
drinking  water. 

4.  I  could  accept  this  water  as  my  everyday  drinking  water. 

5.  Maybe  I  could  accept  this  water  as  my  everyday  drinking 
water. 

6.  I  don't  think  I  could  accept  this  water  as  my  everyday 
drinking  water. 

7.  I  could  not  accept  tf.iS  water  as  my  everyday  drinking 
water. 

8.  I  could  never  drink  this  water. 


9.  I  can't  stand  this  water  in  my  mouth  and  I  could  never 
drink  it. 


497 


Lab  Procedures  477 


(Taste  and  Odor) 


10.  Independently  randomize  sample  order  for  each  tester. 
Allow  at  least  30  minutes  rest  between  repeated  rating 
sessions.  Testers  should  not  know  the  composition  or 
source  of  samples. 

E.  Calculations 
FORMULAS 
1.  ODOR 

The  threshold  odor  number  (T.O.N.)  for  an  indi^'-dual 
tester  is  calculated  using  the  following  formula: 


T.O.N. 


B 


where: 

A  =  mL  sample  and 
B  =  mL  odor-free  water. 

The  threshold  odor  number  for  a  group  is  presented  as 
the  geometric  mean  of  the  individual  tester  thresholds. 

Geometric  Mean  =  (X,  x     x  X3  x  . . .  X„)'/" 

wiiere: 

X,  =  threshold  odor  number  for  tester  number  1, 

X2  =  threshold  odor  number  for  tester  number  2, 

X3  =  threshold  odor  number  for  the  nth  tester, 
and 

n  =  total  number  of  testers. 

2.  TASTR  THRESHOLD 

Calculate  the  individual  tester's  threshold  taste  num- 
ber and  the  threshold  taste  num  ber  for  a  panel  using  the 
same  formulas  that  are  used  for  the  threshold  odor 
tests. 

3.  TASTE  RATING 

Determine  the  taste  rating  for  a  water  by  calculating 
the  arithmetic  mean  and  STANDARD  DEVIATION^  of  all 
ratings  given  for  each  sample. 

Arithmetic   ^  X^  -f  X2  -i-  X3  -f  . . .  X„ 
Mean,  X  ^ 

where:    X,  =  taste  rating  for  tester  number  1, 
Xg  =  taste  rating  for  tester  number  2, 
Xn  =  taste  rating  for  nth  tester,  and 
n  =  number  of  testers. 


Standard  Deviation 


[ 
[ 


(X,  -  X)2  +  (X2  -  X)2  4       (Xn-X)2  1'/* 


n  -  1 


] 


(X,2  +  X22+         X„2)-(X,  +X2+       X^)^  fn  1'^ 


n  -  1 


] 


EXAMPLE  1 

Calculate  the  threshold  odor  nun  ber  (T.O.N.)  for  a  sample 
when  the  first  detectable  odor  occurred  when  the  25  mL 
sample  was  diluted  to  200  mL  (175  mL  of  ode-free  water 
was  added  to  the  25  mL  sample). 


A  or  Sample  Size,  mL       =  25  mL 
B  or  Odor-Free  Water,  mL  =  175  mL 

Calculate  the  threshold  odor  number.  T.O.N. 
T.O.N. 

A 

_25mL+  175  mL 


Unknown 

T.O.N. 


25  rpL 


=  8 


EXAMPLE  2 


Determine  the  geometric  mean  threshold  odor  number  for 
a  panel  of  five  testers  given  the  results  shown  below. 


Unknown 

Geometric  Mean  Threshold 
Odor  Number 


Known 

Tester  1.  X,  =8 
Tester  2.  Xg  =  6 
Tester  3,  X3  =  12 
Tester  4,  X^  =  8 
Tester  5,  X5  =  4 

Calculate  the  geometric  mean 

Ge^omeuic  Mean  ^       x  X2  x  X3  x  X,  x  X^)y- 

=  (8x6xl2x8x  4)^/5 
-  (18432)0  2 
=  7.1 

EXAMPLE  3 

Calculate  the  threshold  taste  number  for  a  sample  when 
the  first  detectable  taste  occurred  when  the  50  mL  sample 
was  diluted  to  200  mL  (150  mL  of  taste-free  water  was 
added  to  the  50  mL  sample). 


Known 


Unknown 


A  or  Sample  Size,  mL       =  50  mL  Threshold  Taste 

Number 

B  or  Taste-Free  Water,  mL  =  150  mL 


Calculate  the  threshold  taste  number. 


Threshold  Taste  Number 


_A  +  B 


_50  mL  +  150  mL 


50  mL 


=  4 


5  Standard  Deviation.  A  measure  of  the  spread  or  dispersion  of  data. 

'^^t  498 


478  Water  Treatment 


(Taste  and  Odor) 


EXAMPLE  4 

Determine  the  taste  rating  for  a  water  by  calculating  the 
arithmetic  mean  and  standard  deviation  for  the  panel  ratings 
given  below. 

Known  Unknown 

Tester  1,     =  4  1.  Arithmetic  Mean,  X 

Tester  2^X^=2  2.  Standard  Deviation,  S 

Tester  3,  X3  =  3 
Tester  4,  X^  =  5 
Tester  5,  X5  =  3 
Tester  6,  Xg  =  1 

1.  Calculate  the  arithmetic  mean,  X,  taste  rating. 

Arithmetic  Mean,  X  ^  X^  +  Xg  +  X3  +  X^  +  Xg  -f  Xg 
Taste  Rating  ^ 

^4+2+3+5+3+1 
6 

6 

=  3 

2.  Calculate  the  standard  deviation,  S,  of  the  taste  rating. 


ERIC 


439 


Lab  Procedures  479 


(Trihalomethanes) 


or 

Standard 
Deviation, 
S 


[ 


(X,^  +  X;^+X/  +  X/  +  X,^  +  X.2) 


(X,+X,+ 


/n 


n  -  1 


J 


[(4^+2^+3^  +5^+3^+1^)  -  (4+2+3+5  ^3+1)^6  "j 
6-1  J 


^  I  (16+4+9+25+9+1)  -  (18)^/6  "|  ^  ^ 
5 


^1^64  -  54 


m 


05 


=  1.4  (same  answer  as  before) 


F.  Reference 
Odor: 

See  page  85.  STANDARD  METHODS,  I6th  Edition. 
Taste: 

See  page  122,  STANDARD  METHODS,  16th  Edition. 
QUESTIONS 

Write  your  answers  in  a  notebool^  and  then  compare  your 
answers  with  those  on  page  483. 

21. 1W  List  the  items  that  can  cause  tastes  and  odors  in 
drinking  water. 

21. IX  Calculate  the  threshold  odor  number  (T.O.N.)  for  a 
sample  when  the  first  detectable  odor  occurred  when 
the  12  mL  sample  was  diluted  to  200  mL  (108  mL  of 
odor-free  water  was  added  to  the  12  mL). 

16.  Trihalomethanes 

A.  Discussion 

The  trihalomethanes  (THMs)  are  members  of  the  family  of 
organohalogen  compounds  which  are  named  as  derivatives 
of  methane.  Current  analytical  chemistry  applied  to  drinking 
water  has  thus  far  detected  chlorofcm.  bromodichloro- 
methane,  dibromochloromethane,  bromoform,  and  dichloro- 
lodomethane. 

The  principal  sources  of  chloroform  and  other  trihalo- 
methanes in  drinking  water  is  the  chemical  interaction  of 
chlorine  added  for  disinfection  and  other  purposes  with  the 
commonly  present  natural  humic  substances  and  other 
precursors  produced  either  by  normal  organic  decomposi- 
tion or  by  the  metabolism  of  aquatic  organisms.  Since  these 
natural  organic  precursors  are  more  commonly  found  in 


surface  water,  water  taken  from  a  surface  source  is  more 
I.,  ely  to  produce  high  THM  levels  than  most  groundwaters. 

Generally,  the  THM  producing  reaction  is: 

Chlorine  +  Precursors  =  Chloroform  +  Other  THMs 

Chloroform  is  the  most  common  THM  found  in  drinking 
water  and  it  is  usually  present  in  the  highest  concentration. 
The  presence  in  drinking  wrter  of  chloroform  and  other 
THMs  and  synthetic  organic  chemicals  may  have  an  adverse 
effect  on  the  health  of  consumers;  therefore,  human  expo- 
sure to  these  chemicals  should  be  reduced. 

B.  Reference 

For  matenals  and  procedures  see: 

Page  591,  STANDARD  METHODS,  16th  Edition. 

NOTE'   A  gas  chromatography  analyzer  is  required  for  this 
analysis. 


17.  Total  Dissolved  Solids 

A.  Discussion 

"Total  dissolved  solids"  (TDS)  refer  to  material  that  passes 
through  a  standard  glass-fiber  filter  disc  and  remains  after 
evaporation  at  180^C.  The  amount  of  dissolved  solids  pre- 
sent in  water  is  a  consideration  in  Its  suitability  for  domestic 
use.  In  general,  waters  with  a  TDS  conten.  of  less  than  50 
mg/L  are  most  desirable  for  such  purposes.  The  higher  the 
TDS  concentration,  the  greater  the  likelihood  of  tastes  and 
odors  and  also  scaling  problems.  As  TDS  increases^  the 
number  of  times  the  water  can  be  recycled  and  reclaimeo 
before  requiring  demineralization  decreases.  In  potable  wa- 
ters, TDS  consists  mainly  of  inorganic  salts,  small  amounts 
of  organic  matter,  and  dissolved  gases.^ 


ERIC 


^Reference,  CHEMISTRY  FOR  ENVIRONMENTAL  ENGINEERING,  Third  Edition.  1978,  by  Clair  N  Sawyer  and  Perry  L  McCarty 
Published  by  McGraw-Hill  Book  Company,  1221  Avenue  of  the  Americas,  New  York,  New  York  10010  Price  $50,95, 

500 


480  Water  Treatment 


Common  Range,  mg/L 
20  to  700 


100  to  1000 


(Total  Dissolved  Solids) 

B.  What  IS  Tested? 

Sample 

Raw  and  Treated 
Surface  Waters 

Groundwater 

C.  Apparatus  Required 

Glass-fiber  filter  discs  (Millipore  AP40:  or  Gelman  Tyoe 
A/E) 

Flask,  suction  500  mL 

Filter  holder  or  Gooch  crucible  adapter 

Gooch  crucibles  (25  ml  if  2.2  cm  filter  used) 

Evaporating  dishes,  100  ml  (high-silica  glass) 

Drying  oven,  ISO^'C 

Steam  bath 

Vacuum  source 

Disiccator 

Analytical  balance 

Muffle  furnace,  550''C 

D.  Procedure 


1. 


1 


Preparation  of  Dish 

Ignite  a  clean  evaporating  dish  at  uoO  ±  50X  for  one 
hour  ir  muffle  furnace. 

Cool  in  desiccator  then  weigh  and  record  weight.  Store 
in  desiccator  until  needed. 

Preparation  of  Glass-fiber  Filter  Disc 

Place  the  disc  on  the  filter  apparatus  oi  insert  into  the 
bottom  of  a  suitable  Gooch  crucible.  While  vacuum  is 
applied,  wash  the  filter  disc  with  three  successive  20  ml 
volumes  of  distilled  water.  Continue  the  suction  to 
remove  all  traces  of  water  from  the  disc  and  discard  the 
washings. 

Sample  Analysis 

1.  Shake  the  sample  vigorously  and  transfer  100  to  150 
mL  to  the  funnel  or  Gooch  crucible  by  means  of  a  150 
mL  graduated  cylinder. 

2  Filter  the  sample  through  the  glass-fiber  filter  and  con- 
tinue to  apply  vacuum  for  about  three  minutes  after 
filtration  is  complete  to  remove  as  much  water  as 
possible. 

3  Transfer  1 00  mL  of  the  filtrate  to  the  weighed  evaporat- 
ing dish  and  evaporate  to  dryness  on  a  steam  bath. 

4.  Dry  the  'Evaporated  sample  for  at  least  one  hour  at 
180X.  Cool  in  desiccator  and  weigh.  Repeat  drying 
cycle  until  constant  weight  is  obtained  or  until  weight 
loss  is  less  than  0.5  mg. 


E  Example 
Results  from  weighings  v/ere- 

Clean  dish  =  47.0028  grams  (47,002.8  mg) 

Dissolved  residue  -f  dish  =  47.0453  r/ams  (47,045.3  mg) 
Sample  volume  =  100  ml 


F  Calculations 

1    Total  Dissolved  Solids,  mg/L 


2.    From  example. 

Total  Dissolved  ^ 
Solids.  mg/L 


,     (A-B)  X  1000 
mL  sample  volume 

where,  A  =  weight  of  dish  and 
dissolved  material 
in  milligrams  (mg) 

B  =  weight  of  clean 
dish  in  milligrams 
(mg) 


(A-B)  X  1000 


mL  sample  volume 
^  (47,045  3  mg  -  47,002  8  mg)(lOOO  mL/L) 
100  mL 

=  425  mg/L 

G.  Comments 

Because  excessive  residue  in  the  evaporating  dish  may 
form  a  water-entrapping  crust,  use  a  sample  that  yields  no 
more  than  200  mg  of  resioue. 

H.  Reference 

See  page  95,  STANDARD  METHODS.  16th  Edition. 

QUESTIONS 

Wnte  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  483. 

21. 1Y  How  are  tnhalomethanes  produced? 

21. 1Z  What  are  "total  dissolved  solids"  (TDS)? 


ERIC 


501 


Lab  Procedures  4S1 

(Total  Dissolved  Solids) 


OUTLINE  OF  PROCEDURE  FOR  TOTAL  DISSOLVED  SOLIDS 


D 


1 .  Ignite  dish  at  550°C 
for  1  hour  in  muffle 
furnace 


4.  Place  glass-fiber 
disc  in  crucible. 


7.  Kilter  out  suspended 
material.  Transfer  100  mL 
of  filtrate  to  weighed  dish. 


2.  Cool 


5.  Wash  filter-crucible 
with  distilled  water. 


8.  Evaporate  to 
dryness  on 
sleambath. 


10.  Cool  in  desiccator. 


ERIC 


3.  Weigh  and  store 
in  desiccator. 


6  Pour  100  mL  sample 
into  Gooch  crucible. 


9.  Dry  evaporated  sample 
for  1  hour  at  180°C 


11.  Weigh. 

502 


482  Water  Treatment 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  21.   ADVANCED  LABORATORY  PROCEDURES 

(Lesson  2  of  2  Lessons) 


Please  write  the  answers  to  these  questions  in  your 
notebook  before  continuing  wiih  the  Objective  Test  on  page 
484.  The  ouestio.i  numbenng  continues  from  Lesson  1. 

9  Why  is  iron  undesirable  in  a  domestic  water  supply'? 

10.  What  precautions  must  be  exercised  when  collecting 
samples  to  be  analyzed  for  iron? 

1 1.  How  would  you  obtain  the  manganese  concentration  in 
a  sample  by  using  a  spectrophotometer  if  turbidity  or 
color  was  interfering  with  the  results? 

12.  What  IS  the  purpose  of  the  f^arble  Test? 

1 3.  Why  is  the  presence  of  certain  metals  in  drinking  water 
of  serious  concern? 

14.  How  would  you  fnterpret  the  results  of  lab  tests  which 
indicate  high  levels  of  n'trate  in  a  raw  water  sample? 

15.  When  performing  the  nitrate  determination,  why  should 
caution  be  exercised  when  using  cadmium  and  what 
precautions  should  be  used? 

16.  How  would  you  interpret  the  meaning  of  changes  (away 
from  normal)  in  conductivity  ii  water? 


17.  Why  are  sulfate  ions  of  concern  in  water  supplies? 

18  How  would  you  attempt  to  reduce  unpleasant  tastes 
and  odors  in  drinking  water? 

19.  Why  should  exposure  to  THMs  be  reduced? 

20.  Why  IS  the  amount  of  dirsolved  solids  present  in  water  a 
consideration  in  its  suitability  for  domestic  use*? 


SUGGESTED  ANSWERS 

Cnapter  21.    ADVANCED  LABORATORY  PROCEDUi'ifcS 


ANSWERS  TO  QUESTIONS  IN  LESSON  1 

Answers  to  questions  on  page  449. 

21. OA  The  intensity  of  a  blue  color  is  measured  when 
measuring  the  concentration  of  phosphorus  in  water. 

21. OB  The  scale  in  spectrophotometers  i3  'jsudily  graduat- 
ed in  two  ways: 

1 .  In  units  of  percent  trarismittance  (%T),  a*.  ur;^hr  e- 
tic  scale  witiT  units  graded  from  0  to  100%  aoo 

2.  In  units  of  absorbance  (A),  a  logarithmic  seal*:  of 
nonequal  divisions  gradua'ed  from  O.O  to  2.0. 

21. OC  If  the  absorbance  reading  w*.s  0.60,  the  unknown 
concentration  was  0.70  mg/L. 

Answers  to  questions  on  page  453. 

21.1  A  Yes,  the  quality  of  water  in  any  lake,  reserve  or 
stream  has  a  very  direct  effect  on  the  abundance  and 
types  of  aquatic  organisms  found. 

21 .1 B  Calcium  in  the  form  of  lime  or  calcium  hydroxide  may 
be  used  to  soften  water  or  to  control  corrosion 

O 

ERLC 


through  pH  adjustm<»nl. 

21.10  Titrate  sample  for  cairium  immediately  after  adding 
sodium  hydroxide  (NaOH)  solKion. 

21  ID  Chlonde  concentrations  above  250  mg/L  are  objec- 
tionable to  many  people  due  to  a  salty  taste. 

Answers  to  questions  on  page  453. 

21. IE  The  most  common  colors  which  occur  in  raw  water 
are  yellow  and  brown. 

21 . 1 F  True  color  is  normally  removed  or  at  least  decreased 
by  coagulation  and  chlonnation  or  ozonation. 

21. 1G  Stock  color  standards  should  be  protected  against 
evaporation  and  contamination  when  not  in  use. 

Answers  to  questions  on  page  460. 

21. 1H  The  presence  of  dissolved  oxygen  (DO)  in  water  can 
contnbute  to  corrosion  of  piping  systems. 

21.11  The  common  range  of  fluoride  in  fluondated  dnnking 
water  is  0.8  to  1.2  mg/L. 


503 


Lab  Procedures  483 


ANSWERS  TO  QUESTIONS  IN  LESSON  2 

Answers  to  questions  on  page  465. 

21.1  J  Problems  that  may  be  caused  by  iron  in  a  domestic 
water  supply  include  staining  of  laundry,  concrete, 
and  porcelain.  A  bitter  astnngent  taste  can  be  detect- 
ed by  some  people  at  levels  above  0.3  mg/L. 

21.1  K  All  glassware  must  be  acid  washed  when  analyzing 
samples  for  Iron  to  remove  deposits  of  iron  oxide 
which  could  give  false  results. 

21.1  L  Manganese  occurs  both  in  suspension  and  as  a 
soluble  complex  in  surface  wat  rs. 

21,1  M  If  the  manganese  concentration  cannot  be  deter- 
mined immediately,  acidify  sample  with  nitric  acid  to 
pH  less  than  2. 

Answers  to  questions  on  page  468. 

21 .1 N  Temperature  is  important  in  the  Marble  Test  because 
the  solubility  of  calcium  carbonate  varies  with  tem- 
perature. Therefore,  the  test  must  be  performed 
immediately  after  the  sample  is  collected  and  as 
rapidly  as  possible. 

21.10  Langelier  Index  ^  Initial  pH  -  Final  pH 

^  8.9  -  8.6 

=  0.3 

Since  the  Langelier  Index  is  positive,  the  water  is 
supersaturated  with  calcium  carbonate  and  not  con- 
sidered corrosjve. 

21, IP  The  concentration  of  most  mecals  in  water  is  deter- 
mined by  using  atomic  absorption  spectioscopy  or 
colorimetric  methods 

Answers  to  questions  on  page  471. 

21. 1Q  In  the  nitrate  test,  all  nitrate  is  reduced  to  nitrite  and 
then  measured  rolonmetrically. 

21. '^R  Removal  of  turoidity  interfering  with  nitrate  analyses 
can  be  accomplished  by  one  of  the  following  meth- 
ods to  remove  suspended  matter  that  can  clog  the 
reduction  column. 

1.  Filter  sample  through  a  glass  fiber  or  a  0.45 
micron  pore  size  filter  ar.  long  as  the  pH  is  less 
than  8,  or 

2.  Add  1  mL  zinc  solution  to  100  mL  of  sample  and 
mix  thoroughly.  Add  enough  sodium  hydroxide 
solution  to  obtain  a  pH  of  10.5.  Let  treated  sample 
stand  a  few  minutes  to  allow  the  heavy  flocculent 
precipitate  to  settle.  Clarify  by  filtering  through  a 
glass  fiber  filter. 

21  IS  The  pH  of  natural  waters  is  controlled  by  the  relative 
amounts  of  carbon  dioxide,  bicarbonate,  and  carbon- 
ate ions. 

Answers  to  questions  on  page  474. 

21. IT  Specific  conductance  or  conductivity  Is  a  numerical 
expression  (expressed  in  micromhos  per  centimeter) 
of  the  ability  of  a  water  to  conduct  an  electrical 
current.  This  number  depends  on  the  total  concen- 
tration of  the  mineral  dissolved  in  the  sample  (TDS) 
and  ♦he  temperature. 

21.1  U  Sulfate  ions  are  of  importance  in  water  supphes 
because  of  the  tendency  of  appreciable  amounts  to 


form  hard  scales  in  boilers  and  heat  exchapgers. 

21.1V  A  50  mL  sample  from  a  well  produced  a  turbidity 
reading  of  40  TU  using  a  nephelometer.  What  was 
the  sulfate  concentration  in  mg/L'? 

Known  Unknown 

Sample  Size,  mL  =  50  mL        Sulfate,  mg/L 
Turbidity.  TU      =  40  TU 

1.  Determine  the  sulfate  concentration  from  the 
graph. 

Sulfate  Concentration,  mg/L  =  15  mg/L 
2  Calculate  the  sulfate  concentration  in  mg/L. 

Sulfate,  mg/L    (Graph  Sulfate,  mg/L)(lOO  mL) 
Sample  Size,  mL 
^(15  mg/L)(lOO  mL) 

50  mL 
=  30  mg/L 

Answers  to  questions  on  page  479. 

21 .1W  Tastes  and  odors  can  be  cauced  in  drinking  water  by 
algae,  actinomycetes,  bacteria,  decaying  vegetation, 
metals  and  pollutants  (most  organic  chemicals  and 
some  inorganic  chemicals).  Dissolved  inorganic  salts 
of  copper,  iron,  manganese,  potassium,  soaium  and 
zinc  can  be  detected  by  taste. 

21  IX  Calculate  the  threshold  odor  number  (T.O.N.)  for  a 
sample  when  the  first  detectable  odor  occurred  when 
the  12  mL  sample  was  diluted  to  200  mL  (188  mL  of 
odor-free  water  was  added  to  the  12  mL). 

Known  Unknown 

A  or  Sample  Size,  mL       =   1 2  mL  T.O.N. 
B  or  Odor-Free  Water.  mL  =  188  mL 


Calculate  the  threshold  odor  number,  T  O.N. 
.  Ajf  B 
A 

12  mL    188  mL 


TO  N.  =^ 


12  niL 


17 


Answers  to  questions  on  page  480. 

21  1Y  The  principal  source  of  chlorofor'^  and  other  tnhalo- 
methar.es  in  dnnkmg  water  is  113  chemical  interac- 
tion of  chlorine  added  for  disinfection  and  other 
purposes  with  the  commonly  present  natural  humic 
substances  and  other  precursors  produced  either  by 
normal  o'-ganic  decomposition  or  by  the  metabolism 
of  aquatic  organisms. 

21 .1Z  Total  Dissolved  Solids'  (TDS)  refer  to  material  that 
passes  through  a  standard  glass-fiber  disc  and  re- 
mains after  evaporation  at  180°C. 


er|c 


504 


484  Water  Treatment 


OBJECTIVE  TEST 

Chapter  21.   ADVANCED  LABORATORY  PROCEDURES 


Please  write  your  name  and  mark  the  correct  answers  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1 .  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
questions. 

TRUE-FALSE 

1 .  Measuring  the  intensity  of  ihe  color  enables  the  concen- 
tration of  a  substance  in  water  to  be  measured. 

1.  True 

2.  False 

2.  The  human  eye  is  more  precise  than  a  spectrophotom- 
eter. 

1.  True 

2.  raise 

3  A  sample  which  has  a  low  color  intensity  will  have  a  low 
percent  transmittance  but  a  high  absorbance. 

1.  True 

2.  False 

4  In  most  natural  waters  calcium  is  the  principal  anion. 

1.  True 

2.  False 

5  Chloride  usually  occurs  in  natural  waters  as  a  basic  salt. 
1.  True 

2  False 

6.  Usually  the  chloride  content  in  water  increases  as  the 
mineral  content  decreases. 

1.  True 

2.  False 

7  True  color  results  from  the  presence  of  suspended 
matenals. 

1.  True 

2.  False 

8  The  formation  of  a  white  flor  during  the  DO  test  indi- 
cates that  there  is  DO  present  in  the  sample. 

1.  True 

2.  False 

9  As  the  temperature  of  water  increases,  the  DO  satura- 
tion value  increases. 

1.  True 

2.  False 

10.  Always  record  temperature  of  water  when  collecting  a 
dissolved  oxygen  sample. 

1.  True 

2.  False 

1 1 .  Iron  IS  an  abundant  and  widespread  constituent  of  rocks 
and  soils. 

1.  True 

2.  False 


1 2  Above  a  pH  of  4.6  the  solubility  of  the  fernc  iron  species 
increases  considerably. 

1  True 

2  False 

1 3  Colloidal  ferric  nydroxide  may  persist  m  smflll  quantities 
in  surface  waters  that  appear  clear. 

1  True 
2.  False 

14.  Manganese  is  much  more  abundant  in  the  earth's  crust 
than  iron 

1.  True 

2.  False 

15.  Manganese  m  surface  waters  occurs  both  in  suspen- 
sion and  as  a  soluble  complex. 

1.  True 

2.  False 

16.  During  the  Marble  Test,  the  water  being  tested  should 
not  be  exposed  to  atmospheric  carbon  dioxide. 

1  True 

2  False 

1 7  Nitrite  represents  the  most  completely  oxidized  form  of 
nitrogen  found  in  water. 

1.  True 

2.  False 

18.  The  nitrate  test  measures  both  nitrate  and  nitrite. 

1.  True 

2,  False 

1 9  Taste  and  odor  are  sensory  clues  which  provide  ♦he  first 
warning  of  potential  hazards  in  the  environment. 

1.  True 
2  False 

20  Water  taken  from  a  groundwater  source  is  more  likely  to 
produce  high  ThM  levels  than  most  surface  waters 

1.  True 
2  F?>'<^9 


MULTIPLE  CHOICE 

21  Analyses  of  which  of  the  following  water  quality  charac- 
teristics are  based  on  the  measurement  of  color  inten- 
sity 

1.  Dissolved  oxygen 

2.  Iron 

3.  Manganese 

4.  pH 

5  Phosphorus 


ERIC 


505' 


Lab  Procedures  485 


22.  Color  intensities  can  be  converted  to  concentrations  of 
substances  using 

1.  Amperometnc  titration. 

2  Nessler  tubes 

3  pH  prohes 

4  Pocket  comparators. 

5  Spectrophotometers. 

23.  The  quality  ot  water  in  any  lake,  reservoir  or  stream  has 

a  very  direct  effect  on  the  of  aquatic  organisms 

found  in  the  water. 

1  Absorbance 

2  Abundance 

3.  Aliquots 

4.  Percent  transmittance 

5.  Transparency 

24.  The  recommended  maximum  allowable  concentration 
of  chlonde  in  drinking  water  is  

1.  50mg/L 

2.  lOOmg/Z- 

3.  150  mg//- 

4.  200  mg/L 

5.  250  mg/L 

25.  Ions  that  interfere  with  ♦he  chloride  test  include 
1  Iron. 

2.  Orthophosphate. 

3.  Sulfide. 

4.  Sulfite. 

5.  Thiosulfate 

26  Color  in  water  supplies  may  result  from 

1.  Copper. 

2.  hardness. 

3  Iron. 

4  Manganese. 

5.  Organic  matter. 

27  Precautions  that  must  be  exercised  when  using  a  dis- 
solved oxygen  (DO)  probe  include 

1.  ACidify  the  sample. 

2.  Keep  the  membrane  in  the  tip  of  the  probe  from 
drying  out. 

3  Keep  the  sample  iced. 

4.  Periodically  check  the  calibration  of  the  probe. 

5.  Remove  reactive  compounds  thai  can  interfere  with 
the  output. 

28.  Samples  being  tested  for  fluoride  must  be  distilled  if  the 
samples  contain  exce  sive  amounts  of 

Aluminum. 

2.  Hardness. 

3.  Hexametaphosphate 

4.  Nitrate. 

5.  Sodium  hydroxide. 

29.  Iron  in  a  domestic  watei  stpply  can  cause 

1.  Bitter  tastes. 

2.  Consumer  complaints. 

3.  Corrosion. 

4.  Staining  ;i  concrete. 

5.  Staining  of  lau-^dry. 


30  Objections  to  manganese  in  domestic  waters  include 

1  CorrcG;vity. 

2  Discolored  di  iveways. 

3  Mardneoo. 

4.  Stained  laun^'ry 

5.  Stained  plumbing  fixtures 

31.  Metals  found  in  drinking  water  include 

1  Calcium 

2  Chloride 

3.  Iron 

4.  Nitrogen. 
5  Sodium. 

32  High  levels  of  nitrate  in  a  domestic  water  suppiy  are 
undesirable  becau'je  of 

1.  Hardness. 

2  Health  threat  due  to  infant  methemoglobinema 

3  Laundry  stains. 

4  Nitrate  stains. 

5  Potential  for  stimulating  excessive  algae  growth. 
33.  Alum  coagulates  most  effectively  at  pH  values  near 


1.  4.3 

2.  5  6 
3  68 

4.  7.5 

5.  8.3 

34.  Tastes  and  odors  in  drinking  waters  can  be  produced  by 

1.  Algae 

2.  Bactena 

3.  Decaying  vegetation. 

4.  Hardness. 

5.  Pollutants. 

35  In  potable  waters  TDS  consists  mainly  of 

1.  Dissolved  minerals. 

2.  Inorganic  salts. 
3  Organic  matter. 

4.  Soluble  acids. 

5.  Vitamins. 

36  Calculate  the  threshold  odor  number  (T.O.N)  for  a 
sample  when  the  first  detectable  odor  occurred  when 
ihe  17  rnL  sample  was  diluted  to  200  mL  (183  mL  of 
odor-free  water  was  added  to  the  17  mL). 

1  4 

2  6 

3  8 

4  12 
5.  17 


end  oC  obleciiw  lis^t 


ERIC 


5n« 


CHAPTER  22 

DRINKING  WATER  REGULATIONS 

by 

Tim  Gannon 


Revised 
by 

Jim  Sequeira 


488  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  22.  Drinking  Water  Regulations 

Page 

OBJECTIVES  491 

GLOSSARY  492 

LESSON  1 

22.0  History  of  Drinking  Water  Laws  and  Standards  493 

22.1  1986  Amendments  to  the  Safe  Drinking  Water  Act  494 

22.10  Major  Aspects  494 

22.11  Schedule  495 

22.2  Disinfectants  and  Disinfection  by-products  496 

22.3  Surface  Water  Treatment  Rule  (SWTR)  496 

22.30  Requirements  for  Non-Filtered  Systems  497 

22.31  Requirements  for  Filtered  Water  Systems  497 

22.32  Monitoring  Requirements  of  the  SWTR  497 

22.33  Turbidity  Requirements  of  the  SWTR  497 

22.4  Types  of  Water  Systems  493 

22.40  Community  Water  Systems  493 

22.41  Non-Community  Water  Systems  493 

22.5  Interim  Primary  Drinking  Water  Standards  498 

22.50  Establishment  of  Drinking  Water  Standards  498 

22.51  Types  of  Contaminants  498 

22.52  Immediate  Threats  to  Health  499 

22.520  Bacteria  .  ..499 

22.521  Nitrate  499 

22.53  Setting  Standards  499 

LESSON  2 

22.6  Primary  Drinking  Water  Standards  5O1 

22.60  Inorganic  Chemical  Standards   501 

22.600  Arsenic  503 

22.601  Barium  503 

ER?C 


Water  Quality  Regulations  489 


22.602  Cadmium  503 

22.603  Chromium  503 

22.604  Fluoride   503 

22.605  Lead  503 

22.606  ^:ercury   503 

22.607  Selenium  503 

22.608  Silver  503 

22.61  Organic  Chemical  Standards  504 

22.610  Trichloroethylene  (TCE)  505 

22.61 1  1.1  -Dichloroethylene  505 

22.612  Vinyl  Chloride  505 

22.613  1.1.1-Trichloroethane  505 

22.614  1 .2-Dlchloroethane  505 

22.615  Carbon  Tetrachloride  505 

22.616  Benzene  505 

22.61 7  1 ,4-Dichlorobenzene  (p-dichlorobenzene)  505 

L    ?  Turbidity  Standards  505 

22.63  Microbiological  Standards  506 

22.630  Conform    506 

22.631  Multiple-Tube  Fermentation  Method  506 

22.632  Membrane  Filter  Method  506 

22.633  Chlorine  Residual  Substitution  506 

22.634  Draft  Coliform  Rule  506 

22.635  Giardia  507 

22.64  Radiological  Standards   507 

22.7    Secondary  Drinking  Water  Standards   508 

22.70  Enforcement  of  Regulations  508 

22.71  Secondary  Maximum  Contaminant  Levels  508 

22.72  Monitoring  509 

22.73  Secondary  Contaminants  509 

22.730  Chloride  509 

22.731  Color  509 

22.73?  Copper  510 

22.733  Corrosivity   510 

22734  Fluoride  510 

22.735  Foamiiig  Agents   510 

22736  Iron  and  Manganese  511 

22.737  Iron  511 

22  738  Manganese  511 

ERIC 


490  Water  Treatment 

22.739  Odor  511 

22.740  pH   512 

22.741  Sulfate  512 

22.742  Total  Dissolved  Solids  512 

22.743  Zinc  512 

22.8  Sampling  Procedures  513 

22.80  Safe  Drinking  Water  Regulations  513 

22.81  Initial  Sampling  51 3 

22.82  Routine  Sampling  51 3 

22.83  Check  Sampling  513 

22.84  Sampling  Points  513 

22.85  Sample  Point  Selection  514 

22.86  Sampling  Schedule  515 

22.87  Sampling  Route  515 

22.88  Sample  Collection  515 

22.9  Reporting  Procedures  515 

22.10  Notification  for  Community  Systems  515 

Suggested  Answers  527 

Objective  Test  530 

Appendix  Coliform  Samples  Required  Per  Population  Served  533 


ERLC 


510 


Water  Quality  Regulations  491 


OBJECTIVES 

Chapter  22.    DRINKING  WATER  REGULATIONS 


Following  completion  of  Chapter  22,  you  should  be  able 

to: 

1.  Identify  the  two  basic  types  of  water  systems, 
2  List  the  types  of  pnmary  contaminants, 

3.  Explain  the  proposed  Surface  Water  Treatment  Rule 
(SWTR), 

4.  Describe  the  Interim  Primary  Drinking  Water  Standards, 

5  List  the  secondary  contaminants, 

6  Develop  and  conduct  a  sampling  program, 

7.  Record  and  report  results,  and 

8.  Comply  with  notification  requirements. 


511 


492  Water  Treatment 


GLOSSARY 

Chapter  22.   DRINKING  WATER  REGULATIONS 

ACUTE  ACUTE 

When  the  effects  of  an  exposure  jause  severe  symptoms  to  occur  quickly,  the  symptoms  are  said  to  be  acute  because  they  are 
br^f  and  severe. 

CHECK  SAMPUNG  CHECK  SAMPLING 

Whenever  an  initial  or  routine  sample  analysis  indicates  that  a  Maximum  Contaminant  Level  (MCL)  has  been  exceeded,  CHECK 
SAMPLING  Is  required  to  confirm  the  routine  sampling  results.  Check  sampling  is  in  addition  to  the  routine  sampling  program. 

CHELATING  AoENT  (key-LAY-ting)  CHELATING  AGENT 

A  chemical  used  to  prevent  the  precipitation  of  metals  (such  as  copper). 

CHLORAMINATION(KLOR-ah-mjn-NAY-shun)  CHLORAMINATION 
The  appllcauon  of  chlorine  and  ammonia  to  water  to  form  chloramines  for  the  purpose  of  disinfection. 

CH.IONIC  CHRONIC 
Effects  of  repeated  exposures  over  a  long  period  of  time  which  eventually  cause  symptoms  that  continue  for  a  long  time. 

INITIAL  SAMPLING  INITIAL  SAMPLING 

The  very  first  sampling  conducted  under  the  Safe  Drinking  Water  Act  for  each  of  the  applicable  contaminant  categories. 

MBAS  MBAS 
Methylene-Blue-Actlve  Substances.  These  substances  are  used  in  surfactants  or  detergents. 

MCL  MCL 

Maximum  Contaminant  Level.  The  largest  allowable  amount.  MCLs  for  various  watei  quality  Indicators  are  specified  in  the  Na- 
tional Drinking  Water  Regulations. 

pCi/L  pCi/L 

PicoCurie  per  Liter.  A  picoCurie  is  a  measure  of  radioactivity.  One  picoCuno  of  radioactivity  is  equivalent  to  0.037  nuclear  disin- 
tegrations per  second. 

ROUTINE  SAMPLING  ROUTINE  SAMPLING 

Sampling  repeated  on  a  regular  basis. 

SURFACTANT  (SIR-fac-TENT)  surfactant 
Abbreviation  for  surface-active  agent.  The  active  agent  in  detergents  that  possesses  a  high  cleaning  ability. 

THRESHOLD  ODOR  NUMBER  THRESHOLD  ODOR  NUMBER 

TON.  The  greatest  dilution  of  a  sample  with  odor-free  water  that  still  yields  a  just-detectable  odor. 

TU  TU 

Turbidity  units.  Turbidity  units  are  a  measure  of  the  cloudiness  of  watei.  If  measured  by  a  nephelometric  (deflected  light)  instru- 
mental procedure,  turbidity  units  are  expressed  in  nephelometric  turbidity  units  (NTU)  or  simply  TU.  Those  turbidity  units  ob- 
tained by  visual  methods  are  expressed  in  the  Jackson  Turbidity  Units  (JTU)  which  are  a  measure  of  the  cloudiness  of  vater, 
they  are  used  to  indicate  the  clarity  of  water.  There  is  no  real  connection  between  NTUs  and  JTUs.  The  Jackson  turbidim^aler  is 
a  visual  method  and  the  nephelometer  is  an  instrumental  method  based  on  deflected  light. 


ERIC 


Water  Quality  Regulations  493 


CHAPTER  22.   DRINKING  WATER  REGULATION^ 

(Lesson  1  of  2  Lessons) 


All  water  treatment  plant  operators  need  to  be  thoroughly 
familiar  with  the  state  and  federal  laws  and  standards  that 
apply  to  domestic  water  supply  systems.  These  regulations 
are  the  goals  and  guideposts  for  the  water  supply  industry. 
Their  purpose  is  to  assure  me  uniform  delivery  of  safe  and 
aesthetically  pleasing  drinking  water  to  the  public. 

This  chapter  will  introduce  the  major  drinking  water  regu- 
lations and  explain  the  monitoring  and  reporting  require- 
ments. For  more  detailed  information,  you  will  need  to  refer 
to  current  copies  of  your  state's  regulations  and  tha  most 
recent  federal  standards.  These  publications  snould  be 
made  readily  available  to  all  operators  since  operators  will 
only  know  whether  their  system  is  in  compliance  by  compar- 
ing monitoring  test  data  with  the  actual  current  regulations. 


er|c 


22.0  HISTORY  OF  DRINKING  WATER  LAWS  AND 
STANDARDS 

Up  until  shortly  after  the  turn  of  the  century,  there  were  no 
standards  for  drinking  water.  The  first  standards,  estab- 
lished in  1914,  were  designed  in  large  part  to  control 
waterborne  bacteria  and  viruses  that  cause  diseases  such 
as  cholera,  typhoid,  and  dysentery.  These  new  standards 
were  ove'whelmingly  successful  in  curbing  the  spread  of 
such  diseases.  However,  with  time  and  technology,  other 
types  of  contaminants,  this  time  chemicals,  again  stirred 
public  concern.  In  1962  the  U.S.  Public  Health  Service  (the 
forerunner  of  the  U.S.  Environmental  Protection  Agency) 
revised  the  national  drinking  water  standards  to  include 
limits  on  select  organic  chemicals. 

In  1972  a  series  of  reports  detailing  organic  contamination 
In  the  drinking  water  supplied  to  the  residents  of  New 
Orleans  from  the  Mississippi  River  triggered  profound 
changes  In  drinking  water  regulations.  A  study  by  the 
Environmental  Defense  Fund  found  that  people  drinking 
treated  Mississippi  River  water  in  New  Orleans  had  a 


greater  chance  of  developing  certain  cancers  than  those  in 
neighboring  areas  whose  drinking  water  came  from  ground- 
water sources.  Heightened  public  awareness  and  concern 
regarding  cancer  became  major  factors  behind  the  push  for 
legislative  action  on  the  issue  of  drinking  water  contamina- 
tion. Ths  finding  of  suspected  carcinogens  in  drinking  water 
established  a  widespread  sense  of  urgency  that  led  to  the 
passage  and  signing  into  law  of  the  Safe  Drinking  Water  Act 
in  December,  1974. 


The  Safe  Drinking  Water  Act  (SDWA)  gave  the  federal 
government,  through  the  U.S.  Environmental  Protection 
Agency  (EPA),  the  authority  to: 

*  Set  national  standards  regulating  the  levels  of  conta- 
minants in  drinking  water; 

*  Require  public  water  systems  to  monitor  and  report 
their  levels  of  identified  contaminants;  and 

*  Establish  uniform  guidelines  specifying  the  acceptable 
treatment  technologies  for  cleansing  drinking  water  of 
unsafe  levels  of  pollutants. 

While  the  SDWA  gave  EPA  responsibility  for  promulgating 
drinking  water  regulations,  it  gave  state  regulatory  agencies 
the  opportunity  to  assume  primary  responsibility  for  enforc- 
ing those  regulations. 

Over  the  past  decade,  implementation  of  the  SDWA  has 
greatly  improved  compliance  with  basic  drinking  water  purity 
across  the  nation.  However,  recent  EPA  surveys  of  surface 
water  and  groundwater  indicate  the  presence  of  synthetic 
organic  chemicals  in  20  percent  of  the  nation's  water 
sources,  with  a  small  percentage  at  levels  of  concern.  In 
addition  research  studies  suggest  that  some  naturally  oc- 
curring contaminants  may  pose  even  greater  risks  to  human 
health  than  the  synthetic  contaminants.  Further,  there  is 
growing  concern  about  microbiological  and  radon  contami- 
nation. 

In  the  years  following  passag?  of  the  SDWA,  Congress  felt 
that  EPA  was  slov/  to  regulate  contaminants  and  states  were 
lax  in  enforcing  the  law.  Consequently,  in  1986  Congress 
enacted  amendments  designed  to  strengthen  the  1974 
SDWA.  These  amendments  included  language  modifica- 
tions, set  deadlines  for  the  establishment  of  maximum 
cor'taminant  levels,  placed  greater  emphasis  on  enforce- 
ment, authorized  penalties  for  tampering  with  drinking  water 


513 


494  Water  Treatment 


supplies  and  mandated  the  complete  elimination  of  lead 
from  drinking  water.  In  addition,  the  SDWA  amendments 
placed  considerable  emphasis  on  the  protection  of  under- 
ground drinking  water  sources. 

22.1    1986  AMENDMENTS  TO  THE  SAFE  DRINKING 
WATER  ACT 

22.10  Major  Aspects 

The  1986  SDWA  amendments  require  that  the  EPA,  the 
states,  and  the  water  supply  industry  undertake  significant 
new  programs  in  the  very  near  future  to  clean  up  the 
country's  drinking  water  supplies.  The  major  aspects  of  the 
1986  Amendments  to  the  SDWA  include: 

1.  Compulsory  revisions  to  the  regulations  for  new  con- 
taminants (as  described  below), 

2.  Definition  of  an  approved  treatment  .echnique  for 
each  regulated  contaminant. 


3.  Filtration  requirement  for  surface  water  supplies. 

4.  Disinfection  of  all  water  supplies,  and 

5.  Prohibition  of  the  use  of  lead  products  in  materials 
used  to  convey  drinking  water. 

The  1986  Amendments  require  the  regulation  of  many 
more  contaminants.  The  Amendments  state  that: 

•  The  EPA  must  regulate  nine  contaminants  within  a 
year  of  enactment  (1987),  another  40  within  two  years 
(1988),  and  the  rest  within  three  years  (1989)  for  a  total 
of  83.  These  83  contaminants  (shown  in  Table  22.1) 
include  14  volatile  organic  chemicals  (VOCs),  five  mi- 
crobiological parameters  and  turbidity.  23  inorganics 
(lOCs),  and  five  radionuclides, 

•  In  addition  to  the  promulgation  of  standards  for  the  83 
contaminants,  EPA  must  develop  at  least  25  more 
primary  standards  by  1991  and  25  additional  standards 
every  three  years  thereafter. 


TABLE  22.1.    CONTAMINANTS  REQUIRED  TO  BE  REGULATED  BY 
THE  SDWA  AMENDMENTS  OF  1986 


Trichloroethylene 
Tetrachloroethylene 
Carbontetrachloride 
1 ,1 ,1  -Trichloroethane 
1,2-Dichloroethane 
Vinyl  chloride 
Methylene  chloride 


VOLATILE  ORGANIC  CHEMICALS 

Chlorobenzene 

Dichlorobenzene 

Trichlorobenzene 

1,1-Dichloroethylene 

trans-1 ,2-Dichloroethylene 

cis-1 ,2-Dichloroethylene 

Benzene 


MICROBIOLOGICAL  AND  TURBIDITY 

Total  conforms  Viruses 

Turbidity  Standard  pkUe  count 

Giardia  lambli  Legionella 


Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Mercury 

Nitrate 

Selenium 

Silver 

Fluoride 

Aluminum 

Antimony 


INORGANICS 

Molybdenum 

Asbestos 

Sulfate 

Copper 

Vanadium 

Sodium 

Nickel 

Zinc 

Tahllium 

Bsryllium 

Cyanide 


ERIC 


514 


Water  Quality  Regulations  495 


TABLE  22.1.    CONTAMINANTS  REQUIRED  TO  BE  REGULATED  BY 
THE  SDWA  AMENDMENTS  OF  1986  (continued) 


ORGANICS 


Endrin 

Vydate 

Lindane 

Simazine 

Methoxychlor 

PAHs 

Toxaphene 

RGBs 

2.4-D 

Atrazine 

2,4.5-TP 

Phthalates 

Aldicarb 

Acn/Iamide 

Chlorodane 

Dibromochloropropane  (DBCP) 

Diaquat 

1,2-DichIoropropane 

Endotha'.l 

Pentachlorophenol 

Glyphosate 

Picloram 

Carbofuran 

Dinoseb 

Alachlor 

Ethylene  dibromide  (EDB) 

Epichlorohydrln 

Dalapon 

Toluene 

Dibromomethane 

Adipates 

Xylene 

2,3.4.8-TCDD  (DIoxin) 

Hexachlorocyclopentadiene 

1,1,2-TrichIoroethane 

RADIONUCLIDES 

Radium  226  and  228  Gross  alpha  particle  activity 

Beta  particle  and  photon  Uranium 
radioactivity  Radon 


Contaminants  on  the  above  list  of  83  ior  which  maximum  contaminant  level  goals  (MCLGs)  were  not  proposed  as  of  November 
13,  1985.^ 


Methylene  chloride 

Antimony 

Endrin 

Dalapon 

Diaquat 

Endothall 

Glyphosate 

Adipates 

2,3.4.8-TCDD  (D'oxin) 
Trichlorobenzene 
Standard  plate  count 
Legionella 
Sulfate 


Thallium 

Beryllium 

Cyanide 

1,1,2-Trichloroethane 

Vydate 

Simazine 

PAHs 

Atrazine 

Phthalate 

Picloram 

Dinoseb 

Hexachlorocyclopentadiene 
Nickel 


'  Note.   MCLGs  have  also  not  been  proposed  for  the  seven  contaminants  EPA  is  proposing  to  delete  from  the  list  of  83  conta- 
minants. These  seven  are  zinc,  silver,  aluminum,  sodium,  dibromomethane,  molybdenum,  and  vanadium. 


ERIC 


515 


496  Water  Treatment 


•  EPA  can  substitute  up  to  seven  other  contaminants  for 
those  on  the  list  if  it  finds  this  will  provide  greater 
health  protection. 

•  By  1988,  EPA  must  specify  criteria  for  filtration  of 
surface  water  supplies. 

•  By  1990,  EPA  must  specify  criteria  for  disinfection  of 
surface  and  groundwater  supplies. 

Even  prior  to  the  passage  of  the  1986  Amendments,  the 
EPA  used  a  regulatory  approach  when  reviewing  drinking 
water  contaminants.  This  type  of  approach,  coincides  with 
the  regulation  requirements  Imposed  by  the  Amendments, 
considers  pollutants  In  four  phases: 

Phase  I:    Volatile  Organic  Chemicals  (VOCs) 

Phase  II:  Synthetic  Organic  Chemicals  (SOCs),  Inorganic 
chemicals,  and  microbiological  contaminant 
regulations 

Phase  III:  Radionuclide  Contaminants  Regulations 

Phase  IV:  Disinfectant  By-Product  Contamination  Regu- 
lations 

22.11  Schedule 

The  EPA's  schedule  for  compliance  with  the  SDWA 
Amendments  of  1986  Is  listed  below. 

June  1987-  Promulgate  MCLs  for  at  least  9  chemi- 
cals. EPA  has  prepared  MCLs  for  8 
VOCs,  fluoride,  and  lead. 

December  1987-  Promulgate  criteria  for  the  mandatory 
filtration  of  surface  water  sources.  This 
has  been  delayed  until  1988. 
January  1988 -Publish  a  list  of  contaminants  which 
may  require  regulation  by  EPA.  Begin 
monitoring  of  33  unregulated  VOCs. 

June  1988-  Promulgate  MCLs  for  at  least  40  conta- 
minant chemicals  in  water. 

June  1989-  Promulgate  MCLs  for  at  least  34  conta- 
minant chemicals  in  water. 
January  1991- Promulgate  MCLs  for  25  contaminant 
chemicals  in  water.  This  Is  the  first  of  a 
triannual  promulgation  of  25  MCLs. 

At  first  glance,  this  schedule  for  setting  standards  appears 
reassuring.  Keep  in  mind,  however,  that  protection  from 
regulated  contaminants  does  not  occur  the  instant  a  regula- 
tion is  published.  The  Act  requires  the  regulation  of  nine 
contaminants  within  12  months  of  its  passage.  These  Phase 
I  contaminant  limits  were  promulgated  In  1987,  but  because 
the  drinking  water  program  is  a  federal-state  partnership, 
states  are  allowed  18  additional  months  to  adjust  their  own 
regulations.  Therefore,  water  systems  will  more  than  likely 
not  be  required  to  meet  Phase  I  regulations  urtil  two-and-a- 
half  years  after  the  law  was  passed. 

All  public  water  systems  must  comply  with  the  regulations. 
This  includes  all  public  and  privately  owned  systems  that: 

1.  Have  at  least  15  service  connections  which  are  used 
at  least  60  days  out  of  the  year,  or 

2.  Serve  an  average  of  at  least  25  people  at  least  60  days 
out  of  the  year. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  527. 


22.0A  What  were  the  first  drinking  water  standards  de- 
signed to  control? 

22.1A  List  the  major  aspects  of  the  1986  Amendments  to 
the  SDWA. 

22.1  B  Why  will  water  systems  not  be  required  to  meet 
Phase  I  regulations  until  two-and-a-half  years  after 
the  law  was  passed? 


22.2  DISINFECTANTS  AND  DISINFECTION 
BY-PRODUCTS 

The  EPA's  initial  draft  list  of  25  regulated  compounds  (the 
first  of  thrije  such  lists  to  be  issued  at  three  year  Intervals) 
emphasJ.:es  limits  on  the  concentration  of  disinfection  re- 
siduals and  disinfection  by-products.  These  new  regulations 
are  expected  to  set  lower  MCLs  for  trihalomethanes  (THMs) 
plus  limit  disinfectants  (chlorine,  chlorine  dioxide,  chlora- 
mines,  hypochlorite  ion,  and  ozone),  inorganic  by-products 
(chlorite),  and  organic  by-products  which  are  principally 
other  chlorinated  compounds  (halogenated  acids,  alcohols, 
aldehydes,  and  ketones  and  halonitrlles).  Compliance  with 
these  standards  is  likely  to  radically  alter  current  water 
treatment  disinfection  practices  by  curtailing  the  use  of 
chlorine  and  Increasing  the  use  of  alternatives  oucn  as 
ozone  and  chloramines. 

Of  the  substances  mentioned  above,  only  trihalomethanes 
(THMs)  are  regulated  at  the  present  time..  THMs  are  the 
product  of  chlorine  combining  with  organic  material  in  the 
water.  They  are  suspected  of  being  carcinogenic.  The  MCL 
established  for  total  trihalomethanes  (TTHMs)  is  0.10  milli- 
grams per  liter  or  100  micrograms  per  liter.  EPA  Is  expected 
to  strengthen  this  standard  by  reducing  the  MCL  and  consid- 
ering whether  additional  standards  of  this  type  are  neces- 
sary. 

22.3  SURFACE  WATER  TREATMENT  RULE  (SWTR) 

In  1987,  the  EPA  prepared  a  draft  Surface  Water  Treat- 
ment Rule  (SWTR)  that  specifies  which  water  supplies  that 
must  be  filtered  and  provides  performance  criteria  for  both 
filtered  water  sources  and  those  treated  by  disinfection  only. 
The  draft  SWTR  specifically  requires  that: 

1 .  All  surface  water  systems  must  disinfect. 

2.  All  surface  water  systems  must  filter  unless  they  meet 
source  water  quality  cnteria  and  site-specific  condi- 
tions. States  w'!l  determine  which  systems  will  need  to 
install  filtration  or  upgrade  existing  filtration  and  disin- 
fection. 


ERIC 


Mfi. 


Water  Quality  Regulations  497 


3.  All  systems  will  need  to  achieve  the  removal  or 
inactivation  criteria  of  Giardia  and  enteric  viruses. 

4.  Only  qualified  operators  will  be  entitled  to  operate  the 
systems. 

The  general  performance  criteria  to  be  met  by  surface 
water  systems  are  primarily  directed  toward  acute  health 
risks  from  waterbo^ne  microbiological  contaminants.  The 
requirements  are: 

1.  At  least  99.9  pr  :ent  removal  and/or  inactivation  of 
Giardia  lamblia  ^ysts,  and 

2.  At  least  99.99  percent  removal  and/or  inactivation  of 
enteric  viruses. 

In  general,  compliance  by  the  surface  water  purveyor 
could  be  through  one  of  the  following  alternatives: 

1 .  Meeting  the  criteria  for  which  filtration  is  not  required 
and  providing  disinfection  according  to  the  specific 
requirements  in  the  SWTR,  or 

2.  Providing  filtration  and  meeting  disinfection  criteria 
required  for  those  supplies  that  are  filtered. 

Mandatory  filtration  is  expected  to  affect  the  small  and 
medium-sized  water  systems  most  severely.  A  few  large 
surface  water  systems  do  not  filter  their  water;  more  than 
nine  million  people  drink  unfiltered  water  in  Seattle,  New 
York  City,  and  Boston  alone.  However,  most  of  the  unfiltered 
surface  water  systems  serve  communities  with  fewer  than 
10,000  residents. 

22.30  Requirement  for  Non-Filtered  Systems 

To  avoid  mandatory  filtration,  a  water  utility  must  meet: 

1.  Source  water  quality  criteria  (coliforms  and  turbidity 
levels),  and 

2.  Certain  site-specific  conditions, 

(a)  has  disinfection  that  achieves  99.9  percent  inacti- 
vation of  Giardia  and  99.99  percent  inactivation  of 
viruses. 

(b)  watershed  control  or  sanitary  surveys  that  satisfy 
regulatory  requirements. 

(c)  no  history  of  waterborne  disease  outbreak  without 
making  treatment  corrections. 

(d)  compliance  with  long-term  coliform  maximum  con- 
taminant level  (MCL). 

(e)  compliance  with  total  trihalomethanes  MCL,  if  the 
system  serves  more  than  10,000  people. 

If  a  system  cannot  meet  the  source  water  quality  criteria 
and  site-specific  conditions  listed  above,  then  the  system 
must  install  and  operate  appropriate  filtration  facilities. 

22.31  Requirements  for  Filtered  Water  Systems 

For  systems  that  filter,  the  primary  concern  is  adequate 
disinfection  and  filtration  performance.  The  requirements 
are: 

1.  For  conventional  or  direct  filtration  systems,  the  fil- 
tered water  turbidity  must  be  less  than  or  equal  to  0.5 
TU^  for  at  least  95  percent  of  each  month's  measure- 
ments. For  sIdw  sand  or  diatomaceous  earth  filtration. 


the  filtered  water  turbidity  must  be  less  than  1  NTU  in 
at  least  95  percent  of  the  measurements  taken  each 
month. 

2.  Filtered  water  must  never  exceed  five  TUs. 

3.  A  disinfectant  residual  in  the  distribution  system  of  0.2 
mg/L  in  95  percent  of  the  samples  be  maintained. 

As  a  further  measure  of  filtration/disinfection  perfor- 
mance, the  SWTR  refers  to  the  use  of  CT  (residual  concen- 
tration X  time)  values  for  various  disinfectants.  Conformance 
with  CT  values  could  be  the  means  of  meeting  Giardia  and 
virus  inactivation  limits.  It  is  expected  that  most  states  will 
follow  EPA  recommendations  and  include  CT  analysis  for 
evaluating  disinfection  effectiveness. 

22.32  Monitoring  Requirements  of  the  SWTR 

Unfiltered  surface  water  systems  must: 

1 .  Monitor  raw  water  for  coliforms  (frequency  is  depen- 
dent on  system  size)  and  turbidity  every  4  hours 
(continuous  monitoring  allowed  with  measurement 
every  4  hours); 

2.  Continuously  monitor  the  disinfectant  residual  enter- 
ing the  distribution  system; 

3.  Sample  the  distribution  system  for  disinfectant  residu- 
als (freqiiency  depends  on  system  size); 

4.  Monitor  daily  to  demonstrate  that  the  level  of  disinfec- 
tion achieved  is  99.9  percent  inactivation  of  Giardia 
and  99.99  percent  inactivation/r6r.r"al  enteric  vi- 
ruses. 

Filtered  systems  must: 

1.  Perform  turbidity  measurements  of  representative 
water  every  4  hours  (which  can  be  continuous  moni- 
toring); 

2.  Continuously  monitor  the  disinfectant  residual  enter- 
ing the  distribution  system; 

3.  Sample  in  the  distribution  system  for  disinfectant 
residuals  (sampling  frequency  depends  on  system 
size). 

22.33  Turbidity  Requirements  of  the  SWTR 

To  avoid  filtration,  the  level  of  a  system's  unfiltered  water 
turbidity  would  have  to  be  less  than  5  TU.  For  filtered  water 
systems,  the  filtered  water  must  be  less  than  either  0.5  TU  or 
less  than  1  TU  for  95  percent  of  the  time,  depending  upon 
the  technology  being  used,  and  must  at  no  time  exceed  5 


ERIC 


Turbidity  Units.  Turbidity  units  are  a  measure  of  the  cloudiness  of  water  If  measured  by  a  nephelometric  (deflected  light)  instrumental 
procedure,  turbidity  units  are  expressed  in  nephelometric  turbidity  units  (NTU)  or  simply  TU  Those  turbidity  units  obtained  by  visual 
methods  are  expressed  in  Jackson  Turbidity  Units  (JTU)  which  are  a  measure  of  the  cloudiness  of  water,  they  are  used  to  indicate  the 
clarity  of  water  There  is  no  real  connection  between  NTUs  and  JTUs.  The  Jackson  turbidimeter  is  a  visual  method  and  the  nephelometer 
is  an  instrumental  method  based  on  deflected  light. 


517 


498  Water  Treatment 


Unflltered  systems  are  required  to  begin  with  a  clean 
source  water  and  have  a  watershed  that  is  protected  from 
human  activities  that  might  otherwise  have  an  adverse 
impact  on  water  quality.  Unfiltered  systems  would  have  very 
little,  if  any,  virus  contamination.  For  these  systems,  the 
major  concern  is  Giardia  contamination  from  animal  activi- 
ties that  cannot  be  prevented  by  watershed  protection.  The 
purpose  of  the  turbidity  limit  for  unflltered  water  is  to  ensure 
a  high  probability  that  turbidity  does  not  Interfere  with 
disinfection  of  Giardia  cysts.  The  turbidity  limit  of  5  TU 
serves  this  purpose. 


For  filtered  water  systems,  the  major  burden  for  Giardia 
removal  rests  with  filtration.  With  conventional  treatment 
and  direct  filtration,  low  turbidity  levels  (<0.5  TU)  are 
needed  to  ensure  effective  Giardia  cyst  removals.  Disinfec- 
tion of  either  Giardia  or  viruses  will  not  be  hampered  at  these 
turbidity  levels. 

For  slow  sand  filtration  and  diatomaceous  earth  filtration, 
effective  Giardia  removal  does  not  necessarily  correlate  with 
low  treated  water  turbidities.  However,  to  ensure  effective 
virus  inactivatlon,  a  low  filtered  water  turbidity  Is  needed. 
Viruses  are  much  smaller  than  Giardia,  and  thus  a  lower 
turbidity  limit  of  1  TU  is  needed  compared  with  the  turbidity 
level  of  5  TU  for  unfiltered  supplies  to  ensure  effective 
disinfection. 

QUESTIONS 

Write  your  answers  In  a  notebook  and  then  compare  your 
answers  with  those  on  page  527. 

22.2A  What  are  THMs? 

22.3A  What  does  the  draft  Surface  Water  Treatment  Rule 
(SWTR)  specifically  require? 

22.3B  How  can  a  water  utility  avoid  mandatory  filtration? 
22.4  TYPES  OF  WATER  SYSTEMS 

All  the  drinking  water  regulations  apply  to  two  types  of 
public  water  systems:  (1)  community  water  systems,  and  (2) 
non-community  water  systems. 


22*40  Community  Water  Systems 

A  community  water  systCir,  is  defined  as  follows: 

1.  Has  at  'east  15  service  connections  used  by  all-year 
residents,  or 

2.  Services  at  least  25  all-year  residents. 
22.41   Non-Community  Water  Systems 

A  non-community  water  system  Is  defined  as  follows: 

1.  Has  at  least  15  service  connections  used  by  travelers 
or  Intermittent  users  at  least  60  days  a  year,  or 

2.  Services  a  daily  average  of  at  least  25  people  at  least 
60  days  a  year. 

Any  water  system  that  provides  services  for  fewer  con- 
nections or  persons  listed  above  is  not  covered  by  the 
SDWA.  However,  regardless  of  size,  all  operators  must 
strive  to  provide  consumers  with  a  potable  drinking  water. 

22.5   INTERIM  PRIMARY  DRINKING  WATER  STANDARDS 

22.50  Establishment  of  Drinking  Water  Standards 

The  drinking  water  standards  established  by  EPA  reflect 
the  best  scientific  and  technical  judgment  available.  They 
were  refined  by  the  suggestions  and  advice  of  the  15- 
member  National  Drinking  Water  Advisory  Council,  made  up 
of  representatives  of  the  general  public,  state  and  local 
agencies,  and  experts  in  the  field  of  public  water  supply.  The 
Department  of  Health  and  Human  Services  as  well  as  other 
agenciss  and  organizations  contributed  to  the  developmen* 
of  the  National  Interim  Primary  Dnnking  Water  Regulations. 

The  regulations  set  achievable  levels  of  dnnking  water 
quality  to  protect  your  health.  They  are  called  "intenm" 
regulations  because  research  continues  on  dnnking  water 
contaminants.  The  existing  standards  may  be  strengthened 
and  new  standards  may  be  established  for  other  substances 
based  on  studies  being  conducted  by  the  National  Academy 
of  Sciences,  EPA,  and  others. 

EPA  has  established  standards  (maximum  contaminant 
levels)  for  ten  chemicals,  six  pesticides,  bacteria,  radioactiv- 
ity, turbidity,  and  tnhalomethanes.  Most  of  ♦hese  substances 
occur  naturally  m  our  environment  and  in  the  foods  we  eat 
The  national  dnnking  water  standards  set  by  EPA  reflect  the 
levels  we  can  safely  consume  in  our  water,  taking  into 
account  the  amounts  we  are  exposed  to  from  these  other 
sources 

22.51  Types  of  Contaminants 

Five  types  of  primary  contaminants  are  considered  to  be 
of  public  health  importance: 

1  INORGANIC  CONTAMINANTS,  such  as  lead  and  mer- 
cury, 

2.  ORGANIC  CONTAMINANTS,  which  now  Include  pesti- 
cides, herbicides  and  tnhalomethanes,  but  may  be  ex- 
panded to  include  solvents  and  other  synthetic  organic 
compounds; 

3.  TURBIDITY,  such  as  small  particles  suspended  in  water 
which  interfere  with  light  penetration  and  disinfection; 

4.  MICROBIOLOGICAL  CONTAMINANTS,  such  as  bacte- 
ria,  virus,  and  protozoa;  and 

5  RADIOLOGICAL  CONTAMINANTS,  which  include  natural 
and  man-made  sources  of  radiation. 


ERIC 


518 


Water  Quality  Regulations  499 


22.52  Immediate  Threats  to  Health 

Only  two  substances  for  which  standards  have  been  set 
pose  an  immediate  threat  to  health  whenever  they  are 
exceeded,  (1)  bacteria,  and  (2)  nitrate. 

22.520  Bacteria 

Coliform  bacteria  from  human  and  animal  wastes  may  be 
found  in  drinking  water  if  t»ie  water  is  not  properly  treated. 
These  bacteria  usually  do  not  themselves  cause  diseases 
transmitted  by  water,  but  indicate  that  other  harmful  organ- 
isms may  be  present  in  the  water.  Waterborne  diseases 
such  as  typhoid,  cholera,  infectious  hepatitis,  and  dysentery 
have  been  traced  to  laiproperly  disinfected  dnnking  water. 
Certain  coliforms  have  been  identified  as  the  cause  of 
"travelers"  diarrhea. 

2Z521  Nitrate 

Nitrate  in  drinking  water  above  the  national  standard  of 
1 00  mg/L  (as  N)  poses  an  immediate  threat  to  children  under 
three  months  of  age.  In  some  infants,  excessive  levels  of 
nitrate  have  been  known  to  react  with  intestinal  bacteria 
which  change  nitrate  to  nitrite  which  reacts  with  the  hemo- 
globin in  the  blood  This  reaction  will  reduce  the  oxygen 
carrying  ability  of  the  blood  and  produce  an  anemic  condi- 
tion commonly  known  as  "blue  baby." 

Non-community  systems  MAY  be  allowed  to  serve  water 
containing  up  to  90  mg/L  nitrate  if. 

1 .  The  water  is  not  available  to  infants  six  months  of  age 
and  younger. 

2.  Posting  of  the  potential  health  hazard  is  maintained; 

3  State  and  local  health  authorities  are  notified  and  agree; 
and 

4.  No  threat  to  health  will  result 

22.53  Setting  Standards 

The  process  by  which  EPA  establishes  drinking  water 
standards  is  both  long  and  complicated.  A  standard  is  the 
maximum  level  of  a  substance  that  EPA  has  deemed  accept- 
able in  drinking  water.  The  first  step  in  the  setting  of  a 
standard  is  to  stu1y  the  hunan  and  animal  health  effects  of  a 
given  chemical.  These  studies  are  normally  performed  using 
rats  or  mice.  Based  on  these  studies,  E'^A  establishes  a  "no 
observed  adverse  effect"  level  (abbreviated  as  "NOAEL").  A 
ssfcty  far  lor  is  added  to  the  NOAEL  and  the  result  is  an 
accep\r.o\e  daily  intake  limit  of  the  chemical  in  question.  The 
limit  is  adjusted  to  take  into  account  the  average  woight  and 
water  consumption  of  the  consumer,  and  the  resulting  figure 
IS  called  a  maximum  contaminant  level  goal,  or  MCLG  . 


The  maximum  contaminant  level  goal  represents  what 
EPA  believes  to  be  a  safe  level  of  consumption  based  solely 
on  Its  studies  of  health  effects.  It  is,  however,  a  goal  rather 
than  an  immediately  achievable  constituent  limit.  To  develop 
more  realistic,  enforceable  limits,  EPA  further  revises  the 
MCLG  to  take  into  account  existing  laboratory  detection 
technology,  costs,  and  reasonableness.  After  adjusting  for 
these  factors,  EPA  sets  the  maximum  contaminant  level 
(MCL)  as  close  to  the  MCLG  as  is  realistically  feasible.  The 
important  difference  between  the  two  levels  is  that  the 
MCLG  is  a  nonenforceable  goal  and  the  MCL  is  an  enforce- 
able standard. 

The  Maximum  Contaminant  Levels  (MCLS)  are  the  highest 
permissible  concentration  of  a  particular  substance  in  water. 
The  MCLs  apply  whether  the  contaminant  is  from  naturally 
occurring  sources  or  from  man-made  pollution.  More  types 
of  contaminents  must  be  monitored  by  community  than  by 
non-community  systems  as  shown  on  Table  22.2, 


TABLE  22.2    CONTAMINANTS  MONITORED  BY 
COMMUNITY  AND  NON-COMMUNITY  WATER  SYSTEMS 

Community  Water  Systems 

Period  of  Exposure 
Contamin<:nt  Which  May  Affect  Health 


Inorganic  Chemicals 
(except  nitrate) 

Inorganic  Chemicals  (nitrate  only) 

Organic  Chemicals 

Turbidity 

Microbiological  Contaminants 
Radiological  Contaminants 


Long-term 

Short-term 
Long-term 
Short-term 
Short-term 
Long-term 


Non-Community  Water  Systems 

Period  of  Exposure 
Which  May  Affect  Health 

Short-term 


Contaminant 


Inorganic  Chemicals 
(nitrate  only) 

Turbidity 

Microbiological  Contaminants 


Short-term 
Short-term 


ERIC 


519 


500  Water  Treatment 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  528. 

22.4A  Define  a  community  water  system. 

22.5A  List  the  five  types  of  primary  contaminants  which  are 
considered  to  be  of  public  health  importance. 


22.5B  Why  is  nitrate  considered  an  immediate  threat  to 
public  health'? 


DISCUSSION  AND  REVIEW  QUESTIONS 

Chapter  22.   DRINKING  WATER  REGULATIONS 

(Lesson  1  of  2  Lessons) 


At  the  end  of  oach  lesson  in  this  chapter  you  will  find  some 
discussion  and  review  questions  that  you  should  answer 
before  continuing.  The  purpose  of  these  questions  is  to 
indicate  to  you  how  well  you  understand  the  material  in  the 
lesson.  Write  the  answers  to  these  questions  in  your  note- 
book before  continuing. 

1 .  What  will  be  the  im  pact  of  the  1 986  Amendments  to  the 
SDWA  on  water  treatment  disinfection  practices? 

2.  Why  are  THMs  regulated? 

3.  Mandatory  filtration  is  expected  to  p.ffect  what  sized 


water  systems  most  severely? 

4.  What  is  a  community  water  system*? 

5.  What  is  the  difference  between  a  community  and  a  non 
community  water  system? 

6.  What  are  f^aximum  Contaminant  Levels  (f^CLs)? 

7.  Why  IS  turbidity  undesirable  in  a  finished  or  treate 
water? 

8    How  do  conform  bacteria  get  into  drinking  water  ar 
what  does  their  presence  indicate? 


ERIC 


520 


Water  Quality  Regulations  501 


CHAPTER  22.   DRINKING  WATER  REGULATIONS 

(Lesson  2  of  2  Lessons) 

22.6  PRIMARY  STANDARDS 

Primary  Standa*'^s  or  MCLs  are  set  for  substances  that 
are  thought  to  pose  a  threat  to  health  when  present  in 
drinking  water  at  certain  levels.  Because  these  substances 
are  of  health  concern,  primary  standards  are  enforceable  by 
law.  (In  contrast,  secondary  standards  relate  to  cosmetic 
factors  and  are  not  federally  enforceable.)  A  primary  stan- 
dard can  also  be  referred  to  as  a  maximum  contaminant 
level  (MCL).  In  July  1987  EPA  finalized  MCLs  for  eight 
volatile  organic  chemicals  bringing  the  number  of  primary 
standards  to  30.  Table  22.3  lists  the  currsnt  (January,  1988) 
primary  standards  and  health  concerns  associated  with  the 
contaminants. 

22.60  Inorganic  Chemical  Standards 

Inorganic  chemicals  are  metals,  salts,  and  other  chemical 
compounds  that  do  not  contain  carbon.  The  health  concerns 


about  inorganic  chemicals  are  not  centered  on  cancer,  but 
rather  on  their  suspected  links  to  several  different  human 
disorders.  For  example,  lead  is  suspected  of  contributing  to 
mental  retardation  in  children. 

Presently,  only  ten  inorganic  chemicals  are  regulated  but 
several  others  are  being  studied  and  considered  possible 
candidates.  They  are:  aluminum,  antimony,  molybdenum, 
asbestos,  sulfate,  copper,  vanadium,  sodium,  nickel,  zinc, 
thallium,  beryllium,  and  cyanide.  The  following  paragraphs 
briefly  discuss  each  of  the  inorganic  contaminants  regulated 
by  the  national  drinking  water  standards.  Waters  exceeding 
the  MCL  for  these  elements  for  short  periods  of  time  will 
pose  no  immediate  threat  to  health.  However,  studies  show 
that  these  substances  must  be  controlled  because  con- 
sumption of  drinking  water  that  exceeds  these  standards 
over  long  periods  of  time  may  prove  harmful. 


502  Water  Treatment 


CONTAMINANT 


TABLE  22,3    PRIMARY  DRINKING  WATER  STANDARDS 

MCL  (mg/L)  HEALTH  EFFECT 


Inorganics 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Mercury 
Nitrate 

Selenium 

Silver 

Fluoride 

Organics 

Endrin 
Lindane 
Methoxychlor 
2,4-D 

2.4,5-TP  Silvex 

Toxaphene 

Benzene 

Carbon  Tetrachloride 
p-Dichlorobenzene 
1,2-Dichloroethane 
1,1-Dichloroethylene 
1,1.1-Trichloroethane 
Trichloroethylene  (TEC) 
Vinyl  Chloride 
Trihalomethanes 

Microbiological 
Total  Conforms 


Physical 

Turbidity 

Radionuclides 

Gross  alpha  particles 
Gross  beta  particles 
Radium  226  &  228 


0.05 
1.00 
0.01 
0.05 
0.05 

0.002 
10.0 

0.01 
0.05 
4.00 


O.OOOn 

0.004 

0.10 

0.1 

0.01 

0.005 

0.005 

0.005 

0.075 

0.005 

0.007 

0.2 

0.005 

0.002 

0.10 


1  per  lOOmL 


1-5  TU 


15pCi/L 
4  mrem/yr 
6  pCi/L 


dermal/nervous  system  toxicity 
circulatory  system  effects 
kidney  effects 
liver  and  kidney  effects 
nervous  system/kidney  damage 

toxic  to  infants  &  pregnant  women 
nervous  system/kidney  disorders 
Methemoglobinemia  ("blue-baby" 

syndrome) 
gastrointestinal  effects 
skin  discoloration 
skeletal  damage 


nervous  system/kidney  effects 
nervous  system/liver  effects 
nervous  system/kidney  effects 
liver/kidney  effects 
liver/kidney  effects 
cancer  risk 
cancer 

possible  cancer 
possible  cancer 
possible  cancer 
liver/kidney  effects 
nervous  system  effects 
possible  cancer 
cancer  risk 
cancer  risk 


indicators  of  disease-causing 
organisms 


interferes  with  disinfection 


cancer 
cancer 
bone  cancer 


ERIC 


522 


Water  Quality  Regulations  503 


22.600  Arsenic 

This  element  occurs  naturally  in  the  environment,  espe- 
cially in  the  western  United  States  and  it  is  also  used  m 
insecticides  Arsenic  is  found  m  foods,  tobacco,  shellfish, 
drinking  water  and  in  the  air  m  some  locations.  The  national 
standard  for  arsenic  is  0  05  milligrams  per  liter  of  water 
Wate*"  that  continuously  exceeds  the  national  standard  by  a 
substantial  amount  over  a  lifetime  may  cause  fatigue  and 
loss  of  energy  Extremely  high  levels  can  cause  poisoning 


22.601  Barium 

Although  not  as  widespre  d  as  arsen»c.  this  element  also 
occurs  naturally  in  the  environment  in  some  areas  Barium 
can  also  enter  water  supplies  through  industrial  v/aste 
discharges  Small  doses  of  barium  are  no*  harmful  How<iv- 
er.  It  IS  quite  dangerous  when  consumed  in  large  quantities 
and  will  bring  on  increased  blood  pressuie,  nerve  damage, 
and  even  death.  1  ne  maximum  amount  of  barium  allowed  in 
drinking  water  by  the  national  standard  is  one  miliig''am  per 
liter  of  water. 

22.602  Cadmium 

Only  extremely  small  amounts  of  this  elenr  e.jt  are  found  in 
natural  waters  m  the  United  States  Waste  discharges  from 
the  electroplating,  photography,  insecticide,  and  metallurgy 
industries  can  increase  cadmium  levels,  hov-'^ver  The  most 
common  source  of  cadmium  in  our  dnnkin  water  is  from 
galvanized  pipes  and  fixtures  The  maximum  amount  of 
cadmium  allowed  in  drinking  water  by  the  national  stanuard 
IS  0  01 0  milligrams  per  liter  of  water 

22.603  Chromium 

This  metal  is  found  in  cigarettes,  some  of  our  foods,  and 
the  air.  Some  studies  suggest  that  m  very  small  amounts, 
chromium  may  be  essential  to  human  beings*  but  this  has 
not  been  proven  The  national  standard  for  chromium  is  0  05 
milligrams  per  liter  of  water. 


22.604  Fluoride 

This  IS  a  natural  mineral  and  many  drinking  waters  contain 
some  fluonde.  Fluoride  produces  two  effects,  depending  on 
Its  concentration,  and  EPA  has  set  both  primary  and  secon- 
dary limits  to  regulate  it.  At  levels  of  6  to  8  mg/L  fluoride  may 
cause  skeletal  fluorosis  which  is  a  brittling  of  the  bones  and 
stiffening  of  the  joints.  On  the  basis  of  this  health  hazard, 
fluonde  has  been  added  to  the  list  of  primary  standards. 

At  levels  of  2  mg/L  and  greater  fluoride  may  cause  dental 
fluorosis  which  is  discoloration  and  mottling  of  the  teeth, 
especially  in  children.  EPA  has  recently  reclassified  dental 
fluorosis  as  a  cosmetic  effect  raised  the  primary  drinking 
water  standard  from  1 .4  -  2  mg/L  to  4  mg/L,  and  established 
a  secondary  standard  of  2  mg/L  for  fluoride. 

22.605  Lead 

This  metal  is  found  in  the  air  and  m  our  food.  Lead  comes 
from  galvanized  pipes,  solder  used  with  copper  pipes,  auto 
exhausts,  and  other  sources.  The  maximum  amount  of  lead 
permitted  in  drinking  water  by  the  national  standards  is  0  05 
milligrams  per  liter  of  water.  Excessive  amounts  well  above 
this  standard  may  result  m  nervous  system  disorders  or 
brain  or  kidney  damage. 

22.606  Mercury 

Mercury  Is  found  naturally  throughout  the  environment. 
Large  increases  in  mercury  levels  in  water  can  be  caused  by 
industrial  and  agricultural  use.  The  health  risk  from  mercury 
is  greater  from  mercury  in  fish  than  simply  from  waterborne 
mercury.  Mercury  poisoning  may  be  ACUTE^  in  large  doses, 
or  CHRONIC^  from  lower  doses  taken  over  an  extended 
time  period. 

22.607  Selenium 

This  mineral  occurs  naturally  in  soil  and  plants,  especially 
in  western  states  Selenium  is  found  in  meat  and  other 
foods.  Although  it  is  believed  to  be  essential  in  the  diet,  there 
are  indications  that  excessive  amounts  of  selenium  may  be 
toxic.  Studies  are  under  way  to  determine  the  amount 
required  for  good  nutrition  and  the  amount  that  may  be 
harmful. 

The  national  standard  for  selenium  is  0.01  milligrams  per 
liter  of  water.  If  a  person's  intake  of  selenium  came  only 
from  drinking  water,  it  would  take  an  amount  many  times 
greater  than  the  standard  to  produce  any  ill  effects. 

22.608  Silver 

This  metal  should  pose  no  problem  Silver  is  sometimes 
used  in  proprietary  water  treatment  devices  for  disinfectmr^ 
water  The  maximum  amount  of  silver  allowed  m  drinking 
water  by  the  national  standard  is  0  05  milligrams  per  liter  of 
water 


2  Acute,   When  the  effects  of  an  exposure  cause  severe  symptoms  to  occur  quickly,  the  symptoms  are  said  to  be  acute  because  they  are 
brief  and  severe, 

3  Chrome,   Effects  of  repeated  exposures  over  a  longer  period  of  time  which  eventually  cause  symptoms  that  continue  for  a  long  time 


ERIC 


504  Water  Treatment 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  528. 

22.6A  What  are  inorganic  chemicals? 

22.6B  Why  is  arsenic  listed  as  a  primary  contaminant? 

22.6C  What  are  two  detnmental  effects  oi  excessive  levels 
of  fluoride? 

22.6D  What  are  the  sources  of  lead  in  drinking  water? 


22.61   Organic  Chemical  Standards 

Organic  chemicals  are  either  natural  or  synthetic  chemical 
compounds  that  contain  carbon.  Synthetic  organic  chemi- 
cals (SOCs)  are  man-made  compounds  and  are  used 
throughout  the  worid  as  pesticides,  paints,  dyes,  solvents, 
plastics,  and  food  additives.  Volatile  organic  chemicals 
(VOCs)  are  a  subcategory  of  organic  chemicals.  These 
chemicals  are  termed  "volatile"  as  they  evaporate  easily.  The 
most  commonly  found  VOCs  are  trihalomethanes  (THMs). 
trichloroethylene  (TOE),  tetrachloroethylene,  and  1,1-dich- 
loroethane.  THMs  were  the  first  regulated  VOC  when  EPA 
finalized  regulations  in  1979. 

The  most  common  sources  of  organic  contamination  of 
drinking  water  are  pesticides  and  herbicides.  Industrial  sol- 
vents, and  disinfection  by-prcducts  (trihalomethanes).  Mil- 
lions of  pounds  of  pesticides  are  used  on  croplands,  forests, 
lawns,  and  gardens  in  the  United  States  each  year.  They 
drain  off  into  surface  waters  or  seep  into  underground  water 
supplies.  Spills,  poor  storage,  and  haphazard  disposal  of 
organic  chemicals  have  resulted  in  widespread  groundwater 
contamination.  This  is  a  critical  problem  since  groundwater, 
once  contaminated,  may  remain  that  way  for  a  long  time. 

Many  organic  chemicals  pose  health  problems  if  they  get 
into  drinking  water  and  the  water  is  not  properiy  treated.  The 
maximum  limits  for  pesticides  in  drinking  water  are  shown 
on  Table  22.3  (page  502).  Based  on  a  review  of  the  available 
toxicological  data,  EPA  has  categorized  the  eight  regulated 
VOCs  as  shown  on  Table  22.4. 

As  directed  by  Congress  in  the  1986  Amendments,  the 
EPA  will  regulate  83  contaminants  by  1989  (including  14 
VOCs  and  35  SOCs)  and  will  undertake  p+udies  of  at  least  25 
additional  contaminants  for  potential  regulation  by  1990. 


TABLF-  22.4   HEALTH  EFFECTS  CATEGORIES  OF  THE  VOCS 

Category  I:     Known  or  Probable  Human  Carcinogens 

Benzene 
Vinyl  Chloride 
Carbon  etrachloride 
1 .2-Dichloroethane 
Trichloroethylene 

Category  II:    Limited  But  Insufficient  Evidence  of  Carcinogenicity 

1,1-Dichloroethylene  -  causes  liver  and  kidney  damage  in  animals  at  high  doses;  also  affects  central  nervous 
system  and  heart 

Category  III:  Inadequate  or  No  Evidence  of  Carcinogenicity 

1 ,1 , 1-Trichloroethane  -  causes  depression  of  central  nervous  system  and  changes  in  the  cardiovascular  svjtem 
ana  liver  in  humans  and  animals  oy^v^m 

p-Dichlorobenzene  -  causes  liver  damage  and  is  suspected  of  being  an  animal  carcinogen 


ERIC 


52i 


Water  Quality  Regulations  505 


22.610  TricMoroethylene  (TCE) 

Although  the  use  of  trichloroethylene  is  declining  because 
of  stringent  regulations,  it  was,  for  many  years,  a  common 
ingredient  in  household  products  (spot  removers,  rug  clean- 
ers, air  fresheners),  dry  cleaning  agents.  Industrial  metal 
cleaners  and  polishers,  refrigerants,  and  even  anesthetics, 
its  Wide  range  of  use  is  perhaps  why  TCE  is  the  organic 
contaminant  most  frequently  encountered  m  groundwater. 
The  MCL  for  TCE  is  0.005  mg/L. 

22.611  1, 1'Dichloroethylene 

This  solvent  is  used  in  manufacturing  plastics  and,  more 
recently,  in  the  production  of  1 ,1 ,1-trichloroethane.  The  MCL 
for  this  chemical  is  0.2  mg/L 

22.612  Vinyl  Chloride 

Billions  of  pounds  of  this  solvent  are  used  annually  in  the 
United  States  to  produce  polyvinyl  chloride  (PVC),  the  most 
widely  used  Ingredient  for  manufacturing  plastics  through- 
out the  world.  There  is  also  evidence  that  vinyl  chloride  may 
be  a  biodegradatlon  end-product  of  tri-  and  tetrachloroethy- 
lene  under  certain  environmental  conditions.  The  MCL  for 
vinyl  chloride  is  0.002  mg/L 

22.613  1,1,1'Trichloroethane 

This  chemical  has  replaced  TCE  in  many  industrial  and 
household  products.  It  is  the  principal  solvent  In  septic  tank 
degreasers,  cutting  oils,  inks,  shoe  polishes,  and  many  other 
products.  Among  the  VOCs  found  in  groundwaters,  1,1,1- 
trlchloroethane  and  TCE  are  encountered  most  frequently 
and  ir  the  highest  concentrations.  The  MCL  for  this  contami- 
nant is  0.2  mg/L 

22.614  1,2'Dichloroethane 

1,2-Dichloroethane  is  used  as  a  solvent  for  fats,  oils, 
waxes,  gums,  and  resins.  The  MCL  for  this  chemical  is  0.005 
mg/L. 

22.615  Carbon  Tetrachloride 

Carbon  tetrachloride  was  once  a  popular  household  sol- 
vent, a  frequently  used  dry  cleaning  agent,  and  a  charging 
agent  for  fire  extinguishers.  Since  1970,  however,  carbon 
tetrachloride  has  been  banned  from  all  use  In  consumer 
goods  in  the  United  States  and  in  1978,  it  was  banned  an 
aerosol  propellant.  Currently  its  principal  use  is  in  ,ne 
manufacture  of  fluorocarbons  which  are  used  as  refriger- 
ants. The  MCL  for  carbon  tetrachloride  is  0.005  mg/L  (5 
ug/L). 

22.616  Benzene 

Benzene  is  usee  primarily  in  the  synthesis  of  styrene  (for 
plastics),  phenol  (for  resins),  and  cyclohexane  (for  nylon). 
Other  uses  include  the  production  of  detergents,  drugs, 
dyes,  and  insecticides.  Benzene  is  still  being  used  as  a 
solvent  and  as  a  component  of  gasoline.  The  MCL  for 
benzene  is  0.005  mg/L  (5  ug/L). 

22.617  1,4'Dichlorobenzene  (p-dichlorobenzene) 

The  principal  uses  of  this  c!<erriical  are  in  moth  control 
(balls,  powders)  and  as  lavatory  deodorants.  The  MCL  Is 
0.075  mg/L  (75  ug/L). 

22.62  Turbidity  Standards 

Turbidity  is  undesirable  in  a  finished  or  treated  water 
because  it  causes  cloudiness  resulting  in  an  unattractive 
water.  However,  the  major  reason  that  turbidity  is  undesira- 
ble is  because  it  causes  a  health  hazard  by: 

ERIC 


1.  Interfenng  with  disinfection  by  reducing  the  ability  of 
the  disinfectant  to  inactivate  or  kill  disease-causing 
organisms. 

2.  Exerting  a  chlorine  demand  which  makes  it  difficult  to 
maintain  a  residual  throughout  the  distribution  sys- 
tem. 

3.  Interfenng  with  the  bacteriological  examination  of  the 
water,  and 

4.  Not  satisfactorily  reducing  "tastes  and  odors"  and 
"asbestos  fibers." 

The  MCLs  for  turbidity  which  apply  to  surface  water  only 
are  shown  on  the  ooster  provided  with  this  manual  and  are: 

•  The  monthly  average  turbidity  MCL  may  not  exceed  1 
TU.  At  state  option  this  may  be  raised  to  5  1 U.  Some 
states  require  0.5  TU  where  there  is  a  major  hazard  of 
wastewater  (sewage)  contamination  of  the  water  sup- 
ply. 

•  Five  turbidity  units  based  on  an  average  for  two 
consecutive  days. 

The  5  TU  MCL  was  included  as  a  state  option  because 
there  are  certain  types  ^f  turbidity  that  do  not  interfere  with 
bacteriological  effectiveness  of  disinfection.  In  such  cases, 
the  state  may  authorize  the  5  TU  MCL  for  a  water  system  on 
a  case-by-case  basis. 

The  two-day-average  turbidity  limit  is  designed  to  protect 
against  the  presence  of  a  high  turbidity  during  certain 
periods,  such  as  periods  of  heavy  runoff,  when  the  adequa- 
cy of  the  treatment  is  particularly  critical  to  protect  the 
public. 

Daily  turbidity  sample  requirements  from  non-community 
systems  using  surface  water  can  be  relaxed  by  the  state  or 
local  health  agency  provided  certain  criteria  are  met. 

The  turbidity  standards  are  currently  being  reviewed  and 
revised  under  the  Surface  Wate''  Treatment  Rules  recently 
drafted.  These  are  discussed  in  Section  22.33,  "Turbidity 
Requirements  of  the  SWTR." 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  528. 

22.6E  What  are  organic  chemicals? 

22.6F  What  have  been  the  common  uses  of  trichloroethy- 
lene (TCE)? 

22.6G  What  is  the  MCL  for  turbidity'? 


525 


506  Water  Treatment 


22.63  Microbiological  Standards 

Bacteria,  viruses,  ?nd  other  organisms  have  long  been 
recognized  as  serious  contaminants  of  drinking  water.  Or- 
ganisms such  as  Giardia  cause  almost  immediate  gastroin- 
testinal illness  when  people  consume  them  in  water.  Even 
though  most  recent  attention  has  been  focused  on  the 
chemical  contaminants  of  drinking  water,  the  EPA  has 
continued  to  pay  special  attention  to  improving  treatment 
effectiveness  with  regard  to  microbiological  contaminants. 
Currently  only  total  coliforms  are  regulated.  EPA,  howevfir. 
Is  considering  creating  MCLs  for  Giardia,  viruses,  standard 
plate  count,  and  Legionella,  In  addition,  EPA  will  publish  final 
rules  for  filtration  in  1988  and  disinfection  by  June  1991. 
Filtration  and  disinfection  of  water  should  effectively  control 
the  threat  posed  by  microbiological  contaminants. 

22.630  Conform 

Cohform  bactena  are  an  indication  of  pos^iible  disease- 
producing  organisms  being  present  in  the  water  supply. 
MCLs  :.ave  been  established  to  indicate  when  a  coliform 
concentration  could  indicate  the  likely  presence  of  disease- 
causing  bactena  These  MCLs  have  been  established  for 
both  the  membrane  filter  method  and  the  multiple-tube 
fermentation  method  of  testing. 

22.631  Multiple  Tube  Fermentation  Method 

The  multiple-tube  fermentation  method  of  testing  for  coli- 
forms determines  the  presence  and  the  number  of  coliforms 
by  the  multiple-tube  dilution  method.  This  is  a  process 
whereby  1 0  mL  of  the  sample  Is  added  to  each  of  five  tubes. 
The  tubes  contain  a  culture  media  and  an  inverted  vial.  If  gas 
accumulates  in  the  inverted  vial,  it  indicates  presumptive 
evidence  of  cohform  organisms  in  that  portion  of  the  sample. 
Should  no  gas  form  in  the  vial,  that  portion  of  the  sample  is 
negative. 

For  a:i  systems,  regardless  of  the  number  of  samples 
taken  per  month,  conforms  must  not  be  present  in  more  than 
10  percent  of  the  portions  per  month.  For  systems  requirf  J 
to  take  fewer  than  20  samples  per  month,  not  more  th  an  one 
monthly  sample  can  have  three  or  more  portions  positive. 
For  systems  required  to  take  20  or  more  samples  per  month, 
not  more  than  five  percent  of  the  monthly  samples  can  have 
three  or  more  portions  positive.  For  water  systems  that 
regularly  take  1 0  or  fewer  samples  per  month,  ONE  positive 
sample  may  be  discarded  if: 

1  The  system  chlorinates  and  maintains  a  residual, 

2  The  system  takes  two  check  samples  on  consecutive 
days,  and 

3.  This  exclusion  has  NOTbeen  used  in  (he  previous  month. 

22.632  Membrane  Filter  Method 

This  method  provides  for  filtering  a  100  mL  water  sample 
through  a  thin,  porous,  cellulose  membrane  filter  under  a 
partial  vacuum  The  filter  is  placed  in  a  sterile  container  and 
incubated  in  contact  with  a  special  liquid  called  a  "culture 
medium"  which  the  bacteria  use  as  a  food  source.  Colonies 
of  bactena  then  grow  on  the  media  The  cohform  colonies 
are  visually  identified,  counted,  and  recorded  as  the  number 
of  coliform  colonies  per  100  mL  of  sample. 


The  coliform  MCLs  using  the  membrane  filter  method  are 
such  that  the  numbers  of  colonies  shall  not  exceed  any  of 
the  following- 

1  One  per  100  mL  as  the  anthmetic  mean  of  all  samples 
examined  per  rrionth, 

2.  Four  per  100  mL  in  more  than  one  sample  when  fewer 
than  20  samples  are  examined  per  month,  and 

3  Four  per  lOO  mL  in  more  than  five  percent  of  the  samples 
when  20  samples  or  more  are  examined  per  month. 


22.633  Chlorine  Residual  Substutution 

At  the  discretion  of  the  state  and  based  upon  a  review  of 
the  water  system,  chlorine  residual  testing  may  be  substitut- 
ed for  some  of  the  bacteriological  testing.  Chlorine  residual 
tebting  could  give  the  operator  a  quicker  indication  of  the 
condition  of  the  system.  However,  the  following  require- 
ments must  be  met: 

1  Samples  must  be  taken  at  points  which  are  representa- 
tive of  conditions  within  the  distnbution  system, 

2  Chlorine  residual  testing  can  replace  only  up  to  75 
percent  of  the  bacteriological  testing, 

3.  At  least  four  chlorine  residual  tests  must  be  taken  to 
substitute  for  one  bacteriological  sample, 

4  A  free  chlorine  residual  of  at  least  0.2  mg/L  must  be 
maintained  throughout  the  distribution  system, 

5  If  free  chlorine  residual  falls  below  0.2  mg/t  check 
samples  must  be  taken  for  bactenological  testing  and  a 
report  must  be  submitted  to  the  state  within  48  hours,  and 

6  Chlorine  residual  must  be  determined  daily. 

In  order  to  meet  the  total  trihalomethanes  (TTHM)  MCL, 
some  water  treatment  plants  practice  CHLORAMINATION.^ 
Chlora.Tiination  is  the  application  of  chlorine  and  ammorjia  to 
form  chloramines.  Experience  has  shown  that  satisfactory 
chlorine  residuals  and  bacteriological  test  results  can  be 
obtained  at  remote  locations  in  distribution  systems  pro- 
vided 

C  X  T  >  120  after  filtration 

where  C  is  the  chlorine  residual  in  mg/L,  and 

T  li:  the  chlorine  contact  time  in  minutes. 

For  example,  if  a  ciear  well  providos  a  minimum  contact  time 
of  120  minutes,  then  the  chlorine  residual  should  be  at  least 
one  mg/L  after  120  minutes. 


22.634  Draft  Coliform  Rule 

The  EPA  has  also  prepared  a  draft  coliform  rule  which 
was  published  in  November  of  1987.  The  Total  Coliform  Rule 
proposes  to  revise  the  MCL  for  total  coliform  and  estab- 
lishes a  nonenforceable  health  goal,  termed  maximum  con- 
tar  jnant  level  goal  of  zero.  The  Rule  also  proposes  changes 
in  monitoring  requirements,  analytical  methodology,  and 
required  responses  to  a  positive  coliform  test.  These  pro- 
posed changes  are  summarized  below. 


^  Chloramination  (KLOR-ah-min-NAY'Shun).    The  application  of  chlorine  and  ammonia  to  water  to  form  chloramines  for  the  purpose  of 


ERLC 


526 


Water  Quality  Regulations  507 


Monitoring  Frequency.  For  systems  which  service  3,300 
persons  or  fewer,  five  samples  per  month  are  reqjired. 
Fewer  samples  will  be  required  if  the  system  filters  and 
disinfects  surface  water  and  groundwater  For  systems 
which  service  more  than  3,300  persons,  the  sampling  fre- 
quency is  based  on  population.  The  population  size  categor- 
ies have  been  reduced  yet  the  minimum  number  of  samples 
required  has  not  changed  substantially  from  the  existing 
regulations. 

Analytical  Methodology.  The  proposed  MCL  for  coliform 
will  be  based  on  the  presence  or  absence  of  total  coliforms 
in  a  sample,  rather  than  on  estimates  of  coliform  density. 
The  total  coliform  analys^^s  must  be  conducted  in  accor- 
dance with  STANDARD  METHODS,^  Method  908,  "Multiple- 
Tube  Fermentation  Technique  for  Members  of  the  Coliform 
Group."  w  ih  a  standard  sample  volume  of  100  mL. 

Response  to  Positive  Coliform  Testing.  The  monthly  MCL 
for  systems  that  analyze  fewer  than  40  samples  per  month 
requires  that  no  more  than  one  sample  per  month  can  be 
coliform  positive.  For  water  systems  that  collect  more  than 
40  samples  per  month,  no  more  than  five  percent  of  the 
samples  collected  can  be  coliform  positive.  The  long-term 
MCL  for  systems  that  analyze  fewer  than  sixty  samples  per 
year  is  that  no  more  than  five  percent  of  the  most  recent  60 
samples  can  be  coliform  positive.  For  systems  with  at  least 
sixty  samples  per  year,  no  more  than  five  percent  of  all 
samples  in  the  most  recent  12-month  period  can  be  coliform 
positive. 

If  coliforms  are  detected  in  any  sample,  the  water  purvey- 
or must  collect  a  set  of  five  repeat  samples  on  the  same  day 
from  the  same  location.  If  coliforms  are  detected  in  a  repeat 
sample,  the  system  must  analyze  the  coliform  positive 
culture  medium  to  determine  if  fecal  coliforms  are  present.  If 
fecal  coliforms  are  present,  the  coliform  MCL  has  been 
violated  and  the  appropriate  health  agency  must  be  notified 
immediately.  If  the  MCL  has  not  been  violated,  another  set  of 
five  repeat  samples  must  be  collected  and  analyzed. 

22.635  Giardia 

The  protozoan  Giardia  lambha  is  presently  the  organism 
most  implicated  in  waterborne  disease  outbreaks  in  the 
United  States.  These  microscopic  creatures  are  found  main- 
ly in  mountain  streams.  Once  inside  the  body,  they  cause  a 
painful  and  disabling  illness.  The  infection  caused  by  Giardia 
s  called  Giardiasis.  The  symptoms  of  Giardiasis  are  usually 
severe  diarrhea,  gas,  cramps,  nausea,  vomiting,  and  fatigue. 

Giardia  and  viruses  have  been  added  to  the  traditional 
coliform  and  turbidity  indicators  of  microbiological  quality.  In 
this  case,  the  Recommended  Maximum  Contaminant  Levels 
(RMCLs)  are  zero  because  the  organisms  are  pathogens,  or 
indicators  of  pathogens,  and  should  not  be  present  in 
drinking  water. 

22.64  Radiological  Standards 

Radon,  radium,  and  uranium  are  three  radioactive  ele- 
ments sometimes  found  in  dnnking  water.  These  materials 
occur  naturally  in  the  ground  and  dissolve  into  groundwater 
supplies.  Because  these  radioactive  matenals  are  frequently 
occurring  potent  carcinogens,  EPA  will  regulate  radon  and 
strengthen  the  standard  for  radium  In  water  supplies  by 
June  1989. 


Radioactivity  is  the  only  contaminant  *or  which  standards 
•  ^.ve  been  set  that  has  been  shown  to  cause  cancer. 
However,  the  possible  exposure  to  radiation  in  drinking 
water  is  only  a  fraction  of  the  exposure  from  all  natural 
sources.  The  rr3in  source  of  radioactive  material  in  surface 
water  is  fallout  trom  nuclear  testing  Other  sources  could  be 
nuclear  power  plants,  nuclear  fuel  piocessing  plants  and 
uranium  mines.  Those  sources  are  monitored  constantly 
and  there  is  no  great  nsk  of  contamination,  barring  acci- 
dents. 

Alpha  and  radium  radioactivity  occur  naturally  in  parts  of 
the  West,  Midwest,  and  Northeast  in  groundwater.  Stan- 
dards for  those  types  of  radioactivity  and  for  man-made,  or 
beta  radiation  have  been  set  at  levels  of  safety  comparable 
to  other  contaminants. 

The  MCLs  for  radiological  contaminants  are  divided  into 
two  categories:  (1)  natural  radioactivity  which  results  from 
well  water  passing  through  deposits  of  naturally  occurring 
radioactive  materials;  and  (2)  man-made  radioactivity  such 
as  might  result  from  industrial  wastes,  hospitals  or  research 
laboratories.  Table  22.5  summarizes  the  MCLs  for  radioac- 
tivity. 


TABLE  22.5    MCLs  FOR  RADIOACTIVITY 


Maximum  Cciitaminant 


  Constituent  Level,  pCi/L^ 

Combined  Radium  226  and  5 
Radium  228 

Gross  Alpha  Activity  15 
(including  Radium  226  but 
excluding  Radium  and  Uranium) 

Tntium  20,000 

Strontium-90  8 

Gross  Beta  Particle  Activity  50 


^  pCi/L  PicoCune  per  Liter  A  picoCune  is  a  measure  of 
radioactivity  One  picoCune  of  radioactivity  is  equivalent  to 
0  037  nuclear  disintegrations  per  second 


Moniionng  for  natural  radioactivity  contamination  is  re- 
quired every  four  years  for  both  surface  water  and  ground- 
water community  systems  Routine  monitoring  procedures 
cO  follow  are. 

1  Test  for  gross  a'^^^i  activity,  if  gross  alpha  exceeds  5 
pCi/L.  then 

2  Test  for  radium  226,  if  radium  223  exceeds  3  pCi/L,  then 

3  Test  for  radium  228 

The  following  MCLs  apply  for  natural  radioactivity 

1  Gross  alpha  activity  15pCi/L,  and 

2  Radium  226  and  radium  228    5  pCi/L. 


*  STANDARD  METHODS  FOR  THE  EXAMiNATlON  OF  WATER  AND  WASTEWATER.  16thEdition,  1985.  Order  No.  10035.  Available  from 
Computer  Services,  American  Water  Works  Association,  6666  W.  Quincy  Avenue,  Denver,  Colorado  60235.  Pnce  to  members,  $72.00, 
nonmembers,  $90.00. 


ErJc  ;v  .527 


508  Water  Treatment 


QUESTIONS 

Write  your  answers  in  a  notebook  and  t*^en  compare  your 
answers  with  those  on  page  528. 

22.6H  EPA  is  considering  the  creation  of  microbiological 
standard  MCLs  for  what  factors? 

22.61  For  water  systems  that  regularly  take  10  or  fewer 
samples  per  month,  under  what  circumstances  may 
ONE  positive  sample  be  discarded? 

22.6J  The  MCLs  for  radiological  contaminants  are  divided 
Into  what  two  categories? 


22.7   SECONDARY  DRINKING  WATER  STANDARDS 

22.70  Enforcement  of  Regufations 

The  National  Secondary  Drinking  Water  Regulations  con- 
trol contaminants  in  drinking  water  that  primarily  affect  the 
aesthetic  qualities  relating  to  the  public  acceptance  of  drink- 
ing water.  At  considerably  higher  concentrations  of  these 
contaminants,  health  implications  may  also  exist  as  well  as 
aesthetic  degradation.  These  regulations  are  not  federally 
enforceable;  however,  some  states  have  passed  laws  re- 
quiring the  state  health  agency  to  enforce  the  regulations. 

22.71  Secondary  Maximum  Contaminant  Levels 

Secondary  Maximum  Contaminant  Levels  (SMCLs)  apply 
to  public  water  systems  and,  in  the  judgment  of  the  EPA 
Administrator,  are  necessary  to  protect  the  public  welfare  or 
for  public  acceptance  of  the  drinking  water.  The  SMCL 
means  the  maximum  permissible  level  of  a  contaminant 
which  is  delive  red  to  the  free-flowing  outlet  of  the  ultimate 
user  of  a  public  water  system.  Contaminants  added  to  the 
water  under  circumstances  controlled  by  the  user,  except 
those  resulting  from  corrosion  of  piping  and  plumbing 
caused  by  water  quality,  are  excluded  by  definition.  Current- 
ly there  are  13  secondary  standards  (see  Table  22.6). 


CONTAMINANT 


TABLE  22.6   SECONDARY  DRINKING  WATER  STANDARDS 

MCL  EFFECT 


Chloride 

Color 

Copper 
Corrosivity 

Fluoride 

Foaming  Agents 
Iron 

Manganese 
Odor 

PH 

Sulfate 

Total  Dissolved  Solids 
Zinc 


250  mg/L 


15  Color 
Units 

1  mg/L 

Non- 

Corrosive 


2  mg/L 

0.5  mg/L 
0.3  mg/L 
0.05  mg/L 

3  Threshold 
Odor  Number^ 

6.5  to  8.5 

250  mg/L 

500  mg/L 

5  mg/L 


taste  and  corrosion  of  water 
pipes 

aesthetic 


taste  and  staining  of  porcelain 

aesthetic  ar<d  health  related  as 
corrosive  water  can  leach  pipe 
materials  into  drinking  water 

dental  fluorosis  (a  brownish 
discoloration  of  the  teeth) 

aesthetic 

taste  and  staining 
taste  and  staining 
aesthetic 

corrosion  control 

taste  and  laxative  effects 

taste  and  possible  relationship 
between  low  hardness  and  heart 
disease 

taste 


«  Threshold  Odor  Number  (TON),  The  greatest  dilution  of  a  sample  with  odor-free  water  that  still  yields  a  jus*'detectable  odor. 


ERLC 


528 


Water  Quality  Regulations  509 


States  may  establish  higher  or  lower  levels  depending  on 
local  conditions,  providing  that  public  health  and  welfare  are 
adequately  protected. 


Aesthetic  qualities  are  important  factors  in  public  accep- 
tance and  confidence  in  a  public  water  system.  States  are 
encouraged  to  implement  SMCLs  so  that  the  public  will  not 
be  driven  to  obtain  drinking  water  from  potentially  lower 
quality,  higher  risk  sources.  Many  states  have  chosen  to 
enforce  both  Primary  and  Secondary  MCLs  tc  assure  that 
the  consumer  is  provided  with  the  best  quality  water  avail- 
able. 

22.72  Monitoring 

Collect  samples  for  secondary  contaminants  at  a  free- 
flowing  outlet  of  water  being  delivered  to  the  consumer. 
Monitor  contaminants  in  these  regulations  at  intervals  no 
Ies5>  frequent  than  the  monitoring  performed  for  inorganic 
chemical  contaminants  (every  three  years)  listed  for  the 
Interim  Primary  Drinking  Water  Regulation  or  applicable  to 
community  water  systems.  Collect  monthly  distribution  sys- 
tem physical  water  quality  monitoring  samples  for  color  and 
odors.  More  frequent  monitoring  would  be  appropriate  for 
specific  contaminants  such  as  pH,  color,  odor  or  others 
under  certain  circumstances  as  directed  by  the  state. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  528. 

22.7A  Under  what  conditions  are  secondary  drinking  water 
regulations  enforceable? 

22.7B  Liot  the  secondary  drinking  water  contaminants. 

22.7C  How  frequently  should  the  contaminants  in  the  sec- 
ondary regulations  be  monitored? 


ERIC 


22.73  Secondary  Contaminants 
22.730  Chloride 

The  MCL  for  chloride  is  250  mg/L. 

UNDESIRABLE  EFFECTS 

1  Objectionable  salty  taste  tn  water. 

2.  Corrosion  of  the  pipes  in  hot  water  and  other  systems. 

STUDIES  ON  THE  MINERALIZATION  OF  WATER  INDI- 
CATE THE  FOLLOV'nNG 

1.  Major  taste  effects  are  producted  by  anions  (where  TDS 
was  studied). 

2.  Chloride  produces  a  taste  effect  somewhere  between  the 
milder  sulfate  and  the  stronger  carbonate. 

3  Laxative  effects  are  caused  by  high  levels  of  sodium  and 
magnesium  sulfate. 

CORROSION  EFFECT 

1  Studies  indicate  that  corrosion  depends  on  concentration 
of  TDS  (TDS  may  contain  50  percent  chloride  ions). 

2  Domestic  plumbing,  water  heaters  and  municipal  water- 
works equipment  will  deteriorate  when  high  concentra- 
tions of  chloride  ions  are  present. 

EXAMPLE: 

Where  the  TDS  =  200  mg/L  (Chloride  =  100  mg/L),  water 
heater  life  will  range  from  1 0  to  1 3  years.  Water  heater  life 
declines  uniformly  as  a  function  cf  TDS  —  1  year  short- 
ened life  per  200  mg/L  additional  TDS. 


22.731  Color 


T  ie  MCL  for  color  is  15  color  units.  The  level  of  this  water 
quality  indicator  is  not  known  to  be  a  measure  of  the  safety 
of  water  However,  high  color  content  may  indicate: 


1  High  organic  chemical  contamination. 
2.  Inadequate  treatment,  and 

3  High  disinfectant  demand  and  the  potential  for  production 
of  excess  amounts  of  disinfectant  by-products. 

Color  may  be  caused  by: 

1.  Natural  color-causing  solids  such  as  aromatic,  polyhy- 
droxy,  methoxy  and  carboxylic  acids, 

2.  Fluvic  and  humic  acid  fractions,  and 

3.  Presence  of  metals  such  as  copper,  iron,  and  manga- 
nese. 


tr  r\  ^ 


510  Water  Treatment 


Rapid  changes  in  color  levels  may  provoke  more  citizen 
complaints  than  relatively  high,  constant  color  levels. 

22J32  Copper 

The  MCL  for  copper  is  1.0  mg/L.  Copper  ;n  drinking  v\/ater 
usually  results  from  the  reaction  of  aggressive  water  on 
copper  plumbing.  Treatment  of  surface  water  in  storage 
reservoirs  to  control  algae  may  also  cause  high  levels  of 
copper 

UNDESIRABLE  EFFECTS 

1  Imparts  some  taste  to  water  (astringent  taste) 

2  Blue  or  blue-green  staining  of  porcelain  at  low  levels  (0  5 
mg/L  in  soft  waters).  At  higher  levels,  4  mg/L  causes 
staining  of  clothing  and  blond  hair 

3.  Larger  doses  will  produce  Wilson's  Disease. 

4.  Prolonged  doses  result  in  liver  damage. 

5  Concentrations  greater  than  one  mg/L  can  produce  in- 
soluble green  curds  when  reacting  with  soap 

DIETARY  REQUIREMENTS 

1.  Adults  require  2.0  mg  daily. 

2  Children  of  preschool  age  require  0.1  mg  for  normal 
growth. 

3.  Water  provides  an  additional  supplement  to  ensure  an 
adequate  intake. 

4.  Excess  copper  intake  or  inability  to  metabolize  copper  is 
called  Wilson's  Disease  and  can  be  arrested  by  the  use  of 
CHELATING  AGENTS.^ 

22J33  Corrosivity 

A  drinking  water  should  be  non-corrosive.  However,  a 
significant  level  of  corrosion  is  very  difficult  to  define  and 
explain  The  corrosivity  of  water  depends  on  the  complex 
characteristics  of  water  which  are  related  to  pH,  alkalinity, 
dissolved  oxygen,  and  total  dissolved  solids  plus  other 
factors.  A  number  of  different  measurements  have  been 
proposed  to  determine  the  degree  of  corrosivity  of  watei, 
but  none  is  completely  satisfactory  (see  Chapter  8,  Corro- 
Gion  Control). 

Al  ^ERSE  EFFECTS 

1.  Aifects  the  aesthetic  quality  (turbid  waters  promote  de- 
posits under  stagnant  conditions  encouraging  bacteri- 
ological growths),  and  causes  taste  and  odor  problems  m 
the  water  supply. 

2.  Serious  economic  impact  (loss  of  system  piping,  water 
loss  from  deteriorating  distribution  system). 

3  Health  implications  (toxic  corrosion  products  such  as 
lead,  cadmium  and  copper). 


22J34  Fluoride 

Fluoride  as  recently  been  added  to  the  list  of  secondary 
drinking  water  standards.  Fluoride  produces  two  effects, 
depending  on  its  concentration.  At  levels  of  6-8  mg/L 
fluoride  may  cause  skeletal  fluorosis  which  is  a  brittling  of 
the  bones  and  stiffening  of  the  joints.  For  this  reason  fluoride 
has  been  aJded  to  the  list  of  primary  standards  (those  that 
have  health  effects). 

At  levels  of  2  mg/L  and  greater  fluoride  may  cause  dental 
fluorosis  which  Is  discoloration  and  mottling  of  the  teeth, 
especially  in  children.  EPA  has  recently  reclassified  dental 
fluorosis  as  a  cosmetic  effect,  raised  the  primary  drinking 
water  standard  from  1 ,4-2  mg/L  to  4  mg/L,  and  established  a 
secondary  standard  of  2  mg/L  for  fluoride. 

22. 735  Foaming  Agents 

The  MCI.  for  foaming  agents  is  0  5  mg/L 
UNDESIRABLE  EFFECTS 

1  Causes  frothing  and  foaming  which  are  associated  with 
contamination  (greater  than  1.0  mg/L). 

2.  Imparts  an  unpleasant  taste  (oily,  fishy,  perfume-like) 
(less  than  1.0  mg/L). 

INFORMATION  ITEMS 

1.  Because  no  convenient  foamability  test  exists  and  be- 
cause SURFACTANTS'"  are  one  major  class  of  sub- 
stances that  cause  foaming,  this  property  is  determined 
indirectly  by  measuring  the  anionic  surfactant  concentra- 
tion in  the  water  {MBAS).^ 

2  Surfactants  are  synthetic  organic  chemicals  and  are  the 
principal  ingredient  of  modern  household  detergents. 

3  The  requirement  for  biodegradability  led  to  the  wide- 
spread use  of  Linear  Alkyl  Benzene  Sulfonate  (LAS),  an 
anionic  surfactant. 

4  Concentrations  of  anionic  surfactants  found  in  drinkhig 
waters  range  from  0  to  2  6  mg/L  in  well  supplies  and  0  to 
5  mg/L  in  surface  water  supplies. 

5  LAS  are  essentially  odorless.  The  odor  and  taste  charac- 
teristics are  likely  to  arise  from  the  degradation  of  waste 
products  rather  than  the  detergents. 

6  If  water  contains  an  average  concentration  of  10  mg/L 
surfactants,  the  water  is  likely  to  be  entirely  of 
wastewater  origin. 

7  From  a  toxicological  standpoint  an  MCL  of  0.5  mg/L, 
assuming  a  daily  adult  human  intake  of  2  liters,  would 
give  a  safety  factor  of  15,000. 


6  Chelating  Agent  (key-LAY  ting)    A  chemical  used  to  prevent  the  precipitation  of  metals  (such  as  copper) 
Surfactant  (sir  FAC-tent)    Abbreviation  for  surface-active  agent  The  active  agent  m  detergent  that  possesses  a  high  cleaning  ability 
MBAS    Methylene-Blue-Active  Substances.  These  substances  are  used  m  surfactants  or  detergents. 

erIc  ^  ■  ^30 


Water  Quality  Regulations  511 


22. 736  Iron  and  ^/Isnganese 

1.  Iron  and  manganese  a'e  frequently  found  together  in 
natural  waters  and  pro  Jtjce  similar  adverse  environmen- 
tal effects  and  color  problems.  Excessive  amounts  of  iron 
and  manganese  are  usually  found  in  groundwater  and  in 
surface  water  contaminated  by  industrial  waste  dis- 
charges. 

2.  Prior  to  1962.  both  were  covered  by  a  single  recommend- 
ed limit. 

3.  In  1962,  the  U.S  Public  Health  Service  recommended 
separate  limits  for  both  iron  and  manganese  to  reflect 
more  accurately  the  levels  at  which  adverse  effects  occur 
for  each. 

4.  Both  are  highly  objectionable  in  large  amounts  in  water 
supplies  for  either  domestic  or  industrial  use. 

5.  Both  impart  color  to  laundered  goods  and  plumbing 
fixtu''es 

6.  Taste  thresholds  in  drinking  water  are  considerably  high- 
er than  the  levels  which  produce  staining  effects. 

7.  Both  are  part  of  our  daily  nutritional  requirements,  but 
these  requirements  are  not  met  by  the  consumption  of 
drinking  water. 

22.737  Iron 

The  MCL  for  iron  is  0.3  mg/L. 
UNDESIRABLE  EFFECTS 

1  At  levels  greater  than  0.05  mg/L  some  color  may  develop, 
staining  of  fixtures  may  occur,  and  precipitates  may  form 

2.  The  magnitude  of  the  staining  effect  is  directly  propor- 
tional to  the  concentration. 

3.  Depending  on  the  sensitivity  of  taste  perception,  a  bitter, 
astringent  taste  can  be  detected  from  0.1  mg/L  to  1.0 
mg/L. 

4.  Precipitates  that  are  formed  create  not  only  color  prob- 
lems but  also  lead  to  bacterial  growth  of  slimes  and  of  the 
iron-loving  bacteria,  CRENOTHRIX,  in  wells  and  distribu- 
tion piping. 

NUTRITIONAL  REQUIREMENTS 

1.  Daily  requirement  is  one  to  two  mg.  but  intake  of  larger 
quantities  is  required  as  a  result  of  poor  absorption. 

2.  The  limited  amount  of  iron  permitted  m  water  (because  of 
objectionable  taste  or  staining  effects)  constitutes  only  a 
small  fraction  of  the  amount  normally  consumed  and 
does  not  have  toxicologic  (poisonous)  significance. 

22. 738  Manganese 

The  MCL  for  manganese  is  0.05  mg/L 
UNDESIRABLE  EFFECTS 

1.  A  concentration  of  mo'-e  than  0.02  mg/L  may  cause 
buildup  of  coatings  in  distribution  piping. 

2.  If  these  coatings  slough  off.  they  can  cai*"^  brown 
blotches  in  laundry  items  and  black  precipitates. 

3.  Manganese  imparts  a  taste  to  water  above  0.15  mg/L. 


4  The  application  of  chlorine  increases  the  likelihood  of 
precipitation  of  manganese  at  low  levels 

5  Unless  the  precipitate  is  removed,  precipitates  reaching 
pipelines  will  promote  bactenal  growth 

TOXIC  EFFECTS 

1.  Toxic  effects  are  reported  as  a  result  of  inhalation  of 
manganese  dust  or  fumes. 

2  Liver  cirrhosis  has  arisen  in  controlled  feeding  of  rats. 


3  Neurological  effects  have  been  suggested,  however, 
these  effects  have  not  been  concretely  determined. 

NUTRITIONAL  REQUIREMENTS 

1.  Daily  intake  of  manganese  from  a  normal  diet  is  about  10 

mg. 

2.  Manganese  is  essential  for  proper  nutrition. 

3.  Diets  deficient  in  manganese  will  interfere  with  growth, 
blood  and  bone  formation,  and  reproduction. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  528. 

22.7D  Why  is  chloride  a  secondary  contaminant? 

22.7E  How  does  copper  usually  get  into  drinking  water? 

22.7F  Why  are  corrosive  waters  undesirable  as  drinking 
water? 

22.7G  What  is  the  impact  of  chlorine  on  manganese? 
22739  Odor 

The  MCL  for  odor  is  a  THRESHOLD  ODOR  NUMBER 
(TON)^oi  3.  Important  facts  to  remember  when  dealing  with 
odors  include: 

1.  Taste  and  odor  go  hand-in-hand 

2  Absence  of  taste  and  odor  helps  to  maintain  the  consum- 
ers confidence  in  the  quality  of  their  water,  even  though  it 
doesn't  guarantee  that  the  water  is  safe. 

3.  Research  indicates  that  there  are  only  four  true  taste 
sensations* 

a.  Sour, 

b.  Sweet. 

c.  Salty,  and 

d.  Bitter. 


9  Threshold  Odor  Number  (TON).   The  greatest  dtluttor)  of  a  sample  with  odor-free  water  that  still  yields  a  just  detectable  odor. 

ERIC  531 


512  Water  Treatment 


4  All  other  sensations  ascribed  to  the  sense  of  taste  are 
actually  odors  even  though  the  sensation  is  not  noticed 
until  the  material  is  taken  into  the  mouth. 

5  Odor  tests  are  less  fatiguing  t04)eople  testing  for  tastes 
and  odors  than  taste  tests. 

6,  Taste  and  odor  tests  are  useful: 

a.  As  a  check  on  the  quality  of  ra^^°  and  treated  water, 
and 

b.  To  help  control  odor  throughout  the  plant. 

7.  Odor  IS  a  useful  test' 

a.  For  determining  the  effectiveness  of  different  kinds  of 
treatment,  and 

b.  As  a  means  for  tracing  the  source  of  contaminants 

22J40  pH 

The  MCL  for  pH  is  defined  as  pH  values  beyond  the 
acceptable  range  from  6.5  to  8.5  A  wide  range  of  pH  values 
in  drinking  water  can  be  tolerated  by  consumers. 

UNDESIRABLE  EFFECTS 

1  When  the  pH  increases,  the  disinfection  activity  of  chlo- 
rine falls  significantly. 

2.  High  pH  may  cause  increased  Production  of  chloroform 
and  other  trihalomethanes  dui.ng  chlorination. 

3  Both  excessively  high  and  low  pHs  may  cause  increased 
corrosivity  which  can  in  turn  crpate  taste  problems, 
staining  problems,  and  significant  health  hazards. 

4.  Metallic  piping  in  contact  with  low  pH  water  will  impart  a 
metallic  taste. 

5.  If  the  piping  is  iron  or  copper,  high  pH  will  cause  oxide 
and  carbonate  compounds  to  be  deposited  leaving  red  or 
green  stains 

6.  At  a  high  pH  drinking  water  acquires  a  bitter  taste. 

7.  The  high  degree  of  mineralization  often  associated  with 
basic  waters  results  in  encrustation  of  water  pipes  and 
water-using  appliances 

22.741  Sulfate 

The  MCL  for  sulfate  is  250  mg/L 
UNDESIRABLE  EFFECTS  AT  HIGH  LEVELS 

1.  Tends  to  form  hard  scales  in  boilers  and  heat  exchang- 
ers. 

2.  Causes  taste  effects. 

3.  Causes  laxative  effect.  This  effect  is  commonly  noted  by 
newuomers  or  casual  or  intermittent  users  of  water  high 
in  sulfate.  Water  containing  more  than  750  mg/L  of 
sulfate  usually  produces  the  laxative  effect  while  water 
with  less  than  600  mg/L  sulfate  usually  does  not  An 
individual  can  become  acclimated  to  sulfate  in  drinking 
water. 

4.  Sodium  sulfate  and  magnesium  sulfate  are  more  active 
as  laxatives,  whereas  calcium  sulfate  is  less  active. 

5.  When  the  magnesium  content  is  200  mg//.,  the  most 
sensitive  person  will  feel  the  laxative  effect,  however, 
magnesium  sulfate  levels  between  500  mg/L  and  1000 
mg/L  will  induce  diarrhea  in  most  i.idividuals. 


6  Tastes  may  sometimes  be  detected  at  200  mg/L  of 
su'fate,  but  generally  are  detected  in  the  range  of  300  to 
400  mg/L 

22.742  Total  Dissolved  Solids  (TDS) 

The  MCL  for  total  dissolved  solids  is  500  mg/L. 
UNDESIRABLE  EFFECTS 

1  TDS  imparts  adverse  taste  effects  at  greater  than  500 
mg/L 

2  Highly  mineralized  water  influences  the  deterioration  of 
distMDution  systems  as  well  as  domestic  plumbing  and 
appha  ices  (the  life  of  a  hot  water  heater  will  decrease 
one  year  with  each  additional  200  mg/i  of  TDS  above  a 
typijal  200  mg/L  value). 

3.  Mineralization  can  also  cause  precipitates  to  form  in 
boilers  ard  other  heating  units,  sludge  in  freezing  proc- 
esses, rings  on  utensils  and  precipitates  in  food  being 
cooked. 

4.  There  may  be  a  great  difference  between  a  detectable 
concentration  and  an  objectionable  concentration  of  the 
neutral  salts.  Many  people  can  become  acclimated  to 
high  levels. 

5-  Studies  show  that  the  temperature  of  mineralized  waters 
influences  their  acceptability  to  the  public. 

22.743  Zinc 

The  MCL  for  zinc  is  5  mg/L. 
UNDESIRABLE  EFFECTS 

1  -  High  concentrations  of  zinc  produce  adverse  physiologi- 

cal effects. 

2  Zinc  imparts  a.  bitter,  astringent  taste  whici  t  is  distinguish- 
able at  4  mg/L  Also  at  4  mg/L  a  metallic  taste  will  exist 

3  Zinc  will  cause  a  milky  appearance  in  water  at  30  mg/L. 
4.  Zinc  may  increase  lead  and  cadmium  concentrations. 

5  The  activity  of  several  enzymes  is  dependent  on  zinc. 

6.  Cadmium  and  lead  are  common  contaminants  of  zinc 
used  in  galvanizing  steel  pipe.  Even  if  the  MCL  of  five 
mg/L  of  zinc  were  dissolved  from  galvanized  water  pipe, 
to  produce  five  mg/L,  the  cadmium  dissolved  would  be 
less  than  O.Ol  mg/L  and  the  lead  dissolved  would  be  less 
than  the  0.05  mg/L  MCL. 


^^IV/)en  testing  raw  water,  be  sure  there  are  no  pathogens  or  toxic  chemicals  present, 

ERIC  . 


Water  Quality  Regulations  513 


PHYSIOLOGICAL  EFFECTS 

1  A  concentration  of  30  mg/L  can  cause  nausea  and 
fainting. 

2  Zinc  salts  act  as  gastrointestinal  irritants.  This  symptom 
of  illness  IS  acute  and  transitory. 

3  The  vomit;ng  concentration  range  is  675  to  2,280  mg/L 

4  A  wide  margin  of  safety  exists  between  normal  food 
intake  and  concentrations  in  water  high  enough  to  cause 
oral  toxicity 

DIETARY  REQUIREMENTS 

1.  The  daily  requirement  for  preschool  children  is  0  3  mg 
Zn/kg  of  weight. 

2.  Total  zinc  in  an  adult  human  body  averages  two  grams. 

3.  Zinc  most  likely  concentrates  in  the  retina  of  the  eye  and 
in  the  prostate. 

4.  Zinc  deficiency  in  animals  leads  to  growth  retardation. 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  529. 

22.7H  Whdt  are  the  undesirable  effects  of  abnormal  pH 
values? 

22.71   Why  are  high  levels  of  sulfate  undesirable  in  drinking 
water? 

22.7J  Why  are  high  levels  of  zinc  undesirable  in  drinkin{j 
water? 


22.3   SAMPLING  PROCEDURES 

22.80  Safe  Drinking  Water  Regulations 

The  Safe  Drinking  Water  Act  and  accompanying  regula- 
tions require  that  you  must  take  the  following  actions  to 
comply: 

1.  Sampling, 

2.  Testing, 

3.  Recordkeeping,  and 

4.  Reporting. 

ERLC 


Understanding  and  implementing  each  of  these  steps  will 
help  ensure  the  success  of  your  operation. 

22.81  Initial  Sampling 

"Initial  sampling"  refers  to  the  very  first  sampling  you  do 
under  the  SDWA  for  each  of  the  applicable  contaminant 
categories  When  you  start  and  when  you  complete  this 
sampling  depends  on: 

1.  The  type  of  contaminant  being  monitored, 

2.  Whether  the  system  is  a  community  or  non-community 
water  system,  and 

3.  Whether  the  water  source  is  a  surface  or  groundwater 
supply. 

The  poster  inside  the  back  cover  of  this  manual  outlines 
the  Interim  Primary  Drinking  Water  Standards  and  summa- 
rizes the  initial  sampling  program  for  each  contaminant 
category  (also  see  Table  22.7  for  required  sampling  pro- 
gram). In  column  7  in  the  poster  and  column  5  in  Table  22.7 
as  well  as  in  other  places,  several  state  options  are  listed. 
You  should  be  familiar  with  the  requirements  of  your  particu- 
lar state. 

22.82  Routine  Sampling 

,  ,outine  sampling  refers  to  sampling  repeated  on  a  regular 
basis.  Table  22.7  and  column  5  on  the  poster  summarize  the 
routine  sampling  requirements  for  each  contaminant  cate- 
gory. 


22.83  Check  Sampling 

Whenever  an  initial  or  routine  sample  analysis  indicates 
that  an  MCL  has  been  exceeded,  check  sampling  is  required 
to  confirm  the  routine  sampling  results.  Check  sampling  is  in 
addition  to  the  routine  sampling  program.  Although  check 
sampling  cannot  be  scheduled  in  advance,  there  are  specific 
check  sampling  procedures  to  follow.  The  number  of  sam- 
ples, sampling  points,  and  frequency  of  sampling  vary 
according  to  the  particular  contaminant.  For  example,  ♦he 
regulations  specify  that  wherever  a  coliform  bacteria  check 
sample  is  required,  the  location  from  which  the  sample  was 
taken  cannot  be  eliminated  from  future  routine  sampling 
without  prior  state  approval. 

22.84  Sampling  Points 

Some  of  the  samples  required  to  determine  compliance 
with  the  primary  regulations  can  be  taken  from  the  routine 
sampling  points.  By  coordinating  the  present  sampling 
points  with  the  sampling  program  required  by  the  regula- 
tions, additional  monitoring  costs  can  be  minimized.  Table 
22.7  summarizes  what,  where  and  how  often  you  need  to 
sample  for  both  community  and  non-community  water  sys- 
tems. The  number  of  sampling  points  required  will  depend 
on  the  specific  size  of  the  population  served  and  layout  of 
each  water  system. 

As  noted  in  Table  22.7,  samples  for  turbidity  must  be 
taken  at  the  points  where  water  enters  the  distribution 
system  and  samples  collected  for  coliform  bacteria,  inorgan- 
ics, organics  and  radiochemicals  must  be  taken  from  the 
consumers'  faucets  at  representative  points  within  the  distri- 
bution system. 


514  Water  Treatment 


TABLE  22.7   REQUIRED  SAMPLING 


WhatTests^  WhalTests^ 
(Community  (Non- 
Systom)  Commun'»y 
System) 


Where 
Samples  Taken 


HowOften^ 
(Community  System) 


How  Often^ 
(Non-Community  System) 


Inorganics 


Organics 


Turbidfty 


Coltform 
Bacteria 


Inorganics  (at 
state  option) 


Organics  (at 
state  option) 


Turbidity 


Coliform 
Bacteria 


At  the 

Systems  using  surface  water  EVERY 

consumer's 

YEAR 

IdUCcl 

Systems  using  groundwater  only  EVERY 

THREE  YEARS 

At  the 

Systems  using  surface  water.  EVERY 

consumer's 

THREE  YEARS 

faucet^ 

Systems  using  groundwater  only  STA  FE 

OPTION 

At  the  point(s) 

Systems  using  surface  water.  DAILY 

whrre  water 

Systems  using  groundwater  only:  STATE 

enters  the 

OPTION 

distribution 

system 

At  the 

Depends  on  number  of  people  served  by 

consumer's 

the  water  system  (see  Appendix  at  end  of 

faucet'' 

chapter) 

Radiochemicals  Radiochemicals 
(Natural)  (Natural) —  (at 

state  option) 

Radiochemicals  Radiochemicals 
(Man-made)       (Man-made)  ~ 
(at  state  option) 


At  the 

consumer's 
faucet'' 

At  the 

consumer's 
faucet'' 


Systems  using  surface  water.  EVERY 
FOUR  YE  ^rs 

System:  oing  groundwater  o  ^ly.  EVERY 
FOUR  YtfARS 

Systems  using  surface  water  servinc 
populations  greater  than  100,000:  EVERY 
FOUR  YEARS 

All  other  systems-  STATE  OPTION 


All  Systems  STATE  OPTION 


All  systems.  STATE  OPTION 


Systems  using  surface  or 
su'-^ace  and  groundwater: 
DAiLY 

Systems  using  groundwater 
only:  STATF  OPTION 

All  systems:  ONE  PER 
QUARTER  (for  each  quarter 
water  is  served  to  public) 

All  systems.  STATE  OPTION 


All  systems.  STATE  OPTION 


^  This  information  is  summarized  or"  the  poster  inside  the  back  cover 

"  The  faucets  selected  must  be  representative  of  conditions  within  the  distribution  system. 


At  the  very  minimum,  a  small  svstem  (with  population  of  25 
to  1000)  must  sample  for  turbidity  and  coliform  bacteria  and 
also  must  have  two  sampling  points. 

1.  One  where  the  water  enters  the  distribution  system,  and 

2  One  at  a  consumer  faucet  at  a  representative  point  in  the 
distribution  system. 

QUESTIONS 

Write  your  answers  In  a  notebook  and  then  compare  your 
answers  with  those  on  page  529. 


22.8A  What  do  the  words  "Initial  Sampling'  mean'? 
22.88  What  is  ''outine  samplinn'? 
22.80  What  is  checK  sampling ' 

22.8D  What  are  the  minimum  sampling  requiremen'ib  for  a 
small  system  with  a  population  of  100  people*? 

er|c  ^^'^ 


22.85  Sampling  Point  Selection 

The  two  major  considerations  in  determining  the  number 
and  location  of  sampling  points  are  that  they  should  be; 

1   Representative  of  each  different  surface  water  source 
entering  the  system,  and 

2.  Representative  of  conditions  within  the  system  such  as 
deadends,  loops,  storage  facilities  and  pressi're  zones. 


Water  Quality  Regulations  515 


22*86  Sampling  Schedule 

A  sampling  schedule  should  be  prepared  which  indicates 
al!  of  the  samples  that  will  be  collected  during  a  yearly 
period  The  schedule  should  include  the  following  informa- 
fon 

1  Sampling  frequency, 

2.  Sampling  point  designation, 

3  Location  (address), 

4.  Type  of  test, 

5.  Sample  volume,  and 

6  Special  handling  instructions. 

This  schedule  should  be  reviewed  with  your  state  he^^lth 
department  to  determine  adequacy  to  meet  the  SDWA 
regulations 

22*87  Sampling  Route 

After  selection  of  the  sampling  points  and  preparation  of 
the  sampling  schedule,  the  next  step  is  to  select  a  route. 
Arrange  your  route  so  that  samples  that  must  be  analzyed 
immediately  are  not  delayed  while  other  sampling  is  done. 
Field  data  forms  must  be  completed  by  the  person  doing  the 
sampling  and  submitted  to  the  laboratory  with  the  samples. 


22.88  Sample  Collection 

Good  sampling  techniques  are  the  key  to  a  meaningful 
and  useful  sampling  program.  The  following  eight  steps  are 
nece^jary  to  the  collection  of  an  acceptable  sample: 


1  Obtain  a  sample  that  is  truly  representative  of  tne  existing 
condition, 

2  Flush  the  line  before  sample  collection, 

3  Fill  the  sample  bottle  without  leaving  any  air  pocket, 
4.  Analyze  residual  chlorine  when  the  sample  is  taken: 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  529. 

22.8E  List  the  information  that  should  be  included  in  a 
sampling  schedule. 

22.8F  List  the  elements  necessary  to  the  collectiori  of  an 
acceptable  sample. 


22.9   REPORTING  PROCEDURES 

The  primary  purpose  of  the  SDWA  is  to  protect  the 
public's  health  There  are  two  genera!  categories  of  report- 
ing called  for  by  the  Act: 

1  Reporting  to  the  public  (public  notification),  and 

2  Reporting  to  the  state 

There  are  three  types  of  reports  that  must  be  sent  to  the 
state: 

1.  Routine  sampling  reports, 

2.  Check  sample  imports,  and 

3.  Violation  reports 

Tables  22.9  through  22.21  outline  reporting  procedures 
for  various  contaminants. 


5  Handle  and  store  the  sample  so  that  it  does  not  become 
contaminated  before  it  reaches  the  laboratory, 

6.  Use  preservation  techniques.  These  preservation  meth- 
ods are  generally. 

a.  pH  control,  and 

b.  Refrigeration: 


22.10   NOTIFICATION  FOR  COMMUNITY  SYSTEMS 

In  general,  public  notification  for  community  systems  is 
only  required  in  the  circumstances  shown  in  Table  22.8. 


7  Keep  accurate  records  of  every  sample  collected  includ- 
ing. 

a  Date  and  time  sampled, 

b.  Location  sampled, 

c.  Name  of  sample  collected, 

d.  Bottle  number, 

e.  Type  of  sample,  and 

f  Name  of  person  collecting  sample.  Any  person  collect- 
ing samples  should  be  required  to  complete  a  form 
providing  the  above  information  at  the  time  of  sample 
collection.  This  form  should  be  supplied  by  the  labora- 
tory: and 

8.  Keep  the  time  between  the  collection  of  the  sample  and 
analysis  as  short  as  possible. 


ERLC 


TABLE  22.8    PUBLIC  NOTIFICATION 


Type  of  Violation 


Required  Notification 
Mail  Newspaper  Broadcast 


Violation  of  Primary  MCL 

Failure  to  comply  with 
testing  procedure 

^'ariance  or  exception 
granted 

Monitoring  failure 

Compliance  schedule  not 
followed 


53 


0 


516  Water  Treatment 


Currently,  public  notification  of  violations  of  the  drinking 
water  regulations  is  cumbersome,  but  the  1986  Amend- 
ments to  the  Safe  Drinking  Water  Act  (SDWA)  provide 
greater  flexibility.  The  EPA  must  amend  its  existing  notifica- 
tion regulations  within  18  months  of  enactment  and  must 


specify  ihe  types  of  notice  to  be  used  to  provide  information 
to  consumers  as  promptly  and  effectively  as  possible,  taking 
into  account  both  the  seriousness  of  any  potential  adverse 
health  effects  and  the  likelihood  of  reaching  all  affected 
people. 


TABLE  22.9   REPORTING  PROCEDURES 
INORGANIC  CHEMICALS  (EXCEPT  NITRATE)  AND  ORGANIC  CHEMICALS 


Take  Samples 


If  no  MCL  IS  exceeded 


If  one  or  more  MCLs  are  exceeded 


Routine 

reporting 

required 


Report  this  to 
the  state  withm 
7  days 


AND 


Take  three  additional  (check) 
samples  at  same  sampling 
point  Within  one  monlh  Then 
determine  the  average  value  of 
the  original  and  three  check 
samples  * 


If  a^  age  value  does 
not  exceed  the  MCL 


Routine 

reporting 

required 


If  average  value 
exceeds  the  MCL 

Report  this  to  the 
state  within  48 
hours 

AND 

Noffy  the 
public 


AND 


Monitor  at  the  frequency  c  ^signated  by 
the  state,  continuing  until    a  MCL  has 
not  been  exceeded  in  two  successive 
samples  or  until  a  monitoring  schedule  is 
set  up  as  a  condition  to  a  vanance, 
exemption  or  enforcement  action. 


Average  value  = 

TOTAL  of  Original  Sample  -f  3  check  samples 
4~ 


ERLC 


536 


Water  Quality  Regulations  517 


TABLE  22.10   REPORTING  PROCEDURES  —  NITRATE 


Take  Sample 

 r  


If  the  MCL 

IS  not  exceedea 


If  the  MCL 
IS  exceeded 


Routine 

reporting 

required 


An  additional  (check) 
sample  must  be  taken 
within  24  hrs. 


If  the  average  (mean)  of 
original  and  check 
sample  DOES  NOT 
exceed  the  MCL 


Routine 

reporting 

required 


If  the  average  (mean) 
of  original  and  check 
sample  does  exceed  the  MCL 


Report  this  to  the 
state  within  48 
hours 


AND 


Notify  the 
public 


AND 


Monitor  at  the  frequency  designated  by 
the  state  until  the  MCL  has  not 
been  exceeded  in  two  successive 
samples  or  until  a  monitonng  schedule 
IS  set  up  as  a  condition  to  variance, 
exemption,  or  enforcement  action. 


ERLC 


537 


518  Water  Treatment 


TABLE  22.11    REPORTING  PROCEDURES  —  DAILY  TURBIDITY  MONITORING 


Take  Sample 


If  the  sample  does  j 
not  exceed  1  TU* 


Routine 

reporting 

required 


If  the  sample 
exceeds  1  TU* 


An  additional  (check) 
sample  must  be  taken 
within  1  hour 


If  check  sample  does 
not  exceed  1  TU* 


If  check  sample 
exceeds  1  TU* 


Routine 

reporting 

required 


Report  this  to 
the  state  within 
48  hours 


*  MCL  of  5  TU  may  be  established  at  state  option 


TABLE  22.12   REPORTING  PROCEDURES  — 
WHEN  CALCUUTING  TWO-DAY  TURBIDITY  AVERAGES 


Using  values  from  original  samples 
on  days  MCL  was  not  exceeded,  and 
check  sample  values  for  days  the 
MCL  was  exceeded,  calculate  the 
two-day  average* 


If  the  average  of  two 
samples  taken  on  consecutive 
days  does  not  exceed  5  TU 


If  the  average  of  two 
samples  taken  on  consecutive 
days  exceeds  5  TU 


Routine 

reporting 

required 


AND 


Notify 
the  public 


Report  this  to 
the  state  within 
48  hours 


•  The  average  is  based  on  the  results  of  samples  taken  on  CONSECUTIVE  DAYS. 

d  538 
ERIC 


Water  Quality  Regulations  519 


TABLE  22.13   REPORTING  PROCEDURES  — 
WHEN  CALCULATING  MONTHLY  AVERAGE  TURBIDITY  VALUES 


Using  values  from  original  samples 
on  days  MCL  was  not  exceeded,  and 
check  sample  values  for  days  the 
WiCL  was  exceeded,  calculate  the 
average  monthly  value. 


If  monthly  average 
of  the  daily  samples 
does  not  exceea  1  TU* 


If  monthly  average 
of  the  daily  samples 
exceeds  1  TU* 


Routine 

reporting 

lequired 


Report  this  to 
the  state  within 
48  hours 


MCL  of  5  TU  may  be  established  at  state  option. 


AND 


Notify 
the  public 


TABLE  22.K   REPORTING  PROCEDURES 
MICROBIOLOGICAL  CONTAMINANTS  —  MEMBRANE  FILTER  METHOD 


Take  Sample 


If  4  colonies/100  mL 
IS  not  exceeded 


If  4  coIonies/100  mL 
IS  exceeded 


Routine 

reporting 

required 


At  least  two  consecutive 
daily  check  samples  must 
te  taken  from  the  same 
sampling  point 


If  none  of  the  check 
samples  contain  one  or 
more  colonies/lOO  mL 


If  any  of  the  check 
samples  contain  one  or 
more  colonies/lOO  mL 


Routine 

reporting 

required 


Report  this  to 
the  state  within 
48  hours 


539 


AND 


Collect  additional  check  samples 
on  a  daily  basis  or  at  a  freruency 
established  by  the  state,  until  the 
results  obtained  from  at  least  2 
consecutive  check  samples  show 
less  than  one  coliform  colony/100  mL 


520  Water  Treatment 


TABLE  22.15   REPORTING  PROCEDURES 
WHEN  CALCULATING  MONTHLY  MEMBRANE 
FILTER  RESULTS 


I.  CALCULATE 
THE  MONTHLY 
AVERAGE 
VALUE 


Using  values  from  original 
samples  ONLY.*  calculate 
the  monthly  average  value 


If  the  monthly  average  of 
the  daily  samples  does  not 
exceed  1  colony/100  mL 


If  the  monthly  average  of 
the  daily  samples  exceeds 
1  colony/1 00  mL 


Routine 

reporting 

required 


Report  this  to 
the  state  within 
48  hours 


AND 


Notify 
the  public 


II.  DETERMINE  THE 
NUMBER  OF  TIMES 
4  COLONIES/100  mL 
WAS  EXCEEDED 


Using  values  from  original 
samples  ONLY,  determine  the 
number  of  times  4  colonies/ 
1 00  mL  was  exceeded** 


If  the  MCL'" 
IS  not  exceeded 


Routine 

reporting 

required 


If  the  MCL— 
IS  exceeded 


Report  this  to 
the  state  within 
48  hours 


AND 


Notify 
the  public 


•  Check  sample  values  arc  not  to  be  used  when  calculating  the  monthly  average. 

"  100  ^^^'"^  FEWER  THAN  20  SAMPLES  PER  MONTH,  merely  count  the  number  of  samples  exceeding  4  colonies/ 

For  systems  taking  20  OR  MORE  SAMPLES  PER  MONTH,  calculate  the  percentage  of  samples  exceeding  4  colonies/ 
lOOmL, 

The  MCL  states  that  coliform  presence  shall  not  exceed  4  colonies/100  mL  m  more  than  one  sample  'f  fewer  than  20  sam- 
ples collected  per  mon»h  or  4  coIonles/100  mL  in  more  than  5%  of  the  samples  if  20  or  more  are  exanimed  per  month. 


ERIC 


540 


Water  Quality  Regulations  521 


TABLE  22.16   REPORTING  PROCEDURES  — 
MICROBIOLOGICAL  CONTAMINANTS-MULTIPLE-TUBE  FERMENTATION  METHOD  (10  mi) 


I  Take-Sample 


If  there  are  fewer 
than  3  tubes  positive 
in  a  single  sample 


If  3  or  more  tubes 
are  positive  in  a 
single  sample 


Routine 

reportinc 

required 


At  least  two  consecutive 
daily  check  samples 
must  be  taken  from  the 
same  sampl.  q  point 


If  none  of  the  check 
samples  contain  one  or 
more  positive  tubes 


If  any  of  the  check 
samples  contain  one  or 
r.^ore  positive  tubes 


Routine 

reporting 

required 


Report  this  to 
the  state  within 
48  hours 


AND 


Collect  additional  check  samples 
on  a  daily  basis  or  at  a  frequency 
established  by  the  state,  until 
the  results  obtained  from  at  least 
2  consecutive  check  samples  show 
no  positive  tubes.   


.  541 


522  Water  Treatment 


TABLE  22.17   REPORTING  PROCEDURES  — 
WHEN  CALCULATING  MONTHLY  MULTIPLE-TUBE 
FERMENTATION  (10  mL)  RESULTS 


I.  CALCULATE  THE 
MONTHLY 
PERCENTAGE 


Using  values  from  original 
saoiples  ONLY*,  calculate  the 
monthly  percentage 


If  10%  or  less  of  the 
I  tubes  for  the  month  are 
!  positive 


If  more  than  10%  of 
the  tubes  for  the 
month  are  positive 


Routine 

reporting 

required 


Report  this  to 
the  state  withm 
48  hours 


AND 


Notify 
the  public 


11.  DETERMINE  THE 
NUMBER  OF  TIMES 
3  OR  MORE  TUBES 
WERE  POSITIVE 


Using  values  from  original 
samples  ONLY*,  determine  the 
number  of  times  3  or  more 
tubes  were  positive/* 


I  If  the  MCL*** 
i  IS  not  exceeded 


Routine  j 
reporting  i 
required  | 


I  If  the  MCL***  I 

I  IS  exceeded 


Repofi  this  to 
the  state  within 
48  hours 

AND 

j  Notify 
j  the  public 

*  Check  sample  values  are  not  to  be  used  when  calculating  the  monthly  percentages. 
Foi  systems  taking  FEWER  THAN  20  SAMPLES  PER  MONTH,  merely  count  the  number  of  samples  which  contained  3  or 
more  positive  portions. 

For  systems  taking  20  OR  MORE  SAMPLES  PER  MONTH,  calculate  the  percentage  of  samples  containing  3  or  more  posi- 
tive portions. 

The  MCL  states  that  not  more  than  1  sampit  may  have  3  or  more  portions  positive  when  fewer  than  20  samples  ire  exam- 
ined per  month  OR  not  more  than  5^o  of  the  samples  may  have  3  or  more  portions  positive  when  20  or  more  samples  are 
examined  per  month. 


ERLC 


542 


Water  Quality  Regulations  523 


TABLE  22.18   REPORTING  PROCEDURES  — 
MICROBIOLOGICAL  CONTAMINANTS  —  CHLORINE  RESIDUAL 


"ake 
Daily  Sample 


If  the  free  chlorine 
residual  is  0.2  mg/L  or 
greater 


If  the  free  chlorine 
residual  is  less  than 
0.2  mg/L 


Routine 

reporting 

required 


A  check  sample  must  be 
taken  within  one  hour 


If  the  check  sample 
indicates  that  the  free 
chlorine  residual  is  0.2 
mg/L  or  greater 


If  check  sample  indicates  that 
the  free  chlorine  residual  is 
less  than  0.2  mg/L 


Routine 
reporting 
I  required 


Report  this  to 
the  state  within 
48  hours 


AND 


Take  a  sample  for  coliform 
bacterial  analysis  from 
that  sampling  point, 
preferably  within  one  hour 


AND 


Report  the  results  of  the 
coiiform  test  to  the  state 
within  48  hours 


ERLC 


543 


524  Water  Treatment 


TABLE  22. 1  >   RCPORTING  PROCEDURES — 
RADIOLOGICAL  CONTAMINANTS  —  NATURAL 
(Test  for  gross  alpha  activity) 


Take  quarterly  samples 
or  composite  quarterly 

i 

Average  the  results*  ~[ 


If  gross  alpha 

activity  IS 

5  pCi/L  or  less 


If  gross  alpha 
activity  IS  greater 
than  5  pCi/L 


OR 


If  gross  activity  is 
greater  than  15  pCi/L 


Routine 

reporting 

required 


Lab  must  test 
for  radium  226 


If  radium  226 
IS  3  pCi/L  or 
less 


If  radium  226 
IS  greater  than 
3  pCi/L 


Routine 

reporting 

required 


IE 


I  Lab  must  lest  tor 
I  radium  228** 


I 


I 


j  If  radium  226  +  radii"^.  228 
j^is  5  pCi/L  or  less  j 


"::-r, 

I  Routine 

reporting 
1^  required  j 


•  Average 


.  Sum  of  four  values 


Report  this  to 

the  state  within 

48  hours 

AND 

Notify  the 

public 

1. 


flf  radium  226  +  radium  228  1 
^is  greater  than  5  pCi/L  j 


Report  this  to  the 
state  within  48  hours 


AND 


Notify 
the  public 


AND 


Monitor  at  quarterly  intervals 
until  the  annual  average  concen- 
tration no  longer  exceeds  the 
MCL  or  until  a  monitoring 
schedule  is  set  up  as  a  condition 
to  a  variance,  exemption  or 
enforcement  action. 


No  averaging  is  required  if  the  quarterly  samples  were  composited.  In  that  case,  use  the  results  of  the  single  sample. 
'  This  step  Is  required  only  for  ihe  initial  monitoring  period  and  not  for  routine  monitoring,  EXCEPT  AS  REQUIRED  BY  THE 
STATE, 


ERIC 


541 


TABLE  22*20  REPORTING  PROCEDURES  — 
RADIOLOGICAL  CONTAMINANTS  —  MAN-MADE 


(Applicable  Only  to  Surface  Water  Systems  Serving  Populations  of  100,000  or  More) 


Take  quarterly  samples 
or  composite  quarterly 

Average  the 
results* 

Compare  the  results  with  the 
following  limits: 
Gross  beta  —  50  pCi/L 
Strontium  90  —  8  pCi/L 
Tritium  —  20.000  pCi/L 

If  none  of  the 
three  limits  are 
exceeded 


Routine 

repor'.ing 

required 


If  gross  beta  is 
greater  than 
50  pCi/L 


An  analysis  of  the  sample  must 
be  performed  to  Identify  the 
major  radioactive  constituents 
present.  The  appropriate  organ 
and  total  bodv  doses  must  be 
calculated  tc  Jetermine  whether 
the  4  mrem/yr  MCL  is  exceeded* 


If  either  tritium 
or  strontium  90 
limits  are  exceeded 


r 


Report  this  to 
the  state  within 
48  hours 


AND 


Notify 
the  public 


If  tritium  and 
strontium  90  are 
BOTH  present  in 
the  sample  in  any 
concentration 


Calculate  the  sum 
of  annual  dose 
equivalents  to  bone 
marrow** 


If  no  total  body  or 
individual  organ  doses 
exceed  4  mrem/yr 


If  any  total  body  or 

individual  organ 

doses  exceed  4  mrem/yr 


Routine 

reporting 

required 


If  the  sum  of  annual 
do^   equivalents  to 
bone  marrow  does  not 
exceed  4  mrem/yr 


Report  this  to  the 
state  within  48  hours 


AND 


Notify 
the  public 


Routine 

reporting 

required 


If  the  sum  of  annual 
dose  equivalents  to 
bone  marrovv  exceeds 
4  mrem/yr 


Report  this  to  the 
state  within  48 
hours 


AND 


Notify  *he  public 


•  Average  =rSum  of  four  values 
4 

No  averaging  Is  requirerl  if  the  quarterly  samples  wc;e  composited.  In  that  case,  use  the  results  of  the  single  sample. 
Q    It  is  likely  that  the  laboratory  will  not  make  these  calculations.  You  will  probably  have  to  get  help  from  state  water  supply  personnel  in  making  these  calculations. 


O 
c 
o 


U9 
IP 


526  Water  Treatment 


TABLE  22.21    REPORTING  PROCEDURES  —  TOTAL  TRIHALOMETHANES 
(Applicable  to  Community  Surface  Water  Systems 
Serving  Populations  of  10,000  or  More) 


4  samples  per  quarter, 
report  arithmetic 
average  to  State  within 
30  days 


After  completing 
one  year  sampling 


Calculate  running 
annual  average  MCL 
quarterly 


If  Avg>MCL 


yes 


no 


Report  to  state  and/or 
EPA  within  30  day^  of 
receipt  of  results 


Notify  State 
within  48  hours 


SURFACE  WATER  SYSTEM 
can  be  reduced  to  a 
minimum  of  1  sample/ 
quarter 


GROUNDWATER  SYSTEMS 
can  be  reduced  to  one 
MAXIMUM  TTHM  POTENTIAL 
per  year  for  each  treatment 
plant 


J 


Change  of  source 
of  water  or  treatment 
program 


no 


no 


yes 


no 


any  sample 
>0.10  mg/L 


any  sample 
^0.10  mg/L 


no 


yes 


yes 


Take  check  sample 
promptly 


If  check  sample 
positive 


Notify  public 


yes 


Monitor  at  the  frequency 
designated  by  the  State 


Send  copy  of 
notice  to  State 


MCL 

Total  trihalomethanes  (the  sum  of 
the  concentrations  of 
bromodlchloromethane, 
dibromochlorometh2ne» 
tribromomethane  (bromoform)  and 
trichloromethane  (chloroform)) 
0.10  mg/L 


ERIC 


547 


QUES  JNS 

Write  your  answers  In  a  notebook  and  then  compare  your 
answers  w>th  those  on  page  529. 

22.9A  What  are  the  two  general  categories  of  reporting 
called  for  by  the  SDWA? 

22.9B  What  are  ihe  three  types  ot  reports  that  must  be  sent 
to  the  state'' 


Water  Quality  Regulations  527 

22.1  OA  If  an  MCL  Is  violated,  what  Is  the  required  public 
notification? 


DiSCUSSiO.:  AND  REVIEW  QUESTIONS 

Chapter  22.   DRINKING  WATER  REGULATIONS 

(Lesson  2  of  2  Lessons) 


Write  the  answers  to  these  questions  In  your  notebook 
before  continuing  w^th  the  Objective  Test  on  page  530.  The 
problem  numbering  continues  from  Lesson  1. 

9.  Why  is  there  a  prinripy  drinking  water  standard  for 
turbidity? 

1 0.  What  are  the  most  common  sources  of  organic  contami- 
nation if  drinking  water? 

11.  What  do  secondary  drinking  water  regulations  control? 

12.  Why  are  secondary  drinking  water  regulations  impor- 
tant? 

13.  How  may  color  be  caused  in  water? 

14.  Why  are  iron  and  manganese  undesirable  in  drinking 
water? 


15.  Why  is  the  absence  Oi  tastes  and  odors  In  dnnking 
water  import' ^t? 

16.  Why  are  high  levels  of  total  dissolved  solids  undesirable 
In  drinking  water? 

17.  Why  wasn't  hydrogen  sulfide  listed  under  the  Secon- 
dary Drinking  Water  Standards? 

18.  How  IS  the  numb<=»»'  of  sampling  points  determined? 

19.  What  are  the  major  considerations  in  determining  the 
number  and  location  of  sampling  points? 

20.  How  is  a  sampling  route  selected? 

21 .  How  can  samples  be  preserved? 


SUGGESTED  ANSWERS 

Chapter  22.    DRINKING  WATER  REGULATIONS 


ANSWERS  TO  QUESTIONS  IN  LESSON  1 

Answers  to  questions  on  pr  le  496. 

22.0A  The  first  c^:  inking  water  standards  were  designed  to 
contrOi  waterborne  bacteria  and  viruses  that  can 
C2jse  diseases  such  as  cholera,  typhoid,  and  dysen- 
tery. 

22.1  A  The  major  aspects  of  the  1986  Amendments  to  the 
SDWA  include: 

1.  Compulsory  revisions  to  the  regulations  for  new 
contaminants, 

2.  Definition  of  an  approved  treatment  technique  for 
each  regulated  contaminant, 

3.  Filtration  requirement  for  surface  water  supplies, 

4.  Disinfection  of  all  water  supplies,  and 

ERIC 


5.  Prohibition  of  thr  use  of  lead  products  In  materials 
used  to  convey  Drinking  water. 

22.1  B  Water  systems  will  not  be  required  to  meet  Phase  I 
regulations  until  two-and-a-half  years  after  the  law 
was  passed  because  the  Act  requires  promulgation 
of  regulations  within  12  months  and  an  additional  18 
months  must  be  given  for  the  states  to  adjust  their 
own  regulations. 

Answers  to  questions  on  page  498. 

22.2A  Trihalomethanes  (THMs)  are  the  product  of  chlorine 
combining  with  organic  material  in  the  water;  they  are 
suspected  carcinogens. 

22.3A  The  draft  Surface  Water  Treatment  Rule  (SWTR) 
specifically  requires  tha^ 

1.  All  r  iace  water  systems  must  disinfect, 


528  Water  Treatment 


2.  All  surface  water  systems  must  filter  unless  they 
meet  source  water  quality  criteria  and  site-specific 
conditions* 

3.  All  systems  will  need  to  achieve  the  removal  or 
inactivation  criteria  of  Giardia  and  enteric  viruses, 
and 

4.  Only  qualified  operators  will  be  entitled  to  operate 
the  systems. 

22.3B  A  water  utility  can  avc  1  mandatory  filtration  by 
meeting  (1)  source  water  quality  criteria  (coliforms 
and  turbidity  levels),  and  (2)  certain  site-specific 
conditions  regarding  disinfection,  watershed  control, 
lack  of  waterborne  disease  outbreaks,  compliance 
with  conform  MCL,  and  total  THM  MCL. 

Answers  to  questions  on  page  500. 
22.4A  A  community  water  system  is  defined  as  follows: 

1.  Has  at  least  15  service  connections  used  by  all- 
year  residents,  or 

2.  Services  at  least  25  all-year  residents. 

22.5A  The  five  types  of  primary  contaminants  which  are 
considered  to  be  of  public  health  importanro  are: 

1.  Inorganic  contaminants, 

2.  Organic  contaminants, 

3.  Turbidity, 

"4.  Microbiological  contaminants,  and 

5.  Radiological  contaminants. 

22.5 B  Nitrate  in  drinking  water  above  the  national  standard 
poses  an  immediate  threat  to  children  under  three 
months  of  age.  In  some  infants,  excessive  levels  o^ 
nitrate  have  been  known  to  react  with  intestinal 
bacteria  which  change  nitrate  to  nitrite  which  reacts 
with  henr^oglobin  in  the  blood  to  produce  an  anemio 
condition  commonly  known  as  "blue  baby." 

ANSWERS  TO  QUf  '>t        iN  LESSON  2 

Answers  to  questions  on  page  j04. 

22.6A  Inorganic  chemicals  ^re  metals,  salts,  and  other 
chemical  compounds  that  do  not  contain  carbon. 

22.68  Arsenic  is  listed  as  a  primary  contaminant  because 
water  that  continuously  exceeds  the  national  stan- 
dard by  a  substantial  amount  over  a  lifetime  may 
cause  fatigue  and  loss  of  energy.  Extremely  high 
levels  can  cause  poisoning. 

22.60  At  levels  of  6  to  8  mg/L  fluoride  may  cause  skeletal 
fluorosis  which  is  a  brittling  of  the  bones  and  stiffen- 
ing of  the  joints.  At  levels  of  2  mg/L  and  greater 
fluoriae  may  cause  dental  fluorosis  which  is  discolor- 
ation and  mottling  of  the  teeth,  especially  in  children. 

22.6D  Lead  may  enter  drinking  water  from  galvanized 
pipes,  solder  used  with  copper  pipes,  and  through 
the  air  from  auto  exhausts. 

Answers  to  questions  on  page  505. 

22.6E  Organic  chemicals  are  either  natural  or  synthetic 
chemical  compounds  that  contain  carbon.  Synthetic 
organic  chemicals  (SOCs)  are  man-made  com- 
pounds that  are  widely  used  as  pesticides,  paints, 
dyes,  solvents,  plastics,  and  food  additives. 

ERIC  549 


22.6F  Trichloroethylene  (TOE)  has  been  widely  used  as  an 
ingredient  in  many  household  products  (spot  remov- 
ers, rug  cleaners,  air  fresheners),  dry  cleanif.g 
agents,  industrial  metal  cleaners  and  polishes,  refrig- 
erants, and  even  anesthetics. 

22.6G  The  monthly  average  turbidity  MCL  may  not  exceed 
1  TU.  At  state  option  this  may  be  raised  to  5  TU. 
Some  states  require  0.5  TU  where  there  is  a  major 
hazard  of  wastewater  (sewage)  contamination  of  the 
water  supply. 

Answers  to  questions  on  page  508. 

22.6H  EPA  is  considering  tha  creation  of  MCLs  for  Giardia. 
viruses,  standard  plate  count,  and  Legionella. 

22.61  For  water  systems  that  regulariy  take  10  or  fewer 
samples  per  month,  ONE  positive  sample  may  be 
discarded  if: 

1.  The  system  chlorinates  and  maintains  a  residual. 

2.  The  system  takes  two  check  samples  on  consecu- 
tive days,  and 

3.  This  exclusion  has  NOT  been  used  in  the  previous 
month. 

22.6J  The  MCLs  for  radiological  contaminants  are  divided 
into  two  categories:  (1)  natural  radioactivity  which 
results  from  well  water  passing  through  deposits  of 
naturally  occurring  radioactive  materials;  and  (2) 
man-made  radioactivity  such  as  might  result  from 
industrial  wastes,  hospitals  or  research  laboratories. 

Answers  to  questions  on  page  509. 

22.7A  Secondary  drinking  water  regulations  are  enforce- 
able after  a  state  has  passed  a  law  requiring  the  state 
health  agency  to  enforce  the  regulations. 

22.7B  The  secondary  drinking  water  contaminants  include: 

1.  Chloride  8.  Manganese 

2.  Color  9.  Odor 

3.  Copper  10.  pH 

4.  Corrosivity  11.  Sulfate 

5.  Foaming  Agents    12.  Total  Dissolved  Solids 

6.  Fluoride  13.  Zinc 

7.  Iron 

22.70  Contaminants  in  the  secondary  regulations  should 
be  monitored  at  intervals  no  less  frequent  than  the 
moi.iionng  performed  for  inorganic  contaminants 
listed  in  the  Interim  Primary  Drinking  Water  Regula- 
tions or  applicable  to  community  water  systems. 
More  frequent  monitoring  would  be  appropriate  for 
specific  contaminants  such  as  pH,  color,  odor  or 
others  undftr  certain  circumstances  as  directed  by 
the  state. 

Answers  to  questions  on  page  511. 

22.7D  Chloride  is  a  secondary  contaminant  because  it 
affects  the  aesthetic  quality  of  water  by  imparting  an 
objectionable  salty  taste  in  water  and  because  it 
causes  corrosion  of  the  pipes  in  hot  water  and  other 
systems. 


Water  Quality  Regulations  529 


227E  Copper  usually  gets  Into  drinking  water  from  the 
reaction  of  aggressive  water  on  copper  plumbing. 

227F  Reasons  why  corrosive  waters  are  undesirable  as 
drinking  water  include: 

1  Affects  the  aesthetic  quality  (turbid  waters),  and 
causes  taste  and  odor  problems  .n  the  water 
supply; 

2.  Has  senous  economic  'mpact  (loss  of  piping  sys- 
tems and  water  loss  from  leaks);  and 

3.  Presents  health  implications  (toxic  corrosion 
products  such  as  lead,  cadmium  and  copper). 

22.7G  The  application  of  chlorine  to  waters  containing 
manganese  increases  the  likelinood  of  precipitation 
at  low  levels.  Unless  the  precipitate  is  removed, 
precipitates  reaching  pipelines  will  promote  bacterial 
growth. 

Answers  to  questions  on  page  ''•S. 

22.7H  The  undesirable  effects  of  abnormal  pH  values  in- 
clude: 

1 .  When  the  pH  increases,  the  disinfection  activity  of 
chlorine  falls  significantly; 

2.  High  pH  may  cause  increased  halogen  reactions, 
which  produce  chloroform  and  other  tnhalometh- 
anes  during  chlorination; 

3  Both  excessively  high  and  low  pHs  may  cause 
increased  corrosivity  which  can  in  turn  create 
taste  problems,  staining  problems,  and  significant 
hea'*h  hazards; 

4.  Metallic  piping  in  contact  with  low  pH  water  will 
impart  a  metallic  taste; 

5.  If  piping  IS  iron  or  copper,  oxide  and  carbonate 
compounds  will  be  deposited  leaving  red  or  green 
stains; 

6.  At  high  pH,  dnnking  water  acquires  a  bitter  taste, 
and 

7.  The  high  degree  of  mineralization  often  associat- 
ed with  basic  waters  results  in  encrustation  of 
water  pipes  and  water-using  appliances. 

22.71    High  levels  of  sulfate  are  undesirable  because  they: 

1.  Tend  to  form  hard  scales  in  bOuers  and  heat 
exchangers, 

2.  Cause  taste  effects,  and 

3.  Cause  a  laxative  effect. 

22.7J  High  levels  of  zinc  are  undesirable  in  dnnking  water 
because  they: 

1  Produce  adverse  physiological  effects, 

2.  Impart  undesirable  tasted, 

3.  Cause  a  milky  appearance  in  the  water,  and 

4.  May  increase  lead  and  cadmium  concentrations. 


22.8C  '.Whenever  an  initial  or  routine  sample  analysis  indi- 
cates that  an  MCL  has  been  exceeded,  CHECK 
SAMPLING  IS  required  to  confirm  the  routine  sam- 
pling results.  Check  sampling  is  in  addition  to  the 
routine  sampling  program. 


22.8D  At  the  very  minimum,  a  small  system  with  a  popula- 
tion of  100  people  must  sample  for  turbidity  and 
coliform  bacteria  and  also  must  have  two  sampling 
points. 

1  One  where  the  water  enters  the  distribution  sys- 
tem, and 

2  One  at  a  consumer  faucet  at  a  point  representa- 
tive of  the  distribution  system. 


Answers  to  questions  on  page  515. 

22.8E  Information  that  should  be  specified  in  a  sampling 
program  includes: 

1.  Sampling  frequency, 

2.  Sampling  point  designation, 

3.  Location, 

4  Type  of  test, 

5.  Sampie  volume,  and 

6.  Special  handling  instructions. 


22.8F  The  following  elements  are  necessary  to  the  cc 'lec- 
tion of  an  acceptable  sample: 

Obtain  a  sample  that  is  truly  representative  of  tne 
existing  condition, 

2.  Flush  the  line  before  sample  collection, 

3.  Fill  the  sample  bOiJe  without  leaving  any  air 
pocket, 

4.  Analyze  residual  chlonne  when  the  sample  is 
taken, 

5.  Maintain  the  sample  so  that  it  does  not  become 
contaminated  before  it  reaches  the  laboratory, 

6.  Use  preservation  techniques  (pH  control  and  re- 
frigeration), 

7.  Keep  accurate  3cords  of  every  sample  collected 
(date,  time,  location,  name  of  sample,  bottle  num- 
ber, type  of  sample,  and  name  of  person  collect- 
ing sample),  and 

8.  Keep  the  time  between  the  collection  of  the  sam- 
ple and  analysis  as  short  as  possible. 


Answers  to  questions  on  page  527. 

22.9A  The  two  general  categories  of  reporting  called  for  by 
the  SDWA  are: 

1 .  P^^norting  to  the  public  (public  notification),  and 

2.  Reporting  to  the  state. 


Answers  to  questions  on  page  514. 

22.8A  "Initial  Sampling'  refers  to  the  very  first  sampling  you 
do  under  the  Safe  Drinking  Water  Act  for  each  of  the 
applicable  contaminant  categories. 

22.8B  Routine  sampling  refers  to  sampling  repeated  on  a 
regular  basis. 

ERIC 


22.9B  The  three  type^  cf  reports  that  must  be  sent  to  the 
state  are: 

1.  Routine  sample  reryorts, 

2.  Check  sample  reports,  and 

3.  Violation  reports. 


2k  lOARequired  public  notification  for  the  violation  of  an 
MCL  includes  mail,  newspaper  and  broadcast. 


530  Water  Treatment 


OBJECTIVE  TEST 

Chapter  22.    DRINKING  WATER  REGULATIONS 


Please  write  your  name  and  mark  the  correct  answers  on 
the  answer  sheet  as  directed  at  the  end  of  Chapter  1 .  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
questions. 

TRUE-FALSE 

1  All  public  water  systems  must  comply  with  the  regula- 
tions of  the  Safe  Drinking  Water  Act 

1  True 
2.  False 

2  MCLs  apply  only  to  contaminants  from  man-mac  ollu- 
tion. 

1.  True 

2.  False 

3.  More  types  of  contaminants  must  be  monitored  by  non- 
community  than  community  systems. 

1  True 
2.  False 

4.  MCLs  have  been  established  to  indicate  when  a  con- 
form concentration  could  indicate  the  likely  ptesence  of 
disease-causing  bacteria. 

1.  True 

2.  False 

5  Monitoring  for  natural  radioactivity  is  required  onh'  for 
groundwater  community  systems. 

1.  True 

2.  False 

6.  The  concerns  with  inorganic  chemicals  In  drinking  water 
are  centered  on  cancer. 

1.  True 

2  False 

7  Coliform  bacteria  in  water  are  used  to  indicate  the 
potential  presence  of  pathogens 

1.  True 

2.  Falsi 

8.  Barium  can  enter  drinking  water  through  natural 
sources  in  the  environment  or  industrial  waste  dis- 
charges 

1.  True 

2.  False 


9  The  health  risk  from  mercury  is  greater  from  waterborne 
mercury  than  simply  from  eating  fish. 

1  True 

2  False 

^0  Secondary  drinking  water  regulations  are  federally  en- 
forceable 

1  True 
2.  False 


1 1  Map  taste  etfocts  in  water  are  produced  by  cations. 

1  Trie 

2  Fals-^ 

12  The  level  of  color  m  water  is  a  measure  of  the  safety  of 
water 

1  True 

2  False 

1 3  Rapid  changes  m  color  levels  may  produce  more  citizen 
complaints  than  relatively  high,  constant  color  levels. 

1  True 

2  False 

1 4  EPA  dnnk'ng  water  regulations  are  called  "intenm"  regu- 
lations because  research  continues  on  drinking  water 
contaminants. 

1  True 

2  False 

15  Taste  tests  are  less  fatiguing  than  odor  tests. 

1  True 

2  False 

16  If  a  water  doesn't  have  any  taste  or  odor,  then  it  is  safe 
to  drink 

1  True 

2  False 

17  Consumers  can  tolerate  a  wide  range  of  pH  values  in 
dnnking  water 

1  True 

2  False 

18  At  low  pH  levels  drinking  water  acquires  a  bitter  taste. 

1  True 

2  False 

19  Samples  should  be  collected  from  consumers'  faucets 
which  are  representative  of  conditions  within  the  distri- 
bution system. 

1.  True 
2  False 

20  Check  sampling  is  part  of  the  rcjtine  sampling  program. 

1  True 

2  False 

21  When  samples  are  delivered  to  the  lab.  lab  personnri 
must  complete  the  field  data  forms  upon  acceptance  of 
toe  samples. 

1  True 

2  False 

22  The  pnmary  purpose  of  the  Safe  Drinking  Water  Act  is 
to  protect  the  public's  health. 

1.  True 

2.  False 


EMC 


551 


Water  Quality  Regulations  531 


23  Sampling  points  must  include  representative  locations 
of  each  different  water  source  entering  the  system 

1.  True 
2  False 

24  Sample  lines  should  be  flushed  before  collecting  a 
sample 

1.  True 

2  False 

25  Failure  to  comply  with  a  testing  procedure  requires 
notification  of  consumers  by  newspaper 

1  True 

2  False 


MULTIPLE  CHOICE 

26.  The  regulations  of  the  Safe  Drinking  Water  Act  which 
operators  must  deal  with  extensively  include 

1  Maximum  Contaminant  Levels. 

2.  Reporting  requirements. 

3.  Sampling  and  testing  requirements. 

4.  Siting  requirements. 

5.  Variations  in  the  regulations. 

27  Types  o*  primary  conta.T»inants  which  are  considered  to 
be  of  public  health  importance  include 

1.  Corrosivity  contaminants. 

2.  Foaming  contaminants. 

3.  Inorganic  contaminants. 

4.  Microbiological  contaminants. 
5  Turbidity 

28.  Contaminants  which  may  affect  public  health  after  a 
short-term  exposure  include 

1.  Microbtologica' contaminants. 

2.  Nitrate. 

3  Organic  chemicals. 

4.  Radiological  chemicals. 

5.  Trihalomethanes. 

The  MCLs  for  organic  chemicais  presently  include 

1.  Herbicides. 

2.  Oils. 

3  Pestic'des. 

4.  Solvents. 

5  Trihalomethanes. 

30.  The  MCL  established  for  total  trihalomethanes  (TTHMs) 

IS 

1.  0.1  micrograms  per  liter. 

2.  1.0  microgram  per  liter. 

3.  0.10  milligrams  per  liter. 

4.  1.0  milligram  per  liter. 

5.  10  milligrams  per  liter. 

31 .  A  stale  may  allow  a  water  utility  to  reduce  the  frequency 
of  sampling  for  THMs  arter  taking  into  consideration 

1.  Age  of  persons  living  in  community. 

2.  Health  of  community. 

3.  Level  of  natural  organics  in  water. 

4.  Quality  and  stability  of  raw  water. 

5.  Type  of  treatment. 

O 

ERIC 


32.  The  Safe  Drinking  Water  Act  gave  the  U.S.  Environmen- 
tal Protection  Agency  the  authority  to 

1.  Establish  uniform  guidelines  of  drinking  water  tech- 

ologies. 

2.  i$5.>-e  NPDES  permits  to  water  purveyors. 

3.  Promulgate  pretreatment  effluent  standards  for 
POTWs. 

4.  Require  monitoring  and  reporting  for  public  water 
systems. 

5.  Set  national  standards  for  regulating  levels  of  conta- 
minants in  drinking  water. 


33.  The  draft  Surface  Water  Treatment  Rule  (SWTR)  re- 
quires that  a  disinfection  residual  of  rng/L  in  95 

percent  of  the  samples  be  maintained. 

1.  0.2 

2.  0.5 

3.  1.0 

4.  2.0 

5.  5.0 


34.  Substances  for  which  drinking  water  standards  have 
been  set  and  which  pose  an  immediate  threat  to  health 
whenever  the  standards  are  exceeded  include 

1.  Arsenic. 

2.  Coliform  bacteria. 

3.  Lead. 

4.  Mercury. 

5.  Nitrate. 


35.  Arsenic  is  commonly  found  in 

1.  Beverages. 

2.  Candy. 

3.  Food. 

4.  Shellfish. 

5.  Tobacco. 


36.  Cadmium  can  enter  drinking  water  from 

1.  Canneries. 

2.  Electroplating. 

3.  Insecticides. 

4.  Metallurgy 

5.  Photographic  processes. 


37.  Water  with  a  high  color  content  may  indicate 

1  High  disinfection  demand. 

2  High  organic  chemical  contamination. 

3.  High  pH. 

4.  Inadequate  treatment. 

5.  Potential  for  production  of  excess  amounts  of  disin- 
fection by-products. 


38.  Reasons  why  copper  is  undesirable  in  drinking  water 
include 

1.  Causes  blue  or  green  staining  of  porcelain. 

2.  Imparts  some  taste  to  water. 

3.  Kills  algae. 

4.  Results  in  liver  damage  after  prolonged  doses. 

5.  Stains  blond  hair. 

552 


532  MTeter  Treatment 


39.  True  taste  sensations  include 

1.  Bitter. 

2.  Rotten. 

3.  Salty 
4  Sour. 
5.  Sweet. 

40.  Undesirable  effects  from  high  levels  of  sulfate  in  drink- 
ing water  include  causing 

1.  Formation  of  hard  scales  in  boilers  and  heat  ex- 
changers. 

2.  Laxative  effects. 

3.  Precipitation  of  calcium  sulfate. 

4.  Taste  effects. 

5.  Undesirable  odors  in  water. 

41   High  levels  of  total  dissolved  solids  are  undesirable  in 
drinking  water  because  they  cause 

1.  Adverse  tastes. 

2  Deterioration  of  distribution  systems. 

3.  Precipitates  to  form  in  boilers. 

4.  Sludge  in  freezing  processes 

5.  Water  to  be  reused  more  often. 

42.  Which  of  the  following  actions  are  required  o^  operators 
by  the  Safe  Dnnking  Water  Act? 

1.  Organizing 

2.  Recordkeeping 

3.  Reporting 

4.  Sampling 

5.  Testing 

43.  When  you  start  and  when  you  finish  your  Initial  Sam- 
pling" program  depends  on 

1.  Available  budget. 

2.  Option  exercised  by  state. 

3.  Type  of  contaminant  being  monitored. 

4.  Whether  the  system  is  a  community  or  non-commu- 
nity water  system. 

5.  Whether  the  water  source  is  a  surface  or  a  ground- 
water supply. 


44.  Samples  should  be  collected  at  the  consumers*  faucet 
for  which  of  the  following  contaminants? 

1.  Coliform  ^actena 
2  Inorganics 

3.  Organics 

4.  Radiochemicals 

5.  Turbidity 

45.  Community  systems  must  sample  for  radioch'^micals 
every 

1.  Six  months. 

2  Year. 

3  Two  years. 
4.  Three  years. 
5  Four  years. 

46.  To  collect  an  acceptable  sample  you  must 

1.  Flush  the  line  before  sample  collection. 

2.  Keep  the  time  between  sample  collection  and  analy- 
sis as  long  as  possible. 

3.  Obtain  a  sample  truly  representative  of  the  existing 
condition. 

4.  Use  preservation  techniques. 

5.  Use  the  proper  reporting  form. 


ERIC 


553 


Water  Quality  Regulations  533 


APPENDIX 

Coiiform  Samples  Required  Per  Population  Served 


Population  Served 


Minimum  Number  of 
Samples  per  Month 


25  to  1,000      1t 

I,  001  to  2,500  2 

2,501  to  3,300  3 

3,301  to  4,100  4 

4,101  to  4.900  5 

4,901  to  5,800  6 

5,801  to  6,709  7 

6,701  to  7,600  8 

7,601  to  8,500  9 

8,501  to  9, 400   10 

9,401  to  10,300   11 

10,301  to  11,100  12 

II,  101  to  12,000   13 

12.001  to  12,900    14 

12,901  to  13,700    15 

13,701  to  14,600   16 

14,601  to  15,500    17 

15,501  to  16,300    18 

16,301  to  17,200    19 

17,201  to  18,100  20 

18,101  to  18,900   21 

18,901  to  19,800    22 

19,801  to  20,700    23 

20,701  to  2 1,500   24 

21.501  to  22,300    25 

22,301  to  23,200    26 

23,201  to  24,000    27 

24.001  to  24,900    28 

24,901  to  25,000   29 

25.001  to  28,000   30 

23.001  to  33,000   35 

33,001  to  37,000   40 

37.001  to  41.000   45 

41.001  to  46.000   50 

46.001  to  50,000   55 

50.001  to  54,000   60 

54.001  to  59,000   65 

59.001  to  64,000   70 

64.001  to  70  000    75 

70.001  to  76,000   80 

76.001  to  83.000   85 

83.001  to  90,000   90 


Population  Served 


Minimum  Number  of 
 Samples  per  Month 

90,001  to  96,000    95 

96,001  to  111,000   TOO 

111,001  to  130,000   110 

130,001  to  160,000   120 

160,001  to  190,000   130 

190,001  to  220,000    140 

220,001  to  250,000   150 

250,001  to  290,000   160 

290,001  to  320,000   170 

320,001  to  360,000   180 

360,001  to  410,000    190 

410,001  to  450,000   200 

450,001  to  500,000   210 

500,001  to  550,000   220 

550,001  to  600,000      230 

600,001  to  660,000    240 

660,001  to  720,000    250 

720,001  to  780,000   260 

780,001  to  840,000   270 

840,001  to  910,000   280 

910,001  to  970,000   290 

970,001  to  1,050,000    300 

1,050,001  to  1,140,000    310 

1,140.001  to  1,230,000   320 

1,230.001  to  1,320,000    330 

1.320.001  to  1,420,000    340 

1,420.001  to  1.520.000   350 

1.520,001  to  1.630,000    360 

1.630,001  to  1.730.000    370 

1,730,001  to  1.850.000   380 

1.850,001  to  1,970,000   390 

1,970,001  to  2,060,000   400 

2,060,001  .to  2,270,000   410 

2,270,001  to  2,510.000   420 

2,510.001  to  2,750,000   430 

2.750.001  to  3.020.000   440 

3.020.001  to  3.320,000   450 

3.320.001  to  3,620,000    460 

3.620.001  to  3.960,000   470 

3.960.001  to  4.310,000   480 

4.310.001  to  4.690,000   490 

More  than  4.690,001    500 


Source:  EPA 

t .  k  community  water  system  serving  25  to  1 .000  persons,  with  written  permission  from  the  state,  may  reduce  this  sampling  frequency,  ex- 
cept in  no  case  sh  ill  it  be  reduced  to  less  than  one  per  quarter  The  decision  by  the  state  will  be  based  on  a  history  of  no  coiiform  bacte- 
rial contamination  for  that  system  and  on  a  sanitary  survey  by  the  state  showing  the  water  system  to  be  supplied  solely  by  a  protected 
groundwater  source,  free  of  sanitary  defects. 


ERIC 


CHAPTER  23 

ADMINISTRATION 


by 

Tim  Gannon 


Revised 
by 

Jim  Sequeira 


ERIC 


536  Water  Treatment 


TABLE  OF  CONTENTS 

Chapter  23.  Administration 

Page 

OBJECTIVES  538 

23.0  Office  Procedures  539 

23.00  Budgeting  539 

23.01  Water  Rates  54O 

23.02  Procurement  of  Materia!  541 

23.03  Treatment  Plant  Records   543 

23.030  Purpose  of  Records  543 

23.031  Types  of  Records  543 

23.032  Types  of  Plant  Operation  Data  544 

23.033  Maintenance  Records   544 

23.034  Inventory  Records  544 

23.035  Equipment  Records  545 

23.036  Disposition  of  Plant  Records  545 

23.04  Organizational  Planning  545 

23.1  Personnel  Administration  547 

23.10  Supervision  547 

23.11  Staffing  547 

23.12  Training  543 

23.13  People    543 

23.14  Operator  Certification  549 

23.140  Need  for  Certified  Operators  549 

23.141  Why  Should  Water  Utility  Operators  Te  Certified?  549 

23.1410  Safety  549 

23.1411  P    action  of  the  Public's  Investment  549 

23.1412  Employee  Pride  and  Recognition  549 

23.142  ABC  549 

23.2  Public  Relations    549 

23.20  Establish  Objectives  549 

23.21  Utility  Operation    549 

23.22  The  Mass  Media  55O 

23.23  Being  Interviewed  55O 


ERLC 


556 


Administration  537 


23.24  Public  Speaking   550 

23.25  Telephone  Contacts  551 

23.26  Customer  Inquiries  551 

23  27  Plant  Tours   551 

23.3  Emergency  Planning   552 

23.4  Hanoling  the  ^Tireat  of  Contaminated  Water  Supplies  553 

23.40  !rT^po»1ance  553 

23.41  Toxicity   553 

23.42  Effaaive  Dosages  554 

23.43  Protective  Measures  554 

23.44  Emergency  Countermeasures  554 

23.45  In  Case  of  Contaminiation  555 

23.5  Additional  Reading  556 

Discussion  and  Review  Questions  556 

Suggested  Answers  557 

Objective  Te«^t  559 


ERLC 


557 


538  Water  Treatment 


OBJECTIVES 

Chapter  23.  ADMINISTRATION 

Following  completion  of  Chapter  23.  you  should  be  able 
to. 

1.  Organize  the  general  operation,  maintenance  and  admin- 
istrative activities  of  a  wate^  utility, 

2.  Explain  the  importance  of  and  need  for  operator  certifica- 
tion, 

3.  Develop  and  implement  a  public  relations  program, 
4  Prepare  a  contingency  plan  for  emergencies, 

5.  Collect,  organize,  file,  retrieve,  use  and  dispose  of  plant 
records,  and 

6.  Successfully  operate  and  maintain  the  water  supply  and 
water  treatment  facilities  of  your  utility  agency. 


ERIC 


553 


Administration  539 


CHAPTER  23.  ADMiNiSTRATiON 


Administering  the  operation  and  maintenance  of  a  water 
treatment  plant  involves  more  than  just  the  technical  aspects 
of  plant  operations.  Supervision,  recordkeeping,  emergency 
planning,  public  relations,  and  ordering  supplies,  for  exam- 
ple, ars  all  necessary  parts  of  the  overall  operation  of  a 
water  tre^uTient  plant  facility.  Whether  an  individual  is  a  chief 
operator  or  novice,  he  or  she  should  at  least  have  a  general 
Idea  of  the  administrative  procedures  associated  with  treat- 
ment plant  operations. 

23.0  OFFICE  PROCEDURES 

23.00  Budgeting 

Budgeting  is  the  art  of  predicting  the  amount  of  money 
necessary  to  achieve  an  organization's  goals.  Preparation 
of  a  budget  requires  effective  planning.  Planning  and  bud- 
geting are  both  •'essential  administrative  functions.  Planning 
identifies  your  goals,  and  budgeting  identifies  how  much 
money  is  needed  to  achieve  these  goals. 

Planning  involves  designing  programs,  setting  goals  and 
objectives,  and  making  basic  policy  decisions  for  the  organi- 
zation as  a  whole.  Budgeting,  on  the  other  hand,  involves 
analyzing  the  many  functions  that  the  organization  must 
perform  to  implement  each  program.  Table  23.1  illustrates 
the  relationship  between  planning  and  budgeting.  Notice 
that  a  third  component,  evaluation,  is  needed  to  determine 
whether  the  goals  and  plans  that  have  been  set  are  reason- 
able and  achievable  in  terms  of  the  money  available.  Ideally, 
these  three  components  form  a  dynamic  process  in  which 
your  goals  and  the  budget  are  periodically  reviewed  and 
revised  to  reflect  a  realistic  assessment  of  your  organiza- 
tion's priorities  and  financial  resources. 


In  prepanng  a  budget,  value  judgments  muct  be  made 
about  t'le  efficiency  of  your  operations.  You  should  con- 
stantly re-evaluate  your  operating  procedures  to  consider 
more  efficient  use  of  personnel  and  materials.  When  making 
these  value  judgments,  examine  how  better  operating  re- 
sults can  be  attained  through  more  efficient  opprating  proce- 
dures. In  examining  personnel  requirements,  determine  if 
personnel  could  be  reassigned  to  perform  more  tasks  more 
efficiently  Look  for  ways  to  reduce  the  expenses  for  power 
and  fusl.  All  phases  of  your  operation  and  maintenance 
should  be  carefully  examined  to  prepare  an  accurate  and 
realistic  budget.  Failure  to  do  so  will  generally  result  in  waste 
and  inefficiency.  Preparation  of  the  budget  should  not  be 
viewed  as  a  paper  exercise  but  as  a  means  of  achieving 
specified  goals,  improving  performance  standards,  and  rais- 
ing the  quality  of  services  to  your  community. 

Budget  preparation  should  be  a  group  project  and  effort. 
Preparing  a  budget  with  staff  involvement  will  create  an 


TABLE  23.1    PLANNING  AND  BUDGETING  RELATIONSHIP 


PLANNING 
Establishes  plans  and 
programs 

Sets  goals  and  objectives 

Makes  basic  policy  decisions 
^     


I 
I 
I 
I 
I 
I 
f 
I 
I 
I 


Revisions 


Periodic  Review 


BUDGETING 
Determines  costs  to 
achieve  plans 


Final 

Budget  and 
Operating  Plan 


EVALUATION 
Tests  budget  against  plan 
Determines  tradeoff  between 
goals  and  costs 


553 


540  Water  Treatment 


atmosphere  of  interest  and  a  f  eel'ng  of  active  participation  In 
one  of  the  most  Important  annual  activities  of  a  water  utility. 
Staff  personnel  can  actively  participate  in  the  budget  pro- 
cess by  providing  information  on  operating  requirements. 
Moreover,  new  programs,  positions,  and  equipment  that  are 
contemplated  should  be  thoroughly  researched  and  justified 
by  staff  to  facilitate  the  budgetary  process. 

For  large  and  small  utilities  alike,  the  amount  of  anticipat- 
ed income  is  also  an  important  factor  in  budgeting.  Using  the 
previous  year's  budget  and  actual  income  for  that  year  can 
give  you  a  good  idea  of  what  program  increases  might  be 
feasible  for  the  future. 

After  the  budget  is  approved,  it  should  be  reviewed  by 
staff  members  who  have  budget-related  responsibilities  to 
give  them  a  clear  understanding  of  the  organization's  finan- 
cial constraints  for  the  upcoming  year. 

An  excellent  too!  to  help  you  control  and  monitor  the 
organization's  operations  is  the  monthly  budget  status  re- 
port. It  is  good  management  practice  to  compare  expendi- 
tures with  budgeted  amounts  at  frequent  regular  intervals. 
Also  evaluate  your  present  financial  status  in  terms  of  the 
amount  of  the  year  that  has  passed  and  the  pace  of 
expenditures.  Figure  23.1  is  an  example  of  a  budget  status 
report.  A  prudent  administrator  will  always  take  care  to 
thoughtfully  analyze  expenditures  so  that  the  budget  is  not 
exceeded. 

CURRENT 


23.01   Water  Rates 

The  process  of  determining  the  cost  of  water  and  estab- 
lishing a  water  rate  schedule  for  customers  is  a  subject  of 
much  controversy.  There  is  no  single  set  of  rules  for 
determining  water  rates.  The  establishment  of  a  rate  sched- 
ule involves  many  factors  including  the  form  of  ownership 
(investor  or  publicly  owned),  differences  in  regulatory  control 
over  the  water  utility  (state  commission  or  local  authority), 
and  differences  in  individual  viewpoints  and  preferences 
concerning  the  appropriate  philosophy  to  be  followed  to 
meet  local  conditions  and  requirements. 


NAriE 

4252  ENGR  &  ARCH 
4258  OTR  PROF  SVC" 
4260  INTDEP  ALLOC 
TRA?j5P0RTNT 

4262  rlEAlr 

4263  LODGH^G 
4270  MBR  FEE.'? 


4271  NEWSPAPERS 

4272  REGIST  &  TUT 
4276  AUTO  ALLOW 
45^C0nP  IIAK  EX 

4292  PROP  UVJ  PRE 

4293  GRIM  lt\S  m> 
"^32f  BANK  FEES 
4376  COWTR  TYPE  1 
4401_CHErt  GASES 
4403  FOOD  (HUHAi<) 

441 1  ore  SPY  -Jt  MT 

4412  ENGR  DRFT 
4422  "JANITORIAC 
4431  SAFETY  EQUIP 
4433  PHOTO  SUPPLY 
4435  AUDI 0/ VISUAL 
4443  ELECT  SUPPLY 
4453  BOOKS  5.  PMPL 

446"1~SNAt:^0OLS  

4462  COrtPTR  SUPLY 
4471  CONSTR  SUPL 
448rVEHCLE  ACCES 

CLASS  SUBTOTAL  2:\>* 


4630  hACH  &  EOUr 
4632 'HEU  \:HICLS;S 

CLASS  SUBTOTAL  4FA 


MClDIFIED 

ENCUMBERED 

EXPENDED 

TOTAL 

UNOBLIGATED 

BUDGET 

AMOUNT 

i^MOUNT 

OBLIGATIONS 

AflCT 

PERCENT  USED 

5,000 

30,565 

4,434 

34,999 

-2<? ,  999 

95:500  "  ' 

0 

37,S'14 

37,5i4 

55,985 

244,407 

0 

81,469 

81 ,469 

162,938 

33-33 

1  ,500 

0 

147 

147 

1,353 

9-80 

700 

0 

21 

21 

^79 

3-00 

1 ,500 

0 

54 

54 

1,446 

3-60 

4,200 

0 

3,179 

3, 179 

1  ,020 

75.70 

200 

0 

307 

307 

-107 

5,000 

0 

659 

659 

4,341 

13-13 

1 , 800 

0 

750 

750 

1 ,050 

41-67 

124.000 

0 

0 

0 

< 24,000 

-00 

87,600 

0 

0 

0 

87.600 

.00 

0 

0 

0 

400 

-00 

"1.000 

0 

563 

563 

436 

56.34 

1 30 , 000 

0 

3,450 

3,450 

126/550 

2-65 

-     —  9 

0 

4 

4 

-4 

.00 

0  ' 

0 

17" 

137 

M3V 

.00 

2,200 

0 

2,088 

2,083 

111 

94.93 

200 

200 

0 

200 

0 

"  200"~ 

0  -  - 

69 

6y 

130 

^4-  /  J. 

0 

0 

3 

3 

-3 

.00 

50 

64 

64 

-14 

"     ~ "1,000 

0- 

47 

49 

VbO 

4-y  / 

0 

0 

38 

38 

-38 

-00 

300 

0 

99 

99 

200 

33.31 

6~f40"~ 

53r-- 

1 ,906 

2,43/ 

3,702  — 

3y-  ^0 

4.395 

476 

1,560 

2,037 

2,357 

46-35 

0 

0 

7 

7 

-7 

-00 

 0— 

 - 

3 

3 

-J 

-00 

471 0  CIP  LBR  REJM 
CLASS  SUBTOTAL  5CP 

ORC^roTAi:  — 


777.292 

21 .765 
9,000 


30.765 
0 

0 

5",5f6-,010 


407  ors" 

0 

y 


0 

40.016 


T55-.'807-' 

13,681 

 0 


-f  95, 824" 

13,681 
 0 


501 ,467 

8,084 
— 97000" 


"2571?- 
62-86 

— :oo' 


T3768i 
-978 


-r3r6Br 

-978 


'f7,084- 
978 


"4^T47' 
.00 


-978 
"4287594- 


-978 
"468,61  r 


978 

1  ,oy;,398" 


-00 
"30712- 


ERIC 


Fig,  23. 1  Budget  status  report 

560 


Administration  541 


Generally,  the  development  of  water  rate  schedules  in- 
volves the  following  procedures: 

•  A  determination  of  the  total  revenue  requirements  for  the 
period  that  the  reies  are  to  be  effective  (usually  one 
year). 

•  A  determination  of  all  the  cost  components  of  system 
operations.  That  is,  how  much  does  it  cost  to  treat  the 
water'?  How  much  does  it  cost  to  distHbute*?  How  much 
does  it  cost  to  install  a  water  service  to  a  customer'?  How 
much  are  administrative  costs? 

•  Distribution  of  the  various  component  costs  to  the  var- 
ious customer  classes  in  accordance  with  their  require- 
ments for  service. 

•  The  design  of  water  rates  that  will  recover  from  each 
class  of  customers,  within  practical  limits,  the  cost  to 
serve  that  class  of  customers. 

Sales  of  water  to  customers  may  be  metered  or  unme- 
tered  In  the  case  of  metered  sales,  the  charge  to  the 
customer  is  basec*  on  a  rate  schedule  applied  to  the  amount 
of  water  used  through  each  water  meter.  If  meters  are  not 
used,  the  charge  per  customer  Is  based  on  a  flat  rate  per 
period  of  time  per  fixtLi»'e,  foot  of  frontage,  number  of  rooms, 
or  other  measurable  unit.  Although  the  flat  rate  basis  still  Is 
fairly  common,  meter-based  rates  are  more  widely  used. 

See  SMALL  WATER  SYSTEM  OPERATION  AND  MAIN- 
TENANCE, Chapter  8,  "Setting  Water  Rates  for  Small  Water 
Utilities,"  for  an  explanation  and  examples  of  how  to  deter- 
mine and  set  water  rates.  This  publication  is  available  from 
Ken  Kerri,  Office  of  Water  Programs,  California  State  Uni- 
versity, Sacramento,  6000  J  Street,  Sacramento,  CA  95819. 
Price,  $20.00. 

23.02  Procurement  of  Material 

Ordering  repair  parts  and  supplies  usually  is  done  when 
the  on-hand  quantity  of  a  stocked  part  or  cnemical  falls 


below  the  reorde''  point,  a  new  item  is  added  to  stock,  or  an 
item  has  been  requested  that  is  not  stocked.  Most  organiza- 
tions require  employees  to  submit  a  requisition  (similar  to 
the  one  shown  in  Figure  23.2)  when  they  need  to  purchase 
equipment  or  supplies.  When  the  requisition  has  been 
approved  by  the  authorized  person  (a  supervisor  or  pur- 
chasing agent,  in  most  cases)  the  items  are  ordered  using  a 
form  called  a  purchase  order.  A  purchase  order  contains  a 
number  of  important  items.  These  items  include:  (1)the  date, 

(2)  a  complete  description  of  each  item  and  quantity  needed, 

(3)  prices,  (4)  the  name  of  the  vendor,,  and  (5)  a  purchase 
order  number. 

A  copy  of  the  purchase  order  should  be  retained  in  a 
suspense  file  or  on  a  clipboard  until  the  ordered  items  arrive. 
This  procedure  helps  keep  track  of  the  items  that  have  been 
ordered  but  have  not  yet  been  received. 

All  supplies  should  be  processed  through  the  storeroom 
immediately  upon  arrival.  When  an  item  is  received  it  should 
be  so  recorded'on  an  inventory  card.  The  inventory  card  will 
keep  track  of  the  numbers  of  an  item  in  stock,  when  last 
ordered,  cost,  and  other  information.  F'jrthcfmore,  by  al- 
ways logging  in  supplies  immediately  upon  receipt,  you  are 
in  a  position  to  reject  defective  or  damaged  shipments  and 
control  shortages  or  errors  in  billing.  Some  utilities  use 
personal  computers  to  keep  track  of  orders  and  deliveries. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  557. 

23.0A  What  is  bidgeting'? 

23.0B  How  can  waste  and  inefficiency  be  reduced  or  elimi- 
nated'^ 

23.0C  List  the  important  items  usually  contained  on  a 
purchase  order. 


ERIC 


561 


COMMODITY 
CODE  nO 


CITY  OF  SACRAMENTO 

RfQUiSiTION 


«fcV 
COJT  CTR 


OeSCRtPTlON 


4  neouiiti tcN  no 


i  PU*^.  l*\C  OROtR  NO 


•0  nCFCR  OutiTlONS  TO 


VEnDORJ  uJfc  IMEJE  COLJ  OnLY 
'*     BRAND  OFftRED  "  LOT  PRiCE  hOPtACMITtM 


iOlil   Of  COiT 


NUMdLR  OF 
RLOUIJ  TiOn 
ATTACHMtNT 


THIS  REQUISITION  WILL  BE  REPRODUCED  TD  CREATE  A 
PURCHASE  ORDER  QUICKLY  AND  PROVIDE  FASTER  DELIVERY 
OF  THESE  ITEMS  TO  YOUR  DEPARTMENT  PLEASE  FOLLOW 
INSTRUCTIONS  CAREFULLY 


iu8 
TOTAi 


SALES 
TAX 


J2  ipEClAl  RIOumtMtNTS  Oft  (NS!«UCTiONi    PRtviOuVPO  HO  OR  6(0  HO    OR  HECOmmEnOED  VEnDORV 


7)  CtftTiF(CAT(ON     HEREBY  mAC,£  THAI  Im£  abOvE  iS  A  j  £OaI  Charge  *OawJT  ThE  *PP«OPRia T IOn  InOiCaTEo 


OEPT  hEaO. 


OFfiClAt  riTlE 


INVOICE 
AMOUNT 


City  state  and  2:r- , 


rOB  DfSTiNAnON 


Fig  23.2  Purchase  order  form 


Administration  543 


23.03  Treatment  Plant  Records 
23,030  Purpose  of  Records 

Accurate  records  are  a  very  important  part  of  effective 
operation  of  a  water  treatment  plant  and  distribution  system 
facilities.  Records  are  a  valuable  source  of  information.  They 
can  save  time  when  trouble  develops  and  provide  proof  that 
problems  were  identified  and  solved.  Pertinent  and  comp'ete 
r^  xds  should  be  used  as  a  basis  for  plant  operation, 
interpreting  results  of  water  treatment,  preparing  preventive 
maintenance  programs  and  preparation  of  budget  requesii. 
When  accurately  kept,  records  orcvide  an  essential  basis  for 
des.gn  of  future  changes  or  expansions  ..f  the  treatment 
plant,  and  also  can  be  used  to  aid  in  the  design  of  other 
water  treatment  plants  where  similar  water  may  be  treated 
and  similar  problems  may  develop. 

If  legal  questions  or  prob'enis  occur  *n  connection  with  the 
treatment  of  the  water  or  the  operation  of  the  plant  accurate 
and  complete  records  will  provide  evidence  of  what  actually 
occurred  and  what  procedures  were  followed. 

Records  are  essential  for  effective  management  of  water 
treatment  facilities  and  to  satisfy  legal  requirements.  Some 
of  the  important  uses  of  records  include: 

1.  Aiding  operators  in  solving  treatment  and  water  quality 
problems 

2.  Providing  a  method  of  alerting  operators  to  changes  In 
source-water  quality, 

3.  Showing  that  the  treated  water  is  acceptable  to  the 
consumer, 

4.  Documenting  that  the  final  product  meets  plant  per- 
fornr.c^ce  standards,  as  well  as  the  standards  of  the 
regulatory  agencies, 

5.  Determing  performance  of  treatment  processes,  equip- 
ment, and  the  plant, 

6.  Satisfying  legal  requirements, 

7       .ng  in  answenng  complaints, 
8.  Anticipating  routine  maintenance. 


9  Providing  data  for  cost  analysis  and  preparation  of 
budgets. 

10  Providing  data  for  future  engineenng  designs,  and 

1 1  Providing  information  for  monti  'y  and  annual  reports. 

23,031   Types  of  Records 

There  are  many  different  types  of  records  that  are  re- 
quired for  effective  management  and  operation  of  water 
supply,  treatment  and  distribution  system  facilities.  Below  is 
a  listing  of  some  essential  records: 

1.  Source  of  supply, 

2.  'Operation, 

3.  t..aboratory, 

4.  Maintenance, 

5.  Chemical  inventory  and  usage, 

6.  Purchases, 

7.  Chlonnation  station, 

8.  Main  disinfection, 

9.  Cross-connection  control, 

10.  Personnel, 

11.  Accidents,  and 

12.  Customer  complaints. 


64 


544  Water  Treatment 


23.032  Types  of  Plant  Operations  Data^ 

Plant  operations  logs  can  be  as  different  as  the  plants  and 
water  systems  whose  information  they  record.  The  differ- 
ences in  amount,  nature,  and  format  of  data  are  so  signifi- 
cant that  any  attempt  to  prepare  a  "typical"  log  would  be  very 
difficult.  This  section  will  outline  the  kinds  of  data  that  are 
usually  required  to  help  you  develop  a  useful  log  for  your 
facilities. 

Treatment  plant  data  such  as  total  flows,  chemical  use, 
chemical  doses,  filter  perforn  ance,  reservoir  levels,  quality 
control  tests,  and  rainfall  and  '•off  information  represent 
the  bulk  of  the  data  required  for  proper  plant  operation. 
Frequently,  however,  source  and  distribution  system  data 
such  as  reservoir  storage  and  water  quality  data  are  includ- 
ed because  of  the  impact  of  this  information  on  plant 
operation  and  operate  esponsibilities.  Typical  plant  oper- 
ations data  include: 

1.  Plant  title,  agency  and  location; 

2.  Date. 

3.  Names  of  ope.ators  and  supervisors  on  duty; 

4.  Source  of  supply. 

a.  Reservoir  elevation  and  volume  of  storage. 

b.  Reservoir  inflow  and  outflow, 

c.  Evaporation  and  precipitation. 

d.  Apparent  runoff,  seepage  loss,  or  infiltration  gam, 
and 

e.  Production  figures  from  wells; 

5.  Water  treatment  plant, 

a.  Plant  Inflow, 

b.  Treated  water  flow, 

c.  Plant  operating  water  (backwash),  and 

d.  Clear  well  level; 

6.  Distribution  system, 

a.  Flows  to  system  (system  demand), 

b.  Distribution  system  respj^voir  levels  and  change^, 
and 

c.  Companson  of  production  with  del.veries  (unac- 
counted for  watery, 

7.  Chemical  inventory  and  usage, 

a.  Chemical  inventory/storage  (measured  use  and  de- 
liveries), 

b.  Metered  or  estimated  plant  usages,  and 

c.  Calculated  usage  of  chemicals  (compare  with  actual 
use): 

8.  Quality  control  tests, 

a.  Turbidity, 

b.  Chlorine  residual, 

c.  Coliforms, 

d.  Odor, 

e.  Color,  and 
f  Other; 

9.  Filter  performance, 
a.  Operation, 

(1)  Total  hc'jrs,  all  units, 

(2)  Filtered  water  turbidities, 

(3)  Head  losses, 

(4)  Levels,  and 

(5)  Flow  rates; 


b  Backwash, 

(1)  Total  hours, 

(2)  Head  losses, 

(3)  Total  washwater  used,  and 

(4)  Duration  and  rate  of  back/surface  wash. 

10  Meteorologic. 

a  Rainfall,  evaporation,  and  temperature  of  both  water 

?nd  air.  and 
b.  Weather  (clear.  v*'oudy,  windy): 

11  Remarks 

Space  should  be  p  D^'ided  to  descnbe  or  explain  unusu- 
al data  or  events.  Extensive  notes  should  be  entered  on 
a  daily  worksne?t  or  diary. 


23.033  Maintenance  Records 

A  good  plant  maintenance  effort  depends  heavily  upon 
good  recordkeeping.  There  are  several  areas  where  proper 
records  and  documentation  Ccin  definitely  improve  overall 
plant  performance. 

23.034  Inventory  Records 

An  inventory  consists  of  the  supplies  the  treatment  plant 
needs  to  keep  on  hand  to  operate  the  facility.  These  mainte- 
nance supplies  may  include  repair  parts,  spare  valves, 
-^lectricaj  supplies,  tools,  and  lubricants.  The  purpose  of 
maintaining  an  inventory  is  to  provide  needed  parts  and 
supplies  quickly,  thereby  reducing  equipment  downtime  and 
work  delays. 

In  deciding  what  supplies  to  stock,  keep  in  mind  the 
economics  involved  in  buying  and  stocking  an  item  as 
opposed  to  depending  upon  outside  availability  to  provide 
needed  supplies.  Is  th^  item  critical  to  continued  plant  or 
process  operation?  S,  uld  certain  frequently  used  repair 
parts  be  kept  on-hand?  Does  the  item  have  a  shelf-life? 

Inventory  costs  can  be  held  to  a  minimum  by  keeping  on 
hand  only  those  parts  and  supplies  for  which  a  definite  need 
exists  or  which  would  take  too  long  to  obtain  from  an  outside 
'/endor.  A  "definite  need**  for  an  item  is  usually  demonstrated 
by  a  history  of  regular  use.  Some  items  may  be  infrequently 
used  but  may  be  vital  in  the  event  of  an  emergency;  these 
items  ohould  also  be  stocked.  Take  care  to  exclude  any 
parts  and  supplies  that  niay  become  obsolete,  and  do  not 
stock  parts  for  equipment  scheduled  for  replacement. 


^  Also  see  Chapter  10,  Plant  Operation,  Section  10.6,  "Operating  Records  and  Reports, "  for  additional  details  and  recordkeeping  forms. 

...v  565 


Administration  545 


Tools  should  be  inventoried.  Tools  that  are  u^ad  by 
operators  on  a  daily  basis  should  be  permanently  signed  out 
to  them.  More  expensive  tools  and  tools  thai  are  only 
occasionally  used,  however,  should  be  kept  in  a  storeroom. 
These  tools  should  be  signed  out  only  when  needed  and 
signed  back  in  immediately  after  use. 

23.035  Equipment  Records 

You  w'M  need  to  keep  accurate  records  to  monitor  the 
operation  and  maintenance  of  plant  equipment.  Equipment 
control  cards  and  work  orders  can  be  used  to: 

^  Record  Important  equipment  data  such  as  make,  model, 
serial  number,  and  date  purchased, 

•  Record  r'^alntenance  and  repair  work  performed  to  date, 

•  Anticipate  preventive  maintenance  nee  is,  and 

•  Schedule  future  maintenance  work. 

23.036  Disposition  of  Plant  Records 

Good  recordkeeping  is  very  important  because  records 
indicate  potential  problems,  adequate  operation,  and  are  a 
good  waterworks  practice.  Usually  the  only  records  required 
by  the  health  agency  is  the  summary  of  the  daily  turbidity  of 
the  treated  surface  water  as  it  enters  the  distribution  system. 
Chlorine  residual  and  bacterial  coi'nts  are  often  required. 
Other  records  that  may  also  be  required  Include: 

1.  Total  trihalomethane  (TTHM)  data  (frequency  of  this 
report  Is  based  on  the  number  of  people  served), 

2.  The  daily  log  and  records  of  the  analyses  to  control  the 
treatment  process  may  be  required  when  there  are 
chronic  treatment  problems, 

3.  Chlorination,  constituent  removal,  and  sequestering  rec- 
ords may  be  required  from  small  systems  (especially 
those  demonstrating  tittle  understanding  of  the  proc- 
esses), and 

4.  Records  showing  the  quantity  of  water  from  each  source 
In  use  may  be  required  from  systems  with  sources 
producing  water  not  meeting  state  and/or  local  health 
department  water  quality  standards. 

An  imp'  '^t  question  is  how  long  records  should  be  kept. 
Records  bnould  be  kept  as  long  as  they  may  be  useful. 
Some  information  will  become  useless  after  a  short  time, 
while  other  data  may  be  valuable  for  many  years.  Data  that 
might  be  used  for  future  design  or  expansion  should  be  kept 
indefinitely.  Laboratory  data  will  always  be  useful  and  should 
be  kept  Indefinitely.  Regulatory  agencies  may  require  you  to 
keep  certain  water  quality  analyses  (bacteriological  test 
results)  and  customer  complaint  records  on  file  for  specified 
time  periods  (10  years  for  chemical  analyses  and  bacteri- 
ological tests). 

Even  if  old  records  are  not  consulted  every  day,  this  does 
not  lessen  their  poioiitial  value.  For  orderly  records  handling 
and  storage,  set  up  a  schedule  to  periodically  review  old 
reviews  and  to  dispose  of  those  records  that  are  no  longer 
needed.  A  decision  can  be  made  when  a  record  Is  estab- 
lished regarding  the  time  period  for  which  it  must  be  re- 
tained. 

QUESTIONS 

Write  your  answers  In  a  nctelx)ok  and  then  compare  your 
answers  with  those  on  page  557. 

23.0D  List  some  of  the  Important  uses  of  records. 

ERLC 


23.0E  What  is  "unaccounted  for  water?" 

23.0F  What  chemical  inventory  and  usage  records  should 
be  kept? 

23.04  Organizatfonai  Planning 

A  definite  plan  of  organization  Is  essential  to  effectively 
operate  a  water  treatment  plant.  Operators  and  othur  per- 
sonnel need  to  understand  their  respective  positions  and 
duties  in  the  whole  picture  of  management.  Only  then  can 
they  devote  their  full  time  and  energy  to  the  effective 
discharge  of  their  proper  functions  while  avoiding  duplica- 
tion of  effort  and  the  confusion,  interpersonal  friction  and 
working  at  cross  purposes  which  could  result  from  the  lack 
of  a  clearcut  plan. 

The  need  for  a  plan  applies  to  both  small  and  large 
organizations.  In  fact,  a  clearly  defined  organizational  struc- 
ture may  be  even  more  important  in  a  small  utility  since  each 
operator  represents  a  greater  percentage  of  the  staff  and 
may  perform  a  wider  variety  of  functions. 


There  are  definite  guidelines  which  are  useful  in  develop- 
ment of  such  an  organizational  plan: 

1  Organization  should  be  based  specifically  upon  the  ob- 
jectives to  be  achieved  and  the  activities  to  be  performed, 

2.  Each  person  should  have  only  one  boss  and  all  direction 
and  guidance  should  come  from  that  supervisor, 

3  The  number  of  supervisory  levels  above  the  working  level 
should  be  kept  to  a  minimum, 

4  Each  supervisor  should  have  a  limited  number  of  people 
to  directly  supervise  (fewer  than  6), 

5.  Delegation  of  authority  should  be  as  complete  as  possi- 
ble with  the  lowest  levels  of  the  work  force  allowed  to 
make  as  manv  decisions  as  appropriate  to  that  level, 

6.  The  responsibility  for  performance  of  each  Individual 
should  be  pi3-determined  and  then  made  perfectly  ^*^ar 
to  the  individual  and  the  staff,  and 

7.  Lines  of  management  authority  must  be  maintained  and 
not  weakened  by  staff  or  functional  authority. 


-■'^  566 


546  Water  Treatment 


To  establish  an  organizatjonal  plan,  you  will  need  a  clear 
understanding  of  the  purposes  and  relationships  of  line  and 
staff  organizations.  Both  must  be  maintained  to  promote 
harmony  and  maximum  effec"veness. 

The  line  organization  is  the  chain  of  command  that  ex- 
tends from  the  manager  down  to  the  lowest  level  of  person- 
nel engaged  in  the  actual  operation  of  the  utility.  This  line 
organization  is  the  framework  for  directly  accomplishing  the 
objectives  of  the  water  utility  agency  or  company.  The 
personnel  in  these  positions  (Table  23.2)  are  responsible  for 
meeting  the  util  y's  objectives.  Without  clearly  defined  ob- 
jectives, the  line  organization  will  find  it  difficult  to  function 
effectively. 

The  staff  organization,  on  the  other  hand.  Is  not  in  the  line 
of  command.  Staff  consists  of  those  positions  that  exist  to 
provide  advice  and  service  to  the  line  personnel  to  assist 
them  in  carrying  out  their  objectives.  Secretaries,  reception- 
ists, clerks,  lawyers,  accountants,  and  purchasing  agents 
are  usually  considered  staff  personnel. 

Organizational  planning  should  be  reviewed  periodically  to 
eliminate  weaknesses,  strengthen  the  structure  and  in- 
crease the  effectiveness  of  management.  Remember  the 
following  points  when  considering  an  organizational  plan. 

1.  Organizations  may  gradually  change  to  meet  changing 
objectives,  and  must  have  regular  attention  if  a  logical 
pattern  is  to  be  maintained: 

2-  A  good  organizational  plan  is  only  a  tool  for  helping 
people  work  together.  The  plan  cannot  provide  for  suc- 
cessful performance  beyond  the  capabilities  of  the  group: 


3-  Organizational  planning  should  actively  include  all  levels 
of  the  organization: 

4-  The  organizational  plan  should  be  published  in  charts  and 
manuals  so  that  it  is  known  to  all  personnel: 

6.  Plat-je  nusit  be  tailored  to  a  specific  organization  and  its 
personnel  and  rarely  can  be  copied  from  another  utility 
without  seme  revisions; 

6.  Good  organizational  planning  can  be  measured  in  good 
operator  morale  and  effectiveness,  and  also  in  dollars 
and  cents  when  unnecessary  jobs  are  eliminated  and 
good  performance  is  encouraged:  and 

7.  A  good  organizational  plan  is  dynamic  and  should  be 
capable  of  changing  to  meet  the  abilities  of  the  operators 
and  the  objectives  of  the  utility. 

The  organization  should  strive  to  locate  weak  points  and 
io  meet  changing  requirements.  There  are  several  signs 
which  may  indicate  difficulties,  so  they  should  be  watched 
for.  The  following  are  some  of  these  signs. 

1  -  Physical,  mental  and  emotional  overloading  which  causes 
undue  fatigue, 

2.  Indecisiveness  in  management  which  delays  decision 
making, 

3.  Poor  teamwork  resulting  from  poor  supervisory  practices 
or  personal  inadequacies  of  a  supervisor,  and 

4.  Failure  to  train  subordinates  v^hlch  causes  problems 
when  supervisors  are  promoted  or  move  on  to  ar.other 
job. 


TA6V.E  23.2   EXAIVIPLE  OF  AN  ORGANIZATION  CHART 
FOR  A  PUBLICLY  OWNED  WATER  UTILITY 


L 


Director 

of 

Publ.'; 

Works 

Legal 
Assistance 


Water  Supply 
 Manager  i 


Accounting 


Source  of 
Supply  0  &  M 


Distribution 
System  0  &  M 


Punfication 


Treatment  Plant 
Superintendent 


Plant 
Operatou 


I  Laboratory 


ERIC 


5B7 


Administration  547 


QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  557. 

23.0G  List  the  guidelines  which  are  useful  in  development 
of  an  organizational  plan. 

23.Gri  What  is  the  primary  purpose  of  the  staff  organiza- 
tion? 

23.0!  rfow  does  management  benefit  from  organizational 
planning? 

23.0J  List  the  signs  that  may  indicate  .o  a  water  utility 
potential  weak  points  or  approaching  organizational 
problems. 

23.1   PERSONNEL  ADMINISTRATION 

Personnel  administration  Is  the  "people  side"  of  the  admin- 
istrative process.  Effective  personnel  administration  begins 
with  reasonable  policies  and  effective  supervisory  skills. 

23.10  Supennslon 

If  you  are  responsible  for  the  supervision  of  other  opera- 
tors, you  are  responsible  for  their  safety  and  also  their 
professional  development  Your  responsibilities  may  include 
assigning  tasks  to  specific  operators,  being  sure  they  under- 
stand the  assignnnent  and  know  how  to  do  the  job  safely, 
and  eventually  making  sure  that  the  job  was  done  properly. 
Also  as  a  supervisor  you  must  t>e  able  to  communicate 

effectively  with  your  supenors.  the  operators  you  supervise 
and  the  consumer  you  serve  To  be  a  successful  supervisor 
you  should: 

1 .  Know  how  to  do  your  job  and  the  jobs  you  expect  the 
operators  to  do  who  work  for  you. 

2.  Know  the  abilities,  knowledge,  skills  and  limitations  of  the 
operators  you  supervise. 

3  Have  sufficient  technical  knowledge  and  judgment  to 
know  v/hen  you  can  safely  make  necessary  technical 
decrions  and  when  you  need  to  call  for  the  advice  of  an 
expert 

4  Be  able  to  help  t'-«tn  the  ope.  ators  who  work  for  you.  both 
for  job  improve^  it  and  for  preparation  for  advancement 
m  the  organization. 

5  Be  a  good  representative  of  your  supervisor  and  your 
utility  agency. 

6.  Have  integrity  and  be  fair  and  objective  in  your  relations 
with  the  operators  who  work  for  you. 

7.  Be  cooperative  with  other  people  in  your  organization 
and  the  public. 

8.  Encourage  innovation  and  new  ideas, 

9.  Select  the  right  people  for  the  organization,  and 

10.  Provide  objective  recognition.  Praise  people  for  good 
performance  and  relate  rewards  to  performance,  not 
seniority  or  personal  relationships. 

When  a  person  t>ecomes  a  supervisor,  a  new  factor  enters 
the  picture — people.  Getting  other  people  to  do  what  needs 
to  be  done,  organizing  their  work,  and  motivating  them  is  as 
much  a  specialty  afi  any  other  kind  of  work  a  person  rnay 
have  previously  done.  When  individuals  move  into  a  supervi- 
sory position,  they  cross  an  important  line.  They  are  no 

O 

ERIC 


longer  judged  by  what  they  can  do  themselves  but  rather 
their  value  depends  upon  what  they  get  done  through 
others. 

Every  new  supervisor  must  learn  to  assign  to  other  people 
work  he  can  probably  do  better  himself.  And  as  anyone  in  a 
supervisory  position  knows,  delegating  to  others  is  no 
simple  task;  it  is  easier  said  than  done.  Four  mistakes  that 
new  supervisors  often  make  are: 

•  They  get  their  fingers  into  employees'  work  too  often. 

«  They  do  a  lot  of  work  themselves  that  employees  should 
be  doing. 

•  They  fail  to  train  and  coach  people  so  they  can  do  the  job 
as  well  as  the  supervisor  can. 

•  They  expect  too  much  of  those  who  work  for  them, 
especially  at  first. 


23.11  Staffing 

Obviously,  the  most  important  factors  which  will  influence 
the  Size  and  qualifications  of  staff  required  are  the  number 
of  services  and  also  the  size  and  complexity  of  the  treatment 
processes  and  facil'»'es  that  must  be  operated  and  main- 
tained Other  important  factors  might  include  age  and  condi- 
tion of  facilities  and  expected  population  growth  rates. 

Several  avenues  could  be  taken  to  determine  staffing 
requirements.  There  are  formulas  based  on  the  size  and 
complexity  of  facilities.  Another  possibility  is  to  determine 
staff  Size  based  on  population  served.  Perhaps  the  best 
approach  is  to  prepare  a  list  of  tasks  that  must  be  per- 
formed, how  long  it  will  take  to  do  each  task,  and  the 
knowledge  and  skills  required  to  perform  the  tasks.  Analysis 
of  this  information  will  provide  an  indication  of  the  qualifica- 
tions and  size  of  staff  needed  to  operate  and  maintain  your 
faciht  es 

Items  that  mi>st  be  considered  when  developing  sti-ffing 
reqijirements  include  the  work  load,  objectives  and  funds 
avaiiable.  The  size,  condition  and  complexity  of  facilities  will 
nave  a  greet  influence  on  the  work  loao.  Other  items  that 
should  be  considered  include  how  constant  is  the  work  load, 
are  there  seasonal  variations,  is  your  recordkeeping  system 
adequc  and  u.3-to  date,  and  are  all  maintenance  activities 
scheduled  as  e^^icier/Jy  as  possible.  Today  in  many  areas 
population  growth  is  a  fa-t  of  life.  Plans  must  b  made  for 
staff  and  facilities  to  be  capable  of  providing  sufficient 
potable  water  and  distnbution  system  pressures  as  growth 
occurs  Records  that  substantiate  efficient  use  of  existing 

568 


548  Water  Treatment 


staff,  productivity  of  staff,  and  a  positive  need  for  future  staff 
a<  e  most  helpful. 

Important  questions  to  be  answered  m  relation  to  staffing 
are  Whai  are  your  objectives'?"  and  "What  level  of  mainte- 
nance do  you  plan  for  your  facilities'?''  A  typical  objective 
might  be  to  deliver  potable  water  at  adequate  pressures  to 
consumers  at  the  lowest  possible  cost  year  after  year  Once 
you  have  identified  your  objectives  and  determined  how  well 
they  are  being  met  now.  you  can  decide  how  to  do  a  better 
jOb  and  the  staffing  needed  to  accomplish  your  objectives. 
During  budget  hearings  you  can  present  graphs  or  charts 
showing  how  you  are  doing  and  what  you  could  accomplish 
with  a  better  trained  and/or  larger  staff. 

Available  funding  is  another  Important  factor  that  must  be 
faced  when  acquiring  the  staff  you  need  to  operate  and 
maintain  your  facilities.  Whatever  objectives  you  may  devel- 
op, or  however  extensive  an  operation  and  maintenance 
program  you  devise,  you  will  probably  be  restricted,  to  some 
deyee,  by  the  amount  of  funds  available. 

Fortunately  e  amount  of  funds  available  does  not  have 
to  be  the  sole  determining  factor  in  the  implementation  of 
your  desired  operation  and  maintenance  programs.  Hope- 
fully, in  this  course,  you  have  learned  the  value  of  good 
records.  As  an  indicator  of  the  existing  condition  of  your 
facilities,  and  as  proof  of  cost-effective  improvement,  re- 
cords can  justify  additional  funding  when  it  is  warranted. 

23*12  Training 

A  prime  responsibility  of  every  supervisor  is  to  see  that  all 
operators  are  properly  trained  to  recognize  all  hazards  and 
to  effectively  accomplish  the  tasks  they  are  assigned.  Su- 
pervirors  must  motivate  operators  to  use  safe  procedures. 
This  section  lists  and  describes  possible  sources  and  types 
of  training  available  for  operators. 

1.  On  the  job.  Much  of  the  training  offered  or  given  in  the 
past  has  been  some  type  of  "on-the-job  training"  usually 
given  by  available  and  experienceo  operators.  This  type 
of  training  is  important  and  has  been  very  effective. 
Proof  of  its  effectiveness  is  indicated  by  the  fact  ♦hat 
many  consumers  have  received  potable  water  as  a 
result  of  the  efforts  of  such  training. 

One  possible  limitation  of  this  type  of  training  Is  that  it 
could  be  too  narrow  in  scope.  "Iri-house"  training  tends 
to  be  limited  to  local  conditions,  philosophies,  and 
experience  unless  the  instructor  makes  special  efforts 
to  broaden  the  scope.  Initial  safety  training  should  be 
completed  BEFORE  cn-the-job  training. 


4. 


2. 


3. 


Professional  magazines  and  papers.  Another  valuable 
source  o)  training  has  been  available  through  articles 
printed  in  local  or  national  professional  magazines. 
Local  or  area  waterworks  associations  periodically  pre- 
sent workshops  where  experienced  operators  offer 
papers  that  are  of  value  in  training  less  experienced 
people  in  the  operation  and  maintenance  of  waterworks 
facilities.  Such  workshops  make  Information  ava'^^Ne  to 
smaller  organizations  in  remote  areas  who  would  other- 
wise not  have  the  benefit  of  such  broad  experience. 

Formal  training.  Recently,  through  the  efforts  of  local 
and  state  waterworks  associations,  the  American  Water 
Works  Association,  and  the  U.S.  Environmental  Protec- 
tion Agency,  attempts  are  being  mado  to  make  formal 
training  available  to  all  operatois.  Such  trainiiig  also  is 
being  made  available  to  others  not  now  in  the  water- 
works field,  but  who  would  like  to  preoore  for  jobs  within 


the  field.  This  particular  training  course  is  a  r<?sult  of 
such  efforts. 

Informal  training.  Effective  training  techniques  include 
informal  meetings  using  drawings  from  available  materi- 
als, suppliers,  knowledge  of  experienced  crews  mem- 
bers, and  invited  guests  to  talk  over  how  to  do  specific 
jobs.  Suppliers  are  often  available  to  train  new  operators 
and  retrain  existing  operators  on  use  of  equipment. 

Training  for  supervisors.  Every  manager  and  supervisor 
must  develop  a  personal  cc':tinulng  education  program. 
Managers  must  keep  up  to  c'ate  with  technical  advances 
in  their  field  and  also  develop  management  skills. 

A  supervisor  snould  participate  in  whatever  training  is 
available  NOW.  As  suggested  in  this  section,  it  is  possi- 
ble to  train  crews  to  perform  effectively  even  without 
formal  training  aids.  It  is  inefficient  supervision  to  assign 
crews  to  perform  work  without  some  form  of  auequate 
training.  The  lack  of  formal  courses  or  training  material 
does  not  make  adequate  training  impossible,  it  only 
makes  it  more  difficult. 


23.13  People 


How  does  the  manager  or  administrator  deal  with  peoole? 
Everv  day  we  have  to  work  with  our  supervisors,  the  pu.DlfC, 
the  people  we  work  with  and  the  people  who  work  for  ns.  In 
this  nianual  we  have  tried  to  outline  how  to  get  the  job  done, 
how  to  create  a  climate  for  good  morale  and  how  to  provide 
training  opportunities  for  operators. 

A  very  highly  specialized  Jd  has  developed  on  how  to 
rnotivate  peopie,  deal  with  co-workers,  and  how  to  super- 
vise or  manage  people  /vorking  for  you.  We  believe  these 
are  complex  topics  that  are  beyond  the  scope  of  this 
manual.  If  you  have  a  need  for  or  wish  to  learn  more  on  how 
to  deal  with  people,  we  suggest  enrolling  in  courses  or 
reading  books  on  supervision  or  personnel  management. 

QUESTIONS 

Write  your  answers  in  ^  notebook  and  then  compare  your 
answers  with  those  on  page  557. 

23.1  A  What  are  the  responsibilities  of  a  suj.drvisor? 

23.1  B  List  the  important  factors  v/hich  will  influence  the  size 
and  qualifications  of  staff  required  by  a  water  utility 
agency. 

23.1  C  What  should  ooerators  be  trained  to  do? 


569 


Administration  549 


23.14  Operator  Certif 'cation 

23. 140  Need  for  Certified  Operators 

Virtually  all  states  and  Canadian  provinces  require  that  a 
certified  operator  be  in  charge  of  a  utility  agency's  water 
supply  system  and  water  treatment  plant.  Water  supply  and 
treatment  facilities  are  often  classified  on  the  basis  of  th< 
number  of  services  and/or  the  capacity  of  the  treatmen 
plant  as  well  as  on  the  complexity  of  the  treatment  pro- 
cesses in  the  plant.  This  classification  and  the  size  of  the 
plant  usually  determine  the  numbers  and  grade  levels  of 
certified  operators  needed  by  the  plant.  To  qualify  for  higher 
levels  of  certification,  operatojs  need  greater  combinations 
of  education  and  experience.  Education  may  be  obtained  by 
attending  technical  schools,  community  colleges,  short 
courses,  workshops,  and  successfully  completing  courses 
like  this  one.  Once  the  required  education  and  experience 
have  been  obtained  for  a  higher  level  of  certification,  the 
operator  must  successfully  pass  a  certification  examination. 
This  examination  is  based  on  what  the  operator  needs  to 
know  to  work  at  a  plant  with  a  specific  plant  classification. 
That  IS  to  say,  the  higher  the  certification  you  seek,  the  more 
extensive  the  test  will  be. 

23. 141  Why  Should  Water  Utility  Operators  Be  Certified? 

23.1410  Safety 

Certified  water  supply  system  and  treatment  plant  opera- 
tors earn  their  certif^'^ates  by  knowing  how  to  do  their  jobs 
safely.  Preparing  fo»  ^^jrtification  examinations  rs  one  means 
by  which  operators  learn  to  identity  safety  hazards  and  to 
follow  safe  procedures  at  all  times  under  all  circumstances. 

Although  it  is  extremely  important,  safety  is  not  the  sole 
benefit  to  be  derived  from  a  certification  program.  Other 
benefits  are  oescribed  below. 

23. 141 1  Protection  of  the  Public's  Investment 

Vast  sums  of  public  funds  have  been  invested  in  the 
construction  of  water  supply  and  treatment  ucilities.  Certifi- 
cation of  operators  assures  utilities  that  these  facilities  will 
be  operated  and  maintained  by  qualified  operators  who 
possess  a  certain  level  of  competence.  These  operators 
shoud  have  the  knowledge  and  skills  not  only  ♦o  prevent 
unnecessary  deterioraton  and  failure  of  the  facilities,  but 
also  to  improve  operation  and  maintenance  techniques. 

23.1412  En  oloyee  Pride  and  Recognition 

Achievement  of  a  level  of  certification  is  a  public  acknowl- 
edgment of  a  water  supoly  system  or  treatment  plant 
operator's  skills  and  knowledge.  Presentation  of  certificates 
at  an  official  meeting  of  the  governing  body  will  place  the 
operators  in  a  position  to  receive  recognition  for  their  efforts 
and  may  even  get  press  coverage  and  public  opinion  that  is 
favorable.  An  improved  public  image  will  give  the  certified 
operator  more  credibility  in  discussions  with  property  own- 
ers. 

Recognition  for  their  personal  efforts  will  raise  the  self- 
esteem  of  all  certified  operators.  Certification  will  also  give 
water  supply  system  and  treatment  plant  operators  an 
upgraded  image  that  has  been  too  long  denied  them.  If 
properly  publicized,  certification  ceremonies  will  give  the 
public  a  more  accurate  image  o\  the  many  dedicated,  well 
qualified  operators  working  for  them.  Certification  provides 
a  measurable  goat  that  operators  can  stnve  for  by  prepanng 
themselves  to  do  a  better  jOb.  Passing  a  certification  exam 

ERLC 


should  be  recognized  by  an  increase  in  salary  and  other 
employee  benefits. 


23.142  ABC 

ABC  Stands  for  the  Association  of  Boards  of  Certification 
for  Operating  Personnel  m  Water  Utilities  and  Pollution 
Control  Systems.  If  you  wish  to  find  out  how  to  become 
certified  <n  your  state  or  province,  contact: 

Executive  Director.  ABC 
Post  Office  Box  786 
Ames,  Iowa  50010-0786 
Phone:  (515)  232-3778 

ABC  will  provide  you  with  the  name  and  address  of  the 
appropnate  contact  person 

QUESTiONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  thoso  on  page  558. 

23.1  D  Name  several  ways  water  supply  and  treatment 
facilities  are  generally  classified. 

23.1  E  How  can  an  operator  achieve  tiigher  levels  of  certifi- 
cation? 

23.1  F  How  can  an  operator  find  out  how  to  become  certi- 

fied? 

23.2  PUBLIC  RELATIONS 

23.20  Establish  Objectives 

The  first  step  in  organizino  an  effective  public  relations 
campaign  is  to  establish  objectives.  The  only  way  to  know 
v/nether  your  program  is  a  success  is  to  have  a  clear  idea  of 
what  you  expect  to  achieve — for  example,  better  customer 
relations,  greater  yvater  conservation,  and  enhanced  organi- 
zational credibility.  Each  objective  must  be  specific,  achiev- 
able, and  measurable.  It  is  also  important  to  know  your 
audience  and  tailor  various  elements  of  your  public  relations 
effort  to  specific  groups  you  wish  to  reach,  such  as  commu- 
nity leaders,  school  children,  or  the  average  customer.  Your 
objective  mav  be  the  same  in  each  case,  but  what  you  say 
and  how  you  say  it  will  depend  upon  your  target  audience. 

23.21  Utility  Operations 

Good  public  relations  begin  at  home.  Dedicated,  service- 
onented  employees  provide  for  better  public  relations  than 


550  Water  Treatment 


paid  advertising  or  complicated  public  relations  campaigns. 
For  most  people,  contact  with  an  agency  employee  estab- 
lishes their  first  impression  of  the  competence  of  the  organi- 
zation, and  those  initial  opinions  are  difficult  to  change. 

In  addition  to  ensuring  that  employees  are  adequately 
trained  to  do  their  jobs  and  knowledgeable  alx)ut  the  utility's 
operations,  management  has  the  responsibility  to  keep 
employees  informed  about  the  organization's  plans,  prac- 
tices, and  goals.  Newsletters,  bulletin  boards,  and  regular, 
open  communication  between  supervisors  and  subordi- 
nates will  help  build  understanding  and  contribute  to  a  team 
spirit. 


Despite  the  old  adage  to  the  contrary,  the  customer  is  not 
always  right.  Management  should  try  to  instill  among  its 
employees  the  attitude  that  while  the  customer  may  be 
confused  or  unclear  about  the  situation,  everyone  is  entitled 
to  courteous  treatment  and  a  factual  explanation.  Whenever 
possible,  employees  should  phrase  responses  as  positively, 
or  neutrally  as  possible,  avoiding  negative  language.  For 
''xample.  "Your  complainf  is  better  stated  as  "Your  ques- 
tion". *you  should  have  ..."  is  likely  to  mcke  the  customer 
defensive,  while  "Will  you  please  ..."  is  courteous  and 
respectful.  "You  made  a  mistake"  emphasizes  the  negative, 
"What  we'll  do ..."  is  a  positive,  problem-solving  approach. 

23.22  The  Mass  Media 

We  'ive  in  tne  age  of  communications,  and  one  of  the  most 
eiferlive  and  least  expensive  ways  to  reach  people  is 
through  the  mass  media— radio,  television,  and  newspa- 
pers. Each  medium  has  different  needs  and  deadlines,  and 
obtaining  coverage  for  your  issue  or  event  is  easier  If  you 
are  aware  of  these  constraints.  Television  must  have  strong 
visualo.  for  example.  When  scheduling  a  press  conference, 
provide  an  interesting  setting  and  be  prepared  to  suggest 
good  shots  to  the  reporter.  Radio's  main  advantage  over 
television  and  newspapers  is  immediacy,  so  have  a  spokes- 
person available  and  prepared  to  give  the  interview  over  the 
telephone  if  necessary.  Newspapers  give  more  thorough.  In- 
depth  coverage  to  stories  than  do  the  broadcast  media,  so 
be  prepared  to  spend  extra  time  with  print  reporters  and 
provide  w.itten  backup  Information  and  additional  contacts. 

ERLC 


It  IS  not  difficult  to  get  press  coverage  for  your  event  or 
press  conference  if  a  few  simple  guidelines  are  followed: 

1.  Demonstrate  that  your  story  is  newsworthy,  that  it 
involves  something  unusual  or  interesting. 

2.  Make  sure  your  story  wiM  fit  the  targeted  format 
(television,  radio,  or  newspaper). 

3.  Provide  a  spokesperson  who  is  interesting,  articulate, 
and  well  prepared. 


23.23  Being  Interviewed 

Whether  you  are  preparing  for  a  scheduled  interview  or 
are  simply  contacted  by  ,he  press  on  a  breaking  news  story, 
here  are  some  key  hints  to  keep  in  mind  when  being 
interviewed. 

1.  Speak  in  persona*  terms,  free  of  institutional  jargon. 

2.  Do  not  argue  or  show  anger  if  the  reporter  appears  to 
be  rude  or  overly  aggressive. 

3.  If  you  don't  know  an  answer,  say  so  and  offer  to  find 
out.  Don't  bluff. 

4.  If  you  say  you  will  call  back  by  a  certain  time,  do  so. 
Reporters  face  tight  deadlines. 

5.  State  your  key  points  early  in  the  interview,  concisely 
and  clearly.  If  the  reporter  wants  more  information,  he 
or  she  will  ask  for  it. 

6.  If  a  question  contains  language  or  concepts  with 
which  you  dissjree.  don't  repeat  them,  even  to  deny 
them. 

7.  Know  your  facts. 

8.  Never  ask  to  see  a  story  before  it  is  printed  or 
broadcast.  Doing  so  indicates  that  you  doubt  the 
repoiter's  ability  and  professionalism. 


23.24  Public  Speaking 

Direct  contact  with  people  in  your  community  is  another 
effective  tool  in  promoting  your  utility.  Though  the  audiences 
tend  to  be  small,  a  personal,  face-to-face  presentation 
geneially  leaves  a  strong  and  long-lasting  impact  on  the 
listener. 

Depending  upon  the  size  of  the  organization,  your  utility 
may  wish  to  establish  a  speaker's  bureau  and  send  a  list  of 
topics  to  service  clubs  in  the  area.  Visits  to  high  schools  and 
college  campuses  can  also  be  beneficial,  and  educators  are 
often  looking  for  new  and  interesting  topics  to  supplement 
their  curriculum. 

Public  speaking  takes  practice.  It  is  important  to  be  well 
prepared  while  retaining  a  personal,  informal  style.  Find  out 
how  long  your  talk  is  expected  to  be,  and  don't  exceed  that 
time  frame.  H  ve  a  definite  beginning,  middle,  and  end  to 
your  presentation.  Visual  aids  such  as  charts,  slides,  or 
models  can  assist  In  conveying  your  message.  The  use  of 
humor  and  anecdotes  can  help  to  warm  up  the  audience  and 
build  rapport  between  the  speaker  and  the  listener.  Just  be 
sure  the  humor  is  natural,  not  forced,  and  that  the  point  of 
your  story  is  accessible  to  the  particular  audience.  Try  to 
keep  in  mind  that  audiences  only  expect  you  to  do  your  best. 
They  are  interested  in  learning  about  their  water  supply  and 
will  appreciate  that  you  are  making  a  sincere  effort  to  inform 
them  about  an  important  subject. 


571 


Administration  551 


23.25  Telephone  Contacts 

First  impressions  are  extremely  important,  and  frequently 
a  person's  first  contact  with  your  water  utility  is  over  the 
telephone.  A  person  who  answers  the  phone  In  a  courteous, 
pleasant,  and  helpful  manner  goes  along  way  toward  estab- 
lishing a  friendly,  cooperative  atmosphere. 

Following  a  few  simple  guidelines  will  help  to  start  your 
utility  off  on  the  right  note  with  your  customers: 

1 .  ANSWER  CALLS  PROMPTLY.  Your  conversation  will 
get  off  to  a  better  start  if  the  phone  is  answered  by  the 
third  or  fourth  ring. 

2.  IDENTIFY  YOURSELF.  This  a^ds  a  personal  note  and 
lets  the  caller  know  who  he  or  she  is  talking  to. 

3.  PAY  ATTENTION.  Don't  conduct  side  conversations. 
Minimize  distractions  so  you  can  give  the  caller  your 
full  attention,  avoiding  repetitions  of  names,  address- 
es, and  other  pertinent  facts. 

4.  MINIMIZE  TRANSFERS.  Nobody  likes  to  get  the  run- 
around.  Few  things  are  more  frustrating  to  a  caller 
than  being  transferred  from  office  to  office,  repeating 
the  situation,  problem  or  concern  over  and  over  again. 
Transfer  only  those  calls  that  must  be  transferred,  and 
make  certain  you  are  referring  the  caller  to  the  right 
person.  Then,  explain  why  you  are  transferring  the 
call.  This  lets  the  caller  know  you  are  referring  him  or 
her  to  a  co*worker  for  a  reason  and  reassures  the 
customer  that  the  problem  or  question  will  be  dealt 
with.  In  some  cases,  it  may  be  better  to  take  a 
message  and  have  someone  return  the  call  than  to 
keep  transferring  the  customer's  call. 

23.26  Consumer  InqtMiies 

No  single  set  of  rules  can  possibly  apply  to  all  types  of 
consumer  questions  or  complaints  about  water  quality  and 
serv.ee.  There  are,  however,  basic  principles  to  follow  in 
responding  to  inquires  and  concerns. 

1.  BE  PREPARED.  Your  employees  should  be  familiar 
enough  with  your  utility's  organization,  services  and 
policies  to  either  respond  to  the  question  or  complaint 
or  locate  the  person  who  can. 

2.  LISTEN.  Ask  the  customer  to  describe  the  problem 
and  listen  carefully  to  the  explanation.  Take  written 
notes  of  the  facts  and  addresses. 

3.  DON'T  ARGUE.  Callers  often  express  a  great  deal  of 
pent-up  frustration  in  tiieir  contacts  with  a  utility.  Give 
the  caller  your  full  attention.  Once  you've  heard  them 
out,  most  people  will  calm  down  and  state  their 
problems  in  more  reasonable  torms. 

4.  AVOID  JARGON.  The  average  consumer  lacks  the 
technical  knowledge  to  understand  the  complexities 
of  water  quality.  U^e  plain,  non-technical  language 
and  avoid  telling  the  consumer  more  than  he  or  she 
needs  to  know. 


5.  SUMMARIZE  THE  PROBLEM.  Repeat  your  under- 
Standing  of  the  situation  back  to  the  caller.  This  will 
assure  the  customer  that  you  understand  the  problem 
and  offer  the  opportunity  to  clear  up  any  confusion  or 

missed  conf:munication. 

6.  PROMISE  SPECIFIC  ACTION.  M  jke  an  effort  to  give 
the  customer  an  immediate,  clear,  and  accurate  an- 
swer to  the  problem.  Be  as  specific  as  possible, 
without  overstepping  your  authority  or  promising 
something  you  can't  deliver. 

In  some  cases,  you  may  wish  to  have  a  representative  of 
the  utility  visit  the  customer  and  observe  the  problem  first 
hand.  If  the  complaint  involves  water  quality,  take  samples  if 
necessary  and  report  back  to  the  customer  to  be  sure  the 
problem  has  oeen  resolved. 

Complaints  can  be  a  valuable  asset  in  determining  con- 
sumer acceptance  and  pinpointing  water  quality  problems. 
Customer  calls  are  frequently  your  first  indication  that  some- 
thing may  be  wrong.  Resoonding  to  complaints  and  inquiries 
promptly  can  save  the  utility  money  and  staff  resources,  and 
minimize  the  number  of  customers  who  are  inconvenienced. 
Still,  education  can  greatly  reduce  complaints  about  water 
quality.  Information  brochures,  utility  bill  inserts,  and  other 
educational  tools  help  to  inform  customers  and  avoid  future 
complaints. 

23.27  Plant  Tour;. 

Tours  of  water  treatment  p.  4nts  can  be  an  excellent  way  to 
inform  the  public  about  your  utility's  efforts  to  provide  a  safe, 
high  quality  water  supply.  Political  leaders,  such  as  the  City 
Council  and  members  of  the  Board  of  Supervisors,  should 
be  invited  and  encouraged  to  tour  the  facilities,  as  should 
school  groups  and  service  clubs. 

A  brochure  describing  your  utility's  goals,  accomplish- 
ments,  operations,  and  processes  can  he  a  good  supple- 
ment to  the  tour  and  should  be  handed  out  at  the  end  of  the 
visit.  The  more  visually  interesting  the  brochure  is,  the  more 
likely  that  it  will  be  read,  and  the  use  of  color,  photographs, 
graphics  or  other  design  features  is  encouraged.  If  you  have 
access  to  the  necessary  equipment  production  of  a  video 
tape  program  about  the  utility  can  also  add  interest  to  the 
facility  tour. 


erJc 


The  tour  Itself  should  be  conducted  by  an  employee  who 
is  very  familiar  with  plant  operations  and  can  answer  the 
types  of  questions  that  are  likely  to  arise.  Consider  includ- 
ing: 

1 .  A  description  of  the  sources  of  water  supply, 


572 


552  Water  Treatment 


2.  History  of  the  plant,  the  years  of  operation,  modifica- 
tions and  innovations  over  the  years, 

3.  Major  plant  design  features,  including  plant  capacity 
and  safety  features, 

4.  Observation  of  the  treatment  processes,  including 
filtration,  sedimentation,  llocculation  and  disinfection, 

5.  A  visit  to  the  laboratory,  including  Information  on  the 
quality  of  water  distributed  to  consumers,  and 

6.  Anticipated  improvements,  expansions,  and  long- 
range  plans  for  meeting  future  service  needs. 

Plant  tours  can  contnbute  to  a  water  utility's  overall 
program  to  ga-n  financing  for  capital  improvements.  If  the 
City  Council  or  other  governing  board  has  seen  the  treat- 
ment process  first  hand,  it  is  more  likely  to  understand  the 
need  for  enhancement  and  support  future  funding. 

QUESTIONS 

Write  your  answers  In  a  notLOook  and  then  compare  your 
answers  with  those  on  page  558. 

23.2A  What  is  probably  the  single  most  important  aspect  of 
a  successful  public  relations  effort? 

23.2B  What  attitude  should  management  try  to  develop 
among  its  employees  regarding  the  consumer? 

23.2C  How  can  you  prepare  yourself  for  an  interview  with 
the  news  media? 

23.2D  How  can  plant  tours  be  most  beneficial  for  a  water 
utility? 

23.3  EMERGENCY  PLANNING 

Contingency  planning  is  an  essential  facet  of  water  utility 
management  and  one  that  is  often  overlooked.  Although 
utilities  in  various  locations  will  be  vulnerable  to  somewhat 
different  kinds  of  natural  disasters,  the  effects  of  these 
disasters  in  many  cases  will  be  quite  similar.  As  a  first  step 
towards  an  effective  contingency  plan,  each  utility  should 
make  an  assessment  of  its  own  vulnerability  and  then 
develop  and  implement  a  comprehensive  plan  of  action. 

All  water  utilities  suffer  from  common  problems,  such  as 
equipment  breakdown,  leaking  pipes  and  variations  in  water 
quality  and  quantity.  During  the  past  few  years  there  has 
also  been  an  increasing  amount  of  vandalism,  civil  disorder, 
toxic  spills,  and  employee  strikes  which  have  threatened  to 
disrupt  water  utility  operations.  Natural  disasters  such  as 
floods,  earthquakes,  hurricanes,  forest  fires,  avalanches, 
and  blizzards  are  a  more  or  less  routine  occurrence  for 
some  utilities. 


ERLC 


Ft  nher,  in  observing  today's  international  tension  and  the 
po  .,tial  for  nuclear  war,  the  effect  such  action  would  have 
on  the  operation  of  water  utilities  must  be  seriously  consid- 
ered. When  such  catastrophic  emergencies  occur,  the  utility 
must  be  prepared  to  minimize  the  effects  of  the  event  and 
have  a  plan  for  rapid  recove'7  to  avoid  serving  contaminated 
water  to  the  consumers.  Such  preparation  should  be  a 
specific  obligation  of  every  utility  manager. 

Once  It  IS  recogn  jed  that  all  water  treatment  plants  are 
subject  to  a  variety  of  emergency  situations,  the  vulnerability 
of  that  treatment  unit  to  the  effects  of  a  disaster  must  be 
assessed  If  the  extent  of  damage  can  be  estimated  for  a 
series  of  most  probable  events,  the  weak  elements  can  be 
studied,  and  protection  and  recovery  operations  can  center 
on  these  elements. 

Although  all  elements  are  important  for  the  utility  to 
function,  experience  with  disasters  points  out  elements  that 
are  most  subject  to  disruption  These  elements  are: 

1  The  absence  of  trained  personnel  to  make  critical  deci- 
sions and  carry  out  orders, 

2  The  loss  of  power  to  the  treatment  facilities, 

3.  An  inadequate  amount  of  supplies  and  matenals,  and 

4.  Inadequate  communication  equipment. 

The  following  steps  should  be  taken  in  assessing  the 
vulnerability  of  a  system: 

1  Identify  and  describe  the  treatment  components, 

i  Assign  assumed  disaster  charactenstic*:, 

3.  Estimate  disaster  effects  on  system  components, 

4  Estimate  water  demand,  quality  and  quantity  dunng  and 
following  a  potential  disaster,  and 

5  Identify  key  system  components  that  wouid  be  primarily 
responsible  for  system  failure. 

If  the  assessment  shows  a  system  is  unable  to  meet 
estimated  requirements  because  of  the  failure  of  ono  or 
more  critical  treatment  components,  the  vulnerable  ele- 
ments have  been  identified.  Repeating  this  procedure  using 
several  "typicaf  disasters  will  usually  point  out  treatment 
plant  weaknesses.  Frequently  the  same  vulnerable  element 
appears  for  a  variety  of  assumed  disaster  events. 

You  might  consider,  for  example,  the  case  of  the  addition 
of  toxic  pollutants  to  water  supplies.  The  list  of  toxic  agents 
that  may  have  a  harmful  effect  on  humans  is  almost  endless. 
However,  it  is  recognized  that  there  is  a  relationship  be- 
tween the  quantity  of  toxic  agents  added  and  the  treatment 
provided  for  the  supply.  Adequate  chlonnation  is  effective 
against  most  biological  agents.  Other  considerations  are  the 
amount  of  dilution  water  and  the  solubility  of  the  chemical 
agents.  There  is  the  possibility  that  during  normal  detention 
times  many  of  the  biological  agents  will  die  off  wiiii  adequate 
chlonnation. 

Although  the  drafting  of  an  emergency  plan  for  a  water 
system  may  be  a  difficult  job,  the  existence  of  such  a  plan 
can  be  of  cntical  importance  Ounng  an  emergency  situation. 

An  emergency  operations  plan  need  not  be  too  detailed, 
since  all  types  of  emergencies  cannot  be  anticipated  and  a 
complex  response  program  can  be  more  confusing  than 
helpful.  Supervisory  personnel  must  have  a  detailed  descrip- 
tion of  their  RESPONSIBILITIES  during  emergencies.  A 

573 


Administration  553 


water  quality  officer  should  be  primarily  responsible  for  the 
SAFETY  of  the  water  supply  Supervisory  people  need 
information,  supplies,  equipment  and  the  assistance  of 
trained  personnel  All  these  can  be  provided  through  a 
properly-constructed  emergency  operation  plan  that  is  not 
extremely  detailed. 

The  following  outline  should  be  followed  when  developing 
an  emergency  operations  plan: 

1.  Make  a  vulnerability  assessment, 

2.  Inventory  organizational  personnel, 

3.  Provide  for  a  recovery  operation  (plan), 

4.  Provide  training  programs  for  operators  in  carrying  out 
the  plan. 

5.  A  plan  should  include  ')ca'  and  regional  coordination 
such  as  health  depart'^  .ent,  police,  and  fire, 

6.  Establish  a  communications  procedure,  and 

7.  Provide  protection  for  personnel,  plant  equipment,  rec- 
ords and  maps. 

By  following  these  steps,  an  emergency  plan  can  be 
developed  and  maintained  even  though  changes  m  person- 
nel may  occur.  "Emergency  Simulation"  training  sessions, 
including  the  use  of  standby  power,  equipment  and  field  test 
equipment  will  insure  that  equipment  and  personnel  are 
ready  at  times  of  emergency. 

A  list  of  phone  numbers  for  operators  to  call  in  an 
emergency  should  be  complete  and  posted  by  a  phone  for 
emergency  use.  You  should  prepare  a  list  for  your  plant 
now,  if  you  have  not  already  done  so. 

1.  Plant  supervisor, 

2.  Director  of  public  works  or  head  of  utility  agency, 

3.  Police, 

4.  Fire, 

5.  Doctor  (2  or  more), 

6.  Ambulance  (2  or  more), 

7.  Hospital  (2  or  more), 

8.  Chlorine  supplier  and  manufacturer, 

9  CHEMTREC  (800  424-9300  for  hazardous  chemical 
spills  sponsored  by  the  Manufacturing  Chemists  Asso- 
ciation), 

10.  Pesticides  (800-424-9300  for  the  National  Agricultural 
Chemists  Association  Cleanup  Crews), 

11.  U.S.  Coast  Guard's  National  Environmental  Response 
Center  (800-424-8802), 

12.  EPA  Hazardous  Materials  Headquarters  (Monday 
through  Friday,  8:00  a.m.  to  4:30  p.m.,  202-245-3045; 
other  times  call  202-554-2329),  and 

13.  FDA  Poison  Control  Center  (202-496-7691  or  202-963- 
7512). 


For  additional  information  on  emergencie<5  see  Chapter  7, 
Disinfection,  Section  7  52,  "Chlorine  Leaks,"  Chapter  10, 
Plant  Operation,  Section  10.9,  "Emergency  Conditions  and 
Procedures,"  and  Chapter  18,  Maintenance,  Section  18.02 
"Emergencies." 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  558. 

23  3A  What  IS  the  first  step  towards  an  effeciive  contingen- 
cy plan  for  emergencies? 

23.3B  How  would  you  handle  undesirable  biological  agents 
suspected  in  the  water  supply  during  an  emergency? 

23  3C  Why  is  a  too  detailed  emergency  operation  plan  not 
needed  nor  desirable? 

23.3D  An  emergency  operations  plan  should  include  what 
specific  information*? 


23.4    HANDLING  THE  THREAT  OF  CONTAMINATED 
WATER  SUPPLIES^ 

23.40  Importance 

More  than  50  water  utilities  in  southern  Louisiana  were 
threatened  with  cyanide  poisoning  in  their  water  suoplies  in 
one  year .  Such  threats  can  occur  anywhere,  and  every  water 
utility  should  be  prepared  to  handle  this  type  of  emergency. 

23.41  Toxicity 

The  term  toxicity  is  often  used  when  discussing  contami- 
nation of  a  water  supply  with  the  intention  of  creating  a 
cerious  health  hazard.  Toxicity  is  the  ability  of  a  contaminant 
(chemical  or  biological)  to  cause  injury  when  introduced  to 
the  body.  The  degree  of  toxicity  varies  with  the  concentra- 
tion of  contaminant  required  to  cause  injury,  the  speed  with 
which  the  injury  lakas  place,  and  the  severity  of  the  injury. 


2  This  section  was  reprinted  from  OPFLOW.  Vol  No.  3  March  1983,  by  permission.  Copyright  1983,  the  American  Water  Works 
Association. 

by  4 


554  Water  Treatment 


The  effect  of  a  toxic  contaminant,  once  added  to  a  v/r^ter 
supply,  depends  on  several  things.  First  the  amount  of 
contaminant  added  can  vary,  as  can  the  size  of  the  water 
supply.  In  general,  it  takes  larger  quantities  of  a  contaminant 
to  be  toxic  in  a  larger  water  supply.  Second,  the  solubility  of 
the  contaminant  can  vary.  The  more  soluble  the  substance  is 
in  water,  the  more  likely  it  is  to  cause  problems.  Finally  the 
detention  time  of  the  contaminant  in  the  water  can  vary.  For 
example,  many  biological  agents  will  die  before  they  can 
cause  a  problem  In  the  water  supply. 

Generally,the  terms  acute  and  chronic  are  used  to  de- 
scribe toxic  agents  and  their  effects.  An  acute  toxic  agent 
causes  injury  quickly.  When  the  contaminant  causes  illness 
in  seconds,  minutes,  or  hours  after  a  single  exposu'-e  or  a 
single  dose,  it  is  considered  an  acute  toxic  agent.  A  chronic 
agent  causes  injury  to  occur  over  an  extended  period  of 
exposure.  Generally,  the  contaminant  is  ingested  in  repeat- 
ed doses  over  a  period  of  days,  months,  or  years. 

23.42  Effective  Dosages 

When  determining  the  effective  dosage  of  a  contaminant 
(the  amount  of  that  contamnant  necessary  to  cause  injury) 
the  following  facts  must  be  considered: 

1.  Quantity  or  concentration  of  the  contaminant, 

2.  Duration  of  exposure  to  the  contaminant, 

3.  Physical  form  of  the  contaminant  (size  of  particle;  phys- 
ical state  —  solid,  liquid,  gas), 

4.  Attraction  of  the  contaminant  to  the  organism  being 
contaminated, 

5.  Solubility  of  the  contaminant  in  the  organism,  and 

6.  Sensitivity  of  the  organism  to  the  contaminant. 

Concentration  of  a  contaminant  can  be  expressed  in  two 
ways.  The  maximum  allowable  concentration  (MAC)  is  the 
maximum  concentration  of  the  contaminant  allowed  in  drink- 
ing water.  Table  23.3  lists  s^^^veral  contaminants  and  their 
MACs,  specifically  for  shoi1-term  emergencies  ranging  up  to 
three  days.  The  MACs  should  not  be  confused  with  concen- 
tration required  to  have  an  acute  effect  on  the  population. 
Lethal  dos  50  (LD  50),  is  used  to  express  the  concentration 
of  a  contarninant  that  will  produce  50  percent  fatalities  from 
an  average  exposure. 


23.43  Protective  Measures 

A  utility  can  take  three  approaches  to  protect  its  water 
supply  from  contamination.  First,  the  utility  can  isolate  those 
reservoirs  that  offer  easy  access  to  the  general  public. 
These  reservoirs  can  be  fenced  off  and  patrolled,  or  they 
can  be  covered.  If  access  to  on-line  reservoirs  is  limited, 
persons  attempting  to  contaminate  the  water  supply  wil! 
generally  be  forced  to  look  to  larger  bodies  of  water. 
Contamination  of  these  large  water  bodies  requires  larger 
quantities  of  contaminant,  increases  the  detention  time  of 
the  contaminant,  and  increases  the  likelihood  of  its  detec- 
tion. 

As  a  second  means  of  protection,  the  water  utility  can 
develop  an  extensive  detection  and  monitoring  program. 
Detecting  any  contaminant  that  might  be  added  to  a  water 
supply  is  difficult  and  expensive.  However,  because  most 
contaminants  cause  secondary  effects  in  a  water  supply, 
such  as  taste,  color,  odor,  or  chlorine  demand,  detection  is 
easier. 

ERIC 


TABLE  23.3 

EMERGENCY  LIMITS  OF  SOME  CHEMICAL  POLLUTANTS 
IN  DRINKING  WATE?-^^ 

Concentration  Limits,  mg/L 

Emergency 
Short  Term 

Chemical  (Three  days)   Long  Term 


Cyanide  (ON)  5  0  0  01 

Aldrin  Q  05  0  032 

Chlordane  0  06  0  003 

DDT  1  4  0.042 

D'eldnn  Q.Ob  0  017 

Endnn  0.01  0  001 

Heptachlor  0.1  O.O^S 

Heptacfilor  epoxide  0.05  0.018 

Lindane  2.0  0.056 

Methoxychlor  2  8  0.035 

Toxaphene  1 4  0.005 

Beryllium  Qi  0  000 

Boron  25  0  1  000 

2  4.D  2  0  0.1 

Ethylene  chlorohydrin  2.0 
Organiphosphorus  and 

carbamate  pesticides  2.0  0.1 00 

Tnnitro  oluene  (N02)(C5H2CH3)  0  75  0.005 


^  These  limits,  based  on  current  knowledge  and  informed 
judgment,  have  been  recommended  by  knowledgeable 
persons  in  the  field  of  toxicology.  They  are  subject  to 
change  should  new  information  indicate  the  need.  Addi- 
tional information  on  some  of  the  chemicals  listed  can  be 
found  in  "Report  of  the  Secretary's  Commission  on  Pesti- 
cides and  Their  Relationship  to  Environmental  Health," 
Parts  I  and  II.  USDHEW,  Washington,  D  C,  Dec.  1369 


Because  utility  operators  "know"  their  water  supply  (they 
know  its  characteristics),  any  subtle  changes  in  taste,  odor, 
color  and  chlorine  demand  are  instantly  recognized.  Once  it 
has  been  determined  that  the  water  supply  may  be  contami- 
nated water  samples  can  be  tested.  Tests  can  either  be 
done  at  the  utility's  laboratory,  if  it  is  a  large  utility,  or  the 
samples  can  be  sent  to  the  state  health  department. 

Finally,  the  utility  can  maintain  a  high  chlorine  residual. 
Generally,  chlonne  residuals  of  one  mg/L  or  higher  effective- 
ly oxidize  or  destroy  most  contaminants.  For  example, 
infectious  hepatitis  virus  will  not  survive  a  free  residual 
Chlorine  level  of  0.7  mg/L 

23.44   Emergency  oountermeasures 

Following  is  a  list  of  emergency  countermeasures  that, 
when  usee  over  a  short  time  period,  can  increase  protection 
of  a  water  supply: 

1  Maintaining  a  high  chlorine  residual  in  the  system, 

2  Having  engineers,  chemists,  and  medical  personnel  on 
24-hour  alert, 

3  Continuously  monitoring  key  points  m  the  distnbution 
system  (monitoring  chlorine  residual  is  mandatory), 

4.  Increasing  security  around  exposed  on-line  reservoirs, 

5  Sealing  off  access  to  manholes  within  a  three-  to  six- 
block  radius  of  highly  populated  areas. 


575 


Administration  555 


6  Setting  up  emergency  crews  that  can  isolate  sections  of 
the  distribution  system,  and 

7  Staffing  the  treatment  facility  on  a  24-hour  basis 


23.45  In  Case  of  Contamination 

If  contamination  of  the  water  supply  is  discovered,  the 
immediate  concern  must  be  the  safety  of  the  public  If  the 
contaminated  water  has  entered  the  distribution  system, 
immediate  public  notification  is  the  highest  priority  The  local 
police  chief,  shenff  or  other  responsible  governmental  au- 
thority will  help  to  spread  the  word  Alternate  sources  of 
water  may  need  to  be  provided 

If  the  contaminated  water  has  not  entered  the  distribution 
system  it  may  be  possible  to  isolate  the  contaminated 
source  and  continue  to  supply  vater  from  other,  unaffected 
sources  If  the  contaminated  water  is  the  only  source  for  the 


community,  treatment  measures  may  be  available  that  will 
remove  the  contaminant  or  reduce  its  toxicity 

Table  23.4  lists  a  series  of  emergency  treatment  steps  that 
can  be  taken  when  identified  chemicals  are  added  to  the 
system.  These  emergency  treatment  methods  are  effective 
only  if  the  contaminant  has  been  identified. 

QUESTIONS 

Write  your  answers  in  a  notebook  and  then  compare  your 
answers  with  those  on  page  558. 

23. 4A  What  does  the  word  toxicity  mean? 

23  4B  The  degree  of  toxicity  varies  with  what  factors? 

23  4C  List  possible  secondary  effects  in  a  water  supply 
which  may  allow  detection  of  a  contaminant  without 
specific  testing 


TABLE  23.4 

EMERGENCY  TREATMENT  FOR  REDUCING  CONCENTRATION  OF  SPECIFIC  CHEMICALS 

IN  COMMUNITY  WATER  SUPPLIES^ 


Concentration 


Treatment 


Concentration 


Treatment 


Arsenicais 

Unknown  organic  and 
inorganic  arsenicals  in 
groundwater  at 
concentrations  of  1 00  mg/L 

Cyanides 

Hydrogen  cyanide 


Acetone  cyanohydnn 
Cyanogen  chloride 

Hydrocarbons 
Kerosene  peak 
concentrations  of  1 40  mg/L 


Miscellaneous  Organic 
Chemicals 

LSD  (lysergic  acid  denvative) 


Precipitation  with  feme  sulfate 
and  liming  to  pH  6  8,  followed  by 
sedimentation  and  filtration. 


Prechlonnation  to  free  residual 
with  pH  7,  followed  by 
coagulation,  sedimentation,  and 
filtration  Caution  housed 
facilities  must  be  adequately 
ventilated. 

Precipitation  with  ferrous  or 
ferric  salts  to  form  Prussian  blue 
(iron  ferric  cyaniae)  followed  by 
coagulation,  sedimentation,  and 
clarification  As  long  as  an 
excess  of  iron  coagulant  is 
applied,  the  filtered  water  should 
be  nontoxic  even  though  it  is 
blue. 

Same  as  for  hydrogen  cyanide 
Same  as  for  hydrogen  cyanide 

Preapplications  of  bleaching  clay 
and  activated  carbon,  plus  some 
increase  in  normal  dosages  of 
alum,  chlonne  dioxide,  lime,  and 
carbon,  to  provide  treatment 
enabling  continued  production  of 
water 


Chlorination  in  alkaline  water,  or 
water  made  alkaline  by  addition 
of  lime  or  soda  ash,  to  provide  a 
free  chlorine  residual.  Two  parts 
free  chlonne  are  required  to 
react  with  each  part  LSD. 


Nerve  Agents 

(Organophosphorus 
compounds) 


Pesticides 

2,4-DCP  (2,4-Dichlorophenol) 
and  impurity  in  commercial 
2,4-D  herbicides) 

DDT(dichloro- 
diphenyltnchloroethane), 
concentrations  of  10  g/L 

Dieldrin,  concentrations  of  10 

g/L 


Endnn,  concentrations  of  1 0 

g/L 


Lindane,  concentrations  of  1 0 

g/L 


Parathion,  concentrations  of 
10  g/L 


Superchlorination  at  pH  7  to 
provide  at  least  40  mg/L  residual 
after  30-min  chlorine  contact 
time,  followed  by  dechlorination 
and  conventional  clarification 
processes 

Adsorption  on  activated  carbon 
followed  by  coagulation, 
sedimentatfon,  and  filtration 

Chemical  coagulation, 
sedimentation  and  filtration. 

Chemical  coagulation, 
sedimentation,  and  filtration. 
Supplemental  treatment  with 
activated  carbon  may  be 
necessary. 

Chemical  coagulation, 
sedimentation,  and  filtration. 
Supplemental  treatment  with 
activated  carbon  may  be 
necessary. 

Application  of  activated  carbon 
followed  by  chemical 
coagulation,  sedimentation,  and 
filtration. 

Chemical  coagulation, 
sedimentation,  and  filtration. 
Supplemental  treatment  with 
activated  carbon  may  be 
necessary.  Omit  prechlorination 
as  chlorine  reacts  with  parathion 
to  form  paraoxon,  which  is  more 
toxic  than  parathion. 


a  Source  Grahar.  \/Valton.  Chief,  Technical  Services.  National  Water  Supply  Research  Laboratory,  USSR  Program.  Oct.  24, 1968 


ERLC 


556  Water  Treatment 


2X5  ADDITIONAL  READING 

1.  TEXAS  MANUAL,  Chapter  18  "Effective  Public  Rela- 
tions in  Water  Works  Operations,"  and  Chapter  19, 
"Planning  and  Financing." 

2.  WATER  RATES  (Ml).  Obtain  from  Computer  Services. 
AWWA,  6666  West  Quincy  Avenue,  Denver,  Coloraoo 
80235.  Order  No.  30001.  Price  to  members,  $13.50,^ 
nonmembers,  $17.00. 

3.  WATER  UTILITY  MANAGEMENT  PRACTICES  (M5). 
Obtain  from  Computer  Services,  AWWA,  6666  West 
Quincy  Avenue,  Denver,  Colorado  80235.  Order  No. 
30005.  Price  to  members,  $16.50;  nonmembers,  $20.50. 

4.  EMERGENCY  PLANNING  FOR  WATER  UTILITY  MAN- 
AGEMENT (Ml 9).  Obtain  from  Computer  Services, 
AWWA,  6666  West  Quincy  Avenue,  Denver,  Colorado 
80235.  Order  No.  30019.  Price  to  members,  $13.50, 
nonmembers,  $17.00. 


DISCUSSiON  AN3  REVIEW  QUESTIONS 

Chapter  23.  ADMINISTRATION 


Please  answer  these  discussion  and  review  questions 
before  continuing  with  the  Objective  Test  on  page  559.  The 
purpose  of  these  questions  is  to  indicate  to  you  how  well  you 
understand  the  material  in  the  'esson.  Write  the  answers  to 
these  questions  in  your  notebook. 

1  Why  must  a  utility  have  clearly  defined  objectives'^ 

2.  How  can  the  success  of  good  organizational  planning 
be  measured*^ 

3.  How  can  the  numbers  and  grade  levels  of  certified 
operators  required  at  a  water  treatment  plant  be  deter- 
mined? 

4.  What  IS  the  first  step  in  organizing  an  effective  public 
relations  effort*^ 

5.  How  can  management  keep  emoloyees  well  informed? 

6.  What  IS  the  value  of  consumer  complaints'? 

7.  What  telephone  procedures  can  be  used  to  help  your 
utility  favorably  Impress  people  who  contact  the  agency 
by  phone? 

8.  How  would  you  assess  the  vulnerability  of  a  water 
supply  system'? 

9.  How  can  a  utility  protect  its  water  supply  from  contami- 
nation? 

10  What  would  you  do  if  you  discovered  that  contaminated 
water  has  entered  your  distribution  system'^ 

ErJc 


1 1 .  Why  are  records  importanf? 

12  Why  should  public  water  systems  be  operated  by 
trained  and  certified  personnel? 

1 3  What  IS  the  difference  between  planning  and  budgeting'? 

14.  What  factors  should  be  considered  when  determining  a 
v.'ater  rate  schedule  for  a  utility'? 

15  List  the  possible  sources  or  types  of  training  available 
for  operators. 


577 


Administration  557 


SUGGESTED  ANSWERS 

Chapter  23.  Administration 


Answers  to  questions  on  page  541 , 

23.0A  Budgeting  is  the  art  of  predicting  the  amount  of 
money  necessary  to  achieve  an  organization's  goals. 

23,0B  Waste  and  inefficiency  can  be  reduced  or  eliminated 
by  carefully  examining  all  phases  of  operation  and 
maintenance  when  preparing  accurate  and  realistic 
budgets. 

23.0C  Important  items  usually  contai'^d  on  a  purchase 
Order  include:  (1)  the  date,  (2)  a  complete  description 
of  each  item  and  quantity  needed,  (3)  prices,  (4)  the 
name  of  the  vendor,  and  (5)  a  purchase  order  num- 
ber. 

Answers  to  questions  on  page  545. 

23.0D  Some  of  the  important  uses  of  records  include: 

1  Aiding  operators  in  solving  treatment  and  water 
quality  problems, 

2.  Providing  a  method  of  alerting  operators  to 
changes  in  source-water  quality, 

3.  Showing  that  the  treated  water  is  acceptable  to 
the  consumer, 

4.  Documenting  that  the  fihal  product  meets  plant 
performance  standards^  as  well  as  the  stan- 
dards of  the  regulatory  agencies. 

5.  Determining  performance  of  treatment  pro- 
cesses, equipment,  and  the  plant, 

6.  Satisfying  legal  requirements, 

7.  Aiding  in  answering  comp'amts, 

8.  Anticipating  routine  maintenance, 

9.  Providing  data  for  cost  analysis  and  prepara- 
tion of  budgets, 

10.  Providing  data  for  future  engineering  designs, 
and 

11.  Providing  information  for  monthly  and  annual 
reports. 

23.0E  "Unaccounted  for  water"  is  the  difference  between 
the  amount  of  treated  water  that  enters  the  distribu- 
tion system  and  waterthat  is  delivered  to  consumers. 

23.0F  Chemical  inventory  and  usage  records  that  should  be 
kept  include: 

1.  Chemical  inventory/storage  (measured  use  and 
deliveries), 

2.  Metered  or  estimated  plant  usages,  and 

3.  Calculated  usage  of  chemicals  (compare  with 
actual  use). 

Answers  to  questions  on  page  547, 

23.0G  Guidelines  which  are  useful  in  development  of  an 
organizational  plan  include: 

1.  Organization  should  be  based  specifically  upon 
the  objectives  to  be  achieved  and  the  activities  to 
be  performed, 

ERIC 


2.  Each  person  should  have  only  one  boss  and  all 
direction  and  guidance  should  come  from  that 
supervisor, 

3.  The  number  of  supervisory  levels  above  the 
working  level  should  be  kept  to  a  minimum, 

4.  Each  supervisor  should  have  a  limited  number  of 
people  to  directly  supervise  (fewer  than  6), 

5.  Delegation  of  authority  should  be  as  complete  as 
possible  with  the  lowest  levels  of  the  work  force 
allowed  to  make  as  many  decisions  as  are  ap- 
propriate to  that  level, 

6.  The  responsibility  for  performance  of  each  indi- 
vidual should  be  pre-determined  and  then  made 
perfectly  clear  to  the  individual  and  the  staff,  and 

7.  Lines  of  management  authority  must  be  main- 
tained and  not  weakened  by  staff  or  functional 
authority. 

23.0H  The  staff  organization  provides  advice  and  service  to 
the  line  personnel  to  assist  them  in  meeting  their 
objectives. 

23.01  Organizational  planning  can  benefit  manag  ,ient  by 
correcting  weaknesses  in  the  organization  of  a  utility. 
It  can  also  strengthen  the  structure  and  increase  the 
effectiveness  of  management,  thereby  reducing 
costs  and  increasing  efficiency, 

23.0J  Signs  that  may  indicate  to  a  utility  potential  weak 
points  or  approaching  organizational  problems  in- 
clude: 

1.  Physical,  mental  and  emotional  overloading 
which  causes  undue  fatigue, 

2.  Indecisiveness  in  management  which  delays  de- 
cision rraking, 

3.  Poor  teamwork  resulting  from  poor  supervisory 
practices  or  personal  inadequacies  of  a  supervi- 
sor, and 

4.  Failure  to  train  subordinates  which  causes  prob- 
lems when  supervisors  are  promoted  or  move  on 
to  another  job. 

Answers  to  questions  on  page  548. 

23  1 A  A  supervisor  is  responsible  for  the  safety  and  profes- 
sional development  of  operators.  Other  responsibil- 
ities may  include  assigning  tasks  to  specific  opera- 
tors, being  sure  they  understand  the  assignment  and 
know  how  to  do  the  job  safely,  and  eventually  making 
sure  that  the  job  was  done  properly. 

23.1  B  The  most  important  factors  which  will  influence  the 
size  and  qualifications  of  staff  required  include  the 
number  of  services  and  also  the  size  and  complexity 
of  the  treatment  processes  and  facilities  that  must  be 
operateo  and  maintained.  Other  important  factors 
might  include  age  and  condition  of  facilities  and 
expected  population  growth  rates, 

23.1  C  Operators  should  be  properly  trained  to  recognize  all 
hazards  and  to  effectively  accomplish  the  tasks  they 
are  assigned.  Supervisors  must  motivate  operators 

578 


558  Water  Treatment 


to  use  safe  procedures. 

Answers  to  questions  on  page  549. 

23.1  D  Water  supply  and  treatment  facilities  are  often  classi- 
fied on  the  basis  of  the  number  of  services  and/or  the 
capacity  of  the  treatment  plant  as  well  as  on  the 
complexity  of  the  treatment  processes  in  the  plant. 

23.1  E  An  operator  can  achieve  higher  levels  of  certification 
by  gaining  the  necessary  education  and  experience 
for  the  next  level  of  certification.  The  operator  then 
must  successfully  pass  the  next  level  certification 
examination. 

23.1  F  To  find  out  how  to  become  certified,  contact  your 
state  certification  board  or  the  Association  of  Boards 
of  Certification  (ABC)  in  Ames.  Iowa. 

Answers  to  questions  on  page  552. 

23.2A  Probably  the  single  most  important  aspect  of  a  public 
relations  effort  is  employee  job  satisfaction  and 
performance. 

23.2B  Management  should  try  to  develop  among  its  em- 
ployees the  attitude  that  even  though  the  consumer 
is  not  always  right,  every  consumer  is  always  entitled 
to  courteous  treatment  and  a  proper  explanation  of 
anything  the  consumer  does  not  understand. 

23.2C  Proper  preparation  for  an  interview  with  the  news 
media  includes: 

1.  Speak  in  personal  terms,  free  of  institutional 
jargon. 

2.  Do  not  argue  or  show  anger  if  the  reporter 
appears  to  be  rude  or  overly  aggressive. 

3.  If  you  don't  know  an  answer,  say  so  and  offer  to 
find  out.  Don't  bluff. 

4.  If  you  say  you  will  call  back  by  a  certain  time,  do 
so.  Reporters  face  tight  deadlines. 

5.  State  your  key  points  early  in  the  interview, 
concisely  and  clearly.  If  the  reporter  wants  more 
information,  he  or  she  will  ask  for  it. 

6.  If  a  question  contains  language  or  concepts  with 
which  you  disagree,  don't  repeat  them,  even  to 
deny  them. 

7.  Know  your  facts. 

8.  Never  ask  to  see  a  story  before  it  is  printed  or 
broadcast.  Doing  so  indicates  that  you  doubt  th.'* 


reporter  s  ability  and  professionalism. 

23.2D  Plant  tours  are  an  excellent  method  of  informing  the 
public  of  the  water  utility's  efforis  to  provide  a  safe, 
wholesome  witer  supply. 

Answers  to  questions  on  page  553. 

23.3A  The  first  step  towards  an  effective  contingency  plan 
for  emergencies  is  to  make  an  assessment  of  vulner- 
ability. Then  a  comprehensive  plan  of  action  can  be 
developed  and  implemented. 

23.3B  Adequate  chlorination  is  effective  against  most  bio- 
logical agents  during  an  emergency.  Othe:*  consider- 
ations include  the  amount  of  dilution  water  and  the 
possibility  that  the  biological  agents  will  die  off  during 
normal  detention  times  with  adequate  chlorination. 

23.3C  A  detailed  emergency  operation  plan  is  not  needed 
since  all  types  of  emergencies  cannot  be  anticipated 
and  a  complex  response  program  can  be  more 
confusing  than  helpful. 

23.3D  An  emergency  operations  plan  should  include: 

1 .  Vulnerability  assessment, 

2.  Inventory  of  personnel, 

3.  Provisions  for  recovery  operation, 

4.  Provisions  for  training  programs  for  operators  in 
carrying  out  the  plan, 

5.  Inclusion  of  coordination  plans  with  health,  po- 
lice and  fire  departments, 

6.  Establishment  of  a  communications  procedure, 
and 

7.  Provisions  for  protection  of  personnel,  plant 
equipment,  records  and  maps. 

Answers  to  questions  on  page  555. 

23.4A  Toxicity  is  the  ability  of  a  contaminant  (chemical  or 
biological)  to  cause  injury  when  introduced  into  the 
body. 

23.4B  The  degree  of  toxicity  varies  with  the  concentration 
of  contaminant  required  to  cause  injury,  the  speed 
with  which  the  injury  takes  place,  and  the  severity  of 
the  injury. 

23.4C  Possible  secondary  effects  in  a  water  supply  which 
may  allow  detection  of  a  contaminant  without  specif- 
ic testing  include  taste,  odor,  color  and  chlori.'»e 
demand. 


ERLC 


579 


Administration  559 

OBJECTIVE  TEST 

Chapter  23.  ADMh>JlSTRATION 


Please  write  your  name  and  mark  the  correct  answers  on 
tne  answer  sheet  as  directed  at  the  end  of  Chapter  1  There 
may  be  more  than  one  correct  answer  to  the  multiple  choice 
questions 

TRUE-FALSE 

1  A  definite  plan  of  organization  is  essential  to  effectively 
operate  a  v/ater  treatment  plant 

1  True 

2  False 

2  The  staff  organization  is  in  the  line  of  command 

1  True 

2  False 

3  Organizational  plans  can  be  copied  from  one  maior 
utility  to  another 

1  True 

2  False 

4  Radio  end  television  give  more  thorough  coverage  of 
stones  than  newspapers 

1  True 

2  Faise 

5  Usually  the  same  vul."»erable  plant  element  appears  as  a 
problem  for  a  variety  of  disaster  events 

1  True 

2  False 

6  Operators  must  be  availaoie  during  nights,  v/eekends. 
and  holidays  to  respond  to  emergencies 

1  True 

2  False 

7  In  a  water  treatment  plant  continuity  of  supply  is  of 
prime  importance 

1  True 

2  False 

8  A  set  of  rules  can  be  established  that  will  apply  to  all 
types  of  people  with  consumer  complaints 

1  True 

2  False 

9.  Try  to  be  friendly  and  courteous  at  all  times  to  people 
with  complaints. 

1  True 

2  False 

10  Complaints  should  be  welcomed  and  ac^^urately  re- 
corded 

1  True 

2  False 


MULTIPLE  CHOICE 

1 1  A  clear-cut  organizational  plan  reduces  or  avoids 

1.  Confusion. 

2  Duplication  of  effort. 

3  Effective  communication. 

4  Fnction 

5  Working  at  cross  purposes 

12  Each  supervisor  should  supervise  no  more  than   

people. 

1  6 

2.  12 

3.  18 

4.  24 

5.  30 

13  Staff  personnel  shown  on  a  water  utility  organization 
chart  include 

1  Accountants. 

2  Lawyers. 

3  Operators. 

4.  Secretaries. 

5.  Superintendent. 

14  Water  utility  operators  stiojld  become  certified  to 

1  Be  able  to  do  a  better  job  of  operating  the  facilities. 

2.  Improve  the  utility's  safety  record. 

3.  Increase  employee  pride  and  recognition. 

4.  Learn  how  to  identify  safety  hazards. 

5  Protect  the  public's  investment  in  the  utility. 

15  Management  has  a  responsibility  to  keep  employees 
well  informed  about  the  organization's 

1   Personnel  actions  (firings  and  demotions). 

2.  Plans. 

3.  Practices. 

4  Purposes. 

5.  Union  dues. 

16  Management  can  keep  employees  well  informed  by 
using 

1.  Bulletin  board  announcements 

2.  Local  newspapers 

3.  Memos. 

4.  Straight  talk  from  supervisors  to  subordinates. 

5  The  office  gossip. 

17  Information  provided  during  a  plant  our  should  include 

1  Description  of  the  sources  of  water  supply. 

2  Information  on  quality  of  water  distributed  to  con- 
sumers 

3  Plans  for  improvement. 

4  Plant  design  features. 

5  Theory  of  hydraulic  turbulence  in  sedimenta.ion 
basins. 


ERIC 


5S0 


560  Water  Treatment 


18.  Emergencies  that  confront  water  utilities  include 

1.  Budget  cuts. 

2.  Employee  strikes. 
3  Fires 

4.  Floods. 

5.  Vandalism. 

19  Elements  of  a  water  utility  which  are  most  likely  to  be 
weak  points  during  a  disaster  include 

1.  Absence  of  trained  personnel  to  make  critical  deci- 
sions. 

2.  Inadequate  amount  of  supplies  and  materials. 

3.  Inadequate  communication  equipment 

4.  Loss  of  power  to  the  treatment  facilities. 

5.  Shortage  of  funds  to  pay  contractors. 

20.  The  first  step  in  organizing  an  effective  public  relations 
campaign  is  to 

1.  Call  a  press  conference. 

2.  Conduct  plant  tours. 

3.  Establish  objectives. 

4.  Meet  with  community  leaders. 

5.  Publish  brochures. 

21 .  When  responding  to  consumer  complaints  or  questions, 
proper  response  phrases  include 

1.  Will  you  please. 

2.  You  made  a  mistake. 


3.  You  should  have. 

4.  Your  complaint. 

5.  Your  question. 

22  To  help  your  utility  make  friends  with  people  who 
contact  the  agency  by  phDne.  you  should 

1  Answer  after  3  or  4  nngs  so  callers  will  know  you  are 
busy 

2.  Answer  by  saying  Hello  ' 

3  Extend  a  pleasant  greeting. 

4  Leave  word  when  away  from  ihe  phone. 

5  Route  the  call  to  someone  who  can  take  a  message. 

23  When  determing  the  effective  dosage  of  a  contaminant 
(the  amount  of  that  contaminant  necessary  to  cause 
injury),  which  of  tha  following  facts  must  be  considered? 

1 .  Duration  of  exposure  to  the  contaminant 

2  Quality  or  concentration  of  the  contaminant 

3  Sensitivity  of  consumers  to  the  contaminant 

4  Solubility  of  tne  contaminant 

5.  Who  is  trie  suspected  source  of  the  contaminant 

24.  Accurate  records  are  very  important  because  they 

1  Are  a  valuable  source  of  information. 

2  Can  save  time  when  trouble  develops. 

3.  Help  prepare  preventive  maintenance  progranrs. 

4.  Provide  proof  that  problems  were  identified  and 
solved. 

5.  Serve  as  a  basis  for  plant  operation. 


/•'■  r. 


APPENDIX 

Final  Examination 

How  to  Solve  Water  Treatment  Plant 
Arithmetic  Problems 

Water  Abbreviations 

Water  Words 

Subject  Index 


ERLC 


582 


WATER  TREATMENT  PLANT  OPERATION 

VOLUME  II 


FINAL  EXAMINATION 
AND 

SUGGESTED  ANSWERS 


583 


Final  Exam  563 


FINAL  EXAMINATION 


This  final  exar.iinaiion  was  prepared  TO  HELP  YOU 
review  the  material  in  this  manual.  The  questions  are  divided 
into  four  types: 

1.  True-False. 

2.  Multiple  Choice. 

3.  Short  Answers,  and 

4.  Problems. 

To  work  this  examination: 

1.  Write  the  answers  to  each  question  in  your  notebook. 

2.  After  you  have  worked  a  group  of  questions  (you  aecide 
how  many),  check  your  answers  '"'^h  the  suggested 
answers  at  the  end  of  this  exam,  ana 

3  If  you  missed  a  question  and  don't  understand  why. 
reread  the  material  in  the  manual. 

You  may  wish  to  use  this  examination  for  review  purposes 
when  preparing  for  civil  service  dnd  certification  examina- 
tions. 

Since  you  have  already  completed  this  course,  you  do  not 
have  to  send  your  answers  to  California  State  University. 
Sacramento. 


True-False 

1.  Iron  and  manganese  are  essential  to  the  growth  of 
many  plants  and  animals,  including  humans 

1.  True 

2.  False 

1  Only  one  cell  of  iron  bacteria  is  needed  to  start  an 
infestation  of  iron  bacteria  in  a  well 

1    *.  rue 
2.  False 

3.  Fumes  from  hydrofluosilicic  acid  are  safe  to  breathe 

1.  True 

2.  False 

4  Insoluble  deposits  should  be  removed  from  chemical 
feed  lines. 

1.  True 

2.  False 


5  In  the  lime  softening  process,  magnesium  is  precipi- 
tated out  as  magnesium  carbonate. 

1.  True 

2.  False 

6.  Acid  softening  may  be  used  instead  of  soda  ash  soften- 
ing. 

1  True 
2.  False 

7  Dry  ice  should  be  used  to  keep  THM  samples  cool  when 
shipping  and  storing. 

1.  True 

2.  False 

8.  THMs  are  produ-^ed  faster  in  corrosive  waters  than  m 
scale  forming  waters 

1  True 

2  FaLse 

9  When  h  gher  mineral  concenlralions  occur  in  the  feed- 
water  the  mineral  concentrations  will  decrease  in  tne 
product  water 

1  True 

2  False 

10  An  increase  in  feedwater  temperature  will  decrease  the 
v^aler  fi  jx 

1  True 

2  False 

1 1  Sedimentation  lanko  should  be  inspected  and  repaired 
when  the  tanks  are  emptied  and  cleaned. 

1  True 

2  False 

1 2  A  precoat  of  filler  sand  js  required  to  dewater  gelatinous 
alum  sludge  when  using  a  vacuum  filler. 

1  True 

2  False 

13  Fiefore  attempting  to  cnange  fuses,  turn  off  power  and 
check  both  power  lines  for  voltage. 

1  True 

2  False 


ERLC 


584 


564  Water  Treatment 


14 


15 


Mechanical  energy  ss  commonly  converted  to  electricat 
energy  by  electric  motors. 

1  True 

2  False 

Always  replace  sprockets  when  replacing  a  chain. 

1  True 

2  False 


Multiple  Choice 

1   Red  water  complaints  in  drinking  water  may  be  caused 
by 

1 .  Corrosive  v/ater 

2  Ferric  hydroxide 

3  Iron  bacteria 

4  Iron  in  the  water 

5  Red  clay  or  snt 


16  A  transducer  is  the  primary  element  that  measures  a 
variable, 

1  True 

2  False 


17  Thin  rubber  or  plastic  gloves  can  be  worn  to  reduce 
markedly  your  chances  of  electrical  shock 

1  True 

2  False 

18.  If  an  operator  is  unsure  of  how  to  perform  a  ]ob.  then  it 
IS  the  operator  s  responsibility  to  ask  for  the  training 
needed 

1.  True 
2  False 

19  Inhalation  of  hydrochloric  (HCl)  vapors  or  mists  can 
cause  damage  to  the  nasal  passages. 

1  True 

2  False 

20  Distilled  water  is  considered  pleasant  to  drink. 

1  True 

2  Faise 

21  Dissolved  oxygen  m  water  can  contribute  to  corrosion 
of  piping  systems 

1  True 

2  False 


22  If  the  manganese  concentration  in  a  sample  cannot  be 
determined  immediately,  acidify  the  sample  with  acetic 
acid 

1  "^rue 

2  False 


2  Chemicals  used  to  oxidize  iron  and  manganese  include 

1  Alum 

2  Chlorine. 

3  Hydrogen  sulfide. 

4  Lime. 

5  Potassium  permanganate 

3  Important  features  of  a  fluoridation  sys;em  include 
prevention  of 

1.  Backsiphonage. 

2  Leaks 

3  Monitoring. 

4  Overfeeding. 
5.  Underfeeding. 

4  When  shutting  down  a  fluoride  chemical  feed  system, 
operators  should 

1  Confirm  that  safety  guards  are  in  place. 

2.  Dram  and  clean  the  mix  and  feed  tanks. 
3  Examine  all  fittings  and  drains  for  leaks. 
4.  Flush  out  all  solution  lines. 

5  Inspect  all  equipment  for  binding  and  rubbing. 

5  Benefits  that  could  result  from  the  lime-soda  ash  softei 
r.g  process  include 

1.  Control  of  corrosion. 

2  Increase  in  sodium  content  of  softened  water 

3  Increase  in  water  hardness. 

4.  Reduction  in  sludge  disposal  problems. 
5  Removal  of  iron  and  manganese 

6  Records  that  should  be  kept  by  the  operator  or  an  ion 
exchange  softening  plant  include 

1.  Blend  rates. 

2  Gallons  of  bnne  used  each  day. 

3  Pounds  of  lime  used  each  day. 

4  Results  of  jar  tests. 

5  Total  flow  per  day  that  bypasses  unit 


23   Non-commu  iity  water  systems  serve  consumers  less 
than  60  days  per  year 

1  True 

2  False 

24.  The  MCL  compliance  for  tnhalomethanes  is  determined 
by  the  running  average  of  four  monthly  averages 

1.  True 

2.  False 

25.  An  acute  toxic  agent  causes  injury  to  occur  over  an 
extended  period  of  time. 

1.  True 

2.  False 

ERIC  58 


7  A  minimum  of  —  samples  per  quarter  (every  3  months) 
for  THM  analysis  must  be  taken  on  the  same  day  for 
each  treatment  plant  in  the  distribution  system. 

1  2 

2  4 

3  6 

4  8 

5  10 

8  Group  1  techniques  for  contrc'ling  THMs  include 

1  Aeration. 

2  Chloramines. 

3  Chlorine  dioxide. 

4  Ozone 

5  Potassium  permanganate 


Final  Hxam  565 


9  The  reverse  osmosis  elements  should  be  cleaned  v^^hen 
the  operator  observes 

1.  Higher  differential  pressures 
2  Higher  operating  pressures 

3.  Higher  suspended  solids  in  product  water. 

4.  Lower  product  water  flow  rate 

5.  Lower  salt  rejection 

10.  Problems  encountered  in  electrodialysis  operation  in- 
clude 

1.  Alkaline  scales  in  the  concentrating  compartments. 

2  Fouling  of  m^.nbranes 

3  Sealing  of  membranes  by  inorganic  materials. 

4.  Sealing  oi  membranes  by  organic  materials. 

5.  Strengthening  oi  membranes. 

1 1  S'udge  ma>  oe  dewatered  by  the  use  of 

1   Belt  filter  presses. 

2.  Centrifuges 

3.  Flocculators. 

4  Solar  lagoons. 

5.  Solids-conlact  units. 

12  Problems  created  by  discharging  sludge  to  sowers 
include 

1 .  Fees  charged  could  be  very  high. 

2.  Increasing  flow  capacity  of  sewers. 

3  Monitoring  requirements  increase. 

4  Operational  problems  may  develop  at  wastewater 
treatment  plant. 

5  Possibility  of  causing  a  sewer  blockage. 

13.  A  good  maintenance  record  system  tells 

1  How  to  handle  consumer  complaints. 

2.  Performance  of  equipment 

3.  QuaiJty  of  raw  water. 

4.  Quality  of  treated  water. 

5.  When  maintenance  is  due. 

14  A  voltage  tester  can  be  useo  to  test  for 

1  Blown  fuses 

2.  Grounds. 

3.  Open  circuits. 

4.  Single  phasing  of  motors. 

5.  Voltage. 

15  Before  a  prolonged  shutdown,  pi  mps  should  be 
drained  to  prevent  damage  fiom 

1.  Cavitation. 

2.  CoTOSion. 

3.  Freezing. 

4.  Sedimentation 

5.  Water  hammer, 

16  Velocity  sensing  devices  measure  flows  by  sensing 

1.  Inches  of  water  (head). 

2.  Loss  of  hydraulic  energy 
3  Pressure  differential. 

4.  Pressure  within  a  restriction. 

5.  Rate  of  rotation. 

17.  Reliable  operation  of  pneumatic  instrumentation  pres- 
sure systems  requires 

1.  Ciean  air. 

2.  Dry  air. 

3.  Moisturized  air. 

4.  Pressurized  air. 

5.  Uninterrupted  power. 

ERLC 


18.  An  operator  must  accept  responsibility  for 

1  Beinq  sure  thai  safety  equipment  will  work  when 
ncedec* 

2  ^-ellow  operators. 

3  Operator  s  own  welfare 

4.  Seeinq  that  the  supervisor  complies  with  safety  rc;  j- 
lattor 

5  U*«>'ty's  equipment. 

19  Ammonia  cylinders  should  be  stored 

1  Away  from  heat 

2.  In  COOL  dry  locations 

3.  In  the  same  room  with  chlonne. 

4  With  caps  in  place  when  not  in  use 
3  With  protection  from  direct  sunlight. 

20.  True  color  is  noriTially  removed  or  at  least  decreased  by 

1.  Chlonnation 

2.  Coagulation. 

3.  Filtration. 

4.  Ozonation 

5  Sedimentation. 

21   High  levels  of  nitrate  in  a  domestic  water  supply  are 
undesirable  because  of 

1.  Hardness. 

2  Health  threat  due  to  «nfant  methemoglobinema. 

3.  Laundry  stains 

4.  Nitrate  tastes. 

5.  Potential  for  stimulating  excessive  algae  growth. 

22.  Primary  contamrants  which  are  considered  to  have 
public  health  importance  include 

1.  Lead. 

2  Mercury. 

3  Nitrate. 

4  Odor. 

5  Sulfate. 

23  Turbidity  is  undesirable  in  drinking  water  because  high 
turbioity 

1  Increases  corrosivity. 

2  Interferes  with  disinfection. 

3  Interferes  with  micribiological  determinations. 

4  Prevents  maintenance  of  an  effective  disinfectant. 
5.  Produces  aesthetic  problems 

24  Possible  approaches  tor  a  utility  to  take  to  protect  its 
water  supply  from  contamination  include 

1  Developing  an  extensive  detection  and  monitoring 
program. 

2  Fencing  off  and  patrolling  reservoirs. 

3  Having  police  lock  up  potential  sources  of  contami- 
nation 

4.  Isolating  reservoirs  that  offer  easy  access  to  the 
general  public 

5  Maintaining  a  low  chlonne  residual  in  the  water. 

25  Important  uses  of  records  include 

1.  Aiding  operators  in  solving  treatment  and  v/ater 
quality  problems. 

2.  Anticipating  routine  maintenance. 

3.  Providing  data  for  future  engineering  de'  gns 

4.  Satisfying  legal  requirements. 

5.  Showing  that  the  treated  water  is  acceptable  to  the 
consumer 

.  c  .586 


566  Water  Treatment 


Short  Answers 

1 .  How  can  the  growth  of  iron  bacteria  in  water  systems  be 
controlled'? 

2  Why  should  water  being  treated  for  iron  and  manganese 
by  ion  exchange  not  contain  any  dissolved  oxygen*? 

3  Why  should  both  underfeeding  and  overfeeding  of  flu- 
oride compounds  be  avcded? 

4.  How  would  you  dispose  of  empty  fluoride  chemical 
containers'? 

5  Why  must  water  be  stabilized  after  softening*? 

6  Why  should  the  same  chemical  hopper  or  feeder  not  be 
used  to  feed  both  lime  and  alum  at  different  times'? 

7  Why  are  trihalomethanes  in  dnnkmg  water  of  concern  to 
w^ter  treatment  plant  operators'? 

8  Where  are  samples  collected  for  THM  analyses'? 

9  What  are  the  common  membrane  demmeraliz.ng  proc- 
esses? 

10  What  causes  "flux  decline?" 

1 1  -  How  can  sludge  be  removed  from  sedimentation  tanks'? 

12.  Why  are  source  water  stabilizing  reservoirs  helpful  for 
water  treatment  plants'? 

13  Why  should  a  qualified  electrician  perform  most  of  the 
necessary  maintenance  and  repair  of  electrical  equip- 
menf? 

14  Why  are  battery-powered  lighting  units  considered  bet- 
ter than  engine-driven  power  sou.ces? 

15.  Why  must  a  suitable  screen  De  installed  on  the  intake 
end  of  pump  suction  piping'? 

16  What  IS  an  analog  instrumenf? 

17  How  are  liquid  levels  in  chemically-active  liquids  meas- 
ured'? 

18  how  can  pumps  in  a  pump  station  be  operated  for 
Similar  lengths  of  time'? 

19.  What  Items  should  be  included  in  a  utility's  policy 
statement  on  safety'? 

20  Why  do  safety  regulations  prohibit  the  use  of  common 
drains  and  sumps  from  chemical  storage  areas  ^ 

21  What  problems  may  be  caused  by  iron  in  a  domestic 
water  supply'? 

22.  What  IS  the  mam  source  of  trihalomethanes  in  dnnkmg 
water'? 

23.  Why  are  nitrate  concentrations  above  xhe  national 
standard  considered  an  immediate  health  threaf? 

24  Why  are  high  levels  of  sulfate  undesirable  m  dnnkinn 
water? 

25  Hovv  can  operators  improve  their  technical  knowledge 
and  skills'? 


Problems 

1  Determine  the  setting  on  a  potassium  permanganate 
chemical  feede.  in  pounds  per  day  if  the  chemical  dose 
is  2.1  mg/L  and  the  flow  is  0.53  MGD. 


2  Determine  the  setting  on  ^  potassium  permanganate 
chemical  feeder  in  pounds  per  million  gallons  if  the 
chemical  dose  is  2  1  mg/L 

3  A  reaction  basin  17  feet  in  diameter  and  4  5  feet  deep 
treats  a  flow  of  400,000  gallons  per  day.  What  is  the 
average  detention  time  in  minutes? 

4  A  flow  of  0  3  MGD  is  to  be  treated  with  an  18  percent 
solution  of  hydrofluosilicic  acid  (HgSiFg).  The  water  to  be 
treated  contains  no  fluoride  and  the  desired  fluoride 
concentration  is  1.1  mg/L.  Assume  the  hydrofluosilicic 
acid  weighs  9.6  pounds  per  gallon  Calculate  the  hydro- 
fluosilicic acid  feed  rate  m  gal'ons  per  day. 

5  A  flow  of  400  GPM  is  to  be  treated  with  a  2  4  percent 
(0.2  pounds  per  gallon)  solution  of  sodium  fluonde 
(NaO  The  water  to  be  treated  contains  0.5  mg/L  of 
fluonde  ion  and  the  desired  fluonde  ion  concentration  is 
0  9  mg/L  Calculate  the  sodium  fluoride  feed  rate  m 
gallons  per  day.  Assume  the  sodium  fluoride  has  a 
fluonde  purity  of  43.4  percent. 

6  How  many  gallons  of  water  with  a  hardness  of  1 5  grains 
per  gallon  may  be  treated  with  an  ion  exchange  softener 
with  an  exchange  capacity  of  24,000  kilograms? 

7  How  many  hours  will  an  ion  exchange  softening  unit 
operate  when  treating  an  average  flow  of  350  GPM'? 
The  unit  is  capable  of  softening  700,000  gallons  of 
water  before  requinng  regeneration. 

8  A  water  utility  collected  and  analyzed  eight  samples 
from  a  water  distnbution  system  on  the  same  day  for 
TTHMs.  The  results  are  shown  below. 

Sample  No.  1      2    3    4     5     6     7  8 

TTHM./ig//.  90  100  120  90   80  110  120  80 

What  was  the  average  for  the  day'? 

9  The  results  of  the  quarterly  average  TTHM  measure- 
ments for  two  years  are  given  below  Calculate  the 
running  annual  average  of  the  four  quarterly  measure- 
ments in  micrograms  per  liter 

Quarter  i     2     3    4     1      2     3  4 


Ave  Quarterly 
TTHM.  ng/L 


73  98  118  92   84  112  121  79 


10  Estimate  the  ability  of  a  reverse  osmosis  plant  to  reject 
minerals  by  calculating  the  mineral  rejection  as  a  per- 
cent The  feedwater  contains  1600  mg/L  TDS  and  the 
product  w^ter  is  145  mg/L. 

1 1  Estimate  the  percent  recovery  of  a  reverse  osmosis  unit 
with  a  4-2-1  arrangement  if  the  feed  flow  is  2.4  MGD  and 
the  product  flow  is  2  0  MOD. 

1 2  Calculate  the  pumping  capacity  of  a  pump  in  gallons  per 
minute  if  14  minutes  are  required  for  the  water  level  in  a 
;ank  to  drop  4.5  feet  The  tank  is  1 1  feet  in  diameter. 

13  Calculate  the  feed  rate  of  a  dry  chemical  feeder  in 
pounds  per  day  if  2.8  pounds  of  chemical  are  caught  in  a 
weighing  tin  during  eight  minutes 

14.  Calculate  the  threshold  odor  number  (T.O.N.)  for  a 
sample  when  the  first  detectable  odor  occurred  when 
the  35  mL  sample  was  diluted  to  200  mL  (163  mL  of 
odor-free  water  was  added  to  the  35  mL  sampie). 


ERIC 


587 


Final  Exam  567 


1 5  Determine  the  taste  rating  for  a  water  by  calculating  the 
arithmetic  mean  for  the  panel  ratings  given  below 

Tester  No.  1     2    3    4    5    6  7 

Rating  4    2    7    3    6    5  8 


16  A  small  water  system  collected  12  samples  dunng  one 
month  After  each  sample  was  collected,  10  mL  of 
sample  was  placed  in  each  of  5  fermentation  tubes  At 
the  end  of  the  month,  the  results  indicated  that  3  out  of  a 
total  of  60  fermentation  tubes  were  positive.  What 
percent  of  \he  portions  tested  during  the  month  were 
positive*? 


SUGGESTED  ANSWERS  FOR  FINAL  EXAMiNATION 


1.  True 

2  True 

3  False 

4  True 

5  False 

6  False 
7.  False 

8  False 

9  False 

10.  False 

11.  True 

12.  False 

13.  True 


Iron  and  manganese  are  essential  to  the  growth 
of  many  plants  and  animals,  including  humans. 

Only  one  cell  of  iron  bacteria  is  needed  to  start 
an  infestation  ot  iron  bacteria  in  a  well 

Hydrofluosihcic  acid  produces  poisonous  fumes 

Insoluble  deposits  should  be  removed  from 
chemical  feed  lines. 

In  the  lime  softening  process,  magnesium  is 
precipitated  out  as  magnesium  hydroxice. 

Caustic  soda  softening  may  be  used  instead  of 
soda  ash. 

Do  not  use  dry  ice  when  shipping  and  storing 
THM  samples  because  the  sample  water  can 
freeze  and  break  the  bottle. 

THMs  are  produced  faster  m  scale  forming 
waters  (hig*"  pH)  than  m  corrosive  waters. 

When  higher  mineral  concentrations  occur  in  the 
feedwater,  the  mineral  concentrations  will  in- 
crease in  the  product  water. 

An  increase  in  feedwater  temperature  will  in- 
crease the  water  flux. 

Sedimentation  tanks  should  be  inspected  and 
repaired  when  the  tanks  are  emptied  and 
cleaned. 

A  precoat  of  diatomaceous  earth  is  required  to 
dewater  gelatinous  alum  sludge  when  using  a 
vacuum  filter. 

Turn  off  power  and  check  both  power  lines  for 
voltage  before  changing  fuses. 


14  False 

15.  True 

16.  False 

17.  True 

18  True 

19  True 
20.  False 

21  True 

22  False 

23.  .  dise 
24  False 

25.  False 


Electrical  energy  is  com^^ionly  converted  into 
mechanical  energy  by  electric  motors. 

Always  replace  sprockets  when  replacing  a 
chimin. 

A  sensor  is  the  primary  element  that  measures  a 
variable. 

Thin  rubber  or  plastic  gloves  can  be  worn  to 
reduce  markedly  your  chances  of  electrical 
shock. 

If  an  operator  is  unsure  of  how  to  perform  a  job, 
then  It  IS  the  operator's  responsibility  to  ask  for 
the  training  needed. 

Inhalation  of  hydrochlonc  (HQ)  vapors  or  mists 
can  cause  damage  to  the  nasal  passage. 

Distilled  water  is  not  considered  pleasant  to 
drink. 

Dissolved  oxygen  in  water  can  contribute  to 
corrosion  in  piping  systems 

If  the  manganese  concentration  in  a  sample 
cannot  be  determined  immediately,  acidify  the 
sample  with  nitric  acid,  not  acetic  acid. 

Non-community  water  systems  serve  consum- 
ers at  least  60  days  a  year. 

i  he  MCL  compliance  for  trihalomethanes  is  de- 
termined by  3  running  average  of  four  quarter- 
ly averages. 

M  :hronic  toxic  agent  causes  injury  to  occur  over 
an  extended  period  of  time. 


ERLC 


568  Water  Treatment 


Multiple  Choice 

1.  1,2,3,4  Red  water  complaints  in  drinking  water 
may  be  caused  by  corrosive  water,  ferric 
hydroxide,  iron  bacteria  and  iron  in  the 
water 

2  2.  5  Chemicals  used  to  oxidize  iron  and  man- 

ganese include  chlorine  and  potassium 
permanganate. 

3  1 ,  2,  4,  5      Important  features  of  a  fluoridation  system 

include  prevention  of  ba^ksiphonage, 
leaks,  overfeeding  and  underfeeding 

4.  2,  4  When  shutting  down  a  fluoride  chemical 

feed  system,  operators  should  dram  and 
clean  the  mix  and  feed  tanks  and  flush  out 
all  se''jtion  lines. 

5.  1,  5  Betiefits  that  could  result  from  the  lime- 

soda  ash  softening  process  include  con- 
trol of  corrosion  and  removal  of  iron  and 
manganese.  Other  ftems  listed  are  limita- 
tions 

6  1,2,5         Records  that  should  be  kept  by  the  opera- 

tor of  an  ion  exchange  softening  plant 
include  blend  rates,  gallons  of  brine  used 
each  day  and  total  flow  per  day  that  by- 
passes unit. 

7  2  A  minimum  of  4  samples  per  quarter  (ev- 

ery 3  months)  for  THM  analysis  must  be 
taken  on  the  same  day  for  each  treatment 
plant  in  the  distribution  system. 

8.  2,  3,  5  Chloramines,  chlonne  dioxide  and  potas- 
sium permanganate  are  Group  1  tech- 
niques fot  controlling  THMs. 

9  1,  2,  4,  5  The  revf^rse  osmosis  elements  should  be 
cleaned  when  the  operator  observes  high- 
er differential  pressures,  higher  operating 
pressures,  lower  product  water  flow  rate, 
and  lower  salt  rejection. 

10  1,2,3.4      Problems  encountered  in  electrodialysis 

operation  include  alkaline  scales  in  the 
concentrating  compartments,  fouling  of 
membranes,  and  sealing  of  membranes  by 
both  organic  and  inorganic  materials, 

11  1 .  2,  4         Sludge  may  be  de\watered  by  the  use  of 

belt  filter  presses,  centrifuges  and  solar 
lagoons 

12  1 ,  3,  4,  5      Problems  created  b>  discharging  sludge  to 

sevi/ers  include:  fees  charged  could  be 
very  high,  monitoring  requirements  in- 
crease, operational  problems  may  develop 
at  wastewater  treatment  plant,  and  possi- 
bi.ity  of  causing  a  sewer  blockage. 

13  2,  5  A  good  maintenance  record  system  tells 

performance  of  equipment  and  when 
maintenance  is  due. 

14  1,  2,  3,  4,  5  A  voltage  tester  can  be  used  to  test  for 

blown  fuses,  grounds,  open  circuits,  single 
phasing  of  motors  and  voltage. 

15  2.3.4         Before  a  prolonged  shutdown,  pumps 

should  be  drained  to  prevent  damage  from 
corrosion,  freezing  and  sedimentation. 


22  1 ,  2,  3 


23.  2,  3,  4,  5 


16  5  Velocity-sensing  devices  measure  flows 

by  sensing  rate  of  rotation, 

17  1.2.4         Reliable  operation  of  pneumatic  instru- 

mentation pressure,  systems  requires 
clean  air,  dry  air  and  pressurized  air. 

18  1.2,  3.  4,  5  Ar  operator  must  accept  responsibility  for 

being  sure  that  safety  equipment  will  work 
when  needed  (your  life  may  depend  on  it), 
fellow  operators,  operator's  own  welfare, 
seeing  that  the  supervisor  complies  with 
safety  regulations  and  the  utility's  equip- 
ment 

19  1,2,4,5      Ammonia  cylinders  should  be  stored  in 

cool,  dry  locations  with  caps  in  place  when 
not  in  use  and  away  from  heat,  drcct 
sunlight  and  chlorine 

20  1 ,  2,  4         True  cole  •  is  normally  removed  or  at  least 

decreased  by  chlorination,  coagulation,  or 
ozonation. 

21.  2,  5  High  levels  of  nitrate  in  a  domestic  water 

supply  are  undesirable  because  of  the 
health  threat  due  to  infant  methemoglobin- 
ema  and  the  potential  for  stimulating  ex- 
cessive algal  growth 

Lead,  mercury  and  nitrate  are  primary  con- 
taminants which  a^s  considered  to  have 
pi'blic  health  importance. 

Turbidity  is  undesirable  in  drinking  water 
because  high  turbidity  interferes  with  dis- 
infection, interferes  with  microbiological 
determinations,  prevents  maintenance  of 
an  effective  disinfectant,  and  produces 
aesthetic  problems. 

24  1 ,  2,  4  Possible  approaches  for  a  utility  to  take  to 
protect  Its  water  supply  from  contamina- 
tion include  developing  an  extensive  de- 
tection and  monitoring  program,  fencing 
off  and  patrolling  reservoirs,  isolating  res- 
ervoirs that  offer  easy  accei^.s  to  the  g  aner- 
al  public,  and  maintaining  a  H/GH  chlonne 
residual  in  the  water 

25.  1,  2,  3,  4,  5  Important  uses  of  records  include  aiding 
operators  m  solving  treatment  and  water 
quality  problems,  anticipating  routine 
maintenance,  providing  data  for  future  en- 
gineering designs,  satisfying  legal  require- 
ments, and  showing  that  the  treated  water 
IS  acceptable  to  the  consumer. 

Short  Answers 

1  The  growth  of  iron  bacteria  can  be  controlled  by  main- 
taining a  free  chlonne  residual  at  all  times  throughout 
the  system. 

2  Water  being  treated  for  iron  and  manganese  by  ion 
exchange  should  not  contain  any  dissolved  oxygen 
because  the  resin  will  become  fouled  with  iron  rust  or 
insoluble  manganese  dioxide. 

3  Underfeeding  should  be  avoided  because  of  the  loss  of 
benefits  expected  from  fluoridation.  Overfeeding  should 
be  avoiding  due  to  the  potential  harm  to  consumers  and 
the  waste  of  chemicals  and  money. 


ERIC 

Ugr  ^   


583 


Final  Exam  569 


4.  Empty  fluoride  chemical  containers  can  be  disposed  of 
by  thoroughly  rinsing  all  containers  with  v^ater  to  re- 
move all  traces  of  chemicals  before  allowing  the  con- 
tainers to  leave  the  plant  Containers  may  be  burned  if  a 
nuisance  will  not  be  created  Remember  that  fluoride 
fumes  can  kill  vegetation. 

5.  Water  must  be  stabilized  after  softening  to  prevent 
corrosion  or  the  formation  of  scale  in  pipes 

6  The  same  chemical  hopper  or  feeder  should  not  be 
used  to  feed  both  lime  and  alum  because  the  resulting 
chemical  reactions  could  generate  enough  heat  to 
cause  a  fire. 

7  Tnhalomethanes  in  drinking  water  are  of  concern  to 
water  treatment  plant  operators  because  of  tie  possible 
heatlh  effects. 

8  Twenty-five  percent  of  the  samples  collected  for  THM 
analyses  are  collected  from  the  extremiti  js  of  the  distri- 
bution system  (the  farthest  points  from  the  plant)  and  75 
percent  must  be  representative  of  the  population 
served 

9.  The  common  membrane  demineralizing  processes  are 
reverse  osmosis  and  electrodialysis. 

10  "Flux  decline'  is  the  loss  of  water  flow  through  tho 
membrane  due  to  compaction  plus  fouling. 

11.  Sludge  can  be  removed  from  sedimentation  tanks  by 
mechanical  rakes  or  scrapers  or  a  vacuum-type  sludge 
removal  device  may  be  used. 

12  Source  v/ater  stabilizing  reservoirs  are  helpful  because 
they  reduce  the  turbidity  in  the  water  being  treated  and 
thus  reduce  the  volume  of  sludge. 

13,  A  qualified  electrician  ohould  perform  most  of  the  nec- 
essary maintenance  and  repair  of  electrical  equipment 
to  avoid  endangering  lives  and  to  avoid  damage  to 
equipment 

14.  Battery-powered  lighting  units  are  considered  better 
than  engine-dnven  power  sources  because  they  are 
more  economical  Also  if  you  have  a  momentary  power 
outage,  the  system  r^^^p'^nds  without  an  engine  gener- 
ator startup, 

15  A  suitable  screen  must  be  installed  on  the  intake  end  of 
pump  suction  piping  to  prevent  foreign  matter  (sticks, 
refuse)  from  being  sucked  into  the  pump  and  clogging 
or  wearing  the  impeller, 

16.  An  analog  instrument  has  a  pointer  (or  other  indicating 
means)  for  reducing  a  dial  or  scale. 

17  Liquid  levels  in  chemically-active  liquids  are  measured 
with  probes. 

18  Pumps  in  a  pump  station  can  be  operated  for  similar 
lengths  of  time  by  the  use  of  manual  or  automatic 
"sequencers "  which  switch  different  pumps  to  the  *'lead" 
pump  position  and  the  others  to  the  "lag"  position 
periodically. 

19  A  utility's  policy  statement  on  safety  should  give  its 
objective  concerning  the  operator's  welfare  The  state- 
ment should  give  the  utility's  recognition  of  the  need  for 
safety  to  stimulate  efficiency,  improve  sarvice,  improve 
moral  and  to  maintain  good  public  relations.  The  policy 
should  recognize  the  human  factor  (the  unsafe  act),  and 
emphasize  the  operator's  responsibility  The  operators 
should  be  provided  with  proper  equtpment  and  safe 


woi  king  conditions  Finally,  the  policy  must  reinforce  the 
supervisory  re^'ponsibility  to  maintain  safe  work  prac- 
tices 

20  Safety  regulations  prohibit  the  use  of  common  drains 
and  sumps  from  cherrncal  storage  areas  to  avoid  the 
possibility  of  chemicals  reacting  and  producing  toxic 
gases,  explosions  and  fires 

21  Problems  that  may  be  caused  by  iron  in  a  domestic 
water  supply  include  staining  of  laundry,  concrete,  and 
porcelain  A  bitter  astnngent  taste  can  be  detected  by 
some  people  at  levels  above  0  3  mg/L 

22  The  mam  source  of  tnhalomethanes  in  dnnkmg  water  is 
the  chemical  interaction  of  chlorine  added  for  disinfec- 
tion and  other  purposes  with  the  commonly  present 
natural  humic  substances  and  other  THM  precursors, 
produced  either  by  normal  organic  decomposition  or  by 
the  metabolism  of  aquatic  organisms 

23  Nitrate  concentrations  in  dnnking  water  above  the  na- 
tional standard  are  considered  an  immediate  threat  to 
children  under  three  months  of  age.  In  some  infants, 
excessive  levels  of  nitrate  have  been  known  to  react 
with  intestinal  bactena  which  change  nitrate  to  nitrite 
which  react  with  hemoglobin  in  the  blood  to  produce  an 
anemic  condition  commonly  known  as  "blue  baby.' 

24  High  levels  of  sulfate  ^le  undesirable  in  drinking  water 
because  they  tend  to  form  hard  scales  in  boilers  and 
heat  exchangers,  cause  taste  effects,  and  cause  a 
laxative  effect, 

25.  Ope»ators  can  improve  their  technical  knowledge  and 
skills  by  training.  Sources  or  types  of  training  include  on 
the  job,  trade  magazines  and  papers,  workshops,  for- 
mal training  in  classrooms,  and  home-study  courses. 

Problems 

1.  Determine  the  setting  on  a  potassium  permanganate 
chem  cal  feeder  in  pounds  per  day  if  the  chemical  dose 
IS  ?.1  vngIL  and  the  flow  is  0  53  MGD. 


Unknown 

Chemical  Feeder, 
lbs/day 


Known 

Flow.  MGD  -  0.53  MGD 
Dose,  mg/L  =  2.1  mg/L 

Determine  the  chemical  feeder  setting  in  pounds  per 
day 

Chemical  Feeder.  ^  ^p,Q^  MGD)(Dose,  mg/L)(8  34  lbs/gal) 
lbs/day 

(0  53  MGD)(2  1  mg/L)(8.34  lbs/gal) 
-  9  3  lbs/day 

Determine  the  setting  on  a  potassium  permanganate 
chemical  feeder  m  pounds  per  million  gallons  if  the 
chemical  dose  is  2  1  mg//_ 

Known  Unknown 

Dose,  mg/L  -  2.1  mg/L  Dose,  Ibs/MG 

Convert  the  dose  from  milligrams  per  liter  to  pounds  per 
million  gallons 

(Dose.  mg//-)(3.785  /-/gal)(  1.000,000) 
(1000  mg/gm){454  gm/lb){1  Million) 
(2  1  mg//_)(3  785  /_/gal)(1 ,000.000) 

(1000  mg/anOi^'^'l  gnr'lb)n  Mdhon) 

17  5  lt;S'^'G 


Dose,  Ibs/i. 


ERIC 


550 


570  Water  Treatment 


3  A  reaction  basin  17  feet  in  diameter  and  4  5  feet  deep 
treats  a  flow  of  400.000  gallons  per  day.  What  is  the 
average  detention  time  in  minutes'? 


Unknown 

Detonuon  Time,  mm 


Known 

Diameter,  ft  =  17  ft 
Depth,  ft  -  4  5  ft 
Flow.  GPD  =  400.000  OPD 

1 .  Calculate  the  basin  volume  in  cubic  feet 

Basin  Vol.  cu  ft  -  (U.785)(D:ameter,  ft)^(Depth.  ft) 

(0  785)(I7  ft)2(4.5) 

=  1021  cu  ft 

2  Convert  the  basin  volume  from  cub'c  feet  to  gallons. 
Basin  Vol,  gal  =  (Basm  Vol,  cu  ft)(7.48  gal/cu  ft) 

=  (1021  cu  ft)(7  48  gai/cu  ft) 
=  7637  gai 

3  Determine  the  average  detention  tin~e  in  minutes  in 
the  reaction  basin. 

Detention  Time.  ^  (Basin  Vol.  gal)(24  hr/day)(60  min/hr) 
"^'^  Flow,  gaii/day 

__  (7637  gal)(24  hr/day)(60  min/hr) 

400,000  gal/day 
^  27  5  minutes 

4  A  flow  of  0  8  MGD  is  to  be  treated  with  an  18  percent 
solution  of  hydrofluosilicic  acid  (H^SiFg).  The  water  to  be 
treated  contains  no  fluoride  and  the  desired  rJuonde 
concentration  is  1.1  mg/L.  Assume  the  hydrofluosilicic 
acid  weighs  9.6  pounds  per  gallon.  Calculate  the  hydro- 
fluo<iilicic  acid  feed  rate  in  gallons  per  day 

Known  Unknown 

Flow,  MGD        =08  MGD       Feed  Rate,  gai/day 
Acid  Solution,  %  =  18% 
Acid,  lbs/gal       -  9  6  lbs/gal 
Desired  F.  mg/L  -  1  1  mg/L 

1  Calculate  the  hydrofluosilicic  acid  feed  rate  in  pounds 
per  day 

Feed  Rate.    (Row  MGDHDesired  F.  mg/i-)(8  34  lbs/gal)(  1 00%) 
'^^^^^^  Actd  Solution.  % 

(0  8  MGD)(1  1  mg/f.)(8  34  Ibs/gal)(l00  o) 
18% 

41  lbs  acid/day 

2  Determine  the  leed  rate  of  the  acid  in  gallons  per  day. 

Feed  Rate,  ^  Feed  Rate,  lbs/day 
gal/day  ^^g"^i 

41  lbs/day 


9  6  lbs  acid/gal  acid 

4.3  gal  acid/day 

5.  A  flow  of  400  GPM  IS  to  be  treated  with  a  2.4  percent 
(0.2  pounds  per  gallon)  solution  ot  sodium  fluonde 
(NaF).  The  water  to  be  treaieri  contains  0.5  mg/L  of 
fluonde  ion  and  the  desired  'luoride  icn  concentration  is 
0  9  mg/L  Calculate  the  sodium  fluoride  feed  rate  in 
gallons  pp  day.  Assume  the  soaium  fluoride  has  a 
fluoride  purity  of  43.4  percent. 


ERIC 


0  2  lbs/gal 


Known  Unknown 

Flow,  MGD  400  GPM       Feed  Rate,  gal/day 

NaF  Solution.  %  -  2  4% 
NaF  Solution. 
!bs/gal 

Desired  F.  mg/L  -  09  mg/L 
Actual  F.  mg/L  -  0.5  mg/L 
Purity.  %  -  43.4% 

1  Convert  the  flow  from  gallons  per  minute  to  million 
gallons  per  day 

Flow.    „  (Flow.  gal/min)(60  mtn/hr)(24  hr/day)(1  Million) 

^:ooo:ooo  ~ 

.  (400  gal/min)(60  nnn/hr)(24  hr/day)(1  Million) 
1,000,000        "  " 

-  0  576  MGD 

2  DeterminG  the  fluoride  dose  in  milligrams  per  liter. 
Feed  Dose.  mg/L    Desired  Dose,  mg/l    Actual  F,  mg/L 

-  0  9  mg//.  -  0.5  mg/L 

-  0  4  mg/L 

3-  Calculate  the  feed  rate  in  pounds  of  fluoride  ion  per 
day. 

pppH  potp 

lbs  F/day  MGD)(Feed  Dose.  mg/iL)(8  34  lbs/gal) 

-  (0.576  MGD)(0  4  mg/L)(8,34  ibs/gal) 

-  1.9  lbs/day 

4  Convert  the  feed  rate  from  pounds  of  fluonde  per  day 
to  gallons  of  sodium  fluoride  solution  per  day. 

Feed  Rate,  ^    (Feed  Rate,  lbs  F/day)(lOO%) 
gal/day     ^^^^  Solution,  lbs  F/gal)(Purity,  %) 

^(19  lbs  F/day)(lOO%) 
(0.2  lbs/gal)(43.4%) 
=  22  gal/day 

6  How  many  gallons  of  water  with  a  hardness  of  1 5  grains 
per  gallon  may  be  treated  by  an  ion  exchange  softener 
with  an  exchange  capacity     24,000  kilograms? 

Known  Unknown 


Hardness, 
grains/gal 


^  15  grains/gal 


Water  Treated, 
gallons 


Exchange 
Capacuy,  -  24,000.000  grasns 
grains 

Calculate  the  gallons  of  water  that  may  be  treated. 

Water  Treated,  gal  ^  Exchange  Capacity,  grains 
Hardness,  grains/gal 
^  24,000.000  grains 

15  grains/gal 
-  1.600,000  gallons 
=  1  6  M  gallons 

7.  How  many  hours  will  an  lon  exchange  softening  unit 
operate  when  treating  an  average  flow  of  350  GPM? 
The  unit  is  capable  of  softening  700,000  gallons  of 
water  before  requinng  regeneration. 


591 


Final  Exam  571 


Known  Unknown 
Ave  Daily  Flow,  GPM  -  350  GPM      Operating  Time. 
Water  Treated  gal     -  700,000  gal  hr 

Estimate  how  many  hours  the  softening  unit  can  oper- 
ate before  requiring  regeneration 


Operating  Time,  hr 


Water  Treated  gal 


(Ave  Daily  Flow.  gal/min){60  min/hr) 
700.000  gal 


(350  gal/min)(60  min/hr) 
-  33  3  hours 

8.  A  water  utility  collected  and  analyzed  eight  samples 
from  a  water  distribution  systen  on  the  same  day  for 
TTHMs.  The  results  are  shown  below 


1  2  3  4  5  6  7  8 
90  100  120  90  80  110  120  80 


Sample  No. 
TTHM.  ^Q/L 

What  was  the  average  for  the  day'? 

Known  Unknown 

Re  Jits  from  analysis  of  8       Average  TTHM  level 
TTiiM  samples  for  the  day 

Cv.  Jiale  the  average  TTHM  level  in  micrograms  per 
liter 

Ave  TTHM     Sum  of  Measurements,  ^g'L 
^^^^  Number  of  Measurements 

90^q/L  .  ^OO^g|L  •  120  ^g/f.  '  90  ^g|L 
'  bOugji  '  110;^g/f.  •  }2QnglL  •  80  ^g/£. 

790  i/g/i 
8 

99  ^g|L 

9  The  results  of  the  quarterly  average  TTHM  measure- 
ments for  two  years  are  given  below  Calculate  the 
running  annual  average  of  the  four  quarterly  measure- 
ments in  micrograms  per  liter 


Quarter 


1     2      3    4     1      2     3  4 


^"TT^T^nl^i  ^3   98  118  92  84  112  121  79 

TTHM  ^Q/L 


Known 


Unknown 


Results  from  analysis  of  2  Running  annual  aver- 
years  of  TTHM  sampling         age  of  quarterly  TTHM 

measurements 

Calculate  the  running  annual  average  of  the  quarterly 
TTHM  measurements 

Annual  Running  TTHM     Sum  of  Ave  TTHM  for  Four  Quarters 

Averago  uQ/L  '  —   ;       -  -   

Number  o*  OuarierS 

QUARTERS  1.  2  3  AND  4 

Annual  Running  TTHM     73hglL  •  98^9//-  •  )\S  uglL  •  92  i,gjL 
Average  hqiL  '  ■  - 

4 

381  i.g.L 
4 

95  i,g;L 


ERIC 


QUARTERS  2  3.  4  AND  1 

A.muai  Running  TTHM     98  ug/L  •  1 18  ugfL     92  ugfL  •  84  ug/i 
Average  uglL  —  '  —j-  

392  ^gli 
4 

98  ug/i 

QUARTERS  3.  4.  1  AND  2 

Annual  Running  TTHM     118  ^g/L  •  92  ng/L  •  84  ug/L  •>  11?  ugfL 
Average  ng(L  ^  

406  ug/L 
4 

102  ugfL 

QUARTERS  3.  4.  1  AND  2 

Annual  Running  TTHM     92  ugfL  •  84  ugfL  ♦  ll2Mg/l  •  121  ^ig/L 
Average  ugfL  ^     '  ^  

409  *ig//L 
4 

102  ug/L 

QUARTERS  1.  2.  3  AND  4 

Annual  Running  TTHM     84  ug/L  •  112  t^g!L  -  121  ug/L  •  79  ug/L 
Average  ^glL  

396  Mg/l 
4 

99i.g/L 

summmry  of  results 

Quarter  1     2     3    4     1      2     3  4 

73   98  118  92   84  112  121  79 


Ave  Quarterly 
TTHM.  ^g/L 


Annua!  Running 
TTHM.  ^g/L 


95   98  102  102  99 


10  Estimate  the  ability  oi  a  reverse  osmosis  plant  to  reject 
minerals  by  calculating  the  mineral  rejection  as  a  per- 
cent The  feedwater  contains  1600  mg/L  TDS  and  the 
product  water  is  145  mg/L 


Known 

Feedwater  TDS. 
mg/L 

Product  Water  TDS. 
mg/L 


Unknown 

1600  mg/L  ^inera^ 

^  Rejection.  % 

145  mg/L 


Calculate  the  mineral  rejection  as  a  percent 

Mineral  Rejection  %    (1    ^Jfl^fJ  '^^^j  ""^1^.  )(100%) 
Feed  TDS.  mg/L 

1600  mg/L 
(1     0  09)(100%) 
91% 


592 


572  Water  Treatment 


1 1  Estimate  the  percent  recovery  of  a  reverse  osmosis  unit 
with  a  4-2-1  arrangement  if  the  feed  flow  is  2  4  MGD  and 
the  product  flow  is  2.0  MGD 


Known 

Product  Row.  MGD  2  0  MGD 
Feed  Flow,  MGD     -  2  4  MGD 

Calculate  the  recovery  as  a  percent. 

(Product  Flow,  MGD)(100S) 


Unknown 

Recovery, 


Recovery. 


Feed  Flow.  MGD 
(2  0  MGD)(100^ 
2  4  MOD 


^  83% 

12  Calculate  the  pumping  capacity  of  a  pump  in  gallons  per 
minute  if  14  minutes  are  required  for  the  water  level  in  a 
tank  to  drop  4.5  feet  The  tank  is  11  feet  in  diameter 

Unknown 


Pump  Capacity. 
GPM 


Known 

Drop,  ft  -  4.5  ft 

Diameter,  ft  -  11  ft 

Pumping  Time,  mm    14  mm 

1  Calculate  the  volume  pumped  m  gallons 

Volume,  gal    {0  785)(Diameter.  ft)2(Drop.  ft)(7  48  gal/cu  ft) 
-  (0  785)(1 1  ft)2(4  5  ft)(7  48  gal/cu  ft) 
3197  gallons 

2  Estimate  the  pi'mpmg  capacity  m  gallons  per  minute 
Pumping  Capa'^.ty.  _  Volume  Pumped,  gallons 

Pumpjng  Time,  mm 
3197  gallons 

1 4  mm 
228  GPM 

13  Calculate  the  feed  rate  of  a  dry  chemical  feeder  m 
pounds  per  day  if  2.8  pounds  of  chemical  are  caught  m  a 
weighing  tin  dunng  eight  minutes 


Known 

Chemical,  lbs  =  2.8  lbs 
Time,  mm      ^  8  mm 


Unknown 

Chemical  Feed, 
lbs/day 


Calculate  the  chemical  feed  rate  in  pounds  of  chemical 
per  day. 

Chemical  Feed.  .(Chemical,  lbs)(60  min/hr)(24  hr/day) 
lbs/day 

(2  8  lbs)(60  min/hr)(24  hr/day) 
8  min 

504  lbs/day 

14.  Calculate  the  threshold  odor  number  (T.O.N.)  for  a 
sample  when  the  first  detectable  odor  occurred  when 


the  35  mL  sample  was  diluted  to  200  mL  (165  mL  of 
odor-free  water  was  added  to  the  35  mL  sample). 

Known  Unknown 

Size  of  Sample,  mL       35  mL  TON 
Odor-Free  Water.  mL  -  165  mL 

Calculate  the  threshold  odor  number,  TON 
TON  Sample,  mL  ^  Odor-Free  Water,  mL 

Size  of  Sample.  mL 
35  mL  •  165  mL 


35  mL 


-  6 


1 5  Determine  tne  taste  rating  for  a  water  by  calculating  the 
arithmetic  mean  for  the  panel  ratings  give  below 

Tester  No  1     2     3    4     5     6  7 

Rating  4     2     7     3     6     5  8 

Known  Unknown 

Taste  Ratings  Anthmetic  Mean,  X 

Calculate  the  arithmetic  mean  X,  taste  ratng 

Arithmetic  Mean  X     X,  -  X2  •  X3  '  X4  •      •  Xg  -  X7 


Taste  Rating 


4-2-7^3^6*5-8 


35 
7 
5 


16  A  small  water  system  collected  12  samples  during  one 
month  After  each  sample  was  collected,  10  mL  of 
sample  was  placed  in  each  of  5  fermentation  tubes.  At 
the  end  of  the  month,  the  results  indicated  that  3  out  of  a 
total  of  60  fermentation  tubes  were  positive  What 
percent  of  the  portions  tested  dunng  the  month  were 
positive'? 


Known 

-  3  positive/mo 

Total  Portions 


Number 
Positive/mo 


Unknown 

Positive  Portions, 

%/mo 


Tested 


60  portions 


Calculate  the  percent  of  portions  tested  during  the 
month  winch  were  positive 

Portions  Positive,  %/mo    (Number  Pos.t.ve/mo)(100%) 

Total  Portions  Tested 
(3  positive/mo)(lOO^o) 
60  portions 

-  5°'o/mo 


EMC 


593 


APPENDIX 

HOW  TO  SOLVE  WATER  TREATMENT  PLANT 
ARITHMETIC  PROBLEMS 


(VOLUME  II) 
by 

Ken  Kerri 


594 


574 


Water  Treatment 


TABLE  OF  CONTENTS 

HOW  TO  SOLVE  WATER  TREATMENT  PLANT  ARITHMETIC  PROBLEMS 


Page 

A.I     Basic  Conversion  Factors  (English  System)  575 

A.2     Basic  Formulas   575 

A.3     Typical  Water  Treatment  Plant  Problems  578 

A.30     Iron  and  Manganese  Control  578 

A.31      Fluondation  578 

A.32      Softening   580 

A  33     Tnhfilomethanes     583 

A.34     Demineralization  584 

A  35      Maintenance   534 

A.36     Safety  585 

A  37      Advanced  Laboratory  Procedures  585 

A.4     Basic  Conversion  Factors  (Matnc  System)   587 

A.5     Typical  Water  Treatment  Plant  Problems  (Metric  System)  587 

A.50      Iron  and  Manganese  Control  587 

A.51      Fluondation    588 

A  52      Softening     599 

A  53     Tnhalomethanes   593 

A. 54      Demineralization  594 

A.55      Maintenance  594 

A.56     Safety  595 

A.57     Advanced  Laboratory  Procedures  595 


ERLC 


595 


Arithmetic  575 


SOLVING  WATER  TREATMENT  PLANT  OPERATION  PROBLEMS 

(VOLUME  II) 


A.1    BASIC  CONVERSION  FACTORS  (ENGLISH  SYSTEM) 

UNITS 

1,000.000=  1  Million  1,000,000/1  Million 


DENSITY 


LENGTH 


12  in  = 
3  ft  = 
5280  ft  = 


AREA 


VOLUME 


7 AS  gal  = 
1000  mL  = 

3.785  L  -- 
231  cti  in  ^ 


WEIGHT 


POWER 


1  ft 
1  yd 
1  mi 


144  sq  in  =  1  sq  ft 
43,560  sq  ft  =  1  acre 


cu  ft 
liter 
gal 
gal 


1000  mg=  1  gm 
1000  gm=  ^  ■ 
454  gm  -- 
2  2  lbs  ^ 


1  kg 
=  1  lb 

;-1  kg 


0.746  kw-  1  HP 


12  in/ft 
3  ft/yd 
5280  ft/mi 


144  sq  in/sq  ft 
43,560  sq  ft/ac 


7.48  gal/cu  ft 
1000  mL/L 
3.785  L/gal 

231  cu  in/gal 


1000  mg/gm 
1000  gm/kg 
454  gm/lb 
2.2  lbs/kg 


0.746  kw/HP 


8.34  lbs  = 
62  4  lbs  = 


1  gal 
1  cu  ft 


DOSAGE 

17.1  mg/L=  1  gram/gal 
64.7  grains  =  1  mg 

PRESSURE 


8.34  lbs/gal 
62.4  Ibs/cu  ft 


17  1  mg/L/gpg 
64.7  grams/mg 


2.31  ft  water  =  1  psi 
0.433  psi=  1  ft  water 


2.31  ft/psi 

  0.433  psi/ft 

1  133  ft  water  =  1  in  Mercury  1.133  ft  water/m  f^ercury 


FLOW 


694  GPM 
1  55CFS^ 


1  MGD 
1  MGD 


TIME 


60  sec 
60  mm 


1  mm 
1  hr 
24  hr=  1  day 


694  GPM/MGD 
1.55CFS/MGD 


60  sec/min 
60  min/hr 
24  hr/day 


NOTE 


in  our  conversion  factors  the  values  in  the  right 
hand  column  may  be  written  either  as  24  hr/day  or  1 
day/24  hours  depending  on  which  units  we  wish  to 
convert  to  our  desired  results. 


ERLC 


A.2    BASIC  FORMULAS 

IRON  AND  MANGANESE 

la.  Stock  Solution, 
mg/mL 


lb.  Dose,  mg/L 

1c   Dose,  Ibs/MG 

2.  Chemical  Feeder. 

lbs/day 

3.  Detention 

Time,  mm 

4     KMnO^  Dose,  mg/L 

FLUORIDATION 

5.    Feed  Rate, 
gal/day 


CONTROL 

^(Polyphosphate.  grams)(1000  mg/gm) 

(Solution,  liter)(1000  mL/L) 
^  (Stock  Solution,  mg/mL)(Volume  Added,  mL) 

Sample  Volume,  L 
^  (Dose,  mg/L)(3.785  L/gal)(1 ,000,000) 
(I000mg/gm)(454  gm/lb)(1  Million) 

=  (Flow.  MGD)(Dose,  mg/L)(8  34  lbs/gal) 

^(Basm  Vol,  gai)(24  hr/day)(60  min/hr) 

Row,  gal/day 
=  0.6(lron,  mg/L)  ^  2.0(Manganese,  mg/L) 


^    (Feed  Rate,  lbs  F/day)(lOO%) 
(NaF  Solution,  lbs  F/gal)(Purity,  %) 


596 


576  Water  Treatment 


6    Feed  Solution, 
gal/day 

7.    Fluoride  Ion 
Purity.  % 

8a  Feed  Dose.  mg/Z. 

8b.  Feed  Rate, 
lbs/day 

9    Feed  Solution, 
gal 


10 


Mixture 
Strength.  % 


^  (Flow.  gal/day)(Feed  Dose,  mg//.) 

Feed  Solution.  mg/Z. 
^(Molecular  Weight  of  Fluonde)(l007o) 

Molecular  Weight  of  Chemical 
=  Desired  Dose,  mg/Z.  -  Actual  Cone,  rug/L 
Feed  Rate,  lbs  F/day 
lbs  F/lb  Commercial  Na^SiFg 
^(Flow  Vol,  gal)(Feed  uose.  mg/Z.) 

Feed  Solution.  mg/Z. 
^  (Tank,  gal)(Tank  %)  -f  (Vendor,  gal)(Vendor.  %) 
Tank,  gal  +  Vendor,  gal 


SOFTENING 


ERIC 


11. 


12. 


Total  Hardness,    _Calcium  Hardness.  ^Magnesium  Hardness. 
mg/Z_  as  CaCOg      mg/Z_  as  CaCOg       mg/Z_  as  CaCOg 

If  alkalinity  is  greater  than  total  hardness. 


^Total  Hardness. 
mg/Z.  as  CaCOg 


13. 


Carbonate  Hardness. 
mg/Z_  as  CaCOg 

and 

Noncarbonate  Hardness.  _  q 
mg/Z_  as  CaCDg 

If  alkalinity  is  less  than  total  hardness, 

=  Alkalinity,  mg/Z.  as  CaCOg 


Carbonate  Hardness 
mg/Z_  as  CaCOg 

anj 


Noncarbonate  Hardness, 
mg/i  as  CaCOa 

14a.  Phenolphthalein 
Alkalinity. 
mg/L  as  CaCOg 

14b  Total  Alkalinity, 

mg/Z-  as  CaCOg 

15a.  Hydrated  Lime 

(Ca(0H)2)  Feed.  mg/Z_ 

15b.  Soda  Ash  (NajCOg) 
Feed.  mg/Z. 

15c.  Total  CO2  Feed, 
(bs/day 

16     Feeder  Setting, 
lbs/day 

17.    Feed  Rate.  Ibs/min 

18     Hardness,  mg/Z. 

1 9.  Exchange  Capacity. 

grains 

20.  Water  Treated,  gal 


Total  Hardness.   _  Alkalinity. 
mg/Z.  as  CaCOg      mg/Z.  as  CaCOg 

^A  X  N  X  50.000 
mZ.  of  sample 

^  B  X  N  X  50.000 
mZ.  of  sample 

(A    B  -f  C  -f  D)1.15 
Purity  of  Lime,  as  a  decimal 

_/  Noncarbonate  ^3''dness.w^Qg,-|QQx 
mg/Z.  as  CaCOg  '  ' 

=  (Ca(0H)2  excess.  mg/q(44/74) 
+  (Mg2*  residual.  mg/q(44/24.3) 

=  (Flow.  MGD)(Conc.  mg/L)(8  34  lbs/gal) 

^  Feeder  Setting,  lbs/day 
(60  mrn/hr)(24  hr/day) 
■  (Hardness,  grains/gal)(17.1  mg/L) 
1  grain/gal 

=  (Resin  Vol.  cu  ft){  Removal  Capacity. 

grains/cu  ft  ' 

-  Exchange  Capacity,  grains 

Hardness,  grains/gal 


597 


Arithmetic  577 


ERIC 


21.  Operating  Time,  hr 

22.  Salt  Needed,  lbs 

23     Bypass  Flow.  GPD 

TRIHALOMETHANES 

24.  Ave  TTHM,  ^g|L 

25.  Annual  Running  TTHM 

Average,  ^g/l. 

DEMINERAUZATION 

26.  Flow,  GPD/sq  ft 

27.  Mineral  Rejection,  % 

28.  Recovery,  % 

29.  Pump  Capacity,  GPM 

30.  Flew,  GPD 

31.  Polymer  Feed, 

lbs/day 

32.  Chemical  Feed. 

lbs/day 

SAFETY 

33.  Injury  Freq  Rate 

34.  Injury  Severity  Rate 


Water  Treated,  gal 


(Ave  Daily  Flow,  gal/mtn)(60  min/hr) 

Salt  Required,  .  /  Haidness  Removed,  gr^ 
lbs/1000  nr  ^ 

^  (Total  Flow,  GPD){Plant  EffI  Hardness,  gpg) 
Raw  Water  Hardness,  gpg 

^  Sum  ot  f/.easurements,  ^g|L 

Number  of  Measurements 
^  Sum  of  Ave  TTHM  for  Four  Quarters 
Number  of  Quarters 

^(Flux,  gm/sq  cm-sec)(1  Liter)(1  Gal)(100  cm)2  (3600  sec)(24  hr) 


(1000  gm)(3.785  L)(3.28  ft)2 

,  Product  TPS,  mg/L  ^^mn^A) 
Feed  TDS,  mg/L 
^(Product  Flow,  MGD)(100%) 

Feed  Flow,  MGD 
^  Tank  Volume,  gal 


(1  hr)(1  day) 


Pumping  Time  mm 
^(Volume  Pumped,  gal)(24  hr/day) 
Time,  hr 

^(Poly  Cone,  mg/L)(Vol  Pumped,  mL)(60  min/hr)(24  hr/day) 
(Time  Pumped,  min)(1000  mL/L)(1000  mg/gm)(454  gm/lb) 
^(Chemical,  gm)(60  min/hr)(24  hr/day) 
(454  grTi/lb)(Time,  mm) 

^  (Injuries,  number/yr)(1 ,000,000) 

Hours  Worked,  number/yr 
^(Number  of  Hours  Lost/yr)  (1,000,000) 


Number  of  Hours  Worked/yr 
ADVANCED  LABORATORY  PROCEDURES 


35.  Threshold  Odor 

Number  (T.O.N.) 

36.  Geometric  Mean 

37.  Threshold  Taste 

Number 

38a.  Antiemetic  Mean,  X 
Taste  Rating 

38b.  Standard  Deviation,  S 
Taste  Rating 


.  Size  of  Sample,  mL  +  Odor-Free  Wate*-,  mL 

Size  of  Sample,  mL 
=  (X^  X     X  X3  X  . . .  XJ^/" 

^  Size  of  Sample,  mL  -j-  Taste-Free  Water,  mL 

Size  of  Sample,  mL 
^  X,  4.  X,  +  X3     ■  ■  ■  X„ 


or  = 


j*  (X,  -  x)^  +  (X,  -  x)^  +  ■  ■  (x„  -  X)^  j  °' 

pX.^  +  X./+  ...  X„^)  -  (X,  +  X,  +  ■  ■  ■  X„)^  /n  j 


39.    Portions  Positive.  %       .(Number  Positive/mo)(1 00%) 


Total  Portions  Tested 


598 


578  Water  Traatment 


A.3   TYPICAL  WATER  TREATMENT  PLANT  PROBLEMS 


EXAMPLE  3 


A.30  Iron  and  Manganese  Control 
EXAMPLE  1 

A  standard  polyphosphate  solution  is  prepared  by  mixing 
and  dissolving  1 .0  grams  of  polyphosphate  in  a  container 
and  adding  distilled  water  to  the  one-liter  mark.  Determine 
the  concentration  of  the  stock  solution  in  milligrams  per 
milliliter.  If  6.0  milliliters  ot  the  stock  solution  are  added  to  a 
one-liter  sample,  what  is  the  polyphosphate  dose  in  milli- 
grams per  liter  and  pounds  per  million  gallons? 

Known  Unknown 

Polyphosphate,  gm  =  1.0  gm  1.  Stock  Solution,  mg/mL 
Solution.  L  =  1.0  L        2.  Dose,  mg/L 

Stock  Solution,  mL  =  6  mL        3.  Dose,  Ibs/MG 
Sample,  L  =  1  L 

1.  Calculate  the  concentration  of  the  stock  solution  in  milli- 
grams per  milliliter. 

Stock  Solution,  ^(Polyphosphate.  gm)(1000  mg/gm) 
"^^1"^^  (Solution,  L){  1 000  mL/L) 

^(1.0gm)(lOOO  mg/gm/ 

(1  L)(1000  mL/L) 
=  1.0  mg/mL 

2  Determine  the  polyphosphate  dose  m  the  sample  in 
milligrams  per  liter. 

Dose,  mg/L  =  (Stock  Solution,  mg/mL)(Vol  Added,  mL) 
Sample  Volume,  L 
^(10  mg/mL)(6  mL) 
1L 

-  6.0  mg/L 

3  Determine  the  polyphosphate  dose  m  the  sample  in 
pounds  of  phosphate  per  million  gallons. 

Dose,  Ibs/MG  =.(Dose,  mg/L)(3.785  L/gal)(1. 000,000) 
(1000  mg/gm)(454  gm/lb)(1  m\\\on) 
^(6.0  mg/L)(3.785  L/gal)(1 ,000,000) 
(1000mg/gm)(454gm/lb)(1  mUon) 
-  50  lbs/f\/lG 

EXAMPLE  2 

Determine  the  chemical  feeder  setting  in  pounds  of  poly- 
phosphate per  day  if  0.62  MGD  is  treated  with  a  dose  of  6 
mg/L 


A  reaction  basin  14  feet  m  diameter  and  4  feet  deep  treats 
a  flow  of  240.000  gallons  per  day.  What  is  the  average 
detention  time  in  minutes'? 


Unknown 

Chemical  Feeder,  lbs/day 


Known 

Flow,  MGD  =0.62  MGD 
Dose,  mg/L  =  6  mg/L 

Determine  the  chemical  feeder  setting  in  pounds  per  day. 
^^bT/Sy^^^^^^^  "  MGD)(Dose,  mg/L)(8.34  lbs/gal) 


=  (0.62  MGD)(6  mg/L)(8.34  lbs/gal) 
=  31  lbs/day 


Unknown 

Detention  Time,  mm 


Known 

Diameter,  ft  -  14  ft 
Depth,  ft      =4  ft 
Flow,  GPD   =  240,000  GPD 

1.  Calculate  the  bas.n  volume  in  cubic  feet. 

Basin  Vol.  cu  ft  =  (0.785)(Diameter.  ft;2(Depth.  ft) 

=  (0.785)(14  ft)2(4  ft) 

=  615  cu  ft 

2  Convert  the  basin  volume  from  cubic  feet  to  gallons. 
Basin  Vol,  gal  =  (Basin  Vol,  cu  ft)(7.48  gal/cu  ft) 
=  (615  cu  ft)(7.48  gal/cu  ft) 
=  4600  gal 

3.  Determine  the  average  detention  time  in  minutes  for  the 
reaction  basin. 

Detention  Time,  ^  (Basin  Vol,  gal)(24  hr/day)(60  min/hr) 

Flow,  gal/day 
^(4600  gal)(24  hr/day)(60  min/hr) 

240,000  gal/day 
=  28  minutes 

EXAMPLE  4 

Calculate  the  potassium  permanganate  dose  in  milligrams 
per  liter  for  a  well  water  with  2.4  mg/L  iron  before  aeration 
and  0.3  mg/L  after  aeration.  The  manganese  concentration 
IS  0.8  mg/L  both  before  and  after  aeration. 

Known  Unknown 

Iron,  mg/L  =  0.3  mg/L        KMnO^  Dose.  mg/L 

Manganese,  mg/L  =08  mg/L 

Calculate  the  potassium  permanganate  dose  in  milligrams 
per  liter 

KMnO^  Dose.  mg/L  -  0  6(lron.  mg/L)  +  2  0(Mangarese.  mg/L) 
-  0  6(0.3  mg/L)  +  2  0(0  8  mg/L) 
=  1  78  mg/L 

NOTE:  If  there  are  any  oxidizable  compounds  (organic 
color,  bactena.  or  hydrogen  sulfide)  in  the  water, 
the  dose  v^ill  have  to  be  increased. 

A.31  Fluoridation 

EXAMPLE  5 

Determine  the  setting  for  a  chemical  feed  pump  in  gallons 
per  day  when  the  desired  fluoride  dose  is  1.8  pounds  of 
fluoride  per  day.  The  sodium  fluoride  solution  contains  0.2 
pounds  of  fluoride  per  gallon  and  the  fluoride  purity  is  43.4 
percent. 

Known  Unknown 

Feed  Rate,  lbs  F/day    =  1.8  lbs  F/day        Feed  Rate. 
NaF  Solution,  lbs  F/gal  =  0.2  lbs  F/gal  gal/day 
Purity.  %  =  43.4% 


ERIC 


599 


Arithmetic  579 


Determine  the  setting  on  the  chemical  feed  pump  in  gallons 
per  day. 

Feed  Rate.  ^    (Feed  Rate,  ibs  F/day)(lOO%) 
gal/day     ^^^p  solution,  lbs  F/gal)(Pur:ty.  %) 

^(1.8  Ibs  F/day)(lOO%) 
(0.2  Ibs  F/gal)(43.4%) 

=  20  J  gal/day 

or  =  21  gal/day 

EXAMPLE  6 

Determine  the  setting  on  a  chemical  feed  pump  in  gallons 
per  day  if  500.000  gallons  per  day  of  water  must  be  treated 
with  0.9  mg/L  of  fluonde.  The  fluonde  feed  solution  contains 
18.000  mg/L  of  fluoride. 

Known  Unknown 

Flow,  gal/day  =  500.000  gal/day  Feed  Pump, 

Fluonde.  mg/L         =  0.9  mg/L  gal/day 
Feed  Sol'Jtion.  mg/L  =  18.000  mg/L 

Determine  the  setting  on  the  chemical  feed  pump  in  gallons 
per  day. 

Feed  Solution.  ^(Flow.  gal/day)(Feea  Dose.  mg/L) 
S^'/^^y  Feed  Solution.  mg/L 

^  (500.000  gal/day)(0.9  mg/L) 

18.000  mg/L 
=  25  gal/day 

EXAMPLE  7 

Determine  the  fluonde  ion  purity  of  Na^SiFg  as  a  percent. 
Known  Unknown 
Fluoride  Chemicai.  NajSiFg         Fluorjd*^  Pun^v  % 
Determine  the  molecu'ar  weight  of  fluoride  and  NajSi'-g. 
Symbol      (No.  Atoms)  (Atomic  Wt)  =  Molecular  Wt 


Na 


45.98 
28.09 
11400 


(2)  (22.99) 
Si  ^  (1)  (28.09) 

Ffi  (6)  (19.00)  -  

Molecular  Weight  of  Chemical        =       1 88  07 
Calculate  the  fluoride  ion  purity  as  a  percent. 
Fluoride  Ion  ^  (Molecular  Weight  of  Fluoride)(lOO%) 
Punty.  %        (Molecular  Weight  of  Chemical) 

^(114.00)(100%) 

188.07 
=  60.62% 


EXAMPLE  8 

A  flow  of  1.7  MGD  is  treated  with  sodium  silicofluoride. 
The  raw  water  contains  0.2  mg/L  of  fluoride  ion  and  the 
desired  fluoride  concentration  is  1.1  mg/L.  What  should  be 
the  chemical  feed  rate  in  pounds  per  day?  Assume  each 
pound  of  commercial  sodium  silicofluoride  (NajSiFg)  con- 
tains 0.6  pounds  of  fluoride  ion. 


Known  Unkno  Nn 

Flow,  MGD  1 .7  MGD        Feed  Rate,  lbs/day 

Raw  Water  F,  mg/L  ^  0.2  mg/L 
Desired  F,  mg/L  =  1  1  mg/L 
Chemical.  Ibs  F/lb    =  0  6  Ibs  F/lb 

1.  Determine  the  fluoride  feed  dose  in  milligrams  per  liter. 

Feed  Dose,  mg/L  =  Desired  Dose.  mg/L  -  Actual  Cone.  mg/L 

-  1  1  mg/L  -  0  2  mg/L 

=  09  mg/L 

2  Calculate  the  fluoride  feed  rate  in  pounds  per  day. 

^^IDS  F/day  "         '^^^Hreed  Dose.  mg/L)(8  34  lbs/gal) 
=  (17  MGD)(0.9  mg/L)(8  34  lbs/gal) 
=  12  8  Ibs  F/day 

3.  Determine  the  chemical  feed  rate  in  pounds  of  commer- 
cial sodium  silicofluonde  per  day. 


Feed  Rate. 


Fee     ate.  lb  r'/day 


lbs/day  ^j^^  Commercial  NagSiFg 

^  1 2.8  Ibs  F/day  

0.6  lbs  h/lb  Commercial  NagSiFg 
=  21.3  lbs/day  Commercia'  NagS'Fg 


EXAMPLE  9 

The  feed  solution  from  a  saturator  containing  1 .8  percent 
fluorido  ion  is  used  to  treat  a  total  flow  of  250.000  gallons  of 
water.  The  raw  water  has  a  fluoride  ion  content  of  0.2  mg/L 
and  the  desired  fluonde  level  in  the  treated  water  is  0.9  nig/ 
L.  How  many  gallons  of  feed  solution  are  needed? 

Known  Unknown 

Flow  Vol.  gal        =  250.000  gal     Feed  Solution,  gallons 
RawWater  F.  mg/L  =  0.2  mg/L 
Desired  F.  mg/L     =  0.9  mg/L 
Feed  Solution.  %F  =  1.8%  F 

1.  Convert  the  feed  solution  from  a  percentage  fluonde  ion 
to  milligrams  fluoride  ion  per  liter  of  water. 

1  0%  F  =  10.000  mg  F/L 

Feed  Solution.  mg/L  .  (Feed  Solution.  %)(1 0.000  mg/L) 

1.0°/- 

^(1.8%  F)(1 0.000  mg/L) 
1.0% 

=  18.000  mg/L 

2.  Determine  the  fluonde  feed  dose  m  milligrams  per  liter. 
Feed  Dose.  mg/L  =  Desired  Dose.  mg/L  -  Raw  Water  F,  mg/L 

-  0.9  mg/L  -  0.2  mg/L 

-  0  7  mg/L 

3.  Calculate  the  gallons  of  feed  solution  needed. 

Feed  Solution,  gal  =  (Flow  Vol.  gal)(Feed  Dose,  mg/f.) 

Feed  Solution.  mg/L 
.^(250.000  gal)(0.7  mg/L) 

18.000  mg/L 
=  9.7  gallons 


soo 


580  Water  Treetment 


EXAMPLE  10 

A  hydrofluosilicic  acid  (HgSiFg)  tank  contains  350  gallons 
of  acid  with  a  strength  of  19.3  percent.  A  cor^imercial  vendor 
delivers  2500  gallons  of  acid  with  a  strength  of  18  1  percent 
to  the  tank  What  is  the  resulting  strength  of  the  mixture  as  a 
percentage*? 


Unknown 

Mixture  Strength,  % 


Known 

Tank  Contents,  gal  =  350  gal 
Tank  Strength,  %    =  19.3% 
Vendor,  gal  -  2500  gal 

Vendor  Strength,  %  =  18  1% 

Calculate  the  strength  of  the  mixture  as  a  percentage. 

Mixture  Strength.  %    (Tank,  gaiHTank,  %)  f  (Vendor,  galKVendor.  %) 

Tank,  gal  +  Vendor,  gaf 
^  (350  galKl9  3%)    (2500  gal)(l8  1%) 

350  gal  ^  2500  gal 
^  b755  i  45.250 

2850 
=  18  2% 

A.32  Softening 
EXAMPLE  11 

Determine  the  total  hardness  of  CaCOg  for  a  sample  of 
water  with  a  calcium  content  of  33  mg/L  and  a  magnesium 
content  of  6  mg/L. 


Known 

Calcium,  mg/L  =  33  mg/L 
Magnesium,  mg/L  =  6  mg/L 


Unknown 

Total  Hardness, 
mg/L  as  CaCOg 


Calculate  the  total  hardness  as  milligrams  per  liter  of  calcium 
carbonate  equivalent. 

Total  Hardness,    ^  Calcium  Hardness,^  Magnesium  Hardness, 
mg/L  as  CaCOa      mg/L  as  CaCO^       mg/L  as  CaCOj 

=  2.5(Ca,  mg/L)  +  4.12(Mg,  mg/L) 

=  ?-5(33  mg/L)  +  4  1?(6  mg/L) 

=  82  mg/L  +  25  mg/L 

=  107  mg/L  asCaC03 

EXAMPLE  12 

The  alkalinity  of  a  water  is  120  mg/L  as  CaCOg  and  'lie 
total  hardness  is  1 05  mg/L  as  CaCOj.  What  is  the  ca'-oonate 
and  noncarbonate  hardness  m  mg/L  as  CaCOj'? 


Known 


Unknown 


Alkalinity,     ^  ^  20  mg/L  as  CaCOg    ^  • 


Hardness,  mg/L 
as  CaCO^ 


mg/L 
Total 

Hardness,  =  105  mg/L  as  CaCOg    2.  Noncarbonate 
mg/^  Hardness,  mg/L 

as  CaCOj 

1 .  Determine  the  carbonate  hardness  in  mg/L  as  CaCOj. 

Since  the  alkalinity  is  greater  than  the  total  hardness,  (1 20 
mg/L  >  105  mg/L), 

Carbonate  Hardness,  ^  Total  Hardness, 
mg/L  as  CaCOg         mg/L  as  CaCOj 


=  105  mg/L  as  CaCO. 


ERLC 


2.  Determine  the  noncarbonate  hardness  m  mg/L  as 
CaCGj 

Since  the  alkalinity  is  greater  than  tne  total  hardness. 


Noncarbonate  Hardness, 
mg/L  as  CaCOg 


0 


In  other  words,  all  of  the  hardness  is  in  the  carbonate 
form. 

EXAMPLE  13 

The  alkalinity  of  a  water  is  92  mg/L  as  CaCOj  and  the  total 
hardness  is  105  mg/L.  What  is  the  carbonate  and  noncar- 
bonate hardness  in  mg/L  ts  CaCOj*? 

Known  Unknown 

Alkalinity,     ^       ^  ^,  Carbonate 

mg/L  ^'  3       Hardness,  mg/L 

Total  as  CaCOg 

Hardness,  =  1 05  mg/L  as  CaCOg    2.  Noncarbonate 
mg/L  Hardness,  mg/L 

as  CaCOj 

1  Determine  the  carbonate  hardness  in  mg/L  as  CaCOg. 

Since  the  alkalinity  is  less  than  the  total  hardness  (92 
mg/L  <  105  mg/L) 

Carbonate  Hardness,  _  Ai^ai.n.tw  n^^/i 
mg/L  as  CaC03     "  Alkalinity,  mg/L  as  CaC03 

=  92  mg/L  as  CaCO^ 

2  Determine  the  noncarbonate  hardness  in  mg/L  as 
CaCOj. 

Since  the  alkalinity  is  less  than  the  total  hardness  (92 
mg/L  <  105  mg/L) 

Noncarbonate 
Hardness,    ^  Total  Hardness,   _  Alkalinity, 
mg/L  as  mg/L  as  CaCOg      mg/L  as  CaCOg 


CaCO, 


105  mg/L  -  92  mg/L 
13  mg/L  as  CaCOg 


EXAMPLE  14 


Results  from  alkalinity  titrations  on  a  water  sample  were 
as  follows. 

Known 

Sample  size,  mL  =  1 00  mL 

mL  tttrant  used  to  pH  8,3,  A  =  1 .1  mL 
Total  mL  of  titrant  used,  B    =  1 2.4  mL 
Acid  normality,  N  =  0.02  N  H^SO^ 

Unknown 

1,  Total  Alkalinity,  mg/L  as  CaCOj 

2  Bicarbonate  Alkalinity,  mg/L  as  CaCOj 

3.  Carbonate  Alkalinity,  mg/L  as  CaCOj 

4.  Hydroxide  Alkalinity,  mg/L  as  CaCOj 

See  Table  14.4,  page  T'l  for  alkalinity  relationships  among 
constituents 

1.  Calculate  the  phenolphthalem  alkalinity  m  mg/L  as 
CaCOj. 


601 


Arithmetic  581 


Phenolphthalein  Alkalinity.  ^Ax  N  x  50.000 
mg/L  as  CaCOg  gg^ple 

^(^^  mL)(0.02  /V)(50.000) 

100  mL 
=  11  mg/L  as  CaCOj 

2.  Calculate  the  total  alkalinity  In  mg/L  as  CaCOg. 

Total  Alkalinity.  x  N  x  50.000 

mg/LasCaCOg     m/.  of  sample 

^(124  mL)(0.02  A/)(50.000) 

100  mL 
=  124  rrg/L  as  CaCOg 

3.  Refer  to  Table  1 4.4  for  alkalinity  constituents.  The  second 
row  indicates  that  since  P  is  less  than  V2T  (11  mg/L  < 
V2(124  mg/L)),  bicarbonate  alkalinity  is  T-2P  ar.d  carbon- 
ate alkalinity  is  2P. 


Bicarbonate  Alkalinity. 
mg/L  as  CaCOg 


Carbonate  Alkalinity, 
mg/L  as  CaCOg 


Hydroxide  Alkalinity, 
mg/L  as  CaCOg 

EXAMPLE  15 


=  T  -  ^'P 

124  mg/L -2(11  mg/L) 
^102  mg/L  as  CaCOg 
:2P 

=  2(11  mg/L) 

=  22  mg/L  is  CaCOg 

■-  0  mg/L  as  CaCOg 


Calculate  the  hydrated  lime  (Ca(0H)2)  with  90  per:;ent 
purity,  soda  ash,  and  carbon  dioxide  requirements  in  milli- 
grams per  liter  for  the  water  shown  below. 


Known 


Constituent*. 


Source  Water 


Softened  Water  After 
Recarfoonation  and  FiKration 


=  0  mg/L 

=  22  mg/L  as  CaCOa 
=  35  mg/L  as  CaCOa 
=  8  mg/L  as  CaCOa 
=  88 


CO2.  mg/L  =  7  mg/L 

Total  Alkalinity,  mg/L=  125  mg/L  as  CaCOa 
Total  Hardness,  mg/L=  240  mg/L  as  CaCOg 
Mg2-^,  mg/L  =  38  mg/L  as  CaCOa 

pH  =76 
Lime  Purity,  %        =  90% 

Unknown 

1.  Hydrated  Lime,  mg/L 

2.  S..da  Ash,  mg/L 

3.  Carbon  Dioxide,  mg/L 

1.  Calculate  the  hydrated  lime  ^3a(OH)2)  required  in  milli- 
grams per  liter. 


A  = 


B  = 


(COg,  mg/L)(74/44) 
(7  mg/L)(74/44) 
12  mg/L 

(Alkalidity,  mg/L)(74/100) 
(125  mg/L)(74/l00) 
93  mg/L 


C  =  (Hydroxide,  mg/L)(74/100) 
=  0 

D  =  (Mg2^  mg/L/74/24.3) 
-(38  mg/L)(74/24.3) 
=  116  mg/L 


Hydrated  Lime 
(Ca(0H)2)  Feed,  ^ 


(A  -f  B  +  C  -f  D)1.15 


mg/L 


Purity  of  Lime,  as  a  decimal 
^  (12  mg/L  -f  93  mg/L  -f  0  -f  1l6mg/L)1.15 
0.90 

^(22^  mg/L)(1.15) 

0.90 
=  282  mg/L 


2.  Calculate  the  soda  ash  required  in  milligrams  per  liter. 


Noncarbonate 
Hardness, 
mg/L  as 
CaCOg 


.  Total  Hardness,   _  Carbonate  Hardness, 
mg/L  as  CaCOg      mg/L  as  CaCOg 

=  240  mg/L  -  125  mg/L 
=  115  mg/L  as  CaCOg 

Soda  Ash  (Na2C03)     Noncarbonate  Hardness, .  Mng/^nnv 
Feed,  mg/L  ^       mg/L  as  CaCOg  mi 

=  (115mg/L)(106/100) 

=  122  mg/L 

3.  Calculate  the  dosage  of  carbon  dioxide  required  for 
recarbonation. 

Excess  Lime,  mg/L  =  {A  +  8  +  C  +  OKO  1 5) 

=  (12  mg/L  +  93  mg/L  +0+116  mg/LK0.l5) 
-  {221  mg/LK0l5) 
=  33  mg/L 

Total  CO2  Feed,  =  (Ca(0H)2  excess,  mg/L)(44/74) 
mg/L  +  (Mg2-^  residual,  mg/L)(44/24.3) 

=  (33  mg/L)(44/74)  +  8  mg/L)(*"  4/24.3) 

=  20  mg/L  +  15  mg/L 

=  35  mg/L 


EXAMPLE  16 

The  optimum  lime  dosage  from  the  jar  tests  is  180  mg/L.  If 
the  flow  to  be  treated  is  1 .7  MGD,  what  is  the  feeder  setting 
in  pounds  per  day  and  the  feed  rate  in  pounds  per  minute? 

Known  Unknown 

Lime  Dose,  mg/L  =  180  mg/L  1.  Feeder  Setting,  lbs/day 
Flow.  MGD         =1.7  MGD     2.  Feed  Rate,  Ibs/min 

1.  Calculate  the  feeder  setting  in  pounds  per  day. 

Feeder  Setting,  =(fiow,  MGD)(Lime,  mg/L)(8.34  Ibs/gal 
lbs/day 

=  (1.7  MGD)(180  mg/L)(8.34  'bs/gal) 
=  2,550  lbs/day 


'  ■  602 


582  Water  Treatment 


2.  Calculate  the  feed  rate  in  pounds  per  minute 

Feed  Rate.  Ibs/min  =  Feeder  Setting  Jbs/day 
(60  min/hr)(24  hr/day) 

2,550  lbs/day 


(60  min/hr)(24  hr/day) 
=  1  8  lbs/mm 


EXAMPLE  17 

How  much  soda  ash  is  requ  ^.d  (pounds  per  day  and 
pounds  per  minute)  to  remove  40  mg/L  noncarbonate  hard- 
ness as  CaCOj  from  a  flow  of  17  MGD'? 

Known  Unknown 

Noncarbonate  1.  Feeder  Setting, 
Hardness  Removed,  =  40  mg/L  lbs/day 

mg/L  as  CaCOg  2.  Feed  Rate. 

Flow.  MGD  =  1 .7  MGD  Ibs/min 

1.  Calculate  the  soda  ash  dose  In  milligrams  per  litsr.  See 
Section  1 4.316,  "Calculation  of  Chemical  Dosages/'  page 
77,  for  the  following  formula. 

Soda  Ash  mg/L  ^/  Noncarbonate  Hardness,...  Qgy^««. 

mg/LasCaCOj  uo/'uu; 

=  {40  mg/L)(106/100) 
=  43  mg/L 

2.  Determine  the  feeder  setting  in  pounds  per  day. 

^^Ibs/da^y^**'"^'  ^  ^^^^"^^  MGD)(Soda  Ash,  mg/L)(8.34  ibs/gal) 
=  (1-7  MGD){43  mg/L)(8  34  Ibs/gal) 
=  610  lbs/day 

3.  Calculate  the  soda  ash  feed  rate  in  pounds  per  minute. 
Feed  Rate,    ^  Feeder  Setting,  lbs/day 

(60  min/hr)(24  hr/day) 

610  lbs/day 
(60  min/hr)(24  hr/day) 
=  0.43  Ibs/min 

EXAMPLE  18 

What  IS  the  hardness  in  milligrams  per  liter  for  a  water  with 
a  hardness  of  12  grains  per  gallon*? 

Known  Unknown 

Hardness,  gpg  -  12  grams/gallon      Hardness,  mg/L 

Calculate  the  hardness  in  milligrams  per  liter. 

Hardness.  mg/L  =  (Hardness.  grains/gal)(17.1  mg/L) 

1  grain/gal 
^(12grains/gal)(17.1  mg/L) 

1  gram/gal 
=  205  mg/L 


Resin  Vol, 
cu  ft 


Known 

=  600  cu  ft 


Unknown 

Exchange  Capacity, 
grains 


Removal  Cap.  =  25,000  gr/cu  ft 
gr/cu  ft 

Estimate  the  exchange  capacity  in  grains  of  hardness. 

^"JrS^  Capacity,  ^  ^Resin  Vol,  cu  ft)(Removal  Capacity,  gr/cu  ft) 
=  (600  cu  ft)(25,0''O  gr/cu  ft) 
=  15.000,000  grains  of  hardness 


EXAMPLE  20 

How  many  gallons  of  water  with  a  hardness  of  12  grains 
per  gallon  may  be  treated  by  an  Ion  exchange  softener  with 
an  exchange  capacity  of  15,000,000  grains? 

Unknown 

Water  Treated, 
gallons 


Known 


Hardness,  i2gra.ns/gal 
grams/gal  ^ 


Exchange 
Capacity,  =  15,000,000  grains 
grains 

Calculate  the  gallons  of  water  that  may  be  treated. 

Water  Treated,  gal  =  Exchange  Capacity,  grains 
Hardness,  grains/gal 
^  15,000.000  grains 

12  grains/gal 
=  1.250.000  gallons 


EXAMPLE  21 

How  many  hours  will  an  ion  exchange  softening  unit 
operate  when  treating  an  average  dally  flow  of  750  GPM? 
The  unit  is  capable  of  softening  1,250,000  gallons  of  water 
before  requinng  regeneration. 


Unknown 

Operating  Time,  hr 


Known 

^GPm"^  =750  GPM 

Water  Treated,  =  1  250.000  gal 
gal  ^ 

Estimate  how  many  hours  the  softening  unit  can  opera. ^ 
before  requiring  regeneratjon. 


Operating  Time,  hr  =_ 


Water  Treated,  gal 


(Ave  Daily  Flow,  gal/min)(60  min/hr) 

1,250,000  gal 
(750  gal/min)(60  min/hr) 
=  27.8  hours 


EXAMPLE  19 

Estimate  the  exchange  capacity  in  grains  of  hardness  for 
an  ion  exchange  unit  which  contains  600  cubic  feet  of  resin 
with  a  removal  capacity  of  25.000  grains  per  cubic  foot. 

O 

ERLC 


EXAMPLE  22 

Determine  the  pounds  of  salt  needed  to  regenerate  an  Ion 
exchange  softening  unit  capable  of  removing  15,000,000 
grains  of  hardness  if  0.25  pounds  of  salt  are  required  for 
every  1000  grains  of  hardness  removed. 


603 


Arithmetic  583 


Hardness 
Removed,  gr 


Known 

=  15.000,000  grains 


Unknown 

Salt  Needed,  lbs 


^^H^f^nn®^*  =0.25  lbs  salt/1000  gr 
lbs/1000  gr 


Salt 
Needed, 
lbs 


=  ( 


(Salt  Required,  lbs/1000  gr)(Hardness  Removed,  gr) 
0  25  lbs  salt. 


.)  (15,000.000  g  ns) 


1000  grams 
=  3750  lbs  of  salt 


EXAMPLE  23 

Estimate  the  bypass  flow  around  an  ion  exchange  soften- 
er if  the  plant  treats  250.000  gallons  per  day  with  a  source 
water  hardness  of  20  grains  per  gallon  if  the  desired  product 
water  hardness  is  5  grains  per  gallon. 


Known 

Total  Flow,  GPD  =  250.000  GPD 

Source  Water      =  20  grains/gallon 
Hardness,  gpg        ^  ^ 


Unknown 

Bypass  Flow,  GPD 


Plant  EffI 
Hardness,  gpg 


=  5  grams/gallon 


Estimate  the  bypass  flow  in  gallons  per  day. 

Bypass  Flow,  GPD  =  (Total  Flow.  GPD)(Plant  EffI  Hardness,  gpg) 
Source  Water  Hardness,  gpg 

^  (250.0^0  GPD)(5  gpg) 
20  gpg 

=  62.500  GPD 

A.33  Trihalomethanes 
EXAMPLE  24 

A  water  utility  collected  and  analyzed  eight  samples  from  a 
water  distribution  system  on  the  same  day  for  TTHf\/]s.  The 
results  are  shown  below. 


1  2  3  4  5  6  7  8 
80  90  100  90  110  100  100  90 


Sample  No. 
TTHM,  ^Q|L 

V/hat  was  the  average  TTHf\/l  for  the  day? 

Known  Unknown 

Results  from  analysis  Average  TTHM  level 

of  8  TTHM  samples  for  the  day 


Calculate  the  average  TTHM  level  in  micrograms  per  liter 

Ave  TTHM,  _  Sum  of  Measurement.  ^g/L 

Number  of  Measurements 

80  ^ig/L  +  90  ^g/L  +  100  ^g/L  +  90  ^g/L 
^    +110  ^g/L  +  100  ^g/L  +  100  ^g/L  +  90  ^g/L 


^760  uglL 
8 

=  95  uglL 


EXAMPLE  25 

The  results  of  the  .uarterly  average  TTHM  measurement 
for  two  years  are  given  below.  Calculate  the  running  annual 
average  of  the  four  quarterly  measurements  in  micrograms 
per  liter. 


1 

77 


Quarter 
Ave  Quarterly 
TTHM.  ng/L 

Known 

Results  from  analysis  of  two 
years  of  TTHM  sampling 


2  3  4 
B8  112  95 


1 

83 


2  3  4 
87  109  89 


Unknown 

Running  Annual  Average  of 
quarterly  TTHM 
measurements 

Calculate  the  running  annual  average  of  the  quarterly  TTHM 
measurements. 

Annual  Running  TTHM  ^  Sum  of  Ave  TTHM  for  Four  Quarters 
Average.  ^g/L  Number  of  Quarters 

QUARTERS  7,  2,  3  AND  4 


Annual  Running  TTHM 
Average.  ^ig/L 


.  77  ng/L  +  88  Mg/L  +  1 1 2  nqlL  ^  95  nqfL 


.  372  ug/L 


=  93  ng/L 

QUARTERS  2,  3,  4  AND  1 


Annual  Running  TTHM 
Average,  /ig/L 


^  88  ngfL  +  112  fig/L  +  95  ^g/L  -  BZng/L 


378  ngfL 


=  95  ng/L 

QUARTERS  3,  4,  1  AND  2 

Annual  Running  TTHM  ^  1l2  ^ig/L 
Average,  Mg/L  ' 

^  377  ngfL 
4 

=  94  ng/L 

QUARTERS  4,  1,2  AND  3 

Annual  Running  TTHM  ^  95  ng/L 
Average,  uglL 


95  ^igfL  +  83  ^g/L  ^  87  ^g/L 


83  ng/L  4  87  ^gjL     109  ug/L 


^  374  ug/L 
4 

=  94  ngfL 

QUARTERS  1,  2,  3  AND  4 

Annual  Running  TTHM  ^  83  ^g/L  + 
Average,  ^g/L 

^  368^g/L 
4 

-  92  ngfL 

SUMMARY  OF  RESULIS 
Quarter  1 
Ave  Quarterly  •  yy 

TTHM.  ^g|L 
Annual  Running 

TTHM  Ave,  hq/L 


87  ng/L  -  109  nqlL  +  B^^g/L 


3  4 
112  95 

93  95 


1 

83 


2  3  4 
87  109  89 

94  94  92 


c 


584  Water  Treatment 


A.34  Demineratization 
EXAMPLE  26 

Convert  a  water  flux  of  12  x  lO'^'grn/sq  cm-sec  to  gallons 
per  day  per  square  foot. 


Known 


Unknown 


^om/<rn?m  «r  =  '  9m/sq  cm-sec  GP^/sq  ft 

gm/sq  cm-sec  ^  ' 

Convert  the  water  flux  from  gm/sq  cm-sec  to  flow  in 
GPD/sq  ft. 

Flow.  (Flux,  gm/sq  cm-secxi  LiterXl  GalXlOO  cmp(3600  secK24  hr) 

GPO/sq  ft  '  

(1000  gmxa  785  LX3  28  ftp(1  hrXI  day) 

,  (00012  gm/sQ  cm  secXI  UerXI  GaiXlOO  cm)»(3600  secX24  hr) 

(1000  gmX3  785  tX3  28  ft)2(1  hrXl  day) 

»»  25  5  GPO/sq  ft 

EXAMPLE  27 

Estimate  the  ability  of  a  reverse  osmosis  plant  to  reject 
minerals  by  calculating  the  mineral  rejection  as  a  percent. 
The  fee(j water  contains  1800  mg/L  TDS  an(j  the  pro(juct 
water  TDS  Is  120  mg/L. 


Known 


Unknown 


Fee(jwater  TDS.      ^  ^qqq  ^g^^        Mineral  Rejection, 

Product  water  TDS.  ^^20  mg/L 
mg/L  ^' 

Calculate  the  mineral  rejection  as  a  percent. 

Mineral  Rejection.  %  =(:  -  Product  TDS,  mg/Ly^^^p,^^ 

Feed  TDS,  mg/L 
=  (1  -  J20mg^j(10Q./^j 

1800  mg/L 
=  (1  -  0.067H100%) 
=  93.3% 

EXAMPLE  28 

Estimate  the  percent  recovery  of  a  rev^jrse  osmosis  unit 
with  a  4-2-1  arrangement  if  the  feed  flow  is  2.0  MGD  and  the 
product  flow  is  1.75  MGD. 


Known 

Product  Flow.  MGD  =1.75  MGD 
Feed  Flow.  MGD     =  2.0  MGD 

Calculate  the  recovery  as  a  percent. 

Recovery.  %  =  (Product  Flow,  MGDK  iOO%) 
Feed  Flov..  MGD 
^(1.75  MQD)(100%) 

2.0  MGD 
=  87.5% 

A,35  Maintenance 

EXAMPLE  29 


Unknown 

Recovery.  % 


Calculate  the  pumping  capacity  of  a  pump  In  gallons  per 
minute  when  12  minutes  are  required  for  the  water  to  rise  3 
feet  in  an  8  foot  by  6  foot  rectangular  tank. 


Known  Unknown 

Length,  ft  =  8  IX  Pump  Capacity.  GPM 

Width,  ft  ==6  ft 
Depth,  ft  -3  ft 
Time,  mm  =12  mm 

1  Calculate  the  volume  pumped  in  cubic  feet. 

Volume  Pumped,  cu  ft  =  (Length,  ft)(Width,  ft)(Depth.  ft) 
=  (8  ft)(6  ft)(3  ft) 
=  144  cu  ft 

2  Convert  the  volume  pumped  from  cubic  feet  to  gallons. 
Volume  Pumped,  gal  =  (Volume  Pumped,  cu  ftK7.48  gal/cu  ft) 

=  (144  cu  ft)(7  48  gal/cu  ft) 
=  1077  gal 

3.  Calculate  the  pump  capacity  in  gallons  per  minute. 

Pump  Capacity,  GPM  =  Volume  Pumped,  gal 
Pumping  Time,  mm 
^  1077  gal 
12  mm 
=  90  GPM 


EXAMPLE  30 

A  small  chemical  feed  pump  lowered  the  chemical  solution 
in  a  2.5-foot  diameter  tank  2.25  feet  dunng  seven  hours. 
Estimate  the  flow  delivered  by  the  pump  in  gallons  per 
minute  and  gallons  per  day. 


Known 

Tank  Diameter,  ft  =  2.5  ft 
Chemical  Drop,  ft  =  2.25  ft 
Time,  hr  =7.0  hr 


Unknown 

Row,  GPM 
Flow,  GPD 


ERIC 


60 


1  Determine  the  gallons  of  chemical  solution  pumped. 
Volume,  gal  =  (0.785KDiameter,  ft)2(Drop,  ftX7  48  gal/cu  ft) 

=  (0.785X2.5  ft)2(2  25  ftX7  48  gal/cu  ft) 
=  83  gallons 

2  Estimate  the  flow  delivered  by  the  pump  in  gallons  per 
mmute  and  gallons  per  day. 

Flow,  C  ^M  =VQt*Jme  Pumped,  gal 
(Time,  hr)(60  min/hr) 

83  gallons 
(7  hr)(60  min/hr) 
=  0.2  GPM 

or 

Flow,  GPD  =  (Volume  Pumped,  gal)(24  hr/day) 
Time,  hr 
^(83  gallons)(24  hr/day) 
7  hr 

-  285  GPD 


Arithmetic  585 


EXAMPLE  31 

Determine  the  cherr.ical  feed  in  pounds  of  polymer  per  day 
from  a  chemical  feed  pump  The  polymer  solution  is  1.8 
percent  or  18.000  nig  polymer  per  liter  Assume  a  specific 
gravity  of  the  polymer  solution  of  1  0.  During  a  test  run  the 
chemical  feed  pump  delivered  650  mL  of  polymer  solution  in 
4.5  minutes. 


Unknown 

Polymer  Feed, 
lbs/day 


Known 

Polymer  Solution,  %  =  1  8  % 
Pclvrrser  Cone.  mg/L  =  18,000  mg/L 
Polymer  Sp  Gr  =10 
Volume  Pumped,  mL  =  650  m/. 
Time  Pumped,  mm    =  4.5  mm 

Calculate  the  polymer  fed  by  the  chemical  feed  pump  in 
pounds  of  polymer  per  day. 

Polymer 

Feed.  _  (Poly  Cone.  mg//.)(Voi  Pumped.  mL)(60  min/hr)(24  hr/day) 
't>s/day     ^j^^Q  romped.  mmMlOOO  mL//.)(1000  mg/gmK454  gm/lb) 

^  (18.000  mg//.)(e50  mL)(60  min/hr)(24  hr/day) 
(4  5  min)(1000  m/.//.)(1000  mg/gm)(454  gm/lb) 
-  8  2  lbs/day 


EXAMPLE  32 

Determine  the  actual  chemical  feed  m  pounds  per  day 
from  a  dry  chemical  feeder.  A  pie  tm  placed  under  the 
chemical  feeder  caught  824  grams  of  chemical  during  five 
minutes 


Known 

Chemical,  gm  =  824  ym 


Unknown 

Chemical  Feed,  lbs/day 


Time,  mm      =  5  mm 

Determine  the  chemical  feed  in  pounds  per  day. 

Chemical  Feed,  lbs/day  =  (Chem.cal  gm)(60  min/hr)(24  hr/day) 

(454  gm/lb)(Time,  mm) 
^  (824  gm)(60  min/hr)(24  hr/day) 

(454  gm/lb)(5  mm) 
=  523  lbs/day 


EXAMPLE  34 

Calculate  the  injury  severity  rate  for  a  water  company 
which  experienced  57  operator-hours  lost  due  to  injuries 
while  the  operators  worked  97,120  hours  during  the  year 


Known 


Number  of 
Hours  Lost 


Number  of 
Hours  Worked 


57  hrs/yr 
97,120  hrs/yr 


Unknown 

Injury  Severity  Rate 


Calculate  the  mjury  severity  rate 

Injury  Seventy  Rate  ^.(Number  of  Hours  Lost/yr)(1 ,000.000) 
Number  of  Hours  Worked/yr 
^(57  hrs/yr)(1, 000,000) 
97,120  hrs/yr 

-  587 

A.37  Advanced  Laboratory  Proceaures 
EXAMPLE  35 

Calculate  the  threshold  odor  number  (T  O.N.)  for  a  sam;>le 
when  the  first  detectable  odor  occurred  when  the  70  m/. 
sample  was  diluted  to  200  mL  (130  mL  of  odor-free  water 
was  added  to  the  70  mL  sample) 


Known 

Size  of  Sample,  n\L    =  70  mL 
Odor-Free  Water,  mL  =130  mL 


Unknown 
T.O.N. 


Calculate  the  threshold  odor  number,  T.O.N. 
T  0  N  =  Sample,  mi  f  Odor-Free  Water,  mL 

Size  of  Sample,  mL 
^(70  mL  4-  130  mL 


70  mL 


=  3 


A.36  Safety 
EXA^.PLE  33 

Calculate  the  mjury  frequency  rate  for  a  water  utility  where 
there  were  four  injunes  in  one  yi 
worked  97,120  hours. 

Known 

=  4  mjuries/yr 


Injuries, 
number/yr 


Hours  Worked 
number/yr 


97,120  hrs/yr 

Calculate  the  injury  frequency  rate. 

Injury  Freq  Rate  =('njunes,  number/yr)(1 ,000  000) 
Hours  Worked,  number/yr 
^(4  injuries/yr)(1 ,000,000) 


97,120  hrs/yr 


-  41.2 


ERIC 


EXAMPLE  36 

Determine  the  geometric  mean  threshold  odor  number  for 
a  panel  of  six  testers  given  the  results  shown  below. 


and  the  operators 

Known 

Unknown 

Tester  1, 

=  2 

Geometnc  Mean 

Unknown 

Tester  2, 

=  4 

Threshold  Odor  Number 

Injury  F''equency 

Tester  3,  X3 

=  3 

Rate 

Tester  4, 

=  3 

Tester  5,  X^ 

=  6 

Tester  6,  Xg 

=  2 

I-  J 


Calculate  the  gee  metric  mean 

Ge^ome^ric  Me  an  ^      x      x  X3  x  X,  x      x  X,)"" 

=  (2x4x3x8xGx  2)"^ 
^  (2304)0 167 

=  3.6 

S06 


586  Water  Treatment 


EXAMPLE  37 

Calculate  the  threshold  taste  number  for  a  sample  when 
the  first  detectable  taste  occurred  when  the  8.3  mL  sample 
was  diluted  lo  200  mL  (191  7  mL  of  taste-free  water  was 
added  to  the  8.3  mL  sample). 


Known 

Sample  Size,  mL  =  8  3  mL 
Taste-Free  Water,  mL  =191.7 


Unknown 

Threshold  Taste 
Number 


Calculate  the  threshold  taste  number 
Threshold 

Taste  ^  Sample  Size,  mL  +  T??te-Free  Water,  mL 
Number 

Sample  Size,  mL 
_  8.3  mL  +  191  7  mL 


83  mL 


24 


(See  top  of  right  column  for  solution 


EXAMPLE  38 

Determine  the  taste  rating  for  a  water  by  calculating  the 
arithmetic  mean  and  standard  deviation  for  the  panel  ratings 
given  below. 

Known  Unknown 

Tester  1,  X,  -  2  1.  Arithmetic  Mean,  X 

Tester  2,  X^  =  5  2  Standard  Deviation,  S 

Tester  3,  X3  =  3 
Tester  4,  X^  =  6 
Tester  5,  X^  ^  2 
Tester  6,  Xg  =  6 


1     Calculate  the  arithmetic  mean,  X,  taste  rating. 

Arithmetic  Mean,  X  ^  X^  ^  Xg  +  X3  +  X^  +  X,  +  X. 
Taste  Rating  

^24-5+3  +  6  +  2  +  6 
6 

^24 
6 

-  4 

2.  Calculate  the  standard  deviation.  S,  of  the  taste  rating. 

Standard     ^  f  (X,-X)^  +  (X^-X)^  f  (X3-X)^  +  (X,-X)^  +  (X,-X)^  +  (X,-X)^  "1  0 5 
Deviation.    ^  ^  _  ^  "  J 

[(2-4)^  T  f  (3  -4)^  I-  (6-4)^  f  (2-4)^4  (6-4)^  "1 

6-1  "J 

(-2)^  +  0)^  M -1)^^(2)^-^  (-2)^ +  (2)^ 
^1^4  +  1  f  1  f  4  ^  4  +  4 

=    (3.6)0  5 
=  1.9 

ERJC  ..       60  V 


Arithmetic  587 


or 


Deviation, 
S 


Standard  (V  +  X,^  +      +  X,^  +  X^^  +  X^^)  -  (X,+  X,+  X3+X,+  X^+X/  /n  "1°= 


n  -  1 


I 


(2^4-5^+3^  +6^4-2^+6^) -(2+5+3-f6-f2-f 6)^/6  j 


05 


^r(4+25-f9-f36-f4-f36)  -  (24)^/6 
L  5 

114  -  96 
=  1.9 


] 


OS 


EXAMPLE  39 

A  small  water  system  collected  14  samples  during  one 
month.  After  each  sample  was  collected,  10  mZ.  of  each 
sample  was  placed  in  each  of  5  fermentation  tubes.  At  the 
end  of  the  month,  the  results  indicated  that  2  out  of  a  total  of 
70  fermentation  tubes  were  positive.  What  percent  of  the 
portions  tested  during  the  month  were  positive? 


WEIGHT 


Number 
Positive/mo 

Total  Portions 
Tested 


Known 

=  2  positive/mo 
70  portions 


Unknown 

Portions  Positive, 
%/mo 


Calculate  the  percent  of  the  portions  tested  durinq  the 
month  which  were  positive. 

Portions  Positive,  %/mo    (Number  Positive/mo)(100%) 

Total  Portions  Tested 
^(2  positive/mo)(1007o) 

70  portions 
=  3%/mo 

A.4  BASIC  CONVERSION  FACTORS  (METRIC  SYSTEM) 
LENGTH 


100  cm  =  1  m 
3  281  ft  =  1  m 


AHEA 


2.4711  ac  = 
10,000  sq  m  = 


1  ha* 
1  ha 


VOLUME 


1000  mL=  1  liter 
1000  L  =  1  cu  m 
3.785  L  =  1  gal 


100  cm/m 
3.281  ft/m 


2.4711  ac/ha 
10,000  sq  m/ha 


1000  mL/L 
1000  L/cu  m 
3.785  L/gal 


c 


1 000  mg  ■■ 
1000  gm  = 


1  gm 
1  kg 


DENSITY 


PRESSURE 


1  kg  =  1  liter 


1000  mg/gm 
1000  gm/kg 


1  kg//. 


10.015  M  = 
1  Pascah 
1  psi  = 


FLOW 


3785  cu  m/day  -- 
3.785  M/-/day  = 


1  kg/sq  cm  10.015  m/kg/sq  cm 
1  N/sq  m         1  Pa/N/sq  m 
6895  Pa         1  psi/6895  Pa 


1  MGD  3785  cu  m/day/MGD 
1  MGD        3.785  M/-/day/MGD 


hectare 


A.5   TYPICAL  WATER  TREATMENT  PLANT  PROBLEMS 
A.50  Iron  and  Manganese  Control 
EXAMPLE  1 

A  standard  polyphosphate  solution  is  prepared  by  mixing 
and  dissolving  1.0  grams  of  polyphosphate  in  a  container 
and  adding  distilled  water  to  the  one-liter  mark.  Determine 
the  concentration  of  the  stock  solution  in  milligrams  per  liter. 
If  6  milliliters  of  the  stock  solution  are  added  to  a  one-liter 
sample,  what  is  the  polyphosphate  dose  in  milligrams  per 
liter  and  milligrams  per  kilogram? 

Known 

Polyphosphate,  gm  =1.0gm 
Solution,  L  =1.0  /- 

Stock  Solution,  mL  =  6  mL 
Sample,  L  =  1  /. 


Unknown 

1.  Stock  Solution,  mg/mL 

2.  Dose,  mg//. 

3.  Dose,  mg/kg 


608 


588  Water  Treatment 


1.  Calculate  the  concentration  of  the  stock  solution  in  milli- 
grams per  milliliter. 

Stock  Solution,  ^(Polyphosphate.  gm)(1000  mg/gm) 
^^1^^  (Solution.  L)(1000  mL/L) 

^(10  gm)(1000  mg/gm) 

(1  L)(1 000  mL/L) 
=  1.0  mg/mL 

2.  Determine  the  polyphosphate  dose  in  the  sample  in 
milligrams  per  liter. 


Dose,  mg/L 


^  (Stock  Solution.  mg/mL)(Vol  Added.  mL) 

Sample  Volume.  L 
^(1.0mg/mL)(6  mL) 
1L 

=  6.0  mg/L 


3.  Determine  the  polyphosphate  dose  in  the  sample  in 
milligrams  of  phosphate  per  kilogram  of  water. 

Dose,  mg/kg  =  (Stock  Solution.  mg/L)(Vol  Added.  mL) 
(Sample  Volume.  L)(1  kg//.) 
^(1.0  mg/mL)(6mL) 

(1  L)(^  kg/L) 
-  6X  mg/kg 

EXAMPLE  2 

Determine  the  chemical  feeder  setting  in  grams  per  sec- 
ond and  kilograms  per  day  if  2  4  MLD  (mega  or  million  liters 
per  day)  are  treated  with  a  dose  of  5  mg/L. 

Known  Unknown 

Flow,  MLD  =2.4  MLD  1.  Chemical  Feeder,  gm/sec 
Dose,  mg/L  =5  mg/L       2.  Chemical  Feeder,  kg/day 

1.  Determine  the  chemical  feeder  setting  in  grams  per 
second. 


Chemical  Feeder, 
gm/sec 


(Flow,  MLDKDose.  mg/LK1 .000.000/M) 
(24  hr/dayK60  min/hrK60  sec/minKlOOO  mg/gm) 

^   (2  4  MLDK5  mg/LK1 .000.000/M) 

(24  hr/dayK60  min/hr)(60  sec/minKlOOO  mg/gm) 


=  0.139  gm/sec 
or   =139  mg/sec 

2.  Determine  the  chemical  feeder  setting  in  kilograms  per 
day. 

Chemical  Feeder,  ^(Row.  MLD)(Dose.  mg/L)(1, 000.000/M) 
•^9/^^^  (1000  mg/gm)(1000  gm/kg) 

^  (2.4  MLD)(5  mg/L )(1, 000.000/M) 


(1 000  nrig/gm)(1 000  gm/kg) 
12  kg/day 


EXAMPLE  3 

A  reaction  basin  4  meters  in  diameter  and  1 .2  meters  deep 
treats  a  flow  of  0.9  MLD.  What  is  the  average  detention  time 
in  minutes? 


Known  Unknown 

Diameter,  m  =  4  m  Detention  Time,  mm 

Depth,  m      =1.2  m 
Flow.  MLD    =0.9  MLD 

1.  Calculate  the  basin  volume  in  cubic  meters. 
Basin  Vol.  cu  m  =  (0.785)(Diameter.  m)2(Depth,  m) 

=  (0.785,  im)2(1.2  m) 
=  15.1  cu  m 

2.  Determine  the  average  detention  time  in  minutes  for  the 
reaction  basin. 

Detention  Time,  ^  (Basin  Vol.  cu  mK24  hr/day)(60  min/hrKlOOO  L/cu  m) 
(Flow.  MLDK1 .000,000/M) 
_  (15  1  cu  mK24  hr/dayK60  min/hrKlOOO  L/cu  m) 


(0  9  MLDK1, 000.000/M) 


=  24  minutes 


EXAMPLE  4 

Calculate  the  potassium  permanganate  dose  in  milligrams 
per  liter  for  a  well  water  with  2.4  mg/L  iron  before  aeration 
and  0.3  mg/L  after  aeration.  The  manganese  concentration 
is  0.8  mg/L  both  befcre  and  after  aeration. 

Known  Unknown 

Iron.  mg/L  =  0.3  mg/L        KMnO^  Dose,  mg/L 

Manganese.  mg/L  =^  0.8  mg/L 

Calculate  the  potassium  permanganate  dose  in  milligrams 
per  liter. 

KMnO^  Dose.  mg/L  =  0.6(lron.  mg/L)  +  2.0(Manganese.  mg/L) 
=  0.6(0.3  mg/L)  +  2  0(0.8  mg/L) 
=  1.78  mg/L 

NOTE:  If  there  are  any  oxidizable  compounds  (organic 
color,  bacteria,  or  hydrogen  sulfide)  in  the  water, 
the  dose  will  have  to  be  increased. 

A.51  Fluoridation 
EXAMPLE  5 

Determine  the  setting  for  a  chemical  feed  pump  in  gallons 
per  day  when  the  desired  fluoride  dose  is  0.9  kilograms  of 
fluoride  per  day.  The  sodium  fluoride  solution  contains  0.025 
kilograms  of  fluonde  per  gallon  and  the  fluoride  purity  is  43.4 
percent. 


Known 

Feed  Rate,  lbs  F/day  =0.9  kg  F/day 
NaF  Solution,  kg  F/L  =0.025  kg  F/L 
Purity,  %  =  43.4% 


Unknown 

1.  Feed  Rate, 
liters/day 

2.  Feed  Rate. 
mL/sec 


Determine  the  setting  on  the  chemical  feed  pump  in  liters  per 
day. 

Feed  Raic. (Feed  Rate,  ka  F/day)(100%) 
^/day       (fgaF  Solution,  kg  F/L)(Purity,  %) 
^  (0.9  kg  F/day)(100%) 
(0.025  kg  F/L)(43.4%) 
83  liters/day 


ERIC 


609 


Arithmetic  589 


2.  Convert  the  feed  rate  from  kilograms  per  day  to  grams 
per  second. 

Feed  Rate,  ^  (Feed  Rate.  kg/day)(1000  gm/kg) 


gm/sec  hr/day)(6C  min/hr)(60  sec/min) 

(0.9  kg/day)(1000  gm/kg) 
(24  hr/day)(60  min/hr)(60  sec/min) 
=  0.010  gm/sec 
or  =10  mg/sec 

3.  Determine  the  setting  on  the  chemical  feed  pump  in 
milliliters  per  second. 


Feed  Rate, 
ml/sec 


(Feed  Rate,  gm/sec)(100%)(1000  ml/L) 
(NaF  Solution,  kg  F;L){Punty,  %)(1000  gm/kg) 


^  (0.010  gm/sec)(100%;(1000  mL/L) 
(0.025  kg  F/L)(43.4%)(1000  gm/kg) 
=  0.92  mL/sec 

EXAMPLE  6 

Detemiine  the  setting  on  a  chemical  feed  pump  in  liters 
per  day  and  milliliters  per  second  if  2  megaliters  per  day  of 
water  must  be  treated  with  0.9  mg/L  of  fluoride.  The  fluoride 
feed  solution  contains  18,000  mg/L  of  fluoride. 


Known 

Flow,  MLD  =2MLD 
Fluoride,  mg/L         =0.9  mg/L 
Feed  Solution,  mg/L  =  18,000  mg/L 


Unknown 

1.  Feed  Pump, 
liters/day 

2.  Feed  Pump, 
mL/sec 


1.  Determine  the  setting  on  the  chemical  feed  pump  in  liters 
per  day. 

Feed  Pump,^(Flow.  MLD)(Feed  Dose,  mg/L)(1,000.000/M) 
liters/day  p^^^  Solution,  mg/L 

^(2.0  MLD)(0.9  mg/L)(1,000,000/M) 

18,000  ing/L 
=  100  liters/day 

2.  Determine  the  setting  on  the  chemical  feed  pump  in 
n»illiliters  per  second. 

(Flow,  MLDHFeed  Dose,  mg/LK1,000,000/M) 


Feed  Pump, 
mL/sec 


(Feed  Solution,  mg/LK24  hr/day)(60  min/hr)(60  sec/min) 

(2  MLDK0.9  mg/LK1.000.000/M) 
(18,.  JO  mg/L)(24  hr/dayH60  min/hrK60  sec/mm) 
»  1  16  mL/sec 


Calculate  the  fluonde  ion  purity  as  a  percent. 

Fluoride  Ion  ^(Molecular  Weight  of  Fluoride)(100%) 
^"•'•^y*  ^^'^^^        (Molecular  Weight  of  Chemical) 
^(114.00)(100%) 

188.07 
=  60.62% 


EXAMPLE  8 

A  flow  of  6.5  MLD  is  treated  with  sodium  silicofluoride. 
The  raw  water  contains  0.2  mg/L  of  fluoride  Ion  and  the 
desired  fluoride  concentration  is  1.1  mg/L.  What  should  be 
the  chemical  feed  rate  In  kilograms  per  day  and  milligrams 
per  second?  Assume  each  gram  of  commercial  sodium 
silicofluoride  (NagSIFg)  contains  0.6  grams  of  fluoride  ion. 

Unknown 


Known 

Flow,  MLD  -6.5  MLD 

Raw  Water  F,  mg/L  =  0.2  mg/L 
Desired  F,  mg/L  =1.1  mg/L 
Chemical,  grn  F/gm  =  0.6  gm  F/gm 


1.  Feed  Rate, 
kg/day 

2.  Feed  Rate, 
mg/sec 


1.  Determine  the  fluoride  feed  dose  in  milligrams  per  liter. 

Feed  Dose,  mg/L  =  Desired  Dose,  mg/L  -  Actual  Cone,  mg/L 
=  1.1  mg/L«  0.2  mg/L 
=  0.9  mg/L 

2.  Calculate  the  chemical  feed  rate  in  kilograms  per  day. 

Feed  Rate.  ^       (Flow,  MLDKFeed  Dose.  mg/LK1.000.000/M) 
kg/day       ^pu^ty.  gm  F/gm  chemicalHlOOO  mg,gmKlOOO  gm/kg) 

^  (6  5  MLDKO  9  mg/LK1 .000.000/M)  

(0  6  gm  F/gm  chemicalKlO(X)  mg/gmKlOOO  gm/kg) 
=  9  75  kg/day 

3.  Calculate  the  chemical  feed  rate  in  milligrams  per  second. 


(Flow.  MLCXOose.  mg/LX1 .000.000/M) 


Feed 
Rate, 

(Purrty,  gm  F/gm  chemicalX24  hr/dayX60  min/hrX60  sec/mm) 
^  (6  5  MLDK0.9  mg/LK1 .000.000/M)  

(0  6  gm  F/gm  chemical)(24  hr/day)(60  min/hrK60  sec/min) 
=  113  mg/sec 


EXAMPLE  7 

Determine  the  fluoride  ion  purity  of  NagSiFg  as  a  percent. 
Known  Unknown 


Fluonde  Chemical,  NagSiFg         Fluoride  Purity,  % 
Deteimine  the  molecular  weight  of  fluoride  and  NagSiF^ 


Symbol 

(No.  Atoms) 

(Atomic  Wt)  = 

Molecular  Wt 

Na2 

(2) 

(22.99) 

45.98 

Si 

(1) 

(28.09) 

28.09 

(6) 

(19.00) 

114.00 

Molecular  Weight  of  Chemical       =       1 88,07 


EXAMPLE  9 

The  feed  solution  from  a  saturator  containing  1.8  percent 
fluoride  ion  is  used  to  treat  a  total  flow  of  0.95  megaliters 
(M L)  of  water.  The  raw  water  has  a  fluoride  ion  content  of  0.2 
mg/L  and  the  desired  fluoride  level  in  the  treated  water  is  0.9 
mg/L  How  many  gallons  of  leea  solution  are  needed? 

Known  Unknown 

Flow  Vol,  ML        =  0.95  ML  Feed  Solution,  liters 

Raw  Water  F,  mg/L  =  0.2  mg/L 
Desired  F.  mg/L  ^0.0  mg/L 
Feed  Solution,  %F  =  1.8%  F 

610 


S90  Water  Treatment 


1.  Convort  the  feed  solution  from  a  percentage  fluoride  ion 
to  milligrams  fluoride  ion  per  liter  of  water. 

1.0%  F  =  10,000  mg  F/L 

Feed  Solution,  mg/L  ^  (Feed  Solution.  %)(1 0,000  mg/L) 

1.0% 

^(1.8%  F)(10,000  mg/L) 
1.0% 

=  18.000  mg/L 

2.  Determine  the  fluoride  feed  dose  in  milligrams  per  liter 
Feed  Dose,  mg/L  =  Desired  Dose.  mg/L  -  Raw  Water  F.  mg/L 

=  0.9  mg/L  -  0  2  mg// 
=  0.7  mg/L 

3  Calculate  the  liters  of  feed  solution  needed. 

Feed  ^  (Flow  Vol.  ML)(Feed  Dose.  mg/L^I  .000.000/M) 

Feed  Solution.  mg/L 
^  (0.95  MLXO  7  mg/L)(1 .000.000/M) 


18.000  mg/L 


=  37  liters 


EXAMPLE  10 

A  hydrofluosilicic  acid  (HgSiFg)  tank  contains  1300  liters  of 
acid  with  a  strength  of  19.3  percent.  A  commercial  vendor 
delivers  10.000  liters  of  acid  with  ^  strength  of  18.1  percent 
to  the  tank.  What  Is  the  resulting  strength  of  the  mixture  as  a 
percentage? 


Unknown 

Mixture  Strength.  % 


Known 

Tank  Contents,  liters  =  1300  L 
Tank  Strength.  %  =  19.3% 
Vendor,  L  =  10.000  L 

Vendor  Strength.  %   -  18.1% 

Calculate  the  strength  of  the  mixture  as  a  percentage. 
Mixture         ^  (Tank.  L)(Tank.  %)  +  (Vendor.  L)(Vendor.  %) 
S*^^"9*^'     '  Tank.  L  +  Vendor.  L 

^  (1300  L)(19  3%)  +  (10.000  L)(18  1%) 

1300  L  H  10.000  L 
_  25.090  +  181.000 


11,300 

=  18  2% 

A.52  Softening 
EXAMPLE  11 

Determine  the  total  hardness  of  CaCO^  for  a  sample  of 
water  with  a  calcium  content  of  33  mg/L  and  a  magnesium 
content  of  6  mg/L. 

Known 

Calcium,  mg/L  =  33  mg/L 
Magnesium,  mg/L  =  6  mg/L 


Unknown 

Total  Hardness, 
mg/L  as  CaCOj 


Calculate  the  total  hardness  as  mill  grams  per  liter  of  calcium 
carbonate  equivalent. 


ERIC 


Total  Hardness,    „  Calcium  Hardness,  _  Magnesium  Hardness, 
mg/L  as  CaCOs      mg/L  as  CaCOa       mg/L  as  CaCOa 

=  2  5(Ca,  mg/L)  +  4.l2(Mg,  mg/L) 

-  2  5(33  mg/L)  t  4.12(6  mg/L) 

=  82  mg/L  +  25  mg/L 

=  107  mg/L  as  CaCOa 

EXAMPLE  12 

The  alkalinity  of  a  water  is  120  mg/L  as  CaCOj  and  the 
total  hardness  is  1 05  mg/L  as  CaCOj.  What  is  the  carbonate 
and  noncarbonate  hardness  in  mg/L  as  CaCOj? 


Known 


Unknown 


Alkalinity,     ^  ^20  mg/L  as  CaCOg  ^-  Carbonate 
mg/L  ^  ^     Hardness,  mg/L  as 

Total  ^^^^3 

Hardness,  =  105  mg/L  as  CaCO.  2-  Noncarbonate 
^Q/i  ^     Hardness,  mg/L  as 

^'  CaC03 

1.  Determine  the  carbonate  hardness  in  mg/L  as  CaCOj. 

Since  the  alkalinity  is  greater  than  the  total  hardness,  (1 20 
mg/L  >  105  mg/L), 

Carbonate  Hardness,  ^  Total  Hardness, 
mg/L  as  CaCOj  mg/L  as  CaCOj 

=  105  mg/L  as  CaCOj 

2  Determine  the  noncarbonate  hardness  m  mg/L  as 
CaCOg 

Since  the  alkalinity  is  greater  than  the  total  hardness, 

Noncarbonate  Hardness,  ^  q 
mg/L  as  CaCOj 

In  other  words,  all  of  the  hardness  is  in  the  carbonate 
form. 


EXAMPLE  13 

The  alkalinity  of  a  water  is  92  mg/L  as  CaCOj  and  the  total 
hardness  is  105  mg/L  What  is  the  carbonate  and  noncar- 
bonate hardness  in  mg/L  as  CaCOj? 


Known 


Unknown 


Alkalinity, 
mg/L 

Total 


92mg/LasCaC03  ^'  Carbonate 

^  ^     Hardness,  mg/L 

CaCOo 


as 


Hardness,  -  105  mg/L  as  CaCOg  2-  Noncarbonate 
mr.//  Hardness,  mg/L  as 

1.  Determine  the  carbonate  hardness  in  mg/L  as  CaCOj. 

Since  the  alkalinity  is  less  than  the  total  hardness  (92 
mg/L  <  105  mg/L) 

'  mg/ras  Ca"  oT^'  =  ^'^^""'^y-        ^  ^^^°3 

=  92  mg/L  as  CaCOj 

2.  Determine  the  noncarbonate  hardness  m  mg/L  as 
CaCOj. 

Since  the  alkalinity  is  less  than  the  total  hardness  {92 
(jl  l  mg/L  <  105  mg/L) 


Arithmetic  591 


Noncarbonate 

Hardness,      _  Total  Hardness,   _  Alkalinity, 
mg/L  as      **  mg/L  as  CaC03     mg/L  as  CaC03 


CaCOo 


=  105  mg/L  -  92  mg/L 
=  13  mg/L  as  CaC03 


EXAMPLE  14 

Results  from  alkalinity  titrations  on  a  water  sample  were 
as  follows: 

Known 

Sample  size,  mL  =100  mL 

mL  titrant  used  to  pH  8.3,  A  =1.1  mL 
Total  mL  of  titrant  used,  B    =  1 2.4  mL 
Acid  normality,  N  =  0.02  N  H^SO^ 

Unknown 

1.  Total  Alkalinity,  mg/L  as  CaCOg 

2.  Bicarbonate  Alkalinity,  mg/L  as  CaCOg 

3.  Carbonate  Alkalinity,  mg/L  as  CaCOg 

4.  Hydroxide  Alkalinity,  mg/L  as  CaCOg 

See  Table  14.4,  page  74,  for  alkalinity  relationships  among 
constituents. 


1.  Calculate  the  phenolphthalein  alkalinity  in  mg/L  as 

,  A  X  N  X  50,000 


CaCOg. 


Phenolphthalein  Alkalinity, 
mg/LasCaC03  mLof  sample 

^(1.1  mL)(0.02  AO(50,000) 

100  mL 
=  11  mg/L  as  CaCOg 

2.  Calculate  the  total  alkalinity  in  mg/L  as  CaCOg. 
Total  Alkalinity,     ^  B  x  N  x  50,000 
mg/LasCaC03     ^L  of  sample 

^(12.4  mLM0.02  AO(50,000) 

100  mL 
=  124  mg/L  as  CaCOg 

Refer  to  Table  14.4  for  alkalinity  constituents.  The  second 
row  indicates  that  since  P  is  less  than  V2'i  (11  mg/L  < 
V2(124  mg/L),  bicarbonate  alkalinity  is  T-2P  and  carbon- 
ate alkalinity  is  2P. 


3. 


Bicarbonate  Alkalinity, _  j  _ 
mg/L  as  CaCOg 


Carbonate  Alkalinity, 
mg/L  as  CaCOg 


Hydroxide  Alkalinity, 
mg/L  as  CaCOg 


=  124  mg/L  -  2(11  mg/L) 
=  102  mg/L  as  CaCOg 

=  2P 

=  2(11  mg/L) 

=  22  mg/L  as  CaCOg 

=  0  mg/L  as  CaCOg 


EXAMPLE  15 

Calculate  the  hydrated  lime  (Ca{0H)2)  with  90  percent 
purity,  soda  ash,  and  carbon  dioxide  requirements  in  milli- 
grams per  liter  for  the  water  shown  below. 


Known 


Constituetits 


Source  Water 


Softened  Wster  After 
RecsrtxMiatton  and  Filtration 


=  0  mg/L 

22  mg/L  as  CaCOs 
=  35  mg/L  as  CaC03 
=  8  mg/L  as  CaCOs 
-88 


CO2.  rt.JL  =  7  mg/L 

Total  Aikaliruty.  mg/L  =  125  mg/L  as  CaC03 

Total  Hardness.  mg/L=  240  mg/L  as  CaCOs 

Mg2*.  mg/L  -  38  mg/L  as  CaCOa 

pH  =76 

Lime  Purity.  %         =  90% 

Unknown 

1.  Hydrated  Lime.  mg/L 

2  Soda  Ash,  mg/L 

3  Carbon  Dioxide.  mg/L 


1.  Calculate  the  hydrate  id  lime  {Ca{0H)2)  required  in  milli- 
grams per  liter. 

A  ={C02,  mg/LK74/44) 
=  (7  mg/L){74/44) 
-12  mg/L 

B  =  (Alkalinity,  mg/L){74/1 00) 
=  {125  mg//_K74/100) 
=  93  mg/L 

C  ==  (Hydroxide,  m5/l){74/1 00) 
=  0 

D  =(Mg2*,  mg/L){74/24.3) 
=  (38  mg/L){74/24.3) 
=  116  mg/L 


Hydfutcd  Lime 
(Ca(0H)2)  Feed. 
mg/L 


(A  -t-  B  -t-  C  -I-  P)1.15 
Purity  of  Lime,  as  a  decimal 
^  (12  mg/L  +  93  mg/L  +  0+1 16mg/L)1.15 


0.90 


^(221  mg/L)(1.15) 

0.90 
=  282  mg/L 


2.  Calculate  the  soda  ash  required  in  milligrams  per  liter. 


Noncarbonate  Hardness. 
mg/L  as  CaCOa 


Soda  Ash  (Na2C03) 
Feed.  mg/L 


Total  Hardness,   _  Carbonate  Hardness. 
mg/L  as  CaCOa      mg/L  as  CaCOa 

240  mg/L  -  125  mg/L 

115  mg/L  as  CaCOa 

r  Noncarbonate  Hardness, 
mg/L  as  CaCOa 

=  (I15mg/LK106/100) 

=  122  mg/L 


=  (' 


)  (106/100) 


ERIC 


612 


592  Water  Treatment 


3.  Calculate  the  dosage  of  carbon  dioxide  required  for 
recarbonation. 

Excess  Ume.  mg/L    (A  +  B  *  C  +  DKO  15) 

=  (12  mg/L  *  93  mg/L  +  0  *  116  mg/L){0  15} 
=  {221  mg/LKO  15) 
=  33  mg/L 

Total  CO2  Feed,  =  (Ca(0H)2  excess,  mg/L)(44/74) 
mg/L  +  (Mg2*  residual.  mg/L)(44/24  3) 

=  (33  m9/L)(41/74)  +  (8  mg/L)(44/24.3) 

20  mg/L  +  15  mg/L 

=  35  mg/L 

EXAMPLE  16 

The  optimum  lime  dosage  from  the  la"  tests  is  180  mg/L.  If 
the  flow  to  be  treated  is  6.5  MLD,  what  is  the  feeder  setting 
in  kilograms  per  day  and  the  feed  rate  'n  grams  per  second'? 

Known  Unknown 

Ume  Dose,  mg/L  =180  mg/i  1.  Feeder  Setting,  kg/day 
Flow,  MLD  =6.5  MLD      2.  Feed  Rate,  gm/sec 

1.  Calculate  the  feeder  setting  in  kilograms  per  day. 
Feeder  Setting,  ^.(Flow,  MLD)(Lime,  mg/L)(1,000,000/M) 

(1000  mg/gm)(1000  gm/kg) 
^(6.5  MLD)(180  mg/L)(1.000,000/M) 

(1000  mg/gm)(1000  gm/kg) 
=  1170  kg/day 

2.  Calculate  the  feed  rate  in  grams  per  second. 
Feed  Rate,         (Flow,  MLDKLime,  mg/L)(1.000,000/M) 

^"^^^^      (1000  mg/gm)(24  hr/day)(60  min/hr)(60  sec/mm) 
(6.5  MLD)(180  mg/L)(1,000,000/M) 
(1000  mg/gm)(24  hr/day)(60  min/hr)(60  sec/mm) 
=  13.5  gm/sec 


EXAMPLE  17 

How  much  soda  ash  is  required  (kilograms  per  day  and 
grams  per  second)  to  remove  40  mg/L  noncarbonate  hard- 
ness as  CaCOj  from  a  flow  of  6.5  MLD? 


Known 

Noncarbonate  Hardness, 
Removed.  mg/L  as      =  40  mg/L 
CaCOj 

Flow,  MLD  =6.5  MLD 


Unknown 

1.  Feeder 
Setting, 
kg/day 

2.  Feed  Rate, 
gm/iec 


1 .  Calculate  the  soda  ash  dose  in  milligrams  per  liter.  See 
Section  14.316,  "Calculation  of  Chemical  Dosages,"  page 
77,  for  the  following  formula. 

Soda  Ash,  mg/L  =(  ^^"^^''^0"^^®^^^^^^ 
mg/L  as  oaocj^ 

=  (40  mg/L)(106/lOO) 

=  43  mg/L 

2.  Determine  the  feeder  setting  in  kilograms  per  day. 


Feeder  Setting.  ^  (Flow.  MLD)(Soda  Ash.  mg/L)(1.000.000/M) 
(1000  mg/gm)(1000  gm/kg) 
^(6  5  .v1LD)(40  mg/L)(1,000.000/M) 

(1000  mg/gm)(1000  gm/kg) 
=  260  kg/day 

3.  Calculate  the  soda  ash  feed  rate  in  grams  per  second. 
Feed  Rate.  ^    (Flow.  MLD)(Soda  Ash,  mg/L)(1.000,000/M) 
gm/sec      ^^qqq  mg/gm)(24  hr/day)(60  min/hr)(60  sec/mm) 

(6.5  MLD)(40  mg/L)(1.000.000/M) 
(1000  mg/gm)(24  hr/day)(60  min/hr)(60  sec/mm) 
=  30  gm/sec 


EXAMPLE  18 

What  IS  the  hardness  in  grains  per  gallon  for  a  water  with  a 
hardness  of  200  mg/L? 

Known  Unknown 

Hardness,  mg/L  =  12  mg/L     Hardness,  grains/gallon 
Calculate  the  hardness  in  grains  per  gallon. 
Hardness.    ^(Hardness,  mg/L)(1  gram/gal) 
17,1  mg/L 
^(200  mg/L)(1  grain/gal) 

17.1  mg/L 
=  11.7  grams/gal 


EXAMPLE  19 

Estimate  the  exchange  capacity  in  milligrams  of  hardness 
for  an  ion  exchange  unit  which  contains  20  cubic  meters  of 
resin  with  a  removal  capacity  of  14,000  milligrams  per  cubic 
meter. 

Known  Unknown 

Resin  Vol,  cu  m  =20  cu  m  Exchange  Capacity. 

Removal  Cap.    ^  ^^  qqq         ,^  m.ll.grams 
mg/cu  m  ^' 

Estimate  the  exchange  capacity  in  milligrams  of  hardness. 

Exchange  Capacity.  w  .       w«        .  ^       .       .  , 

milligrams  "  ^  ^"  mKRemoval  Capacity,  mg/cu  m) 

=  (20  cu  m)(  14,000  mg/cu  m) 

=  280,000  mg  of  hardness 


EXAMPLE  20 

How  many  liters  of  water  with  a  hardness  of  200  mg/L  may 
be  treated  by  an  ion  exchange  softener  with  an  exchange 
capacity  of  280,000  milligrams? 


ERIC 


Known 

Hardness,  mg/L  =200  mg/L 
Exchange 

Capacity,       =  280,000  milligrams 

mg 


Unknown 

Water  Treated, 
liters 


613 


Arithmetic  593 


Calculate  the  liters  of  water  that  may  be  treated 
Water  Treated,  _  Exchange  Capacity,  mg 
Hardness,  mg//. 
^  280.000  mg 
200  mg/L 
=  1400  liters 

EXAMPLE  21 

How  many  hours  will  an  ion  exchange  softening  unit 
operate  when  treating  an  average  daily  flow  of  50  liters  per 
second.  The  unit  is  capable  of  softening  4,500,000  liters  of 
water  before  requiring  regeneration. 

Known  Unknown 

Ave  Daily  Flow,  L/sec  =  50  L/sec  Operating  Time,  hr 
Water  Treated,  L       -  4,500,000  L 

Estimate  how  many  hours  the  softening  unit  can  operate 
before  requiring  regeneration. 


Operating  ^ 
Time,  hr 


Water  Treated,  L 


(Ave  Daily  Flow,  L/sec)(60  sec/min)(60  min/hr) 
4.500.000  L 


(50  L/sec)(60  sec/min)(60  min/hr) 
=  25  hours 

EXAMPLE  22 

Determine  the  kilograms  of  salt  needed  to  regenerate  an 
Ion  exchange  softening  unit  capable  of  removing  225,000 
milligrams  of  hardness  if  7  kilograms  of  salt  are  required  for 
every  1000  milligrams  of  hardness  removed. 


Hardness 
Removed,  mg 


Known 

=  225,000  mg 


Unknown 

Salt  Needed,  kg 


n^.n'^'^'    =7  kg  salt/1000  mg 
kg/1 000  mg  ^  ^ 

Calculate  the  kilograms  of  salt  needed  to  regenerate  the  ion 
exchange  softening  unit. 


Salt  Needed, 
kg 


(Salt  Required,  kg/1000  mg)(Hardness  Removed,  mg) 

^  (7  kg  salt)(225.000  mg) 

1000  mg 
=  1575  kilograms  of  salt 


EXAMPLE  23 

Estimate  the  bypass  flow  m  cubic  meters  per  day  and 
megaliters  per  day  around  an  ion  exchange  softener  in  a 
plant  that  treats  1000  cubic  meters  per  day  with  a  source 
water  hardness  of  350  mg/L  if  the  desired  product  water 
hardness  is  80  mg/L. 


Total  Flow, 
cu  m/day 

Source  Water 
Hardness, 
mg/L 

Plant  EffI  Hardness,  _qq 
mg/L 


Known 

=  1000  cu  m/day 

=  350  mg/L 


Unknown 

1.  Bypass  Flow, 
cu  m/day 

2,  Bypass  Flow. 
MLD 


C 


1  Estimate  the  bypass  flow  in  cubic  meters  per  day. 

Bypass  Flow.  ^  (Total  Flow,  cu  m/day)(Plant  EffI  Hardness,  mg/L) 
cu  m/day  Source  Water  Hardness.  mg/L 

^  (1000  cu  m/day)(80  mg/L) 

350  mg/L 
=  229  cu  m/day 

2  Estimate  *he  bypass  flow  in  megaliters  per  day. 

Bypass  Flow.     (Total  Flow  co  m/dayKPlant  EffI  Har<Jne>s.  mg/LKlOOO  Lycu  m) 
(Source  Water  Hardness.  mg/LK1  000  000/M) 
_  (1000  CO  m/dayK80  mg/LKlOOO  L/co  m) 

(350  mg/LKI  OOOOOO/M) 
^  0  229  MLO 


A,53  Trihalomethanes 
EXAMPLE  24 

A  water  utility  collected  and  analyzed  eight  samples  from  a 
water  distribution  system  on  the  same  day  for  TTHMs  The 
results  are  shown  below. 


Sample  No. 
TTHM,  ng/L 


1  2  3  4  5  6  7  8 
80  90  100  90  110  100  100  90 


What  was  the  average  TTHM  for  the  day? 


Known 

Results  from  analysis 
of  8  TTHM  samples 


Unknown 

Average  TTHM  level 
for  the  day 


Calculate  the  average  TTHM  level  in  micrograms  per  liter. 

Ave  TTHM,  ^  Sum  of  Measurement,  fig/L 

^^^^  Number  of  Measurements 

80  fig/L  +  90  fig/L  +  100  /ig/L  +  90  /ig/L 
+  110/ig/L  +  l00/ig/L  +  lOO/ig/L  +  90 /ig/L 


^  760  fig/L 
8 

=  95  fig/L 


EXAMPLE  25 

The  results  of  the  quarterly  average  TTHM  measurement 
for  two  years  are  given  below.  Calculate  the  running  annual 
average  of  the  four  quarterly  measurements  m  micrograms 
per  liter. 


Quarter 
Ave  Quarterly 
TTHM.  Mg/L 


1     2     3    4     1     2     3  4 
77  88  112  95  83  87  109  89 

Known  Unknown 

Results  from  analysis  of  two    Running  Annual  Average  of 
years  of  TTHM  sampling        quarterly  TTHM 

measurements 

Calculate  the  running  annua;  average  of  the  quarterly  TTHM 
measurements. 

Annual  Running  TTHM  _  Sum  of  Ave  TTHM  for  Four  Quarters 
Average.  ^g/L         *"  Number  of  Quarters 


S14 


594  Water  Treatment 


QUARTERS  h  ^  3  AND  4 

Annual  Runmng  TTHM  ^  77  hq/L  +  88  ng/L  ^  112  ng/L  +  95  ngfL 
Average.  ;ig/l  

4 

^  372  Mg/l 
4 

=  93  Mg/i 

QUARTERS  2,  3,  4  AND  1 

Annual  Running  TTHM  ^  88Mg/L  +112  ^g/l  +  95  ^g/l  ^  83^9/1 
Average,  ng/L  

4 


^  378  ng/L 
4 

=  95/ig/l 


QUARTERS  3,  4.  /  /^A/D  2 

Annual  Running  TTHM  ^112  ng/L  +  95  ng/L  ^  83  ^g/l  +  87  ng/L 
Average,  ng/L  '  

4 

^  377  uglL 
4 

=  94  uglL 

QUARTERS  4,  7,  2  AND  3 

Annual  Running  TTHM  ^  95  ngfL  +  83  uglL  +  87  /ig/L  +  109  ^g/L 
Average.  //g/L  

4 

^  374  tiglL 
4 

-  94;ig/L 

QUARTERS  /,  2.  3  .AA/D  4 

Annual  Running  TTHM  ^  83  uglL  ^  87  /ig/l  +  109  ^LgjL  +  89  ^^g/L 
Average.  ^g/L   ^  

4 

^  368  pg/L 


Flow,  L/sq  cm-sec  =Flux,  gm/sq  cm-sec 
1000  gm/L 
^12x10'^  gm/sq  cm-sec 

1000  gm/L 
-  12x10-7  £./sq  cm-sec 

2.  Convert  the  water  flux  from  gm/sq  cm-sec  to  flow  In  liters 
per  day  per  square  centimeter. 

Flow.       _  (Flux,  gm/sq  cm-secK60  sec/mm)(60  mm/hrK24  hr/day) 

L/sq  ^'  '  

cm-day  1000  gm/L 

^  (0  0012  gm/sq  cm-sec)(60  s«»''/mmK60  min/hr)(24  hr/day) 


<  jOOgm/L 


-  0  10  L/sq  cm-day 


EXAMPLE  27 

Estimate  the  ability  of  a  reverse  osmosis  plant  to  reject 
minerals  by  calculating  the  mineral  rejection  as  a  percent. 
The  feedwater  contains  1800  mg/£.  IDS  and  the  product 
water  IDS  is  120  mg/L 

Known  Unknown 

Feedwater  TDS,  nig,L  =  1800  mg/L  Mineral  Rejection,  % 
Product  Water  TDS,  mg/L  =  120  mg/L 

Calculate  the  mineral  rejection  as  a  percent. 

Mineral  Rejection,  %  =(1  -  Product  TDS,  mg/L  ^^mno/.) 

Feed  TDS,  mg/L 

=  (1  -J20jl}g/L)(l007o) 
1800  mg/L 

=  (1  -  0.067)(l007o) 

=  93  3% 


-  92  ixgIL 

SUMMARY  OF  RESULTS 

Quarter  1     2     3    4     1     2     3  4 

^™,'!.'g^^^  77  88  112  95  83  87  109  89 

Annual  Runnir  g  ^3  g 

TTHM  Ave,  ^g/L 


A,54  Demlnerallzation 
EXAMPLE  26 

Convert  a  water  flux  of  12  x  10  gm/sq  cm-sec  to  liters 
per  second  per  square  centimeter  and  liters  per  day  per 
square  centimeter. 

Known  Unknown 

Water  Flux,        ^12x10""*  1   Flow,  liters  per 

gm/sq  cm-sec    gm/sq  cm-sec  sec/sq  cm 

2.  Flow,  liteis  per 
day/sqcm 

1 .  Convert  the  water  flux  from  gm/sq  cm-sec  to  flow  in  liters 
per  second  per  square  centimeter. 


ERIC 


EXAMPLE  28 

Estimate  the  percent  recovery  of  a  reverse  osmosis  unit 
with  a  4-2-1  arrangement  if  the  feed  flow  is  8  0  MLD  and  the 
product  flow  IS  7.0  MLD 

Known  Unknown 

Product  Flow,  MLD  =8.0  MLD  Recovery,  % 

Feed  Flow,  MLD     =  7.0  MLD 

Calculate  the  recovery  as  a  percent. 

Recovery.  %  ^.(Product  Flow,  MLD)  (100%) 
Feed  Flow.  MLD 
^(7  0  MLD)(100%) 

8.0  MLD 
=  87.5% 

A.55  Maintenance 
EXAMPLE  29 

Calculate  the  pumping  capacity  of  a  pump  m  hters  per 
second  when  12  minutes  are  required  for  the  water  to  rise 
1.0  meters  In  a  2.5  meter  by  2,0  meter  rectangular  tank. 


61; 


Arithmetic  595 


Known  Unknown 

Length,  m  =  2.5  m  Pump  Capacity,  L/sec 

Width,  m  =  2.0  m 
Depth,  m  =1.0m 
Time,  mm  =12  min 

1.  Calculate  the  volume  pumped  in  cubic  meters. 
Volume  Pumped,  cu  m  =  (Length,  ft)(Wjdth,  m)(Depth,  m) 

=  (2.5  m)(2.0  m)(1.0  m) 
=  5.0  m 

2.  Calculate  the  pump  capacity  in  liters  per  second. 
Pump  Capacity,  ^  (Volume  Pumped,  cu  m)(1000  L/cu  m) 

Liters/sec  Pumping  Time,  mm 

^(SOcu  m)(1000  L/cu  m) 

12  mm 
=  417  L/sec 

EXAMPLE  30 

A  small  chemical  feed  pump  lowered  the  chemical  solution 
in  a  0.8-meter  diameter  tank  0.7  meters  during  7.0  hours 
Estimate  the  flow  delivered  by  the  pump  in  liters  per  second 
and  milliliters  per  second. 


Known 

Tank  Diameter,  m  =  0.8  m 
Chemical  Drop,  m  =  0  7  m 
Time,  hr  =  7  0  hr 


Unknown 

1.  Flow,  L/sec 
2  Flo^' ,  mL/sec 


1  Deternine  the  liters  of  chemical  solution  pumped 

volume,  liters  =  {0  785)(Diameter,  m)2(Drop,  m)(1000  L/cu  m) 
=  (0  785)(0  8  m)2{0  7  m)(100f^  L/cu  m) 
=  352  liters 

2.  estimate  the  flow  delivereo  by  the  pump  in  liters  per 
second. 


Flow,  L/sec 


volume  Pumped,  L 


(Pumpmg  Time,  hr)(60  min/hr)(60  sec/mm) 
^  352  L   

(7  0  hr)(60  min/hr);60  sec/mm) 
=  0.014  L/sec 


3.  Estimate  the  flow  oelivered  by  the  pump  in  milliliters  per 
second. 


Flow,  mL/sec  •■ 


{Vciume  Pumped,  L)(1000  mL/L) 
(Pumping  Time,  hr)(60  min/hr)(60  sec/mm) 

(352  L)(1  OOP  mL/L) 
(7.0  hr)(60  min/hr)(60  sec/mm) 
=  14  mL/sec 


EXAMPLE  31 

Determine  the  chemical  feed  in  kilograms  of  polymer  per 
day  and  grams  per  second  from  a  chemical  feed  pump.  The 
polymer  solution  is  1.8  percent  or  18,000  mg  polymer  per 
liter.  Assume  a  specific  gravity  of  the  polymer  solution  of  1 .0. 
During  a  test  run  the  chemical  feed  pump  c  Ivered  650  mL 
of  polymer  solution  in  4.5  minutes. 


ERLC 


Known 

Polymer  Solution,  %  =  1 .8  % 
Polymer  Cone,  mg/L  =  18,000  mg/L 
Polymer  Sp  Gr  =1.0 
Volume  Pumped,  mL  =  650  mL 
Time  Pumped,  min    =  4.5  mm 


Unknown 

1.  Polymer  Feed, 
kg/day 

2.  Polymer  Feed, 
gm/sec 


1.  Calculate  the  polymer  fed  by  the  chemical  feed  pump  in 
kilograms  of  polymer  per  day. 

Polymer  Feed.  _  {Vol  Pumped,  mLHPoly  Cone.  mg/LX60  min/hrX24  hr/day) 
^gl^^y  (Time  Pumped.  minXI  000  mL/LXlOOO  mg/gmXlOOO  gm/kg) 

(650  mLXI  8.000  mg/LX60  min/hrX24  hr/day) 
(4  5  mmXlOOO  mL/LXlOOO  mg/gmXlOOO  gm/kg) 
-  3  7  kg/day 

2  Calculate  the  polymer  fed  by  the  chemical  feed  pump  in 
grams  of  polymer  per  second. 


Polymer  Feed, 
gm/sec 


(Vol  Pumped.  mLXPo^y  Cone.  mg/L) 


(Time  Pumped,  mmXlOOO  mL/LX60  sec/mmXlOOO  mg/gm) 
(650  mLXI  8.000  mg/L) 


(4  5  minXlOOO  mL/LX60  sec/mjnXlOOO  mg/gm) 
=  0  043  gm/sec 
or    -  43  mg/sec 

EXAMPLE  32 

Determine  tht  actual  chemical  feed  in  kilograms  per  day 
and  grams  per  second  from  a  dry  chemical  feeder.  A  pie  tin 
placed  under  the  chemical  feeder  caught  824  grams  of 
chemical  during  five  minutes. 


Known 

Chemical,  gm  =  824  gm 
Time,  mm      =  5  mm 


Unknown 

1 .  Chemical  Feed,  kg/day 

2.  Chemical  Feed, 
gm/sec 

1.  Determine  the  chemical  feed  in  kilograms  per  day. 
Chemical  Feed,  ^(Chemical,  gm)(60  min/hr)(24  hr/day) 

*^9/day  (Time,  min)(1 000  gm/kg) 

=  (824  gm)(60  min/hr)(24  hr/day) 

^5  min)(1000  gm/kg) 
=  237  Kg/day 

2.  Determine  the  chemical  feed  in  grams  per  secor^J. 

Chemical  Feed,  ^       Chemical,  gm 
gm/sec  (j,^g^  min)(60  sec/mm) 

824  gm 
(5  min)(60  sec/mm) 
=  2  75  gm/sec 

A.56  Safety 
EXAMPLE  33 

Calculate  the  injury  frequency  rate  for  a  water  utility  where 
there  were  four  injuries  in  one  year  and  the  operators 
worked  97,120  hours. 


Injuries, 
number/yr 


Known 

=  4  injuries/yr 


Unknown 

Injury  Frequency 
Rate 


Hours  Worked  =  97.120  hrs/yr 
number/yr 


616 


596  Water  Treatment 


Calculate  the  injury  frequency  rate. 

Injury  Freq  Rate  =  number/yr)(1 ,000,000) 

Hours  Worked,  number/yr 
^(4  >njuries/yr)(1, 000,000) 
97,120  hrs/yr 

=  41.2 


Known 

Tester  1,  X,  =  2 
Tester  2,  Xj  -  4 
Testers,  X3  =  3 
Tester  4,  X^  =  8 
Tester  5,  Xg  =  6 
Testers,  Xg  =  2 


Unknown 

Geometric  Mean 
Threshold  Odor  Number 


EXAMPLE  34 

Calculate  the  Injury  severity  rate  for  a  water  company 
which  experienced  57  operator-hours  lost  due  to  injuries 
while  the  operators  worked  97,120  hours  during  the  year. 


Known 

Number  of 
Hours  Lost 


Number  of 
Hours  Worked 


=  57  hr/yr 
=  97.120  hrs/yr 


Unknown 

Injury  Seventy  Rate 


Calculate  the  injury  seventy  rate. 

Injury  Seventy  Rate  =  (Number  of  Hours  Lost/yr)(1 ,000,000) 
Number  of  Hours  Worked/yr 
^(57  hrs/yr)(1 ,000,000) 


97,120  hrs/yr 


587 


A.57  Advanced  Laboratory  Procedures 
EXAMPLE  35 

Calculate  the  threshold  odor  number  (T.O.N.)  for  a  sample 
when  the  first  detectable  odor  occurred  when  the  70  mL 
sample  was  diluted  to  200  mL  (130  mL  of  odor-free  water 
was  added  to  the  70  n\L  sample). 

Known  Unknown 

Size  of  Sample,  mL      70  mL  T.O  N 

Odor-Free  Water,  mL  =  130  mL 

Calculate  the  threshold  odor  number,  TO.N. 

J.O.N.  =  ^'^^     Sample.  mL  +  Odor-Free  Water,  mL 
Size  of  Sample,  mL 
^(70  mL  +  130  )  . 


70  mL 


=  3 


Calculate  the  geometnc  mean. 

Ge^omeuic  Mean  =      x     x  X3  x  X,  x     x  X,)Vn 

=  (2x4x3x8x6x  2)^/^ 
=  f2304)0i67 
=  3.6 

EXAMPLE  37 

Calculate  the  thresholc^  taste  number  for  a  sample  when 
the  first  detectable  taste  occurred  when  the  8.3  mL  sample 
was  diluted  to  200  mL  (191.7  mL  of  taste-free  water  was 
added  to  the  8.3  mL  sample). 


Known 

Sample  Size,  mL        =  8.3  mL 
Taste-Free  Water,  mL  =191.7 

Calculate  the  threshold  taste  number. 


Unknown 

Threshold  Taste 
Number 


Threshold         ^  Sample  Size,  mL  4-  Taste-Free  Water,  mL 

Taste  Number  z      —r.  ;  

Sample  Size,  mL 

_8.3  mL  +  191.7  mL 


8.3  mL 


24 


EXAMPLE  38 

Determine  the  taste  rating  for  a  water  by  calculating  the 
anthmetic  mean  and  standard  deviation  for  the  panel  ratings 
given  below. 


Known 

Tester  1,  X,  -  2 
Tester  2,  X^  =  5 
Testers.  X3  =  3 
Tester  4,  X^  =  6 
Tester  5,  Xg  =  2 
Tester  6.  Xg  =  6 


Unknown 

1.  Arithmetic  Mean,  X 

2.  Standard  Deviation,  S 


1.    Calculate  the  arfthmettc  mean,  X,  taste  rating 


Arithmetic  Mean,  X 
Taste  Rating 


Xi  +  X,  -f  X, 


X4  +  X,  -f  Xg 


^2+5+3+6+2+6 


EXAMPLE  36 

Determine  the  geometric  mean  threshold  odor  number  for 
a  panel  of  six  testers  given  the  results  shown  below. 

ERIC 


6 
=  4 


617 


Arithmetic  597 


2.  Calculate  the  standard  deviation.  S,  of  the  taste  rating. 

Standard     _ f  (X,-Xp  +  (X^-X)^  +  (X^-Xf  +  (X,-Xp  +  (X,-Xp  +  (X,-Xp  "| 
Deviation.   |_  —  J 

[(2-4)^  4-  (5-4f  +  (3-4f  +  (6-4p  +  (2-4)g  +  (6-4)^  "|  "  » 
6-1  J 

=  j"  (-2)^  +  (1  )^  +  (- 1  )^  +  (2)^  +  (-2)^  +  (2)^  j  ' ' 
=  1^4  +  1  +1  ■»  4  +  4  +  4J05 

-[tT 

=    (3  6)0  5 
-  1.9 

or 

Standard     ^  f  (^i^    V    V    X/  f  X^^  -f  X/)  -  (X,-f Xg+  X.+X.-f  X^+X/  /n  los 
Deviation,    |  I 

[(2^+5^+3^  4-6^+2^+6^) -(2+5+3+6+2+6)^/6  "j-^ 
n-1  J 

^1^(4+25+9+36+4  +  36)  -  (24)^/6 
114  -  96 

=[t]" 


(3  6)0  5 
1.9 


EXAMPLE  39 

A  small  water  system  collected  14  samples  during  one 
month.  After  each  sample  was  collected,  10  mL  of  each 
sample  was  placed  in  each  of  5  fermentation  tubes.  At  the 
end  of  the  month,  the  results  indicated  that  2  out  of  a  total  of 
70  fermen.ation  tubes  were  positive.  What  percent  of  the 
portions  tested  during  the  month  were  positive*? 


Known 

'"pr,:ve/n,o=2P<-e/- 


Unknown 

Portions  Positive, 
%/mo 


Total  Portions 
Tested 


70  portions 


ERIC 


Calculate  the  percent  of  the  portions  lested  during  the 
month  which  were  positive. 

Portions  Positive,  %/mo  =  (Number  Positive/mo)(100%) 

Total  Portions  Tested 

^(2  positive/mo)(lOO%) 

70  portions 
=  3%/mo 


613 


WATER 


ABBREVIATIONS 


ac 

acre 

km 

kilometer 

ac-ft 

acre-feet 

kN 

kilonewton 

af 

acre  feet 

kW 

kilowatt 

amp 

ampere 

kWh 

kilowatt-hour 

degrees  Celsius 

L 

liter 

cfm 

cubic  feet  per  minute 

lb 

pound 

cfs 

cubic  feet  per  second 

Ibs/sq  in 

pounds  per  square  inch 

Ci 

Cune 

m 

meter 

cm 

centimeter 

M 

mega 

cu  ft 

cub'o  feet 

M 

million 

cu  in 

cubic  inch 

mg 

milligram 

cu  m 

cubic  meter 

mg/L 

milligram  per  liter 

cu  yd 

cubic  yard 

MGD 

million  gallons  per  day 

degrees  Fahrenheit 

mL 

milliliter 

ft 

feet  or  foot 

min 

minute 

ft-lb/min 

foot-pounds  pc  minute 

mm 

millimeter 

g 

gravity 

N 

Newton 

gal 

gallot. 

ohm 

ohm 

gal/day 

gallons  per  day 

Pa 

Pascal 

gm 

gram 

pCi 

picoCune 

GPD 

gallons  per  oay 

psf 

pounds  per  square  foot 

GPM 

gallons  per  minute 

psi 

pounds  per  square  inch 

gpg 

grains  per  gallon 

psig 

pounds  per  square  inch  gage 

gr 

gram 

ppb 

parts  per  billion 

ha 

hectare 

ppm 

parts  per  million 

HP 

horsepov\/er 

sec 

second 

hr 

hour 

sq  ft 

square  feet 

in 

inch 

sq  in 

square  inches 

k 

kiio 

W 

watt 

kg 

kilogram 

ERIC 


619 


WATER  WORDS 


A  Summary  of  the  Words  Defined 
in 

WATER  TREATMENT  PLANT  OPERATION 

and 

WATER  SUPPLY  SYSTEM  OPERATION 

PROJECT  PRONUNCIATION  KEY 

by  Warren  L.  Prentice 


The  Project  Pronunciation  Key  Is  designed  to  aid  you  in 
the  pronunciation  of  new  words.  While  this  Key  is  based 
primarily  on  familiar  sounds,  it  does  not  attempt  to  follow  any 
particular  pronunciation  guide.  This  Key  is  designed  solely 
to  aid  operators  in  this  program. 

You  may  find  it  helpful  to  refer  to  other  available  sources 
for  pronunciation  help.  Each  c  urrent  standard  dictionary 
contains  a  guide  to  its  own  pronunciation  Key.  Each  Key  will 
be  different  from  each  other  and  from  this  Key.  Examples  of 
the  differences  between  the  Key  used  in  this  program  and 
the  WEBSTER'S  NEW  WORLD  DICTIONARY  "Key^".  are 
shown  below. 

In  using  this  Kc;y.  you  should  accent  (say  louder)  the 
syllable  which  appears  in  capital  letters.  The  following  chart 
is  presented  to  give  examples  of  how  to  pronounce  words 
using  the  Project  Key. 


SYLLABLE 


Word 

1st 

2nd 

3rd 

4th 

5th 

acid 

AS 

id 

coagulant 

CO 

AGG 

you 

lent 

biological 

BUY 

0 

LODGE 

ik 

cull 

The  first  word  ACID  has  its  first  syllable  accented.  The 
second  word,  COAGULANT  has  its  second  syllable  accent- 
ed. The  third  word,  BIOLOGICAL,  has  its  first  and  third 
syllables  accented. 


We  hope  you  will  find  the  Key  useful  in  unlocking  'he 
pronunciation  of  any  new  word. 


4h 


r  Pr  o  j  f  f  t    Kp  y 

^1  c  i(i  A  S  ,  ' 

h  I  o  I  o  (] ;  ^  .i  1       B  U  y-o-LO  D  G  e  -  ;  I 


We  h  s  t p  r  Key 


^  The  WEBSTER'S  NEW  WORLD  DICTIONARY.  Second  College  Edition,  1972,  was  chosen  rather  than  an  unabridged  dictionary  because 
of  its  availability  to  the  operator.  Other  editions  may  be  slightly  different. 


er|c 


620 


602  Water  Treatment 


WATER  WORDS 


ABC  ABC 
See  Association  of  BOARDS  of  Certification 

ABSORPTION  (ab-GORP-shun)  ABSORPTION 

Taking  in  or  soaking  up  of  one  substance  into  the  body  of  another  by  molecular  or  chemical  action  (as  tree  roots  absorb  dis- 
solved nutrients  in  the  soil). 

ACCURACY  ACCURACY 
How  closely  an  instrument  measures  the  true  or  actual  value  of  the  process  variable  being  measured  or  sensed. 

ACID  RAIN  ACID  RAIN 

Precipitation  which  has  been  rendered  (made)  acidic  by  airborne  pollutants. 

ACIDIC  (uh-SID-ick)  ACIDIC 
The  condition  of  water  or  soil  which  contains  a  sufficient  amount  of  acid  substances  to  lower  the  pH  below  7  0. 

ACIDIFIED  (uh-SID-uh-FIE-d)  ACIDIFIED 

The  addition  of  an  acid  (usually  nitric  or  sulfuric)  to  a  sample  to  lower  the  pH  below  2  0.  The  purpose  of  acidification  is  to  "fix  "  a 
sample  so  it  won't  change  until  it  is  analyzed. 

ACRE-FOOT  ACRE-FOOT 
A  volume  of  water  that  covers  one  acre  to  a  depth  of  one  foot,  or  43,560  cubic  feet  (1233.5  cubic  meters). 

ACTIVATED  CARBON  ACTIVATED  CARBON 

Adsorptive  particles  or  granules  of  carbon  usually  obtained  by  heating  carbon  (such  as  wood).  These  particles  or  granules  have 
a  high  capacity  to  selectively  remove  certain  trace  and  soluble  materials  from  water 

ADSORBATE  (add-SORE-bait)  ADSORBATE 
The  material  being  removed  oy  the  adsorption  process. 

ADSORBENT  (add-SORE-beni)  ADSORBENT 
The  material  (activated  carbon)  that  is  responsible  for  removing  the  undesirable  substance  in  the  adsorption  process. 

ADSORPTION  (add-SORP-shun)  ADSORPTION 
The  collection  of  a  gas,  liquid,  or  dissolved  substance  on  the  surface  or  interface  zone  of  another  material. 

AERA  HON  (air-A-shun)  AERATION 
fhe  process  of  adding  air  to  water  Air  can  be  added  to  water  oy  either  passing  air  through  water  or  passing  water  through  air 

AEROBIC  (air-O-bick)  AEROBIC 
A  condition  in  which  "free"  (atmospheric)  or  dissolved  oxygen  is  present  in  the  water. 

AESTHETIC  (es-THET-ick)  AESTHETIC 
Attractive  or  appealing. 

AGE  TANK  AGE  TANK 

A  tank  used  to  store  a  chemical  solution  of  known  concentration  for  feed  to  a  chemical  feeder.  Also  called  a  DAY  TANK. 

ER?C  621 


Words  603 


BINDING  AIR  BINDING 

A  situation  wheie  air  enters  the  fil*er  media  Air  is  harmful  to  both  the  filtration  and  backwash  processes.  Air  can  prevent  the 
passage  of  water  dunng  the  filtration  process  af.d  can  cause  the  loss  of  filter  media  during  the  backwash  process. 

AIR  GAP 

An  open  vertical  drop,  or  vertical  empty  space,  that  separates  a  drinking 
(potable)  water  supply  to  be  protected  from  another  water  system  in  a 
water  treatment  plant  or  other  location.  This  open  gap  prevents  the 
contamination  of  drinking  water  by  backsiphonage  or  backflow  because 
there  is  no  way  raw  water  or  any  other  water  can  reach  the  drinking  water 


OTIINKINO 
WATCH 


AIR  GAP 


3 


OPEN 
TANK 


TO 

riANT 


 X 


A'f^  PA'^'^'NG  AIR  PADDING 

Pumping  dry  air  into  a  container  to  ass  st  with  the  withdrawal  of  a  hquid  or  to  force  a  liquefied  qas  such  as  chlorine  out  of  a 
container.  » 

AIR  STRIPPING  AIR  STRIPPING 

A  treatment  process  used  to  remove  dissolved  gas9s  and  volatile  substances  from  water  Large  volumes  of  air  are  bubbled 
through  the  water  being  treated  to  remove  (str-p  out)  the  dissolved  gases  and  volatile  substances. 

ALARM  CONTACT  ^LARM  CONTACT 

A  switch  that  operates  when  some  pre-set  low,  high  or  abnormal  condition  exists. 

ALGAE  (Al-gee)  ALGAE 
Microscopic  plants  which  contain  chlorophyll  and  live  floating  or  suspended  m  water.  They  also  may  be  attached  to  structures 
rocks  or  other  submerged  surfaces.  Excess  algal  growths  c?.n  impart  tattes  and  odors  to  potable  water.  Algae  produce  oxygen 
during  sunlight  hours  and  use  oxygen  during  the  night  hours.  Their  biological  activities  appreciably  affect  the  pH ,.  >d  dissolved 
oxygen  of  the  water. 

ALGAL  BLOOM  (AL-gull)  ALGAL  BLOOM 

S  jdden,  massive  growths  of  microscopic  and  macroscopic  plant  life,  such  as  green  or  blue-green  alqae,  which  develop  in  lakes 
and  reservoirs.  ^  ^        ^  k 

ALGICIDE  (AL-gi-SIDE)  ALGICIDE 
Any  substance  or  chemical  specifically  formulated  to  kill  or  control  algae. 

ALIPHATIC  HYDROXY  ACIDS  (AL-uh-FAT-ick)  ALIPHATIC  HYDROXY  ACIDS 

Organic  acids  w,:h  carbon  atoms  arranged  in  branched  or  unbranched  open  chains  rather  than  in  rings 

ALIQUOT  (AL-li-kwot)  ALIQUOT 
Portion  of  a  sample 

ALKALI  (AL-ka-he)  ALKALI 

Various  soluble  salts,  principally  of  sodium,  potassium,  magnesium,  and  calcium,  that  have  the  property  of  combining  with 
acids  to  form  neutral  salts  and  may  be  us3d  in  chemical  water  treatment  processes. 

ALKALINE  (AL-ka-LINE)  ALKALINE 
The  condition  of  water  or  soil  which  contains  a  sufficient  amount  of  alkali  substances  to  raise  the  pH  above  7.0. 
ALKALINITY  (AL-ka-LIN-it-tee)  ALKALINITY 
The  capacity  of  water  to  neutralize  acids  This  capacity  is  caused  by  the  water's  content  of  carbonate,  bicarbonate,  hydroxide, 
and  occasionally  borate,  silicate,  and  phosphate.  Alkalinity  is  expressed  m  milligrams  per  liter  of  equivalent  calcium  carbonate 
Alkalinity  is  not  the  same  as  pH  because  water  does  not  have  tc  strongly  basic  (high  pH)  to  have  a  high  alkalinity.  Alkahnity  is 
a  measure  of  how  much  acid  can  be  added  to  a  liquid  without  causing  a  great  change  in  pH. 

ALLUVIAL  (uh-LOU-vee-ul)  ALLUVIAL 
Relating  to  mud  and/or  sand  deposited  by  flowing  water.  Alluvial  deposits  may  occur  after  a  heavy  ram  storm. 

ALTERNATING  CURRENT  (A.C.)  ALTERNATING  CURRENT  (A.C.) 

An  electric  current  that  reverses  its  direction  (positive/negative  values)  at  regular  intervals. 


ERIC  . '  0  622 


604  Water  Treatment 


ALTITUDE  VALVE  ALTITUDE  VALVE 

A  valve  that  automatically  shuts  off  the  flow  into  an  elevated  tank  en  the  water  level  »n  the  tank  reaches  a  predetermined  lev- 
el The  \  Jive  automatically  opens  when  the  pressure  in  the  distribution  system  drops  below  the  pressure  in  the  tank. 

AMBIENT  TEMPERATURE  (AM-bee-ent)  AMBIEhiT  TEMPERATURE 

Temperature  of  the  surrounding  air  (or  other  medium).  For  example,  temperature  of  the  room  where  a  gas  chlorinator  is  in- 
stalled. 

AMERICAN  WATER  WORKS  ASSOCIATION  AMERICAN  WATER  WORKS  ASSOCIATION 

A  professional  organization  for  all  persons  working  in  the  water  utinW  field  For  information  on  AWWA  membership  and  publica- 
tions, contact  AWWA,  6666  W.  Quincy  Avenue,  Denver,  Colorado  80235 

AMPERAGE  (AM-purr-ac,o)  AMPERAGE 

The  strength  of  an  electric  current  measured  in  amperes  The  amount  of  electric  current  flow,  similar  to  the  flow  of  water  in  gal- 
lons per  minute. 

AMPERE  (AM-peer)  AMPERE 

The  unit  used  to  measure  current  strength  The  current  produced  by  an  electromotive  force  of  one  volt  acting  through  a  resis- 
tance of  one  ohm. 

AMPEROMETRIC  (am-PURR-o-MET-rick)  AMPEROMETRIC 
Based  on  the  electric  current  that  flows  between  two  electrodes  in  a  solution. 

AMPEROMETRIC  TITRATION  AMPEROMETRIC  TITRATION 

A  means  of  measunng  concentrations  of  certain  substances  in  water  (such  as  strong  oxidizers)  based  on  the  electric  current 
that  flows  during  a  chemical  reaction.  See  TITRATE 

AMPLITUDE  AMPLITUDE 
The  maximum  strength  of  an  alternating  current  during  its  cycle,  as  distinguished  from  the  mean  or  effective  strength. 

ANAEROBIC  (AN-air-O-bick)  ANAEROBIC 
A  condition  in  which  "free"  (atmospheric)  or  dissolved  oxygen  is  NOT  present  in  water. 

ANALOG  ANALOG 
The  readout  of  an  instrument  by  a  pointer  (or  other  indicating  means)  against  a  dial  or  scale. 

ANGSTROM  (ANG-strem)  ANGSTROM 

A  unit  of  length  equal  to  one  tenth  of  a  nanometer  or  one  ten-billionth  of  a  meter  (1  Angstrom  =  0.000  000  000  1  meter).  One 
Angstrom  is  the  approximate  diameter  of  an  atom. 

ANALYZER  ANALYZER 

A  device  which  conducts  periodic  or  continuous  measurement  of  some  factor  such  as  chlorine,  fluoride  or  turbidity.  Analyzers 
operate  by  any  of  several  methods  including  photocells,  conductivity  or  complex  instrumentation. 

ANION  (AN-EYE-en)  ANION 

A  negatively  charged  ion  in  an  electrolyte  solution,  attracted  to  the  anode  under  the  influence  o^  a  difference  in  electrical  poten- 
tial. Chloride  (CI")  is  an  anion. 

ANIONIC  POLYMER  (AN-eye-ON-ick)  ANIONIC  POLYMER 

A  polymer  having  negatively  charged  groups  of  ions,  often  used  as  a  filter  aid  and  fc    '©watering  sludges 

ANNULAR  SPACE  (AN-you-ler)  ANNULAR  SPACE 

A  ring-shaped  space  located  between  two  circular  objects,  such  as  two  pipes.       ^.^^  ^^^^ahhulah  space 

PIPE  LINER 
PIPE 

ANODE  (an-O-d)  ANODE 

The  positive  pole  or  electrode  of  an  electroh  tic  system,  such  as  a  battery  The  anode  attracts  negatively  charged  particles  or 
ions  (anions). 

ERIC  (^23 


Words  605 


APPROPRIATIVE  APPROPRIATIVE 

Water  rights  to  or  ownership  of  water  supply  which  is  acquired  for  the  beneficial  use  of  water  by  following  a  specific  legal 
procedure 

APPURTENANCE  (uh-PURR-ten-nans)  APPURTENANCE 

Machinery,  appliances,  structures  and  other  parts  of  the  mam  structure  necessary  to  allow  it  to  operate  as  intended,  but  not 
considered  part  of  the  mam  structure. 

AQUEOUS  (A-kwee-us)  AQUEOUS 
Something  made  up  of,  similar  to.  or  containing  water;  v^atery. 

AQUIFER  (ACK-whfer)  AQUIFER 

A  natural  underground  layer  of  porous,  water-bearing  materials  (sand,  gravel)  usually  capable  of  yielding  a  large  amour.t  or 
supply  of  water 

ARTESIAN  (are-TEE-zhun)  ARTESIAN 

Pertaining  to  groundwater,  a  well,  or  underground  basm  where  the  water  s  under  a  pressure  greater  than  atmospheric  and  will 
rise  above  the  level  of  its  upper  confining  surface  if  given  an  opportunity  to  do  so. 

ASEPTIC  (a-SEP-tick)  ASEPTIC 
Free  from  the  living  germs  of  disease,  fermentation  or  putrefaction.  Sterile. 

ASSOCIATION  OF  BOARDS  OF  CERTIFICATION  ASSOCIATION  OF  BOARDS  OF  CERTIFICATION 

An  international  organization  representing  over  1 1 0  boards  which  certify  the  operators  of  waterworks  and  wastewater  facilities. 
For  information  on  ABC  publications  regerding  the  preparation  of  and  how  to  study  for  operator  ce.iif ication  examinations  con- 
tact ABC.  P.O.  Box  786,  Ames,  Iowa  50010-0786. 

ASYMMETRIC  (A-see-MET-rick)  ASYMMETRIC 
Not  similar  in  size,  shape,  form  or  arrangement  of  parts  on  opposite  sides  of  a  line,  point  or  plane. 

ATOM  ATOM 
The  smallest  unit  of  a  chemical  element,  composed  of  protons,  neutrons  and  electrons. 

AVAILABLE  CHLORINE  AVAILABLE  CHLORINE 

A  measure  of  the  amount  of  chlorine  a.ailable  in  chlorinated  lime,  hypochlorite  compounds,  and  other  materials  that  are  used 
as  a  source  of  chlorine  when  compared  with  that  of  elemental  (liquid  or  gaseous)  chlonne. 

AVAILABLE  EXPANSION  AVAILABLE  EXPANSION 

The  vertical  distance  from  the  sand  surface  to  the  underside  of  a  trough  in  a  sand  filter.  This  distance  is  also  called 
FREEBOARD. 

AVERAGE  AVERAGE 

A  number  obtained  by  adding  quantities  or  measurements  and  dividing  the  sum  or  total  by  the  number  of  quantities  or  measure- 
ments Also  called  the  ARITHMETIC  MEAN. 
Average  =  Measurements 
Number  of  Measurements 

AVERAGE  DEMAND  AVERAGE  DEMAND 

The  total  demand  for  water  during  a  penod  of  time  divided  by  the  number  of  days  m  that  time  penod.  This  is  also  calleo  the 
AVERAGE  DAILY  DEMAND. 

AWWA  AWWA 
See  AMERICAN  WATER  WORKS  ASSOCIATION 

AXIAL  TO  IMPELLER  AXIAL  TO  IMPELLER 

The  direction  in  which  matenal  being  pumped  flows  around  the  impeller  or  flow  parallel  to  the  impeller  shaft. 

AXIS  OF  IMPELLER  AXIS  OF  IMPELLER 

An  imaginary  (me  running  along  the  center  of  a  shaft  (such  as  an  impeller  shaft). 

BACK  PRESSURE  BACK  PRESSURE 

A  pressure  that  can  cause  water  to  backflow  into  the  water  supply  when  a  user  's  water  system  is  at  a  higher  pressure  than  the 
public  water  system. 

E±  624 


606  Water  Treatment 


BACKFLOW  BACKFLOW 

A  reverse  flow  condition,  created  by  a  difference  in  water  pressures,  which  causes  water  to  flow  back  into  the  distribution  pipec 
of  a  potable  water  supply  from  any  sou.rce  or  sources  other  than  an  intended  source  Also  see  BACKSIPHONAGE. 

BACKSIPHONAGE  BACKSIPHONAGE 
A  form  of  backflow  caused  by  a  negative  or  below  atmospheric  pressure  within  a  water  system.  Also  see  BACKFLOW. 

BACKWASHING  BACKWASHING 
The  process  of  reversin  .  the  flow  of  water  back  through  the  filter  media  to  remove  the  entrapped  solids. 

BACTERIA  (back-TEER-e-uh)  BACTERIA 

Bacteria  are  living  organisms,  micrcscopic  in  size,  which  usually  consist  of  a  single  cell  Most  bacteria  use  organic  matter  for 
their  food  and  produce  waste  prod  jcts  as  a  result  of  their  life  processes. 

BAFFLE  BAFFLE 

A  flat  board  or  plate,  deflector,  guide  or  similar  device  constructed  or  placed  in  ti^yving  water  or  slurry  systems  to  cause  more 
uniform  flow  velocities,  to  absorb  energy,  and  to  divert,  guide,  or  agitate  liquids  (water,  chemical  solutions,  slurry) 

BAILER  (BAY-ler)  BAILER 

A  10-  to  20-foot-long  pipe  equipped  with  a  valve  at  the  lower  end.  A  bailer  is  used  to  remove  slurry  from  the  bottom  or  the  side 
of  a  well  as  it  is  being  drilled 

BASE  METAL  BASE  METAL 

A  metal  (such  as  iron)  which  reacts  w  h  dilute  hydrochloric  acid  to  form  hydrogen.  Also  see  NOBLE  METAL 

BATCH  PROCESS  BATCH  PROCESS 

A  treatment  process  in  which  a  tank  or  reactor  is  filled,  the  water  is  treated  or  a  chemical  sciution  is  prepared,  and  the  tank  is 
emptied  The  tank  may  then  be  filled  and  the  process  repeated. 

BENCH  SCALE  TESTS  BENCH  SCALE  TESTS 

A  method  of  studying  different  ways  or  chemical  doses  for  treating  water  on  a  small  scale  in  a  laboratory. 

BIOCHEMICAL  OXYGEN  DEMAND  BIOCHEMICAL  OXYGEN  DEMAND 

BOD  The  rate  at  which  microorganisms  use  the  oxygen  in  water  whilf  stabilizing  decomposable  organic  matter  under  aerobic 
conditions  In  decomposition,  organic  matter  serves  as  food  for  th;:  bacteria  and  energy  results  from  its  oxidation. 

BIOLOGICAL  GROWTH  BIOLOGICAL  GROWTH 

The  activity  and  growth  of  any  and  all  living  organisms. 

BLANK  BLANK 

A  bottle  containing  only  dilution  water  or  distilled  water,  the  sample  being  tested  is  not  added.  Tests  are  free  ontly  run  on  a 
SAMPLE  and  a  BLANK  and  the  differences  are  compared. 

BOD  (pronounce  as  separate  letters)  BOD 

Biochemical  Oxygen  Demand  The  rate  at  which  microorganisms  use  the  oxygen  in  water  while  stabilizing  decomposable  or- 
ganic nPutter  under  aerobic  conditions  In  decomposition,  organic  matter  serves  as  food  for  the  bacteria  and  energy  results 
from  Its  oxidation 

BONNET  (BON-it)  BONNET 
The  cover  on  a  gate  valve. 

BOWLS,  PUMP  BOWLS,  PUMP 

The  submerged  pumpmg  unit  in  a  well,  including  the  shaft,  impellers  and  housing. 

BRAKE  HORSEPOWER  BRAKE  HORSEPOWER 

(1)  The  horsepower  required  at  the  top  or  end  of  a  pump  shaft  (mput  to  a  pump). 

(2)  The  energy  provided  by  a  motor  or  other  power  source. 

BREAKPOINT  CHLORINATION  BREAKPOINT  CHLORINATION 

Addition  of  chlorine  to  water  until  the  chlorine  demand  has  been  satisfied  At  th;s  point,  further  additions  of  chlonne  will  result  m 
a  free  residual  chlorine  that  is  directly  proportional  to  the  amount  of  chlorine  added  beyond  the  breakpoint. 

ER?C  62o 


Words  607 


BREAKTHROUGH  BREAKTHROUGH 
A  crack  or  break  in  a  filter  bed  allowing  the  passage  of  floe  or  particulate  matter  through  a  filter.  This  will  cause  an  increase  in 
filter  effluent  turbidity  A  breakthrough  can  occur  (1)  when  a  filter  is  first  placed  m  service.  (2)  when  the  effluent  valve  suddenly 
opens  or  closes,  and  (3)  dunng  periods  of  excessive  head  loss  throuqh  the  filter  (including  when  the  filter  is  exposed  to  negative 
heads). 

BRINELLING  (bruh-NEL-ing)  BRINELLING 
Tiny  indentations  (dents)  high  on  the  shoulder  of  the  beanng  race  or  bearing  A  type  of  bearing  failure 

BUFFER  BUFFER 
A  solution  or  liquid  whose  chemical  makeup  neutralizes  acids  or  bases  without  a  great  change  m  pH 

BUFFER  CAPACITY  BUFFER  CAPACITY 

A  measure  of  the  capacity  of  a  solution  or  hquid  to  neutralize  acids  or  bases.  This  is  a  measure  of  the  capacity  of  water  for 
offering  a  resistance  to  changes  in  pH. 

C  FACTOR  C  FACTOR 

A  factor  or  value  used  to  indicate  the  smoothness  of  the  interior  of  a  oipe.  The  higher  the  C  Factor,  the  smoother  the  pipe,  the 
greater  the  carrying  capacity,  and  the  smaller  the  friction  or  energy  losses  from  water  flowing  in  the  pipe  To  calculate  the  C 
Factor,  measure  the  flow,  pipe  diameter,  distance  between  two  pressure  gages,  and  the  friction  or  energy  loss  of  the  water  be- 
tween the  gages. 

C  Factors  ^'Q^-  GPM  

193  75  (Diameter,  ft)^®^  (Slope)^^^ 

CAISSON  (KAY-sawn)  CAISSON 

A  structure  or  chamber  which  is  usually  sunk  or  lowered  by  digging  from  the  inside  Used  to  gam  access  to  the  bottom  of  a 
stream  or  other  body  of  water 

CALCIUM  CARBONATE  EQUILIBRIUM  CALCIUM  CARBONATE  EQUILIBRIUM 

A  water  is  considered  stable  when  it  is  just  saturated  with  calcium  carbonate.  In  this  condition  the  water  will  neither  dissolve  nor 
deposit  calcium  carbonate  Thus,  in  this  water  the  calcium  carbonate  is  m  equilibrium  with  the  hydrogen  ion  concentration. 

CALCIUM  CARBONATE  (CaC03)  EQUIVALENT  CALCIUM  CARBONATE  (CaC03)  EQUIVALENT 

An  expression  of  the  concentration  of  specified  constituents  m  water  m  terms  of  their  equivalent  value  to  calcium  cdroonate 
For  example  the  hardness  in  water  which  is  caused  by  calcium,  magnesium  and  other  ions  is  usually  described  as  calcium  car- 
bonate equivalent. 

CALIBRATION  CALIBRATION 
A  procedure  which  checks  or  adjusts  an  instrument's  accuracy  by  comparison  with  a  standard  or  reference 

CAPILLARY  ACTION  CAPILL/  R v  ACTION 
The  movement  of  water  through  very  small  spaces  due  to  molecular  forces. 

CAPILLARY  FORCES  CAPILLARY  FORCES 
The  molecular  forces  which  cause  the  movement  of  water  through  very  small  spaces. 

CAPILLARY  FRINGE  CAPILLARY  FRINGE 

The  porous  material  just  above  the  water  table  which  may  hold  water  by  capillarity  (a  property  of  surface  tension  that  draws  wa- 
ter upwards)  in  the  smaller  void  spaces 

CARCINOGEN  (car-SlN-o-|en)  CARCINOGEN 
Any  substance  which  tends  to  produce  cancer  in  an  organism. 

CATALYST  (CAT-uh-LlST)  CATALYST 

A  substarice  that  changes  the  speed  or  yield  of  a  chemical  reaction  without  bemg  consumed  or  chemically  changed  by  the 
chemical  reaction. 

CATALYZE  (CAT-uh-LIZE)  CATALYZE 
To  act  as  a  catalyst.  Or.  to  speed  up  a  chemical  reaction. 

CATALYZED  (CAT-uh-LIZED)  CATALYZED 
To  be  acted  upon  by  a  catalyst 

ERIC  626 


608  Water  Treatment 


CATHODE  (KA-thow-d)  CATHODE 

The  negative  pole  or  electrode  of  an  electrolytic  cell  or  system.  The  cathode  attracts  positively  charged  particles  or  ions 
(cations). 

CATHODIC  PROTECTION  (ca-THOD-ick)  CATHODIC  PROTECTION 

An  electrical  system  for  prevention  of  rust,  corrosion,  and  pitting  of  metal  surfaces  which  are  m  contact  with  water  or  soil  A 
low-voltage  current  is  made  to  flow  through  a  liquid  (water)  or  a  soil  in  contact  with  the  metal  in  such  a  manner  that  the  external 
electromotive  force  renders  the  metal  structure  cathodic  This  concentrates  corrosion  on  auxiliary  anodic  parts  vyhich  are  delib- 
erately allowed  to  corrode  instead  of  letting  the  structure  corrode 

CATION  (CAT-EYE-en)  CATION 

A  positively  charged  ion  in  an  electrolyte  solution,  attracted  to  the  cathode  under  the  influence  of  a  difference  in  electrical  poten- 
tial Sodium  ion  (Na*)  is  a  cation. 

CATIONIC  POLYMER  CATIONIC  POLYMER 

A  polymer  having  positively  charged  groups  of  ions;  often  used  as  a  coagulant  aid. 

CAVITATION  (CAV-uh-TAY-shun)  CAVITATION 

The  formation  and  collapse  of  a  gas  pocket  or  bubble  on  the  blade  of  an  impeller  or  the  gate  of  a  valve  The  collapse  of  this  gas 
pocket  or  bubble  drives  water  into  the  impeller  or  gate  with  a  terrific  force  that  can  cause  pitting  on  the  impeller  or  gate  surface 
Cavitation  is  accompanied  by  loud  noises  that  sound  like  someone  is  pounding  on  the  impeller  or  gate  with  a  hammer. 

CENTRATE  CENTRATE 
The  water  leaving  a  centifuge  after  most  of  the  solids  have  been  removed 

CENTRIFUGAL  PUMP  (sen-TRlF-uh-gull)  CENTRIFUGAL  PUMP 

A  pump  consisting  of  an  impeller  fixed  on  a  rotating  shaft  that  is  enclosed  in  a  casing,  and  having  an  miet  and  discharge  con- 
nection. As  the  rotating  impeller  whirls  the  water  around,  centrifugal  force  builds  up  enough  pressure  to  force  the  water  through 
the  discharge  outlet 

CENTRIFUGE  CENTRIFUGE 
A  mechanical  device  that  uses  centrifugal  or  rotational  forces  to  separate  solids  from  liquids 

CHECK  SAMPLING  CHECK  SAMPLING 

Whenever  an  initial  or  routine  sample  analysis  indicates  that  an  MCL  has  been  exceeded.  CHECK  SAMPLING  is  required  to 
confirm  the  routine  sampling  results.  Check  sampling  is  in  addition  to  the  routine  sampling  program. 

CHECK  VALVE  CHECK  VALVE 

A  special  valve  with  a  hinged  disc  or  flap  that  opens  in  the  direction  of  normal  flow  and  is  forced  shut  when  flows  attempt  to  go 
in  the  reverse  or  opposite  direction  of  normal  flow. 

CHELATING  AGENT  (key-LAY-tmg)  CHELATING  AGENT 

A  chemical  used  to  prevent  the  precipitation  of  metals  (such  as  copper). 

CHELATION  (key-LAY-shun)  CHELATION 

A  chemical  complexing  (forming  or  joining  together)  of  metallic  cations  (such  as  copper)  with  certain  organic  compounds,  such 
as  EDTA  (ethylene  diamine  tetracetic  acid)  Chelation  is  used  to  prevent  the  precipitation  of  metals  (copper).  Also  see 
SEQUESTRATION. 

CHLORAMINATION  (KLOR-am-i-NAY-shun)  CHLORAMINATION 
The  application  of  chlorine  and  ammonia  to  water  to  form  chloramines  for  the  purpose  of  disinfection. 

CHLORAMINES  (KLCR-uh-means)  CHLORAMINES 
Compounds  formed  by  th*^  reaction  of  hypochlorous  acid  (or  aqueous  chlorine)  with  ammonia. 

CHLORINATION  (KLOR-uh-NAY-shun)  CHLORINATION 

The  application  of  chlorine  to  water,  generally  for  the  purpose  of  disinfection,  but  frequently  for  accomplishing  other  biological 
or  chemical  results  (ahing  coagulation  and  controlling  tastes  and  odors) 

CHLORINATOR  (KLOR-uh-NAY-ter)  CHLORINATOR 
A  metering  device  which  is  used  to  add  chlorine  to  water 


Words  609 


CHLORINE  DEMAND  CHLORINE  DEMAND 

Chlorine  demand  js  the  difference  between  the  amount  of  chlorine  added  to  water  and  the  amount  of  residual  chlorine 
remaining  after  a  given  contact  time  Chlorine  demand  may  change  with  dosage,  time,  temperature,  pH,  and  nature  and  amount 
of  the  impurities  in  the  water. 

Chlorine  Demand,  mg/L  =      Chlorine     -  Chlonne 

Applied,  mg/L     Residual,  mg/L 

CHLORINE  REQUIREMENT  CHLORINE  REQUIREMENT 

The  amount  of  chlonne  which  is  needed  for  a  particular  purpose  Some  reasons  for  adding  chlorine  are  reducing  the  number  of 
coliform  bacteria  (Most  Probable  Number),  obtaining  a  particular  chlorine  residual,  or  oxidizing  some  substance  m  the  water.  In 
each  case  a  definite  dosage  of  chlorine  will  be  necessary  This  dosage  is  the  chlorine  requirement. 

CHLOROPHENOLIC  (klor-o-FEE-NO-lick)  CHLOROPHENOLIC 
Chlorophenolic  compounds  are  phenolic  compounds  (carbolic  acid)  combined  with  chlonne. 

CHLOROPHENOXY  (KLOR-o-fuh-KNOX-ee)  CHLOROPHENOXY 

A  class  of  herbicides  that  may  be  founc<  in  domestic  water  supplies  and  cause  adverse  health  effects.  Two  widely  used  chloro- 
phenoxy  herbicides  are  2,4-D  (2.4-Dichlorophenoxy  acetic  ac.d)  and  2,4,5-TP  (2,4,5-Trichlorophenoxy  propionic  acid  (silvex)). 

CHLORORGANIC  (klor-or-GAN-nick)  CHLORORGANIC 

Organic  compounds  combinec*  ;vith  chlonne  These  compounds  generally  originate  from,  or  are  associated  with,  life  processes 
such  as  those  of  algae  in  water. 

CIRCLE  OF  INFLUENCE  CIRCLE  OF  INFLUENCE 

The  circular  outer  edge  of  a  depression  produced  in  the  water  table  by  the  pumping  of  water  rrom  a  well.  Also  see  CONE  OF 
INFLUENCE  and  CONE  OF  DEPRESSION 

(SEE  DRAWING  ON  PAGE  600] 
CIRCUIT  CIRCUIT 

The  complete  path  of  an  electric  current,  including  the  generating  apparatus  or  other  source,  or,  a  specific  segment  or  section 
of  the  complete  path. 

CIRCUIT  BREAKER  CIRCUIT  BREAKER 

A  safety  device  in  an  electrical  circuit  that  automatically  shuts  off  the  circuit  when  it  becomes  overlOc  ^ed.  The  device  can  be 
manually  reset. 

CISTERN  (SIS-turn)  CISTERN 
A  smaM  tank  (usually  covered)  or  a  storage  facility  used  to  store  water  for  a  home  or  farm  Often  used  to  store  ram  water. 

CLARIFIER  (KLAIR-uh-fire)  CLARIFIER 

A  large  circular  or  rectangular  tank  or  basin  in  which  water  is  held  for  a  period  of  time  during  which  the  heavier  suspended 
solids  settle  to  the  bottom  Clarifie.s  are  also  called  SETTLING  BASIN  I  and  SEDIMENTATION  BASINS 

CLEAR  WELL  CLEAR  WELL 

A  reservoir  for  the  storage  of  filtered  water  of  sufficient  capacity  to  prevent  the  need  to  vary  the  filtration  rate  with  variations  in 
demand  Also  used  to  provide  chlonne  contact  time  for  disinfection. 

COAGULANT  AID  COAGULANT  AID 

Any  chemical  or  substance  used  to  assist  or  modify  coagulation. 

COAGULANTS  (co-AGG-you-lents)  COAGULANTS 

Chemicals  that  cause  very  fine  particles  to  clump  together  into  larger  particles.  This  makes  it  easier  to  separate  the  solids  from 
the  water  by  settling,  skimming,  draining  or  filtenng. 

COAGULATION  (co-AGG-you-LAY-shun)  COAGULATION 

The  clumping  together  of  very  fine  particles  into  larger  particles  caused  by  the  use  of  chem.cals  (coagulants).  The  ch'^micals 
neutralize  the  electrical  charges  of  the  fine  particles  and  cause  destabilization  of  the  particles.  This  clumping  together  makes  it 
easier  to  separate  the  solids  from  the  water  by  settling,  skimming,  draining,  or  filtering. 

COLIFORM  (COAL-i-form)  COLIFORM 

A  group  of  bacteria  found  in  the  intestines  of  warm-blooded  animals  (including  humans)  and  also  in  plants,  soil,  air  and  water. 
Fecal  coliforms  are  a  specific  class  of  bactena  which  only  inhibit  the  ntestines  of  warm-blooded  animals.  The  presence  of  coli- 
form bacteria  is  an  indication  that  the  water  is  polluted  and  may  contain  pathogenic  organisms. 

^  828 


610 


Water  Treatment 


TOP  OR  PLAN  VIEW 


GROUND  SURFACE 


^ORIGINAL  WATER  LEVEL 

^CIRCLE 

OF  INFLUENCE 

CONE  OF  \ 

DEPRESSION — ^  \ 

^WELL 

I 


SIDE  OR  ELEVATION  VIEW 


ERIC 


62;} 


Words  611 


COLLOIDS  (CALL-loids)  COLLOIDS 

Very  small,  finely  divide  1  solids  (particles  that  do  not  dissolve)  that  remain  dispersed  in  a  liquid  for  a  long  time  due  to  their  small 
size  and  electrical  charge.  When  most  of  the  particles  in  v/ater  have  a  negative  electrical  charge,  they  tend  to  repel  each  other 
This  repulsion  prevents  the  particles  from  clumping  together,  becoming  heavier,  and  sGttling  out 

COLORIMETRIC  MEASUREMENT  COLORIMETRIC  MEASUREMENT 

A  means  of  measuring  unknown  chemical  concentrations  in  v/ater  by  measuring  a  sample's  color  intensity.  The  specific  color  of 
the  sample,  developed  by  addition  of  chemical  reagents,  is  measured  with  a  photoelectric  colorimeter  or  is  compared  with  "col- 
or standards"  using,  or  corresponding  with,  known  concentrations  of  the  chemical. 

COMBINED  AVAILABLE  RESIDUAL  CHLORINE  COMBINED  AVAILABLE  RESIDUAL  CHLORINE 

The  concentration  of  residual  chlorine  which  is  combined  with  ammonia  (NH3)  and/or  orgc  nc  nitrogen  in  water  as  a  chloramine 
(or  other  chloro  derivative)  yet  is  still  available  to  oxidize  organic  matter  and  utilize  its  bactericidal  properties 

COMBINED  RESIDUAL  CHLORINATION  COMBINED  RESIDUAL  CHLORINATION 

The  application  of  chlorine  to  water  to  produce  combined  available  residual  chlorine.  This  rtiidual  can  be  made  up  of 
monochloramines,  dichloramines,  and  nitrogen  trichloride. 

COMPLETE  TREATMENT  COMPLETE  TREATMENT 

A  method  of  treating  water  which  consists  of  the  addition  of  coagulant  chemicals,  flash  mixing,  coaguiation-flocculation, 
sedimentation  and  filtration.  Also  called  CONVENTIONAL  FILTRATION. 

COMPOSITE  (come-PAH-zit)  (PROPORTIONAL)  SAMPLES  COMPOSITE  (PROPORTIONAL)  SAMPLES 

A  composite  sample  is  a  collection  of  individual  samples  c'  ..led  at  regular  mtei  'als,  usually  every  one  or  two  hours  dunng  a 
24-nour  time  span.  Each  individual  sample  is  combined  witn  the  others  m  proportion  to  the  rate  of  flow  when  the  sample  was 
collected.  The  resulting  rnixture  (composite  sample)  forms  a  representative  sample  anc'  <s  analyzed  to  determine  the  average 
conditions  during  the  sampling  period 

COMPOUND  COMPOUND 

A  substance  compc:*Rd  of  two  or  more  elements  whose  composition  is  constant.  For  example,  table  salt  (sodium  chloride- 
NaCI)  IS  a  compound. 

CONCENTRATION  POLARIZATION  CONCENTRATION  POLARIZATION 

(1 )  The  ratio  of  the  salt  concentration  in  the  membrane  boundary  layer  to  the  salt  concentration  in  the  water  being  treated  The 
most  common  and  serious  problem  resulting  from  concentration  polarization  is  the  increasing  tendency  for  precipitation  of 
sparingly  soluble  sal*s  anc*  vhe  deposition  of  particulate  matter  on  the  membrane  surface. 

(2)  Used  in  corrosion  studies  to  indicate  a  depletion  of  Ions  near  an  electrode. 

(3)  The  basis  for  chemical  analysis  by  a  polarograph. 

CONDITIONING  CONDITIONING 
Pretreatment  of  sludge  to  facilitate  removal  of  water  in  subsequent  treatment  processes 

CONDUCTANCE  CONDUCTANCE 

A  rapid  method  of  estimating  the  dissolved-solids  content  of  a  water  supply.  The  measurement  indicates  the  capacity  of  a  sarr  - 
pie  of  water  to  carry  an  electrical  current,  which  is  related  to  the  concentration  of  ionized  substances  in  the  water  Also  call*^ d 
SPECIFIC  CONDUCTANCE. 

CONDUCTIVITY  CONDUCTIVITY 
A  measure  of  the  ability  of  a  solution  (water)  to  carry  an  electric  curren' 

CONDUCTOR  CON  DUCTOR 

A  substance,  body,  device  or  wire  that  readily  conducts  or  carries  electrical  current. 

CONDUCTOR  CASING  CONDUCTOR  CASING 

Tne  outer  cas«ng  of  a  well.  The  purpose  of  this  casing  is  to  prevent  contaminants  from  surface  waters  c  shallow  ,  oundwaters 
from  entering  a  well. 

CONE  OF  DEPRESSION  CONE  OF  DEPRESSION 

The  depression,  roughly  conical  in  shape,  produced  in  the  water  table  by  the  pumping  of  water  from  a  well  Also  see  CIRCLE 
OF  INFLUENCE  and  CONE  OF  INFLUENCE. 

[SEE  DRAWING  ON  PAGE  610] 

C  •  .  630 


612  Water  Treatment 


CONE  OF  INFLUENCE  CONE  OF  INFLUENCE 

J^J'i^^J!?.%l'3Pr^  ^^^P®'  P''0'^"ced  in  the  water  table  by  the  pumping  of  water  from  a  well.  Also  see  CIRCLE 

OF  INFLUENCE  and  CONE  OF  DEPRESSION 

[SEE  DRAWING  ON  PAGE  600] 

CONFINED  SPACE-  CONFINED  SPACE 

A  space  defined  by  the  concurrent  existence  of  the  following  conditions. 

A  Existing  ventilation  is  insufficient  to  remove  dangerous  air  contamination  and/or  oxygen  deficiency  which  may  exisi  or  de- 
velop, and 

B  Ready  access  or  egress  (getting  out)  for  the  removal  of  a  suddenly  disabled  employee  (operator)  is  difficult  due  to  the  loca- 
tion and/or  size  of  the  opening(s) 

Also  see  definitions  of  DANGEROUS  AIR  CONTAMINATION  and  DEFICIENCY, 

CONSOLIDATED  FORMATION  CONSOLIDATED  FORMATION 

A  geologic  material  whose  particles  are  stratified  (layered),  cemented  or  firmly  packed  together  (hard  rock),  usually  occurnnq  at 
a  depth  below  the  ground  surface.  Also  see  UNCONSOLIDATED  FORMATION. 

CONTACTOR  CONTACTOR 
An  electrical  switch,  usually  magnetically  operated 

CONTAMINATION  CONTAMINATION 

The  introduction  into  water  of  microorganisms,  chemicals,  toxic  substances,  wastes,  or  wastewater  in  a  concentration  that 
makes  the  water  unfit  for  its  next  intended  use 

CONTINUOUS  SAMPLE  CONTINUOUS  SAMPLE 

A  flow  of  water  from  a  particular  place  in  a  plant  to  the  location  where  samples  are  collected  for  testing.  This  continuous  stream 
may  be  used  to  obtain  grab  or  composite  samples  Frequently,  several  taps  (faucets)  will  flow  continuously  m  the  laboratory  to 
provide  test  samples  from  various  places  in  a  water  treatment  plant. 

CONTROL  LOOP  CONTROL  LOOP 

The  path  through  the  control  system  between  the  sensor,  which  measures  a  process  variable,  and  the  controller  which  con- 
trols or  adjusts  the  process  variable. 

CONTROL  SYSTGM  CONTROL  SYSTEM 

A  system  which  senses  and  controls  its  own  operation  on  a  close,  continuous  basis  in  what  is  called  DroDortional  (or 
modulating)  control.  ^   ^  ^ 

CONTROLLER  CONTROLLER 
A  device  which  controls  the  starting,  stopping,  or  operation  of  a  device  or  piece  of  equipment 

CONVENTIONAL  FILTRATION  CONVENTIONAL  FILTRATION 

A  method  of  treating  water  which  consists  of  the  addition  of  coagulant  chemicals,  flash  mixing,  coagulation-flocculation 
sedimentation  and  filtration  Also  called  COMPLETE  TREATMENT.  Also  see  DIRECT  FILTRATION  and  IN-LINE  FILTRATION. 

CONVENTIONAL  TREATMENT  CONVENTIONAL  TREATMENT 

See  CONVENTIONAL  FILTRATION.  Also  called  COMPLETE  TREATMENT. 

CORPORATION  STOP  CORPORATION  STOP 

A  water  service  shutoff  valve  located  at  a  street  water  mam  This  valve  cannot  be  operated  from  the  ground  surface  because  it 
IS  buried  and  there  is  no  valve  box.  Also  called  a  CORPORATION  COCK. 

CORROSION  CORROSION 
The  gradual  decomposition  or  destruction  of  a  material  by  chemical  action,  often  dec.  to  an  electrochemical  reaction  Corrosion 
may  be  caused  by  (1)  stray  current  electrolysis.  (2)  galvanic  corrosion  caused  by  dissimilar  metals,  or  (C)  differential- 
concentration  cells.  Co'-rosion  starts  at  the  surface  of  a  material  and  moves  inward. 

CORROSION  INHIBITORS  CORROSION  INHIBITORS 

Substances  that  slow  the  rate  of  corrosion. 


CONFINED  SPACES,  General  Industry  Safety  Orders,  Article  108,  Title  8.  California  Administrative  Code,  Cal/OSHA  Consultation 
Service,  Sacramento,  California,  October,  1980. 


Er|c  631 


Words  613 


CO  R  ROS I VIT  Y  CO  R  ROS I VITY 

An  indication  of  the  corrosiveness  of  a  water  The  corrosiveness  of  a  water  is  described  by  the  water  s  pH,  alkalinity,  hardness, 
temperature,  total  dissolved  solids,  dissolved  oxygen,  and  the  Langelier  Index. 

COULOMB  (COO-lahm)  COULOMB 

A  measurement  of  the  amount  of  electrical  charge  conveyed  by  an  electric  current  of  one  ampere  in  one  second  One  ccjlomb 
equals  about  6.25  x  10^^  electrons  (6,250,000.000.000,000,000  electrons). 

COUPON  COUPON 

A  steel  specimen  inserted  into  water  to  measure  the  corrosiveness  of  water.  The  rate  of  corrosion  is  measured  as  the  loss  of 
weight  of  the  coupon  (in  milligrams)  per  surface  area  (in  square  decimeters)  exposed  to  the  water  per  day. 

10  decimeters  =  1  meter  =  100  centimeters 

CROSS-CONNECTION  CROSS-CONNECTION 

A  connection  between  a  drinking  (potable)  water  system  and  an  unapproved  water  supply  For  example,  if  you  have  a  pump 
moving  nonpotable  water  and  hook  into  the  drinking  water  system  to  supply  water  for  the  pump  seat,  a  cross-connection  or 
mixing  between  the  two  water  systems  can  occur.  This  mixing  may  lead  to  contamination  of  the  drinking  water. 

CURB  STOP  CURB  STOP 

A  water  service  shutoff  valve  located  in  a  water  service  pipe  near  the  curb  and  between  the  water  main  and  the  building.  This 
valve  IS  usually  operated  by  a  wrench  or  valve  key  and  is  used  to  start  or  stop  tlows  in  the  water  service  line  to  a  building.  Also 
called  a  "curb  cock. " 

CURIE  CURIE 

A  measure  of  radioactivity  One  Cune  of  radioactivity  is  equivalent  to  3.7  -  10^°  or  37.000,000,000  nuclear  disintegrations  per 
second. 

CURRENT  CURRENT 

A  movement  or  flow  of  electricity  Water  flowing  in  a  pipe  is  measured  in  gallons  per  second  past  a  certain  point,  not  by  the 
number  of  water  molecules  going  past  a  point  Electric  current  is  measured  by  the  number  of  coulombs  per  second  flowing  past 
a  certain  point  in  a  conductor.  A  coulomb  is  equal  to  about  6.25  ^  10^^  electrons  (6,25o.000,000,000, 000,000  electrons)  A  flow 
of  one  coulomb  per  second  is  called  one  ampere,  the  unit  of  the  rate  of  flow  of  current. 

CYCLE  CYCLE 
A  complete  alteration  of  voltage  and/or  current  in  an  alternating  current  (A.C.)  circuit. 

DANGEROUS  AIR  CONTAMINATION  DANGEROUS  AIR  CONTAMINATION 

An  atmosphere  presenting  a  threat  of  causing  death,  injury,  acute  illness,  or  disablement  due  to  the  presence  of  flammable 
and/or  explosive,  toxic  or  otherwise  injurious  or  incapacitating  substances. 

A  Dangerous  air  contamination  due  to  the  flammability  of  a  gas  or  vapor  is  defined  as  an  atmosphere  containing  the  gas  or  va- 
por at  a  concentration  greater  than  20  percent  of  its  lower  explosive  (lower  flammable)  limit. 

B  Dangerous  air  contamination  due  to  a  combustible  particulate  is  defined  ab  a  concentration  greater  than  20  percent  of  the 
minimum  explosive  concentration  of  the  particulate. 

C  Dangerous  air  contamination  due  to  the  toxicity  of  a  substance  is  defined  as  the  atmospheric  concentration  immediately 
hazardous  to  life  or  health. 

DATEOMETER  (day-TOM-uh-ter)  DATEOMETER 

A  small  calendar  disc  attached  to  motors*  and  equipment  to  indicate  the  year  in  which  the  last  maintenance  service  was  per- 
formed. 

DATUM  LINE  DATUM  LINE 

A  line  from  which  heights  and  depths  are  calculated  or  measured  Also  called  a  DATUM  PLANE  c  a  DATUM  LEVEL 

DAY  TANK  DAY  TANK 

A  tank  used  to  store  a  chemical  solution  of  known  concentration  for  feed  to  a  chemical  *eeder  A  day  tank  usually  stores  suffi- 
cient chemical  solution  to  properly  treat  the  water  being  treated  for  at  least  one  day.  AJso  called  an  AGE  TANK. 

DEAD  END  DEAD  END 

The  end  of  a  water  mam  which  is  not  connected  to  other  parts  of  the  distribution  system  by  means  of  a  connectn  .g  loop  of  pipe. 

DECANT  DECANT 
To  draw  off  the  upper  layer  of  liquid  (water)  after  the  heavier  material  (a  solid  or  another  liquid)  has  settled. 

^  632 


614  Water  Treatment 


DECHLORINATION  (dee-KLOR-uh-NAY-shun)  DECHLORINATION 

The  deliberate  removal  of  chlorine  from  water  The  partial  or  complete  reduction  of  residual  chlorine  by  any  chemical  or  Dhvs- 
icaf  process.  ^ 

DECIBEL  (DES-uh-bull)  DECIBEL 

A  unit  for  expressing  the  relative  intensity  of  sounds  on  a  scale  from  zero  for  the  average  least  perceptible  sound  to  about  130 
for  tJ^e  average  level  at  which  sound  causes  pain  to  humans. 

DECOMPOSITION  DECOMPOSITION 
The  conversion  of  chemically  unstable  materials  to  more  stable  forms  by  chemical  or  biological  action.  If  organic  matter  decays 
when  there  is  no  oxygen  present  (anaerobic  conditions  or  putrefaction),  undesirable  tastes  and  odors  are  produced  Decay  of 
organic  matter  when  oxygen  is  present  (aerobic  conditk  ^s)  tends  to  produce  much  less  objectionable  tastes  and  odors. 

DEFLUORIDATION  (de-FLOOR-uh-DAY-shun)  DEFLUORIDATION 
The  removal  of  excess  fluoride  in  drinking  water  to  prevent  the  mottling  (orown  stains)  of  teeth. 

DEGASIFICATION  (DEE-GAS-if-uh-KAY-shun)  DEGASIFICATION 

M  water  treatment  process  which  -emoves  dissolved  gases  from  the  water  The  gases  may  be  removed  by  either  mechanical  or 
chemical  treatment  methods  or  a  combination  of  both. 

DEMINERALIZATION  (DEE-MIN-er-al-uh-ZAY-shun)  DEMINERALIZATION 
A  treatment  process  which  removes  dissolved  minerals  (salts)  from  water. 

DENSITY  (DEN-sit-tee)  DENSITY 
A  measure  of  how  heavy  a  substance  (solid,  liquid  or  gas)  is  for  its  size.  Density  is  expressed  in  terms  of  weight  per  unit  volume 
that  IS,  grams  per  cubic  centimeter  or  pounds  per  cubic  feet.  The  density  of  water  (at  4°C  or  39^F)  is  1.0  gram  per  cubic  centi- 
meter or  about  62.4  pounds  per  cubic  foot. 

DESALINIZATION  (DEE-SAY-leen-uh-ZAY-shun)  DESALINIZATION 

ThG  removal  of  dissolved  salts  (such  as  sodium  chlonde,  NaCI)  from  water  by  natural  means  (leachinq)  or  bv  specific  water 
treatment  processes. 

DESICCANT  (DESS-uh-kant)  DESICCANT 
A  drying  agent  which  is  capable  of  removing  or  absorbing  moisture  from  the  atmosphere  in  a  small  enclosure. 

DESICCATION  (DESS-uh-KAY-shun)  DESICCATION 
A  process  used  to  thoroughly  dry  air;  to  remove  virtually  all  moisture  from  air. 

DESICCATOR  (DESS-uh-KAY-tor)  DESICCATOR 
A  closed  container  into  which  heated  weighing  or  drying  dishes  are  placed  to  cool  in  a  dry  environment.  The  dishes  may  be 
empty  or  they  may  contain  a  sample.  Desiccators  contain  a  substance,  sur^  as  anhydrous  calcium  chlonde  which  absorbs 
moisture  and  keeps  the  relative  .umidity  near  zero  so  that  the  dnh  or  sa.nple  v^HI  not  gam  vveight  from  absorbed  moisture. 

DESTRATIFICATION  (de-STRAT-uh-fuh-KAY-shun)  DESTRATIFICATION 
The  development  of  vertical  mixing  within  a  lake  or  reservoir  to  eliminate  (either  totally  or  partially)  separate  layers  of 
temperature,  plant,  or  animal  life  This  vertical  mixing  can  be  caused  by  mechanical  means  (pumps)  or  through  the  use  of  forced 
air  diffusers  which  release  air  into  the  lower  layers  of  the  reservoir. 

DETECTION  LAG  DETECTION  LAG 

The  time  period  between  the  moment  a  change  is  made  and  the  moment  when  such  a  change  is  finally  sensed  by  the  associat- 
ed measuring  instrument. 

DETENTION  TIME  DETENTION  TIME 

(1)  The  theoretical  (calculated)  time  required  for  a  small  amount  of  water  to  pass  through  a  tank  at  a  given  rate  of  flow. 

(2)  The  actual  time  in  hours,  minutes  or  seconds  that  a  small  amount  of  water  is  in  a  settling  basin,  flocculating  basin  or  rapid- 
mix  chamber  In  storage  reservoirs,  detention  time  is  the  length  of  time  entering  water  will  be  held  before  being  drafted  for 
use  (several  weeks  to  years  several  months  being  typical). 

Detention  Time,  hr=:(BQsin  Volume,  gal)(24  hr/day) 

Flow,  gal/day 

DEW  POINT  POI^^ 
The  temperature  to  which  air  with  a  given  quantity  of  water  vapor  must  be  cooled  to  cause  condensation  of  the  vapor  in  the  air. 

633 


Words  615 


DEWATER  DEWATER 

(1)  To  remove  or  separate  a  portion  of  the  water  present  in  a  sludge  or  slurry.  To  dry  sludge  so  it  can  be  handled  and  disposed 
of 

(2)  To  remove  or  dram  the  water  from  a  tank  or  a  trencn. 

DIATOMACEOUS  EARTH  (DYE-uh-toe-MAY-shus)  DIATOMACEOUS  EARTH 

A  fme.  siliceous  (made  of  silica)  "earth"  composed  matnly  of  the  skeletal  remains  of  diatoms 

DIATOMS  (DYE-uh-toms)  DIATOMS 
Unicellular  (single  cell),  microscopic  algae  with  a  rigid  (box-like)  internal  structure  consisting  mainly  of  silica. 

DIGITAL  READOUT  DIGITAL  READOUT 

Use  of  numbers  to  indicate  the  value  or  measurement  of  a  variable.  The  readout  of  an  instrument  by  a  direct,  numencal  reading 
of  the  measured  value. 

DILUTE  SOLUTION  DILUTE  SOLUTION 

A  solution  that  has  been  made  weaker  usually  by  the       hon  of  water. 

DIMICTIC  (die-MlCK-tick)  DIMICTIC 
Lakes  and  reservoirs  which  freeze  over  and  normally  go  through  two  stratification  and  two  mixing  cycles  within  a  year. 

DIRECT  CURRENT  (D.C  )  DIRECT  CURRENT  (D.C.) 

Electrical  current  flowing  in  one  direction  only  and  essentially  free  from  pulsation. 

DIRECT  FILTRATION  DIRECT  FILTRATION 

A  method  of  treating  water  which  consists  of  the  addition  o'  coagulanf  chemicals,  flash  mixing,  coagulation,  minimal 
flocculation,  and  filtration.  The  flocculation  facilities  may  be  omitted,  but  the  physical-chemical  reactions  vv^ill  occur  to  seme  ex- 
tent. The  sedimentation  process  is  omitted.  Also  see  CONVENTIONAL  FILTRATION  and  IN-LINE  FILTRATION. 

DIRECT  RUNOFF  DIRECT  RUNOFF 

Water  that  flows  over  the  ground  surface  or  through  the  ground  drectly  into  streams,  rivers,  or  lakes. 

DISCHARGE  HEAD  DISCHARGE  HEAD 

The  pressure  (in  pounds  per  square  inch  or  psi)  measured  at  the  centerline  of  a  pump  discharge  and  very  close  to  the  discharge 
flange,  converted  into  feet. 

Discharge  Head,  ft  =  (Discharge  Pressure,  psi)(2  31  ft/psi) 

DISINFECTION  (dis-in-FECK-shun)  DISINFECTION 

The  process  designed  to  kill  most  microorganisms  in  water,  including  essentially  all  pathogenic  (disease-causing)  baclena 
There  are  several  ways  to  disinfect,  with  chlorine  being  most  frequently  used  in  water  treatment.  Compare  with  STERILIZA- 
TION. 

DISTILLATE  (DiS-tuh-late)  DISTILLATE 
In  the  distillation  of  a  sample,  a  portion  is  evaporated,  the  part  that  is  condensed  afterwards  is  the  distillate. 

DIVALENT  (die-VAY-lent)  DIVALENT 
Having  a  valence  of  two,  such  as  the  ferrous  ion,  Fe^'. 

DIVERSION  DIVERSION 
Use  of  part  of  a  stream  flow  as  a  water  supply. 

DPD  (pronounce  as  separate  leUers)  DPD 

A  method  of  measuring  the  chlorine  residual »"  iter.  The  residual  may  be  determined  by  either  titrating  or  comparing  a  devel- 
oped color  with  color  standards.  DPD  stano&  .or  N.N-diethyl-p-phenylene-diamine. 

DRAFT  DRAFT 

(1)  The  act  of  drawing  c  removing  water  from  a  tank  or  reservoir. 

(2)  The  water  which  is  drawn  or  removed  from  a  tank  or  reservoir. 


634 


616  Water  Treatment 


DRAWDOWN  DRAWDOWN 

(1)  The  drop  in  the  water  table  or  level  of  water  in  the  ground  when  water  is  being  pumped  from  a  well. 

(2)  The  amount  of  water  used  from  a  tank  or  reservoir. 

(3)  The  drop  in  the  water  level  of  a  tank  or  reservoir 

DYNAMIC  PRESSURE  DYNAMIC  PRESSURE 

When  a  pump  is  operating,  the  vertical  distance  (in  feet)  from  a  reference  point  (such  as  a  pumD  centerline)  to  the  hydraulic 
grade  line  is  the  dynamic  head. 

Dynamic  Pressure,  psi  =  (Dynamic  Head,  ft)  (0.433  psi/ft) 

EDUCTOR  (e-DUCK-ter)  5DUCT0R 

A  hydraulic  device  used  to  create  a  negative  pressure  (suction)  by  forcing  a  I  quid  through  a  restriction,  such  as  a  Venturi.  An 
eductor  or  aspirator  (the  hydraulic  device)  may  be  used  m  the  laboratory  in  place  of  a  vacuum  pump.  As  an  injector,  it  is  used  to 
produce  vacuum  for  chlorinators. 

EFFECTIVE  RANGE  EFFECTIVE  RANGE 

That  portion  of  the  design  range  (usually  upper  90  percent)  in  which  an  instrument  has  acceptable  accuracy  Also  see  RANGE 
and  SPAN. 

EFFECTIVE  SIZE  (E.S  )  EFFECTIVE  SIZE  (E.S.) 

The  diameter  of  the  particles  in  a  granular  sample  (filter  media)  for  which  10  percent  of  the  total  grains  are  smaller  and  90  per- 
cent larger  on  a  weight  basis  Effective  size  is  obtained  by  passing  granular  material  through  sieves  with  varying  dimensions  of 
mesh  and  weighing  the  material  retained  by  each  sieve.  The  effective  size  is  also  approximately  the  average  size  of  the  grams. 

EFFLUENT  (EF-loo-ent)  EFFLUENT 

Water  or  other  liquid  —  raw.  partially  or  completely  treated  —  flowing  FROM  a  reservoir,  bas»n.  treatment  process  or  treatment 
plant. 

EJECTOR  EJECTOR 
A  device  used  to  disperse  a  chemical  solution  into  water  being  treated. 

ELECTROCHEMICAL  REACTION  ELECTROCHEMICAL  REACTION 

Chemical  changes  produced  by  electricity  (electrolysis)  or  the  production  of  electncity  by  chemical  changes  (galvanic  action).  In 
corrosion,  a  chemical  reaction  is  accompanied  by  the  flow  of  electrons  through  a  metallic  path.  The  electron  flow  may  come 
from  an  external  force  and  cause  the  reaction,  such  as  electrolysis  caused  by  a  D.C.  (direct  current)  electric  railway  or  the  elec- 
tron flow  may  be  caused  by  a  chemical  reaction  as  in  the  galvanic  action  of  a  flashlight  dry  cell. 

ELECTROCHEMICAL  SERIES  ELECTROCHEMICAL  SERIES 

A  list  of  metals  with  the  standard  electrode  potentials  given  m  volts.  The  size  and  sign  of  the  electrode  potential  indicates  how 
easily  these  elements  will  take  on  or  give  up  Plectrons,  or  corrode.  Hydrogen  is  conventionally  assigned  a  value  of  zero. 

ELECTROLYSIS  (ee-leck-TRAWL-uh-sis)  ELECTROLYSIS 
The  decomp'   tion  of  material  by  an  outside  electrical  current 

ELECTROLYTE  (ee-LECK-tro-LIGHT)  ELECTROLYTE 
A  substance  which  dissociates  (separates)  into  two  or  more  ions  when  it  is  dissolved  in  water. 

ELECTROLYTIC  CELL  (ee-LECK-tro-LIT-ick)  ELECTROLYTIC  CELL 

A  device  in  which  the  chemical  decomposition  of  material  causes  an  electric  current  to  flow.  Also,  a  device  <n  which  a  chemical 
reaction  occurs  as  a  result  of  the  flow  of  electric  current.  Chlorine  and  caustic  (NaOH)  are  made  from  salt  (NaCi)  m  eletrolytic 
cells. 

ELECTROMOTIVE  FORCE  (E.M.F.)  ELECTROMOTIVE  FORCE  (E.M  F.) 

The  electrical  pressure  available  to  cause  a  flow  of  current  (amperage)  when  an  electncal  circuit  is  closed.  See  VOLTAGE. 

ELECTROMOTIVE  SERIES  ELECTROMOTIVE  SERIES 

A  list  of  metals  and  alloys  presented  in  the  order  of  their  tendency  to  corrode  (or  go  into  l  jiution).  Also  called  the  Galvanic  Se- 
ries. This  is  a  practical  application  of  the  theoretical  ELECTROCHEMICAL  SERIES. 

ELECTRON  ELECTRON 
An  extremely  small,  negatively  charged  particle,  the  part  of  an  atom  that  determines  its  chemical  properties 

633 


Words  617 


ELEMENT  ELEMENT 

A  substance  which  cannot  be  separated  into  its  constituent  parts  and  still  retain  its  chemical  identity  For  example,  sodium  (Na) 
IS  an  element. 

END  BELLS  END  BELLS 

Devices  ijsed  to  hold  the  rotor  and  stator  of  a  motor  m  position. 

END  POINT  END  POINT 

Samples  are  titrated  to  the  end  point  This  means  that  a  chemical  is  added,  drop  by  drop,  to  a  sample  until  a  certain  color 
change  (blue  to  "lear.  for  example)  occurs  This  is  called  the  END  POINT  of  the  titration.  In  addition  to  a  color  change,  an  end 
point  may  be  reached  by  the  formation  of  a  precipitate  or  the  reaching  of  z  specified  pH.  An  end  pomt  may  be  detected  by  the 
use  of  an  electronic  device  such  as  a  pH  meter 

ENDEMIC  (en-DEM-ick)  ENDEMIC 
Something  peculiar  to  a  particular  people  or  locality,  such  as  a  disease  v/hich  is  always  present  in  the  population. 

ENDRIN  (EN-drin)  ENDRIN 
A  pesticide  toxic  to  freshwater  and  marine  aquatic  life  that  produces  adverse  health  effects  m  domestic  water  supplies. 

ENERGY  GRADE  LINE  (EGL)  ENERGY  GRADE  LINE  (EGL) 

A  line  that  represents  the  elevation  of  energy  iiead  of  water  flowing  in  a  pipe,  conduit  or  channel.  The  line  is  drawn  above  the 
hydraulic  grade  line  (gra^^^ent)  a  distance  equal  to  the  velocity  head  (V2/2g)  of  the  water  flowing  at  each  section  or  point  along 
the  pipe  or  channel.  AL    .ee  HYDRAULIC  GRADE  LINE. 

[SEE  DRAWING  ON  PAGE  618] 

ENTERIC  ENTERIC 
Of  intestinal  origin,  especially  applied  to  wastes  or  bactena. 

ENTRAIN  ENTRAIN 
To  trap  bubbles  m  water  either  mechanically  through  turbulence  or  chemically  through  a  reaction. 

ENZYMES  (EN-zimes)  ENZYMES 

Organic  substances  (produced  by  living  organisms)  which  cause  or  speed  up  chemical  reactions.  Organic  catalysts  and/or  bio- 
chemical catalysts. 

E.PA  E.P.A. 
U.S.  Environmental  Protection  Agency. 

EPIDEMIC  (EP-uh-DEM-ick)  EPIDEMIC 
A  disease  that  occurs  in  a  large  numl>er  of  people  in  a  locality  at  the  same  time  and  spreads  from  person  to  person. 

EPIDEMIOLOGY  (EP-uh-DE-me-ALL-o-gee)  EP'DEMIOLOGY 

A  branch  of  medicine  which  studies  epidemics  (diseases  which  affect  significant  numbers  of  people  during  the  same  time  peri- 
od in  the  same  locality).  The  objective  of  epidemiology  is  to  determine  the  factors  that  cause  epidemic  diseases  and  how  to  pre- 
vent them. 

EPILIMNION  (EP-uh-LIM-knee-on)  EPILIMNION 

The  upper  layer  of  water  in  a  thermally  stratified  lake  or  reservoir.  This  layer  consists  of  the  warmest  w^ter  and  has  a  fairly 
uniform  (constant)  temperature.  The  layer  Is  readily  mixed  by  wind  action. 

EQUILIBRIUM,  CALCIUM  CARBONATE  EQUILIBRIUM.  CALCIUM  CARBONATE 

A  watr  r  IS  coi.  iered  stable  when  it  is  jUSt  saturated  with  calcium  carbonate.  In  this  condition  the  water  will  neither  dissolve  nor 
deposit  calcium  carbonate.  Thus,  in  this  water  the  calcium  carbonate  is  in  equilibrium  with  the  hydrogen  ion  concentration. 

EQUIVALENT  WEIGHT  EQUIVALENT  WEIGHT 

That  weight  which  will  react  with,  displace  or  is  equivalent  to  one  gram  atom  of  hydrogen. 

ESTER  ESTER 
A  compound  formed  by  the  reaction  between  an  acid  and  an  alcohol  with  the  elimination  of  a  molecule  of  water. 

EUTROPHIC  (you-TRO-fick)  EUTROPHIC 
Reservoirs  and  lakes  which  are  rich  in  nutrients  and  very  productive  in  terms  of  aquatic  anima.  and  plant  life. 

ER?C  .  636 


618  Water  Treatment 


Words  619 

EUTROPHICATION  (you-TRO-fi-KAY-shun)  EUTROPHICATION 
I^t'^T'^t^V^/M  °'  ^       °^  ^''^^^  ^^'^y  °'  ^2*®''       "sually  causes  an  increase  in  the  growth  of  aquatic 

aniiTlal  2nQ  pl3nt  III© 

EVAPORATION  EVAPORATION 
..V  process  by  which  water  or  other  liquid  becomes  a  gas  (water  vapor  or  ammonia  vapor) 

EVAPOTRANSPIRATlON(ee-VAP-o-TRANS-purr-A-shun)  EVAPCTRANSPIRATION 
The  process  by  which  water  vapor  passes  into  the  atmosphere  from  living  plants.  Also  called  TRANSPIRATION. 

FACULTATIVE  (FACK-ul-TAY-tive)  FACULTATIVE 
Facultative  bacteria  can  use  either  molecular  (dissolved)  oxygen  or  oxygen  obtained  from  food  material  such  as  sulfate  or  ni- 
»rate  ions  m  other  words,  facultative  bacteria  can  li^e  under  aerobic  or  anaerobic  conditions. 

FEEDBACK 

The  circulating  action  between  a  sensor  measuring  a  process  variable  and  the  controller  which  controls  or  adjusts  the  process 

FEEDWATER 

The  water  that  is  fed  to  a  treatment  process:  the  water  that  is  going  to  be  treated. 

FINISHED  WATER  FINISHED  WATER 

Water  that  has  passed  through  a  water  treatment  plant,  all  the  treatment  processes  are  completed  or  "finished."  This  water  is 
ready  to  be  delivered  to  consumers.  Also  caiie'i  PRODUCT  WATER. 

^^^^^^  FIX,  SAMPLE 

A  sample  is  "fixed'*  in  the  field  by  adding  chemicals  that  prevent  the  water  quality  indicators  of  interest  in  tne  sample  from  chanq- 
ing  before  final  measurements  are  performed  later  in  the  lab. 

FLAGELLATES  (FLAJ-el-LATES)  FLAGELLATES 
Microorgan-^fTs  that  move  by  the  action  of  tail-like  projections. 

FLAME  POLISKED  ^^^^^  pO^.SHED 

Melted  by  a  flame  to  smooth  out  irregularities  Sharp  or  broken  edges  of  glass  (such  as  the  end  of  a  glass  tube)  are  rotated  in  a 
flarne  until  the  edge  melts  slightly  and  becomes  smooth.  ;  me  mioieu  mi  d 

FLOAT  ON  SYSTEM  PLOAT  ON  SYSTEM 

A  methodof  operating  a  water  storage  facility  Daily  flow  into  the  facility  is  approximately  equal  to  the  average  daily  demand  for 
water  When  consumer  demands  for  water  are  low,  the  storage  facility  will  be  filling.  During  periods  of  high  demands,  the  facility 
Will  be  emotvina.  r  ^  , 


Will  be  emptying. 
FLOC 


FLOC 


Clumps  of  bacteria  and  particulate  impurities  that  have  come  together  and  formed  a  cluster.  Found  in  flocculation  tanks  and 
settling  or  sedimentation  basins. 

FLOCCULATION  (FLOCK-you-LAY-shun)  FLOCCULATION 
The  gathering  together  of  fine  particles  after  coagulation  to  forn,  larger  particles  by  a  process  of  gentle  mixing. 

FLUIDIZED(FLEW..d.|.2d)  FLUIDIZED 
A  mass  of  solid  particles  that  is  made  to  flow  like  a  liquid  by  injection  of  water  or  gas  is  said  to  have  been  fluidized.  In  water 
treatment,  a  bed  of  filter  media  is  fluidized  by  backwasnmg  water  through  the  filter. 

FLUORIDATION  (FLOOR-uh-DAY-shun)  FLUORIDATION 
The  addition  of  a  chemical  to  increase  the  concentration  of  fluoride  ions  in  drinking  water  to  a  predetermined  optimum  limit  to 
reduce  the  incidence  (number)  of  dental  caries  (tooth  decay)  in  children.  Defluoridation  is  the  removal  of  excess  fluoride  in 
drinking  water  to  prevent  the  mottling  (brown  stains)  of  teeth. 

f^l-USHING  PLASHING 
A  method  used  to  clean  water  distribution  lines.  Hydrants  are  opened  and  water  with  a  high  velocity  flows  through  the  pipes 
removes  deposits  from  the  pipes,  an^  flows  out  the  hydrants. 

•^"-^^  FLUX 
A  flowing  or  flow 

ERIC  ,t  ^38 


620  Water  Treatment 


FOOT  VALVE  FOOT  VALVE 

A  special  type  of  check  valve  located  at  the  bottom  end  of  the  suction  pipe  on  a  punrio  This  valve  opens  when  the  pump  oper- 
ates to  allow  water  to  enter  the  suction  pipe  but  closes  when  the  pump  shuts  off  to  prevent  water  from  flowing  out  of  the  suction 
pipe 

FREE  AVAILABLE  RESIDUAL  CHLORINE  FREE  AVAILABLE  RESIDUAL  CHLORINE 

That  portion  of  the  total  available  residual  jhlorine  composed  of  dissolved  chlorine  gas  (Cy,  hypochlorous  acid  (HOCI),  and/or 
hypochlorite  ion  (OCl  )  remaining  in  water  after  chlonnation.  This  does  not  .nclude  chlonne  that  has  combined  with  ammonia, 
nitrogen,  or  other  compounds. 

FREE  RESIDUAL  CHLORINATION  FREE  RESIDUAL  CHLORINATION 

The  application  of  chlorine  to  water  to  produce  a  free  available  chlorine  residual  equal  to  at  least  80  percent  of  the  total  residual 
chlorine  (sum  of  free  and  combined  available  chlorine  residual). 

FREEBOARD  FREEBOARD 

(1)  The  vertical  distance  from  the  normal  water  surface  to  the  top  of  the  confining  wall. 

(2)  The  vertical  distance  from  the  sand  surface  to  the  underside  of  a  trough  in  a  sand  fil- 
ter. This  distance  Is  also  called  AVAILABLE  EXPANSION. 


n 

FREEBOARD 

i 

— i 

wateOepth 

FRICTION  LOSSES  FRICTION  LOSSES 

The  head,  pressure  or  energy  {they  are  the  same)  lost  by  water  flowing  in  a  pipe  or  cha...iel  as  a  result  of  turbulence  caused  by 
the  velocity  of  the  flowng  water  and  the  roughness  of  the  pipe,  channel  walls,  and  restrictions  caused  by  fittings.  Water  flowing 
in  a  pipe  loses  pressure  or  energy  as  a  result  of  friction  losses.  Also  see  HEAD  LOSS. 

FUNGI  (FUN-ji)  FUNGI 

Mushrooms,  molds,  mildews,  rusts,  and  smuts  that  are  small  non^chlorophyll-bearing  plants  lacking  roots,  stems  and  leaves. 
They  occur  in  natural  waters  and  grow  best  in  the  absence  of  light.  Their  decomposition  may  cause  objectionable  tastes  and 
odors  in  water. 

FUSE  FUSE 

A  protective  device  having  a  stnp  or  wire  of  fusible  metal  which,  when  placed  in  a  circuit,  will  melt  and  break  the  electncal  circuit 
if  heated  too  much.  High  temperatures  will  develop  in  the  fuse  when  a  current  flows  through  the  fuse  in  excess  of  that  which  the 
circuit  will  carry  safely. 

GAGE  PRESSURE  GAGE  PRESSURE 

The  pressure  within  a  closed  container  or  pipe  as  measured  with  a  gage.  In  contrast,  absolute  pressure  is  the  sum  of  atmos- 
pheric pressure  {14.7  Ibs/sq  in)  PLUS  pressure  within  a  vessel  {as  measured  by  a  gage).  Most  pressure  gages  read  in  "gage 
pressure"  or  psig  {pounds  per  square  inch  gage  pressure). 

GALVANIC  CELL  GALVANIC  CELL 

An  eletrolytic  cell  capable  of  producing  electncal  energy  by  electrochemical  action.  The  decomposition  of  materials  in  the  cell 
causes  an  electric  (eleci.on)  current  to  flow  from  cathode  to  anode. 

GALVANIC  SERIES  GALVANIC  SERIES 

A  list  of  metals  and  a^'oys  presented  m  th3  order  of  their  tendency  to  corrode  (or  go  into  solution).  Also  called  the 
ELECTROMOTIVE  SERIES.  This  is  a  practical  application  of  the  theoretical  ELECTROCHEMICAL  SERIES. 

GALVANIZE  GALVANIZE 
To  coat  a  metr  (especially  iron  or  steel)  with  zinc.  Galvanization  is  the  process  of  coating  a  metal  with  zinc. 

GARNET  (GAR-nit)  GARNET 

A  group  of  hard,  reddish,  glassy,  mineral  sands  made  up  of  silicates  of  base  metals  (calcium,  magnesium,  iron  and 
manganese).  Garnet  has  a  higher  density  than  sand. 

GEOLOGICAL  LOG  GEOLOGICAL  LOG 

A  detailed  description  of  all  underground  features  discovered  during  the  drilling  of  a  well  (depth,  thickness  and  type  of 
formations). 

GEOPHYSICAL  LOG  GEOPHYSICAL  LOG 

A  record  of  the  structure  and  composition  of  the  earth  encountered  when  drilling  a  well  or  <5imilar  type  of  test  hole  or  bonng. 

GERMICIDE  (GERM-uh-SIDE)  GERMICIDE 
A  substance  formulated  to  kill  germs  or  mi  roorganisms.  The  germicidal  properties  of  chlorine  make  it  an  effective  disinfectant. 

Er|c  63J 


Words  621 


GIARDIASIS  (gee-are-DYE-uh-sis)  GIARDIASIS 
Intestinal  disease  caused  by  an  infestation  of  Giardia  flagellates 

GRAB  SAMPLE  GRAB  SAMPLE 

A  single  sample  collected  at  a  particular  time  and  place  which  represents  the  composition  of  the  water  only  at  that  time  and 
place. 

GRADE  GRADE 

(1)  The  elevation  of  the  in;ert  (lowest  point)  of  the  bottom  of  a  pipeline,  canal,  culvert  or  similar  conduit 

(2)  The  inclination  or  slope  of  a  pipeline,  conduit,  stream  channel,  or  natural  ground  surface,  usually  p.^pressed  in  terms  of  the 
ratio  or  percentage  of  number  of  units  of  vertical  rise  or  fall  per  unit  of  horizontal  distance  A  0.5  percent  grade  would  be  a 
drop  of  one-half  foot  per  hundred  feet  of  pipe. 

GRAVIMETRIC  GRAVIMETRIC 

A  means  of  measuring  unknown  concentrations  of  water  quality  indicators  in  a  sample  by  WEIGHING  a  precipitate  or  residue  of 
the  sample. 

GRAVIMETRIC  FEEDER  GRAVIMETRIC  FEEDER 

A  dry  chemical  feeder  which  delivers  a  measured  weight  of  chemical  during  c  specific  time  period. 

GREENSAND  GREENSAND 

A  sand  which  looks  like  ordinary  filter  sand  except  that  it  is  green  in  color.  This  sand  is  a  natural  ion  exchange  mineral  which  is 
capable  of  softening  water  and  removing  iron  and  manganese. 

GROUND  GROUND 

An  expression  representing  an  electrical  connection  to  earth  or  a  large  conductor  which  is  t  the  earth  s  potential  or  neutral 
voltage. 

HARD  WATER  HARD  WATER 

Water  having  a  high  concentntion  of  calcium  and  magnesium  ions  A  water  may  be  considered  hard  if  it  has  a  hardness  greater 
than  the  typical  hardness  of  water  from  the  region  Sone  textbooks  define  hard  water  as  water  with  a  hardness  of  more  than 
100  mg/L  as  calcium  carbonate. 

HARDNESS,  WATER  HARDNESS,  WATER 

A  characteristic  of  water  caused  mainly  by  the  salts  c*  calcium  and  magnesium,  such  as  bicarbonate,  carbonate,  sulfate,  chlo- 
ride and  nitrate  Excessive  hardness  in  water  is  undesirable  because  it  causes  the  formation  of  soap  curds,  increased  use  of 
soap,  deposition  of  scale  in  boilers,  damage  in  some  industrial  processes,  and  sometimes  causes  objectionable  tastes  in  drink- 
ing water. 

HEAD  HEAD 

The  vertical  distance  (in  feet)  equal  to  the  pressure  (in  psi)  u  a  specific  point.  The  pressure  head  is  equal  to  the  pressure  in  psi 
times  2.31  ft/psi. 

HEAD  LOSS  HEAD  LOSS 

The  head,  pressure  or  energy  (they  are  tne  same)  lost  by  water  flowing  in  a  p»pe  or  channel  as  a  result  of  turbulence  caused  by 
the  velocity  of  the  flowing  water  and  the  roughness  of  the  pipe,  channel  walls  or  restrictions  caused  by  fittings.  Water  flowing  in 
a  pipe  loses  head,  pressure  or  energy  as  a  result  of  friction  losses.  Also  see  FRICTION  LOSSES. 

HEADER  HEADER 
A  large  pipe  to  which  a  senes  of  smaller  pipes  are  connected.  Also  called  a  MANIFOLD. 

HEAT  SENSOR  HEAT  SENSOR 

A  device  that  opens  and  closes  a  switch  in  response  to  changes  in  the  temperature.  This  device  might  be  a  metal  contact,  or  a 
thermocouple  which  generates  a  minute  electrical  current  proportional  to  the  difference  in  heat,  or  a  variable  resistor  whose 
value  changes  in  response  to  changes  in  temperature.  Also  called  a  TEMPERATURE  SENSOR. 

HECTARE  (HECK-tar)  HECTARE 
A  measure  of  area  in  the  metric  system  similar  to  an  acre.  One  hectare  is  equal  to  10,000  square  meters  and  2.4711  acres. 
HEPATITIS  (HEP-up-TIE-tis)  HEPATITIS 
Hepatitis  is  an  inflammation  of  the  liver  usually  caused  by  an  acute  viral  infection.  Yellow  jaundice  is  one  symptom  of  hepatitis. 
HERBICIDE  (HERB-uh-SlDE)  HERBICIDE 
A  compound*  usually  a  man-made  organic  chemical,  used  to  kill  or  control  plant  growth. 

^  '  640 


622  Water  Treatment 


HERTZ  HERTZ 

The  number  of  complete  electromagnetic  cycles  or  waves  m  one  second  of  an  electrical  or  electronic  circuit  Also  called  the  fre- 
quency of  the  current  Abbreviated  Hz 

HIGH-LINE  JUMPERS  HIGH-LINE  JUMPERS 

Pipes  or  hoses  connected  to  fire  hydrants  and  laid  on  top  of  the  ground  to  provide  emergency  water  service  for  an  isolated  por- 
tion of  a  distrib-Jtion  system 

HOSE  BIB  HOSc  BIB 

Faucet.  A  location  in  a  water  line  where  a  hose  is  connected 

HTH  (pronounce  as  separate  letters)  HTH 
High  Test  Hypochlorite  Calcium  hypochlorite  or  Ca(0Cl)2 

HYDRATED  LIME  HYDRATED  LIME 

Limestone  that  has  been  burne:*  and  treated  with  water  under  contro'led  conditions  until  the  calcium  oxide  portion  has  been 
converted  to  calcium  hydroxide  (Ca(0H)2)  Hydrated  lime  is  quicklime  combined  with  water  CaO  -  HgO  ^  Ca(0H)2.  Also  called 
Slaked  lime.  Also  see  QUICKLIME 

HYDRAULIC  GRADE  LINE  (HGL)  HYDRAULIC  GRADE  LINE  (HGL) 

The  surface  or  pro.ila  or  water  flowing  in  an  open  channel  or  a  pipe  flowing  partially  fi  I!.  If  a  pipe  is  under  pressure,  the  hydrau- 
lic grade  line  is  at  the  level  water  would  rise  to  in  a  small  vertical  tube  connected  to  ine  pipe  Also  see  ENERGY  GRADE  LINE 

l^EE  DRAWING  ON  PAGE  618] 

HYDRAULIC  GRADIENT  HYDRAULIC  GRADIENT 

The  Slope  of  the  hydraulic  grade  line.  This  is  the  slope  of  the  water  surface  in  an  open  channel,  the  slope  of  the  water  surface  of 
the  groundwater  table,  or  the  slope  of  the  water  pressure  for  pipes  under  pressure. 

HYDROGEOLOGIST  (HI-dro-gee-ALL-u»  y!^X)  HYDROGEOLOGIST 
A  person  who  studies  and  works  with  groundwater. 

HYDROLOGIC  CYCLE  (HI-dro-LOJ-ick)  HYDROLOGIC  CYCLE 

The  process  of  evaporation  of  waier  into  the  air  and  its  return  to  Earth  by  precipitation  (rain  or  snow)  This  process  also  in- 
cludes transpiration  from  plants,  groundwater  movement,  and  runoff  into  rivers,  streams  and  the  ocean.  Also  called  the  WATER 
CYCLE 

HYDROLYSIS  (hi-DROLL-uh-sis)  HYDROLYSIS 
A  chemical  reaction  in  which  a  compound  is  converted  nUo  another  compound  by  taking  up  water 

HYDROPHILIC  (Hl-dro-FILL-ick)  HYDROPHILIC 
Having  a  strong  affmny  (liking)  for  water.  The  opposite  of  HYDROPHOBIC. 

HYDROPHOBIC  (HI-dro-FOE-bick)  HYDROPHOBIC 
Having  a  strong  aversion  (dislike)  for  water  The  opposite  of  HYDROPHILIC. 

HYDROPNEUMATIC  (HI-dro-new-MAT-ick)  HYDROPNEUMATIC 

A  water  system,  usually  small,  in  which  a  water  pump  is  automatically  controlled  (started  and  stopped)  by  the  air  pressur  ?  in  a 
compressed-air  tank. 

HYDROSTATIC  PRESSURE  (HI-dro-STAT-ick)  HYDROSTATIC  PRESSURE 

(1)  The  pressure  at  a  specific  elevation  exerted  by  a  body  of  water  at  rest,  or 

(2)  In  the  case  of  groundwater,  the  pressure  at  a  specific  elevation  due  to  the  weight  of  water  at  higher  levels  in  the  same  zone 
of  saturation. 

HYGROSCOPIC  (HI-grow-SKOP-ick)  HYGROSCOPIC 
Absorbing  or  attracting  moisture  from  the  air. 

HYPOCHLORINATION  (HI-poe-KLOR-uh-NAY-shunj  HYPOCHLORINATION 
The  application  of  hypochlorite  compounds  to  water  for  the  purpose  of  disinfection. 

HYPOCHLORINATORS  (HI-poe-KLOR-uh-NAY-tors)  HYPOCHLORINATORS 

Chlorine  pumps,  chemical  feed  pumps  or  devices  used  to  dispense  chlorine  solutions  made  from  hypochlorites  such  as  bleach 
podium  hypochlorite)  or  calcium  hypochlorite  into  the  water  being  treated. 

ERIC  ^ii 


r 


Words  623 

HYPOCHLORITE  (HI-poe-KL OR-ite)  HYPOCHLORITE 

Chemical  compounds  containing  available  chionne,  used  for  disinfection  They  are  available  as  liquids  (bleach)  or  solids 
(powder,  granules  and  pellets).  Salts  of  hypochlorous  acid. 

HYPOLIMNION  (HI-poe-LIM-knee-on)  HYPOLIMNION 

The  lowest  layer  in  a  thermally  stratified  lake  or  reservoir  This  layer  consists  of  colder,  more  dense  water,  has  a  constant  tem- 
perature and  no  mixing  occurs 

IMHOFF  CONE  ,MHOFF  CONE 

A  clear,  cone-shaped  container  marked  with  graduations.  The  cone  is  used  to  measure 
the  volume  of  settleable  solids  in  a  specific  volume  (usually  one  liter)  of  water. 

IMPELLER  IMPELLER 
A  rotating  set  of  vanes  in  a  pump  designed  to  pump  or  lift  water 

IMPERMEABLE  (im-PURR-me-uh-BULL)  IMPERMEABLE 

Not  easily  penetrated  The  property  of  a  material  or  soil  that  does  not  allow,  or  allows  only  with  great  difficulty,  the  movement  or 
passage  of  water. 

INDICATOR  (CHEMICAL)  INDICATOR  (CHEMICAL) 

A  substance  that  gives  a  visible  change,  usually  of  color,  at  a  desired  point  in  a  chemical  reaction,  generally  at  a  specified  end 
point. 

INDICATOR  (INSTRUMENT)  INDICATOR  (INSTRUMENT) 

A  device  which  indicates  the  result  of  a  measurement  Most  indicators  in  the  water  utility  field  use  either  a  fixed  scale  and  mov- 
able indicator  (pointer)  such  as  a  pressure  gage  or  a  movable  scale  and  movable  indicator  like  those  used  on  a  circular-flow  re- 
cording chart.  Also  called  a  RECEIVER 

INFILTRATION  (IN-fill-TRAY-shun)  INFILTRATION 

The  gradual  flow  or  movement  of  water  into  and  through  (to  percolate  or  pass  through)  the  pores  of  the  soil.  Also  called  PER- 
COLATION. 

INFLUENT  (IN-flu-ent)  INFLUENT 
Water  or  other  liquid  —  raw  or  partially  treated  —  flowing  /A/TO  a  reservoir,  basin,  treatment  process  or  treatment  plant. 

INITIAL  SAMPLING  INITIAL  SAMPLING 

The  very  first  sampling  conducted  under  the  Safe  Drinking  Water  Act  for  each  of  the  applicable  contaminant  categories. 

IN-LINE  FILTRATION  IN.LIne  FILTRATION 

The  addition  of  chemical  coagulants  directly  to  the  filter  inlet  pipe  The  chemicals  are  mixed  by  the  flowing  water.  Flocculation 
and  sedimentation  facilities  are  eliminated  This  pretreatment  method  is  commonly  used  in  pressure  filter  installation.  Also  see 
CONVENTIONAL  FILTRATION  and  DIRECT  FILTRATION. 

INORGANIC  INORGANIC 

Material  such  as  sand,  salt,  iron,  calcium  salts  and  other  mineral  materials  Inorganic  substances  are  of  mineral  origin,  whereas 
organic  substances  are  usually  of  animal  or  plant  origin.  Also  see  ORGANIC. 

INPUT  HORSEPOWER  INPUT  HORSEPOWER 

The  total  power  used  in  operating  a  pump  and  motor. 
Input  Horsepower,  HP  ^  (Brake  Horsepower.HP)(1QQ%) 

Motor  Efficiency,  % 

INSECTICIDE  INSECTICIDE 
Ally  substanrp  c.  chemical  formulated  to  kill  or  control  insects 

INSOLUBLE  (in-SAWL-you-bull)  INSOLUBLE 
Something  that  cannot  be  dissolved 

INTEGRATOR  INTEGRATOR 

A  devicf  or  meter  that  continuously  measures  and  calculates  (adds)  total  flows  m  gallons,  million  gallons,  cubic  feet,  or  some 
other  \jX\\\  of  volume  measurement.  Also  called  a  TOTALIZER. 

erJc  :^  642 


624  Water  Treatment 


INTERFACE  INTERFACE 

The  common  boundary  layer  between  two  substances  such  as  water  and  a  solid  (metal),  or  between  two  fluids  such  as  water 
and  a  Qc  -  (air);  or  between  a  liquid  (water)  and  another  liquid  (oil). 

INTERLOCK  INTERLOCK 

An  electrical  switch,  usually  magnetically  operated  Used  to  interrupt  all  (local)  power  to  a  par.?l  or  device  when  the  door  is 
opened  or  the  circuit  exposed  to  service. 

INTERNAL  FRICTION  INTERNAL  FRICTION 

Friction  within  a  fluid  (water)  due  to  cohesive  forces 

INTERSTICE  (in-TUR-stiihz)  INTERSTICE 
A  very  small  open  space  in  a  rock  or  granular  material.  Also  called  a  void  or  void  space.  Also  see  PORE 

INVERT  (IN-vert)  INVERT 
The  lowest  point  of  the  channel  inside  a  pipe,  conduit,  or  canal 

ION  ION 
An  electrically  charged  atom,  radica!  (such  as  SO/  ).  or  molecule  formed  by  the  loss  or  gam  of  one  or  more  electrons. 

ION  EXCHANGE  ION  EXCHANGE 

A  water  treatment  process  involving  the  reversible  interchange  (switching)  of  ions  between  the  water  being  treated  and  the  sol- 
id resin  Undesirable  ions  in  the  water  are  switched  with  acceptable  ions  on  the  resin. 

ION  EXCHANGE  RESINS  ION  EXCHANGE  RESINS 

Insoluble  polymers,  used  in  water  treatment,  that  are  capable  of  exchanging  (switching  or  giving)  acceptable  cations  or  anions 
to  the  water  being  treated  for  less  desirable  ions. 

IONIC  CONCENTRATION  IONIC  CONCENTRATION 

The  concentration  of  any  ion  in  solution,  usually  expressed  in  moles  per  liter. 

IONIZATION  (EYE-on-uh-ZAY-shun)  IONIZATION 
The  splitting  or  dissociation  (separation)  of  molecules  into  negatively  and  positively  charged  ions 

JAR  TEST  JAR  TEST 

A  laboratory  procedure  that  simulates  a  water  treatment  plant's  coagulation/flocculation  units  with  differing  chemical  doses 
and  also  energy  of  rapid  mix,  energy  of  slow  mix,  and  settling  time.  The  purpose  of  this  procedure  is  to  ESTIMA  TE  the  minimum 
or  ideal  coagulant  dose  required  to  acnieve  certain  water  quality  goals.  Samples  of  water  to  be  treated  are  commonly  placed  m 
SIX  jars.  Various  amounts  of  chemicals  are  added  to  each  jar»  stirred  and  the  settling  of  solids  is  observed.  The  dose  of  chemi- 
cals that  provides  satisfactory  settling  removal  of  turbidity  and/or  color  is  the  dose  used  to  treat  the  water  being  taken  into  the 
plant  at  that  time  When  evaluating  the  results  of  ajar  test,  the  operator  should  also  consider  the  floe  quality  m  the  flocculation 
area  and  the  floe  loading  on  the  filter. 

JOGGING  JOGGING 
The  frequent  starting  and  stopping  of  an  electric  motor. 

JOULE  (jewel)  JOULE 

A  measure  of  energy,  work  or  quantity  of  heat.  One  joule  is  the  work  done  when  the  point  of  application  of  a  force  of  one  new- 
ton  IS  dispiJ^ced  a  distance  of  one  meter  in  the  direction  of  force 

KELLY  KELLY 

The  square  section  of  a  rod  which  causes  the  rotation  of  the  drill  bit.  Torque  from  a  drive  table  is  applied  to  tne  square  rod  to 
cause  the  rotary  motion.  The  drive  table  is  chain  or  gear  driven  by  an  engine. 

KILO  KILO 

(1)  Kilogram, 

(2)  Kilometer. 

(3)  A  prefix  meaning  "thousand"  used  m  the  metric  system  and  othe**  scientific  systems  of  measurement 

KINETIC  ENERGY  KINETIC  ENERGY 

Energy  possessed  by  a  moving  body  of  matter,  such  as  water,  as  a  result  of  its  motion. 

KJELDAHL  NITROGEN  (KELL-doll)  KJELDAHL  NITROGEN 

Mitr^noq  m  the  form  of  organic  proteins  or  their  decomposition  product  ammonia,  as  measured  by  the  Kjeldahl  Method. 

ERIC 

643 


Words  625 


LANGELIER  INDEX  (LI.)  LANGELIER  INDEX  (LI.) 

An  index  reflecting  the  equilibrium  pH  of  a  water  with  respect  to  calcium  and  alk-:  .itv  This  index  is  used  in  stabilizing  water  to 
control  both  corrosion  and  the  deposition  of  scale 

Langelier  Index  =  pH  -  pH^ 

where  pH  =  actual  pH  of  the  water,  and 

pHj.  =  pH  at  which  v^ater  having  the  same  alkalinity  and  calcium  content  is  just  saturated  with  calcium  carbonate. 

LAUNDERING  WEIR  (LAWN-der-ing  weer)  LAUNDERING  WEIR 

Sec'imentation  basin  overflow  weir  A  plate  with  V-notches  along  ;he  top  to  assure  a  uniform  flow  rate  and  avoid  short-circuit- 
ing. 

LAUNDERS  (LAWN-ders)  LAUNDERS 

Sedimentation  basin  and  filter  discharge  channef  consisting  of  overflow  weir  plates  (in  sedimentation  basins)  and  conveyinq 
t.oughs. 

LEAD  (LE£.d)  LEAD 
A  wire  or  conductor  that  can  carry  electricity. 

LEATHERS  LEATHERS 
O  rings  or  gaskets  used  with  piston  pumps  to  provide  a  seal  between  the  piston  and  the  side  wall. 

LEVEL  CONTROL  LEVEL  CONTROL 

A  float  device  (or  pressure  switch)  which  senses  changes  in  a  measured  variable  and  opens  or  closes  a  switch  in  response  tc 
that  change  in  its  cimpLst  form,  this  control  might  be  a  floating  ball  connected  mechanica.ly  to  a  switch  or  valve  such  as  is 
used  to  stop  water  flow  into  a  toilet  when  the  tank  is  full. 

Lindane  (LYNN-dane}  LINDANE 

A  pesticide  that  causes  adverse  health  effects  in  domestic  watet  supplies  and  also  is  toxic  to  freshwater  and  marine  aquatic 
life 

LINEARITY  (LYNN-ee-AIR-it-ee)  I  NjEARITY 

How  closely  an  instrument  measures  actual  values  of  a  variable  through  its  effective  range,  a  measure  ust  J  to  determine  the 
acct,  icy  of  an  instrument. 

LITTORAL  ZONE  (LIT-or-al)  LITTORAL  ZONE 

(1)  That  portion  of  a  body  of  fresh  water  extending  from  the  shoreline  lakeward  to  the  limit  of  occupancy  of  rooted  plants. 

(2)  The  stnp  of  land  along  the  shoreline  between  the  high  and  low  water  levels. 

'  OGARITHM  (LOG-a-rith-m)  LOGARITHM 

The  exponent  that  indicates  the  power  to  which  a  number  must  be  raised  to  produce  a  given  number.  For  example,  if  =  N 
the  2  IS  ihe  logarithm  of  N  (to  the  base  B),  or  10^  =  100  and  log^^  100  =  2.  Also  abbreviated  to  "log." 

LOGGING,  ELECTRICAL  LOGGING,  ELECTRICAL 

A  procedure  used  to  detfennine  the  porosity  (spaces  or  voids)  of  formations  in  search  of  water-beanng  formations  (aquifers). 
Electrical  probes  are  lowered  into  wells,  an  electncal  current  is  induced  at  various  depths  a'^d  the  resistance  measured  of  var- 
ious formations  indicates  the  porosity  of  the  material. 

M  or  MOLAR  M  or  MOLAR 

A  molar  ?oiution  consists  of  one  gram  molecular  weight  of  a  compound  dissolved  in  enough  water  to  make  one  liter  of  solution. 
A  gram  molecular  weight 's  the  molecular  weight  of  a  compound  in  grams.  For  example,  the  molecular  weight  of  sulfunc  acid 
(HgoO^)  IS  98  A  one  M  solution  of  sulfuric  acid  woulc*  consist  of  98  grams  of  H.SO.  dissolved  in  enough  distilled 
water  to  make  one  Ijter  of  solution. 

MACROSCOPIC  (MACK-row-SKAWP-ick)  ORGANISMS  MACROSCOPIC  ORGANISMS 

Organisms  big  enough  to  be  seen  by  the  eye  without  the  aid  of  a  microscope. 

MANDREL  (MAN-drill)  MANDREL 
A  special  tool  used  to  push  be«-ings  in  or  to  pull  sleeves  out. 

MANIFOLD  MANIFOLD 
Marge  pipe  to  which  a  se  .3  of  smaller  pipes  are  connected.  Also  called  a  h.cADER. 

ERLC  ^  64i 


626  Water  Treatment 


MANOMETER  (man-NAH-mut-ter)  MANOMETER 

An  instrument  for  measuring  pressure  Usually,  a  manometer  is  a  glass  tube  filled  with  a  liquid  that  is  used  to  measure  the  dif- 
ference in  pressure  across  a  .  ow-measuring  device  such  as  an  orifice  or  Venturi  meter.  The  instrument  used  to  measure  blooo 
pressure  is  a  type  of  manometer. 


VENTURI  METER 


MAXIMUM  CONTAMINANT  LEVEL  (MCL) 
See  MCL 


MAXIMUM  CONTAMINANT  LEVEL  (MCL) 


MBAS 

Methylene  -  Blue  -  Active  Substances.  These  substances  are  used  in  surfactants  or  detergents. 
MCL 


MBAS 


MCL 


Maximum  Contaminant  Level  The  largest  allowable  amount.  MCLs  for  various  water  quality  indicators  are  specified  in  the  Na- 
tional Intenm  Primary  Drinking  Water  Regulations  (NIPDWR) 


MEASl 'RED  VARIABLE 


MEASURED  VARIABLE 


A  cha''acteristic  or  component  part  that  is  sensed  and  quantified  (reduced  to  a  reading  of  some  kind)  by  a  primary  element  or 
sensor. 


MECHANICAL  JOINT 

A  flexible  device  that  joins  pipes  or  fittings  together  by  the  use  of  lugs  and  bolts. 
MEG 


MECHANICAL  JOINT 


MEG 


A  procedure  ♦jsed  for  checking  the  ins^^ation  resistance  on  motors,  feeders,  buss  bar  systems,  grounds,  and  branch  circuit  wir- 
ing. Also  see  MEGGER. 


MEGGER  (from  megohm) 


MEGGER 


An  instrument  used  for  checking  the  insulation  resistance  on  motors,  feeders,  buss  bar  systems,  grounds,  and  branch  circuit 
wiring.  Also  see  MEG. 

MEGOHM  MEGOHM 
Meg  means  one  million,  so  5  megohms  means  5  million  ohms.  A  megger  reads  in  millions  of  ohms. 

MENISCUS  (meh-NiS-cuss)  MENISCUS 

The  curved  top  of  a  column  of  liquid  (water,  oil,  mercury)  in  a  bmall  tube.  When  the  liquid  wets  the  sides  of  the  container  (as  with 
water),  the  curve  forms  a  valley.  When  the  confining  sides  are  not  wetted  (as  with  mercury),  the  curve  forms  a  hill  or  upward 
bulge. 


WATER 


MERCURY 


(READ 
BOTTOM) 


(READ 
TOP) 


MESH 


MESH 


One  of  the  openings  or  spaces  in  a  screen  or  woven  fabric  The  value  of  the  mesh  is  usually  given  as  the  number  of  openings 
per  inch  This  value  does  not  consider  the  diameter  of  the  wire  or  fabnc,  therefore,  the  mesh  number  does  not  always  have  a 
definite  relationship  to  the  size  of  the  hole. 


ERIC 


64; 


Words  627 


MESOTROPHIC  (MESS-o-TRO-fick)  MESOTROPHIC 

Reservoirs  and  lakes  which  contain  moderate  quantities  of  nutrients  and  are  moderately  productive  in  terms  of  aquatic  animal 
and  plant  life. 

METABOLISM  (meh-TAB-uh-LIZ-um)  METABOLISM 

(1)  'lie  biochemical  procesres  in  which  food  is  used  and  wastes  are  formed  by  living  organisms. 

(2)  All  biochemical  reactions  involved  in  cell  formation  and  growth. 

METALIMNION  (MET  uh-LIM-knee-on)  METALIMNION 

The  middle  layer  in  a  thermally  stratified  lake  or  reservoir  In  this  layer  there  is  a  rapid  decrease  in  temperature  with  depth.  Also 
called  the  THERMOCLINE. 

METHOXYCHLOR  (meth-OXY-klor)  METHOXYCHLOR 

A  pesticide  which  causes  adverse  health  effects  in  domestic  water  supplies  and  is  also  toxio  to  freshwate»  and  marine  aquatic 
life.  The  chemical  name  for  methoxychlor  ib  2,2-bis  (p-methoxyphenol)-1,1,1-trich!oroethane. 

METHYL  ORANGE  ALKALINITY  METHYL  ORANGE  ALKALINITY 

A  measure  of  the  total  alkalinitv  in  a  water  sample  The  alkalinity  is  measured  by  the  amount  of  standard  sulfuric  acid  required 
to  lower  the  pH  of  the  water  to  pH  level  of  4.5,  as  indicated  by  the  change  in  color  of  methyl  orange  from  orange  to  pink. 
Methyl  orange  alkalinity  is  expressed  as  milligrams  per  liter  equivalent  calcium  carbonate. 

mg/L  mg/L 
See  MILLIGRAMS  PER  LITER. 

MICROBIAL  GROWTH  (my-KROW-bee-ul)  MICROBIAL  GROWTH 

The  activity  and  growth  of  microorganisms  such  as  bacteria,  algae,  diatoms,  plankton  and  fungi 

MICRON  (MY-kron)  MICRON 
A  unit  of  length.  One  millionth  of  a  meter  or  one  thousandth  of  a  millimeter.  One  micron  equals  0.00004  of  an  inch. 

MICROORCmNISMS  (MY-crow-OR-gan-IS-zums)  MICROORGANISMS 
Living  organisms  that  can  be  seen  individually  only  with  the  aid  of  a  microscope. 

MIL  MIL 

A  unit  of  length  equal  to  0.001  of  an  inch.  The  diameter  of  w;res  and  tubing  is  measured  in  mils,  as  is  the  thickness  of  plastic 
sheeting. 

MILLIGRAMS  PER  LITER,  mg/L  MILLIGRAMS  PER  LITER,  mg/L 

A  measure  of  the  concentration  by  weight  of  a  substance  per  unit  volume.  For  practical  purposes,  one  mg/L  of  a  substance  in 
fresh  water  is  equal  to  one  part  per  million  parts  (ppm).  Thus  a  liter  of  water  with  a  specific  gravity  of  1.0  weighs  one  million 
milligrams.  If  it  contains  1 0  milligrams  of  calcium,  the  o  ncentration  is  1 0  milligrams  per  million  milligrams,  or  1 0  milligrams  per 
liter  (10  mg/L).  or  10  parts  of  calcium  per  million  parts  of  water,  or  10  parts  per  million  (10  ppm). 

MILLIMICRON  (MILL-uh-MY-kron)  MILLIMICRON 
A  un..  of  length  equal  to  1 0  V  (one  thousandth  of  a  micron),  1 0  ®  millimeters,  or  1 0  ^  meters,  correctly  called  a  nanometer,  nm. 

MOLAR  MOLAR 
See  M  for  MOLAR. 

MOLE  MOLE 
The  molecular  weight  of  a  substv;nce,  usually  expressed  in  grams. 

MOLECULAR  WEIGHT  MOLECULAR  WEIGHT 

The  molecular  weight  of  a  compound  m  grams  is  the  sum  of  the  atomic  weights  of  the  elements  m  the  compound.  The  molecu- 
lar weight  of  sulfuric  acid  (HgSO^)  in  grams  is  98. 

Element  Atomic  Weight  Numb3r  of  Atom's  Molecular  Weight 
H                                      1                                     2  2 
S                                   32                                    1  32 
0                                    16                                     4  64 

98 

MOLECULE  (MOLL-uh-KULE)  MOLECULE 
The  smallest  division  of  a  compound  that  still  retains  or  exhibits  all  t.'>e  properties  of  the  substance. 

Er|c  :-' 


646 


628  Water  Treatment 


MONOMER  (MON-o-MER)  MONOMER 
A  molecule  of  low  molecular  weight  capable  of  reacting  with  identical  or  different  monomers  to  form  polymers. 

MONOMICTIC  (mo-no-MICK-tick)  MONOMICTIC 

Lakes  and  reservoirs  which  are  relatively  deep,  do  nut  f-^eeze  over  during  the  winter  months,  and  undergo  a  single  stratification 
and  mixing  cycle  dunng  the  year  These  laKes  and  reservoirs  usually  become  destratified  during  the  mixing  cycle,  usually  in  the 
fall  of  the  year. 

MONOVALENT  MONOVALENT 
Having  a  valence  of  one,  such  as  the  cuprous  (copper)  ion,  Cu\ 

MOST  PROBABLE  NUMBER  (MPN)  MOST  PROBABLE  NUMBER  (MPN) 

See  MPN. 

MOTILE  (MO-till)  MOTILE 

Capable  of  self-propelled  movement  A  term  that  is  sometimes  used  to  distinguish  between  certain  types  of  organisms  found  in 
water 

MOTOR  EFFICIENCY  MOTOR  EFFICIENCY 

The  ratio  of  energy  delivered  by  a  motor  to  the  energy  supplied  to  it  during  a  fixed  period  or  cycle.  Motor  efficiency  ratings  will 
vary  depending  upon  motor  manufacturer  and  usually  will  range  from  ^8.9  to  90.0  percent 

MPN  (pronounce  as  separate  letters)  MPN 

MPN  IS  the  Most  Probable  Number  of  coliform-group  organisms  per  unit  volume  of  sample  water.  Expressed  as  the  number  of 
organisms  per  100  mL  of  sample  water. 

MUDBALLS  MUDBALLS 

Matenal  that  is  approximately  round  m  shape  and  varies  from  pea-sized  up  to  two  or  more  inches  in  diameter.  This  material 
forms  in  filters  and  gradually  increases  in  size  when  not  removed  by  the  backwashing  process. 

MULTISTAGE  PUMP  MULTI-STAGE  PUMP 

A  pump  that  has  more  than  one  impeller.  A  single-stage  pump  h-as  one  impeller 

N  or  NORMAL  N  or  NORMAL 

A  normal  solution  contains  one  gram  eq>  valent  weight  of  reactant  (compound)  per  liter  of  solution.  The  equivalent  weight  of  an 
acid  IS  that  weight  which  contains  one  gram  atom  of  lonizable  hydrogen  or  its  chemical  equivalent.  For  example,  the  equivalent 
weight  of  sulfuric  acid  (H^SO^)  is  49  (98  divided  by  2  because  there  are  two  replaceable  hydrogen  ions).  A  one  N  solution  of 
sulfuric  acid  would  consist  of  49  grams  of  H^SO^  dissolved  in  enough  water  to  make  one  liter  of  solution. 

NATIONAL  ENVIRONMENTAL  NATIONAL  ENVIRONMENTAL 

TRAINING  ASSOCIATION  TRAINING  ASSOCIATION 
A  professional  organizaiton  devoted  to  serving  the  environmental  trainer  and  promoting  better  operation  of  waterworks  and 
pollution  control  facilities  For  information  on  NETA  membership  and  publications,  contact  NETA,  P.O.  Box  346,  Valparaiso  In- 
diana 46383. 

NATION,  L  INSTITUTE  OF  N.  .TIONAL  INSTITUTE  OF 

OCCUPAflONAL  SAFETY  AND  HEALTH  OCCUPATIONAL  SAFETY  AND  HEALTH 
See  NIOSH. 

NATIONAL  INTERIM  PRIMARY  NATIONAL  INTERIM  PRIMARY 

DRINKING  WATER  REGULATIONS  DRINKING  WATER  REGULATIONS 
Commonly  referred  to  as  NIPDWR. 

NATIONAL  SAFE  DRINKING  WATER  REGULATIONS  NATIONAL  SAFE  DRINKING  WATER  REGULATIG.4S 
Commonly  referred  to  as  NSDWR. 

NEPHELOMETRIC  (NEFF-el-o-MET-rick)  NEPHELOMETRIC 

A  means  of  measuring  turbidity  in  a  sample  by  using  an  instrument  called  a  nephelometer.  A  nephelometer  passes  light  through 
a  sample  and  the  amount  of  light  deflected  (usually  at  a  90-degree  angle)  is  then  measured. 

NETA  NETA 
See  National  Environmental  Training  Association. 

ERIC  G47 


Words  629 


NEWTON  NEWTON 

A  force  which,  when  applied  to  a  body  having  a  mass  of  one  kilogram,  gives  it  an  acceleration  of  one  meter  per  second  per 
second. 

NIOSH  NIOSH 

The  National  Institute  of  Occupational  Safety  and  Health  is  an  organization  that  tests  and  approves  safety  equipment  for  par- 
ticular applications  NIOSH  is  the  primary  Federal  agency  engaged  in  research  in  the  national  effort  to  eliminate  on-the-job  haz- 
ards to  tne  health  and  safety  of  working  people.  The  NIOSH  Publications  Catalog  contains  a  listing  of  NIOSH  publications  main- 
ly on  industrial  hygiene  and  occupational  health  To  obtain  a  copy  of  the  catalog,  write  to  NIOSH  Publications,  4676  Columbia 
Parkway,  Cincinnati,  Ohio  45226. 

NIPDWR  NIPDWR 
National  Interim  Primary  Drinking  Water  Regulations. 

NITROGENOUS  (nye-TRAH-jen-us)  NITROGENOUS 

h  term  used  to  describe  chemical  compounds  (usually  organic)  containing  nitrogen  in  combined  forms.  Proteins  and  n.trates 
are  nitrogenous  compounds. 

NOBLE  METAL  NOBLE  METAL 

A  chemically  inactive  metal  (such  as  gold)  A  metal  that  does  not  corrode  easily  and  is  much  scarcer  (and  more  valuable)  than 
the  so-called  useful  or  base  metals.  Aiso  see  BASE  METAL. 

NOMINAL  DIAMETER  NOMINAL  DIAMETER 

An  approximate  measurement  of  the  diameter  of  a  pipe.  Although  the  nominal  diameter  is  used  to  describe  the  size  or  diameter 
of  a  pipe.  It  is  usually  not  the  exact  Inside  diameter  of  the  pipe. 

NONIONIC  POLYMER  (NON-eye-ON-ick)  NONIONIC  POLYMER 

A  polymer  tiiat  has  no  net  electrical  charge. 

NONPOINT  SOURCE  NONPOINT  SOURCE 

A  runoff  or  discharge  from  a  field  or  '  milar  source  A  point  source  refers  to  a  discharge  that  comes  out  the  end  of  a  pipe. 

NONPOTABLE  (non-POE-tuh-bull)  NONPOTABLE 

Water  that  may  contain  objectionable  pollution,  contamination,  minerals,  or  infective  agents  and  is  considered  unsafe  and/or 
unpalatable  for  drinking. 

NORMAL  NORMAL 
See  N  for  NORMAL. 

NPDES  PERMIT  NPDES  PERMIT 

National  Pollutant  Discharge  Elimination  System  permit  is  the  regulatory  agency  document  designed  to  control  all  discharges  of 
pollutants  from  point  sources  in  U.S.  waterways.  NPDES  permits  regulate  discharges  into  navigable  waters  from  all  point 
sources  of  pollution,  including  industries,  municipal  treatment  plants,  large  agricultural  feed  lots  and  return  irrigation  flows. 

NSDWR  NSDWR 
National  Safe  Dnnking  Water  Regulations 

NUTRIENT  NUTRIENT 

Any  substance  that  is  2ssir,ilated  (taken  m)  by  organisms  and  promotes  growth.  Nitrogen  and  phosphorous  are  nutrients  which 
promote  the  growth  of  Jgae.  There  are  other  essential  and  trace  elements  which  are  also  considered  nutrients. 

OCCUPATIONAL  SAFETY  AND  HEALTH  ACT  OF  1970  OCCUPATIONAL  SAFETY  AND  HEALTH  ACT  OF  1970 

See  OSHA. 

ODOR  THRESHOLD  ODOR  THRESHOLD 

The  minimum  odor  of  a  water  sample  that  can  just  be  detected  after  successive  dilutions  with  odorless  water.  Also  called 
THRESHOLD  ODOR. 

OFFSET  (or  DROOP)  OFFSET 

The  difference  between  the  actual  value  and  the  desired  value  (or  set  point),  characteristic  of  proportional  contro^ers  that  do 
not  incorporate  reset  action. 

OHM  OHM 
The  unit  of  electrical  resistance.  The  resistance  of  a  conductor  m  which  one  volt  produces  a  current  of  one  ampere. 


C  ..10  643 


630  Water  Treatment 


OLFACTORY  FATIGUE  (oh-FAK-tore-ee)  OLFACTORY  FATIGUE 

A  condition  m  which  a  person  s  nose,  after  exposure  to  certain  odors,  is  no  longer  able  to  detect  the  odor. 

OLIGOTROPHlC(AH-lig.o-TRO-fick)  OLIGOTROPH!C 
Reservoirs  and  lakes  which  are  nutrient  poor  and  contain  little  aquatic  plant  or  animal  life. 

ORGANIC  ORGANIC 

Substances  that  come  from  anima!  or  plant  sources  Organic  substances  always  contain  carbon  (Inorganic  matendls  are 
chemical  substances  of  mineral  origin  )  Also  see  INORGANIC. 

ORGANICS  ORGANICS 

(1)  A  term  jsed  to  refer  to  chemical  compounds  made  from  caibon  molecules  These  compounds  may  be  natural  materials 
(such  as  animal  or  plant  sources)  or  man-made  materials  (such  as  synthetic  organics).  Also  see  ORGANIC. 

(2)  Any  form  of  animal  of  plant  i.i'e  Also  see  BACTERIA. 

ORGANISM  ORGANISM 
Any  form  of  animal  or  plant  life.  Also  see  BACTERIA. 

ORIFICE  (OR-uh-fiss)  ORIFICE 

Ar,  opening  (hole)  m  a  plate,  wall  or  partition  An  orifice  flange  or  plate  placed  in  a  pipe  consists  of  a  slot  or  a  calibrated  circular 
hole  smaller  than  the  pipe  diameter  The  difference  m  pressure  in  the  pipe  above  and  at  the  onfice  may  be  used  to  determine 
the  flow  m  the  pipe. 

ORP  ORP 
Oxidation-Reduction  Potential  The  electrical  potential  required  to  transfer  electrons  from  one  compound  or  element  (the 
oxidant)  to  another  compound  or  element  (the  reductant).  used  as  a  qualitative  measure  of  the  state  of  oxidation  m  water  treat- 
ment systems. 

ORTHOTOLIDINE  (or-tho-TOL-uh-dine)  ORTHOTOLIDINE 

Orthotolidine  is  a  colorimetric  indicator  of  chlorine  residual  If  chlorine  is  present,  a  yellow-colored  compound  is  produced.  This 
reagent  is  no  longer  approved  for  chemical  analysis 

OSHA  (0-shuh)  OSHA 

The  Wilhams-Steiger  Occupational  Safety  and  Health  Act  of  1970  (OSHA)  is  a  taw  designed  to  protect  the  health  and  safety  of 
industrial  workers  and  also  the  operators  of  water  supply  system?  and  treatment  plants. 

OSMOSIS  (oz-MOE-sis)  OSMOSIS 

The  passage  of  a  liquid  from  a  weak  solution  to  a  more  concentrated  solution  across  a  semipermeable  membrane.  The  mem- 
brane allows  the  passage  o^  the  water  (solvent)  but  not  the  dissolved  solids  (solutes)  This  process  tends  to  equalize  the  condi- 
tions on  either  side  of  the  mernbra'^e. 

OVERALL  EFFICIENCY,  PUMP  OVERALL  EFFICL-NCY.  PUMP 

The  combined  efficiency  of  a  pump  and  motor  together  Also  called  the  WIRE-TO-WATER  EFFICIENCY. 

OVERDRAFT  OVERDRAFT 

The  pumping  of  water  from  a  groundwater  basin  or  aquifer  in  excess  of  the  supply  flowing  into  the  basin.  This  pumping  ''esults 
in  a  deoletion  or  "mining*  of  the  groundwater  in  the  basin. 

OVERFLOW  RATE  OVERFLOW  RATE 

One  of  the  guidelines  for  the  design  of  settl.ng  tanks  and  clanfiers  m  treatment  plants  Used  by  operators  to  determine  if  tanks 
and  clanfiers  are  hydraulically  (flow)  over-  or  underloaded.  Also  called  SURFACE  LOADING. 

Overflow  Rate.  GDP/sq  ft    =   ^'ow.  gallons/day 

Surface  Area,  sq  ft 

OVERTURN  OVERTURN 
The  almost  spontaneous  mixing  of  all  layers  of  water  m  a  reservo.r  or  lake  when  the  water  temperature  becomes  similar  from 
top  to  bottom  This  may  occur  m  the  fall/winter  when  the  surface  waters  cuol  to  the  same  temperature  as  the  bottom  waters  and 
also  in  the  spring  when  the  surface  waters  warm  after  the  ice  melts. 

OXIDATION  (ox-uh-DAY-shun)  OXIDATION 

Oxidation  Is  the  addition  of  oxygen,  removal  ot  hydrogen,  or  the  removal  of  electrons  from  an  element  or  compound  in  the  envi- 
ronment, organic  matter  is  oxidized  to  more  stable  substances.  The  opposite  o.*  REDUCTION. 

O 


^  643 


Words  631 


OXIDATION-REDUCTION  POTENTIAL  OXIDATION-REDUCTION  POTENTIAL 

The  electrical  potentia.  required  to  transfer  electrons  from  one  compound  or  element  (the  oxidant)  to  another  compound  or  ele- 
ment (the  reductant),  used  as  a  qualitative  measure  of  the  state  of  oxidation  in  water  treatment  systems. 

OXIDIZING  AGENT  OXIDIZING  AGENT 

Any  substance,  such  as  oxygen  (O2)  or  chlorine  (CU.  that  will  readily  add  (take  on)  elejtrons  The  opposite  is  a  REDL  ::iNG 
AGENT 

OXYGEN  DEFICIENCY  OXYGEN  DEFICIENCY 

An  atmosphere  containing  oxygen  at  a  concentration  of  less  than  19.5  percent  by  volume. 

OZONATION  (0-zoe-NAY-shun)  OZONATION 
The  application  of  ozone  to  water  for  disinfection  or  for  taste  and  odor  control 

PACKER  ASSEMBLY  PACKER  ASSEMBLY 

An  inflatable  device  used  to  seal  the  tremie  pipe  mside  the  well  casing  to  prevent  the  grout  from  entering  the  inside  of  the  con- 
ductor casing. 

PALATABLE  (PAL-a-ta-ble)  PALATABLE 
Water  at  a  desirable  temperature  that  is  free  from  objectionable  tastes,  odors,  colors,  and  turbidity  Pleasing  to  the  senses. 

PARSHALL  FLUME  PARSHALL  FLUME 

A  device  used  to  measure  the  flo  v  m  an  open  channel.  The  flume  narrows  to  a  throat  of  fixed  dimensions  and  then  expands 
again  The  rate  of  flow  can  be  calculated  by  measuring  the  difference  in  head  (pressure)  before  and  at  the  throat  of  the  flume. 


;hroat 

PLAN 


WATER  SURFACE 
FLOW 


ELEVATION 

PARTICLE  COUNT  PARTICLE  COUNT 

The  results  of  a  microscopic  examination  of  treated  water  with  a  special  particle  counter  which  classifies  suspended  particles 
by  number  and  size 

PARTICULATE  (oar-TICK-you-let)  PARTICULATE 

A  very  small  solid  suspended  in  water  which  can  vary  widely  in  size,  shape,  density,  and  electrical  charge.  Colloidal  and  dis- 
persed particulates  are  artificially  gathered  together  by  the  processes  of  coagulation  and  flocculation. 

PARTS  PER  MILLION  (PPM)  PARTS  PER  MILLION  (PPM) 

Pans  per  million  parts,  a  measurement .  f  concentration  on  a  weight  or  volume  basis  This  term  is  equivalent  to  milligrams  per 
liter  (mg/L)  which  is  the  preferred  term 

PASCAL  PASCAL 
The  pressure  or  stress  of  one  newton  per  square  meter.  (Abbreviated  Pa) 
1  psi  --  6895  Pa  -  6.895  kN/sq  m  -  0  0703  kg/sq  cm 

PATHOGENIC  ORGANISMS  (path-o-JEN-ick)  PATHOGENIC  ORGANISMS 

Orgr.i-^isms,  including  bacteria,  virust.,  ^r  cysts,  capable  of  causing  diseases  (typhoid,  cholera,  dysentery)  in  a  host  (S'jch  as  a 
person)  There  are  many  types  of  organisms  which  do  NOT  cause  disease.  These  organismb  arc  called  non-pathogenic. 

PATHOGENS  (PATH-o-jens)  PATHOGENS 
Pathogenic  or  disease-causing  organ«srns 

ErJc  650 


632  Water  Treatment 


PCBs  PCBs 
See  POLYCHLORINATED  BIPHENYLS. 

PC»/^  pCi/L 

PicoCune  per  Liter  A  picoCurie  is  a  measure  of  radioactivity.  One  picoCune  of  radioactivity  is  equivalent  to  0.037  nuclear  disin- 
tegrations per  second. 

PEAK  DEMAND  PEAK  DEMAND 

The  maximum  momentary  load  placed  on  a  water  treatment  plant,  pumping  station  or  distribution  system,  fhis  demand  is  usu- 
ally the  maximum  average  load  in  one  hour  or  less,  but  may  be  specified  as  the  instantaneous  or  with  some  other  short  time 
periorl. 

PERCENT  SATURATION  PERCENT  SATURATION 

The  amount  of  a  substance  that  is  dissolved  in  a  solution  compared  with  the  amount  that  could  be  dissolved  m  the  solution,  ex- 
pressed as  a  percent. 

Amount  of  Substance 
Percent  Saturation,  %      =      That  is  Dissolved     ^  -,qqo/^ 

Amount  That  Could  Be 
Dissolved  in  Solution 

PERCOLATING  WATER  (PURR-co-LAY-ting)  PERCOLATING  WATER 

Water  that  passes  through  soil  or  rocks  under  the  force  of  gravity. 

PERCOLATION  (PURR-ko-LAY-shun)  PERCOLATION 
The  slow  passage  of  water  through  a  filter  medium;  or,  the  gradual  penetration  of  soil  and  rocks  by  wate^ 

PERIPHYTON  (puh-RIF-uh-tawn)  PERIPHYTON 

Microscopic  plants  and  animals  that  are  firmly  attached  to  solid  surfaces  under  water  such  as  rocks,  logs,  pilings  and  other 
structures. 

PERMEABILITY  (PURR-me-u:.  BILL-uh-tee)  PERMEABILITY 
The  property  of  a  material  or  soil  that  permits  considerable  movement  of  water  through  it  when  it  is  saturated. 

PERMEATE  (PURR-me-ate)  PERMEATE 

(1)  To  penetrate  and  pass  through,  as  water  penetrates  and  passes  through  soil  and  other  porous  materials. 

(2)  The  demineralized  water. 

PESTICIDE  PESTICIDE 

Any  substance  or  chemical  designed  or  formulated  to  mII  or  control  weeds  or  animal  pests  Also  see  ALGICIDE,  HERBICIDE, 
INSECTICIDE,and  RODENTICIDE. 

PET  COCK  PET  COCK 

A  small  valve  or  faucet  used  to  dram  a  cylinder  or  fitting. 

pH  (pronounce  as  separate  letters)  pH 

pH  IS  an  expression  of  the  intensity  of  the  basic  or  acid  condition  of  a  liquid.  Mathematically,  pH  is  the  logarithm  (base  10)  of  tne 
reciprocal  of  the  hydrogen  ion  activity. 

pH     =  Log 


(H-) 


The  pH  may  range  from  0  to  14,  where  0  is  most  acid,  14  most  basic,  and  7  neutral  Natural  waters  usually  have  a  pH  between 
6.5  and  8.5. 

PHENOLIC  COMPOUNDS  (FEE-noll-LICK)  PHENOLIC  COMPOUNDS 

Organ":  compounds  that  are  derivatives  of  benzene. 

PHENOLPHTHALEIN  ALKALINITY  (FEE-nol-THAY-leen)  PHENOLPHTHALEIN  ALKALINITY 

The  alkalinity  in  a  water  sample  measured  by  the  amount  of  standard  acid  required  to  lower  the  pH  to  a  level  of  8.3,  as  indicated 
by  the  change  In  color  of  phenolphthalein  from  pmk  to  clear.  Phenolphthalem  alkalinity  is  expressed  as  m.iligrams  per  liter 
equivalent  calcium  carbonate. 

ERIC 

651 


Words  633 


PHOTOSYNTHESIS  (foe-tow-SIN-thuh-sis)  PHOTOSYNTHESIS 

A  process  m  which  organisms,  with  the  aid  of  chlorophyll  (green  plant  enzyme),  convert  carton  dioxide  and  inorganic 
substances  into  oxygen  and  additional  plant  material,  using  sunlight  for  energy.  All  green  plants  c  -^w  by  this  process. 

PHYTOPLANKTON  (FI-tow-PLANK-ton)  PHYTOPLANKTON 
Small,  usually  microscopic  plants  (such  as  algae),  found  in  lakes,  reservoirs,  and  other  bodies  of  water. 

PICO  PICO 
A  prefix  used  in  the  metric  system  and  other  scientific  systems  of  measurement  which  means  10     or  0.000  000  000  001. 

PICOCURIE  PICOCURIE 
A  measure  of  radioactivity.  One  picoCurie  of  radioactivity  is  equivalent  to  0.037  nuclear  disintegrations  per  second. 

PITLESS  ADAPTER  PITLESS  ADAPTER 

A  fitting  which  allows  the  wed  casing  to  be  extended  above  ground  while  having  a  discharge  connection  located  below  the  frost 
line  Advantages  of  using  a  pitless  adapter  include  the  elimination  of  the  need  for  a  pit  or  pump  house  and  it  is  a  water-tight 
design,  which  helps  maintain  a  sanitary  water  supply. 

PLAN  VIEW  PLAN  VIEW 

A  diagram  or  photo  shov/ing  a  facility  as  it  would  appear  when  looking  down  on  top  of  it. 

PLANKTON  PLANKTON 

(1)  Small,  usually  licroscopic.  plants  (phytoplank^'^n)  and  animals  (zoopiankton)  in  aquatic  systems. 

(2)  All  of  the  smaller  floating,  suspended  or  self-propelled  organisms  in  a  body  of  water. 

PLUG  FLOW  PLUG  FLOW 

A  type  of  flow  t^at  occurs  in  tanks,  'tasins  or  reactors  when  a  slug  of  water  moves  through  a  tank  without  ever  dispersing  or 
mixing  with  the  rest  of  the  water  flowing  through  the  tank. 

PMCLs  PMCLs 

Primary  Maximum  Contaminant  Levels.  Primary  MCLs  for  various  water  quality  indicators  are  established  to  protect  public 
health. 

POINT  SOURCE  POINT  SOURCE 

A  discharge  that  comes  out  of  the  end  of  a  pipe.  A  nonpoint  source  refers  to  runoff  or  a  discharge  from  a  field  or  similar  source. 

POLE  SHADER  POLE  SHADER 

A  copper  bar  circling  the  laminated  iron  core  inside  the  coil  of  a  magnetic  starter. 

POLLUTION  POLLUTION 

The  impairment  (reduction)  of  water  quality  by  agricultural,  domestic,  or  industrial  wastes  (including  thermal  and  atomic 
wastes),  to  a  degree  that  has  an  adverse  effect  on  any  beneficial  use  of  water. 

POLYCHLORINATED  BIPHENYLS  POLYCHLORINATED  BIPHENYLS 

A  class  of  organic  compounds  that  cause  adverse  health  effects  in  domestic  water  supplies. 

POLYELECTROLYTE  (POLLY-ee-LECK-tro-lite)  POLYELECTROLYTE 

A  high-molecular-weight  (r  *  "ively  heavy)  substance  having  points  of  positive  or  negative  electrical  charges  that  is  formed  by 
either  natural  or  man-made .  jcesses.  Natural  polyelectrolytes  may  be  of  biological  origin  or  derived  from  starch  products  and 
cellulose  derivatives.  Man-made  polyelectrolytes  consist  of  simple  substances  that  have  been  made  into  complex,  high- 
molecular-weight  substances.  Used  with  other  chemical  coagulants  to  aid  in  binding  small  suspended  particles  to  larger 
chemical  floes  for  their  removal  from  water.  Often  called  a  POl "  MER, 

POLYMER  POLYMER 

A  chemical  formed  by  the  union  of  many  monomers  (a  molecule  of  low  molecular  weight).  Polymers  are  used  with  other  chemi- 
cal coagulants  to  aid  in  binding  small  suspended  particles  to  larger  chemical  floes  for  their  removal  from  water.  All 
polyelectrolytes  are  polymers,  but  not  all  polymers  are  polyelecfolytes. 

PORE  PORE 
A  very  small  open  space  in  a  rock  or  granular  material.  Also  see  INTERSTICE, 

ERLC 


652 


634  Water  Treatment 


POROSITY  POROSITY 

(1)  A  measure  of  the  spaces  or  voids  in  a  material  or  aquifer. 

(2)  The  ratio  of  the  volume  of  spaces  in  a  rock  or  soil  to  the  total  volume.  This  ratio  is  usually  expressed  as  a  percentage. 

Porosity,  %  =:(Vo>"^e  of  Spaces)(100%) 
Total  Volume 

POSITIVE  8ACTLR  OLOGJCAL  SAMPLE  POSITIVE  BACTERIOLOGICAL  SAMPLE 

A  water  sample  in  which  gas  is  produced  by  coliform  organisms  during  mcubation  in  the  multiple  tube  fermentation  test.  See 
Chapter  11,  Lab  Procedures,  "Coliform  Test,  "  for  details. 

POSITIVE  DISPLACEA/r-^NT  PUMP  POSITIVE  DISPLACEMENT  PUMP 

A  type  of  piston,  diaphragm,  gear  or  screw  pump  that  delivers  a  constant  volume  with  each  stroke.  Positive  displacement 
pumps  are  used  as  chemical  solution  feeders. 

POSTCHLORINATION  POSTCHLORINATION 
The  addition  of  chlorine  to  the  plant  effluent,  FOLLOWING  plant  treatment,  for  disinfection  purposes. 

POTABLE  WATER  (POE-tuh-buli)  POTABLE  WATER 

Water  that  does  not  '^ontain  objectionable  pollution,  contamination,  minerals,  or  infective  agents  and  is  considered  satisfactory 
for  drinking. 

POWER  FACTOR  pOWER  FACTOR 

The  ratio  of  the  true  power  passing  through  an  electric  circuit  to  the  product  of  the  voltage  and  amperage  in  the  circuit.  This  is  a 
measure  of  the  lag  or  load  of  Jhe  current  with  lespect  to  the  voltage. 

PPM  PPM 
See  PARTS  PER  MILLION. 

PRECHLORINATION  PRECHLORINATION 
The  addition  of  chlorine  at  the  headworks  of  the  plant  PRIOR  TO  other  treatment  processes  mamly  for  disinfection  and  control 
of  tastes,  odors  and  aquatic  growths.  Also  applied  to  aid  in  coagulation  and  settling. 

PREC"^  TATE  (pre-SIP-uh-TATE)  PRECIPITATE 

(1)  An  insoluble,  finely  divided  substance  which  is  a  product  of  a  chemical  reaction  within  a  liquid. 

(2)  The  separation  f^om  solution  of  an  insoluble  substance. 

PRECIPITATION  (pre-SIP-uh-TAY-shun)  PRECIPITATION 

(1)  The  process  by  which  atmospheric  moisture  falls  onto  a  land  or  water  surface  as  ram,  snow,  hail,  or  other  forms  of  mois- 
ture. 

(2)  The  chemical  transformation  of  a  substance  in  solution   ♦o  an  insoluble  form  (precipitate). 

PRECISION  PRECISION 

The  ability  of  an  instrument  to  measure  a  process  variable  and  to  repeatedly  obtain  the  same  result.  The  ability  of  an  instrument 
to  reproduce  the  same  results. 

PRECURSOR,  THM  (pre-CURSE-or)  PRECURSOR,  THM 

Natural  organic  compounds  found  in  all  surface  and  groundwaters  These  compounds  M^AV react  with  halogens  (such  as  chlo- 
rine) to  form  tnhalomethanes  (try-HAL-o-MEi  H-hanes)  (THMs);  they  MUST  be  present  m  order  for  THMs  to  form. 

PRESCRIPTIVE  (pre-SKRIP-tive)  PP^SqrIPjIVE 

Water  rights  which  are  acquired  by  diverting  water  and  putting  it  to  use  m  accordance  with  specified  procedures.  These  proce- 
dures include  filing  a  request  to  use  unused  water  in  a  stream,  river  or  lake  with  a  .tate  agency. 

PRESSURE  CONTROL  PRESSURE  CONTROL 

A  switch  which  operates  on  changes  in  pressure.  Usually  this  is  a  diaphragm  pressing  against  a  spnng.  When  the  force  on  the 
diaphragm  overcomes  the  spring  pressure,  the  switch  is  actuated  (activated). 

PRESSURE  HEAD  PRESSURE  HEAD 

The  vp-tTdt  c?i^tance  (in  feet)  equal  to  the  pressure  (in  psi)  at  a  specific  point.  The  pressure  head  is  equal  to  the  pressure  in  psi 
timtd  2.31  ft/psi.  ^ 


Words  635 


PRESTRESSED  PRESTRESSED 

A  prestressed  pipe  has  been  reinforced  with  wire  strands  (which  are  under  tension)  to  give  the  pipe  an  active  resistance  to 
loads  or  pressures  on  it. 

PRIMARY  ELEMENT  PRIMARY  ELEMENT 

The  hydraulic  structure  used  to  measure  flows.  In  op€  channels,  weirs  and  flumes  are  primary  elements  or  devices.  Venturi 
meters  and  orifice  plates  are  the  primary  elements  in  pipes  or  pressure  conduits. 

PR'M^  PRIME 

The  action  of  filling  a  pump  casing  with  water  to  remove  the  air  Most  pumps  must  be  primed  before  startup  or  they  will  not 
pump  any  water. 

PROCESS  VARIABLE  PROCESS  VARIABLE 

A  physical  or  chemical  quant'ty  which  is  usually  measured  and  controlled  in  the  operation  cf  a  water  treatment  plant  or  an  in- 
dustrial plant. 

PRODUCT  WATER  PRODUCT  WATER 

Water  that  has  passed  through  a  water  treatment  plant  All  the  treatment  processes  are  completed  or  finished.  This  water  is  the 
product  from  the  water  treatment  plant  and  is  ready  to  be  delivered  to  the  consumers.  Also  called  FINISHED  WATER. 

PROFILE  PROPJLE 
A  drawing  showing  elevation  p>otted  against  distance,  such  as  the  vertical  section  or  side  view  of  a  pipeline. 

PRUSSIAN  BLUE  PRUSSIAN  BLUE 

A  blue  paste  or  liquid  (often  on  a  paper  like  carbon  paper)  used  to  show  a  contact  area.  Used  to  determine  if  qate  valve  seats  fit 
properly.  ^ 

PSIG  PS,Q 

Pounds  per  Square  Inch  Gage  pressure  The  pressure  within  a  closed  container  or  pipe  measured  with  a  aaae  in  pounds  ner 
square  inch.  See  GAGE  PRESSURE.  y  y      ^'  k 

PUMPING  WATER  LEVEL  PUMPING  WATER  LEVEL 

The  vertical  d'stance  in  feet  from  the  centerline  of  the  pump  discharge  to  the  level  of  the  free  pool  while  water  is  beinq  drawn 
from  the  pool. 

PURVEYOR,  WATER  (purr-VAY-or)  PURVEYOR,  WATER 

An  agency  or  person  that  supplies  water  (usually  potable  water). 

PUTREFACTION  (PEW-truh-FACK-shun)  PUTREFACTION 

Biological  decomposition  of  organic  matter,  with  the  production  of  ill-smelling  and  tasting  products,  associated  with  anaerobic 
(no  oxygen  present)  conditions. 

QUICKLIME  QUICKLIME 
A  material  that  is  mostly  calcium  oxide  (CaO)  or  calcium  oxide  in  natural  association  with  a  lesser  amount  of  magnesium  oxide. 
Quicklime  is  capable  of  combining  with  water  to  form  hydrated  lime.  Also  see  HYDRATED  LIME 

RADIAL  TO  IMPELLER  RADIAL  TO  IMPELLER 

Perpendicular  to  the  impeller  shaft.  Material  being  pumped  flows  at  a  right  angle  to  the  impeller. 

RADICAL  RADICAL 
A  group  of  atoms  that  is  capable  of  remaining  unchanged  during  a  series  of  chemical  reactions.  Such  combinations  (radicals) 
exist  in  the  molecules  of  many  organic  compounds;  sulfate  (SO/  )  is  an  inorganic  radical. 

RANGE  RANGE 

The  spread  from  minimum  to  maximum  values  that  an  instrument  is  designed  to  fpeasure.  Also  see  SPAN  and  EFFECTIVE 
RANGE. 

RANNEY  COLLECTOR  rAnnEY  COLLECTOR 

This  water  collector  is  constructed  as  a  dug  well  from  12  to  16  feet  (3.5  to  5  m)  m  diameter  that  has  been  sunk  as  a  caisson  near 
the  bank  of  a  river  or  lake  Screens  are  driven  radially  and  approximately  honzont^illy  from  this  well  into  the  sand  and  the  gravel 
deposits  underlying  the  river. 

[SEE  DRAWING  ON  PAGE  636] 


636  Water  Treatment 


/-PUMP 


WATER  TABLE 


r 


GROUND  SURFACE 


COLLECTOR  PIPE 


ELEVATION  VIEW 


PLAN  VIEW  OF  COLLECTOR  PIPES 


RANNEY  COLLECTOR 


RAW  WATER  RAW  WATER 

(1)  Water  in  its  natural  state,  prior  to  any  treatment. 

(2)  Usually  the  water  entering  the  first  treatment  process  of  a  water  treatment  plant. 

REAERATION  (RE-air-A-shun)  REAERATION 

'i  3  introduction  of  air  through  forced  air  diffusers  into  the  lower  layers  of  the  reservoir.  As  the  air  bubbles  form  and  nse 
tnrough  the  water,  oxygen  from  the  air  dissolves  into  the  water  and  replenishes  the  dissolved  oxygen.  The  rising  bubbles  also 
cause  the  lower  waters  to  rise  to  the  surface  where  oxygen  from  the  atmosphere  is  transferred  to  the  water.  This  is  sometimes 
called  surface  reaeration. 

REAGENT  (re-A-gent)  REAGENT 

A  pure  chemical  substance  that  is  used  lo  make  new  products  or  is  used  in  chemical  tests  to  measure,  detect,  or  examine  other 
substances. 

RECARBONATION  (re-CAR-bun-NAY-shun)  RECARBONATION 

A  process  in  whion  carbon  dioxide  is  bubbled  into  the  water  being  treated  to  lower  the  pH.  The  pH  may  also  be  lowered  by  the 
addition  of  acid  Recarbonation  is  the  final  stage  in  the  lime-soda  ash  softening  process.  This  process  converts  carbonate  ions 
to  bicarbonate  ions  and  stabilizes  the  solution  against  the  precipitation  of  carbonate  compounds. 

653 


Words  637 

RECEIVER  RECEIVER 
A  device  which  indicates  the  value  of  a  measurement.  Most  receivers  m  the  water  utility  field  use  either  ct  fixed  scale  and  mov- 
able indicator  (pointer)  such  as  pressure  gage  or  a  moving  chart  with  movable  pen  such  as  on  a  circular-flow  recording  chart. 
Also  called  an  INDICATOR. 

RECORDER  RECORDER 
A  device  that  creates  a  permanent  record,  on  a  paper  chart  or  magnetic  tape,  of  the  changes  of  some  measured  variable. 

REDUCING  AGENT  REDUCING  AGENT 

Any  substance,  such  as  base  metal  (iron)  or  the  sulfide  ion  (S^  ,)  that  will  readily  donate  (give  up)  electrons.  The  opposite  is  an 
OXIDIZING  AGENT. 

REDUCTION  (re-DUCK-shun)  REDUCTION 
Reduction  is  the  addition  of  hydrogen,  removal  of  oxygen,  or  the  addition  of  electrons  to  an  element  or  compound.  Under  an- 
aerobic  conditions  (no  dissolved  oxygen  present)  sulfur  compounds  are  reduced  to  odor-producing  hydrogen  sulfide  (H^S)  and 
other  compounds.  The  opposite  of  OXIDATION. 

REFERENCE  REFERENCE 
A  physical  or  chemical  quantity  whose  value  is  known  exactly,  and  thus  is  used  to  calibrate  or  standardize  instruments. 
RELIQUEFACTION  (re-LICK-we-FACK-shun)  RELIQUEFACTION 
The  return  of  a  gas  to  the  liqud  state;  for  example,  a  condensation  of  chlorine  gas  to  return  it  to  its  liquid  form  by  cooling. 

REPRESENTATIVE  SAMPLE  REPRESENTATIVE  SAMPLE 

A  portion  of  material  or  water  that  is  as  nearly  identical  in  content  and  consistency  as  possible  to  that  in  the  larger  body  of 
material  or  water  being  sampled. 

RESIDUAL  CHLORINE  RESIDUAL  CHLORINE 

The  amount  of  free  and/or  available  chlorine  remaining  after  a  given  contact  time  under  specified  conditions 
RESIDUE  PES,j3UE 
The  dry  solids  remaining  after  the  evaporation  of  a  sample  of  water  or  sludge.  Also  see  TOTAL  DISSOLVED  SOLIDS. 

RESINS  RESINS 
See  ION  EXCHANGE  RESINS. 

RESISTANCE  RESISTANCE 

That  property  of  a  conductor  or  wire  that  opposes  the  passage  of  a  current,  thus  causing  electncal  energy  to  be  transformed 
into  heat. 

RESPIRATION  RESPIRATION 
The  process  In  which  an  organism  uses  oxygen  for  its  life  processes  and  gives  off  carbon  dioxide. 

REVERSE  OSMOSIS  (oz-MOE-sis)  REVERSE  OSMOSIS 

The  application  of  pressure  to  a  concentrated  solution  which  causes  the  passage  of  a  liquid  from  the  concentrated  solution  to  a 
weaker  solution  across  a  semipermeable  membrane.  The  membrane  allows  the  passage  of  the  water  (solvent)  but  not  the  dis- 
solved solids  (solutes).  The  liquid  produced  is  a  demineralized  water.  Also  see  OSMOSIS. 

RIPARIAN  (ri-PAIR-ee-an)  RIPARIAN 

Water  rights  which  are  acquired  together  with  title  to  the  land  bordering  a  source  of  surface  water.  1  ne  right  to  put  to  beneficial 
use  surface  water  adjacent  to  your  land 

RODENTICIDE  (row-DENT-L  »-SIDE)  RODENTICIDE 
Any  substance  or  chemical  used  to  kill  or  control  rodents. 

ROTAMETER  (RODE-uh-ME-ter)  ROTAMETER 
A  device  used  to  measure  the  flow  rate  of  gases  and  liquids.  The  gas  or  liquid  being  measured  flows  vertically  up  a  tapered, 
calibrated  tube  Inside  the  tube  is  a  small  ball  or  bullet-shaped  float  (it  may  rotate)  that  rises  or  falls  depending  on  the  flow  rate! 
The  flow  rate  may  be  read  on  a  scale  behind  or  on  the  tube  by  looking  at  the  middle  of  the  ball  or  at  the  widest  part  or  top  of  the 
float. 

ROTOR  ROTOR 
The  rotating  part  of  a  machine.  The  rotor  is  surrounded  by  the  stationary  (non-moving)  parts  (stator)  of  the  machine. 

ERJC  .  , 


638  Water  Treatment 


ROUTINE  SAMPLING  ROUTINE  SAMPLING 

Sampling  repeated  on  a  regular  basis. 

SACRIFICIAL  ANODE  SACRIFICIAL  ANODE 

An  easily  corroded  material  deliberately  installed  in  a  pipe  or  tank.  The  intent  of  such  an  installation  is  to  give  up  (sacrifice)  this 
anode  to  corrosion  wh:le  the  water  supply  facilities  remain  relatively  corrosion  free 

SAFE  DRINKING  WATER  ACT  SAFE  DRINKING  WATER  ACT 

Commonly  referred  to  as  SDWA  An  Act  passed  by  the  U  S  Congress  in  1974.  The  Act  establishes  a  cooperative  program 
among  local,  state  and  federal  agencies  to  insure  safe  drmking  water  for  consumers. 

SAFE  WATER  SAFE  WATER 

Water  that  does  not  contain  harmful  bacteria,  or  toxic  materials  or  chemicals.  Water  may  have  taste  and  odor  problems,  color 
and  certain  mineral  problems  and  still  be  considered  safe  for  drinking. 

SAFE  YIELD  SAFE  YIELD 

The  annual  quantity  of  water  that  can  be  taken  from  a  source  of  supply  over  a  period  of  years  without  depleting  the  source  per- 
manently (beyond  its  ability  to  be  replenished  naturally  in  "wet  years"). 

SALINITY  SALINITY 

(1)  The  relative  concentration  of  dissolved  salts,  usualy  sodium  chloride,  in  a  given  water. 

(2)  A  measure  of  the  concentration  of  dissolved  mineral  substances  in  water. 

SANITARY  SURVEY  SANITARY  SURVEY 

A  detailed  evaluation  and/or  inspection  of  a  source  of  water  supply  and  all  conveyances,  Siorage,  treatment  and  distribution 
facilities  to  insure  its  protection  from  all  pollution  sources. 

SAPROPHYTES  (SAP-row-FIGHTS)  SAPROPHYTES 
Organisms  living  on  dead  or  decaying  organic  matter.  They  help  natural  decomposition  of  organic  matter  in  water. 

SATURATION  SATURATION 

The  condition  of  a  liquid  (water)  when  it  has  laken  into  solution  the  maximum  possible  quantity  of  a  given  substance  at  a  given 
temperature  and  pressure. 

SATURATOR  (SAT-you-RAY-tore)  SATURATOR 

A  device  which  produces  a  fluoride  solution  lor  the  fluoridation  process  The  device  is  usually  a  cylindrical  container  with  granu- 
lar sodium  fluoride  on  the  bottom  Water  flows  either  upward  or  downward  through  the  sodium  fluoride  to  produce  the  fluoride 
solution 

SCFM  SCFM 

Cubic  Feet  of  air  per  Minute  at  Standard  conditions  of  temf^erature,  pressure  and  humidity  (0°C  / 14.7  psia  /  50%  relative  hu- 
midity). 

SDWA  SDWA 
See  SAFE  DRINKING  WATER  ACT. 

SECGHI  DISC  (SECK-key)  SECCHI  DISC 

A  flat,  white  disc  lowered  into  the  water  by  a  rope  until  it  is  just  barely  v.sible.  At  this  point,  the  depth  of  the  disc  from  the  water 
surface  is  the  recorded  Secchi  disc  transparency. 

SEDIMENTATION  (SED-uh-men-TAY-shun)  SEDIMENTATION 

A  water  treatment  process  in  which  solid  particles  settle  cut  of  the  water  being  treated  in  a  large  clanfjer  or  sedimentation 
basin. 

SEIZE  UP  SEIZE  UP 

Seize  up  occurs  when  an  engine  overheats  and  a  part  expands  to  the  point  where  the  engine  will  not  run  Also  called  "freezing. " 

SENSOR  SENSOR 

An  instrument  that  measure  (senses)  a  physical  condition  or  variable  of  interest.  Floats  and  thermocouples  are  examples  of 
sensors. 

SEPTIC  (SEP-tick)  SEPTIC 

A  condition  produced  by  bacteria  when  all  oxygen  supplies  are  depleted  U  severe,  bottom  deposits  and  water  turn  black,  give 
off  foul  odors,  and  the  water  has  a  greatly  increased  chlorine  demand. 

Er|c  657 


Words  639 


SEQUESTRATION  (S£E-k.ves-TRAY-Ghun) 


SEQUESTRATION 


Jc''S^l?f  "L^  "^'"^  °'  "'^^^"'^  ^  ^'^"^  (such  as  iron)  with  certain  inorganic  compounds,  such 

as  phosphate  Sequestntion  prevents  the  prec'      'cn  of  the  rr  jtNs  (iron).  Also  see  CHELATION 


SERVICE  PIPE 


SERVICE  PIPE 

The  pipeline  extending  from  the  water  mam  to  the  huilding  served  or  to  the  consumer's  system 

P^'N^  SET  POINT 

The  position  at  which  the  control  c  controller  i<^  set  This  is  the  same  as  the  desired  value  of  the  process  variable. 

SEWAGE  ^r-.*..^^ 

SEWAGE 

W^STEWaTe?  ^^^^       ^'^"^  ^^'^"^^  ^^"^^'^     ^  wastewater  treatment  plant.  The  prefsrred  term  is 


SHEAVE  (SHE-v) 

V-belt  dnve  pulley  which  is  commonly  made  of  cast  iron  or  steel. 
SHIM 


SHEAVE 


SHIM 


JI^llTV^^  ^^^^^^  "^^'^i"  ^''^  '"^^'^^^  between  two  surfaces  to  align  or  space  the  surfaces  correctly.  Shims  can  be  used  any- 
where a  spacer  is  needed.  Usually  shims  are  0.001  to  0.020  inches  thick. 


SHOCK  LOAD 


SHOCK  LOAD 


I^^fnf  H  "^^^^^  treatment  plant  of  rav^  water  containing  unusual  amounts  of  algae,  colloidal  matter,  color,  suspended 
solids,  turbidity,  or  otner  pollutants.  ^ 


SHORT-CIRCUITING 


SHORT-CIRCUITING 


A  condition  that  occurs  in  tanks  or  basins  when  some  of  the  water  travels  faster  than  the  rest  c  the  flowing  water.  This  is  usual- 
prasS  d^^^^^^  ^  reaction,  or  settling  times  in  comparison  wi»h  the  theoretical  (calculated)  or 


SIMULATE 


SINGLE-STAGE  PUMP 


SIMULATE 

To  reproduce  the  action  of  some  process,  usually  on  a  smaller  scale. 
SINGLE-STAGE  PUMP 

A  pump  that  has  only  one  impeller  A  multi-stage  pomp  has  more  than  one  impeller. 

^^•^•^^  SLAKE 
To  mix  with  water  with  a  true  chemical  combination  (hydrolysis)  taking  place,  such  as  in  the  slaKing  of  lime. 

"-IME  SLAKED  LIME 

See  HYDRATED  LIME. 


SLOPE 

The  slope  or  inclination  of  a  trench  bottom  or  a  trench  side  wall  is  the  ratio  of  the 
vertical  d.stance  to  the  horizontal  distance  or  "rise  over  run."  Also  see  "^RADE  (2). 


SLOPE 


2  VERTICAL 
1  HORIZONTAL 


2:1  SLOPE 

SLUDGE  (sluj) 

T'he  ?9ttleable  solids  separatee  from  water  during  processing. 
SLURt'.Y  (SLUR-e) 


SLUDGE 


SLURRY 

A  watery  mixtun  or  -uspens^^n  of  insoluble  (not  dissolved)  matter;  a  thin  watery  mud  or  anv  substance  resembling  it  (st  ^,h  as  a 
grit  slurry  or  a  lime  aiurry).  y  i  v    «o  « 

EMC  658 


640  Water  Treatment 


SMCLs  SMCLs 

Secondary  Mcaximum  Contaminant  Levels  Secondary  MCLs  for  various  water  (^jality  iridicators  are  estabuo.  .od  to  protect  pub- 
lic welfare 

SNARL  SNARL 

Suggested  No  Adverse  Response  Level  The  concentrat«on  of  a  chemical  in  water  that  is  expected  not  to  cause  an  adverse 
health  effect 

SOFTWARE  PROGRAMS  SOFTWARE  PROGRAMS 

Computei  programs,  the  list  of  instructions  that  tell  a  computer  how  to  perform  ^  given  task  or  tasks. 

SOFT  WATER  SOFT  WATER 

Water  having  a  low  concentration  of  calcium  end  nagnesium  ions  According  to  U  S.  Geological  Survey  gui  Jines,  soft  water  is 
water  having  a  hardness  of  60  milligrams  per  liter  or  less. 

SOLENOID  (SO-luh-noid*  SOLENOID 
A  magnetically  (electrical  coil)  operated  mechanical  device.  Solenoids  can  operate  pilot  valves  or  electrical  switches. 

SOLUTION  SOLUTION 
A  liquid  mixture  of  dissolved  substances  In  a  solution  it  is  impossible  to  see  all  the  separate  parts. 

SOUNDING  TUBE  SOUNDING  TUBE 

A  pipe  or  tube  used  for  measuring  the  depths  of  water. 

SPAN  SPAN 
Th^  scale  or  range  of  values  an  instrument  is  designed  to  measure.  Also  see  RANGE. 

SPECIFIC  CONDUCTANCE  SPECIFIC  CONDUCTANCE 

A  rapid  method  of  estimating  the  dissolved-solids  content  of  a  water  supply.  The  measurement  indicates  the  capacity  of  a  sam- 
ple of  water  to  carry  an  electncal  current,  which  is  related  to  the  concentration  of  ionized  substances  in  the  wrter.  Also  called 
CONDUCTANCE. 

SPECIFIC  GR.AVITY  SPECIFIC  GRAVITY 

Weight  of  a  particle,  substance,  or  chemical  solution  in  relation  to  the  weight  of  water.  Water  has  a  specific  gravity  of  1.000  at 
4°C(39''F)  Particulates  in  raw  water  may  have  a  specific  gravity  of  1.005  to  2.5. 

SPECIFIC  YIELD  SPECIFIC  YIELD 

The  quantity  of  water  that  a  unit  volume  saturated  permeable  rc':k  or  soil  will  yield  when  drained  by  gravity.  Specific  yield  may 
be  expressed  as  a  ratio  or  as  a  pe''centage  by  volume. 

SPOIL  SPOIL 
Excavated  matenal  cuch  as  soil  from  the  trench  of  a  water  mam. 

SPORE  SPORt 

The  reoroductive  uody  of  an  organism  which  is  capable  of  giving  rise  to  a  new  organ  sm  either  directly  or  indirectly.  A  viable 
(able  to  live  and  grow)  bc::>  regarded  as  the  resting  stage  of  an  'Organism.  A  spore  is  usually  more  resistant  to  disinfectants  and 
heat  than  most  organisms. 

SPRING  LINE  SPRING  LINE 

Theoretical  center  of  a  pipeline.  Also,  the  guideline  for  laying  a  course  of  bricks. 

STALE  WATER  STALE  WATER 

Water  which  has  not  flowed  recently  and  may  have  picked  up  tastes  and  odors  from  distribution  lines  or  storage  facilities. 

STANDARD  STANDARD 

A  physical  or  chemical  quantity  whose  value  is  known  exactly,  and  is  used  to  calibrate  or  standardize  instruments.  Also  see 
REFERENCE. 

STANDARD  METHODS  STANDARD  METHODS 

STANDARD  METHODS  FOR  THE  EXAMINATION  OF  WATER  AND  WASTEWATER.  A  joint  publication  of  the  American  Public 
Health  Association.  American  Wat     Vorks  Association,  and  the  Water  Pollution  Control  Federation  which  outlines  the 


ERLC 


procedures  used  to  analyze  the  imputi-  es  in  water  and  wastewater,  t^f.- 


Words  641 


STANDARD  SOLUTION  STANDARD  SOLUTION 

A  solution  in  which  the  exact  concentration  of  a  chemica!  or  compound  is  known. 

STANDARDIZE  STANDARDIZE 
To  comj.  are  with  a  standard. 

(1)  In  wet  chemistry,  to  find  out  the  exact  stren(,*h  of  a  solution  by  companng  it  with  a  standard  of  known  strength. 

(2)  To  set  up  an  instrument  or  device  to  read  a  standard  This  allows  you  to  adjust  the  instrument  so  that  it  reads  accurately,  or 
enables  you  to  apply  a  correction  factor  to  the  readings. 

STARTERS  STARTERS 

Devices  used  to  start  up  large  motors  gradually  to  avoid  severe  mechanical  shock  to  a  driven  machine  and  to  prevent  dis- 
turbance to  the  electrical  lines  (causing  dimming  and  flickering  o.  ghts). 

STATIC  HEAD  STATIC  HEAD 

When  water  is  not  mov'«ng,  the  vertical  distance  (in  feet)  from  a  specific  )int  to  the  water  surface  is  the  static  head.  (The  static 
pressure  in  psi    the  static  head  in  feet  times  0.433  psi/ft.)  Also  see  uYNAMIC  PRESSURE  and  STATIC  PRESSURE. 

STATIC  PRESSURE  STATIC  PRESSURE 

When  water  is  not  moving,  the  v  ical  distance  (m  feet)  from  a  specific  point  to  the  water  surface  is  th^'  static  head.  The  static 
pressure  in  psi  is  the  static  hea"  in  feet  times  0.433  psi/ft.  Also  see  DYNAMIC  PRESSURE  and  STA   J  HEAD. 

STATIC  WATER  DEPTH  STATIC  WATER  DEPTH 

The  vertical  distance  in  feet  from  the  centerline  of  the  pump  discharge  down  to  the  surface  level  of  the  free  pool  while  no  water 
is  being  drawn  from  the  pool  or  water  table. 

STATIC  WATER  LEVEL  STATIC  WATER  LEVEL 

(1)  The  elevation  or  level  of  the  water  table  in  a  well  when  the  pump  is  not  operating. 

(2)  The  level  or  elevation  to  which  water  would  rise  in  a  tube  cc  ^nected  .o  an  artesian  aquifer,  or  basin,  or  conduit  under  pres- 
sure. 

STATOR  STATOR 
That  portion  of  a  machine  which  contains  the  stationary  (non-moving)  parts  that  surround  the  moving  parts  (rotor). 

STERILIZATION  (STARE-uh-lijh-ZAY-shun)  STERILIZATION 

The  removal  or  destruction  of  all  microorganisms,  including  pathogenic  and  other  bacteria,  vegetative  forms  and  spores. 
Compare  with  DISINFECT  ION. 

STETHOSCOPE  STETHOSCOPE 
An  instrument  used  to  magnify  sounds  and  convey  them  to  the  ear. 

STRATIFICATION  (STRAT-uh-fuh-KAY-shun)  STRATIFICATION 

The  formation  of  separate  layers  (of  temperature,  plant,  or  animal  life)  m  a  lake  or  reservoir.  Each  layer  has  similar 
'Characteristics  such  as  all  water  in  the  layer  has  the  same  temperature.  Also  see  THERMAL  STRATIFICATION. 

SUBMERGENCE  SUBMERGENCE 
The  distance  between  the  water  surface  and  the  media  surface  in  a  filter. 

SUBSIDENCE  (sub-SIDE-ence)  SUBSIDENCE 

The  dropping  or  lowenng  of  the  ground  surface  as  a  result  of  removing  excess  water  (overdraft  or  over  pumping)  from  an 
aquifer  After  excess  water  has  been  removed,  the  soil  will  settle,  become     npacted  and  the  ground  surface  will  drop. 

SUCTION  LIFT  SUCTION  LIFT 

ThG  NEGATIVE  pressure  [in  feet  (meters)  of  water  or  inches  (centimeters)  of  mercury  vacuum]  on  the  suction  side  of  the  pump. 
The  pressure  can  be  measured  from  the  centerline  of  the  pump  DOWN  rO(litt)  the  elevation  of  the  hydraulic  grade  line  on  the 
suction  side  of  the  pump. 

SUPERCHLORINATION  (SUE-per-KLOR-uh-NAY-shun)  SUPERCMLORINATION 

Chlorination  with  doses  that  are  deliberately  selected  to  produce  free  or  combinea  residuals  so  large  as  to  require 
dechlorination. 

SUPPRNATANT  (sue-per-NAY-tent)  SUPERNATANT 

.d  removed  from  settled  sludge  Supematant  commonly  refers  to  the  liquid  between  the  sludge  on  the  bottom  and  the  water 
bufface  of  a  basin  or  container. 

ERIC  660 


642  Water  Treatment 


SUPERSATURATED 


SUPERSATURATED 


An  unstable  condition  of  a  solution  (water)  in  which  the  solution  contains  a  substance  at  a  concentration  greater  than  the  satu- 
ration concentration  for  the  substance 

SURFACE  LOADING  SURFACE  LOADING 

One  of  the  guidehnes  for  the  design  of  settling  tanks  and  clarifiers  ir  treatment  plants  Used  by  operators  to  determine  if  tanks 
and  clarifiers  are  hydraul.cally  (flow)  over-  or  underloaded.  Also  called  OVERFLOW  RATE. 


Surface  Loading,  GPD/sq  ft  ^  Flow,  gallon/day 


Surface  Area,  sq  ft 


SURFACTANT 


SURFACTANT  (sir-FAC-ter.t) 

Abbreviation  for  surface-active  agent  The  active  agent  in  detergents  that  possesses  a  high  cleaning  ability. 

SURGE  CHAMBER  c^URGE  CHAMBER 

A  chamber  or  tank  connected  to  a  pipe  and  located  at  or  near  a  valve  that  may  quickly  open  or  close  or  a  pump  ♦hat  may 
suddenly  start  or  stc^  When  the  flow  of  water  in  a  pipe  starts  or  stops  quickly,  the  surge  chamber  allows  water  to  flow  into  or 
out  of  the  pipe  and  minimize  any  sudden  positive  or  negative  pressure  waves  or  surges  in  the  pipe. 


OPEN  TOP 


CLOSED 
ON  top" 


z 


AIR 


TYPES  or  SURGE  CHAMBERS 


SURGE  CHAMBER 

SUSPENDED  SOLIDS  SUSPENDED  SOLIDS 

(1 1  Solic<s  t^at  either  float  on  the  surface  or  are  suspended  .n  water  o:  other  liquids,  and  which  are  largely  removable  by  labora- 
tory filtering. 

(2)  Tnc  quantity  of  matenal  removed  from  water  m  a  laboratory  test,  as  prescribed  m  STANDARD  METHODS  FOR  T>  .1  EXAMI- 
NATION OF  WATER  AND  WASTEWATER  and  referred  to  as  nonfilterable  residue. 


Words  643 


TAILGATE  SAFETY  MEETING  TAILGATE  SAFETY  MEETING 

The  term  TAILGATE  comes  from  the  safety  reetings  regularly  held  by  the  construction  industry  around  the  tailgate  of  a  truck. 

TCE  TCE 
See  TRICHLOROETHANE. 

TDS  TDS 
See  TOTAL  DISSOLVED  SOLIDS. 

TELEMETRY  (tel-LEM-uh-tree)  TELEMETRY 
The  electrical  link  between  the  transmitter  and  the  receiver  Telep*  ^ne  lineb  are  commonly  used  to  serve  as  the  electncal  line. 

TEMPERATURE  SENSOR  TEMPERATURE  SENSOR 

A  device  that  opens  and  closes  a  switch  m  response  to  changes  in  the  temperature  This  device  might  be  a  metal  contact,  or  a 
thermocc  jple  that  generates  minute  €  jctrical  current  proportional  to  the  difference  in  heat,  or  a  variable  resistor  whose  value 
changes  in  response  to  changes  in  temperature.  Also  called  a  HEAT  SENSOR. 

THERMAL  STRATIFICATION  (STRAT-uh-fuh-KAY-shun)  THERMAL  STRATIFICATION 

The  formation  of  layers  of  different  temperatures  In  a  lake  or  reser^/oir.  Also  tee  STRATIFICATION. 

THERMOCLINE  (THUR-moe-KLINE)  THERMOCLINE 

The  middle  layer  in  a  thermally  stratified  lake  or  reservoir  In  this  layer  there  is  a  rapid  decrease  in  temperature  with  depth.  Also 
called  the  METALIMNION. 

THERMOCOUPLE  THERMOCOUPLE 

A  heat-sensing  device  made  of  two  conductors  of  different  metals  joined  at  their  ends.  An  elect,  ic  current  is  produced  when 
there  is  a  difference  in  temperature  between  the  ends. 

THICKENING  THICKENING 
Treatment  to  remove  water  from  the  sludge  mass  to  reduce  the  voiume  that  must  be  handled. 

THM  THM 
See  TRIHALOMETHANES. 

THM  PRECURSOR  THM  PRECURSOR 

See  PRECURSOR,  THM. 

THRESHOLD  ODOR  THRESHOLD  ODOR 

The  vr-  num  odor  of  a  water  sample  that  can  just  be  detected  after  successive  dilutions  with  odorless  water.  Also  called 
ODO.  ..iRESHOLD. 

THRESHOLD  ODOR  NUMBER  THRESHOLD  ODOR  NUMBER 

TON.  The  greatest  dilution  of  a  sample  with  odor-free  water  that  still  yields  a  just-detectable  odor. 

THRUST  BLOCK  THRUST  BLOCK 

A  mass  of  concrete  or  similar  material  appropriately  placed  around  a  pipe  to  prevent  movement  when  the  pipe  is  carrying  water. 
Usually  placed  at  bends  and  valve  structures. 

TIME  LAG  TIME  LAG 

The  time  requir'^d  for  processes  and  control  systems  to  respond  tc  a  signal  or  to  reach  a  desired  level. 

TIMER  TIMER 
A  device  for  automatically  starting  or  stopping  a  machine  or  other  device  at  a  given  time, 

TITRATE  (TIE-trate)  TITRATE 

To  TITRATE  a  sample,  a  chemical  solution  of  known  strength  is  added  on  a  drop-by-drop  basis  until  a  certain  color  change, 
precipitate,  or  pH  change  in  the  sample  is  observed  (end  point).  Titration  is  the  process  of  adding  the  chemical  reagent  m 
increments  until  completion  of  the  reaction,  as  signaled  by  the  end  point. 

TOPOGRAPHY  TOPOGRAPHY 
The  arrangement  of  hills  and  valleys  in  a  geographic  area. 


662 


644  Water  Treatment 


TOTAL  DISSOLVED  SOLIDS  (TDS)  TOTAL  DISSOLVED  SOLIDS  (TDS) 

All  of  the  dissolved  sohds  in  a  water  TDS  »s  measured  on  a  sample  of  water  that  has  passed  through  a  /ery  fme  mesh  filter  to 
remove  suspended  solids  The  water  passing  through  th'i  filter  is  evaporated  and  the  residue  represents  the  dissolved  solids. 
Also  see  SPECIFIC  CONDUCTANCE. 

TOTAL  DYNAMIC  HEAD  (TDH)  TOTAL  DYNAM'C  HEAD  (TDH) 

When  a  pump  is  lifting  or  pumping  water,  the  vertical  distance  (in  feet)  from  the  elevation  of  the  energy  grade  line  on  the  suction 
side  of  the  pump  to  the  elevation  of  the  energy  grade  line  on  the  discharge  side  of  the  pump. 

TOTAL  RESIDUAL  CHLORINE  TOTAL  RESIDUAL  CHLORINE 

"^he  amount  of  available  chlorine  remaining  after  a  given  contact  time.  The  sum  of  the  combined  available  resiOuai  chlonne  and 
the  free  available  residual  chlorine.  Also  see  RESIDUAL  CHLORINE 

TOTALIZER  TOTALIZER 

A  device  or  meter  that  continuously  measures  and  calculates  (adds)  total  flows  m  gallons,  million  gallons,  cubic  feet,  or  some 
other  unit  of  volume  measurement.  Also  called  an  INTEGRATOR. 

TOXAPHENE  (TOX-uh-FEEN)  TOXAPHENE 
A  chemical  that  causes  adverse  health  effects  ^n  domestic  water  supplies  and  also  is  toxic  to  freshwater  and  marine  aquatic  life. 

TOXIC  (TOX-ick)  TOXIC 
A  substance  which  is  poisonous  to  an  organism. 

TRANSDUCER  (trans-DUE-sir)  TRANSDUCER 

A  device  which  senses  some  varying  condition  and  converts  it  to  an  electrical  or  other  signal  for  transmission  to  some  other  de- 
vice (a  receiver)  for  processing  or  decision  making. 

TRANSMISSION  LINES  TRANSMISSION  LINES 

Pipelines  that  transport  raw  water  from  its  source  to  a  water  treatment  plant.  After  treatment,  water  is  usually  pumped  into  pipe- 
lines {transmission  lines)  that  are  connected  to  a  distribution  grid  system. 

TRANSMISSIVITY  (TRANS-miss-SIV-it-tee)  TRANSMISS:VITY 
A  measure  of  the  ability  to  transmit  (as  in  the  ability  of  an  aquifer  to  transmit  water) 

TRANSPIRATION  (TRAN-spur-RAY-shun)  TRANSPIRATION 

The  process  by  which  water  vapor  is  released  tc  the  atmosphere  by  living  plants.  This  process  is  similar  to  people  sweating. 
Also  called  EVAPOTRANSPIRATION. 

TREMIE  (TREH-me)  TREMIE 
A  device  xised  to  place  concrete  or  grout  unrJer  water 

TRICHLOROETHANE  (TCE)  (try-KLOR-o-ETH-hane)  TRIChLOROETHANE  (TCE) 

An  organic  chemical  used  as  a  cleaning  solvent  that  causes  adverse  health  effects  in  domestic  water  supplies. 

TRIHALOMETHANES  (tri-HAL-o-METH-hanes)  TRIHALOMETHANES 

Derivatives  of  methane,  CH^,  in  winch  three  halogen  atoms  (chlorine  or  bromine)  are  substituted  for  three  of  the  hydrogen 
atoms  Often  formed  during  chlorination  by  reactions  with  natural  organic  materials  in  the  water.  The  resulting  compounds 
(THMs)  are  suspected  of  causing  cancer. 

TUBE  SETTLER  TUPE  SETTLER 

A  device  that  uses  bundles  of  small  bore  (2  to  3  inches  or  50  to  75  rnm)  tubes  installed  on  an  incline  as  an  aid  to  sedimentation. 
The  tubes  may  come  in  a  variety  of  shapes  including  circular  and  rectangular  As  water  rises  withm  the  tubes,  settling  solids  fall 
to  the  tube  surface.  As  the  sludge  (from  the  settled  solids)  in  the  tube  gains  weight,  it  moves  down  the  tubes  and  settles  to  the 
bottom  of  the  basin  for  removal  by  conventional  sludge  collection  means  Tube  settlers  are  sometimes  installed  m 
sedimentation  basins  and  clarifiers  to  improve  part''*le  removal. 

TUBERCLE  (TOO-burr-cull)  TUBERCLE 
A  protective  crust  of  corrosion  products  (rust)  which  builds  up  over  a  pit  caused  by  the  loss  of  metal  due  to  corrosion. 

ERIC 

663 


Words  645 


TUBERCULATION  (too-BURR-que-LAY-shun)  TUBERCULATION 
The  development  or  formation  of  smali  mounds  of  corrosion  products  (rust)  on  the  inside  of  iron  pipe  These  mounds 
(tubercules)  increase  the  roughness  of  the  inside  of  the  pipe  thus  increasing  resistance  to  water  flow  (..icreases  the  C  Factor). 

^^^^'^  TURBID 
Having  a  cloudy  or  muddy  app-^arance. 

TURBIDIMETER  TURBIDIMETER 
C  3  TURBIDITY  METER. 

TURBIDITY  (ter-BID-it-tee)  TURBIDITY 
The  cloud/  appearance  of  water  caused  by  the  presence  of  suspended  and  colloidal  matter.  In  the  waterworks  field,  a  turbiduy 
measurement  is  used  to  indicate  the  clanty  of  water.  Technically,  turbidity  is  an  optical  property  of  the  water  based  on  the 
amount  of  light  reflected  by  suspended  particles.  Turbidity  cannot  be  directly  equated  to  suspended  so'ids  because  yvhite  par- 
tides  reflect  more  light  than  dark-colored  particles  and  many  small  particles  will  reflect  more  light  than  ?n  equivalent  larae 
particle.  »  -i  y 

TURBIDITY  METER  TURBIDITY  METER 

An  instrument  for  measuring  and  comparing  the  turbidity  of  liquids  by  passing  light  through  them  and  determining  how  much 
light  IS  reflected  by  the  particles  In  the  liquid. 

TURBIDITY  UNITS  (TU)  TURBIDITY  UNITS  (TU) 

Turbidity  units  are  a  measure  of  the  cloudiness  of  water.  If  measured  by  a  nephelometric  (deflected  light)  instrumental 
procedure,  turbidity  units  are  expressed  in  nephelometric  turbidity  units  (NTU)  or  simply  TU.  Those  turbidity  units  obtained  by 
visual  methods  are  expressed  in  Jackson  Turbidity  Units  (JTU)  which  are  a  measure  of  the  cloudiness  of  water  they  are  used 
to  indicate  the  darity  of  water.  There  is  no  real  connection  between  NTUs  and  JTUs.  The  Jackson  turbidimeter  is  a  visual  meth- 
od and  the  nephelometer  is  an  instrumental  method  based  on  deflected  light. 

TURN-DOWN  RATIO  TURN-DOWN  RATIO 

The  ratio  of  the  design  range  to  the  range  of  acceptable  accuracy  or  precision  of  an  instruir.dnt.  Also  see  EFFECTIVE  RANGE. 

UNCONSOLIDATED  FORMATION  UNCONSOLIDATED  FORMATION 

A  sediment  that  is  loosely  arranged  or  unstratified  (not  in  layers)  or  whose  part.cles  are  not  cemented  together  (soft  rock);  oc- 
curring either  at  the  ground  surface  or  at  a  depth  below  the  surface.  Also  see  CONSOLIDATED  FORMATION. 

UNIFORMITY  COEFFICIEMT  (U.C.)  UNIFORMITY  COEFFICIENT  (U.C.) 

The  ratio  of  (H '  ?  diameter  of  a  grain  (particle)  of  a  size  that  is  barely  too  large  to  pao=.  through  a  sieve  that  allows  60  percent  of 
the  material  (b\  eight)  to  pass  through,  to  (2)  the  diameter  of  a  grain  (particle)  of  a  size  that  is  barely  too  large  to  pass  throuqh 
a  sieve  that  allows  10  percent  of  the  material  (by  weight)  to  pass  through. 

, ,  .,      .  „    „           Particle  Diameter^^ 
Uniform.;/  Coefficient  =  fSlL. 

Particle  Diameter,^.^ 

VARIABLE  FREQUENCY  DRIVE  VARIABLE  FREQUENCY  DRIVE 

A  control  system  that  allows  the  frequency  of  the  current  applied  to  a  motor  to  be  varied.  The  motor  is  connected  to  a  low- 
frequency  source  while  standing  still;  the  frequency  is  then  increased  gradually  until  the  motor  and  pump  (or  other  driven  ma- 
chine) IS  at  the  desired  speed. 

VARIABLE,  MEASURED  VARIABLE,  MEASURED 

A  factor  (flow,  temperature)  that  is  sensed  and  quantified  (reduced  io  a  reading  of  some  kind)  by  a  primary  element  or  sensor 

VARIABLE,  PROCESS  VARIABLE,  PROCESS 

A  physical  or  chemical  quantity  which  is  usually  measured  and  controlled  in  the  operation  of  a  water  treatment  plant  or  an  in- 
dustrial plant. 

VELOCITY  HEAD  VELOCITY  HEAD 

The  energy  in  flowing  water  as  determined  by  a  vertical  height  (in  feet  or  meters)  equal  to  the  square  of  the  velocity  of  flowing 
water  divided  by  twice  the  acceleration  due  to  g-'avily  (V^/ag). 

Er|c  664 


646  Water  Treatment 


VENTURI  METER 


VENTURI  METER 


A  flow  measuring  device  placed  m  a  pipe.  The  device  consists  of  a  tubt  whose  diameter  gradually  decreases  to  a  throat  and 
then  gradually  expands  to  the  diameter  oi  the  pipe.  The  flow  is  determined  on  the  basis  of  the  differences  in  pressure  (caused 
by  different  velocity  heads)  between  the  entrance  and  throat  of  the  Venturi  meter. 


VENTURI  METER 


MANOMETER 


NOTE    Most  Venturi  meters  have  pressure  sensing  taps  rather  than  a  manometer  to  measure  the  pressure  difference.  The 
p'^stream  tap  is  the  high  pressure  tap  or  side  of  the  monometer. 


VISCOSITY  (vis-KOSS-uh-tee)  VISCOSITY 

A  property  of  water,  or  any  other  fluid,  which  resists  efforts  to  change  its  shape  or  flow.  Syrup  is  more  viscous  (has  a  higher 
viscosity)  than  water.  The  viscosity  of  water  ncreases  significantly  as  temperatures  decrease.  Motor  oil  is  rated  by  how  thick 
(visccus)  It  is:  20  weight  oil  is  considered  ralativcly  th;r.  while  50  weight  oi!  is  relatively  thick  or  viscous. 

VOID  VOID 

A  pore  or  open  space  m  rock,  soil  or  other  granular  material,  not  occupied  by  solid  matter.  The  pore  or  open  space  may  be 
occupied  by  air,  water,  or  other  gaseous  or  liquid  material.  Also  called  a  void  space  or  interstice. 

VOLATILE  (VOL-uh-tull)  VOLATILE 

A  substance  that  is  capable  of  bemg  evaporated  or  easily  changed  to  a  vapor  at  relatively  low  temperatures.  For  example,  gas- 
oline i^  a  highly  volatile  liquid. 


VOLATILE  ACIDS 


VOLATILE  ACIDS 


Acids  produced  during  digestion.  Fatty  acids  which  are  soluble  in  water  and  can  be  steam-distilled  at  atmosphenc  pressure. 
Also  called  "organic  acids."  Volatile  acids  are  commonly  reported  as  equivalent  to  acetic  acid. 

VOLATILE  LIQUIDS  VOLATILE  LIQUIDS 

Liquids  which  easily  vapoiize  or  evaporate  at  room  ♦emperatures. 

VOLATILE  SOLIDS 

Those  solids  in  water  or  other  liquids  that  are  lost  on  ignition  of  the  dry  solids  at  550**C. 
VOLTAGE 

The  electrical  pressure  available  to  cause  a  flow  of  current  (amperage)  when  an  electrical  circuit  is  closed.  See  ELECThOMO- 
TIVE  FORCE  (E.M.F.). 


VOLATILE  SOLIDS 


VOLTAGE 


VOLUMFTRIC 


VOLUMETRIC 


A  measurement  based  on  the  volume  of  some  'actor.  Volumetric  titration  is  a  means  o<  measuring  unknown  concentrations  of 
water  quality  indicators  in  a  sample  by  determining  the  volume  of  titrant  or  liquid  reagent  needed  to  complete  particular  reac- 
tions. 

VOLUMETRIC  FEEDER  VOLUMETRIC  FEEDER 

A  dry  chemical  feeder  which  delivers  a  measu»'ed  volume  of  chemical  during  a  r>pecific  time  period. 

VORTEX  VORTEX 

A  revolving  mass  of  water  which  forms  a  whirlpool.  This  whirlpool  is  caused  by  water  flowing  out  of  a  stmH  opening  in  the  bot- 
tom of  a  basin  or  reservoir.  A  funnel-shaped  opening  is  created  downward  from  the  water  surface. 


WASTEWATER 


WASTEWATER 


The  used  water  and  solids  froin  a  commun,^,'  (including  used  water  from  industrial  proc^=»sses)  that  flow  to  a  treatment  plant. 
Storm  water,  surface  water,  and  groundwater  infiltration  also  may  be  included  in  the  wastewater  ihat  enters  a  wastewater  treat- 
ment plant  The  term  "sewage"  usually  refers  to  household  wastes,  but  this  word  is  being  isplaced  by  the  term  "wastewater." 


ERLC 


665 


Words  647 


WATER  HAMMER  WATf.R  HAMMER 

The  sound  like  someone  hammering  on  a  pipe  that  occurs  v  hen  a  valve 's  opened  or  ciosed  very  rapidly.  When  a  valve  position 
IS  changed  quickly,  the  water  pressure  in  a  pipe  v/ill  increase  and  decrease  back  and  forth  very  quickly.  This  rise  and  fall  in 
pressures  can  do  serious  damage  to  the  system. 

WATER  PURVEYOR  (purr-VAY-or)  WATER  PURVEYOR 

An  agency  or  person  that  supplies  water  (usually  potable  water). 

WATER  TABLE  WATER  TABLE 

The  upper  surface  of  the  zone  of  saturation  of  groundwater  in  an  unconfined  aquifier. 

WATT  ^^jj 

A  unit  of  power  equal  to  one  joule  per  second  The  power  of  a  current  of  one  ampere  flowing  across  a  potential  differenr-^  of 
one  volt. 

WEIR(weer) 

(1)  A  wall  or  plate  placed  in  an  open  channel  and  used  to  measure  the  ^low  of  water.  The  depth  of  the  ''low  over  the  weir  can  be 
used  to  calculate  the  flow  rate,  or  a  chart  or  conversion  table  may  be  used. 

(2)  A  wall  or  obstruction  used  to  control  flow  (from  settling  tanks  and  clarifisrs)  to  assure  un-form  flow  rate  and  avoid  short- 
circuiting. 

WEIR  DIAMETER  (weer)  VVEIR  DIAMETER 

Many  circular  clanfiers  have  a  circular  weir  within  the  outside  edge  ^amcter 

of  tiie  clarlfier.  A||  the  water  leaving  the  clarifier  flows  over  this  weir.  ^—t^^T  ojamcter 

The  diameter  .  the  weir  is  the  length  o";  a  line  from  one  edge  of  a   3 

weir  to  the  opposite  edge  and  passing  through  the  center  of  the    ^ 

circle  formed  by  the  weir.  top  vi£w  cmTsicim 


WEIR  LOADING  VVEIR  LOADING 

A  guideline  used  to  determine  the  length  of  weir  needed  on  settling  tanks  and  clanfiers  -n  treatment  :)lants.  Used  by  operators 
to  determine  if  weirs  are  hydraulically  (flow)  overloaded. 

Weir  Loading,  GPM/ft  ^'Q^- 

Length  of  Weir,  ft 

WELL  LOG  VVELL  LOG 

A  record  of  the  thick -ess  and  characteristics  of  the  soi:.  rock  ancJ  water-bearing  formations  encountered  durinq  the  drillinq 
(sinking)  of  a  well.  ^  ^ 

WETCKEMISTRY  WET  CHEMISTRY 

Labor  jtory  procedures  used  to  analyzs  a  sample  of  water  using  liquid  chemical  solutions  (wet)  instead  of,  or  m  addition  to  lab- 
oratoi  y  instruments. 

WHOLESOME  WATER  WHOLESOME  WATER 

A  water  that  is  safe  and  palatable  for  human  consumption. 

WIRE-TO-WATER  EFFICIENCY  WIRE-TO-W/TER  EFFICIENCY 

The  efficiency  of  a  pump  and  motor  together.  Also  called  the  OVERALL  EFFICIENCY. 

YIELD  YIELD 
The  quantity  of  water  (expressed  as  a  rate  of  flow  —  GPM,  GPH.  GPD,  or  total  quantity  per  year)  that  can  be  collected  for  a 
given  use  from  surface  or  groundwater  sources.  The  yield  may  vary  with  the  use  proposed,  with  the  plan  of  development,  and 
also  vv'th  economic  considerations.  Also  see  SAFE  YIELD. 

ZEOLITE  2E0LITE 
A  type  of  ion  exchange  material  used  to  soften  water.  Natural  zeolites  are  siliceous  compounds  (made  of  silica)  which  remove 
calcium  and  magnesium  from  hard  water  and  replace  them  with  sodium.  Synthetic  or  organic  zeolites  are  ion  exchange  materi- 
als which  remove  calcium  or  magnesium  and  replace  them  w.th  either  sodium  or  hvdroaen 

668 


648  Water  Treatment 


ZETA  POTENTIAL  ZETA  POTENTIAL 

In  coagulation  and  flocculation  procedures,  the  difference  in  the  electrical  charge  between  the  dense  layer  of  ions  surrounding 
the  particle  and  the  charge  of  the  bulk  of  the  suspended  fluid  surrounding  this  particle.  The  zeta  potential  is  usually  measured  in 
millivolts. 

ZONE  OF  AERATION  ZONE  OF  AERATION 

The  comparatively  dry  soil  or  rock  located  between  the  ground  surface  and  the  top  of  the  water  table. 

ZONE  OF  SATURATION  ZONE  OF  SATURATION 

The  soil  or  rock  located  below  the  top  of  the  groundwater  table.  By  definition,  the  zone  of  saturation  is  saturated  with  water. 
Also  see  WATER  TABLE. 

ZOOPLANKTON  (ZOE-PUNK-ton)  ZOOPlANKTON 
Small,  usually  microscopic  animals  (such  as  protozoans),  found  in  lakes  and  ''eservoirs. 


ERIC 


667 


SUBJECT  INDEX 


A 

ABC.  549 

Accident 

prevention.  425 
reports.  395-397,  4?5.  436 
Accuracy,  instrumentation,  343 
Acetic  acid  (glacial),  402 
Acid  feed  systems.  37. 157 
Acids 

chemical  handling.  402 
safety.  402 
Activated  carbon.  125. 126. 129.  414 
Additional  reading.  21.  58.  106.  130.  173.  322.  380.  437 
Administration 
ABC,  549 
budgeting.  539 
certification,  549 
complaints.  551 
consumer  complaints.  551 
contaminated  water  supplies.  553 
contingency  planning.  552 
continuing  education.  548 
disposition  of  plant  records.  545 
enc-ergencies.  552 
employee  pride.  549 
interviews.  550 
line  organization.  546 
mass  media.  550 
newspapers.  550 
offjce  procedures.  539 
operator  certification.  549 
organization  procedures,  545 
people.  548 
planning.  539 

planning  for  emergencies.  552 
plant  tours.  551 
pride,  employee.  549 
procurement  of  materials.  541.  542 
public  relations.  549 
public  speaking.  550 
purchase  order.  541. 542 
radio.  550 
rates,  water.  54C 
recognition.  549 
records,  plant.  543.  544 
staff.  546 
staffing.  547 
supervision.  647 
te!eviston.  550 
tours.  551 
training.  548 
water  rates.  540 
Adsorption.  125. 126 
Adverse  effects 
>^  hardness.  71 


iron  and  manganese.  6 
Aeration 

iron  and  manganese.  12. 13. 17 

trihalomethanes.  124-127. 129 
Aii  cooled  engines.  311 
Air  release  assembly.  102 
Air  supply  systems.  371.  373 
Air  temperatures,  fluoridation.  29 
Alarms 

fluoridation.  44 

instrumentation.  367.  3b8 

reverse  osmosis.  157 
Algae  counts.  449 

Alignment.  p'«mps.  253.  271.  278-280 
Alkalinity,  sof,    ^ng.  71 .  73.  74.  82 
Alternating  current  (A.C  ^  223 
Alum.  413 
Alum  sludge.  200 
Aluminum  sulfate.  413 
Amendments  to  SDWA.  494-496 
Ammeter.  227.  228 
Ammonia.  406 
Amplitude.  223 
Amps.  224 

Analog.  343.  363.  364 
Analysis 

also  see  Laboratory  test  procedures 

iron  and  manganese.  7.  8 
Annunciator  panels.  367.  368 
Aquifer.  9 

Arch,  chemicals,  402 

Arithmetic  assignment.  21.  58. 106. 130. 173.  322.  435 
Arsenic.  503 

Atmospheres,  explosive.  432 
Autoclaves.  432 
Automatic 

controller.  368 

valves.  305 
Auxiliary  electrical  power.  244.  245 


B 

Backfiow.  13 
Backsiphonage.  21 
Backwash,  ion  exchange.  95. 100 
Backwash  recovery  ponds.  187 
Backwash  wastewater.  200 
Bacteria 

Iron  and  manganese.  6.  7.  21 

regulations.  499 
Barium.  503 
Bases 

chemical  handling.  405 

safety.  405 

668 


650  Water  Treatment 


Bases 

chemical  handling,  405 

safety,  405 
Batch  systenfis  ^7,  38 
Batteries,  223,  245 

Bearings,  punfip,  253,  258,  259,  271,  273 

Beer's  Law,  448 

Belt  drives,  pumps,  274,  277 

Belt  filter  presses,  186,  191,  194 

Belts,  compressors,  289 

Bench  scale  tests 

iron  and  manganese,  13,  20 

trihalomethanes,  124,  126,  128 
Benefits,  softening,  71,  75 
Blending,  ion  exchange,  105 
Blown  fluse,  227 
Blue  baby,  499 

Booster  shots,  immunization,  431 
Brackish  water,  141,  142 
Breakers,  circuit,  224,  230 
Breakpoint  chlorination,  14 
Brine 

disposal,  d'jmineralization,  142 

disposal,  process  wastas,  184,  185,  195,  200 

electrodlalysis,  163 

ion  exchange,  96-98,  100 

reverse  osmosis,  157,  161 
Bromide,  119,  123,  124 
Bubbler  tube,  352,  354 
Budgeting,  539,  540 
Buildings,  maintenance,  321,  322 
Butterfly  valves,  292,  295 
Bypass,  ion  exchange,  105,  106 
By-products,  disinfection,  496 

C 

Cadmium,  503 

Calcium  carbonate  equivalent,  71,  72 
Calcium  carbonate  stability  test,  466 
Calcium  test  procedures,  450 
Calculations 

chemical  feeders,  319,  320 

fluoridation,  54-58 

ion  exchange  softening,  101-105 

lime-soda  ash  softening,  77,  85-90 

reverse  osmosis,  146,  ''47,  151 

trihalomethanes,  122 
Calibration 

chemical  feeders,  317,  318 

instrumentation,  343,  374 
Caibon  dioxide,  76,  82,  410,  416 
Carbonate  hardness,  71 
Cartridge  filters,  157,  168,  171 
Casing,  pumps,  254,  253,  259 
Cathodic  protection,  321 
Caustic  soda,  407 
Caustic  soda  softening,  71,  81 
Cavitation,  pumps,  256,  257 
Centrifugal  pumps,  249,  257,  284,  285 
Centnfuges,  186,  191,  195-197 
Certification,  549 
Chain  drives,  pumps,  277 
Charts 

circular,  364-367,  377 

fluoridation,  45-47 

strip.  364-367,  377 
Check  sampling,  513 
Check  valves,  271.  273,  296  305 
Chelating  agent,  S10 

ERLC 


Chemical  feeders 

acid  feed  systems,  37 
batch  systems,  37,  38 
calculating  doses,  54-58 
calculations,  319,  320 
calibration,  317,  318 
chemical  storage,  316 
chlorinators,  320 
day  tank,  38,  40 
diaphragm  pumps,  31 
dose,  317-319 
drainage,  317 
dry  chemical,  317 
dry  feeders,  31,  37,  53 
electronic  pumps,  31,  33,  45 
feed  rate,  317-320 
gas,  317 

gravimetric  feeders,  31,  36 
instrumentation,  360 
liquid,  317 

maintenance.  20,  52,  316 
metering,  317 
operation,  44 

peristaltic  pumps,  31,  32,  45 
positive  displacement  pumps,  31 
saturators,  38,  39,  41,  53 
shutdown,  52 
solid,  317 

solution  feeders,  31,  37 
solution  preparation,  45 
startup,  44 

storage,  chemical,  316 
volumetric  feeders,  31,  34,  35,  37 

Chemical  flush  system,  168 
Chemical  handling 

acetic  acid  (glacial),  402 

acids,  402 

activated  carbon,  414 
alum,  413 

aluminum  sulfate,  413 
ammonia,  406 
bases,  405 

calcium  hydroxide,  406 
carbon  dioxide,  416 
caustic  soda,  407 
chlorine,  408 
Chlorine  Manual,  410 
drams,  415 
ferric  chlonde,  413 
ferric  sulfate,  413 
ferrous  sulfate,  413 
fluoride  compounds,  413 
gas-detection  equipment,  421 
gas  mask,  409-411 
gases,  408 

hydrochloric  acid,  403 
hydrofluoric  acid,  403 
hydrofluosilicic  acid,  402 
hypochlorite,  407 
muriatic  acid,  403 
nitric  acid,  405 

potassium  permanganate,  414 
powdered  activated  carbon,  414 
powders,  414 
safety,  402,  431 
safety  shower,  403,  404 
salts,  412 

self-contained  breathing  apparatus,  409-411 
sodium  aluminate,  413 


Index  651 


sodium  carbonate,  408 

sodium  hydroxide  407 

sodium  silicate,  407 

storage.  316 

sulfur  dioxide.  412 

sulfuric  acid.  405 
Chemical  metering  pumps.  258 
Chemical  reactions,  lime-soda  ash  softening.  75-77 
Chemical  storage.  316.  415 
Chemicals,  labc  atory.  431 
Chemistry 

softening.  72 

trihalomethanes.  119. 123 
CHEMTREC  (800)  424-9300.  220 
Chloramination,  506 
Chloramines,  128.  129 
Chloride 

regulations,  509 

test  procedures.  451 
Chlorination 

iron  and  mangatiese.  9-14, 17.  20 

reverse  osmosis,  157 
Chlorinators,  320,  321 
Chlorine,  119,  123,  124,  126.  129.  408 
Chlorine  dioxide,  124, 125.  128.  129 
Chlorine  Manual,  410 
Chlorine  residual  substitution,  506,  523 
"Christmas  Tree"  arrangement,  151,  152 
Chromium.  503 
Circuit  breakers,  224,  230 
Circuits,  223.  225 
Circular  charts,  364-367,  377 
Classification,  fire  protection,  417 
Cleaning 

membranes.  161 

safety,  420 

stacks,  168 

tanks,  185,  187 
Coagulants,  82 

Coagulation/sedimentation/filtration,  124,  126,  129 

Code  requirements,  fuel  storage.  315 

Conform  rule,  506,  507 

Conforms,  498,  506,  533 

Collecting  samples.  7,  515 

Collection  of  sludges.  184 

Collection  systems,  wastewater,  195.  200 

Colloidal  suspensions.  6 

Colloids,  156 

Color 

iron  and  manganese,  6 

regulations.  509 

removal,  82 

test  procedures,  453 
Community  water  systems.  498,  499 
Comparator,  pocket,  448 
Complaints,  551 
Compliance  schedule.  496 
Compounds,  fluoride,  29,  30,  53 
Compressors 

belts,  289 

controls,  289 

drain,  289 

filter,  287 

fins,  288 

lubrication,  288 

maintenance,  287 

types.  287 

unloader,  288 

use,  287 

ERIC 


valves.  289 
Concentration  of  sludges.  186 
Concentration  polarization.  151 
Concrete  tanks.  321 
Conditioning  of  sludges.  185 
Conductors.  225 
Confined  spaces.  187.  348 
Consumer  complaints.  551 
Contaminated  water  supplies 
contamination,  553-555 
countermeasures,  554 
effective  dosages,  554 
emergency  treatment.  555 
leth Jl  dose  50  (LD  50),  554 
maxiniuiK  allowable  concentration  (MAC).  554 
protective  nit^asures,  554 
response,  555 
toxicity.  553 

treatment,  emergency,  555 
Contingency  planning,  552 
Continuing  education,  548 
Control 

iron  and  manganese.  6.  9 
loop.  344 
panels,  429 
pumps.  273 
systems.  342-347,  377 
trihalomethanes.  124 
Controllers.  343-345.  368 
Controls 

compressors.  289 
panels.  429 
systems.  342-347,  377 
Coding  systems,  engines.  311.  313-315 
Copper,  510 
Corrosivity,  510 
Couplings.  253,  278-280 
Cranes,  420 
Crenothrix,  51 1 
Cross-connection,  265 
Current,  electrical,  223,  225,  228,  428 
Cuveue,  448 
Cycle,  electncal.  223 

D 

Dall  tube.  358 
Dateometer,  274 
Day  tank,  38,  40 
Decant,  1 87 
Dechlorination,  13 
D6jcibel,  422 
Demineralization 

also  see  Electrodialysis 
and  Reverse  osmosis 
brackish  water,  141,  142 
bnne  disposal,  142 
distillation,  142,  143 
electrodialysis,  142, 143, 163 
feedwater,  142 
freezing,  142,  143 
ion  exchange,  142,  143 
mineralized  waters.  141 
processes.  142, 143 
reverse  osmosis.  142.  143 
salinity,  142 
sea  watei,  142 
total  dissolved  solids.  141 
Desiccant,  378 
Desiccation,  371 

670 


652  Water  Treatment 


Design  review 

electrodialysis.  168 

fluoridation.  42 
Dewatering  of  sludges.  184,  186,  190 
Dial  indicators.  280.  281 
Diaphragm  operated  valves,  305,  306 
Diaphragm  pumps.  31 
Diarrhea,  travelers,"  499 
Diesel 

engines.  309.  310 

fuel  storage.  315 
DifferentiaNpressure  sensing.  356.  358.  359 
Digital,  343.  363-365 
Direct  current  (D.C.).  223 
Direct  current,  electrodialysiJ.  165.  166.  168.  171 
Dirty  water 

iron  and  manganese.  6 

red  water.  21 
Disinfection  alternatives,  128 
Disinfection  by-products,  496 
Disposal  of 

sluc'jjes.  179,  184-186.  196 

spent  brine,  98. 1"^*^.  184-186. 195 
Disposition  of  plant  records,  545 
Dissolved  oxygen  test  procedures,  454 
Distillation,  142,  143 
Divalent.  7.  70 
DO  samples,  457.  458 
DO  saturation  table.  457 
Dose,  chemical  feeders.  317-319 
Downflow  saturators.  38,  41 
Drainage  waters,  plant.  202 
Draining  tanks.  185.  187.  188 
Drains 

chemical  feeders.  317 

chemical  handling,  415 

compressors.  289 
Drinking  wp.tar  regulations 

see  Regulations,  drinking  water 
Driving  equipment,  pumps,  282 
Drowning,  434 

Dry  chemical  feeders,  31,  37,  53.  317 

Drying  beds.  190-193.  200 

Dust,  fluoridation.  53 

Dy  amic  types  of  pumps.  250 


Eccentric  valves.  292-294 
Effects  of 

iron  and  manganese,  6 

trihalomethanes.  119 
Electric  motors,  234-241 ,  274-276 
Electrical  equipment 

additional  reading.  2^7,  248 

alternating  current  (A.C).  223 

ammeter,  227,  228 

amplitude,  223 

amps.  224 

auxiliary  electrical  power.  244,  245 

batteries.  223,  245 

beware.  220 

blown  fuse.  227 

breakers.  224.  230 

circuit  breakers.  224.  230 

circuits,  223.  225 

conductors,  225 

control  panels.  429 

controls.  282 


current.  223,  225.  228.  428 
cycle.  223 

direct  current  (D.C.).  223 
electri;:  motors.  234-241 
electromotive  force  (E.M.F.).  2^11 
emergency  lighting.  245.  246 
fundamentals,  221 
fuse  puller.  226 
fuses. 223.  226.  22'.  230 
ground  231 

ground  fault  interrupter  (G.F.L).  429 
hazards.  221 
hertz.  223 

instrumentation.  429 
insulation,  motors,  234 
insulation  resistance.  229 
insulators,  225 
kirk-key.  245 

lighting,  emergency.  245.  246 

(imitations,  221 

magnetic  starters,  231-233 

mair/enance.  220.  274 

megger,  229 

megohm,  229 

meters,  electrical,  225 

motor  insulation,  234 

motor  starters,  231 ,  428 

motors,  223,  234-241,  274,  428 

name  plate,  234.  236 

ohm,  224 

ohm  meters,  230 

Ohm's  Law,  224 

overload  relays.  231 

panels,  control.  429 

phase.  223 

power  requirements,  225 

protection  devices,  230 

recordkeeping,  236,  242,  243 

safety,  221,247,  428 

standby  power  generation,  244,  245 

starters,  231,  428 

switch  gear,  230,  246 

switches.  223 

tag.  warning.  222 

testers,  225 

thermal  overloads.  231 

transformers.  223,  246,  247,  428 

transmission,  246 

troubleshooting.  234,  237-241 

voltage  testing,  225.  227,  428 

volts,  221 ,  223,  225,  246 

warning  tag,  222 

watts.  224 
Electrical  \u  ^ards,  345 
Electrode  tab,  171 
Electrodialysis 

also  see  Demineralization 
and  Reverse  osmosis 

additional  reading,  173 

advantages,  163 

?rithmetic  assignment,  173 

brine,  163 

cartridge  filters,  168, 171 
chemical  flush  system,  168 
cleaning  stacks,  168 
description,  163, 164 
design,  168 

direct  current,  165, 166. 168.  171 
electrode  tab.  171 


ERLC 


67i 


electrodialysis  polarity  reversal  (EDR),  165,  168 

energy  requirements,  163 

feedwater  quality,  171 

flow  diagram,  168-170 

touting.  164 

Langelier  Index,  164 

log  sheet,  172 

membranes,  163-168,  173 

multi-compartment  units,  165,  167 

operation.  168.  171 

piping.  168 

pH. 171 

power  supply,  168 

pressures,  168 

pretreatment,  168 

principles,  165 

pumping  equipment,  168 

recordkeeping,  172 

safety,  171, 173 

scaling,  164,  171 

specifications,  168 

stack.  1C4, 168,  171 

stages,  164 

temperature,  168 
Electrodialysis  polarity  reversal  (EDR),  165,  168 
Electrolyte,  245 

Electromotive  force  (E.M.R).  221 
Electronic  chemical  pumps,  31,  33.  45 
Elements,  instrumentation,  363 
Emergencies 

administration,  552 

phone  numbers,  220 

preparation  for,  435 

procedures.  220,  552 

safety.  435 

team.  220 
Emergency 

lighting,  245,  246 

treatment,  555 
Employee  pride,  549 
End  bells.  234 
Endemic,  29 

Energy  requirements,  electrodialysis,  163 
Enforcement,  regulations,  509 
Engines 

air  cooled,  311 

cooling  systems,  311,  313-315 
diesel.  309.  310 
fuel  storage.  315 
fuel  system.  311-313 
gasoline.  307 
governor.  311 
lubrication.  307 
maintenance,  307.  31 1 
operation,  diesel,  309 
problems.  307 
running.  307 
standby.  316 
starting.  307-309.  31 1 
trouDleshooting.  307.  311.  3l3 
water  cooled.  311 
Equipment 

gas  detection,  421 
lab  safety,  431 
records,  545 
safety,  432 

service  card,  218.219 
Equivalent  weight,  72 
Establishment,  regulations,  498 


Ester.  147 

Explosive  atmospheres.  432.  433 
Extinguishers,  fire,  417-419 
Eye  protection.  433 

F 

Falls,  injury.  348 
Feasibility  analysis  process,  121 
Feed  rate,  chemical.  317-320 
Feedback,  instrumentation.  344 
Feeders,  chemical 

see  Chemical  feeders 
Feedwater 

demineraliza{;on.  142 

electrodialysis.  171 

reverse  osmosis.  161 
Federal  Register.  119.  129 
Ferric  chloride.  413 
Ferric  sulfate.  413 
Ferrous  sulfate.  413 
Filter  backwash  wastewater.  200 
Filter,  compressor.  287 
Filter  presses,  186.  195.  198 
Filtration,  iron  and  manganese.  13.  14.  16-20 
Fins,  compressors.  288 
Fire  prevention.  417 
Fire  protection 

classification.  417 

extinguishers.  417-419 

flammable  storage.  419 

hoses.  418 

prevention.  417 

storage,  flammables,  419 
First  aid 

equipment,  432 

fluoride,  53 

safety,  395 
Flammable  storage,  419 
Flanges,  pumps,  253 
Floats,  level,  349,  352,  353 

Flow  measurement 
Dail  tube,  358 

differential-pressure  sensing.  356.  358.  359 

magnetic.  356 

orifice,  358,  359 

positive  displacement.  356 

propeller  meter.  356-358 

rate  of  flow.  356 

rotameter.  355.  356 

service  meters.  356 

ultrasonic.  356 

velocity  sensing.  356.  357 

ventun.  358.  359 
Fluoride,  regulations,  503 
Fluoridation 

additional  reading,  58 

air  temperatures.  29 

alarms.  44 

anthmetic  assignment.  58 
batch  mix.  38 
calculating  doses.  54-58 
charts.  45-47 
chemical  feeders.  31-42 

(also  see  Chemical  feeders) 
compounds.  29.  30.  53.  413 
day  tank.  38.  40 
design  review.  42 
downflow  saturators.  38.  41 


v  672 


654  Water  Treatment 


Fluoridation  (continued) 
dust ,  63 

first  aid.  fluoride,  03 
fluoride  lOn,  29 

hydrofluosilicic  ?cid,  29,  30,  42,  43,  45,  49 
importance,  29 

Interim  Pnmary  Drinking  Water  Regulations,  29 
levels,  29 

log  sheets,  44,  45,  49-51 
maintenance,  52 

maximum  contaminant  level  (MCL),  29 

operation,  44 

optimum  level,  29 

overfeeding,  42,  48 

poisoning,  fluoride,  53 

programs,  29 

public  notification,  48 

records,  44,  45,  49-51 

safety,  53,  54 

safety  equipment,  44,  53,  54 

sanitary  defects,  52 

saturator,  38,39,  41,  53 

shutdown,  52 

sodium  fluoride,  29, 30,  38 

sodium  silicofluoride,  29,  30,  48,  50 

solution  preparation,  45 

specification  revievi/,  42 

startup,  44 

systems,  30,  37 

training,  54 

treatment  charts,  45-47 
underfeeding,  48 
upflow  saturators,  38,  39,  41 
Fluoride 

compounds,  413 
ion,  29 

test  procedures,  457 
Flux  decline,  146 
Flux,  reveise  osmosis,  145, 146 
Foaming  agents,  510 
Foot  protection,  433 
Foot  valves,  271,  296 
Forklifts.  425 

Formation  of  THMs,  119,  123,  124, 126 
Fouling,  electrodialysis,  164 
Freezing,  demineralization,  142,  143 
Frequency  of  sampling,  514,  533 
Fuel  storage 

code  requirements,  315 

diesel,  315 

gasoline,  315 

Fiquid  petroleum  gas  (LPG),  316 

natural  gas,  316 
Fuel  systems,  engines,  31 1-313 
Fueling  vehicles,  423 
Fuse 

blov\/n,  227 

puller,  226 
Fuses,  223,  226.  227,  230 


G 

Gas,  chemical  feeders,  317 
Gas-detection  equipment,  421 
Gas  masks,  409-41 1 
Gases 

chemical  handling,  408 
^  safety,  408 

ERIC 


Gasoline 

engines,  307 

fuel  storage,  315 
Gate  valves,  2:89,  290 
GFl  (ground  fault  interrupter),  429 
Giardia,  497,  607 
Glassv/are,  laboratory  sr.rety,  429 
Globe  valves,  292,  305,  306 
Gloves,  434 
Governor,  engines,  311 
Gravimetric  chemical  feeders,  31.  36 
Greensand,  iron  and  manganese,  14,  16-20 
Ground,  electncal,  231 
Ground  fault  interrupter  (G.F.I.),  429 
Group  1  and  2  THM  treatment  techniques,  129 

H 

Hand  protection,  434 
Handling  of  chemicals 

see  Chemical  handling 
Handling  proces^  wastes,  179,  18t) 
Hard  hat,  434 
Hard  water,  70 
Hardness,  70-72,  75,  76,  505 
Hardness  leakage,  101 
Hazardous  gases,  421 
Hazards 

drowning,  434 

electrical,  221,  345 

gases,  421 

instrumentation,  345-348 

laboratory,  429 

maintenance,  420 

mechanical,  347 
Head  protection,  434 
Health  effects 

iron  and  manganese,  6 

trihalomethanes,  119 

VOCs,  504,  505 
Health  regulations,  498,  499 
Hartz,  223,  369 

History  of  drinking  water  laws,  493 

Hollow  fine  fiber,  reverse  osmosis,  153,  155 

Horizontal  centrifugal  pumps,  257 

Hoses,  fire,  418 

Hot  plates,  431 

Human  factors,  safety,  400 

Hydrated  lime,  76,  406 

Hydrochloric  acid,  403 

Hydrofluoric  acid,  403 

Hydrofluosilicic  l  cid,  29,  30,  42,  43,  45,  49,  402,  403 
Hydrogen  sulfide,  r05 
Hyd-olysis,  147,  150,  157 
Hygroscopic,  316 
Hypochlorite,  407 

I 

Immeaiate  threats  to  health,  499 
Immunization,  shots,  431 
Impeller,  pumps,  249,  251,  258,  259 
Indicators,  instruments,  363 
Initial  sampling,  51? 

Inorganic  chemicals,  regulations,  501,  502,  516 
Inspection  of 

pumps,  286 

tanks,  321 
Instrumentation 

accuracy,  343 


^  673 


index  655 


air  supply  systems.  371,  373 
alarms,  367,  368 
analog,  343,  363,  364 
annunciator  panels,  367,  368 
automatic  controller,  368 
bubbler  tube,  352,  354 
calibration,  343,  374 
categories,  363 

charts,  strip  and  circular,  364-367,  377 

chemical  feed,  360 

circular  chart,  364-367,  377 

confined  spaces,  348 

control  loop,  344 

control  systems,  342-347,  377 

controllers,  343-345,  368 

differential  pressure  sensing,  356,  358,  359 

digital,  343,  363-365 

electrical  equipment.  429 

electrical  hazards,  345 

elements,  363 

feedback,  344 

floats,  349,  352,  353 

flow,  356-360 

hazards,  345-348 

importance,  342 

Indicators,  363 

integrator,  367 

laboratory,  374,  375 

level  sensing,  349,  352-354 

magnetic  flow  sensing,  356 

maintenance,  375,  379,  380 

measurement,  342,  348,  363,  377 

mechanical  hazards,  347 

motor  control  station,  345-347 

multi-meter,  374 

"on-off  controls,  368 

operation,  375,  379 

panel,  343,  363 

pH,  360,  361,  374 

phone  lines,  369,  372 

pneumatic  systems,  360,  362,  367,  374,  378 

precision,  343 

pressure  sensing,  349-351 

probes,  352,  353 

process  control,  368 

proportional  control,  368 

pump  controllers,  368-371 

rate  of  flow,  356 

recorders,  363-367,  377 

records,  379 

rotameters,  355,  356,  360 
safety,  345,  429 
sensors,  348 
shutdown.  378,  379 
signal  transmitters,  360 
snubber,  349,  351 
standardization,  343 
startup,  378,  379 
strip  chart,  364,  366,  367,  377 
surge  protection,  349,  351 
symbols,  339-341 
telemetering,  360,  369,  372 
testing,  374 
total  flow,  356 
totalizers,  365-367 
t'-ansducers,  C57,  360 
transmitters,  348,  357,  360 
troubleshooting.  376,  378 
turbidimeter,  360,  361,  374 

ERLC 


ultrasonic  flow  sensing,  356 
vaults,  348 

velocity  sensing,  356,  357 

VOM,  374,  376 
Insoluble  compounds,  6 
Insulation,  motors,  234 
Insulation,  resistance,  229 
Insulators,  225 
Integrator,  instrument,  367 
Interim  Primary  Drinking  Water  Standards 

arsenic,  503 

bacteria,  499 

barium,  503 

cadmium,  503 

chromium,  503 

establishment,  498 

fluoride,  503 

immediate  threats  to  health,  499 
lead,  503 

long-term  threats  to  health,  499 
mercury,  503 

National  Drinking  Water  Advisory  Council,  498 
nitrate.  499,  517 
radioactivity,  507 
regulations.  29.  498 

selenium,  503 

silver,  503 
Internal  combustion  engines 

see  Engines 
Interviews,  550 
Inventory,  544 
Ion  exchange 

demineralization,  142,  143 

iron  and  manganese,  11 

softeners,  99 

trihalomethanes,  125,  126 

wastes,  200 
Ion  exchange  resin,  11,  125.  126 
Ion  exchange  softening 

also  see  Lime-soda  ash  softening 
and  Softening 

air  release  assembly,  102 

backwash,  95, 100 

blending,  105 

brine,  96-98,  100 

bypass,  105,  106 

calculations,  101-105 

description  of  process,  91  94 

disposal  of  spent  brine,  98 

hardness  leakage,  101 

iron  and  manganese  problems,  97,  93,  100 

limitations,  72 

maintenance,  99 

monitoring,  97,  98 

operation,  96,  97 

recordkeeping,  106 

resin,  91,  94,  95 

rinse,  96,  97,  100 

salt  solution  characteristics,  103 

sanitary  defects,  brine  storage  tanks,  99 

service,  95,  96, 100 

shutdown,  101 

split  treatment,  105 

startup,  101 

testing,  97 

tro'')leshootmg,  100 

wastes,  200 

zeolite,  91 


674 


6S6  Water  Treatment 


Iron  and  Manganese 
adverse  effects,  6 
aeration.  12. 13. 17 
analysis,  7,  8 
bacteria,  6,  7,  21 
bench  scale  tests,  9, 13,  20 
breakpoint  chlorination,  14 
chlorination.  9-14,  17, 20 
collecting  samples.  7 
color.  6 
control.  6.  9 
dechlorination.  13 
dirty  water,  6 
effects,  6 

filtration.  13.  14.  17 
greensand.  14. 16-20 
health  effects,  6 
ion  exchange,  11 

ion  exchange  problems,  97,  98,  100 
limits,  6 

maintenance,  15,  20 

measurement,  6,  20 

monitoring,  15,  20 

need  to  control,  6 

objections,  6 

occurrence,  6 

operation,  16-20 

oxidation,  12,  13 

permanganate,  13, 17-19 

pH,  12,  17,  19 

phosphate  treatment,  9-11 

polyphosphate  treatment,  9-11 

problems,  ion  exchange,  97,  98,  100 

proprietary  processes,  14 

red  water  problems,  21 

regulations,  511 

reservoirs,  6 

samples.  7 

sludge  handling  and  disposal,  200 

tastes  and  odors,  6 

troubles.hooting,  21 

zeolite,  14 
Iron,  regulations,  511 
Iron  (total),  test  procedures,  461 


J 


Jar  tests,  softening,  85-90 
Jogging,  237 


K 


Kemmerer-type  sampler,  457,  458 
Kirk-key,  245 


L 

Laboratory  instrumentatioi  4.  375 
Laboratory  safety 

autoclaves,  432 

biological  considerations,  431 

booster  shots,  431 

chemicals.  431 

eauipment.  431 

O 

ERLC 


glassware,  429 
Hazards,  429 
hot  plates,  431 
immunization,  431 
pipet  washers,  4^2 
radioactivity,  431 
shots,  booster,  431 
sterilizers,  432 
water  stills,  431 
Laboratory  test  procedures 
algae  counts,  449 
calcium,  450 

calcium  carbonate  stability  test,  466 
chloride,  451 
color,  453 

dissolved  oxygen,  454 
fluoride,  457 
iron  (total),  461 
manganese,  463 
marble  test,  466 
metals,  467 
nitrate,  468 
odor,  474 
pH,  471 

specific  conductance,  471 

sulfate.  472 

taste  and  odor,  474 

total  dissolved  solids,  479 

trihalomethanes,  479 
Lagoons,  process  wastes,  187 
Landfills,  sanitary,  186, 195,  200,  201 
Langelier  Index,  73,  164 
Lead. 503 

Leakage,  hardness,  101 
Lethal  dose  50  (LD  50),  554 
Let's  Build  a  Pump.  249 
Level  controls,  282 

Level  sensing  instruments,  349,  352-354 
Library,  maintenance,  218,  220 
Lighting,  emergency,  245.  246 
Lime,  76,  82 
Lime  sludge,  200 
Lime-soda  ash  softening 

also  see  Ion  exchange  softening 
ana  Softening 

alkalinity,  82 

application  of  lime,  82 

benefits,  75 

calculation  of  dosages,  77,  85-90 
carbon  dioxide,  76,  82 
caustic  soda  softening,  77,  81 
chemical  reactions,  75-77 
coagulants,  82 
color  removal,  82 
handling  lime,  82 
hardness  removal,  76 
hydrated  lime,  76 
jar  tests,  85-90 
lime.  76,  82 

lime-soda  ash  softening,  75,  81 
lime  softening,  78,  79 
limitations.  75 
narble  test.  83 

National  Lime  Association.  82 
partial  lime  softening,  78 
permanent  hardness.  76 
polyphosphate,  78,  83 
quicklime,  76,  84 
recarbonation,  76,  78,  79.  83 


675 


Index  657 


recordkeeping,  85 
safety,  82. 84 
slake.  76.  84 
sludge,  85,  200 
split  treatment.  78-81 
stability,  73,  76.  83 
storage  of  lime.  82 
supersaturated,  76 
temporary  hardness,  76 

Lime  softening,  78.  79 
Limitations 

ion  exchange  softening.  72 

linne-soda  ash  softening.  75 

softening.  71 ,  72.  75 
Limits 

fluoride,  29 

iron  and  manganese.  6 
Une  organization,  546 
Linear  AlkyI  Benzene  Sulfonate  (LAS),  510 
Uquid  chemical  feeders,  317 
Uquid  petroleum  gas  (LPG),  316 
Location  of  sampling,  514 
Lock  out.  safety,  429.  430 
Log  sheets 

electrodialysis.  172 

fluoride,  44.  45.  49-51 

reverse  osmosis,  159, 160 
Long-term  threats  to  health,  503 
LPG  (liquid  petroleum  gas).  316 
Lubrication 

compressors,  288 

engines,  307 

maintenance,  262-264 

mechanical  equipment.  262-?64 

pumps.  253.  262-264 

valves.  291 


Magnetic  flow  measurement.  356 
Magnetic  starters,  231-233 
Maintenance 

administration,  544 

buildings.  321 . 322 

cathodic  protection.  321 

chemical  feeders.  20.  52.  316 

chlorinators.  320.  321 

cleaning,  420 

compressors,  287 

concrete  tanks.  321 

cooling  systems.  31 1,  313-315 

cranes,  420 

diesel  engines.  309.  310 
electrical  equipment.  220,  274 
engines,  307,  311 
equipment  service  card.  218.  219 
fluoridation.  52 
gasoline  engines.  307 
hazards,  420 
inspection  tanks.  321 
instrumentation.  375,  379,  380 
ion  exchange  softeners.  99 
iron  and  manganese.  15 
library.  218.  220 
lubrication.  262-264 
manholes.  421 


manuals.  218 

manufacturers.  218 

mechanical  equipment.  249 

painting.  420 

power  tools,  421 

preventive.  218 

program.  218 

pumps.  209.  265 

recordkeeping,  218,  544 

records,  218 

reservoirs,  321 

safety.  420,  423.  424 

service  record  card.  218.  219 

steel  tanks.  321 

tanks,  321 

tools,  power.  421 

valves.  289,  291.  292.  305 

vehicles,  423.  424 

welding.  422 
Manholes.  421 
Manganese 

also  see  Iron  and  manganese 

aeration.  12.  13 

limits,  6 

oxidation,  13 

regulations,  511 

test  procedures,  463 
Man-made  radioactivity,  507 
Manuals,  maintenance.  218 
Manufacturers.  218 
Marble  test,  83,  466 

Maximum  allowable  concentration,  (MAC),  554 
Maximum  Contaminant  Level  (MCL)  (primary  standards) 

chlorine  residual  substitution,  503 

fluoride,  29,  503 

inorganic  chemicals,  498,  516 

man-made  radioactivity,  507 

membrane  filter,  506 

microbiological  contaminants,  506 

multiple-tube  fermentation,  506 

natural  radioactivity,  507 

organic  chemicals,  498 

radiological  contaminants,  507 

regulations.  499,  509 

trihalomethanes,  119,  498,  526 

turbidity,  498 

types,  498 

MBAS.  510 
MCLs.  499 
Mass  media,  550 
Measurement 

instrumentation.  342.  348.  363.  377 

iron  and  manganese.  6.  20 

safety.  399 
Mechanical  equipment 

centrifugal  pumps.  249 

Let's  Build  a  Pump,  249 

lubrication.  262-264 

maintenance.  249 

pumps,  249 

repair  shop.  249 
Mechanical  seals.  271 
Megger.  229 
Megohm.  229 

Membrane  filter,  506,  519,  520 
Membranes 

electrodialysis,  163-168,  173 

reverse  osmosis,  142,  145, 146, 161 
Mercury,  503 


ERLC 


878 


658  Water  Treatment 


Metals,  test  procedures,  467 

Metering  chemical  feeders,  317 

Meters,  etectrical,  225 

Methemoglobinema,  468 

Microbiological  contaminants,  506,  519,  521*523 

Microbiological  organism  fouling,  157 

Mineral  rejection,  146-148 

Mineralized  waters,  141 

Monitoring 

ion  exchange  softening,  97,  98 

iron  and  manganese,  15,  20 

process  wastes,  183,  202 

regulations.  498 

reverse  osmosis,  159-161 

SmR.  497 

trihalomethanes,  121, 123,  128 

wastes,  183,  202 
Motor 

contro:  station,  345-347 

electrical,  223,  234-241,  274,  428 

insulation,  234 

pump,  223-241,256 

safety,  428 

starters,  231,  428 
Multi-compartment  units,  electrodialysis,  165, 167 
Multi-meter,  374 

Multiple-tube  fermentation,  506,  521 
Muriatic  acid,  403 


N 


Name  plate,  234,  236 

National  Drinking  Water  Advisory  Council,  498 
National  Electrical  Safety  Code.  162 
National  Lime  Association,  82 
National  Secondary  Drinking  Water  P.agulations 

see  Secondary  Drinking  Water  Regulations 
National  Safety  Council.  398 
Natural  gas,  316 
Natural  r:idioactlvity,  507 
Nessler  tubes,  448,  453,  461 
Newspapers,  550 
Nitrate 

regulations,  499,  517 

test  procedures,  468 
Nitiic  acid,  405 
Noise  protection,  422 
Noisy  pump,  283 

Non-community  water  systems,  498,  499 
Noncarbonate  hardness,  76 
Notification  515 
NPPES  Permit,  98, 183 

O 

Objections 

iron  and  manganese,  6 
Occurrence,  iron  and  manganese,  6 
Odor 

legulations,  511 

test  procedures,  474 
Office  procedures,  539 
Ohm,  224 
Ohm  meters,  230 
Ohm's  Law,  224 
Olfactory  fatigue,  403 
"On-cff  controls,  368 

ERIC 


Operation 

Cfiemical  feeders,  44 

diesel  engines,  309 

electrodialysis,  168,  171 

fluoridation,  44 

greensand,  19 

instrumentation,  375,  379 

ton  exchange  softeners,  95,  96 

iron  and  manganese,  16-20 

reverse  osmosis,  156-161 

safety,  394,  432 

valves,  289,  291 
Operator  certification,  549 
Operator  protection 

atmospheres,  explosive,  432 

drowning,  434 

equipment,  safety,  432 

explosive  atmospheres,  433 

eye  protection,  433 

first  aid  equipment,  432 

foot  protection,  433 

gas  detection  equipment,  421 

gloves,  434 

hand  protection.  434 

hard  hat,  434 

hazardous  gases,  421 

head  protection,  434 

noise,  422 

respiratory  protection,  409-411,  432,  433 
safety,  394.  432 
safety  equipment.  432 

self-contained  breathing  apparatus.  409-411,  432,  433 
traffic,  421 
water  safety,  434 
Optimum  level,  fluoride,  9 

Organic  chemicals,  regulations,  498,  502,  504,  605,  516 

Organization  procedures,  545,  546 

Orifice  flow  measurement,  358,  359 

OSHA.  393 

Osmosis,  1^2,  ^44 

Overfeeding  fluor'de,  42,  48 

Overload  relays.  231 

Oxidation 

iron  and  manganese.  12.  13 

trjhalomethanes.  125, 126 
Oxygen  saturation  table,  457 
Ozone,  125, 126,  128,  129 


P 

Packing 

pumps,  255,  265-269.  272 

valves,  291 
Painting,  420 
Panels 

control.  429 

instrumentation.  343,  363 
Partial  lime  softeniug,  78 
Parts,  valves,  289 
People,  548 

Peristaltic  pumps,  31,  32,  45 
Permanent  hardness,  76 
Permanganate,  potassium 
handling,  414 

iron  and  manganese,  13, 17-19 
safety,  414 

trihalomethanes,  124, 126, 129 
Permerte.  153.  157 

677 


index  659 


PH 

instrumentation.  360,  061 .  374 

regulat  ons,  512 

test  procedures.  471 
pH.  effects  on 

electrodjalysis,  171 

reverse  osmosis,  147,  150. 156, 157 

softening,  73.  74 

trihalomethanes,  123 
Phase,  electrical,  223 
Phenols.  513 
Phone  lines,  369.  372 
phosphate  treatment,  9-1 1 
Pipet  washers,  432 
Piston  pumps,  257,  259 
Planning 

administration,  539 

emergencies.  552 
Plant 

drainage  waters,  202 
maintenance,  420 
tours.  551 

Pneumatic  systems,  360,  362,  367,  374,  378 
Pocket  comparators,  448 
Poisoning,  fluoride,  53 
Pole  shader,  237 

Policy  statement,  safety,  393,  394 
Polyphosphate  treatment 

iron  and  manganese,  9-1 1 

reverse  osmosis,  156, 157 

softening,  78,  83 
Ponds,  process  wastes,  187 
Positive  displacement  flow  measurement,  356 
Positive  displacement  pumps,  31,  286 
Potassium  permanganate 

see  Permanganate 
Powdered  activated  carbon,  414 
Powders,  414 

Power  requirements,  225,  283 
Power  supply,  electrodialysis,  168 
Power  tools,  421 
Precision,  instrumentation,  343 
Precursors,  THM,  119,  123,  124,  126 
Preparation  for  emergencies,  435 
Pressure  sensing  insf^'^nentation,  349-351 
Pressures,  electrodialysis,  168 
Pretreatment 

electrodialysis.  1 68 

reverse  osmosis,  156 
Prevention  of  fires,  41 7 
Preventive  maintenance,  218,  265 
Pride,  employee.  549 
Primary  standards,  498.  501 

a!so  see  Interim  Primary  Standards 
Prime,  pumps,  282,  284 
Probes,  instrumentation,  352,  353 
Process  control  instrumentation,  368 
Process  variable,  343 
Process  wastes 

alum  sludge,  200 

backwash  recovery  ponds,  187 

backwash  wastewater,  200 

belt  f'lter  pressos,  186, 191, 194 

brine,  i  84. 185,  195,  200 

centrifuges,  186,  191,  195-197 

cleaning  tanks,  185, 187 

collectiot.  of  sludges,  184 

collection  systems,  195,  200 

concentration.  186 

conditioning,  185 

ERLC 


decant,  i87 

aewatering  of  sludges,  184-186,  190 

disposal  of  sludges  and  brines,  179. 184-186.  195 

draining  tanks,  185,  187,  188 

drying  beds,  190-193,  200 

filter  backwash  wastewater,  200 

filter  presses,  186, 195, 198 

handling,  179,  185 

ion  exchange  wastes,  200 

iron  sludge,  200 

lagoons,  187 

landfills,  186,  195,  200,  201 

lime  sludge,  200 

monitoring,  183,  202 

need  for  handling  and  disposal,  183 

NPDES  Permit,  183 

ponds,  187 

Public  Law  92-500,  183 
reporting,  202 

sand  drying  beds,  190-193,  200 
sanitary'  landfills,  186,  195,  200,  201 
sewers,  195,  200 

sludge  pumps,  202 

sludge  volumes,  184 

solar  lagoons,  187,  190 

sources,  183,  184,  186 

supernatant,  190 

tanks,  draining  and  cleaning,  185 

temperature  effects,  184 

thickening,  185.  186 

vacuum  filters,  186.  195,  199 

vacuum  tank  truck,  189,  190,  200 

volumes  of  sludges,  184 

wastewater  collection  systems,  195  200 

Water  Pollution  Control  Act,  183 
Procurement  of  materials.  541,  5^2 
Program,  maintenance.  218 
Progressive  cavity  pumps,  257-261,  273 
Propeller  meter,  356-358 
Propeller  pumps,  273 
Proportional  control  instrumentation,  368 
Proprietary  processes,  iron  and  manganese,  14 
Protection  devices,  electrical  equipment,  230 
Protective  measures,  water  supply.  554 
Prussian  blue,  291 
Public  Law  92-500,  183 
Public  notification,  fluoride,  48 
Public  relations.  549 
Public  speaking.  550 
Pumping  equipment  electrodialysis,  168 
Pump  controllers,  instrumentation,  368-371 
Pump  maintenance 

alignment,  271,  278-280 

bearings,  271,  273 

belt  drives,  274,  277 

chain  drives,  277 

check  valves,  271 ,  273.  296-305 

controls,  273 

couplings,  278-280 

dial  indicators.  280,  281 

electric  motors,  234-241,  274-276 

foot  valves,  271,  296 

mechanical  seals.  271 

packing,  265-269,  272 

preventive  maintenance,  265 

progressive  cavity  pumps,  273 

propeller  pumps.  273 

reciprocating  pumps,  272 

shear  pin.  272.  280 

shutdown,  271 

678 


660  Water  Treatment 


Pump  maintenance  (continued) 

variable  speed  belt  drives.  278 

wearing  rings.  271 
Pump  operation 

centrifugal  pumps.  284.  285 

discharge,  283 

driving  equipment  282 

electrical  controls,  282 

inspection.  286 

level  controls.  282 

noisy  pump,  283 

positive  displacement  pumps.  31.  286 

power  requirements.  283 

prime,  282,  284 

rotation,  282 

shutdown.  282.  284.  286 

starting.  282-286 

troubleshooting.  283 
Pumping  equipment,  electrodialysis,  168 
Pumps 

alignment.  253.  271.  278-280 

bearings.  253.  258,  259.  271.  273 

casing,  254,  258,  259 

cavitation,  256.  257 

centrifugal  pumps,  249-257,  284,  285 

chemical  metering,  258 

couplings,  253.  278-280 

displacement.  250 

dynamic  types.  250 

flanges,  253 

horizontal  centrifugal  pumps,  257 
impeller,  249,  251,  258,  259 
Let's  Builds  Pump,  249 
lubrication,  253.  262-264 
maintenance 

see  Pump  maintenance 
motors,  223-241,  256 
packing.  255.  265-270,  272 
piston  type,  257.  259 
progressive  cavity,  257-261 ,  273 
reciprocating,  257,  259,  272 
rings,  wearing,  254-256 
screw  flow,  257-261 
seal  255 

shaft.  251.  253,  258,  259 
sleeves.  251,253,  258,  259 
stuffing  boxes.  255 
suction,  253,  254.  256 
vertical  centrifugal  pumps,  257-259 
wearing  rings,  254-256 
Purchase  order,  541,  5^2 


Q 


Quicklime.  76.  84.  406 

R 

Radio,  550 

Radioactivity,  431,  507 
Radiological  contaminants,  507,  524,  525 
Rate  of  flow  instrumentation,  356 
Rates,  water,  542 
Recarbonation  76,  78,  79,  83 
Reciprocating  pumps.  257.  259.  272 
Recognition,  employee.  549 
Recorders,  instruments.  363-367, 377 

er|c 


Recordkeeping 

electrical  equipment  236,  242.  243 
electrodialysis,  172 
equipment,  545 
fluoridation.  44,  45,  49-51 
irstrumentation,  379 
inventory,  544 

ion  exchange  softening.  106 

lime-soda  ash  softening,  85 

maintenance,  218,  644 

plant,  543-545 

process  wastes.  202 

reverse  osmosis,  159. 160 

softening.  85 
Recovery,  reverse  osmosis.  151. 161 
Rod  water  problems.  21 
Regulations,  drinking  water 

arsenic,  503 

bacteria.  499 

barium,  503 

cadmium,  503 

check  sampling,  513 

chloride,  509 

chlorine  residual  substitution,  506.  523 
chromium,  503 
conforms,  498,  533 
color,  509 

community  water  systems,  499 
copper,  510 
corrosivity,  510 
establishment.  498 
filtration,  497 
fluoride,  503 
foaming  agents,  510 
health,  498,  499 

immediate  threats  to  health,  499 

initial  sampling,  513 

inorganic  chemicals,  498,  519 

Interim  Primary  Drinking  Water  Standards,  498 

iron,  511 

lead,  303 

long-term  threats  to  health,  498,  499 
ma<imum  contaminant  levels,  498-509 
MCLs,  499 

membrane  filter,  506,  519,  520 
mercury,  503 

microbiological  contaminants,  506,  519,  521-523 
monitoring,  497 

multiple-tube  fermentation,  506,  521 
National  Drinking  Water  Advisory  Council,  498 
natural  radioactivity,  507 
nitrate,  499,  517 

non-community  water  systems,  499 
notification,  515 
odor,  511 

organic  chemicals,  498,  516 
pH,  512 

primary  standards,  498 
radioactivity,  507 

radiological  contaminants,  507,  524,  525 

regulations,  513 

reporting  procedures,  515-526 

required  sampling,  514 

routine  sampling,  513 

Safe  Drinking  Water  Act.  513 

sampling  points,  514 

sampling  procedures,  513-515 

Secondary  Drinking  Water  Regulations.  509-515 

selenium,  503 


679 


short-term  exposure,  499 
silver,  503 
solvents,  498 
standards  498 
sulfate,  512 

total  dissolved  solids  (TDS),  512 

trihalomethanes,  498,  526 

turbidity.  498,  518.  519 

zinc.  512 
Regulatory  agencies,  safety.  393 
Rejection,  mineral,  146 
Repair  shop,  249 
Reporting  procedures.  515-526 
Reporting,  safety,  395-397,  435,  436 
Reporting,  waste  disposal,  202 
Representative  sample,  121 
Required  saiTipling,  514 
Reservoirs,  6, 321 

Resin,  Ion  exchange,  91,  94,  95. 125 
Respiratory  protection,  409-41 1,  432,  433 
Responsibilities,  safety,  393,  394 
Reverse  osmosis  (RO) 

also  see  Demineralization 
and  Electrodlalysis 

acid  feed  system,  157 

additional  reading,  173 

alarms,  157 

arithmetic  assignment,  173 
brine,  157.  161 
calculations,  146,  147,  151 
cartridge  filters.  '.57 
Chlorlnation,  157 

"Christmas  Tree"  arrangement,  151,  152 
cleaning  membrane,  161 
colloids,  156 

concentration  polarization,  151 
dGflnition,  142 
feed,  161 
flow  diagram,  158 
flux,  145,  146 
flux  decline,  146 
hollow  fine  fiber,  153,  155 
hydrolysis,  147. 150,  157 
layout,  158 
leg  sheet,  159, 160 
membrane,  142,  145,  146,  161 
microbiological  organisms,  157 
mineral  rejection,  146-148 
monitoring,  159-161 
operation,  156-161 
osmosis,  142,  144 
permeate,  153,  157 
pH  effects,  147,  150,  156,  157 
polyphosphate  treatm'^^nt,  156,  157 
pretreatment,  156 
recordkeeping,  159,  160 
recovery,  151.  161 
rejection,  mineral,  146 
safety,  162 
sealants,  156 
spiral  wound,  153,  154 
suspended  solids,  156 
temperature  effects,  147,  149, 150,  156 
threshold  treatment,  156 
troubleshooting,  161 
tubular,  153 
turbidity,  156 
types  of  plants,  153 
Rings,  wearing.  254-256 

ER?C 


Index  661 


Rmse,  lofi  exchange  softening,  96,  97, 100 
Rotameter,  355-356,  360 
Rotation  of  pump  operation,  282 
Rotor,  234 

Route,  sampling.  515 
Routine  sampling,  513 


S 


Safe  Drinking  Water  Act.  493,  494,  513 
Safety 

accident  prevention,  425 

accident  reports,  395-397,  435,  436 

acetic  acid  (glacial),  402 

acids,  402 

activated  carbon,  414 
additional  reading.  437 
alum,  413 

aluminum  sulfate,  413 
ammonia,  406 

atmospheres,  explosive,  432 
autoclaves,  432 
bases,  405 

biological  considerations,  431 
booster  shots,  431 
calcium  hydroxide,  406 
carbon  dioxide,  410 
caustic  soda,  407 
chemical  handling,  402,  431 
chemical  storage  drains,  415 
chemicals,  laboratory,  431 
chlorine,  408 
Chlorine  Manual,  410 
class'fication,  fires,  417 
cleaning.  420 
control  panels,  429 
costs,  399 
cranes,  420 
current.  428 
drains,  415 
drowning,  434 

electrical  equipment,  22:.  247,  428 
electrodlalysis,  171,  173 
emergencies,  435 
equipment,  432 

explosive  atmospheres.  432,  433 

extinguishers,  fire,  417-419 

eye  protection,  433 

ferric  chloride,  413 

ferric  sulfate,  413 

ferrous  sulfate,  413 

fire  protection,  417 

first  aid,  395 

flammable  storage,  419 

fluondation,  53.  54 

fluoride  compounds.  413 

foot  protection,  433 

forklifts,  425 

fueling  vehicles,  423 

gas  detection  equipment.  421 

gas  masks,  409-411 

gases,  408 

glassware,  429 

gloves,  434 

hand  protection,  434 

handling  chemicals,  402 

680 


662  Water  Treatment 


Safety  (continued) 
hard  hat.  434 
hazardous  gases.  421 
hazards,  laboratory,  429 
hazards,  maintenance.  420 
head  protection,  434 
hot  plates,  431 
human  factors,  400 
hydrated  lime,  406 
hydrochloric  acid,  403 
hydrofli  oric  acid,  403 
hydrofluOSilicic  arid,  403 
hypochlorite,  407 
immunization,  431 
instrumentation,  345,  429 
laboratory,  429-431 
lime-soda  ash  softening,  82,  84 
lock  out,  429,  430 
maintenance,  420,  423,  424 
manholes,  421 
measuring,  399 
motors,  428 
muriatic  acid,  403 
National  Safety  Council,  398 
nitric  acid,  405 
noise,  422 
operator,  394.  432 
OSHA.  393 
painting,  420 
panels,  control,  429 
pipet  washers,  432 
plant  maintenance,  420 
policy  statement,  393,  394 
potassium  permanganate,  414 
powdered  activated  carbon,  414 
powders.  41 4 
power  tools,  421 
quicklime.  406 
radioactivity,  431 
regulatory  agencies,  393 
reporting.  395-397,  435,  436 
respiratory  protection,  409-41 1,  432,  433 
responsibilities,  393,  394 
reverse  osnr.osis,  162 
'iafety  check,  vehicles,  423,  424 
safety  shower,  403,  404 
salts.  412 
seat  belts,  423 

self-contained  breathing  apparatus,  409-411,  432,  433 

shots,  booster,  431 

shower,  safety,  403,  404 

sodium  aluminate,  413 

sodium  carbonate,  408 

sodium  hydroxide,  407 

sodium  silicate,  407 

softening,  82,  84 

standard  operating  procedures  (SOP),  395, 429,  430,  432 

starters,  428 

sterilizers,  432 

stills,  water,  431 

storage,  chemicals,  415 

storage,  flammables,  419 

sulfur  dioxide,  412 

sulfuric  acid,  405 

supervisors,  394 

tailgate  training.  398 
tools,  power.  421 
traffic.  421 
training,  398 


transformers,  428 

underwater  inspection,  435 

unsafe  acts,  394 

utilities,  393 

valves,  422 

vehicles,  423 

voltage,  428 

water,  434 

water,  stills,  431 

welding,  422 
Safety  check,  vehicles,  423,  424 
Safety  equipment 

fluoridation,  44,  53,  54 

operator  protection,  432 

shower,  403,  404 
Safety  shower,  403,  404 
Salinity,  142 

Salt  solution  characteristics,  103 
Salts 

handling,  412 

safety,  412 
Sampling 

iron  and  manganese,  7 

points,  514 

trihalomethanes,  121,  122 
Sampling  procedures 
check  sampling,  513 
collection,  515 
frequency,  514,  533 
how  often,  514 
initial  sampling,  513 
location,  514 

number  of  samples,  coliform,  533 
required  sampling,  514 
route.  515 

routine  sampling,  513 

Safe  Drinking  Water  Regulations.  513 

sampling  points,  514 

schedule.  515 
Sand  drying  beds.  190-193,  200 
Sanitary  defects 

brine  storage  tanks,  99 

fluoridation,  52 
Sanitary  landfills,  186. 195.  200,  201 
Saturators,  fluoridation,  38,  39,  41,  53 
Scaling 

electrodialysis,  164, 171 

reverse  osmosis,  156 

Schedule 

compliance,  496 
sampling.  515 

Screw  flow  pumps,  257-261 
Sea  water,  142 
Seal,  pump,  255 
Seat  belts,  423 
Seats,  valves,  291 

Secondary  Drinking  Water  Regulations 
chloride,  509 
color,  510 
copper,  610 
corrosivity,  510 
enforcement,  508 
foamir  '  agents,  510 
hardness,  513 
hydrogen  sulfide,  513 
Iron,  511 

iron  and  manganese,  51 1 


681 


Index  863 


manganese,  51 1 

maximum  contaminant  !evels  (MCLs),  508,  509 

monitoring,  509 

odor,  511 

pH,  512 

phenols,  513 

sulfate,  512 

total  dissolved  solids  (TDS),  512 
zinc,  512 
Selenium,  503 

Self-contained  breathing  apparatus,  409-411,^  432,  433 

Sensois,  instpjmenta  in,  348 

Service,  ion  exchange  softeners,  95,  96,  100 

Service  meters,  356 

Service  record  card,  218.  219 

Sewers,  195,  200 

Shaft,  pump,  251,  253,  253,  259 

Shear  pin,  272.  280 

Short-term  exposure,  499 

Shots,  booster,  431 

Shower,  safety,  403,  404 

Shutdown 

chemical  feeders,  52 

fluoridation,  52 

instrumentation,  378,  379 

ion  exchange  softeners,  101 

pumps,  271,282,  284,  286 
Signal  transmitters,  360 
Silver,  503 
Slake,  76,  84 

Sleeves,  pump,  261,  253,  258,  259 
Sludge  pumps,  202 
Sludge,  softening,  85 
Sludge  volumes,  184 
Snubber,  349-351 

Sodium 

aluminate,  413 
carbonate,  408 
fluoride,  20,  30,  38 
hydroxide,  407 
silicate,  407 

silicofluoride,  29,  30,  48,  50 
Softening 

also  see  Ion  exchange  softening 
and  Lime-soda  ash  softening 
additional  reading,  106 
alkalinity,  71,  73,  74,  82 
arithmetic  assignment,  106 
basic  methods,  75 
benefits,  71,  75 

calcium  carbonate  equivalent,  71,  72 

carbonate  hardness,  71 

chemical  reactions,  75-77 

chemistry,  72 

hard  water,  70 

hardness,  70-72,  75,  76 

Importance,  71 

Ion  exchange  softening,  91 

j£r  tests,  85-90 

Langelier  Index,  73 

lime-soda  ash  softening,  75,  81 

limitations,  71,  72,  75 

need,  71 

noncarbonate  hardness,  76 
permanent  hardness,  76 
pH,  73,  74 
recordkeeping,  85 
safety,  82,  84 
sludge,  85 

Er|c  .  :  0 


Stability,  73,  76,  83 

temporarv  hardness.  76 

total  hprdness,  71 

zeolitfi,  91 
Solar  lagoons,  187,  190 
Solid  chomica!  feeders,  317 
Solution  feedi.s,  31,  37 
Solution  preparation,  fluoridation,  45 
Solvents,  49b 

Specific  conductance  test  procedures,  471 
Specification  review 

electrodialysis,  168 

fluoridation,  42 
Spectrophotometer 

absorbance,  448 

calibration,  448 

description,  448 

percent  transmittance,  448 

standards,  449 

transmittance,  448 

units,  448 
Spiral  wound  membrane,  153,  154 
Split  treatment 

ion  exchange  softening,  105 

lime-soda  ash  softening,  78-81 
Stability,  water,  73,  76,  83 
Stack,  electrodialysis,  164, 1S8,  171 
Staff,  546 
Staffing,  547,  548 
Stages,  electrodialysis,  164 
Standard  deviation,  477 

Standard  operating  procedures  (SOP),  395,  429,  430,  432 

Standardization,  instrumentation,  343 

Stanc»ards,  drinking  water.  498,  499.  501,  505 

Standby  engines,  316 

Standby  power  generation,  244,  245 

Starters,  electrical,  231,  428 

Startup 

chemical  feeders,  44 

engines,  307-309.  311 

fluoridation,  44 

instrumentation,  378,  379 

ion  exchange  softeners,  101 

pumps,  282-286 

Stator,  234 
Steel  tanks,  321 
Sterilizers,  432 
Stethoscope,  274 
Stills,  water,  4C1 
Storage  of 

chemicals,  316,  415 

flammables,  419 

fuel,  315,  316 

limo,  82 

safety,  415 
Strip  chart.  364,  C36,  367,  377 
Stuffing  boxes,  pumps,  255 
Suction,  pumps,  253,  254,  256 
Sulfate 

regulations,  512 

test  procedures,  472 
Sulfur  dioxide,  412 
Sulfuric  acid,  405 
Supernatant,  190 
Supersaturated,  76 
Supervision,  547 
Supervisors,  safety.  394 

Surface  Water  Treatment  Rule  (SWTR),  496-498 
Surfactant,  510 

682 


664  Water  Treatment 


Switch  gear,  electrical.  230,  246 
Switches,  electrical,  223 
Symbols,  instrumentation.  339-341 
Synthetic  resins.  t25. 126 

r 

Tag.  warning.  222 
Tailgate  training.  398 
Tanks 

draining  and  cleaning.  185 

steel,  maintenance.  321 
Taste  rating  scale.  476 
Tastes  and  odors 

iron  and  manganese,  6 

test  procedures,  474 
Telemetering,  instrumentation.  360.  369.  372 
Television.  550 
Temperature  effects 

electrodialysis,  168 

process  wastes.  184 

reverse  osmosis.  i47, 149. 150. 156 

THM  formation,  123 
Temporary  hardness,  76 
Test  procedures 

see  Laboratory  test  procedures 
Testers,  electrical.  225 
Testing,  instrumentation.  374 
Testing  ion  exchange  softeners.  97 
Thermal  overloads.^231 
Thickening  wastes.  185,  186 
Threshold  Odor  Number  (TON).  474.  511 
Threshold  treatment,  156 
Titrate.  72 

TON  (Threshold  Odor  Number).  474.  511 
Tools,  power.  421 

Total  dissolved  solids  (TDS),  141.  479.  512 

Total  flow,  instrumentation,  356 

Total  hardness.  71 

Totalizers,  instrumentation.  365-367 

Tours,  plant.  551 

Toxicity.  553 

Traffic,  421 

Training 

administration,  548 

fluoridation.  54 

safety,  398 
•  Transducers.  357.  360 

Transformers.  223.  246.  247.  428 

Transmission,  electrical,  246 

Transmitters,  348,  357.  360 

"■travelers"  diarrhea,  499 

1  reatment  charts,  fluoridation,  45-47 

Treatment,  emergency.  565 

Trihalomethanes 

activated  carbon.  125.  i26. 129 

additional  reading.  130 

adsorption.  125. 126 

aeration,  124-127. 129 

arithmeth  assignment.  130 

bench-scale  studies.  124. 126. 128 

bromide.  119.  123.  124 

calculations.  122 

chemical  reactions,  119. 123 

chioramines,  128, 129 

chlorine.  119.  123,  124.  126,  129 

coagulation/sedimentation/filtratlon.  124. 126. 129 

control  strategies.  124 

ERIC 


disinfection  alternatives.  1 28 

existing  treatment  processes.  124 

feasibility  analysis  process.  121 

Federal  Register,  119,  129 

formation.  119,  123.  124.  126 

Group  1  a.id  2  treatment  techniques.  129 

health  effects,  119 

ion  exchange  resins.  125.  126 

maximum  contaminant  level  (MCL).  119 

monitoring.  121. 123. 128 

options  for  control.  124 

oxidation.  125. 126 

ozone.  125.  126.  128,  129 

pH.THM  formation.  123 

potassium  permanganate,  124,  126,  129 

precursors.  THM.  119.  123.  124.  126 

problem.  119 

regulations,  498,  526 

resins,  synthetic,  125 

sampling.  121.  i22 

sources  of  water.  124 

synthetic  resins,  125,  126 

temperature.  THM  formation.  123 

test  procedures.  479 

ultraviolet  ligtit,  1 25 

variance,  129 
Troubleshooting 

electrical  equipment.  234, 237-241 

engines.  307,  311.  313 

instrumentation.  37G-378 

ion  exchange  softeners.  1 00 

iron  and  manganese.  21 

pumps,  283 

reverse  osmosis,  161 
Tubular  membranes.  1C3 
Turbidimeter,  360,  361 ,  374 
Turbidity  regulations,  497,  498,  505,  518.  519 

U 

Ultrasonic  flow  measurement.  356 
Ultraviolet  light.  125 
Underfeeding,  fluoridation,  48 
Underwater  inspection,  435 
Unloader,  compressor.  288 
Unsafe  acts.  394 
Upflow  satuiatoi  s.  38.  39.  41 
Utilities,  safety,  393 

V 

Vacuum  filters,  1bG.  195. 199 
Vacuum  tank  truck,  189,  190,  200 
Valves 

automatic.  305 

butterfly.  292.  295 

check.  271.  273  296-305 

compressor.  289 

diaphragm  operated,  305,  306 

ecce,itric.  292-294 

foot.  271.  296 

gate.  289.  290 

globe.  292.  305.  306 

lubrication.  291 

maintenance.  289.  291.  2^2.  305 
operation,  289,  291 
packing,  291 
parts.  289 


6S3 


safety,  422 
seats.  291 
types.  297 
use.  289.  296 

wafer  check  valve.  296,  297,  302 
Variable  speed  belt  drives,  278 
Variance.  THM,  129 
Vaults.  Instrumentation,  348 
Vehicles 

accident  prevention,  ^i?5 

fork'ifts.  425.  426 

fur? 

mar  ,.iance,  423,  424 
operation,  423 
safety  check,  423,  424 
seat  belts,  423 
types,  423 

Velocity  sensing  flow  measurement,  356,  357 
Venturi,  358,  359 

Vertical  centrifugal  pumps,  257-259 
Viscosity,  262 
Volatile,  125 

Volatile  organic  chemicals,  504 
Voltage  testing,  225,  2^1,  428 
Volts,  221,  223,  225,  246 
Volumes  of  sludges,  184 
Volumetric  feeders,  31,  34,  35,  37 


VOM,,  374,  376 


W 


Wafer  check  valve,  296,  297,  302 
Warning  tag,  222 

Wastewater  collection  systems,  195,  200 
Water 

cooled  engines,  311 

hammer,  284 

Pollution  Control  Act,  183 

rates,  542 

safety,  434 

stills,  431 
Watts,  224 

Wearing  rings,  pumps,  271 
Welding,  422 
Wilson's  disease  502 


Zeorie 

Iron  and  manganese,  14 

softening,  91 
Zinc,  504 


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^  687 
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ERIC 


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